Handbook of Condensation Thermoplastic Elastomers
|
|
- Denis Fletcher
- 6 years ago
- Views:
Transcription
1 Handbook of Condensation Thermoplastic Elastomers Edited by Stoyko Fakirov WILEY-VCH Verlag GmbH & Co. KGaA
2
3 Handbook of Condensation Thermoplastic Elastomer Edited by S. Fakirov
4 Further Titles of Interest Th. Meyer, J. Keurentjes (Eds.) Handbook of Polymer Reaction Engineering 2005, ISBN H.-G. Elias Macromolecules Vols , ISBN , , , M. F. Kemmere, Th. Meyer (Eds.) Supercritical Carbon Dioxide in Polymer Reaction Engineering 2005, ISBN M. Xanthos (Ed.) Functional Fillers for Plastics 2005, ISBN R. C. Advincula, W. J. Brittain, K. C. Caster, J. Rühe (Eds.) Polymer Brushes 2004, ISBN S. Fakirov (Ed.) Handbook of Thermoplastic Polyesters 2002, ISBN E. S. Wilks (Ed.) Industrial Polymers Handbook Products, Processes, Applications 2000, ISBN
5 Handbook of Condensation Thermoplastic Elastomers Edited by Stoyko Fakirov WILEY-VCH Verlag GmbH & Co. KGaA
6 Editor Prof. Stoyko Fakirov University of Sofia Faculty of Chemistry 1164 Sofia Bulgaria All books published by Wiley-VCH are carefully produced. Nevertheless, authors, editor, and publisher do not warrant the information contained in these books, including this book, to be free of errors. Readers are advised to keep in mind that statements, data, illustrations, procedural details or other items may inadvertently be inaccurate. Library of Congress Card No.: Applied for British Library Cataloging-in-Publication Data: A catalogue record for this book is available from the British Library Bibliographic information published by Die Deutsche Bibliothek Die Deutsche Bibliothek lists this publication in the Deutsche Nationalbibliografie; detailed bibliographic data is available in the Internet at < WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim All rights reserved (including those of translation into other languages). No part of this book may be reproduced in any form nor transmitted or translated into machine language without written permission from the publishers. Registered names, trademarks, etc. used in this book, even when not specifically marked as such, are not to be considered unprotected by law. Printed in the Federal Republic of Germany Printed on acid-free paper Cover Design Grafik Design Schulz, Fußgönheim Printing Strauss GmbH, Mörlenbach Bookbinding Litges & Dopf, Heppenheim ISBN ISBN
7 Preface Thermoplastic elastomers (TPE) belong to a relatively new and small class of engineering plastics. Nevertheless, they enjoy a steady growth because of their unusual and very important combination of properties. During service, TPE behave as elastomers (e.g., as vulcanized natural rubber) but, in contrast to the classical elastomers, they can be processed by means of the conventional techniques and equipment utilized for all thermoplastics. This peculiarity of TPE is related to their different type of crosslinking. Unlike the classical elastomers, TPE are crosslinked by thermally labile aggregates, which melt during processing and regenerate after cooling down. This is because TPE are always block copolymers comprising the so-called hard blocks (forming solid crystallites or glassy regions), and soft blocks (imparting the elastomeric properties). TPE can be produced using all chemical approaches for polymer synthesis. By means of polycondensation and polyaddition processes the three main types of TPE can be prepared: polyester-based, polyamide-based, and polyurethanes. The polyester-based TPE were first introduced in the USA by DuPont, the polyamide-based in France, and polyurethanes are developed and applied worldwide. All they have found new and interesting applications. While the polymerization-based TPE and, partly, the poly(ether ester)s (PEE) are relatively well covered in the literature, this is not the case of polyamide-based TPE and polyurethanes when new and specific applications are considered. The main goal of this project is to combine the efforts of scientists with yearlong experience worldwide to fill this gap. A peculiarity of this international team of contributors is that for the first time the research results of a well known polymer institute in Ukraine will get the deserved credit that, for understandable reasons, was not possible some years ago. For instance, the application opportunities of polyurethanes were broadened significantly by preparing systems with various chemical compositions and molecular structures as (semi) interpenetrating networks. Another peculiarity is the fact that for the first time detailed information regarding the most important polyamide-based TPE will
8 be offered by the team who created them. Last but not least, thermoplastic elastomers, being multi-block copolymers comprising entities built up of very flexible ( soft ) chains and others of much less flexible ( hard ) chains, are capable of displaying such unique properties as shape memory effects. For this reason, they belong to the group of intelligent ( smart ) materials with interesting and completely new technical and biomedical applications. This book covers the chemical aspects, physical structure and properties, application opportunities, life cycle assessment, recycling possibilities, and the future trends of the three classes of thermoplastic elastomers. It should be mentioned that the Contributors, the Editor, as well as the Publisher are well aware that, strictly speaking, the title Condensation Thermoplastic Elastomers is chemically not sufficiently correct for the covered classes of polymers. Nevertheless, it was preferred, e.g., to the chemically correct title Thermoplastic Elastomers by Polycondensation and Polyaddition, at least for the following reasons: (i) the polyurethane group behaves chemically much more as a typical