Catalytic Oxidation Metal and Non-Metal Systems 26 Hisashi YAMAMOTO (Molecular Catalyst Research Center, Chubu University, Japan)
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1 Program MONDAY, JULY 6, :00 17:00 Registration 17:10 17:20 Opening Remarks: Keiji MARUOKA 17:20 18:05 Plenary Lecture 1 Chair: Yasuyuki KITA Asymmetric counteranion directed catalysis (ACDC): a general approach to enantioselective synthesis 24 Benjamin LIST (Department of Homogeneous Catalysis, Max-Planck-Institut für Kohlenforschung, Germany) 18:05 18:50 Plenary Lecture 2 Chair: Yasuyuki KITA Catalytic Oxidation Metal and Non-Metal Systems 26 Hisashi YAMAMOTO (Molecular Catalyst Research Center, Chubu University, 19:00 20:30 Reception TUESDAY, JULY 7, :00 12:00 Session A Chairs: Keiji MARUOKA Tomislav ROVIS 9:00 9:30 [A-1] New catalytic strategies for chemical synthesis 30 Matthew GAUNT (Department of Chemistry, University of Cambridge, UK) 9:30 10:00 [A-2] Transfer hydrogenation reactions of ketimines by means of chiral phosphoric acid 32 Takahiko AKIYAMA (Department of Chemistry, Gakushuin University, 10:00 10:30 [A-3] Catalytic Asymmetric Semipinacol Rearrangement 34 Yong-Qiang TU (State Key Laboratory of Applied Organic Chemistry, Lanzhou University, China) 10:30 11:00 Coffee Break
2 11:00 11:30 [A-4] Enantioselective Multicatalysis 36 Peter R. SCHREINER (Institute of Organic Chemistry, Justus-Liebig University, Germany) 11:30 12:00 [A-5] Metal-Free Oxidative Coupling Reactions by Hypervalent Iodine Reagent 38 Yasuyuki KITA (Research Organization of Science and Technology, Ritsumeikan University, 12:00 12:30 12:30 14:00 (Poster Numbers: 1, 3, 5, 7, 9, 11, 13, 15, 19, 21, 23, 25, 27) Lunch 14:00 14:45 Plenary Lecture 3 Chair: Hisashi YAMAMOTO The discovery and invention of new chemical reactions using photoredox catalysis 28 David W.C. MACMILLAN (Department of Chemistry, Princeton University, USA) 14:45 17:45 Session B Chairs: Darren J. DIXON Masahiro TERADA 14:45 15:15 [B-1] Searching for Selective Reactions on Complex Molecular Scaffolds with Catalysis 42 Scott J. MILLER (Department of Chemistry, Yale University, USA) 15:15 15:45 [B-2] Discovery of 4-oxa-5-azahomoadamantanes: Novel alkoxyamine-type precatalysts for alcohol oxidation 44 Yoshiharu IWABUCHI (Graduate School of Pharmaceutical Sciences, Tohoku University, 15:45 16:15 Coffee Break 16:15 16:45 [B-3] Asymmetric photo-organocatalysis: making chiral molecules with light 48 Paolo MELCHIORRE (Institute of Chemical Research of Catalonia (ICIQ), Spain)
3 16:45 17:15 [B-4] In-situ generation of less accessible or unprecedented imines form aminals for asymmetric organocatalysis 52 Keiji MARUOKA (Graduate School of Science, Kyoto University, 17:15 17:25 [B-5 (PS No. 55)] Development of efficient peptide catalysts by a facile library screening method 163 Kengo AKAGAWA (Institute of Industrial Science, The University of Tokyo, 17:25 17:35 [B-6 (PS No. 17)] Catalytic direct Mannich-type reaction of carboxylic acids using boron compounds as a chemoselective activator 111 Yohei SHIMIZU (Graduate School of Pharmaceutical Sciences, The University of Tokyo, 17:35 17:45 [B-7 (PS No. 53)] Asymmetric organocatalysis with helically chiral poly(quinoxaline- 2,3-diyl)s bearing DMAP-type pendants 160 Takeshi YAMAMOTO (Graduate School of Engineering, Kyoto University, 17:45 18:15 (Poster Numbers: 31, 33, 35, 37, 39, 41, 43, 45, 47, 49, 51, 57, 59) 18:15 19:30 Dinner 19:30 21:30 Poster Session [1]: Odd Numbers WEDNESDAY, JULY 8, :00 12:00 Session C Chairs: Takahiko AKIYAMA Petri M. PIHKO 9:00 9:30 [C-1] Enantioselective Catalysis With Cations and Anions 54 Dean F. TOSTE (Department of Chemistry, University of California, Berkeley, USA) 9:30 10:00 [C-2] Synthesis of natural products based on guanidine-thiourea bifunctional organocatalysis 56 Kazuo NAGASAWA (Department of Biotechnology and Life Science, Tokyo University of Agriculture and Technology,
