Watercare Air Quality Group March 2002 APPENDIX A. Monitoring Site Location Diagrams
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1 APPENDIX A Monitoring Site Location Diagrams Appendix A contains 4 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A1 of A55
2 Mt Eden Site 4:65 Figure 1 Mt Eden, Auckland Site 4:65 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A2 of A55
3 Penrose Site 4:23 Penrose (ACI) Site 4:19 Figure 2 Penrose, Auckland Site 4:19 Site 4:23 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A3 of A55
4 St Albans Site 16:67 Figure 3 St Albans, Christchurch Site 16:67 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A4 of A55
5 APPENDIX B Graphed Results for SO 2 Appendix B contains 5 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A5 of A55
6 Penrose: 21 Sulphur dioxide (1 hour fixed averages) 35 3 Concentration (µg/m 3 ) AAQG = 35µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A6 of A55
7 35 St Albans: 21 Sulphur dioxide (1 hour fixed averages) 3 Concentration (µg/m 3 ) AAQG = 35µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A7 of A55
8 Penrose (ACI): 21 Sulphur dioxide (24 hour fixed averages) 12 1 Proposed AAQG = 12µg/m 3 Concentration (µg/m 3 ) Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A8 of A55
9 St Albans: 21 Sulphur dioxide (24 hour fixed averages) 12 1 Concentration (µg/m 3 ) Proposed AAQG = 12µg/m 3 2 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A9 of A55
10 APPENDIX C Graphed Results for CO Appendix C contains 11 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A1 of A55
11 St Albans: 21 Carbon monoxide (1 hour fixed averages) Concentration (mg/m 3 ) Proposed AAQG = 3 mg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A11 of A55
12 5 St Albans: Carbon monoxide (1 hour averages) (2) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A12 of A55
13 5 St Albans: Carbon monoxide (1 hour averages) (1999) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A13 of A55
14 5 St Albans: Carbon monoxide (1 hour averages) (1998) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A14 of A55
15 5 St Albans: Carbon monoxide (1 hour averages) (1997) 4 Concentration (mg/m 3 ) 3 2 Air Quality Guideline 1 Jan-97 Feb-97 Mar-97 Apr-97 May-97 Jun-97 Jul-97 Aug-97 Sep-97 Oct-97 Nov-97 Dec-97 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A15 of A55
16 St Albans: 21 Carbon Monoxide (8 hour fixed averages) 2 15 Concentration (mg/m 3 ) 1 5 Proposed AAQG = 1 mg/m 3 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A16 of A55
17 3 St Albans: Carbon monoxide (8 hour moving averages) (2) 25 Concentration (mg/m 3 ) Air Quality Guideline 5 Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A17 of A55
18 3 St Albans: Carbon monoxide (8 hour moving averages) (1999) 25 Concentration (mg/m 3 ) Air Quality Guideline 5 Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A18 of A55
19 3 St Albans: Carbon monoxide (8 hour moving averages) (1998) 25 Concentration (mg/m 3 ) Air Quality Guideline 5 Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A19 of A55
20 3 St Albans: Carbon monoxide (8 hour moving averages) (1997) 25 Concentration (mg/m 3 ) Air Quality Guideline 5 Jan-97 Feb-97 Mar-97 Apr-97 May-97 Jun-97 Jul-97 Aug-97 Sep-97 Oct-97 Nov-97 Dec-97 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A2 of A55
21 APPENDIX D Graphed Results for NOx Appendix D contains22 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A21 of A55
22 Mt Eden: 21 Nitrogen dioxide (1 hour averages) Concentration (µg/m 3 ) Proposed 1 hour AAQG = 2 (µg/m 3 ) 2 1 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A22 of A55
