Powder Surface Area and Porosity
|
|
- Bernard Alexander
- 6 years ago
- Views:
Transcription
1 Powder Surface Area and Porosity
2 Powder Technology Series EDITED BY BRIAN SCARLETI Delft University of Technology The Netherlands Many materials exist in the form of a disperse system, for example powders, pastes, slurries, emulsions and aerosols. The study of such systems necessarily arises in many technologies but may alternatively be regarded as a separate subject which is concerned with the manufacture, characterization and manipulation of such systems. Chapman and Hall were one of the first publishers to recognize the basic importance of the subject, going on to instigate this series of books. The series does not aspire to define and confine the subject without duplication, but rather to provide a good home for any book which has a contribution to make to the record of both the theory and the application of the subject. We hope that all engineers and scientists who concern themselves with disperse systems will use these books and that those who become expert will contribute further to the series. Particle Size Measurement T. Allen 4th edn, hardback ( X), 832 pages Powder Surface Area and Porosity S. Lowell and Joan E. Shields 3rd edn, hardback ( ), 256 pages Pneumatic Conveying of Solids R.D. Marcus, L.S. Leung, G.E. Klinzing and F. Rizk Hardback ( ), 592 pages Particle Technology Hans Rumpf Translated by F.A. Bull Hardback ( ), 216 pages
3 Powder Surface Area and Porosity S. LOWELL Quantachrome Corporation, USA JOAN E. SHIELDS c. w. Post Campus of Long Island University, USA THIRD EDITION Springer-Science+Business Media, B.V.
4 First edition 1979 published as Introduction to Powder Surface Area by John Wiley & Sons Inc., New York Second edition 1984 published as Powder Surface Area and Porosity by Chapman and Hall Ltd Third edition ,1991 S. Lowell and J.E. Shields Originally published by Chapman and Hall in Softcover reprint of the hardcover 1 st edition 1991 Typeset in 1O/12pt Times by Best-set Typesetter Ltd, Hong Kong ISBN ISBN (ebook) DOI / Apart from any fair dealing for the purposes of research or private study, or criticism or review, as permitted under the UK Copyright Designs and Patents Act, 1988, this publication may not be reproduced, stored or transmitted, in any form or by any means, without the prior permission in writing of the publishers, or in the case of repro graphic reproduction only in accordance with the terms of the licences issued by the Copyright Licensing Agency in the UK, or in accordance with the terms of licences issued by the appropriate Reproduction Rights Organization outside the UK. Enquiries concerning reproduction outside the terms stated here should be sent to the publishers at the UK address printed on this page. The publisher makes no representation, express or implied, with regard to the accuracy of the information contained in this book and cannot accept any legal responsibility or liability for any errors or omissions that may be made. British Library Cataloguing in Publication Data Lowell, S. (Seymour) An introduction to powder characterization. 1. Powders I. Title Library of Congress Cataloging-in-Publication Data available
5 Contents Preface Symbols x xi PART 1 THEORETICAL 1 1 Introduction Real surfaces Factors affecting surface area Surface area from particle size distributions 5 2 Gas adsorption Introduction Physical and chemical adsorption Physical adsorption forces 9 3 Adsorption isotherms 11 4 Langmuir and BET theories (kinetic isotherms) The Langmuir isotherm, Type I The Brunauer, Emmett, and Teller (BET) theory Surface areas from the BET equation The meaning of monolayer coverage The BET constant and site occupancy Applicability of the BET theory Some criticism of the BET theory 27 5 The single point BET method Derivation of the single point method Comparison of the single point and multipoint methods Further comparisons of the multi- and single point methods 32 6 Adsorbate cross-sectional areas Cross-sectional areas from the liquid molar volume Nitrogen as the standard adsorbate Some adsorbate cross-sectional areas 41
6 vi Contents 7 Other surface area methods Harkins and Jura relative method Harkins and Jura absolute method Permeametry 46 8 Pore analysis by adsorption The Kelvin equation Adsorption hysteresis Types of hysteresis Total pore volume Pore size distributions Modelless pore size analysis V-tcurves 68 9 Microporosity Introduction Langmuir plots for microporous surface area Extensions of Polanyi's theory for micropore volume and area The t-method The as-method The micropore analysis method Total micropore volume and surface area Theory of wetting and capillarity for mercury porosimetry Introduction Young and Laplace equation Wetting or contact angles Capillarity Washburn equation Interpretation of mercury porosimetry data Applications of the Washburn equation Intrusion-extrusion curves Common features of porosimetry curves Solid compressibility Surface area from intrusion curves Pore size distribution Volume In radius distribution Pore surface area distribution Pore length distribution Pore population Plots of porosimetry functions Comparisons of porosimetry and gas adsorption 119
