High H2 Adsorption by Coordination Framework Materials

Size: px
Start display at page:

Download "High H2 Adsorption by Coordination Framework Materials"

Transcription

1 Arianna Marchioro Florian Degueldre High H2 Adsorption by Coordination Framework Materials Xiang Lin, Junhua Jia, Xuebo Zhao, K. Mark Thomas, Alexender J. Black, Gavin S. Walker, Neil R. Champness, Peter Hubberstey, and Martin Schröder

2 The challenge of H 2 storage Even if enough hydrogen could be produce to use it as an energy source: Current technology: Store it in under high pressure; Store it under liquid form; HOW TO STORE IT? These solutions require a large consume of energy! Alternative option : storage by physical adsorption

3 Why physical adsorption? Chemical adsorption: Strong interaction chemical bond formation between the adsorbent and the adsorbate on the surface Irreversible Physical adsorption : Weak interaction resulting from Van der Waals forces Reversible Physical adsorption can be simply controlled by varying the pressure on porous materials

4 Porous materials Zeolites Aluminosilicates Often used as molecular sieves Carbon nanotubes : Actual capacity: 1% wt at room temperature and 4% at 77K Metal coordination frameworks: Crystalline nanoporous material Metal atoms at vertices of a lattice Organic linker molecules Periodic structure Have an exceptional surface area

5 Background on adsorption Adsorption isotherms: describe the equilibrium for adsorption at constant T Most frequently used isotherms: Langmuir used for chemisorption and high P physisorption Brunauer, Emmett, Teller (BET) used for physisorption Langmuir isotherm: For monolayer processes Relates the fraction of adsorbed molecules to the gas pressure of a medium above the solid surface Gives the number of max molecules absorbed on a specific surface

6 Background on adsorption (2) BET isotherm: For multilayer processes Also relates the number of adsorbed molecules on the surface to the pressure Find the specific surface in m 2 /g of the adsorbent Pore size can be obtained by sorption data by applying a Dubinin Astakhov analysis

7 Problem of the article Investigation of the correlation between pore size and gas adsorption behaviour, varying the pressure Three compounds are tested, changing pore size by varying the organic backbone length

8 Structure of coordination framework materials (1) Based on biphenyl, terphenyl and quaterphenyl tetracarboxylic acids

9 Structure of coordination framework materials (2) A solvothermal reaction of these compounds with Cu(NO 3 ) 2. 5/2 H 2 0 in acidic conditions gives the solvated structures

10 Characterisation (1) X Ray diffraction PLATON/SQUEEZE : estimate the contribution of solvent in X Ray diffraction PLATON/SOLV : estimate the percentage of pore volume in respect to the total volume Results : % 70.4% 75.5%

11 Characterisation (2) Powder X Ray diffraction Used to confirm the phase purity ; Stable in dry conditions. Loss of porosity and cristallinity in moisture. Thermal gravimetric analysis (TGA) Heat the crystal to remove solvent and weight to verify it

12 Characterisation (3) Goal : estimation of ratio Cu/L 1 3 have the same thermal behavior C : Blue green crystal becomes deep purpleblue loss of solvent From 120 C : No change in weight loss From 300 C : Degradation of materials

13 Characterisation (4) Dimensions of the pores for each compound Compound BET Area [m 2 g 1 ] Pore Volume* [cm 3 g 1 ] Pore Volume (N 2 ) [cm 3 g 1 ] Pore Size (N 2 ) [Å] Pore volume and pore size are determined from the N 2 sorption isotherms at 78K. The variation of the ligand length makes the estimation of the pore size difficult by cristallography*. We can see a form of linearity

14 H 2 sorption isotherm (1) Results for gravimetric sorption at 1 bar and 78 K wt% 2.52 wt% 2.24 wt% The smaller the pore are, the higher the H 2 sorption is. H 2 sorption shows good reversibility and an absence of hysteresis.

15 H 2 sorption isotherm (2) At low pressure region, the difference between 1 and 2 is greater.

16 Results at higher P (1) Compound 1: 4.02 wt% at 20 bar max estimated adsorption 4.20 wt% nearly saturated at 20 bar Compound 2: 6.06 wt% at 20 bar max estimated adsorption 6.70 wt% Due to larger pore volume and surface area (longer organic ligand)

17 Results at higher P (2) Compound 3: Longest organic ligand largest pore volume and surface area 6.07 wt%h 2 at 20 bar : comparable to compound 2 Larger max adsorption : 7.01 wt% H 2 Higher H 2 adsorption would be observed at P>20 bar but measurements have not been reported here

18 Pore size vs. maximum H 2 uptake Ratios of pore volumes for 1 3: From crystallography : 1:1.59:1.88 From N 2 calculations: 1:1.30:1.67 Max theoretical H 2 uptake: 1:1.60:1.67 From 1 to 2, proportional increase in max H 2 uptake is larger than in pore volume: Due to more optimal pore geometry in 2? From 2 to 3, proportional increase in max H 2 uptake is less than in pore volume: Lower affinity between H 2 molecules and the pores of 3

19 Pore size vs. density Density of liquid H 2 : g cm -3 at 20 K Calculated densities suggest that H 2 is highly compressed within the pores Contrasting trends: increasing max H 2 uptake with increasing pore size decreasing adsorbed H 2 density with increasing pore size There is an optimum pore size! Better adsorption in smaller pores at low P due to the overlap of the potential energy fields of the pore walls Better adsorption at higher P if larger pore volume