4 10:00 10:30 [C-3] Design of Supramoleular Catalysts for the Enantio-, Diastereo-, Regio-, and Substrate-Selective Diels-Alder Reactions 58 Kazuaki ISHIHARA (Graduate School of Engineering, Nagoya University, 10:30 11:00 Coffee Break 11:00 11:30 [C-4] Catalytic methods for simplifying synthesis 60 Darren J. DIXON (Department of Chemistry, University of Oxford, UK) 11:30 12:00 [C-5] Asymmetric catalysis for the Michael addition of α,β-unsaturated carboxylic acids 62 Yoshiji TAKEMOTO (Graduate School of Pharmaceutical Sciences, Kyoto University, 12:00 12:30 (Poster Numbers: 2, 4, 6, 8, 10, 12, 16, 18, 20, 22, 24, 26, 28) 12:30 14:00 Lunch 14:00 17:30 Session D Chairs: Matthew GAUNT Takashi OOI 14:00 14:30 [D-1] Enantio- and Site-Selective Molecular Transformation by Organocatalysis 64 Takeo KAWABATA (Institute for Chemical Research, Kyoto University, 14:30 15:00 [D-2] Deprotonative functionalization of arenes and heteroarenes using organocatalytic systems 66 Yoshinori KONDO (Graduate School of Pharmaceutical Sciences, Tohoku University, 15:00 15:30 [D-3] Activation of nucleophiles for asymmetric reactions with organic molecules 68 Li DENG (Department of Chemistry, Brandeis University, USA) 15:30 16:00 Coffee Break
5 16:00 16:30 [D-4] Enantioselective Double Aldol Reaction Catalyzed by Chiral Phosphine Oxides 70 Makoto NAKAJIMA (Graduate School of Pharmaceutical Sciences, Kumamoto University, 16:30 17:00 [D-5] Nucleophilic Carbenes for Asymmetric Umpolung: From Acyl Anion to Internal Redox Catalysis and Beyond 72 Tomislav ROVIS (Department of Chemistry, Colorado State University, USA) 17:00 17:10 [D-6 (PS No. 14)] Enantioselective Organocatalytic Photoredox Reactions Promoted by Iron(II) Complexes 107 Pier Giorgio COZZI (Dipartimento di Chimica G. Ciamician, Università di Bologna, Italy) 17:10 17:20 [D-7 (PS No. 44)] Asymmetric fluoro-lactonization catalyzed by a chiral hydroxyl carboxylate under phase-transfer conditions 149 Hiromichi EGAMI (School of Pharmaceutical Sciences, University of Shizuoka, 17:20 17:30 [D-8 (PS No. 40)] Catalytic behaviour of carbon acid derivatives 144 Hikaru YANAI (School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 17:30 18:00 (Poster Numbers: 30, 32, 34, 36, 38, 42, 46, 48, 50, 52, 54, 56, 58, 60) 18:00 19:30 Dinner 19:30 21:30 Poster Session [2]: Even Numbers THURSDAY, JULY 9, :00 12:00 Session E Chairs: Paolo MELCHIORRE Makoto NAKAJIMA 9:00 9:30 [E-1] Run to the Hills: Mechanistic Insights on Selectivity and Rates in Organocatalysis 74 Petri M. PIHKO (Department of Chemistry and NanoScience Center, University of Jyväskylä, Finland)
6 9:30 10:00 [E-2] Pot-synthesis of medicinally important organic compound by organocatalyst 76 Yujiro HAYASHI (Graduate School of Science, Tohoku University, 10:00 10:30 Coffee Break 10:30 11:00 [E-3] Asymmetric Catalysis of Designer Chiral Organic Ion Pairs 80 Takashi OOI (Institute of Transformative Bio-Molecules (ITbM), Nagoya University, 11:00 11:30 [E-4] Enantioselective Transformation of Cationic Intermediates Mediated by Chiral Phosphoric Acid Catalyst 82 Masahiro TERADA (Graduate School of Science, Tohoku University, 11:30 12:00 [E-5] Organocatalysis: a new toolbox in asymmetric catalysis Karl Anker JØRGENSEN (Department of Chemistry, Aarhus University, Denmark) 86 12:00 12:15 Announcement of Grant Recipients 12:15 12:20 Closing Remarks: Keiji MARUOKA 12:20 13:20 Lunch
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