polyester or polyamide group, rather than as a polyolefin, (ii) similarly to other cases (e.g., the synthesis of nylon 6) regardless of the chemical route of the synthesis, via polymerization or via polycondensation, the final polymer is distinguished by a chemical structure typical of polycondensates, and (iii) the selected title sounds more comprehensive and more attractive. As the Editor, I have enjoyed working with the individual contributors and have greatly appreciated their support, prompt response, and patience. By analogy with my previously edited books, this one could hardly be realized in its present shape without the generous advice and suggestions of my friend, Prof. J. Karger-Kocsis, who was involved in the design of this project from the very beginning, and to whom I would like to express my most cordial gratitude. This book could not have been produced without the constant support of my colleague of many years, Ms. S. Petrovich, who has maintained contact with contributors, polished the English, and helped in the processing of the book. For this, I express my sincere gratitude. The Authors, The Editor, and the Publisher would like to thank all those publishers, who generously gave their permission to reprint materials from their own publications. Details are given at the end of the book. Last but not least, I am grateful to the Foundation of Science and Technology of New Zealand, who made possible the sabbatical visit of the Editor at the University of Auckland, Department of Mechanical Engineering, Centre for Advanced Composite Materials, where this project was finalized. S. Fakirov Auckland, December 2004
9 Contents PART I Chapter 1 INTRODUCTION Creation and Development of Thermoplastic Elastomers, and Their Position Among Organic Materials E. Maréchal 1. Birth and development of TPEs: a brief survey Main routes to thermoplastic elastomer preparation Living anionic polymerization Living cationic polymerization Controlled radical polymerization Polycondensation and polyaddition Chemical modification and grafting Preparation by blending Preparation by dynamic vulcanization Techniques used in the characterization of TPEs Chromatography Spectrometric techniques Scattering techniques Microscopies Controlled degradation Thermal techniques Properties and processing of TPEs Injection molding Compression molding Extrusion Blow processings Thermoforming Reactive processings Degradation in processing... 15
10 viii Content 5. Position of TPEs among organic materials and their applications Future trends References Chapter 2 Polycondensation Reactions in Thermoplastic Elastomer Chemistry: State of the Art, Trends, and Future Developments E. Maréchal 1. Introduction Preparation of block copolymers by polycondensation. A critical review General considerations Direct polycondensation of α,ω-difunctional oligomers Polycondensation of an α,ω-difunctional oligomer with the precursors of another block Oligomer-coupling reactions Characterization techniques. Side reactions New structures Block copolymers containing liquid crystalline structures Liquid crystalline sequences as part of the backbone Liquid crystalline sequences as side chains Metallo-supramolecular block copolymers Block copolymers prepared from metal-containing macrocycles The use of microorganisms Conclusions References PART II Chapter 3 POLYESTER-BASED THERMOPLASTIC ELASTOMERS Polyester Thermoplastic Elastomers: Synthesis, Properties, and Some Applications Z. Roslaniec 1. Introduction Chemical structure of polyester elastomers Poly(alkylene oxide) flexible segment-based polyester elastomers... 79
11 Content ix 4. Modified poly(butylene terephthalate) rigid segment-based polyester elastomers Branched polyester elastomers Synthesis of poly(ether ester) block copolymers Other multiblock polyester elastomers Polyester thermoplastic elastomers from blends A new processing aspect: weldability of polyester elastomers Polyester elastomers for biomedical application Conclusions and outlook References Chapter 4 Terpoly(Ester-b-Ether-b-Amide) Thermoplastic Elastomers: Synthesis, Structure, and Properties R. Ukielski 1. Introduction Chemical structure of terpoly(ester-b-ether-b-amide)s Synthesis of triblock (GT-b-PO4-b-PA) n polymers Solubility of the blocks Structure-property relationships Thermal properties of (4GT-b-PO4-b-PA12) n Phase composition of terpoly(ester-b-ether-b-amide)s Mechanical properties of (4GT-b-PO4-b-PA12) n Conclusions and outlook References Chapter 5 High Performance Thermoplastic Aramid Elastomers: Synthesis, Properties, and Applications H. Yamakawa, H. Miyata 1. Introduction Development of thermoplastic aramid elastomers Type I poly(aramid-b-polyether) elastomers Synthesis of reactive aramid compounds Synthesis of aramid elastomers Thermal properties Mechanical properties
12 x Content 3.5. Dynamic-mechanical properties Chemical properties Type II poly(aramid-b-polyether) elastomers Synthesis of reactive aramid compounds Synthesis of aramid elastomers Thermal properties Mechanical properties Chemical properties Aramid elastomers with other polyether soft segments Poly(aramid-b-polyester) elastomers Synthesis and properties of aramid-b-polyester elastomers A novel synthetic route to aramid-b-polyester elastomers Applications Conclusions References Chapter 6 Poly(Ether Ester) Thermoplastic Elatomers: Phase and Deformation Behavior on the Nano- and Microlevel S. Fakirov 1. Introduction Phase behavior of PEEs Number of phases present and their miscibility Amorphous phase distribution in PEE copolymers Does crystal thickening exist in segmented and multiblock copolymers? Deformation behavior of PEE as revealed by small-angle X-ray scattering Effect of chain flexibility on the deformation of PET, PBT, PEE, and PBT/PEE blend Relationship between macro- and nano-deformation in PEE Chord distribution of a neat EM400 bristle Nanostructure evolution during the straining cycle Conclusions and outlook Acknowledgement References