20 Volumetric storage Excellent gravimetric H 2 storage capacities Also highest volumetric storage capacities yet reported for coordination frameworks The value of 43.6 g L 1 for 2 is close to the 2010 U.S. Department of Energy target of 45 g L 1

21 Conclusion The sorption isotherms of 1 3 are reversible No evidence for chemisorption of H 2 H 2 adsorption is controlled by the available pore volume: Proportional decrease in adsorbate density with increasing pore size Increasing max H 2 uptake with increasing pore size Comprise between larger pore volume strength of the interaction In prospect: synthesizing new coordination frameworks for enhanced storage by searching for new metal building blocks by determining the optimum pore size by optimizing the framework topology

22 Remarks Advantages Experimental section : complete and allows to reproduce the experiment Desavantages Results sometimes not so well exposed : Tables are better than sentences Simple (understable) explainations Illustrations Interesting and challenging subject

Adsorption Processes. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad

Adsorption Processes. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Adsorption Processes Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Introduction Principles of adsorption Types of adsorption Definitions Brief history Adsorption isotherms Mechanism

More information

Ethers in a Porous Metal-Organic Framework

Ethers in a Porous Metal-Organic Framework Supporting Information Enhanced Isosteric Heat of H 2 Adsorption by Inclusion of Crown Ethers in a Porous Metal-Organic Framework Hye Jeong Park and Myunghyun Paik Suh* Department of Chemistry, Seoul National

More information

Electronic Supplementary Information. Materials

Electronic Supplementary Information. Materials Electronic Supplementary Information S1 Enhancement of H 2 Adsorption in Li + -Exchanged Co-ordination Framework Materials Sihai Yang, 1 Xiang Lin, 1 Alexander J. Blake, 1 K. Mark Thomas, 2 Peter Hubberstey,

More information

Specific Surface Area and Porosity Measurements of Aluminosilicate Adsorbents

Specific Surface Area and Porosity Measurements of Aluminosilicate Adsorbents ORIENTAL JOURNAL OF CHEMISTRY An International Open Free Access, Peer Reviewed Research Journal www.orientjchem.org ISSN: 0970-020 X CODEN: OJCHEG 2016, Vol. 32, No. (5): Pg. 2401-2406 Specific Surface

More information

Electronic Supplementary Information (ESI) Framework

Electronic Supplementary Information (ESI) Framework Electronic Supplementary Information (ESI) Exceptionally High H 2 Storage by a Metal Organic Polyhedral Framework Yong Yan, Xiang Lin, Sihai Yang, Alexander J. Blake, Anne Dailly, Neil R. Champness, Peter

More information

Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Science,

Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Science, Supporting information A rht type Metal-Organic Framework based on Small Cubicuboctahedron Supermolecular Building Blocks and Adsorption Properties Liangjun Li a,b, Sifu Tang a, Xiaoxia Lv a,b, Min Jiang

More information

Sustainable Hydrogen and Electrical Energy Storage 6. F.M. Mulder & M. Wagemaker

Sustainable Hydrogen and Electrical Energy Storage 6. F.M. Mulder & M. Wagemaker Sustainable Hydrogen and Electrical Energy Storage 6 F.M. Mulder & M. Wagemaker 1 Comparison liquid and gaseous H 2 with other liquid fuels Natural gas gasoline Volumetric energy density H 2 is lower than

More information

GAS-SURFACE INTERACTIONS

GAS-SURFACE INTERACTIONS Page 1 of 16 GAS-SURFACE INTERACTIONS In modern surface science, important technological processes often involve the adsorption of molecules in gaseous form onto a surface. We can treat this adsorption

More information

Characterisation of Microporous Materials by Finite Concentration Inverse Gas Chromatography

Characterisation of Microporous Materials by Finite Concentration Inverse Gas Chromatography Characterisation of Microporous Materials by Finite Concentration Inverse Gas Chromatography Surface Measurement Systems Ltd. Finite concentration IGC SEA is a useful tool for the investigation of surface

More information

Supporting Information

Supporting Information A Calcium Coordination Framework Having Permanent Porosity and High CO 2 /N 2 Selectivity Debasis Banerjee, a, * Zhijuan Zhang, b Anna M. Plonka, c Jing Li, b, * and John B. Parise a, c, d, * (a) Department

More information

Particle Size Determinations: Dynamic Light Scattering: page 161 text

Particle Size Determinations: Dynamic Light Scattering: page 161 text Particle Size Determinations: Dynamic Light Scattering: page 161 text Dynamic light scattering (also known as Photon Correlation Spectroscopy or Quasi- Elastic Light Scattering) is a technique which can

More information

Metal-Organic Frameworks and Porous Polymer Networks for Carbon Capture

Metal-Organic Frameworks and Porous Polymer Networks for Carbon Capture Carbon Capture Workshop, Tuesday, April 3 rd, Texas A&M, Qatar Metal-Organic Frameworks and Porous Polymer Networks for Carbon Capture J. P. Sculley, J.-R. Li, J. Park, W. Lu, and H.-C. Zhou Texas A&M

More information

BET Surface Area Analysis of Nanoparticles *

BET Surface Area Analysis of Nanoparticles * OpenStax-CNX module: m38278 1 BET Surface Area Analysis of Nanoparticles * Nina Hwang Andrew R. Barron This work is produced by OpenStax-CNX and licensed under the Creative Commons Attribution License