23 2 Mt Eden: Nitrogen dioxide (1 hour averages) (2) Jan- Feb- Apr- May- Jul- Sep- Oct- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A23 of A55
24 Mt Eden: Nitrogen dioxide (1 hour averages) (1999) 2 18 Current 1 hour guideline = 3 µg/m 3 Proposed 1 hour guideline = 2 µg/m Nov-98 Dec-98 Feb-99 Mar-99 May-99 Jul-99 Aug-99 Oct-99 Dec-99 Jan- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A24 of A55
25 2 Mt Eden: Nitrogen dioxide (1 hour averages) (1998) 18 Current 1 hour guideline = 3 µg/m 3 Proposed1 hour guideline = 2 µg/m Concentration (µg/m 3 ) Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A25 of A55
26 2 Mt Eden: Nitrogen dioxide (1 hour averages) (1997) 18 Current 1 hour guideline = 3 µg/m 3 Proposed1 hour guideline = 2 µg/m Dec-96 Jan-97 Mar-97 Apr-97 Jun-97 Aug-97 Sep-97 Nov-97 Jan-98 Feb-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A26 of A55
27 Penrose: 21 Nitrogen dioxide (1 hour fixed averages) Concentration (µg/m 3 ) Proposed 1 hour AAQG = 2 (µg/m 3 ) 2 1 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A27 of A55
28 2 Penrose: Nitrogen dioxide (1 hour averages) (2) 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A28 of A55
29 Penrose: Nitrogen dioxide (1 hour averages) (1999) 2 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A29 of A55
30 2 Penrose: Nitrogen dioxide (1 hour averages) (1998) 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A3 of A55
31 Penrose: Nitrogen dioxide (1 hour averages) (1997) 2 18 Current 1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Dec-96 Jan-97 Mar-97 Apr-97 Jun-97 Aug-97 Sep-97 Nov-97 Jan-98 Feb-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A31 of A55
32 St Albans: 21 Nitrogen dioxide (1 hour fixed averages) Concentration (mg/m3) Proposed 1 hour AAQG = 2 (µg/m 3 ) 1 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A32 of A55
33 2 St Albans: Nitrogen dioxide (1 hour averages) (2) 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan- Feb- Mar- Apr- May- Jun- Jul- Aug- Sep- Oct- Nov- Dec- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A33 of A55
34 St Albans: Nitrogen dioxide (1 hour averages) (1999) 2 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan-99 Feb-99 Mar-99 Apr-99 May-99 Jun-99 Jul-99 Aug-99 Sep-99 Oct-99 Nov-99 Dec-99 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A34 of A55
35 St Albans: Nitrogen dioxide (1 hour averages) (1998) 2 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan-98 Feb-98 Mar-98 Apr-98 May-98 Jun-98 Jul-98 Aug-98 Sep-98 Oct-98 Nov-98 Dec-98 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A35 of A55
36 St Albans: Nitrogen dioxide (1 hour averages) (1997) 2 18 Current1 hour Air Quality Guideline = 3 µg/m 3 Proposed 1 hour Air Quality Guideline = 2 µg/m Concentration (µg/m 3 ) Jan-97 Feb-97 Mar-97 Apr-97 May-97 Jun-97 Jul-97 Aug-97 Sep-97 Oct-97 Nov-97 Dec-97 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A36 of A55
37 Mt Eden: 21 Nitrogen dioxide (24 hour fixed averages) 3 25 Concentration (µg/m 3 ) Proposed AAQ guideline = 1µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A37 of A55
38 2 Mt Eden: Nitrogen dioxide (24 hour averages) (1996-2) hour guideline = 1 µg/m Dec-96 Jul-97 Feb-98 Aug-98 Mar-99 Sep-99 Apr- Oct- Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A38 of A55
39 Penrose: 21 Nitrogen dioxide (24 hour fixed averages) 3 25 Concentration (mg/m 3 ) Proposed AAQ guideline = 1µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A39 of A55
40 Penrose: Nitrogen dioxide (24 hour averages) (1996-2) 1 24 hour Air Quality Guideline = 1 µg/m Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A4 of A55