7 Contents vii Hysteresis, entrapment and contact angle Introduction Contact angle changes Porosimetric work Theory of porosimetry hysteresis Pore potential Other hysteresis theories Equivalency of mercury porosimetry and gas adsorption Particle size Introduction Stokes'law X-ray absorption Particle size distributions Reynolds number Particle porosity and density Wall effects Particle concentration Diffusion effects Terminal velocity PART 2 EXPERIMENTAL Adsorption measurements - preliminaries Reference standards Other preliminary precautions Representative samples Sample conditioning Vacuum volumetric measurements Nitrogen adsorption Deviations from ideality Sample cells Evacuation and degassing Temperature control Isotherms Low surface areas Saturated vapor pressure Automated instrumentation Quasi-equilibrium systems Dynamic methods Influence of helium
8 viii Contents 16.2 Nelson and Eggertsen continuous flow method Carrier gas and detector sensitivity Design parameters for continuous flow apparatus Signals and signal calibration Adsorption and desorption isotherms by continuous flow Low surface area measurements Data reduction - continuous flow Single point method Other flow methods Pressure jump method Continuous isotherms Frontal analysis Gravimetric method Electronic micro balances Buoyancy corrections Thermal transpiration Other gravimetric methods Comparison of experimental adsorption methods Chemisorption Introduction Chemisorption equilibrium and kinetics Chemisorption isotherms Surface titrations Mercury porosimetry Introduction Pressure generators Dilatometer Continuous scan porosimetry Logarithmic signals from continuous scan porosimetry Low-pressure intrusion-extrusion scans Contact angle for mercury porosimetry Density measurement True density Apparent density Bulk density Tap density Effective density Density by Mercury porosimetry 232
9 Particle size analysis Introduction Sample preparation Sedimentation fluid Dispersion Data reduction Contents ix References Index
10 Preface The rapid growth of interest in powders and their surface properties in many diverse industries prompted the writing of this book for those who have the need to make meaningful measurements without the benefit of years of experience. It is intended as an introduction to some of the elementary theory and experimental methods used to study the surface area, porosity, density, and particle size of powders. It may be found useful by those with little or no training in solid surfaces who have the need to learn quickly the rudiments of surface area, density, pore size, and particle size measurements. S. Lowell J.E. Shields
11 Symbols Use of symbols for purposes other than those indicated in the following table are so defined in the text. Some symbols not shown in the table are also defined in the text. d A C c D E f F g G G S h H Hi Hsv k K C L M M MPa n N N.AI" P Po P PSIA adsorbate cross-sectional area area; condensation coefficient; collision frequency BET constant concentration diameter; coefficient of thermal diffusion adsorption potential permeability aspect factor flow rate; force; feed rate gravitational constant Gibbs free energy free surface energy heat of immersion per unit area; height enthalpy heat of immersion heat of adsorption BET intercept; filament current thermal conductivity; specific reaction rate Harkins-Jura constant length heat of liquefaction mass molecular weight megapascals number of moles number of molecules; number of particles Avogadro's num'ber molecular collisions per square cm per second pressure saturated vapor pressure porosity pounds per square inch absolute
12 xii Symbols PSIG pounds per square inch gauge, radius 'k core radius 'p pore radius 'h hydraulic radius R gas constant; resistance s BET slope S specific surface area; entropy St total surface area t time; statistical depth T absolute temperature U pore potential v linear flow velocity; settling velocity V volume V molar volume Vp pore volume W work; weight W m monolayer weight X mole fraction a temperature coefficient ~ affinity coefficient, nonideality correction; compressibility y surface tension 11 viscosity e contact angle eo fraction of surface unoccupied by adsorbate en fraction of surface covered by n layers of adsorbate ~m micrometers (10-6 m) v vibrational frequency n surface pressure p density 1: monolayer depth; time per revolution; time for one cycle 'I' change in particle diameter per collector per revolution
