Contents. Page. Welcome Message. Committee. General Information. Program-at-a-Glance. Registration Hours. NTU Shuttle Bus - Campus Loop

Transcription

1 1

2 Contents Page Welcome Message Committee General Information Program-at-a-Glance Registration Hours NTU Shuttle Bus - Campus Loop Meals and Refreshments Oral Presentations Poster Presentations ii iii iii iv iv v vii viii x i

3 Welcome To 1 st SJG-TSPSC-2017 Participants The Organizing Committee extends a warm welcome to all the participants of the 1 st Singapore Japan Germay Trilateral Symposium on Precision Synthesis & Catalysis We are pleased to bring togegther the top synthetic organic chemists from the 3 countries, namely Japan, Germany and Singapore. We would like to take this opportunity to thanks and acknowledge the Grant-in-Aid for Scientific Research on Innovative Areas, MEXT, Nanyang Technological University, sponsors and doners who have supported us in making this inaugural symposium possible. We hope you will have a stimulating and enriching symposium. Organising Committee Shunsuke CHIBA (Nanyang Technological University, Singapore) Kazushi MASHIMA (Osaka University, Japan) Jun OKUDA (RWTH Aachen University, Germany) ii

4 Committee Organizing Committee Kazushi MASHIMA Jun OKUDA Shunsuke CHIBA Osaka University, Japan RWTH Aachen University, Germany Nanyang Technological University, Singapore General Information Getting to Conference Venue Conference Venue 20 th to 21 st Dec 2017: Nanyang Technological University School of Physical and Mathematical Sciences (SPMS) 21 Nanyang Link Singapore Scientific Program: Lecture Theatre 5 (LT5) located at Level 3 Poster Presentations: SPMS Atrium located at Level 3 Symposium Activity SPMS Building iii

5 Program at-a-glance 1st SJGTS-PSC Nov (Monday) 21 Nov (Tuesday) 22 Nov (Wednesday) Arrival / Registration & Opening Remarks AM Oral Presentations Break Oral Presentations Gardens by the Bay (Excursion) Lunch & Poster Presenations Lunch PM Oral Presentations Break Oral Presentations Evening Students' Dinner Speakers' Dinner Dinner Registration Hours Admission to all sessions and hosted functions requires identification. Please wear your name badge at all times. Registration 20 November, Monday Opens 08:30 and Closes 09:30 Help Desk 20 November, Monday Opens 08:30 and Closes 16:30 21 November, Tuesday Opens 08:30 and Closes 16:00 Poster Interactive Session Date & Day Interactive Hours 20 November, Monday From 12:30 to 14:30 iv

6 NTU Shuttle Bus (Campus Loop Blue) NEC SPMS NEC - Nanyang Executive Centre SPMS School of Physical and Mathematical Sciences v

7 NTU Shuttle Bus Campus Loop (Blue) Shuttle Bus frequency Op hours(hrs) Mon - Fri Freq(mins) Form NEC to SPMS Board at: Nanyang Heights, Opp. Hall 8 Hall 6, Opp. Hall 2 Opp. Hall 4 Opp. Innovation Centre Alight at: Opp. SPMS From SPMS to NEC: Board at: Opp. SPMS Opp. WKWSCI Opp. CEE NIE, Opp. LWN Library Opp. Hall 3 & 16 Opp. Hall 14 & 15 Opp. Hall 10 & 11 Alight at: Nanyang Heights, Opp. Hall 8 vi

8 Meals and Refreshments Served in the SPMS Atrium Coffee/Tea Breaks 20 November, Monday (AM) From 10:30 to 11:00 (PM) From 16:00 to 16:30 21 November, Tuesday (AM) From 10:30 to 11:00 (PM) From 15:30 to 16:00 Standing Lunch Buffet 20 November, Monday From 12:30 to 14:30 21 November, Tuesday From 12:30 to 14:00 Bento Set Dinner (For Poster Presenting Students Only) 20 November, Monday From 18:00 (Picp Help Desk) Speaker Dinner 20 November, Monday from 19:00 to 22:00 The Shangri-la (The Line) Lower Lobby, Tower Wing 22 Orange Grove Road, Singapore Standing Dinner Buffet 21 November, Tuesday From 18:00 to 17:30 Excursion 22 November, Wednesday Bus pick-up at NEC Main Lobby at 09:30 (1-way) Drop off at: Gardans by the Bay (Ticket of admission at own cost) Useful Telephone Numbers Emergency Police: 999 Ambulance / Fire Brigade: 995 Ambulance (Non-emergency): 1777 About Singapore Tourist Hotline: City Search: Flight Information: Cab Services General Taxi Call Centre: (65) Comfort Citycab (Dial-A-Cab): (65) Premier Taxi: (65) SMRT Taxis: (65) vii