41 St Albans: 21 Nitrogen dioxide (24 hour fixed averages) 3 25 Concentration (µg/m 3 ) Propsoed AAQ guideline = 1µg/m 3 5 Jan-1 Feb-1 Mar-1 Apr-1 May-1 Jun-1 Jul-1 Aug-1 Sep-1 Oct-1 Nov-1 Dec-1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A41 of A55
42 St Albans: Nitrogen dioxide (24 hour averages) (1997-2) 1 24 hour Air Quality Guideline = 1 µg/m 3 8 Concentration (µg/m 3 ) Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A42 of A55
43 APPENDIX E Quarterly Results for VOC Appendix E contains 4 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A43 of A55
44 VOC Results Apr May Jun Quarter Results (µg/m 3 ) Analyte LOD Chch 1 Chch 2 Mt Eden 1 Mt Eden 2 Penrose 1 Penrose 2 (µg/m 3 ) SQ5435 RB552 SN3298 SQ5337 SQ5214 SQ5378 Target VOCs ethanol ND ND ND ND ND ND acetone ND ND ND ND ND ND pentane dichloromethane ND ND ND ND ND ND butan-2-one <LOD <LOD 1 1 hexane <LOD ethyl acetate ND ND ND ND ND ND trichloromethane ND ND ND ND ND ND 1,1,1-trichoroethane ND ND ND ND ND ND benzene methylhexane <LOD <LOD 1 1 2,3-dimethylpentane ND ND ND ND ND ND 3-methylhexane heptane <LOD <LOD 1 1 trichloroethene.5 <LOD <LOD <LOD <LOD <LOD.5 propyl acetate.5 <LOD <LOD <LOD <LOD 1 1 methylcyclohexane ND ND ND ND ND ND 4-methylpentan-2-one ND ND ND ND ND ND toluene octane ND ND ND ND ND ND tetrachloroethene <LOD <LOD butyl acetate ND ND ND ND ND ND ethylbenzene m+p-xylene o-xylene nonane ND ND ND ND ND ND alpha pinene ND ND ND ND ND ND propylbenzene ND ND ND ND ND ND 1,3, <LOD <LOD 1 1 trimethylbenzene beta pinene <LOD <LOD <LOD <LOD decane ND ND ND ND ND ND 1,2, trimethylbenzene limonene ND ND ND ND ND ND undecane ND ND ND ND ND ND dodecane ND ND ND ND ND ND tetradecane ND ND ND ND ND ND Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A44 of A55
45 VOC Results Jul-Aug-Sep Quarter Results (µg/m 3 ) Analyte LOD Chch 1 Chch 2 Mt Eden 1 Mt Eden 2 Penrose 1 Penrose 2 (µg/m 3 ) RB5562 RB5515 RH2118 RH234 RB5434 RB5386 Target VOCs ethanol ND ND ND ND ND ND Isopropyl alcohol ND ND ND ND ND ND acetone ND ND ND ND ND ND pentane dichloromethane <LOD <LOD <LOD <LOD butan-2-one ND ND ND ND ND ND hexane ethyl acetate ND ND ND ND ND ND trichloromethane ND ND ND ND ND ND 1,1,1-trichoroethane ND ND ND ND ND ND benzene methylhexane <LOD <LOD.6.5 2,3-dimethylpentane ND ND ND ND ND ND 3-methylhexane <LOD <LOD.6.6 heptane <LOD <LOD.5 <LOD trichloroethene <LOD <LOD <LOD <LOD propyl acetate.5 <LOD <LOD <LOD <LOD methylcyclohexane <LOD <LOD <LOD <LOD 4-methylpentan-2-one ND ND ND ND ND ND toluene octane ND ND ND ND ND ND tetrachloroethene <LOD <LOD <LOD <LOD butyl acetate.5 <LOD <LOD <LOD <LOD.5.5 ethylbenzene m+p-xylene o-xylene nonane ND ND ND ND ND ND alpha pinene ND ND ND ND ND ND propylbenzene ND ND ND ND ND ND 1,3, <LOD <LOD.6.6 trimethylbenzene beta pinene ND ND ND ND ND ND decane ND ND ND ND ND ND 1,2, trimethylbenzene limonene ND ND ND ND ND ND undecane ND ND ND ND ND ND dodecane ND ND ND ND ND ND tetradecane ND ND ND ND ND ND Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A45 of A55
46 VOC Results Oct-Nov-Dec Quarter Results (µg/m 3 ) Analyte LOD Chch 1 Chch 2 Mt Eden 1 Mt Eden 2 Penrose 1 Penrose 2 (µg/m 3 ) RF6584 RF651 RV728 RV867 RV566 RV1199 Target VOCs ethanol ND ND ND ND ND ND Isopropyl alcohol ND ND ND ND ND ND acetone ND ND ND ND pentane ND ND ND ND ND ND dichloromethane 1.9 ND ND ND ND ND ND butan-2-one ND ND ND ND ND ND hexane ethyl acetate ND ND ND ND ND ND trichloromethane ND ND ND ND ND ND 1,1,1-trichoroethane ND ND ND ND ND ND benzene methylhexane ND ND ND ND 2,3-dimethylpentane ND ND ND ND ND ND 3-methylhexane ND ND ND ND heptane ND ND ND ND trichloroethene ND ND ND ND ND ND propyl acetate ND ND ND ND ND ND methylcyclohexane ND ND ND ND 4-methylpentan-2-one ND ND ND ND ND ND toluene octane ND ND ND ND ND ND tetrachloroethene ND ND ND ND ND ND butyl acetate ND ND ND ND ND ND ethylbenzene m+p-xylene o-xylene nonane ND ND ND ND ND ND alpha pinene ND ND ND ND ND ND propylbenzene ND ND ND ND ND ND 1,3,5-trimethylbenzene ND ND ND ND ND ND beta pinene ND ND ND ND ND ND decane ND ND ND ND ND ND 1,2, trimethylbenzene limonene ND ND ND ND ND ND undecane.7 ND ND ND ND dodecane.6 ND ND ND ND.6.9 tetradecane Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A46 of A55