Powder Surface Area and Porosity
Powder Surface Area and Porosity Powder Technology Series Edited by B. Scarlett Department of Chemical Engineering University of Technology Loughborough Powder Surface Area and Porosity S. Lowell PhD Quantachrome
More informationElectrical and Magnetic Methods of Non-destructive Testing
Electrical and Magnetic Methods of Non-destructive Testing NON-DESTRUCTIVE EVALUATION SERIES Non-destructive evaluation now has a central place in modem technology both as a means of evaluating materials
More informationIntroduction to CLASSICAL MECHANICS
Introduction to CLASSICAL MECHANICS Introduction to CLASSICAL MECHANICS A.P. FRENCH Massachusetts Institute oj Technology M.G. EBISON The Institute oj Physics, London KLUWER ACADEMIC PUBLISHERS DORDRECHT
More informationStructure and Properties of Oriented Polymers
Structure and Properties of Oriented Polymers Structure and Properties of Oriented Polymers Edited by 1. M. Ward IRC in Polymer Science and Technology Universities of Leeds, Bradford and Durham UK I uni
More informationGeophysical Interpretation using Integral Equations
Geophysical Interpretation using Integral Equations Geophysical Interpretation using Integral Equations L. ESKOLA Head of the Geophysics Department, Geological Survey of Finland 1~lll SPRINGER-SCIENCE+BUSINESS
More informationAstronomy with a Budget Telescope
Astronomy with a Budget Telescope Springer-Verlag London Ltd. Patrick Moore and John Watson Astro omy w h a Budget elescope With 100 Figures, 98 in colour, Springer British Library Cataloguing in Publication
More informationPhysics and Chemistry of Interfaces
Hans Jürgen Butt, Karlheinz Graf, and Michael Kappl Physics and Chemistry of Interfaces Second, Revised and Enlarged Edition WILEY- VCH WILEY-VCH Verlag GmbH & Co. KGaA Contents Preface XI 1 Introduction
More informationChemistry by Computer. An Overview of the Applications of Computers in Chemistry
Chemistry by Computer An Overview of the Applications of Computers in Chemistry Chemistry by Computer An Overview of the Applications of Computers in Chemistry Stephen Wilson Theoretical Chemistry Department
More informationParticle Size Determinations: Dynamic Light Scattering: page 161 text
Particle Size Determinations: Dynamic Light Scattering: page 161 text Dynamic light scattering (also known as Photon Correlation Spectroscopy or Quasi- Elastic Light Scattering) is a technique which can
More informationFinite Element Analysis for Heat Transfer. Theory and Software
Finite Element Analysis for Heat Transfer Theory and Software Hou-Cheng Huang and Asif S. Usmani Finite Element Analysis for Heat Transfer Theory and Software With 62 Figures Springer-Verlag London Berlin
More informationConvective Heat Transfer
Convective Heat Transfer Solved Problems Michel Favre-Marinet Sedat Tardu This page intentionally left blank Convective Heat Transfer This page intentionally left blank Convective Heat Transfer Solved
More informationSpecific Surface Area and Porosity Measurements of Aluminosilicate Adsorbents
ORIENTAL JOURNAL OF CHEMISTRY An International Open Free Access, Peer Reviewed Research Journal www.orientjchem.org ISSN: 0970-020 X CODEN: OJCHEG 2016, Vol. 32, No. (5): Pg. 2401-2406 Specific Surface
More informationP.M. Cohn. Basic Algebra. Groups, Rings and Fields. m Springer
Basic Algebra P.M. Cohn Basic Algebra Groups, Rings and Fields m Springer P.M. Cohn, MA, PhD, FRS Department of Mathematics, University College London, Gower Street, London WC1E 6BT, UK British Library
More informationThermal Plasmas. Fundamentals and Applications. Volume 1
Thermal Plasmas Fundamentals and Applications Volume 1 Thermal Plasmas Fundamentals and Applications Volume 1 Maher I. Boulos University 0/ Sherbrooke Sherbrooke, Quebec, Canada Pierre Fauchais University
More informationDifferential Scanning Calorimetry
Differential Scanning Calorimetry Springer-Verlag Berlin Heidelberg GmbH G. W. H. H6hne. W. F. Hemminger H.-J. Flammersheim Differential Scanning Ca lori metry 2nd revised and enlarged edition With 130
More informationPractical Astronomy. Springer-Verlag London Ltd.
Practical Astronomy Springer-Verlag London Ltd. Other titles in this series The Modern Amateur Astronomer Patrick Moore (Ed.) Telescopes and Techniques: An Introduction to Practical Astronomy C. R. Kitchin
More informationChemical Kinetics and Catalysis
Chemical Kinetics and Catalysis FUNDAMENTAL AND APPLIED CATALYSIS Series Editors: M. V. Twigg Johnson Matthey Catalytic Systems Division Royston, Hertfordshire, United Kingdom M. S. Spencer School of Chemistry
More informationProbability Theory, Random Processes and Mathematical Statistics