More information

Understanding Importance of Water Sorption Isotherm Shape, Hysteresis, and Models on Pharmaceutical Materials

Understanding Importance of Water Sorption Isotherm Shape, Hysteresis, and Models on Pharmaceutical Materials Understanding Importance of Water Sorption Isotherm Shape, Hysteresis, and Models on Pharmaceutical Materials Dr. Daniel J. Burnett Surface Measurement Systems, Ltd. Dburnett@surfacemeasurementsystems.com

More information

in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)]

in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)] Supporting Information Stepwise and Hysteretic Sorption N 2, O 2, CO 2, and H 2 Gases in a Porous Metal-Organic Framework [Zn 2 (BPnDC) 2 (bpy)] Hye Jeong Park and Myunghyun Paik Suh Contribution from

More information

Electronic Supplementary Information. Selective Sorption of Light Hydrocarbons on a Family of

Electronic Supplementary Information. Selective Sorption of Light Hydrocarbons on a Family of Electronic Supplementary Information Selective Sorption of Light Hydrocarbons on a Family of Metal-Organic Frameworks with different Imidazolate Pillars Hong-Ru Fu and Jian Zhang* State Key Laboratory

More information

A flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases. Supporting Information

A flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases. Supporting Information A flexible MMOF exhibiting high selectivity for CO 2 over N 2, CH 4 and other small gases Jingming Zhang, a Haohan Wu, a Thomas J. Emge, a and Jing Li* a a Department of Chemistry and Chemical Biology,

More information

Hydrogen Adsorption and Storage on Porous Materials. School of Chemical Engineering and Advanced Materials. Newcastle University United Kingdom

Hydrogen Adsorption and Storage on Porous Materials. School of Chemical Engineering and Advanced Materials. Newcastle University United Kingdom Hydrogen Adsorption and Storage on Porous Materials K. M. Thomas. School of Chemical Engineering and Advanced Materials H2FC SUPERGEN Conference Birmingham University, 16-18 th December 2013 Newcastle

More information

Electronic Supplementary Information. Pore with Gate: Modulating Hydrogen Storage in Metal Organic. Framework Materials via Cation Exchange

Electronic Supplementary Information. Pore with Gate: Modulating Hydrogen Storage in Metal Organic. Framework Materials via Cation Exchange Electronic Supplementary Information Pore with Gate: Modulating Hydrogen Storage in Metal Organic Framework Materials via Cation Exchange Sihai Yang, 1 Samantha K. Callear, 2 Timmy A. J. Ramirez-Cuesta,

More information

Nanoporous Sorbent and its Application for Hydrogen Storage at Ambient Temperature

Nanoporous Sorbent and its Application for Hydrogen Storage at Ambient Temperature Journal of Applied Chemical Research, 9, 3, 33-41 (2015) Journal of Applied Chemical Research www.jacr.kiau.ac.ir Synthesis and Characterization of Zn 3 Nanoporous Sorbent and its Application for Hydrogen

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 15 Supporting Information Co-MOF as sacrificial template: Manifesting new Co

More information

Synthesis and hydrogen-storage behavior of metal organic framework MOF-5

Synthesis and hydrogen-storage behavior of metal organic framework MOF-5 international journal of hydrogen energy 34 (2009) 1377 1382 Available at www.sciencedirect.com journal homepage: www.elsevier.com/locate/he Synthesis and hydrogen-storage behavior of metal organic framework

More information

Recap: Introduction 12/1/2015. EVE 402 Air Pollution Generation and Control. Adsorption

Recap: Introduction 12/1/2015. EVE 402 Air Pollution Generation and Control. Adsorption EVE 402 Air Pollution Generation and Control Chapter #6 Lectures Adsorption Recap: Solubility: the extent of absorption into the bulk liquid after the gas has diffused through the interface An internal

More information

Fundamentals of Physisorption

Fundamentals of Physisorption Chapter 2 14 Fundamentals of Physisorption 1. Background Early work into determining a universal equation of state for all gases led to the development of the ideal gas law: " = "# (1) This law, derived

More information

Lecture 5. Solid surface: Adsorption and Catalysis

Lecture 5. Solid surface: Adsorption and Catalysis Lecture 5 Solid surface: Adsorption and Catalysis Adsorbtion G = H T S DG ads should be negative (spontaneous process) DS ads is negative (reduced freedom) DH should be negative for adsorption processes

More information

Adsorption of gases on solids (focus on physisorption)

Adsorption of gases on solids (focus on physisorption) Adsorption of gases on solids (focus on physisorption) Adsorption Solid surfaces show strong affinity towards gas molecules that it comes in contact with and some amt of them are trapped on the surface

More information

ISO 9277 INTERNATIONAL STANDARD. Determination of the specific surface area of solids by gas adsorption BET method

ISO 9277 INTERNATIONAL STANDARD. Determination of the specific surface area of solids by gas adsorption BET method INTERNATIONAL STANDARD ISO 9277 Second edition 2010-09-01 Determination of the specific surface area of solids by gas adsorption BET method Détermination de l'aire massique (surface spécifique) des solides

More information

Supporting Information for the manuscript. Metastable interwoven mesoporous metal-organic frameworks

Supporting Information for the manuscript. Metastable interwoven mesoporous metal-organic frameworks S1 Supporting Information for the manuscript Metastable interwoven mesoporous metal-organic frameworks Yabing He, ab Zhiyong Guo, b Shengchang Xiang, c Zhangjing Zhang, c Wei Zhou, d,e Frank R. Fronczek,

More information

Supplementary Information. Supplementary Figure 1 Synthetic routes to the organic linker H 2 ATBDC.