47 APPENDIX F Laboratory Results Appendix F contains 7 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A47 of A55
48 Certificate of Analysis Client: Watercare Air Quality Group PO Box 5977 Mangere Bridge AUCKLAND 171 Attention: Johanna Symons Date Received: 17 July 21 Laboratory Reference: 1-297/1-7 Sample Type: Analysis: 3M Vapour Monitor Volatile Organic Compounds Method: The badge was desorbed with carbon disulphide. The extract was analysed by gas chromatography - mass spectrometry. Detection limits are given for target compounds used to validate the analysis. Non target compounds are identified by a mass spectral library search [Wiley Library (HP G135A)]. Full details of the methodology and precision are available on request. Results are reported in total micrograms (µg) of analyte on an as received basis and are not corrected for desorption efficiencies. M. D. Valentine A. R. Lister Trace Organics Laboratory Trace Organics Laboratory AgriQuality Environmental AgriQuality Environmental Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A48 of A55
49 VOC RESULTS Amounts are in total micrograms (µg) per badge Watercare Reference AQG A 3-1 AQG A 3-2 AQG A 3-3 AQG A 3-4 AQG A 3-5 AQG A 3-6 AQG A 3-7 Blank AgriQuality Lab /7 Reference 297/1 297/2 297/3 297/4 297/5 297/6 Target VOCs ethanol <2 <2 <2 <2 <2 <2 <2 acetone <1 <1 <1 <1 <1 <1 <1 pentane <1 dichloromethane <1 <1 <1 <1 <1 <1 <1 butan-2-one 2 3 <2 <2 4 4 <2 hexane <2 <2 ethyl acetate <2 <2 <2 <2 <2 <2 <2 trichloromethane <2 <2 <2 <2 <2 <2 <2 1,1,1-trichoroethane <2 <2 <2 <2 <2 <2 <2 benzene <2 2-methylhexane 5 5 <2 <2 3 3 <2 2,3-dimethylpentane <2 <2 <2 <2 <2 <2 <2 3-methylhexane <2 heptane 4 4 <2 <2 2 2 <2 trichloroethene <2 <2 <2 <2 <2 2 <2 propyl acetate <2 <2 <2 <2 5 5 <2 methylcyclohexane <2 <2 <2 <2 <2 <2 <2 4-methylpentan-2-one <2 <2 <2 <2 <2 <2 <2 toluene <2 octane <2 <2 <2 <2 <2 <2 <2 tetrachloroethene <2 <2 <2 butyl acetate <2 <2 <2 <2 <2 <2 <2 ethylbenzene <2 m+p-xylene <2 o-xylene <2 nonane <2 <2 <2 <2 <2 <2 <2 alpha pinene <2 <2 <2 <2 <2 <2 <2 propylbenzene <2 <2 <2 <2 <2 <2 <2 1,3,5-trimethylbenzene 3 3 <2 <2 2 2 <2 beta pinene 2 2 <2 <2 <2 <2 <2 decane <2 <2 <2 <2 <2 <2 <2 1,2,4-trimethylbenzene <2 limonene <2 <2 <2 <2 <2 <2 <2 undecane <2 <2 <2 <2 <2 <2 <2 dodecane <2 <2 <2 <2 <2 <2 <2 tetradecane <2 <2 <2 <2 <2 <2 <2 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A49 of A55
50 Certificate of Analysis Client: Watercare Services Limited PO Box 5977 Mangere Bridge AUCKLAND 171 Attention: Judy Warren Date Received: 15 October 21 Client Reference: Project AQG-A-3 Laboratory Reference: /1-7 Sample Type: Analysis: 3M Vapour Monitor Volatile Organic Compounds Method: The badge was desorbed with carbon disulphide. The extract was analysed by gas chromatography - mass spectrometry. Detection limits are given for target compounds used to validate the analysis. Non target compounds are identified by a mass spectral library search [Wiley Library (HP G135A)]. Full details of the methodology and precision are available on request. Results are reported in total micrograms (µg) of analyte on an as received basis and are not corrected for desorption efficiencies. M. D. Valentine A. R. Lister UltraTrace Laboratory UltraTrace Laboratory AgriQuality Environmental AgriQuality Environmental Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A5 of A55