Probability Theory, Random Processes and Mathematical Statistics Mathematics and Its Applications Managing Editor: M.HAZEWINKEL Centre for Mathematics and Computer Science, Amsterdam, The Netherlands Volume
More informationThermodynamics of Surfaces and Capillary Systems
CHEMICAL ENGINEERING SERIES CHEMICAL THERMODYNAMICS SET Volume 7 Thermodynamics of Surfaces and Capillary Systems Michel Soustelle Thermodynamics of Surfaces and Capillary Systems Chemical Thermodynamics
More informationAdvanced Engineering. Dynamics. H. R. Harrison. T. Nettleton. Formerly Department of Mechanical Engineering & Aeronautics City University London
Advanced Engineering Dynamics H. R. Harrison Formerly Department of Mechanical Engineering & Aeronautics City University London T. Nettleton Formerly Department of Mechanical Engineering & Aeronautics
More informationLecture 5. Solid surface: Adsorption and Catalysis
Lecture 5 Solid surface: Adsorption and Catalysis Adsorbtion G = H T S DG ads should be negative (spontaneous process) DS ads is negative (reduced freedom) DH should be negative for adsorption processes
More informationPhysics for Scientists & Engineers with Modern Physics Douglas C. Giancoli Fourth Edition
Physics for Scientists & Engineers with Modern Physics Douglas C. Giancoli Fourth Edition Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the
More informationISO 9277 INTERNATIONAL STANDARD. Determination of the specific surface area of solids by gas adsorption BET method
INTERNATIONAL STANDARD ISO 9277 Second edition 2010-09-01 Determination of the specific surface area of solids by gas adsorption BET method Détermination de l'aire massique (surface spécifique) des solides
More information1000 Solved Problems in Classical Physics
1000 Solved Problems in Classical Physics Ahmad A. Kamal 1000 Solved Problems in Classical Physics An Exercise Book 123 Dr. Ahmad A. Kamal Silversprings Lane 425 75094 Murphy Texas USA anwarakamal@yahoo.com
More informationMultilayer Adsorption Equations. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad
Multilayer Adsorption Equations Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Empirical isotherm equations BET Surface area determination Limitation Measurement method BDDT
More informationElectrochemical Process Engineering. A Guide to the Design of Electrolytic Plant
Electrochemical Process Engineering A Guide to the Design of Electrolytic Plant Electrochemical Process Engineering A Guide to the Design of Electrolytic Plant F. Goodridge and K. Scott University of Newcastle
More informationConversion Tables of Units in Science & Engineering
Conversion Tables of Units in Science & Engineering Conversion Tables of Units in Science & Engineering Ari L. Horvath Imperial Chemical Industries PLC, Mond Division, Runcorn, Cheshire, UK M MACMILLAN
More informationAn Introduction to Chemical Kinetics
An Introduction to Chemical Kinetics Michel Soustelle WWILEY Table of Contents Preface xvii PART 1. BASIC CONCEPTS OF CHEMICAL KINETICS 1 Chapter 1. Chemical Reaction and Kinetic Quantities 3 1.1. The
More informationRarefied Gas Dynamics
Rarefied Gas Dynamics Rarefied Gas Dynamics Mikhail N. Kogan Computer Center Academy of Sciences of the USSR Moscow Translated from Russian Translation Editor Leon Trilling Department of Aeronautics and
More informationMACMILLAN PHYSICAL SCIENCE
Thermal physics MACMILLAN PHYSICAL SCIENCE Series advisers Physics titles: Dr R L Havill, University of Sheffield Dr A K Walton, University of Sheffield Chemistry titles: Dr D M Adams, University of Leicester
More informationCHARACTERIZATION OF FLUID-ROCK INTERACTION BY ADSORPTION CALORIMETRY
SCA2018_053 1/8 CHARACTERIZATION OF FLUID-ROCK INTERACTION BY ADSORPTION CALORIMETRY D. Korobkov 1, V. Pletneva 1, E. Dyshlyuk 2 1 Schlumberger, Moscow Research Center and 2 Dahran Carbonate Research Center
More informationOSCILLATION THEORY FOR DIFFERENCE AND FUNCTIONAL DIFFERENTIAL EQUATIONS
OSCILLATION THEORY FOR DIFFERENCE AND FUNCTIONAL DIFFERENTIAL EQUATIONS Oscillation Theory for Difference and Functional Differential Equations by Ravi P. Agarwal Department of Mathematics, National University
More informationPearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world
Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world Visit us on the World Wide Web at: www.pearsoned.co.uk Pearson Education Limited 2014
More informationBET Surface Area Analysis of Nanoparticles *
OpenStax-CNX module: m38278 1 BET Surface Area Analysis of Nanoparticles * Nina Hwang Andrew R. Barron This work is produced by OpenStax-CNX and licensed under the Creative Commons Attribution License
More informationSelection Methods in Plant Breeding
Selection Methods in Plant Breeding PLANT BREEDING SERIES Edited by Professor P.D.S. Caligari Head of the Department of Agricultural Botany The University of Reading, UK Modem plant breeders need to have
More informationBASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA
BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA BASICS OF ANALYTICAL CHEMISTRY AND CHEMICAL EQUILIBRIA BRIAN M. TISSUE Virginia Tech Department of Chemistry Blacksburg, VA Cover Design: Wiley Cover
More informationHigh H2 Adsorption by Coordination Framework Materials
Arianna Marchioro Florian Degueldre High H2 Adsorption by Coordination Framework Materials Xiang Lin, Junhua Jia, Xuebo Zhao, K. Mark Thomas, Alexender J. Black, Gavin S. Walker, Neil R. Champness, Peter
More informationSYSTEMATIC ERRORS IN ENGINEERING EXPERIMENTS
SYSTEMATIC ERRORS IN ENGINEERING EXPERIMENTS By the same author A Background to Engineering Design SYSTEMATIC ERRORS IN ENGINEERING EXPERIMENTS PETER POLAK Department of Mechanical Engineering, University
More informationGas content evaluation in unconventional reservoir
Gas content evaluation in unconventional reservoir Priyank Srivastava Unconventional reservoirs 1 Average monthly prod. (mscf) The Problem Gas in-place calculation Prediction of production decline Total
More informationFOUNDATION SCIENCE FOR ENGINEERS
FOUNDATION SCIENCE FOR ENGINEERS Other titles of interest to engineers Dynamics G.E. Drabble Electric Circuits P. Silvester Electromagnetism R.G. Powell Engineering Mathematics, fourth edition K.A. Stroud
More informationCharacterisation of Microporous Materials by Finite Concentration Inverse Gas Chromatography
Characterisation of Microporous Materials by Finite Concentration Inverse Gas Chromatography Surface Measurement Systems Ltd. Finite concentration IGC SEA is a useful tool for the investigation of surface
More informationTHEORY OF MOLECULAR EXCITONS
THEORY OF MOLECULAR EXCITONS THEORY OF MOLECULAR EXCITONS A. S. Davydov Kiev State University Kiev, USSR Translated from Russian by Stephen B. Dresner g? SPRINGER SCIENCE+BUSINESS MEDIA, LLC 1971 Aleksandr
More informationNOTICE CONCERNING COPYRIGHT RESTRICTIONS
NOTICE CONCERNING COPYRIGHT RESTRICTIONS This document may contain copyrighted materials. These materials have been made available for use in research, teaching, and private study, but may not be used
More informationColloids and Interfaces with Surfactants and Polymers An Introduction
Colloids and Interfaces with Surfactants and Polymers An Introduction Colloids and Interfaces with Surfactants and Polymers An Introduction J. W. Goodwin ß 2004 John Wiley & Sons, Ltd ISBN: 0-470-84142-7
More informationSOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS
SOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS ASAP 2020 Plus: Accelerated Surface Area and Porosimetry System The Micromeritics ASAP 2020 Plus integrates a variety of automated gas
More informationLab. Standard Methods
Lab Standard Methods Quantachrome Instruments LabQMC 1900 Corporate Drive, Boynton Beach, FL 33426. 561.731.4999 Fax: 561.732.9888 www.labqmc.quantachrome.com lab.qt@anton-paar.com Standard Methods Technical
More informationION EXCHANGE TRAINING MANUAL
ION EXCHANGE TRAINING MANUAL GEORGE P. SIMON ~ SPRINGER SCIENCE+BUSINESS MEDIA, LLC Copyright 1991 by Springer Science+ Business Media New York Originally published by Van Nostrand Reinhold in 1991 Library
More informationOn Normalized Integral Table Algebras (Fusion Rings)
On Normalized Integral Table Algebras (Fusion Rings) For further volumes: www.springer.com/series/6253 Algebra and Applications Volume 16 Series Editors: Alice Fialowski Eötvös Loránd University, Budapest,
More informationEthers in a Porous Metal-Organic Framework
Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National
More informationUniversitext. Series Editors:
Universitext Universitext Series Editors: Sheldon Axler San Francisco State University, San Francisco, CA, USA Vincenzo Capasso Università degli Studi di Milano, Milan, Italy Carles Casacuberta Universitat
More informationMETHODS FOR PROTEIN ANALYSIS
METHODS FOR PROTEIN ANALYSIS Robert A. Copeland, PhD The DuPont Merck Pharmaceutical Company Experimental Station P.O. Box 80400 Wilmington, DE 19880-0400 METHODS FOR PROTEIN ANALYSIS A Practical Guide
More informationChemical Engineering Thermodynamics
Chemical Engineering Thermodynamics P Liquid P x 1 sat P 1 T sat T 2 T x 1 T x 1 T y 1 Liquid Vapour sat P 2 P x 1 P y 1 P y 1 Vapour sat T 1 x, y 1 1 x, y 1 1 Pradeep Ahuja Contents CHEMICAL ENGINEERING
More informationSpringer Berlin Heidelberg New York Barcelona Budapest Hong Kong London Milan Paris Santa Clara Singapore Tokyo
Springer Berlin Heidelberg New York Barcelona Budapest Hong Kong London Milan Paris Santa Clara Singapore Tokyo J. M. RUeger Electronic Distance Measurement An Introduction Fourth Edition With 56 Figures
