[Volume I] 1. CHEMICAL CALCULATIONS
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1 [Volume I] 1. CHEMICAL CALCULATIONS 1. What is Avogadro s number? (2) 2. Define mole (3) 3. What is stoichiometry? (11) 4. Define oxidation in terms of electronic concept (13) 5. Define reduction in terms of electronic concept (14) 6. Define oxidation number (14) 7. Define molarity (20) 8. Define molality (21) 9. Define normality (20) 10. Define mole fraction (21) 11. What are the methods can be used to determine equivalent mass? (26) 12. How can you determine the amount of substance by volumetric analysis? (24) 13. What is equivalent mass of acid? (28) 14. What is equivalent mass of base? (29) 15. What is equivalent mass of salt? (29) 16. What is equivalent mass of oxidizing, reducing agent? (29,30) 1. How will you calculate the molecular mass of a volatile compound using Victor Meyer s method? (31) 2. Calculate Embirical formula and molecular formula (6-11) 3. How will you determine the equivalent mass of elements by hydrogen displacement method? (26) 4. How will you determine the equivalent mass of elements by oxide method? (27) 5. How will you determine the equivalent mass of elements by chloride method? (28) 2. GENERAL INTRODUCTION TO METALLURGY 1. Distinguish between ore and mineral with suitable example (37) 2. What are the different method of concentration of ore? (40) 3. Define metallurgy (42) 4. What is calcinations? Give example (43) 5. What is roasting? (42) 1
2 6. What is anode mud? (45) 7. What are the major steps involved in the metallurgical process? (42) 8. What is gravity separation? (40) 1. Explain froth floatation process with near diagram (40) 2. How electrolytic separation process is useful in the separation of magnetic impurities from non magnetic ores? Draw the diagram (41) 3. How the impurities of ore are removed by chemical method? (41) 4. What is smelting? Explain the process (43) 5. What is zone refining? Explain the process (46) 6. How nickel is extracted by Mond s process? (47) 7. Explain about electrolytic refining (45) 8. Explain about Bessimerisation process (44) 3. ATOMIC STRUCTURE I 1. What is Zeeman effect? (54) 2. What is stark effect? (54) 3. State Hund s rule (59) 4. State Pauli s exclusion principle (58) 5. What are the defects of Rutherford s model? (52) 1. Explain Aufbau principle (59) 2. What are the postulates of Bohr s theory of atom? (52) 3. Explain the various quantum numbers (54) 4. Explain Rutherford nuclear model of an atom (51) 5. What are the limitations of Bohr s theory? (53) 4. PERIODIC CLASSIFICATION 1. Why noble gases have zero electron gain enthalpy? (85) 2. Out of fluorine and chlorine, which has greater electron gain enthalpy? (85) 3. Define electronegativity (86) 4. Why boron has lower ionization energy than Beryllium? (88) 5. What is periodic law? (67) 2
3 6. What is modern periodic law? (69) 7. What is isoelectronic? (80) 8. Define ionization energy (81) 9. Define electron affinity (84) 10. Electron affinity of Be and Mg is zero. Why? (89) 1. What are the difference between electron gain enthalpy and electro negativity? (87) 2. Explain the factors which influence ionization enthalpy (83) 3. Explain the factors which influence electron affinity (86) 5. GROUP 1S BLOCK ELEMENTS 1. What are isotopes? Mention the isotopes of hydrogen. (96) 2. Mention the uses of deuterium. (99) 3. How do you convert para hydrogen and ortho hydrogen? (101) 4. How is hydrogen peroxide prepared in the laboratory? (104) 5. How does heavy water react with metals? (103) 6. Write about reducing property of hydrogen peroxide (105) 7. Write about oxidizing property of hydrogen peroxide (105) 8. Mention the uses of hydrogen peroxide (106) 9. What is photoelectric effect? (108) 10. What are the uses of sodium? (112) 11. Mention the uses of heavy water (104) 12. How does deuterium react with nitrogen and metals? (99) 13. How is hydrogen peroxide solution concentrated? (105) 1. Explain the preparation of heavy water (101) 2. Explain how liquid hydrogen can be used as a fuel (106) 3. How is sodium extracted? Explain with a diagram (110) 4. How is lithium extracted? (109) 5. Differentiate between ortho and para hydrogen (100) 3
4 6. GROUP 2S BLOCK ELEMENTS 1. What are the important ores of Magnesium? (119) 2. How is Gypsum prepared? Mention its uses (122) 3. What are the diagonal relationship between Be and Al? (119) 4. What is slaking of lime? (122) 5. How is plaster of paris prepared? (123) 6. Mention the uses of plaster of paris (123) 1. How is magnesium extracted from its ore? (119) 7. P- BLOCK ELEMENTS 1. Mention the nature of hydrides in P block elements (130) 2. What are the uses of Borax (132) 3. Mention the uses of Nitrogen compounds (140) 4. How is nitric acid prepared in the lab? (140) 5. What are acidic oxides? (143) 6. What are basic oxides? (144) 7. What are amphoteric oxides? (144) 8. Write note on peroxides (144) 1. Explain inert pair effect with suitable example. (128) 2. How borax bead test is helpful in identifying basic radicals in qualitative analysis? (133) 3. Discuss the structural differences between diamond and graphite (134) 4. Write a short note on fixation of nitrogen (139) 5. How nitric acid is prepared by Ostwald process? (141) 6. Explain the laboratory preparation of ozone (145) 7. Which is considered to earth s protective umbrella? (147) 8. How is ammonia manufactured by Haber s process? (138) 9. How is molecular oxygen important for all oxygenated animals? (141) 4