9 Oral Presentations The duration of each talk (inclusive of Q&A session) is 30 minutes. The meeting room comes equipped with a computer, LCD projector and screen. The computers are configured with Microsoft Windows Operating System. We suggest that you bring your presentation files in thumb drives and upload to the computers before the start of your session. If you are using your own laptop or tablet (either MAC of PC based) please bring your own VGA adaptor cable. 20 November, Monday Time Speaker / Title 09:20 Speech by Shunsuke CHIBA Session Chair: Tamio HAYASHI 09:30 L01 Kazushi MASHIMA (Japan) Organosilicone Compounds for Salt-free Reduction of Metal Compounds, Generating Catalytically Active Species 10:00 L02 Shunsuke CHIBA (Singapore) Molecular Transformation by Sodium Hydride-Iodide Composite 10:30 AM Tea Break Session Chair: Kazushi MASHIMA 11:00 L03 Jun OKUDA (Germany) Triphenylborane and Hydridotriphenylborate Anion: Overlooked Catalysts 11:30 L04 Rei KINJO (Singapore) Organoboranes featuring Unique Bonding and Electronic Property 12:00 L05 Matthias TAMM (Germany) Anionic N-Heterocyclic Carbene Ligands as Anicillary Ligands in Homogeneous Catalysis 12:30 Lunch & Poster Presentations Session Chair: Choon Hong TAN 14:30 L06 F. Ekkehardt HAHN (Germany) Substrate Activation with Complexes Bearing Protic N-heterocyclic or Mesoionic Carbenes 15:00 L07 Robin CHI Yonggui (Singapore) Carbene Organic Catalysis: New Activation Modes and Rapid Synthesis of Functional Molecules 15:30 L08 Albrecht BERKESSEL (Germany) Carbene Catalysis and the Breslow Intermediate 16:00 PM Tea Break Session Chair: Robin CHI Yonggui 16:30 L09 Kazuaki ISHIHARA (Japan) Chiral Nucleohpilic Amidophosphate-catalyzed Enatioselective Iodocyclization 17:00 L10 Choon Hong TAN (Singapore) Chiral Cationic Ion-Pairing Catalysis 17:30 L11 Keiji MARUOKA (Japan) Practical Synthesis of Four Different, Bifunctional Organocatalysts for Asymmetric Catalysis 18:00 End of Presentations 18:10 Bento Set Dinner for Students 19:00 Speaker Dinner viii

10 21 November, Tuesday Time Speaker / Title Session Chair: Jun OKUDA 09:00 L12 Naohiko YOSHIKAI (Singapore) Low-Valent Cobalt Catalysis: C H Activation and Beyond 09:30 L13 Carsten BOLM (Germany) Mechanochemical Activation in Asymmetric Synthesis and Catalysis 10:00 L14 Shigeki MATSUNAGA (Japan) Unique Reactivity and Selectivity of Cp*Co(III) Catalysis in C-H Bond Functionalization 10:30 AM Tea Break Session Chair: Martin OESTREICH 11:00 L15 Naoto CHATANI (Japan) Rhodium-Catalyzed C-H Alkylation Using a Bidentate Directing Group 11:30 L16 Bernhard BREIT (Germany) On the Invention of Atom-Economic Reactions: Rhodium-Catalyzed Addition of Pronucleophiles to Alkynes and Allenes 12:00 L17 Masaya SAWAMURA (Japan) Organometallic Catalysis with Polystyrene-Cross-Link Phosphines 12:30 Lunch Session Chair: Naohiko YOSHIKAI 14:00 L18 Yoshiaki NAKAO (Japan) C H Functionalization by Nickel Catalysis 14:30 L19 Martin OESTREICH (Germany) Solving Two Long-Standing Problems in Silicon Chemistry 15:00 L20 Michinori SUGINOME (Japan) Selective Organic Synthesis via Transition-metal-catalyzed C-H Activation 15:30 PM Tea Break Session Chair: Shunsuke CHIBA 16:00 L21 Kyoko NOZAKI (Japan) Catalysis toward Utilization of Renewable Resources 16:30 L22 Han Sen SOO (Singapore) Artificial Photosynthesis by Light Absorption, Charge Separation, and Photoredox Catalysis 17:00 L23 Nobuharu IWASAWA (Japan) Visible-light Driven Carboxylation Reactions 17:30 Poster Award Ceremony & Closing Remarks 18:00 Dinner 22 November, Wednesday 09:30 Excursion: Gardens by the Bay (Pick at up NEC Lobby) ix