More informationGAS-SURFACE INTERACTIONS
Page 1 of 16 GAS-SURFACE INTERACTIONS In modern surface science, important technological processes often involve the adsorption of molecules in gaseous form onto a surface. We can treat this adsorption
More informationPractical Statistics for Geographers and Earth Scientists
Practical Statistics for Geographers and Earth Scientists Nigel Walford A John Wiley & Sons, Ltd., Publication Practical Statistics for Geographers and Earth Scientists Practical Statistics for Geographers
More informationPhysical Adsorption of Gases onto Mesoporous Silica Material SBA-15
University of Tennessee, Knoxville Trace: Tennessee Research and Creative Exchange University of Tennessee Honors Thesis Projects University of Tennessee Honors Program 5-2012 Physical Adsorption of Gases
More informationCollection of problems in probability theory
Collection of problems in probability theory L. D. MESHALKIN Moscow State University Collection of problems in probability theory Translated from the Russian and edited by LEO F. BORON University of Idaho
More informationApplications of Electroactive Polymers
Applications of Electroactive Polymers Applications of Electroactive Polymers Edited by Bruno Scrosati Chemistry Department University of Rome 'La Sapienza' Italy [cn[ SPRINGER-SCIENCE+BUSINESS MEDIA,
More informationINTRODUCTION TO THE PHYSICS OF THE EARTH S INTERIOR
INTRODUCTION TO THE PHYSICS OF THE EARTH S INTERIOR SECOND EDITION JEAN-PAULPOIRIER Institut de Physique du Globe de Paris PUBLISHED BY THE PRESS SYNDICATE OF THE UNIVERSITY OF CAMBRIDGE The Pitt Building,
More informationEnergetic Performances of the Metal-Organic Framework ZIF-8 by. High Pressure Water Intrusion-Extrusion Experiments
Energetic Performances of the Metal-Organic Framework ZIF-8 by High Pressure Water Intrusion-Extrusion Experiments Guillaume Ortiz, Habiba Nouali, Claire Marichal, Gérald Chaplais, Joël Patarin Equipe
More informationAN INTRODUCTION TO HYDRODYNAMICS AND WATER WAVES
AN INTRODUCTION TO HYDRODYNAMICS AND WATER WAVES HYDRODYNAMICA SIVE DE VIRIBUS ET MOTIBUS FLUIDORUM COMMENTARII 'Remember, when discoursing about water, to induce first experience, then reason.' - Leonardo
More informationThis content has been downloaded from IOPscience. Please scroll down to see the full text.
This content has been downloaded from IOPscience. Please scroll down to see the full text. Download details: IP Address: 46.3.203.124 This content was downloaded on 30/12/2017 at 22:16 Please note that
More informationReliability Evaluation of Engineering Systems:
Reliability Evaluation of Engineering Systems: Concepts and Techniques Roy Billinton PhD, DSc, FEIC, FRSC, FIEEE, PE c. J. MacKenzie Professor of Electrical Engineering University of Saskatchewan and Ronald
More informationTHERMAl PHYSICS. P. C. RIEDl AN INTRODUCTION TO THERMODYNAMICS, STATISTICAL MECHANICS AND KINETIC THEORY
THERMAL PHYSICS THERMAl PHYSICS AN INTRODUCTION TO THERMODYNAMICS, STATISTICAL MECHANICS AND KINETIC THEORY P. C. RIEDl Department of Phsyics, University of St Andrews M P. C. Riedi 1976 Softcover reprint
More informationLandolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W.
Landolt-Börnstein Numerical Data and Functional Relationships in Science and Technology New Series / Editor in Chief: W. Martienssen Group VIII: Advanced Materials and Technologies Volume 6 Polymers Subvolume
More informationAPPLICATION OF DIFFERENTIAL SCANNING CALORIMETRY TO CORE ANALYSIS
SCA2013-055 1/7 APPLICATION OF DIFFERENTIAL SCANNING CALORIMETRY TO CORE ANALYSIS Evgeny Dyshlyuk, Schlumberger This paper was prepared for presentation at the International Symposium of the Society of
More information18.13 Review & Summary
5/2/10 10:04 PM Print this page 18.13 Review & Summary Temperature; Thermometers Temperature is an SI base quantity related to our sense of hot and cold. It is measured with a thermometer, which contains
More informationNumerical Methods for the Solution of Ill-Posed Problems
Numerical Methods for the Solution of Ill-Posed Problems Mathematics and Its Applications Managing Editor: M.HAZEWINKEL Centre for Mathematics and Computer Science, Amsterdam, The Netherlands Volume 328
More informationThe Effects of Adsorption and Desorption on Production and Reinjection in Vapor- Dominated Geothermal Fields
Home et al The Effects of Adsorption and Desorption on Production and Reinjection in Vapor- Dominated Geothermal Fields Roland N Horne, Henry J Ramey, Jr, Shubo Shang, Antonio Correa, John Hornbrook Stanford
More informationThermodynamic Properties of Cryogenic Fluids
Thermodynamic Properties of Cryogenic Fluids THE INTERNATIONAL CRYOGENICS MONOGRAPH SERIES General Editors Founding Editor K. D. Timmerhaus, Chemical Engineering Department University of Colorado. Boulder.
