Collegiate Institute for Math and Science. AP Chemistry Summer Assignment 2017 Name:

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1 Summer Assignment 2017 Name: I am so excited to have you in next year s class! You have shown the willingness, care, and time necessary to be successful next year and get a 5 on the May 2018 AP exam! First off, you should send me an with a short introduction of yourself, what you are interested in pursuing after high school, what classes you have liked and why, and how you learn best. You can also share any other details you d like (any difficulties, personal circumstances, favorite color, etc.) Due by August 1 st. My for the summer will be ethelkhanis@gmail.com. Second, please get familiar with the class website: cimschemistry.weebly.com This needs to become your best friend, your sweartomytims confidant, and lifeline. If you lose the summer assignment, you will find it here. There are THREE parts to the Summer Assignment. All three parts are due on the first day of class in September NO EXCEPTIONS. Part 1 asks you to use your investigative skills to find the answers to a set of questions. Part 2 deals with the memorization of common ions essential for this course. Part 3 provides information and practice on the use of significant figure rules in calculations. Part 1: Chemistry Basics Utilize Internet Resources to complete the following problems. The URLs below represent a fraction of the available chemistry addresses available. Please feel free to expand the list and find other web sites that help prepare you for the coming year. I recommend that you complete as many online quizzes as possible, take detailed notes, and practice the items indicated in the packet. The goal of this assignment is to give you a basic introduction/review to things that should be in your Chemistry toolkit when we start. Let me know if there are any problems in submitting the assignment on time. Any basic chemistry textbook can help you find the information needed to complete the summer assignment please see my website for details. General Chemistry Sites: Quizzes (multiple choice and free response): Study Cards:

2 Part 1 Name: Part A 1. Write the most common guidelines to determine significant figures (digits) with an example. (Use Part C to help you) 2. Use factor labeling method to convert the following: a. 515 m = _ miles. b. 200 in = meters c. 325 days = seconds. d. 20 gallons = ml e. 3 meters into centimeters f. 10 kilometers into meters g. 15,050 milligrams into grams h. 3,264 milliliters into liters I. 9,674,444 grams into kilograms 3. Classify each of the following as units of mass, volume, length, density, energy, or pressure. a. mg b. ml c. cm 3 d. mm e. kg/m 3 f. kj g. atm h. cal. 4. Most laboratory experiments are performed at room temperature at 25 C. Express this temperature in: a. F b. K 5. How many significant figures are in each of the following? a mm b kj c x10 23 atoms d L e cm 3 f. 100 g h i Record the following in correct scientific notation: a) 350,000,000 cal b) mol c) Ǻ d) 765,400,000,000 atoms 7. Calculate the following to the correct number of significant figures. a g / cm 3

3 b g / 1.01 L c g g d g g e. 2.1 x 3.21 f x 120 g Give the chemical symbols for the following elements: a. Carbon b. sulfur c. Titanium d. Nitrogen e. Helium 9. Write the Latin and Common names for each of the elements symbols: a. Na b. Au c. Ag d. Sn e. Fe f. Hg g. K 10. A solid white substance A is heated strongly in the absence of air. It decomposes to form a new white substance B and a gas C. The gas has exactly the same properties as the product obtained when carbon is burned in an excess of oxygen. Based on these observations, can we determine whether solids A and B and the gas C are elements or compounds? Explain your conclusions for each substance. 11. Label each of the following as either a physical process or a chemical process. a. Corrosion of aluminum metal. b. Melting of ice. c. Pulverizing an aspirin. d. Digesting a candy bar. e. Explosion of nitroglycerin. f. Milk turning sour. g. Burning of paper. h. Forming of frost on a cold night. i. Bleaching of hair with hydrogen peroxide. j. A copper wire is hammered flat. Part B 12. Calculate the mass of O2 produced if 2.50 g KClO3 are completely decomposed by heating. 13. Write the formula of the following compounds? (Use criss cross method) a. Calcium sulfate. b. Ammonium Phosphate c. Lithium Nitrite d. potassium perchlorate. e. Barium Oxide f. Zinc sulfide. 14. Convert 3.57 atm to: (Using factorlabeling method) a. mm Hg b. pascals 15. Define the words: atomic number, atomic mass, mass number, molecular formula, structural formula, empirical formula, isotopes, cation, anion, metalloid, allotrope, stoichiometry. 16. White gold is an alloy that typically contains 60.0% by mass gold and the remainder is platinum. If 175 g of gold are available, how many grams of platinum are required to combine with the gold to form this alloy?