Supplementary Information. Supplementary Figure 1 Synthetic routes to the organic linker H 2 ATBDC. Supplementary Information Supplementary Figure 1 Synthetic routes to the organic linker H 2 ATBDC. S1 Supplementary Figure 2 1 H NMR (D 2 O, 500MHz) spectrum of H 2 ATBDC. S2 Supplementary Figure 3 13

More information

Electronic Supporting information (ESI) for

Electronic Supporting information (ESI) for Electronic Supporting information (ESI) for Experimental assessment of physical upper limit for hydrogen storage capacity at 20 K in densified MIL-101 monoliths Hyunchul Oh a, Dan Lupu b, Gabriela Blanita

More information

Module 5: "Adsoption" Lecture 25: The Lecture Contains: Definition. Applications. How does Adsorption occur? Physisorption Chemisorption.

Module 5: Adsoption Lecture 25: The Lecture Contains: Definition. Applications. How does Adsorption occur? Physisorption Chemisorption. The Lecture Contains: Definition Applications How does Adsorption occur? Physisorption Chemisorption Energetics Adsorption Isotherms Different Adsorption Isotherms Langmuir Adsorption Isotherm file:///e

More information

Having a High Mg/Al Molar Ratio

Having a High Mg/Al Molar Ratio SUPPORTING INFORMATION High-Temperature CO 2 Sorption on Hydrotalcite Having a High Mg/Al Molar Ratio Suji Kim, Sang Goo Jeon, and Ki Bong Lee*, Department of Chemical and Biological Engineering, Korea

More information

High-Pressure Volumetric Analyzer

High-Pressure Volumetric Analyzer High-Pressure Volumetric Analyzer High-Pressure Volumetric Analysis HPVA II Benefits Dual free-space measurement for accurate isotherm data Free space can be measured or entered Correction for non-ideality

More information

A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties

A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Supporting information for A Third Generation Breathing MOF with Selective, Stepwise, Reversible and Hysteretic Adsorption properties Suresh Sanda, Srinivasulu Parshamoni and SanjitKonar* Department of

More information

Powder Surface Area and Porosity

Powder Surface Area and Porosity Powder Surface Area and Porosity Powder Technology Series Edited by B. Scarlett Department of Chemical Engineering University of Technology Loughborough Powder Surface Area and Porosity S. Lowell PhD Quantachrome

More information

Storage of Hydrogen, Methane and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications

Storage of Hydrogen, Methane and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications Storage of Hydrogen, Methane and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications (Supporting Information: 33 pages) Hiroyasu Furukawa and Omar M. Yaghi Center

More information

Simultaneously High Gravimetric and Volumetric Gas Uptake Characteristics of the Metal Organic Framework NU-111

Simultaneously High Gravimetric and Volumetric Gas Uptake Characteristics of the Metal Organic Framework NU-111 Simultaneously High Gravimetric and Volumetric Gas Uptake Characteristics of the Metal Organic Framework NU-111 Yang Peng, a,b Gadipelli Srinivas a,b, Christopher E. Wilmer, c Ibrahim Eryazici, d Randall

More information

DMOF-1 as a Representative MOF for SO 2 Adsorption in both Humid and Dry Conditions

DMOF-1 as a Representative MOF for SO 2 Adsorption in both Humid and Dry Conditions DMOF-1 as a Representative MOF for SO 2 Adsorption in both Humid and Dry Conditions Julian Hungerford, Souryadeep Bhattacharyya, Uma Tumuluri, Sankar Nair, Zili Wu, and Krista S. Walton* School of Chemical

More information

CHARACTERIZATION OF 3A MOLECULAR SIEVE USING TRISTAR MICROMERITICS DEVICE

CHARACTERIZATION OF 3A MOLECULAR SIEVE USING TRISTAR MICROMERITICS DEVICE CHARACTERIZATION OF 3A MOLECULAR SIEVE USING TRISTAR MICROMERITICS DEVICE Sh. Azarfar 1i, S. Mirian 2, H. Anisi 3, R. Soleymani 4, S. Sadighi 5 1i, 4 Research & Development division, Nitelpars.Co (Fateh

More information

IEA-HIA Task 32 Hydrogen-based Energy Storage Hydrogen storage in porous materials

IEA-HIA Task 32 Hydrogen-based Energy Storage Hydrogen storage in porous materials IEA-HIA Task 32 Hydrogen-based Energy Storage Hydrogen storage in porous materials Michael Hirscher Max Planck Institute for Intelligent Systems Stuttgart, Germany MH2018 November 1, 2018 Outline IEA Hydrogen

More information

the multiple helices

the multiple helices Supporting Information A 3D porous metal-organic framework containing nanotubes based on the multiple helices Lei Hou,* Li-Na Jia, Wen-Juan Shi, Li-Yun Du, Jiang Li, Yao-Yu Wang* and Qi-Zhen Shi Key Laboratory