13 Content xi Chapter 7 Condensation Thermoplastic Elastomers Under Load: Methodological Studies of Nanostructure Evolution by X-ray Scattering N. Stribeck 1. Introduction Phase separation Living nanostructure X-ray techniques in process monitoring Progress in technology and methodology Materials Basic notions Nanostructure topology Non topological parameters Isotropic vs. anisotropic SAXS patterns Multidimensional chord distributions Longitudinal and transverse structure Void scattering Theoretical Basic definitions in SAXS Projections and sections Projections useful for TPEs studied under uniaxial load Correlation functions and their derivatives Data processing Nanostructure evolution and processes observed with condensation TPEs Poly(ether ester)s during straining Swollen and drawn poly(ether amide)s Acknowledgement References Chapter 8 Dielectric Relaxation of Polyester-Based Thermoplastic Elastomers T. A. Ezquerra 1. Introduction Study of the relaxation behavior by means of dielectric spectroscopy Dielectric spectroscopy of poly(ether ester) thermoplastic elastomers Dielectric spectroscopy of multiblock thermoplastic elastomers Relaxation behavior of poly(ester carbonate) block copolymer across the melting region
14 xii Content 6. Conclusion Acknowledgement References PART III Chapter 9 POLYAMIDE-BASED THERMOPLASTIC ELASTOMERS Thermoplastic Poly(Ether-b-Amide) Elastomers: Synthesis F. L. G. Malet 1. Introduction Chemical structure of TPE Synthetic methods Polymerization in solution Interfacial polymerization Direct polycondensation using condensing agents Anionic polymerization Thermal polymerization Thermal polymerization of TPE-A with ester links Polymerization processes Nature of the raw materials Influence of the catalyst Influence of the molar ratio Influence of the temperature Influence of the stirring Influence of the vacuum level Conclusion References Chapter 10 Poly(Ether-b-Amide) Thermoplastic Elastomers: Structure, Properties, and Applications R.-P. Eustache 1. Structure and characterization Crystallinity and morphology Microphase separation vs. hard and soft segment block length
15 Content xiii 2. Properties Mechanical properties Physico-chemical properties Processing Applications Sporting goods Medicine Industry Breathable structures Fragrance carrier Polymer additives and polymer components Conclusions and outlook References Chapter 11 Semicrystalline Segmented Poly(Ether-b- Amide) Copolymers: Overview of Solid-State Structure-Property Relationships and Uniaxial Deformation Behavior J. P. Sheth, G. L. Wilkes 1. Introduction PTMO-PA12 based copolymers Mechanical properties Thermal analysis Structure determination by scattering and microscopy studies Uniaxial deformation behavior Other poly(ether-b-amide) copolymers Poly(ethylene oxide)-based PEBA PEBA based on aromatic PA segments of uniform length Conclusion References
P. M. Ajayan, L. S. Schadler, P. V. Braun Nanocomposite Science and Technology
P. M. Ajayan, L. S. Schadler, P. V. Braun Nanocomposite Science and Technology Nanocomposite Science and Technology. Edited by P.M. Ajayan, L.S. Schadler, P.V. Braun Copyright ª 2003 WILEY-VCH Verlag GmbH
More informationLiquid Crystal. Liquid Crystal. Liquid Crystal Polymers. Liquid Crystal. Orientation of molecules in the mesophase
Liquid Crystal - Liquid crystals (LCs) are a state of matter that have properties between those of a conventional liquid and those of a solid crystal. (Fourth state of matter) Liquid Crystal Orientation
More informationAn Introduction to Polymer Physics
An Introduction to Polymer Physics David I. Bower Formerly at the University of Leeds (CAMBRIDGE UNIVERSITY PRESS Preface Acknowledgements xii xv 1 Introduction 1 1.1 Polymers and the scope of the book
More informationTitle: Cesa-extend a User Friendly Technology to Enhance Reprocessing and Recycling of Condensation Plastics
GPEC 24 Paper Abstract #52: Title: Cesa-extend a User Friendly Technology to Enhance Reprocessing and Recycling of Condensation Plastics Author(s): V. Karayan, Clariant Masterbatches, and M. Villalobos,
More informationPaul Rempp and Edward W. Merrill. Polymer Synthesis. 2nd, revised Edition. Hüthig & Wepf Verlag Basel Heidelberg New York
Paul Rempp and Edward W. Merrill Polymer Synthesis 2nd, revised Edition Hüthig & Wepf Verlag Basel Heidelberg New York Table of Contents Part I: Polymerization Reactions Chapter 1: General Considerations
More informationTOPIC 7. Polymeric materials
Universidad Carlos III de Madrid www.uc3m.es MATERIALS SCIENCE AND ENGINEERING TOPIC 7. Polymeric materials 1. Introduction Definition General characteristics Historic introduction Polymers: Examples 2.
More informationMembrane Technology. in the Chemical Industry. Edited by Suzana Pereira Nunes and Klaus-Viktor Peinemann. Second, Revised and Extended Edition
Membrane Technology in the Chemical Industry Edited by Suzana Pereira Nunes and Klaus-Viktor Peinemann Second, Revised and Extended Edition Membrane Technology Edited by Suzana Pereira Nunes and Klaus-Viktor
More informationPeriodic table with the elements associated with commercial polymers in color.
Polymers 1. What are polymers 2. Polymerization 3. Structure features of polymers 4. Thermoplastic polymers and thermosetting polymers 5. Additives 6. Polymer crystals 7. Mechanical properties of polymers
More informationVeronika R. Meyer. Pitfalls and Errors of HPLC in Pictures
Veronika R. Meyer Pitfalls and Errors of HPLC in Pictures Further Titles for Chromatographers S. Kromidas (ed.) HPLC Made to Measure A Practical Handbook for Optimization 2006 ISBN 3-527-31377-X P. C.