More informationInitial Boundary Value Problems in Mathematical Physics
Initial Boundary Value Problems in Mathematical Physics Initial Boundary Value Problems in Mathematical Physics Rolf leis University of Bonn Federal Republic of Germany Springer Fachmedien Wiesbaden GmbH
More informationConcepts in Surface Physics
M.-C. Desjonqueres D. Spanjaard Concepts in Surface Physics Second Edition With 257 Figures Springer 1. Introduction................................. 1 2. Thermodynamical and Statistical Properties of
More informationDIPOLE MOMENTS IN ORGANIC CHEMISTRY
DIPOLE MOMENTS IN ORGANIC CHEMISTRY PHYSICAL METHODS IN ORGANIC CHEMISTRY B. I. lonin and B. A. Ershov NMR Spectroscopy in Organic Chemistry, 1970 V. I. Minkin, O. A. Osipov, and Yu. A. Zhdanov Dipole
More informationLiquid Chromatography Mass Spectrometry. Techniques and Applications
Liquid Chromatography Mass Spectrometry Techniques and Applications MODERN ANALYTICAL CHEMISTRY Series Editor: David Hercules University of Pittsburgh ANALYTICAL ATOMIC SPECTROSCOPY William G. Schrenk
More informationContents. Preface XI Symbols and Abbreviations XIII. 1 Introduction 1
V Contents Preface XI Symbols and Abbreviations XIII 1 Introduction 1 2 Van der Waals Forces 5 2.1 Van der Waals Forces Between Molecules 5 2.1.1 Coulomb Interaction 5 2.1.2 Monopole Dipole Interaction
More informationGIS AND TERRITORIAL INTELLIGENCE. Using Microdata. Jean Dubé and Diègo Legros
GIS AND TERRITORIAL INTELLIGENCE Spatial Econometrics Using Microdata Jean Dubé and Diègo Legros Spatial Econometrics Using Microdata To the memory of Gilles Dubé. For Mélanie, Karine, Philippe, Vincent
More informationCLAY MINERALS BULLETIN
CLAY MINERALS BULLETIN DECEMBER, 1959 Vol. 4, NO. 22 A GAS ADSORPTION METHOD FOR RAPID COMPARISON OF SPECIFIC SURFACE AREAS By J. M. HAYNES Research Laboratories, English Clays Lovering Pochin & Co. Ltd.,
More informationElectronic Supporting information (ESI) for
Electronic Supporting information (ESI) for Experimental assessment of physical upper limit for hydrogen storage capacity at 20 K in densified MIL-101 monoliths Hyunchul Oh a, Dan Lupu b, Gabriela Blanita
More informationHeat Transfer in Fluidized Beds
Heat Transfer in Fluidized Beds Powder Technology Series EDITED BY BRIAN SCARLETI Delft University of Technology The Netherlands and GENJI JIMBO Chubu Powtech Plaza Lab Japan Many materials exist in the
More informationSTOCHASTIC PROCESSES FOR PHYSICISTS. Understanding Noisy Systems
STOCHASTIC PROCESSES FOR PHYSICISTS Understanding Noisy Systems Stochastic processes are an essential part of numerous branches of physics, as well as biology, chemistry, and finance. This textbook provides
More informationIntroductory Chemistry Essentials Nivaldo J. Tro Fourth Edition
Introductory Chemistry Essentials Nivaldo J. Tro Fourth Edition Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world Visit us on the World
More informationPart II. Pressure Measurements in the Range from 10 2 Pa to 10 8 Pa
Part II Pressure Measurements in the Range from 10 2 Pa to 10 8 Pa Introduction The pressure range 10 2-10 8 Pa has been selected as it is the interval covering the highest variety of interests and applications
More informationList of Principal Symbols
Symbol Quantity First appearance on page Upper-case characters A Vector of the cell boundary area between wall and fluid 23 in the calculation domain C Coordinate position of the cell centroid 23 C c Cunningham
More informationPhysical Chemistry of Surfaces
Physical Chemistry of Surfaces Fifth Edition ARTHUR W. ADAMSON Department of Chemistry, University of Southern California Los Angeles, California >) A WILEY-INTERSCIENCE PUBLICATION John Wiley &. Sons,
More informationFoundations of. Colloid Science SECOND EDITION. Robert J. Hunter. School of Chemistry University of Sydney OXPORD UNIVERSITY PRESS
Foundations of Colloid Science SECOND EDITION Robert J. Hunter School of Chemistry University of Sydney OXPORD UNIVERSITY PRESS CONTENTS 1 NATURE OF COLLOIDAL DISPERSIONS 1.1 Introduction 1 1.2 Technological
More informationCHARCOAL SORPTION STUDIES I. THE PORE DISTRIBUTION IN ACTIVATED CHARCOALS1
