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1 Subject : I- Application of Spectroscopy, photo Chemistry and Solid State Chemistry Maximum Marks : Q1 Explain the kinetics of solid state reactions. Q2 What are basic principles, spectral parameters and spectrum display of Mossbauer spectroscopy. Q.3 Describe the cyclisation reaction rearrangement of 1,4 and 1, 5 dienes. Q.4 Define the two dimensional NMR Spectroscopy COSY and INEPT. Q.5 Describe the organic charge transfer complex and new super conductors Q1 Explain photochemical formation of smog. Q2 What is electron spin resonance spectroscopy. Give hyperfine coupling and spin orbit coupling. Q.3 Write notes on the following a) Oxetane formation b) Photochemistry of revision c) Cyclo hexa dienones Q.4 Describe the characteristics of vibration frequencies of alkenes, alkynes, alcohol and acetones. Q.5 Describe the types of excitation and fate of excited molecules
2 Subject : II - Bio-inorganic Chemistry, Bio-organic chemistry and Bio physical chemistry Maximum Marks : Q1 Explain the structure and function of cell membrane. Q2Explain the electron transfer in biology. Q 3Describe Hydrolysis and synthesis of ATP from ADP. Q.4 Explain poly peptide and protein structure. Q.5 Explain the Biological cell structure and functions of proteins and enzymes. Q1 Explain techniques and methods of immobilization of enzymes. Q2Write note on essential and trace metals. Q.3Write the note on chain configuration of macro molecules. Q4 Explain multiple displacement reaction and the coupling of ATP cleavage to eridergonic processes. Q.5 Describe the Na+/K+ Pump
3 Subject : III Environmental Chemistry Maximum Marks : Q.1 Describe and C and N cycles. Q2 Write a short note on water treatment process. Q3 What are the different types of activated sludge processes employed in waste water treatment Q4 What are Fertilizers? How are they classified? Write their characteristics. Q. 5 Explain the soil composition, macro and micro nutrients Q1(a) What is meant by pesticides. (b) Explain DDT in details. Q.2Explain Bio Diversity. Q3 Write short note on following a) Acid Rain b) Global Warming Q4 Define meaning of environment? What are its various segments? Q. 5 Detail study of thermal power plant pollution?
4 Subject IV (Optional)- Chemistry of Natural Products Maximum Marks : 30 Q1 (a) How will you estabilish the structure of α - Terpeneol. (b) Discuses the general method for structure determination of terpenoids. Q2 What are the constituents and biological activity of vitexin? Q3 Discuss the biosynthesis of steroids. Q4 Explain the synthesis B-Carotene. Q.5 Explain the occurrence and classification of prostaglandins. Q1 Discuss the position of hydroxyl group and double bond in cholesterol. Q2 (a) Describe the brief account of structure of Abietic acid. (b) What is special Isoprene rule? Q3 Discuss about the synthesis of Butein. Q.4 Discuss the role of Alkaloids. Q.5 Write the syntheses of PGE2.
5 Subject IV (Optional)- Organotransition Metal chemistry Maximum Marks : 30 Q1 Explain Zeigler-Natta polymerication of olefins. Q2 Explain the routes of synthesis in alkyls transition metals. Q3 Describe the nature of bond structure characteristics of low valent carbenes. Q4 Give the preparation properties, nature of bonding and structural features of transition metal complexes. Q5 Explain the Fluxional organometallic Compounds. Q1 Explain homogeneous catalytic hydrogenation. Q2 Explain fluxionality and dynamic equilibria in compound dienyl complexes. Q.3 Explain the importance of reactions relating to necleophilic and elctrophilic reactions of ligands. Q.4 Explain the stability and decomposing and pathway of alkyne transition metals. Q5 Describe the alkyl transition metal types and Routes of synthesis.
6 Subject : V (Optional)- Medicinal Chemistry Maximum Marks : 30 Q1 Write the synthesis of: (a) Uracil (b) Mustards (c) Melphalan Q2 What do you mean by β-lactam Rings? Q3Write a short note on the significance of drug metabolism in medicinal chemistry. Q4 Explain the history and development of QSAR. Q5 What is Biotransformation. Describe significance of drug metabolism in medicine. Q1 Give synthesis of: (a) Penicillin (b) Tetracycline Q2 What is pharmacodynamics? Q3Describe the cardiovascular drug. Q4 Explain the synthesis of diazepam use flow sheet diagram method. Q5 Explain drug receptor and give its classification by flow sheet method.
7 Subject : V (Optional)- ANALYTICAL CHEMISTRY Maximum Marks : 30 Q1 Explain the extraction and purification of food sample by HPCL. Q.2 Write a short note on Heavy metal pollution and its contamination. Q3Describe the role of analytical chemistry. Q4 What are carbohydrates Explain in detail. Q5 Write the short notes on following (A) Standard deviation (B) Mean and Median Q1 Define the various terms 1. R.S.D. 2. S.D. Q2 What is soil pollution.how it analysed. Q3 What are gravimetric techniques? Explain. Q4 Explain the following: (a) Crude protein (b) Food contamination Q5 Discuss about the classification of drugs
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