More informationIntroduction to Synthetic Methods in Step-Growth Polymers 1.1 INTRODUCTION Historical Perspective Some of the earliest useful polymeric
Synthetics Polymers Introduction to Synthetic Methods in Step-Growth Polymers 1.1 INTRODUCTION 1.1.1 Historical Perspective Some of the earliest useful polymeric materials, the Bakelite resins formed from
More informationLecture No. (1) Introduction of Polymers
Lecture No. (1) Introduction of Polymers Polymer Structure Polymers are found in nature as proteins, cellulose, silk or synthesized like polyethylene, polystyrene and nylon. Some natural polymers can also
More informationPOLYMERS: CHEMISTRY AND PHYSICS OF MODERN MATERIALS
POLYMERS: CHEMISTRY AND PHYSICS OF MODERN MATERIALS THIRD EDITION J.M.G. COWIE Heriot-Watt University Scotland,UK VALERIA ARRIGHI Heriot-Watt University Scotland,UK Contents Preface The Authors xv xvii
More informationPolymer engineering syllabus (BSc)
Polymer engineering syllabus (BSc) First semester Math 1 Physics 1 Physics 1 lab General chemistry General chemistry lab workshop Second semester Math 2 Physics 2 Organic chemistry 1 Organic chemistry
More informationSimple Methods for Identification of Plastics
Dietrich Braun Simple Methods for Identification of Plastics 5 th Edition Braun Simple Methods for Identification of Plastics Dietrich Braun Simple Methods for Identification of Plastics 5 th Edition
More informationMaterials Engineering with Polymers
Unit 73: Unit code Materials Engineering with Polymers K/616/2556 Unit level 4 Credit value 15 Introduction This unit will provide students with the necessary background knowledge and understanding of
More informationRelativistic Quantum Mechanics and Field Theory
Relativistic Quantum Mechanics and Field Theory Relativistic Quantum Mechanics and Field Theory FRANZ GROSS College of William and Mary Williamsburg, Virginia and Continuous Electron Beam Accelerator Facility
More informationAPPLIED NONLINEAR DYNAMICS
APPLIED NONLINEAR DYNAMICS Analytical, Computational, and Experimental Methods Ali H. Nayfeh Virginia Polytechnic Institute and State University Balakumar Balachandran University of Maryland WILEY- VCH
More informationJames F. Haw In-Situ Spectroscopy in Heterogeneous Catalysis
James F. Haw In-Situ Spectroscopy in Heterogeneous Catalysis In-Situ Spectroscopy in Heterogeneous Catalysis. By James F. Haw Copyright O 2002 Wiley-VCH Verlag GmbH & Co. KGaA ISBN: 3-527-30248-4 Related
More informationIntroduction to Reactive Extrusion
3 1 Introduction to eactive Extrusion Christian Hopmann, Maximilian Adamy, and Andreas Cohnen WTH Aachen University, Institute of Plastic Processing (IKV), Seffenter Weg 201, D-52074 Aachen, Germany Engineering
More informationAhmet Gürses. Introduction to Polymer Clay Nanocomposites
Ahmet Gürses Introduction to Polymer Clay Nanocomposites Introduction to Polymer Clay Nanocomposites Introduction to Polymer Clay Nanocomposites Ahmet Gürses Published by Pan Stanford Publishing Pte.
More informationPoly(ether-ester) Multiblock Copolymers Based on Poly(oxymethylene-alt-oxyalkylene) Glycols
Macromolecular Research, Vol. 10, No. 4, pp 230-235 (2002) Poly(ether-ester) Multiblock Copolymers Based on Poly(oxymethylene-alt-oxyalkylene) Glycols Jin Bong Kim*, Jae Hwan Chun, Dong Hee Kim, Yun Hee
More information240EQ016 - Polymers and Biopolymers
Coordinating unit: Teaching unit: Academic year: Degree: ECTS credits: 2018 295 - EEBE - Barcelona East School of Engineering 713 - EQ - Department of Chemical Engineering MASTER'S DEGREE IN CHEMICAL ENGINEERING
More informationCOMPATIBILIZERS VISCOSITY CHAIN EXTENDERS MODIFIERS XIBOND BLEND OPTIMIZERS COUPLING AGENTS SURFACE MODIFIERS
COMPATIBILIZERS CHAIN EXTENDERS VISCOSITY MODIFIERS XIBOND BLEND OPTIMIZERS SURFACE MODIFIERS COUPLING AGENTS XIBOND Blend Optimizers At Polyscope, we offer a wide range of polymer additives for the compounding
More information(Refer Slide Time: 00:58)
Nature and Properties of Materials Professor Bishak Bhattacharya Department of Mechanical Engineering Indian Institute of Technology Kanpur Lecture 18 Effect and Glass Transition Temperature In the last
More informationPolymers in Modified Asphalt Robert Q. Kluttz KRATON Polymers
Polymers in Modified Asphalt Robert Q. Kluttz KRATON Polymers Polymers in Modified Asphalt Types of Polymers Compatibility of Polymers Effects of Polymers Analysis of polymers Recovery of PMA What Is a
More informationMATERIALS SCIENCE POLYMERS
POLYMERS 1) Types of Polymer (a) Plastic Possibly the largest number of different polymeric materials come under the plastic classification. Polyethylene, polypropylene, polyvinyl chloride, polystyrene,
More informationPolymer Reaction Engineering
Polymer Reaction Engineering Polymerization Techniques Bulk Solution Suspension Emulsion Interfacial Polymerization Solid-State Gas-Phase Plasma Polymerization in Supercritical Fluids Bulk Polymerization
More informationPOLYMER SCIENCE : lecture 1. Dr. Hanaa J. Alshimary Second class Poly. Eng. Dep. Introduction of Polymers Polymer poly mer Monomer Polymerization
Introduction of Polymers Polymer - The word polymer is the Greek word : poly means many and mer means unit or parts, A Polymer is a large molecule that comprises repeating structural units joined by the
More informationMechanical Properties of Polymers. Scope. MSE 383, Unit 3-1. Joshua U. Otaigbe Iowa State University Materials Science & Engineering Dept.