CHARCOAL SORPTION STUDIES I. THE PORE DISTRIBUTION IN ACTIVATED CHARCOALS1 BY H. L. MCDERMOT AND J. C. ARNEI-I. ABSTRACT The pore distributions of three activated charcoals have been calculated from the
More informationInvertebrate Biology A FUNCTIONAL APPROACH P. CALOW CROOM HELM LONDON A HALSTED PRESS BOOK JOHN WI LEY & SONS NEW YORK - TORONTO
INVERTEBRATE BIOLOGY Invertebrate Biology A FUNCTIONAL APPROACH P. CALOW CROOM HELM LONDON A HALSTED PRESS BOOK JOHN WI LEY & SONS NEW YORK - TORONTO 1981 P. Calow Croom Helm Ltd, 2-10 St John's Road,
More informationTHEORY OF PLASMAS TEORIYA PLAZMY. TEOPMH lljla3mbi
THEORY OF PLASMAS TEORIYA PLAZMY TEOPMH lljla3mbi The Lebedev Physics Institute Series Editors: Academicians D. V. Skobel'tsyn and N. G. Basov P. N. Lebedev Physics Institute, Academy of Sciences of the
More informationSIZE EXCLUSION CHROMATOGRAPHY
SIZE EXCLUSION CHROMATOGRAPHY Edited by B.J. HUNT Polymer Research Group Department of Chemistry University of Lancaster and S.R. HOLDING RAPRA Technology Ltd Shrewsbury Springer-Science+Business Media,
More informationADSORPTION IN MICROPOROUS MATERIALS: ANALYTICAL EQUATIONS FOR TYPE I ISOTHERMS AT HIGH PRESSURE
ADSORPTION IN MICROPOROUS MATERIALS: ANALYTICAL EQUATIONS FOR TYPE I ISOTHERMS AT HIGH PRESSURE A. L. MYERS Department of Chemical and Biomolecular Engineering University of Pennsylvania, Philadelphia
More informationThe Practice Book for Conceptual Physics. Paul G. Hewitt Eleventh Edition
The Practice Book for Conceptual Physics Paul G. Hewitt Eleventh Edition Pearson Education Limited Edinburgh Gate Harlow Essex CM20 2JE England and Associated Companies throughout the world Visit us on
More informationFLUID MECHANICS AND HEAT TRANSFER
AN INTRODUCTION TO FLUID MECHANICS AND HEAT TRANSFER AN INTRODUCTION TO FLUID MECHANICS AND HEAT TRANSFER WITH APPLICATIONS IN CHEMICAL & MECHANICAL PROCESS ENGINEERING BY J. M. KAY AND R. M. NEDDERMAN
More informationIgor Emri Arkady Voloshin. Statics. Learning from Engineering Examples
Statics Igor Emri Arkady Voloshin Statics Learning from Engineering Examples Igor Emri University of Ljubljana Ljubljana, Slovenia Arkady Voloshin Lehigh University Bethlehem, PA, USA ISBN 978-1-4939-2100-3
More informationCharacterisation of Porous Hydrogen Storage Materials: Carbons, Zeolites, MOFs and PIMs
Characterisation of Porous Hydrogen Storage Materials: Carbons, Zeolites, MOFs and PIMs Steven Tedds, a * Allan Walton, a Darren P. Broom, b and David Book a DOI:.39/c0fd00022a Electronic Supplementary
More informationNumerical Data Fitting in Dynamical Systems
Numerical Data Fitting in Dynamical Systems Applied Optimization Volume 77 Series Editors: Panos M. Pardalos University of Florida, U.S.A. Donald Hearn University of Florida, U.S.A. The titles published
More informationGraduate Texts in Mathematics 22
Graduate Texts in Mathematics 22 Managing Editors: P. R. Halmos C. C. Moore Donald W. Barnes lohn M. Mack An Aigebraic Introduction to Mathematical Logic Springer Science+Business Media, LLC Donald W.
More informationSTRESS IN ASME PRESSURE VESSELS, BOILERS, AND NUCLEAR COMPONENTS
STRESS IN ASME PRESSURE VESSELS, BOILERS, AND NUCLEAR COMPONENTS Wiley-ASME Press Series List Stress in ASME Pressure Vessels, Boilers, and Nuclear Jawad October 2017 Components Robust Adaptive Control
More informationINTERNATIONAL STANDARD
Provläsningsexemplar / Preview INTERNATIONAL STANDARD ISO 13317-3 First edition 2001-03-01 Determination of particle size distribution by gravitational liquid sedimentation methods Part 3: X-ray gravitational
More informationTHE BOUNDARY ELEMENT METHOD
THE BOUNDARY ELEMENT METHOD SOLID MECHANICS AND ITS APPLICATIONS Volume 27 Series Editor: G.M.L. GLADWELL Solid Mechanics Division, Faculty of Engineering University of Waterloo Waterloo, Ontario, Canada
More informationTRANSPORT PHENOMENA AND UNIT OPERATIONS
TRANSPORT PHENOMENA AND UNIT OPERATIONS TRANSPORT PHENOMENA AND UNIT OPERATIONS A COMBINED APPROACH Richard G. Griskey A JOHN WILEY & SONS, INC., PUBLICATION This book is printed on acid-free paper Copyright
More information