51 VOC RESULTS Amounts are in total micrograms (µg) per badge Watercare Reference MfE Chch MfE Chch MfE Penrose MfE Penrose MfE MtE MfE MtE MfEC RB5562 RB5515 RB5434 RB5386 RH211 8 RH23 4 Blank AgriQuality Lab / / Reference 4178/1* 4178/2* 4178/5 4178/6 4178/7 Target VOCs ethanol <2 <2 <2 <2 <2 <2 <2 isopropyl alcohol <1 <1 <1 <1 <1 <1 <1 acetone <1 <1 <1 <1 <1 <1 <1 pentane <1 dichloromethane <1 <1 <1 <1 <1 butan-2-one <1 <1 <1 <1 <1 <1 <1 hexane <2 ethyl acetate <2 <2 <2 <2 <2 <2 <2 trichloromethane <2 <2 <2 <2 <2 <2 <2 1,1,1-trichoroethane <2 <2 <2 <2 <2 <2 <2 benzene <2 2-methylhexane <2 <2 <2 2,3-dimethylpentane <2 <2 <2 <2 <2 <2 <2 3-methylhexane <2 <2 <2 heptane <2 <2 <2 <2 trichloroethene 3 2 <2 <2 <2 <2 <2 propyl acetate < 2 <2 5 5 <2 <2 <2 methylcyclohexane <2 <2 <2 <2 <2 4-methylpentan-2-one <2 <2 <2 <2 <2 <2 <2 toluene <2 octane <2 <2 <2 <2 <2 <2 <2 tetrachloroethene 3 3 <2 <2 <2 <2 <2 butyl acetate <2 <2 2 2 <2 <2 <2 ethylbenzene <2 m+p-xylene <2 o-xylene <2 nonane <2 <2 <2 <2 <2 <2 <2 alpha pinene <2 <2 <2 <2 <2 <2 <2 propylbenzene <2 <2 <2 <2 <2 <2 <2 1,3,5-trimethylbenzene <2 <2 <2 beta pinene <2 <2 <2 <2 <2 <2 <2 decane <2 <2 <2 <2 <2 <2 <2 1,2,4-trimethylbenzene <2 limonene <2 <2 <2 <2 <2 <2 <2 undecane <2 <2 <2 <2 <2 <2 <2 dodecane <2 <2 <2 <2 <2 <2 <2 tetradecane <2 <2 <2 <2 <2 <2 <2 < = less than the limit of detection * badges received without closure caps Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A51 of A55
52 Certificate of Analysis Client: Watercare Air Quality Group PO Box 5977 Mangere Bridge AUCKLAND 171 Attention: Judy Warren Date Received: 16 January 22 Laboratory Reference: 2-74/1-7 Sample Type: Analysis: 3M Vapour Monitor Volatile Organic Compounds Method: The badge was desorbed with carbon disulphide. The extract was analysed by gas chromatography - mass spectrometry. Detection limits are given for target compounds used to validate the analysis. Non target compounds are identified by a mass spectral library search [Wiley Library (HP G135A)]. Full details of the methodology and precision are available on request. Results are reported in total micrograms (µg) of analyte on an as received basis and are not corrected for desorption efficiencies. J. Fry M. Rogers UltraTrace Laboratory UltraTrace Laboratory AgriQuality Environmental AgriQuality Environmental Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A52 of A55
53 VOC RESULTS Amounts are in total micrograms (µg) per badge Watercare Reference MfE Chch MfE Chch MfE MtE MfE MtE MfE MfE MfEC Penrose Penrose RF6584 RF651# RV728 RV867 RV566 RV1199 Blank AgriQuality Lab. 2-74/1 2-74/2 2-74/5 2-74/6 2-74/3 2-74/4 2-74/7 Reference Target VOCs ethanol <2 <2 <2 <2 <2 <2 <2 isopropyl alcohol <1 <1 <1 <1 <1 <1 <1 acetone <1 <1 <1 <1 <1 pentane <1 <1 <1 <1 <1 <1 <1 dichloromethane <1 <1 <1 <1 <1 butan-2-one <1 <1 <1 <1 <1 <1 <1 hexane <2 ethyl acetate <2 <2 <2 <2 <2 <2 <2 trichloromethane <2 <2 <2 <2 <2 <2 <2 1,1,1-trichoroethane <2 <2 <2 <2 <2 <2 <2 benzene <2 2-methylhexane 2 2 <2 <2 <2 <2 <2 2,3-dimethylpentane <2 <2 <2 <2 <2 <2 <2 3-methylhexane 3 2 <2 <2 <2 <2 <2 heptane 6 4 <2 <2 <2 <2 <2 trichloroethene <2 <2 <2 <2 <2 <2 <2 propyl acetate <2 <2 <2 <2 3 3 <2 methylcyclohexane <2 <2 <2 <2 <2 4-methylpentan-2-one <2 <2 <2 <2 <2 <2 <2 toluene <2 octane <2 <2 <2 <2 <2 <2 <2 tetrachloroethene <2 <2 <2 <2 <2 <2 <2 butyl acetate <2 <2 <2 <2 <2 <2 <2 ethylbenzene <2 m+p-xylene <2 o-xylene <2 nonane <2 <2 <2 <2 <2 <2 <2 alpha pinene <2 <2 <2 <2 <2 <2 <2 propylbenzene <2 <2 <2 <2 <2 <2 <2 1,3,5-trimethylbenzene <2 <2 <2 <2 <2 <2 <2 beta pinene <2 <2 <2 <2 <2 <2 <2 decane <2 <2 <2 <2 <2 2 <2 1,2,4-trimethylbenzene <2 limonene <2 <2 <2 <2 <2 <2 <2 undecane <2 <2 <2 <2 3 3 <2 dodecane <2 <2 <2 <2 2 3 <2 tetradecane <2 <2 <2 <2 <2 <2 <2 < = less than the limit of detection ` Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A53 of A55