5 8. SOLID STATE-I 1. Define unit cell (156) 2. How many types of cubic unit cell exists? (158) 3. What are miller indices? (161) 4. What are anisotropic and isotropic? (153,154) 5. How many type of cubic unit cell exists? (158) 1. Give the distinguishing features of crystalline solids and amorphous solids (153,154) 2. Draw a neat diagram for sodium chloride structure and explain (159) 3. Draw a neat diagram for cesium chloride structure and explain (160) 9. GASEOUS STATE 1. Define Boyle s law and Charle s law (171) 2. Define Graham s law of diffusion (172) 3. Write the significance of Vanderwaal s constants (184) 4. Write the limitations of Vanderwaal s equation (185) 5. Define Joule Thomson s effect (192) 6. What is meant by inversion temperature? (193) 7. State Dalton s law of partial pressure (175) 8. What is critical temperature? (186) 9. What is critical pressure? (186) 10. What is critical volume? (186) 11. What are the conditions for liquefaction of gases? (193) 1. Deduce the relationship between critical constants and Vanderwaal s constants (188) 2. Describe Linde s process of liquefaction of gases (194) 3. Describe Claude s process of liquefaction of gases (195) 4. Derive Vanderwaal s equation of state (180) 5. Explain Andrews Isotherm of Carbondioxide (186) 6. Explain Thomson s experiment of carbondioxide (187) 5
6 [Volume II] 10. CHEMICAL BONDING 1. What is the structure of BeCl 2? (2) 2. What is octet rule? Give an example (2) 3. What is meant by electrovalent bond? (3) 4. What is meant by hybridization? (25) 5. Define resonance (25) 6. What is covalent bonding? (4) 7. What are the different types of chemical bonding? (5) 8. What is coordinate or dative bond? (27) 1. Discuss the important properties of electrovalent compounds (11) 2. Calculate the lattice energy of NaCl using Born Haber cycle (8,9) 3. Explain the important properties of covalent compounds (13) 4. Discuss the partial covalent character in ionic compounds using Fajan s rule (14) 5. Discuss the shapes of the following molecules NH 3, H 2 O, SO 2, SF 6 (19,20) 6. Explain the consequences of resonance with suitable example (25,26) 11. COLLIGATIVE PROPERTIES 1. What is colligative property? Mention them (31) 2. Define relative lowering of vapour pressure (33) 3. What do you understand by molal elevation of boiling point? (42) 4. Define osmosis and osmotic pressure (45) 5. What are the characteristics of osmatic pressure? (46) 6. Define Raoult s law (32) 7. What is Boyle s Vont Hoff law (46) 8. What is Cherle s Vont Hoff law (46) 9. Define Vant Hoff factor (48) 10. What are isotonic solution? (46) 11. What are the advantages of Berkley Hartley method? (47) 6
7 1. Explain the determination of relative lowering of vapour pressure by Ostwald walker method (34) 2. Describe the determination of depression in freezing point by Beckmann method (39) 3. Explain the determination of elevation of boiling point by Cottrell method (44) 4. Explain the laws of osmotic pressure and its determination by Berkley Hartley method (47) 12. THERMODYNAMICS-I 1. What are homogeneous and heterogeneous system? (56) 2. Define zeroth law of thermodynamics (61) 3. Define adiabatic process (58) 4. Write the differences between endothermic and exothermic process (60) 5. Define first law of thermodynamics (64) 6. What are intensive and extensive properties? (56) 7. Define enthalpy (65) 8. Define enthalpy of combustion (68) 9. Define enthalpy of neutralization (70) 1. Describe a bomb calorimeter and explain how heat of formation of an organic compound is determined (68) 2. Distinguish between reversible and irreversible process (59) 13. CHEMICAL EQUILIBRIUM-I 1. Define law of mass action (80) 2. What are reversible and irreversible reactions? (76) 3. What are homogeneous and heterogeneous equations? (80) 4. Chemical equilibrium is dynamic in nature. Why? (78) 5. What is equilibrium constant? (82) 1. Explain the characteristics of a chemical equilibrium (78) 2. Derive an expression for the Kp, Kc for the equilibrium H 2 +I 2 2HI (85) 3. Derive an expression for the Kp, Kc for the dissociation of PCl5 (87) 4. What are the characteristics of equilibrium constant? (91) 7