11 Poster Presentations Venue: Activity MAS Atrium (Level 3) 20 November, Monday 12:30 14:30 Notes for Poster Presentations Prepare your Poster Each presenter is provided with a 1 meter high by 0.7 meter wide poster board that is marked with the allocated number. Poster size should be no larger than A1 (Portrait) size (594 mm width x 841 mm height). Mounting tapes will be made available at the Help Desk / Registration Desk during set up day. Printing of Poster All printing of posters must be done before the start of conference. Set Up Your Poster / Give Your Presentation Your poster must be on display from 12:00 14:30 on 20 November and presenters should be available during the scheduled interactive hours. Posters should be set up no later than 11:00 on the day of poster presentation. Removal of Posters Posters must be removed by 15:30 on 21 November. Posters that are still remain on the poster boards after that time will be removed by the organizer. x

12 Poster ID P01 P02 P03 P04 P05 P06 P07 P08 P09 P10 P11 P12 P13 P14 Title / Authors Youka BUNNO (Hokkaido University) Cp*Co(III)-Catalyzed Dehydrative C-H Allylation of 6-Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohol Xi-Yang CUI (Nanyang Technological University) Guanidine)copper Complex-Catalysed Dynamic Kinetic Allylic Alkynylation Under Biphasic Conditions Shumpei AKITA (University of Tokyo) Synthesis and Reactivity of Methylpalladium Complexes Bearing a Partially Saturated IzQO Ligand Atsushi KAGA (Nanyang Technological University) Nucleophilic Amination of Methoxy Arenes Promoted by a Sodium Hydride/Iodide Composite Kenya HIGASHIHARA (Osaka University) Asymmetric Hydrogenation of Simple Olefins Catalyzed by Chloride-bridged Dinuclear Rhodium(III) Complexes Martin MEIER (Westfälische Wilhelms-Universität) Transmetallation Reactions of NR,O-NHC Ligands Yukako YOSHINAGA (Kyoto University) Cu-Catalyzed Asymmetric Cyclopropanation Utilizing Chirality-Switchable 2,2 -Bipyridine Ligands Attached to Helical Polyquinoxalines Miloš Đokić (Nanyang Technological University) Selective Carbon-Carbon Bond Cleavage Under Visible Light and Ambient Conditions by Earth-Abundant Vanadium Photocatalysts Takuya IGARASHI (Osaka University) Catalytic Double Carbon-Boron Bond Formation for the Synthesis of Cyclic Diarylborinic Acids as Versatile Building Blocks for π-extended Heteroarenes Jialin MING (Nanyang Technological University) Aryloxymethyltrifluoroborates for Rhodium-Catalyzed Asymmetric Conjugate Arylation. O Methoxyarylation through 1,4-Rhodium Shift Yuto YASUDA (Hokkaido University) Asymmetric Copper Catalysis with Phenol NHC Chiral Ligands: A Case of Allyl Allyl Coupling with Organoboron Reagents Bochao SU (Nanyang Technological University) Isolation and Diverse Reactivity of 1,4,2-Diazaborole Takuya MOCHIZUKI (Nagoya University) Enantioselective Aza-Friedel Crafts Reaction of Indoles with Ketimines Catalyzed by Chiral Potassium Binaphthyldisulfonates Qiao SUN (Nanyang Technological University) Cobalt-Catalyzed C H Methylation with Methyl Tosylate P15 Myuto KASHIHARA (Kyoto University) Reductive Denitration of Nitroarenes xi

13 Poster ID P16 P17 P18 P19 P20 Title / Authors Yuto SHIMAZAKI (Kyoto University) Design of New Chiral Iodine Catalyst Based on Indanol Scaffold Naoto SAHARA (Nagoya University) Hypoiodite-catalyzed ChemoselectiveDirect -Azidation of Carbonyl Compounds Xingxing WU (Nanyang Technological University) Construction of Fused Pyrrolidines and β-lactones via Carbene-Catalyzed C-N, C-C and C-O Bond Formations Keiichi SUMIYAMA (Tokyo Institute of Technology) Cobalt-Salophen Complex Catalyzed Preparation of Alkyl Iodides from Aldehydes via Oxidative Deformylation Hiroaki ODA (Osaka University) Nickel Catalyzed Asymmetric Allylic Alkylation of β-ketoesters with Allylic Alcohols xii