More information

Concepts in Surface Physics

Concepts in Surface Physics M.-C. Desjonqueres D. Spanjaard Concepts in Surface Physics Second Edition With 257 Figures Springer 1. Introduction................................. 1 2. Thermodynamical and Statistical Properties of

More information

Hydrogen adsorption by graphite intercalation compounds

Hydrogen adsorption by graphite intercalation compounds 62 Chapter 4 Hydrogen adsorption by graphite intercalation compounds 4.1 Introduction Understanding the thermodynamics of H 2 adsorption in chemically modified carbons remains an important area of fundamental

More information

S BET vs. S DFT. Supporting Information

S BET vs. S DFT. Supporting Information Supporting Information Naturally Nitrogen and Calcium-doped Nanoporous Carbon Derived from Pine Cone with Superior CO 2 Capture Capacities Bingjun Zhu, Congxiao Shang and Zhengxiao Guo S BET vs. S DFT

More information

THEORETICAL INVESTIGATIONS ON NANOPOROUS MATERIALS AND IONIC LIQUIDS FOR ENERGY STORAGE

THEORETICAL INVESTIGATIONS ON NANOPOROUS MATERIALS AND IONIC LIQUIDS FOR ENERGY STORAGE 1 THEORETICAL INVESTIGATIONS ON NANOPOROUS MATERIALS AND IONIC LIQUIDS FOR ENERGY STORAGE A Dissertation by MOUSUMI MANI BISWAS Submitted to the Office of Graduate Studies of Texas A&M University in partial

More information

Supporting Information

Supporting Information Supporting Information Aqueous, screen-printable paste for fabrication of mesoporous composite anatase-rutile TiO 2 nanoparticle thin films for (photo)electrochemical devices Amrita Yasin, Fuqiang Guo,

More information

Supporting Information

Supporting Information Supporting Information Highly Selective Carbon Dioxide Sorption in an Organic Molecular Porous Material Hyunuk Kim, Yonghwi Kim, Minyoung Yoon, Soyoung Lim, Se Min Park, Gon Seo, Kimoon Kim*, National

More information

EXECUTIVE SUMMARY. especially in last 50 years. Industries, especially power industry, are the large anthropogenic

EXECUTIVE SUMMARY. especially in last 50 years. Industries, especially power industry, are the large anthropogenic EXECUTIVE SUMMARY Introduction The concentration of CO 2 in atmosphere has increased considerably in last 100 years, especially in last 50 years. Industries, especially power industry, are the large anthropogenic

More information

SYNTHESIS AND CHARACTERIZATION OF NITROGEN-CONTAINING MICROPOROUS CARBON WITH A THREE-DIMENSIONAL NANO-ARRAY STRUCTURE

SYNTHESIS AND CHARACTERIZATION OF NITROGEN-CONTAINING MICROPOROUS CARBON WITH A THREE-DIMENSIONAL NANO-ARRAY STRUCTURE SYNTHESIS AND CHARACTERIZATION OF NITROGEN-CONTAINING MICROPOROUS CARBON WITH A THREE-DIMENSIONAL NANO-ARRAY STRUCTURE Peng-Xiang Hou 1, Takashi Kyotani 1, Koich Matsuoka 1, Akira Tomita 1, Norihiko Setoyama

More information

Supplementary Information

Supplementary Information Supplementary Information Co-doping of MOF-5 framework and its effect on gas adsorption behaviour J.A. Botas a,*, G. Calleja a, M. Sánchez-Sánchez,b, M.G. Orcajo a a Department of Chemical and Energy Technology,

More information

Microporous Carbon adsorbents with high CO 2 capacities for industrial applications

Microporous Carbon adsorbents with high CO 2 capacities for industrial applications Microporous Carbon adsorbents with high CO 2 capacities for industrial applications Santiago Builes, a,b Thomas Roussel,* b Camelia Matei Ghimbeu, c Julien Parmentier, c Roger Gadiou, c Cathie Vix-Guterl

More information

Characterization of Solid State Drugs by Calorimetry

Characterization of Solid State Drugs by Calorimetry Characterization of Solid State Drugs by Calorimetry Christin T. Choma TA Instruments, 109 Lukens Drive, New Castle, DE 19720, USA Drug product development and manufacture requires numerous studies to

More information

m WILEY- ADSORBENTS: FUNDAMENTALS AND APPLICATIONS Ralph T. Yang Dwight F. Benton Professor of Chemical Engineering University of Michigan

m WILEY- ADSORBENTS: FUNDAMENTALS AND APPLICATIONS Ralph T. Yang Dwight F. Benton Professor of Chemical Engineering University of Michigan ADSORBENTS: FUNDAMENTALS AND APPLICATIONS Ralph T. Yang Dwight F. Benton Professor of Chemical Engineering University of Michigan m WILEY- INTERSCIENCE A JOHN WILEY & SONS, INC., PUBLICATION Preface xi

More information

Gas content evaluation in unconventional reservoir

Gas content evaluation in unconventional reservoir Gas content evaluation in unconventional reservoir Priyank Srivastava Unconventional reservoirs 1 Average monthly prod. (mscf) The Problem Gas in-place calculation Prediction of production decline Total

More information

Adsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different Proportions

Adsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different Proportions 2015 2 nd International Conference on Material Engineering and Application (ICMEA 2015) ISBN: 978-1-60595-323-6 Adsorption of Methylene Blue on Mesoporous SBA 15 in Ethanol water Solution with Different