8 14. CHEMICAL KINETICS-I 1. Define rate law (99) 2. Define order (100) 3. What is molecularity? (101) 4. Define rate of a reaction (96) 5. Define rate constant (99) 6. What are the differences between rate of reaction and rate constant of reaction? (101) 1. Write the differences between order and molecularity (101) 2. Describe the factors on which the rate of reaction depends (98) 15. BASIC CONCEPTS OF ORGANIC CHEMISTRY 1. What is catenation (109) 2. Define homolytic and heterolytic fission (128) 3. What is substitution reaction? (129) 4. What is addition reaction? (130) 5. What is elimination reaction? (130) 6. What is polymerization reaction? (131) 7. What is condensation reaction? (131) 8. Define reduction and oxidation reaction (132) 9. What are acid and basic hydrolysis? (131,132) 10. Note on carbonium ion and carbanion (134) 1. What are the characteristics of organic compounds? (113) 2. What are homologous series? Explain their characteristics (113) 3. Distinguish between electrophiles and nucleophiles (133) 4. Explain the types of isomerism (126) 5. Explain the classification of organic compounds (109) 6. Explain about inductive effect (135) 7. Explain about resonance effect (136) 8
9 16. PURIFICATION OF ORGANIC COMPOUNDS 1. What are various methods used for purification and separation of organic compounds? (140) 2. What is sublimation? (142) 3. What is chromatography? (146) 4. What are the difference between paper and thin layer chromatography? (149) 5. What are different types of distillation? (143) 6. What is crystallization? (141) 7. What are the different stages of crystallization? (141) 8. What are the adsorbents used in column chromatography? (147) 9. What is an eluent? (147) 10. What are the advantages of distillation under reduced pressure? (145) 11. What are the types of paper chromatography? (148) 1. Explain the purification of compounds by using thin layer chromatography (147) 2. Explain the general characteristics of organic compounds (140) 3. Explain the procedure involved in steam distillation (144) 4. Explain the principle involved in the distillation under reduced pressure (145) 5. Explain about column chromatography (147) 6. Explain about paper chromatography (148) 17. DETECTION AND ESTIMATION OF ELEMENTS (No book back question and answers. Only sums. just refer) 1. How do you detect the presence of sulphur in an organic compound? (153) 2. How do you detect the presence of halogen in an organic compound? (153) 3. How do you detect the presence of oxygen in an organic compound? (152) 1. How do you detect the presence of carbon and hydrogen in an organic compound? (151) 2. Write the chemical equations involved in Lassigne test for nitrogen (152) 3. Explain the estimation of carbon and hydrogen by Lebig s combustion method (154) 4. Explain the estimation of nitrogen by Kjeldahl s method (157) 5. Explain the estimation of sulphur by Carius method (160) 6. Explain the estimation of halogen by Carius method (161) 9
10 18. HYDROCARBONS 1. What is ozonolysis? (180) 2. Define Markovnikov s rule (179) 3. Mention the uses of ethylene (181) 4. Mention the uses of acetylene (188) 5. What is wurtz reaction? (170) 6. Write Kolbe s electrolytic method (171) 7. What is Finkelstein s reaction (173) 8. Define aromatization (174) 9. What is epoxidation? (181) 10. Write Diels Alder reaction (181) 11. What are test for acetylene (188) 12. What happens when acetylene is passed through red hot tube? (188) 13. What is hydroboration? (180) 14. How is ethylene hydrated? (179) 1. Define aromaticity (193) 2. What is Friedel craft s reaction? (195) 3. Mention the uses of benzene (199) 4. What is wurtz fittig reaction? (213) 5. Write briefly resonance in benzene (201) 5 MARKS 19. AROMATIC HYDROCARBONS 1. Explain about the structure of benzene (198) 20. ORGANIC HALOGEN COMPOUNDS 1. What is Hunsdiecker reaction? (206) 2. What is Finkelstein reaction? (206) 3. What is swartz reaction? (207) 4. How is DDT prepared? Mention its uses (214) 5. What is fittig reaction? (213) 10
11 6. What are Grignard reagent? (215) 7. Mention the uses of alkyl halides (211) 1. Discuss SN1 reaction mechanism (209) 2. Discuss SN2 reaction mechanism (208) 3. Discuss E1 mechanism (210) 4. Discuss E2 mechanism (210) 5. Explain synthetic uses of methyl magnesium iodide (216) 6. What are the general methods of preparation of alkyl halides (206) ***** DEDICATED TO : ALL THE TEACHERS AND STUDENTS BY : G. SURESH MSc,M.A,B.Ed 26/GANDHI NAGAR, CHINNAMANUR THENI [DT] PH: E mail: vivekasuresh@gmail.com WORKING AT : A MATRIC HR.SEC.SCHOOL NEAR BUS STAND UTHAMAPALAYAM THENI [DT] Note: I hope the students can study selective questions from this question bank If any mistakes or your suggestions, please send your valuable thoughts to that whatsapp number or id to help all the students If blue print published, select the questions according to that THANK GOD AND THANK YOU ALL ALL THE BEST 11
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