Scientific Program. International Workshop on Organofluorine Chemistry

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1 Scientific Program of International Workshop on Organofluorine Chemistry 2013 Hosted by Nanjing University of Science & Technology Shanghai Institute of Organic Chemistry Nanjing, ~14

2 Thursday, September 12 12:00~22:00 Registration Zilu Hotel, Nanjing University of Science & Technology, Nanjing, China 12:00~22:00 Registration Zilu Hotel, Nanjing University of Science & Technology, Nanjing, China Friday, September 13 Session 1 Chairperson:Chun Cai Nanjing University of Science and Technology; caichun@njust.edu.cn 8:30~9:00 Opening remarks 9:00~9:45 Recyclable Fluorous Asymmetric Organocatalysis Wei Zhang University of Massachusetts Boston, USA ; wei2.zhang@umb.edu 9:45~10:00 Break Session 2 Chairperson:Santos Fustero Universidad de Valencia, Spain; Santos.fustero@uv.es 10:00~10:45 Organometallic Aspects of Fluoroalkylation Reactions P-2 David Vivic Lehigh University, USA; vicic@lehigh.edu 10:45~11:15 The chemistry of trifluorodiazoethane O-1 Jun an Ma Tianjin University; majun_an68@tju.edu.cn 11:15~11:45 Some formations of C-C bonds at a vicinal position of a O-2 trifluoromethyl Yong Guo Shanghai Institute of Organic Chemistry; yguo@sioc.ac.cn 11:45~12:15 Design and synthesis novel 19F MRI agents O-3 Zhongxing Jiang Wuhan University; zxjiang@whu.edu.cn 12:15~14:00 Lunch and rest Session 3 Chairperson : Jianbo Wang Peking University; wangjb@pku.edu.cn 14:00~14:45 Synthesis and Photovoltaic Applications of Donor-Acceptor Dyes bearing Perfluoroalkoxy Substituents Gianluca Pozzi P-1 P-3

3 CNR-Istituto di Scienze e Tecnologie Molecolari, Italy; gianluca.pozzi@istm.cnr.it 14:45~15:15 Copper-Catalyzed Fluorination Reactions O-4 Guosheng Liu Shanghai Institute of Organic Chemistry; gliu@mail.sioc.ac.cn 15:15~15:45 Copper(I)-Catalyzed Coupling Cyclization of Methyl O-5 Perfluoroalk-2-ynoates: Synthesis of Perfluoroalkylated Heterocyclic Compounds Weiguo Cao Shanghai University; wgcao@staff.shu.edu.cn 15:45~16:00 Break Session 4 Chairperson : Wei Zhang University of Massachusetts Boston, USA; wei2.zhang@umb.edu 16:00~16:45 Enantioselective Synthesis of Organofluorine Compounds P-4 Norio Shibata 16:45~17:15 Nagoya Institute of Technology, Japan; nozshiba@nitech.ac.jp Radical Organocatalytic Enantioselective Fluorination O-6 Wenbin Yi Nanjing University of Science and Technology; yiwenbin@njust.edu.cn 17:15~18:00 Defect-free Dendrimer Synthesis and Chirality Issue in P-5 Biomaterials Bruce Yu University of Maryland;byu@rx.umaryland.edu 18:00~18:30 Novel Trifluoromethylation based on Radical or Carbene Process O-7 Jianbo Wang Peking University; wangjb@pku.edu.cn 18:30~20:30 Welcome banquet Saturday, September 14 Session 5 Chairperson : Dominique Cahard Universit et INSA de Rouen, France; dominique.cahard@univ-rouen.fr 8:00~8:45 Synthesis of Monofluoroalkenes via C-F Bond Activation P-6 Jean-François Paquin Chaire de recherche du Canada en chimie organique et médicinale, Canada; jean-francois.paquin@chm.ulaval.ca 8:45~9:15 Oxidative trifluoromethylation and trifluoromethylthiolation O-8 Fengling Qing Shanghai Institute of Organic Chemistry; flq@mail.sioc.ac.cn 9:15~10:00 Self-Disproportionation of Enantiomers: Theory and Practical P-7

4 10:00~10:20 Break Applications for Unconventional Preparation of Enantiomerically Pure Compounds Vadim A. Soloshonok University of the Basque Country, Spain; Session 6 Chairperson : Sensuke Ogoshi Osaka University, Japan; ogoshi@chem.eng.osaka-u.ac.jp 10:20~11:05 New Perspectives of Transition metals in Fluorine Chemistry P-8 Santos Fustero Universidad de Valencia, Spain; Santos.fustero@uv.es 11:05~11:35 A Trifluoromethylthio-substituted Electrophilic Hypervalent O-9 Iodine Reagent: Preparation and Reactivity Qilong Shen Shanghai Institute of Organic Chemistry; shenql@mail.sioc.ac.cn 11:35~12:05 Copper-Mediated Trifluoromethylselenolation of Aryl and Alkyl Halides O-10 Zhiqiang Weng Fuzhou Univeisity; zweng@fzu.edu.cn 12:05~14:00 Lunch and rest Session 7 Chairperson : Fengling Qing Shanghai Institute of Organic Chemistry; flq@mail.sioc.ac.cn 14:00~14:45 Group10-Metal-Catalyzed Coupling Reactions of Perfluoro-Alkenes and Arenes Sensuke Ogoshi Osaka University, Japan; ogoshi@chem.eng.osaka-u.ac.jp 14:45~15:15 Synthesis and reaction of some fluorine-containing phosphonium salts Jichang Xiao Shanghai Institute of Organic Chemistry; jchxiao@mail.sioc.ac.cn 15:15~15:45 Organocatalysis asymmetric reaction by the cleavage of carbon-carbon bonds through a mild release of trifluoroacetate Fanhong Wu Shanghai Institute of Technology; wfh@sit.edu.cn 15:45~16:00 Break Session 8 Chairperson : Jinbo Hu Shanghai Institute of Organic Chemistry; jinbohu@mail.sioc.ac.cn 16:00~16:45 Enantioselective Metal-Catalyzed Hydride Transfer Reactions for the Construction of Stereogenic Trifluoromethylated Carbon Centres Dominique Cahard Universit et INSA de Rouen, France; dominique.cahard@univ-rouen.fr P-9 O-11 O-12 P-10

5 16:45~17:00 Closing ceremony 17:00~21:00 Excursion to Nanjing Confucius Temple

Self-stable Electrophilic Reagents for Trifluoromethylthiolation. Reporter: Linrui Zhang Supervisor: Prof. Yong Huang Date:

Self-stable Electrophilic Reagents for Trifluoromethylthiolation Reporter: Linrui Zhang Supervisor: Prof. Yong Huang Date: 2017-12-25 Content Introduction Trifluoromethanesulfenates: Preparation and reactivity