Mechanical Properties of Polymers Scope MSE 383, Unit 3-1 Joshua U. Otaigbe Iowa State University Materials Science & Engineering Dept. Structure - mechanical properties relations Time-dependent mechanical
More informationChemistry by Computer. An Overview of the Applications of Computers in Chemistry
Chemistry by Computer An Overview of the Applications of Computers in Chemistry Chemistry by Computer An Overview of the Applications of Computers in Chemistry Stephen Wilson Theoretical Chemistry Department
More informationThe vibrational spectroscopy of polymers
D. I. BOWER Reader in Polymer Spectroscopy Interdisciplinary Research Centre in Polymer Science & Technology Department of Physics, University of Leeds W.F. MADDAMS Senior Visiting Fellow Department of
More informationStructure and Properties of Oriented Polymers
Structure and Properties of Oriented Polymers Structure and Properties of Oriented Polymers Edited by 1. M. Ward IRC in Polymer Science and Technology Universities of Leeds, Bradford and Durham UK I uni
More informationProperties of polypropylene modified with elastomers
Plasticheskie Massy, No. 5, 2005, pp. 31 34 Properties of polypropylene modified with elastomers G. M. Danilova-Volkovskaya Rostov State Academy of Agricultural Engineering Selected from International
More information2. Amorphous or Crystalline Structurally, polymers in the solid state may be amorphous or crystalline. When polymers are cooled from the molten state
2. Amorphous or Crystalline Structurally, polymers in the solid state may be amorphous or crystalline. When polymers are cooled from the molten state or concentrated from the solution, molecules are often
More informationEdited by Avraam I. Isayev. Encyclopedia of Polymer Blends
Edited by Avraam I. Isayev Encyclopedia of Polymer Blends Related Titles Isayev, Avraam I. (ed.) Encyclopedia of Polymer Blends Volume 1: Fundamentals 2010 PRINT ISBN: 978-3-527-31929-9 Isayev, Avraam
More informationTable of Contents. Synthetic Polymer-Polymer Composites. Herausgegeben von Debes Bhattacharyya, Stoyko Fakirov. ISBN (Buch):
Table of Contents Synthetic Polymer-Polymer Composites Herausgegeben von Debes Bhattacharyya, Stoyko Fakirov ISBN (Buch): 978-1-56990-510-4 ISBN (E-Book): 978-1-56990-525-8 For further information and
More informationPolymers on the Crime Scene
Polymers on the Crime Scene Valerio Causin Polymers on the Crime Scene Forensic Analysis of Polymeric Trace Evidence Valerio Causin Università di Padova Padova, Italy ISBN 978-3-319-15493-0 DOI 10.1007/978-3-319-15494-7
More informationSIZE EXCLUSION CHROMATOGRAPHY
SIZE EXCLUSION CHROMATOGRAPHY Edited by B.J. HUNT Polymer Research Group Department of Chemistry University of Lancaster and S.R. HOLDING RAPRA Technology Ltd Shrewsbury Springer-Science+Business Media,
More informationUnit title: Polymer Chemistry
Unit title: Polymer Chemistry Unit code: L/601/0415 QCF level: 5 Credit value: 15 Aim This unit enables learners to gain an understanding of aspects of the structure, reaction mechanisms and polymer preparations.
More informationPolymers and Composite Materials
Polymers and omposite Materials Shibu G. Pillai hemical Engineering Department shibu.pillai@nirmauni.ac.in ontents lassification of Polymers Types of polymerization Elastomers/ Rubber Advanced Polymeric
More informationMechanical properties of polymers: an overview. Suryasarathi Bose Dept. of Materials Engineering, IISc, Bangalore
Mechanical properties of polymers: an overview Suryasarathi Bose Dept. of Materials Engineering, IISc, Bangalore UGC-NRCM Summer School on Mechanical Property Characterization- June 2012 Overview of polymer
More informationQuick Facts College of Polymer Science and Polymer Engineering
Minor in Polymer Science and Polymer Engineering Program Description: This minor is a 6 course/18 credit program that provides students a broad foundation in polymer science and polymer engineering through
More informationMATERIALS SCIENCE TEST Part 1: Structure & Synthesis Topics
Fairfax Science Olympiad Tryouts 2018 Name: _ Score: /75 MATERIALS SCIENCE TEST Part 1: Structure & Synthesis Topics In questions 1-6, draw a diagram of the named functional group. Use R to denote the
More informationMultiple mechanisms can attack polymer chains here s what can go wrong. By Jeffrey Jansen the Madison group, Madison, Wisconsin, Usa
CONSULTANT S CORNER Plastic Failure Through Molecular Degradation Multiple mechanisms can attack polymer chains here s what can go wrong By Jeffrey Jansen the Madison group, Madison, Wisconsin, Usa [Note:
More informationPART I FUNDAMENTALS OF SUPRAMOLECULAR POLYMERS COPYRIGHTED MATERIAL
PART I FUNDAMENTALS OF SUPRAMOLECULAR POLYMERS COPYRIGHTED MATERIAL CHAPTER 1 A BRIEF INTRODUCTION TO SUPRAMOLECULAR CHEMISTRY IN A POLYMER CONTEXT RAYMOND J. THIBAULT and VINCENT M. ROTELLO 1.1. INTRODUCTION
More informationPROPERTIES OF POLYMERS
PROPERTIES OF POLYMERS THEIR CORRELATION WITH CHEMICAL STRUCTURE; THEIR NUMERICAL ESTIMATION AND PREDICTION FROM ADDITIVE GROUP CONTRIBUTIONS Third, completely revised edition By D.W. VÄN KREVELEN Professor-Emeritus,