More information

GRAVIMETRIC ANALYSIS

GRAVIMETRIC ANALYSIS GRAVIMETRIC ANALYSIS Gravimetric methods are quantitative methods in which the mass of the analyte or some compound that is chemically related to the analyte is determined. What are the steps in a gravimetric

More information

A new tetrazolate zeolite-like framework for highly selective CO 2 /CH 4 and CO 2 /N 2 separation

A new tetrazolate zeolite-like framework for highly selective CO 2 /CH 4 and CO 2 /N 2 separation Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Material (ESI) for ChemComm. Supporting Information A new tetrazolate

More information

Adsorptive separation of methanol-acetone on isostructural series of. metal-organic frameworks M-BTC (M = Ti, Fe, Cu, Co, Ru, Mo): A

Adsorptive separation of methanol-acetone on isostructural series of. metal-organic frameworks M-BTC (M = Ti, Fe, Cu, Co, Ru, Mo): A Supporting information Adsorptive separation of methanol-acetone on isostructural series of metal-organic frameworks M-BTC (M = Ti, Fe, Cu, Co, Ru, Mo): A computational study of adsorption mechanisms and

More information

Metal-Organic Frameworks for Adsorbed Natural Gas Fuel Systems. Hong-Cai Joe Zhou Department of Chemistry Texas A&M University

Metal-Organic Frameworks for Adsorbed Natural Gas Fuel Systems. Hong-Cai Joe Zhou Department of Chemistry Texas A&M University Metal-Organic Frameworks for Adsorbed Natural Gas Fuel Systems Hong-Cai Joe Zhou Department of Chemistry Texas A&M University 2 US primary energy consumption by fuel, 1980-2035 (quadrillion Btu per year)

More information

1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification.

1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification. 1. Materials All chemicals and solvents were purchased from Sigma Aldrich or SAMCHUN and used without further purification. 2. Experimental procedures Benzo[1,2-c:3,4-c':5,6-c'']trifuran, 1: The synthesis

More information

Supporting Information

Supporting Information Supporting Information Hydrogen Storage in the Dehydrated Prussian Blue Analogues M 3 [Co(CN) 6 ] 2 (M = Mn, Fe, Co, Ni, Cu, Zn) Steven S. Kaye and Jeffrey R. Long* Dept. of Chemistry, University of California,

More information

Materi Pengayaan Polimer Koordinasi

Materi Pengayaan Polimer Koordinasi Materi Pengayaan Polimer Koordinasi Coordination Polymers; Design, Analysis and Application Stuart R. Batten, Suzanne M. Neville and David R. Turner Coordination polymers are infinite repeating structures

More information

Adsorption Equilibrium and Kinetics of H 2 O on Zeolite 13X

Adsorption Equilibrium and Kinetics of H 2 O on Zeolite 13X Korean J. Chem. Eng., 8(4), 55-530 (00) Adsorption Equilibrium and Kinetics of H O on Zeolite 3X Young Ki Ryu*, Seung Ju Lee, Jong Wha Kim and Chang-Ha Lee *External Relations Department, Procter & Gamble

More information

Modelling hydrogen adsorption within spherical, cylindrical and slit-shaped cavities

Modelling hydrogen adsorption within spherical, cylindrical and slit-shaped cavities University of Wollongong Research Online Faculty of Informatics - Papers (Archive) Faculty of Engineering and Information Sciences 2009 Modelling hydrogen adsorption within spherical, cylindrical and slit-shaped

More information

Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks

Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks Supporting Information Cooperative Template-Directed Assembly of Mesoporous Metal-Organic Frameworks Lin-Bing Sun, Jian-Rong Li, Jinhee Park, and Hong-Cai Zhou* Department of Chemistry, Texas A&M University,

More information

IV.D.2 Hydrogen Storage Materials for Fuel Cell-Powered Vehicles

IV.D.2 Hydrogen Storage Materials for Fuel Cell-Powered Vehicles IV.D.2 Hydrogen Storage Materials for Fuel Cell-Powered Vehicles Andrew Goudy Delaware State University 2 N. Dupont Highway Dover, DE 99 Phone: (32) 857-6534 Email: agoudy@desu.edu DOE Managers Ned Stetson

More information

SOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS

SOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS SOPHISTICATED DESIGN, INTUITIVE OPERATION, RESEARCH-GRADE RESULTS ASAP 2020 Plus: Accelerated Surface Area and Porosimetry System The Micromeritics ASAP 2020 Plus integrates a variety of automated gas

More information

Thomas Roussel, Roland J.-M. Pellenq, Christophe Bichara. CRMC-N CNRS, Campus de Luminy, Marseille, cedex 09, France. Abstract.

Thomas Roussel, Roland J.-M. Pellenq, Christophe Bichara. CRMC-N CNRS, Campus de Luminy, Marseille, cedex 09, France. Abstract. A GRAND CANONICAL MONTE-CARLO STUDY OF H ADSORPTION IN PRISTINE AND Li-DOPED CARBON REPLICAS OF FAUJASITE ZEOLITE Thomas Roussel, Roland J.-M. Pellenq, Christophe Bichara CRMC-N CNRS, Campus de Luminy,

More information

A vanadium(iv) pyrazolate metal organic polyhedron with permanent porosity and adsorption selectivity

A vanadium(iv) pyrazolate metal organic polyhedron with permanent porosity and adsorption selectivity Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Electronic supporting Information A vanadium(iv) pyrazolate metal organic polyhedron with permanent

More information

Adsorption Asmaa Shankar

Adsorption Asmaa Shankar Volume 1, Issue 1, January 2013, Online: Adsorption Asmaa Shankar ABSTRACT This electronic document is a live template. The various components of your paper [title, text, heads, etc.] are already defined

More information

ADSORPTION. Briefly, adsorption is the surface accumulation of material.