4 17. What is the empirical formula of a compound that contains 53.73% Fe and 46.27% of S? 18. Determine the number of molecules in 2.23 mol of nitrogen (N2) molecules. 19. List the following has diatomic molecule, Molecular compound, Ionic compound, Atomic element. a. F2 b. Cl2 c. C d. NaCl e. KF f. CO2 g. H2 h. Ag i. Rust (Fe2O3) j. MgO k. O2 l. I2 20. State the contribution of the following chemist in one line. a. Democritus b. Mendeleev c. Henry Becquerel d. Roentgen e. J. J Thompson f. Faraday g. Chadwick h. Millikan i. Proust j. Cavendish k. Madam Curie 21. What is the difference between a. Chlorine atom and Chloride ion b. b. Sodium atom and sodium ion 22. How many grams of nitrogen are present in 2.3 moles of nitrogen gas? 23. Calculate the mass in grams of each of the following: a x atoms of Mg. b x Formula units of CaCl How do you distinguish: a. An element from a compound. b. An element from a mixture. c. A true solution from a heterogeneous mixture. d. Distillation from filtration. 25. An extensive property is one that depends on the amount of the sample. Which of the following Properties are extensive? a. volume b. density c. temperature d. energy e. melting point. 26. Define Acid, base and salt? Give some examples of each. 27. What is the difference between the BronstedLowry, Lewis and Arrhenius definition of a base? An Acid? Part C 28. What mass of copper is required to replace silver from 4.00g of silver nitrate dissolved in water? Cu(s) + AgNO3 Cu(NO3)2 + Ag. 29. Write the chemical formulas for the following compounds: a. Calcium Carbonate b. Ammonium Phosphate c. Sodium Chloride d. Sodium Oxide e. Calcium Sulfate f. Sodium Nitrite g. Magnesium Acetate h. Potassium cyanide i. Zinc (II) Nitrate j. Iron (III) Phosphate k. Nickel (II) Fluoride 30. Define a. Law of conservation of mass. b. Law of multiple proportion. 31. An isotope of Iodine used in thyroid disorders is a. Protons are in its nucleus? b. Neutrons are in its nucleus? I has how many

5 c. Electrons are in an Iodine atom? d. Neutrons and protons are in the I 1 formed from this isotope? 32. Mercury has an atomic mass of amu. Calculate the a. Mass of 3.0 x atoms. b. Number of atoms in one nanogram of Mercury. 33. Calculate the molar masses ( g/ mol) of a. Ammonia ( NH3) b. Baking soda ( NaHCO3)) c. Osmium Metal (Os) 34. Convert the following to moles a grams of Carbon dioxide. b. 6.0 x 10 g of Hydrazine (N 2H4), a rocket propellant. 35. The molecular formula of morphine, a painkilling narcotic, is C17H19NO3. a. What is the molar mass? b. What fraction of atoms in morphine is accounted for by carbon? c. Which element contributes least to the molar mass? 36. Complete the list ionic compounds ( name or formula) a. Cupric Hydroxide b. Strontium Chromate c. Ammonium Perchlorate d. NaHCO3 e. Fe2(CO3)3 f. Sodium Hydroxide. g. Potassium Chloride. 37. Determine the formula mass for the following: a. N2O5 b. CuSO4 C. Ca(HCO3)2 d. CaSO4. 2 H2O 38. Calculate the percentage by mass of the following compounds: a. SO3 b. CH3COOCH3 c. Ammonium Nitrate. 39. Determine the empirical formula of the compounds with the following compositions by mass: a % C, 27. 8% S, % Cl b % C, 9.6 % O, and 68.7 % F Part D 40. Write balanced chemical equations for the reactions of sodium with the following nonmetals to form ionic solids. a. Nitrogen b. Oxygen c. Sulfur d. Bromine 41. Write a balanced equation for the following: a. Reaction of boron trifluoride gas with water to give liquid hydrogen fluoride and solid boric acid, (H3BO3). b. Reaction of magnesium Oxide with Iron to form Iron (III) Oxide and Magnesium. c. The decomposition of dinitrogen Oxide gas to its elements. d. The reaction of Calcium Carbide solid with water to form calcium hydroxide and acetylene (C2H2) gas.