More informationMohamed Daoud Claudine E.Williams Editors. Soft Matter Physics. With 177 Figures, 16 of them in colour
Mohamed Daoud Claudine E.Williams Editors Soft Matter Physics With 177 Figures, 16 of them in colour Contents 1. Droplets: CapiUarity and Wetting 1 By F. Brochard-Wyart (With 35 figures) 1.1 Introduction
More informationIntroduction to Engineering Materials ENGR2000 Chapter 14: Polymer Structures. Dr. Coates
Introduction to Engineering Materials ENGR2000 Chapter 14: Polymer Structures Dr. Coates 14.1 Introduction Naturally occurring polymers Wood, rubber, cotton, wool, leather, silk Synthetic polymers Plastics,
More informationINORGANIC AND ORGANOMETALLIC POLYMERS
INORGANIC AND ORGANOMETALLIC POLYMERS RONALD D. ARCHER Professor Emeritus University of Massachusetts, Amherst A John Wiley & Sons, Inc., Publication New York ž Chichester ž Weinheim ž Brisbane ž Singapore
More informationSCH4U Synthesis and Polymers. Synthesis Reactions and Addition and Condensation Polymers
SCH4U Synthesis and Polymers Synthesis Reactions and Addition and Condensation Polymers ADDITION POLYMERS ADDITION POLYMERS A + A + A + A A A A A monomers polymer + + + ethylene (ethene) polyethylene
More informationWolfgang Demtroder Molecular Physics
Wolfgang Demtroder Molecular Physics Related Titles Bethge, K., Gruber, G., Stohlker, T. Physik der Atome und Molekiile Eine Einfuhrung 437 pages with 192 figures 2004, Hardcover ISBN 3-527-40463-5 Hollas,
More informationLandolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W.
Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W. Martienssen Group VIII: Advanced Materials and Technologies Volume 6 Polymers Subvolume
More informationInitial Boundary Value Problems in Mathematical Physics
Initial Boundary Value Problems in Mathematical Physics Initial Boundary Value Problems in Mathematical Physics Rolf leis University of Bonn Federal Republic of Germany Springer Fachmedien Wiesbaden GmbH
More informationPolymer Blends: State of the Art, New Challenges, and Opportunities
1 1 Polymer Blends: State of the Art, New Challenges, and Opportunities Jyotishkumar Parameswaranpillai, Sabu Thomas, and Yves Grohens 1.1 Introduction A polymer blend is a mixture of two or more polymers
More informationGUJARAT TECHNOLOGICAL UNIVERSITY, AHMEDABAD, GUJARAT COURSE CURRICULUM. Course Title: Polymer Chemistry (Code: )
GUJARAT TECHNOLOGICAL UNIVERSITY, AHMEDABAD, GUJARAT COURSE CURRICULUM Course Title: Polymer (Code: 3322301) Diploma Programme in which this course is offered Plastic Engineering Semester in which offered
More informationUV-VIS Spectroscopy and Its Applications
SPRINGER LABORATORY Heinz-Helmut Perkampus UV-VIS Spectroscopy and Its Applications Translated by H. Charlotte Grinter and Dr. T. L. Threlfall With 78 Figures and 21 Tables Springer -Ver lag Berlin Heidelberg
More informationEffect of crystallinity on properties. Melting temperature. Melting temperature. Melting temperature. Why?
Effect of crystallinity on properties The morphology of most polymers is semi-crystalline. That is, they form mixtures of small crystals and amorphous material and melt over a range of temperature instead
More informationLecture Notes in Artificial Intelligence
Lecture Notes in Artificial Intelligence Subseries of Lecture Notes in Computer Science Edited by J.G. Carbonell and J. Siekmann 1047 Lecture Notes in Computer Science Edited by G. Goos, J. Hartmanis and
More informationAdvances in shape memory polymers
Woodhead Publishing Series in Textiles: Number 146 Advances in shape memory polymers Jinlian Hu TheTextile Institute WP WOODHEAD PUBLISHING Oxford Cambridge Philadelphia New Delhi Contents Woodhead Publishing
More informationPROGRESS IN INORGANIC CHEMISTRY. Volume 11
PROGRESS IN INORGANIC CHEMISTRY Volume 11 Advisory Board THEODORE L. BROWX UNIVERSITY OF ILLINOIS, URBANA, ILLINOIS JAhlES P. COLLMAK STANFORD UNIVERSITY, STANFORD, CALIFORNIA F. ALBERT COTTON M.I.T.,
More informationNuclear Magnetic Resonance Data
Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W. Martienssen Group III: Condensed Matter Volume 35 Nuclear Magnetic Resonance Data
More informationREACTIVE POLYMERS FUNDAMENTALS AND APPLICATIONS
REACTIVE POLYMERS FUNDAMENTALS AND APPLICATIONS A CONCISE GUIDE TO INDUSTRIAL POLYMERS Johannes Karl Fink Montanuniversität Leoben Leoben, Austria Copyright 2005 by William Andrew, Inc. No part of this
More informationChemistry Class 12 th NCERT Solutions
This e-book is prepared by the CBSE board exam experts of jagranjosh.com, an online educational portal of Dainik Jagran. The purpose of providing solutions for CBSE class 12 th Science and Mathematics
More informationFoundations and Applications of Engineering Mechanics
Foundations and Applications of Engineering Mechanics 4843/24, 2nd Floor, Ansari Road, Daryaganj, Delhi - 110002, India Cambridge University Press is part of the University of Cambridge. It furthers the
More informationrace to the Second Edition Preface to the First Edition 'kno\t'ledgements Contents