ADSORPTION. Briefly, adsorption is the surface accumulation of material. ADSORPTION Briefly, adsorption is the surface accumulation of material. Adsorption is a unit operation in which dissolved constituents are removed from the solvent (water) by transfer to the surfaces of

More information

Multilayer Adsorption Equations. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad

Multilayer Adsorption Equations. Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Multilayer Adsorption Equations Ali Ahmadpour Chemical Eng. Dept. Ferdowsi University of Mashhad Contents Empirical isotherm equations BET Surface area determination Limitation Measurement method BDDT

More information

Complex Compounds Background of Complex Compound Technology

Complex Compounds Background of Complex Compound Technology Complex Compounds For more than 20 years, Rocky Research has been a pioneer in the field of sorption refrigeration utilizing complex compounds. Our technology earned special recognition from NASA in 1999.

More information

SUPPLEMENTARY INFORMATION

SUPPLEMENTARY INFORMATION doi:10.1038/nature14327 Supplementary Text Structure solution and Rietveld refinement of mmen-mn 2 (dobpdc) Initially, the previously reported crystal structure of the isostructural Zn 2 (dobpdc) 13, with

More information

Effect of temperature and humidity on vegetable grade magnesium stearate

Effect of temperature and humidity on vegetable grade magnesium stearate Powder Technology 147 (2004) 79 85 www.elsevier.com/locate/powtec Effect of temperature and humidity on vegetable grade magnesium stearate Mikko Koivisto a, *, Hannu Jalonen b, Vesa-Pekka Lehto a a Department

More information

Hollowing Out MOFs: Hierarchical Micro- and Mesoporous MOFs with Tailorable Porosity via Selective Acid Etching

Hollowing Out MOFs: Hierarchical Micro- and Mesoporous MOFs with Tailorable Porosity via Selective Acid Etching Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Supporting Information Hollowing Out MOFs: Hierarchical Micro- and Mesoporous MOFs with

More information

High-Connected Mesoporous Metal Organic Framework

High-Connected Mesoporous Metal Organic Framework Supporting Information High-Connected Mesoporous Metal Organic Framework Xiaojun Gu, a Zhang-Hui Lu a,b and Qiang Xu* a,b a National Institute of Advanced Industrial Science and Technology (AIST), Ikeda,

More information

Supporting Information. Table of Contents

Supporting Information. Table of Contents Supporting Information Polyamine-Cladded 18-Ring-Channel Gallium Phosphites with High-Capacity Hydrogen Adsorption and Carbon Dioxide Capture Ming-Jhe Sie, 1 Chia-Her Lin, 2, * and Sue-Lein Wang, 1, *

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) Enhancing stability and porosity of penetrated

More information

Supporting Information

Supporting Information Supporting Information 1 Selective CO 2 Uptake and Inverse CO 2 /C 2 H 2 Selectivity in a Dynamic Bi-Functional Metal-Organic Framework Wenbin Yang a Andrew J. Davies, a Xiang Lin, a Mikhail Suyetin, a

More information

Synthesis of nano-sized anatase TiO 2 with reactive {001} facets using lamellar protonated titanate as precursor

Synthesis of nano-sized anatase TiO 2 with reactive {001} facets using lamellar protonated titanate as precursor Supporting Information Synthesis of nano-sized anatase TiO 2 with reactive {001} facets using lamellar protonated titanate as precursor Liuan Gu, Jingyu Wang *, Hao Cheng, Yunchen Du and Xijiang Han* Department

More information

Interpretation of Full Sorption-Desorption Isotherms as a Tool for Understanding Concrete Pore Structure

Interpretation of Full Sorption-Desorption Isotherms as a Tool for Understanding Concrete Pore Structure Interpretation of Full Sorption-Desorption Isotherms as a Tool for Understanding Concrete Pore Structure The MIT Faculty has made this article openly available. Please share how this access benefits you.

More information

Separation Benzene and Toluene from BTX using Zeolite 13X

Separation Benzene and Toluene from BTX using Zeolite 13X Iraqi Journal of Chemical and Petroleum Engineering Iraqi Journal of Chemical and Petroleum Engineering Vol.9 No.3 (September 27) 7-24 ISSN: 997-4884 University of Baghdad College of Engineering Separation

More information

Electronic Supplementary Information (ESI)

Electronic Supplementary Information (ESI) Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) A photoluminescent covalent

More information

PREPARATION OF ACTIVATED CARBON FROM PULP AND PAPER MILL WASTES TO BE TESTED FOR THE ADSORPTION OF VOCS

PREPARATION OF ACTIVATED CARBON FROM PULP AND PAPER MILL WASTES TO BE TESTED FOR THE ADSORPTION OF VOCS PREPARATION OF ACTIVATED CARBON FROM PULP AND PAPER MILL WASTES TO BE TESTED FOR THE ADSORPTION OF VOCS A. GREGÓRIO *, A. GARCIA-GARCIA #, D. BOAVIDA *, I. GULYURTLU * AND I. CABRITA * * Department of