54 APPENDIX G Terms and Conditions for the Supply and Use of Environment Canterbury Information Appendix G contains 2 pages including cover Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A54 of A55
55 Terms and conditions for the supply and use of Environment Canterbury (promotional name for Canterbury Regional Council) information. Environment Canterbury Your regional council DESCRIPTION OF INFORMATION Information supplied to: JWarren (Judy) Description of information to which these terms and conditions apply: Ten minute average PM 1 measured by TEOM@4 C at St Albans Coles Pl from March 1 to July 31, 21. For gaps of less than 6 hours interpolation has been used to fill gaps. Interpolated and non interpolated data are given. Daily averages from 9am are also included and the relationship with beta data defined and beta equivalent concentrations calculated. GENERAL TERMS AND CONDITIONS 1. Environment Canterbury owns the copyright on the information. 2. Environment Canterbury shall be acknowledged as the source of the information used in any reports, publications, media statements or other documents, or oral statements which include the information and are made available to third parties or the general public. 3. A copy of these terms and conditions shall accompany any of the attached information which is made available to third parties. 4. The user of the attached information agrees to indemnify Environment Canterbury for any losses sustained as a consequence of breach of any of these conditions. DISCLAIMER The attached information is supplied on the basis that it is accurate to the best of Environment Canterbury knowledge and belief and is based on the information currently held by Environment Canterbury. While Environment Canterbury has exercised all reasonable skill and care in controlling this information, Environment Canterbury accepts no liability in contract, tort or otherwise howsoever, for any loss, damage, injury or expense (whether direct, indirect or consequential) arising out of the provision of this information or its use by you. NOTE ON PROVISIONAL INFORMATION The attached information is provisional/audited (delete one) information. Provisional information has not yet been checked using the Council s Quality Assurance audit procedures. Provisional information may be subject to significant changes and are not citeable until reviewed and approved by Environment Canterbury. Information users are cautioned to consider carefully the nature of provisional information before using it for decisions that concern personal or public safety or the conduct of business that involves monetary or operational consequences. Prepared by: Teresa Aberkane Date: 8/8/1 Watercare Services Ltd: AQG-A;3. MfE GEMS Annual Report Appendicies A55 of A55
The following report includes the data for the above referenced project for sample(s) received on 5/15/2017 at Air Toxics Ltd.
5/26/2017 Ms. Anna Kelley Hamilton Co. Environmental Services 250 Wm. Howard Taft Cincinnati OH 45219 Project Name: Sun Coke Project #: Workorder #: 1705303 Dear Ms. Anna Kelley The following report includes
GAMINGRE 8/1/ of 7
FYE 09/30/92 JULY 92 0.00 254,550.00 0.00 0 0 0 0 0 0 0 0 0 254,550.00 0.00 0.00 0.00 0.00 254,550.00 AUG 10,616,710.31 5,299.95 845,656.83 84,565.68 61,084.86 23,480.82 339,734.73 135,893.89 67,946.95
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