Contents race to the Second Edition Preface to the First Edition 'kno\t'ledgements Chemistry and Basic Intermediates. Introduction. Basic Chemistry Basic Structure of a Polyurethane Elastomer. Synthesis
More informationA Glossary of Terms Used in the Adhesives, Coatings and Elastomers (ACE) Sector
A Glossary of Terms Used in the Adhesives, Coatings and Elastomers (ACE) Sector Abrasion resistance The ability of the coating membrane to resist mechanical action such as foot traffic and particles, which
More informationPolymer Composite Materials - Interface Phenomena & Processes
Polymer Composite Materials - Interface Phenomena & Processes SOLID MECHANICS AND ITS APPLICATIONS Volume 90 Series Editor: G.M.L. GLADWELL Department of Civil Engineering University of Waterloo Waterloo,
More informationContents. Preface XIII. 1 General Introduction 1 References 6
VII Contents Preface XIII 1 General Introduction 1 References 6 2 Interparticle Interactions and Their Combination 7 2.1 Hard-Sphere Interaction 7 2.2 Soft or Electrostatic Interaction 7 2.3 Steric Interaction
More informationShape Memory Polymers:
Shape Memory Polymers: Fundamentals, Advances and Applications Jinlian Hu SMITHERS R A P R A A Smithers Group Company Shawbury, Shrewsbury, Shropshire, SY4 4NR, United Kingdom Telephone: +44 (0)1939 250383
More informationChapter 13 - Polymers Introduction
Chapter 13 - Polymers Introduction I. Nomenclature A. Polymer/Macromolecule polymer - nonmetallic material consisting of large molecules composed of many repeating units - from Greek: poly (many) and meros
More informationOrientational behavior of liquid-crystalline polymers with amide groups
Advances in Materials 2014; 3(6): 89-93 Published online January 06, 2015 (http://www.sciencepublishinggroup.com/j/am) doi: 10.11648/j.am.20140306.14 ISSN: 2327-2503 (Print); ISSN: 2327-252X (Online) Orientational
More informationPOLYMER CHEMISTRY AN INTRODUCTION. Malcolm P. Stevens. University of Hartford. New York Oxford OXFORD UNIVERSITY PRESS
T H I R D E D I T I O N POLYMER CHEMISTRY AN INTRODUCTION Malcolm P. Stevens University of Hartford New York Oxford OXFORD UNIVERSITY PRESS 1999 CONTENTS Preface, PART I xvii POLYMER STRUCTURE AND PROPERTIES
More informationPOLYMER CHEMISTRY. An Introduction. Malcolm P. Stevens University of Hartford SECOND EDITION
POLYMER CHEMISTRY An Introduction SECOND EDITION Malcolm P. Stevens University of Hartford New York Oxford OXFORD UNIVERSITY PRESS 1990 Contents PART I POLYMER STRUCTURE AND PROPERTIES 1. Basic principles,
More informationChristel Anne Ross. Invasion Success by Plant Breeding
Christel Anne Ross Invasion Success by Plant Breeding VIEWEG+TEUBNER RESEARCH Christel Anne Ross Invasion Success by Plant Breeding Evolutionary Changes as a Critical Factor for the Invasion of the Ornamental
More informationThe chemistry of. a-haloketones, a-haloaldehydes and a-haloimines
The chemistry of a-haloketones, a-haloaldehydes and a-haloimines THE CHEMISTRY OF FUNCTIONAL GROUPS A series of advanced treatises under the general editorship of Professor Saul Patai The chemistry of
More informationNMR Spectroscopy of Polymers
r NMR Spectroscopy of Polymers Edited by ROGER N. IBBETT Courtaulds Research and Technology Coventry BLACKIE ACADEMIC & PROFESSIONAL An Imprint of Chapman & Hall London Glasgow New York Tokyo Melbourne
More information1.1 Basic Polymer Chemistry. 1.2 Polymer Nomenclature. 1.3 Polymer Synthesis. 1.4 Chain Growth Polymerization. Polymer =
1.1 Basic Polymer hemistry Polymers are the largest class of soft materials: over 100 billion pounds of polymers made in US each year lassification systems 1.2 Polymer Nomenclature Polymer = Monomer =
More informationAdvanced Structured Materials
Advanced Structured Materials Volume 26 Series editors Andreas Öchsner, Southport Queensland, Australia Lucas F.M. da Silva, Porto, Portugal Holm Altenbach, Magdeburg, Germany More information about this
More information240EQ232 - Polymer Experimental Methods
Coordinating unit: Teaching unit: Academic year: Degree: ECTS credits: 2018 295 - EEBE - Barcelona East School of Engineering 713 - EQ - Department of Chemical Engineering MASTER'S DEGREE IN CHEMICAL ENGINEERING
More informationION EXCHANGE TRAINING MANUAL
ION EXCHANGE TRAINING MANUAL GEORGE P. SIMON ~ SPRINGER SCIENCE+BUSINESS MEDIA, LLC Copyright 1991 by Springer Science+ Business Media New York Originally published by Van Nostrand Reinhold in 1991 Library
More informationHigh strength high modulus Fibres
High strength high modulus Fibres Module 2: FAQ Q1. Define aramids. A manufactured fibre in which the fibre-forming substance is a long-chain synthetic polyamide in which at least 85% of the amide (-CO-NH-)
More informationCombustion and thermal degradation of polymers
Polymers and biomaterials - laboratory Combustion and thermal degradation of polymers Theoretical background dr Hanna Wilczura-Wachnik University of Warsaw Faculty of Chemistry Chemical Technology Division
More informationA polymer is a very large molecule that is built from monomers. A monomer is one of the repeating units that make up a polymer.