More information

Supporting Information

Supporting Information Supporting Information Highly selective carbon dioxide adsorption in a water-stable Indium-organic framework material Jin-Jie Qian, a,bi Fei-Long Jiang, a Da-Qiang Yuan, a Ming-Yan Wu, a Shu-Quan Zhang,

More information

Adsorption (Ch 12) - mass transfer to an interface

Adsorption (Ch 12) - mass transfer to an interface Adsorption (Ch 12) - mass transfer to an interface (Absorption - mass transfer to another phase) Gas or liquid adsorption (molecular) onto solid surface Porous solids provide high surface area per weight

More information

Automated multi-vapor gravimetric sorption analyzer for advanced research applications

Automated multi-vapor gravimetric sorption analyzer for advanced research applications Automated multi-vapor gravimetric sorption analyzer for advanced research applications Automated multi-vapor gravimetric sorption analyzer for advanced research applications Key benefits of the DVS Advantage

More information

CHARACTERIZATION OF FLUID-ROCK INTERACTION BY ADSORPTION CALORIMETRY

CHARACTERIZATION OF FLUID-ROCK INTERACTION BY ADSORPTION CALORIMETRY SCA2018_053 1/8 CHARACTERIZATION OF FLUID-ROCK INTERACTION BY ADSORPTION CALORIMETRY D. Korobkov 1, V. Pletneva 1, E. Dyshlyuk 2 1 Schlumberger, Moscow Research Center and 2 Dahran Carbonate Research Center

More information

High capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework

High capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework High capacity hydrogen and nitric oxide adsorption and storage in a metal-organic framework Bo Xiao, 1 Paul S. Wheatley, 1 Xuebo Zhao, Ashleigh J. Fletcher, Sarah Fox Adriano G Rossi, Ian L. Megson, 3

More information

Adsorption Characteristics of Water and Silica. Gel System for Desalination Cycle. Oscar Rodrigo Fonseca Cevallos

Adsorption Characteristics of Water and Silica. Gel System for Desalination Cycle. Oscar Rodrigo Fonseca Cevallos Adsorption Characteristics of Water and Silica Gel System for Desalination Cycle Thesis by Oscar Rodrigo Fonseca Cevallos In Partial Fulfillment of the Requirements For the Degree of Master of Science

More information

Efficient removal of typical dye and Cr(VI) reduction using N-doped

Efficient removal of typical dye and Cr(VI) reduction using N-doped Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Efficient removal of typical dye and Cr(VI) reduction using N-doped magnetic porous carbon

More information

Electronic Supplementary Information

Electronic Supplementary Information Electronic Supplementary Information The directing effect of linking unit on building microporous architecture in tetraphenyladmantane-based poly(schiffbase) networks Guiyang Li, Biao Zhang, Jun Yan and

More information

Supporting Information. A novel microporous metal-organic framework exhibiting high acetylene and methane storage capacities

Supporting Information. A novel microporous metal-organic framework exhibiting high acetylene and methane storage capacities Supporting Information A novel microporous metal-organic framework exhibiting high acetylene and methane storage capacities Xing Duan, a Chuande Wu, b Shengchang Xiang, c Wei Zhou, de Taner Yildirim, df

More information

Electronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented

Electronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented Electronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented stable microporous metal-imidazolate framework Shui-Sheng Chen, a,c Min Chen, a Satoshi Takamizawa,

More information

Preparation of biomass derived porous carbon: Application for methane energy storage

Preparation of biomass derived porous carbon: Application for methane energy storage Edith Cowan University Research Online ECU Publications Post 013 016 Preparation of biomass derived porous carbon: Application for methane energy storage Yong Sun Edith Cowan University, y.sun@ecu.edu.au

More information

Selected Applications of Metal-Organic Frameworks in Sustainable Energy Technologies

Selected Applications of Metal-Organic Frameworks in Sustainable Energy Technologies Page 1 of 8 Page 1 of 8 Return to Web Version Selected Applications of Metal-Organic Frameworks in Sustainable Energy Technologies By: Stephen R. Caskey, Adam J. Matzger, Material Matters 2009, 4.4, 111.

More information

Lab. Standard Methods

Lab. Standard Methods Lab Standard Methods Quantachrome Instruments LabQMC 1900 Corporate Drive, Boynton Beach, FL 33426. 561.731.4999 Fax: 561.732.9888 www.labqmc.quantachrome.com lab.qt@anton-paar.com Standard Methods Technical

More information

ISO 9277 INTERNATIONAL STANDARD. Determination of the specific surface area of solids by gas adsorption BET method

ISO 9277 INTERNATIONAL STANDARD. Determination of the specific surface area of solids by gas adsorption BET method INTERNATIONAL STANDARD ISO 9277 Second edition 2010-09-01 Determination of the specific surface area of solids by gas adsorption BET method Détermination de l'aire massique (surface spécifique) des solides

More information

ADSORPTION ON SURFACES. Kinetics of small molecule binding to solid surfaces

ADSORPTION ON SURFACES. Kinetics of small molecule binding to solid surfaces ADSORPTION ON SURFACES Kinetics of small molecule binding to solid surfaces When the reactants arrive at the catalyst surface, reactions are accelerated Physisorption and Chemisorption 1- diffusion to

More information