1.8 Polymers The General Structure of Polymers A polymer is a very large molecule that is built from monomers. A monomer is one of the repeating units that make up a polymer. Many biological molecules,
More informationAging behavior of polymeric absorber materials for solar thermal collectors
Aging behavior of polymeric absorber materials for solar thermal collectors Susanne Kahlen, Gernot M. Wallner, Reinhold W. Lang July, 211 Introduction Plastics based collectors 2 SOLARNOR all-polymeric
More informationMETHODS FOR PROTEIN ANALYSIS
METHODS FOR PROTEIN ANALYSIS Robert A. Copeland, PhD The DuPont Merck Pharmaceutical Company Experimental Station P.O. Box 80400 Wilmington, DE 19880-0400 METHODS FOR PROTEIN ANALYSIS A Practical Guide
More informationPolymers. Steep Slope = 3/5 : Self-Avoiding Walk (Polymer Solution) Shallow Slope = 1/2 : Gaussian Random Walk (Polymer Melt)
Polymers 1 Polymers Steep Slope = 3/5 : Self-Avoiding Walk (Polymer Solution) Shallow Slope = 1/2 : Gaussian Random Walk (Polymer Melt) 2 If we consider a series of chains = 0 Except when i = j, and
More informationDEPARTMENT OF POLYMER AND PROCESS ENGINEERING (http://www.uet.edu.pk/polymer.htm)
DEPARTMENT OF POLYMER AND PROCESS ENGINEERING (http://www.uet.edu.pk/polymer.htm) Programs Offered The Department offers the following degree programmes a) M.Sc. Polymer and Process Engineering b) Ph.D.
More informationRubber Nanocomposites and Nanotextiles in Automobiles
Preface In the early 1990s, a research team from Toyota Central Research Development Laboratories in Japan worked on Nylon 6 clay nanocomposites and revealed an improved process for producing Nylon 6 clay
More informationChapter : 15. POLYMERS. Level-1:Questions
1) What are polymers? Chapter : 15. POLYMERS Level-1:Questions A: These are referred to as Macromolecules which are formed by joining of repeating structural units on a large scale. 2) Give two examples
More informationAn Introduction to Polymer Physics
An Introduction to Polymer Physics Why & What Why do you choose this course? What do you know about polymer (physics)? Wentao Hao College of Chemical Engineering Hefei University of 2 Physics Physics (Greek(
More informationCOMPOSITE MATERIALS. Asst. Prof. Dr. Ayşe KALEMTAŞ
COMPOSITE MATERIALS Office ours: Tuesday, 16:30-17:30 akalemtas@mu.edu.tr, akalemtas@gmail.com Phone: +90 252 211 19 17 Metallurgical and Materials Engineering Department ISSUES TO ADDRESS Polymers Applications
More informationGünter Zschornack Handbook of X-Ray Data
Günter Zschornack Handbook of X-Ray Data Günter Zschornack Handbook of X-Ray Data With 113 Figures and 161 Tables 123 Ass.-Prof. Dr. rer. nat. habil. Günter Zschornack Technische Universität Dresden Institut
More informationStress Relaxation Behaviour of PALFnDPE Composites
Chapter 7 Stress Relaxation Behaviour of PALFnDPE Composites The results presented in this chapter have been communicated for publication to Journal of Reinforced Plastics and Composites. 7.1 Introduction
More informationPROTEIN SEQUENCING AND IDENTIFICATION USING TANDEM MASS SPECTROMETRY
PROTEIN SEQUENCING AND IDENTIFICATION USING TANDEM MASS SPECTROMETRY Michael Kinter Department of Cell Biology Lerner Research Institute Cleveland Clinic Foundation Nicholas E. Sherman Department of Microbiology
More informationINTRODUCTION TO SOL-GEL PROCESSING
INTRODUCTION TO SOL-GEL PROCESSING THE KLUWER INTERNATIONAL SERIES in SOL-GEL PROCESSING: TECHNOLOGY AND APPLICATIONS Consulting Editor Lisa Klein Rutgers, the State University of New Jersey INTRODUCTION
More informationDIPOLE MOMENTS IN ORGANIC CHEMISTRY
DIPOLE MOMENTS IN ORGANIC CHEMISTRY PHYSICAL METHODS IN ORGANIC CHEMISTRY B. I. lonin and B. A. Ershov NMR Spectroscopy in Organic Chemistry, 1970 V. I. Minkin, O. A. Osipov, and Yu. A. Zhdanov Dipole
More informationAbstract Process Economics Program Report 51C POLYMER NANOCOMPOSITES (June 2002)
Abstract Process Economics Program Report 51C POLYMER NANOCOMPOSITES (June 2002) With the rush of interest in all things related to nanotechnology, polymer nanocomposites represent one of the emerging
More informationweb-matse443 (E. Manias) Introduction in Polymer Science & Engineering
web-matse443 (E. Manias) Introduction in Polymer Science & Engineering Textbook: Alternate: "Fundamentals of Polymer Science (2 nd ed.) by PC Painter & MM Coleman (CRC Press) Essentials of Polymer Science
More informationPolymers and Nanomaterials from Liquid-Liquid Interfaces: Synthesis, Self-Organisation and Applications
Preface My interest in liquid liquid interfaces, the reactions occurring at them and through them, as well as their physical properties and potential applications was initiated during my early days of
More informationPROTEIN CONDENSATION Kinetic Pathways to Crystallization and Disease
PROTEIN CONDENSATION Kinetic Pathways to Crystallization and Disease This book deals with the phase transitions, self-assembly, and aggregation of proteins in solution. Its primary purpose is to bring
More information