6 e. The reaction of solid calcium cyan amide (CaCN2) with water to from calcium carbonate and ammonia gas. f. Ethane burns in air (Oxygen). g. Hydrogen reacts with oxygen to from Water. h. Nitrogen gas reacts with Hydrogen to form Ammonia. i. Hydrogen reacts with Iodine gas to form Hydrogen Iodide. j. Sodium reacts with Iodine gas to form Sodium Iodide. k. Sodium Oxide reacts with water to form sodium hydroxide and hydrogen. l. Carbon dioxide combines with water to form carbonic acid. m. Magnesium and nitrogen gas combine to form magnesium nitride. n. Conc. Hydrochloric acid reacts with Conc. Sodium hydroxide to form sodium chloride and water. 42. Define limiting reagent, theoretical yield, and actual yield. 43 Define the following terms: a. Electrochemistry b. Electrolysis c. Voltaic Cell 44. Name the five different types of chemical reaction and their general formulas. 45. Define solubility. Prepare a list of solubility rules for ionic compounds in water. (online resources) (IMPORTANT) 46. Name the following: a. CO2 b. P4S10 c. NI3 d. PCl5 e. CCl4 f. SF6 g. CH4 h. C2H6 i. C3H8 47. Define Oxidation number. Find the Oxidation number of a. Carbon in CO2. b. Sulfur in H2SO4. c. Phosphorus in PO43 d. Manganese in MnO Define strong electrolyte, weak electrolyte, precipitation reactions and solubility? 49. What is an Activity series of metal? How does it help us in studying properties of elements? 50. Define the terms: Exothermic, endothermic reactions? How much heat is required to raise the temperature of 100 grams of water from 25 0 C to 82 0 C? 51. A piece of unknown metal with mass 14.9 g is heated to C and dropped into 75.0 g of water at 20 0 C. The final temperature of the system is 28 degree Celsius. What is the specific heat of the metal? 52. What is a solute and solvent? Define Molarity, Molality, molefraction and Mass percent of a solution? 53. Calculate the molarity of a solution that contains 20.0grams of sodium hydroxide in 200ml? 54. How many grams of solute are present in 50.0 ml of M sodium chloride?

7 PART 2: COMMON IONS This part of the summer assignment for is quite simple (but not easy). You need to master the formulas, charges, and names of the common ions. On the first day of the school year, you will be given a quiz on these ions. You will be asked to: write the names of these ions when given the formula and charge write the formula and charge when given the names I have included several resources in this packet. First, there is a list of the ions that you must know on the first day. This list also has, on the back, some suggestions for making the process of memorization easier. For instance, many of you will remember that most of the monatomic ions have charges that are directly related to their placement on the periodic table. There are naming patterns that greatly simplify the learning of the polyatomic ions as well. Also included is a copy of the periodic table used in. Notice that this is not the table used in Regents chemistry. The AP table is the same that the College Board allows you to use on the test. Notice that it has the symbols of the elements but not the written names. You need to take that fact into consideration when studying for the aforementioned quiz! I have included a sheet of flashcards for the polyatomic ions that you must learn. I strongly suggest that you cut them out and begin memorizing them immediately. Use the hints on the common ions sheet to help you reduce the amount of memorizing that you must do. Do not let the fact that there are no flashcards for monatomic ions suggest to you that the monatomic ions are not important. They are every bit as important as the polyatomic ions. If you have trouble identifying the charge of monatomic ions (or the naming system) then I suggest that you make yourself some flashcards for those as well. Doubtless, there will be some students who will procrastinate and try to do all of this studying just before the start of school. Those students may even cram well enough to do well on the initial quiz. However, they will quickly forget the ions, and struggle every time that these formulas are used in lecture, homework, quizzes, tests and labs. All research on human memory shows us that frequent, short periods of study, spread over long periods of time will produce much greater retention than long periods of study of a short period of time. I could wait and throw these at you on the first day of school, but I don t think that would be fair to you. Use every modality possible as you try to learn these speak them, write them, visualize them. PART 3: SIGNIFICANT FIGURES IN CALCULATIONS Unless you have been exposed to significant figure rules in another course, this topic will take a bit of study. I have attached a twosided page with explanations of the rules, and examples of problem solving in addition, subtraction, multiplication, and division. There is also a page of problems for you to complete. This page is due at the beginning of class on the first day of next school year. There are some excellent videos and practice activities produced by Khan Academy for this subject. I look forward to seeing you all at the beginning of the next school year. If you need to contact me during the summer, you can me and I will get back to you quickly. Best of luck to you all, Ms. Khanis ethelkhanis@gmail.com

8 Common Ions and Their Charges A mastery of the common ions, their formulas and their charges, is essential to success in. You are expected to know all of these ions on the first day of class, when I will give you a quiz on them. You will always be allowed a periodic table, which makes indentifying the ions on the left automatic. For tips on learning these ions, see the opposite side of this page. From the table: Ions to Memorize Cations Name Cations Name H + Hydrogen Ag + Silver Li + Lithium Zn 2+ Zinc Na + Sodium Hg22+ Mercury(I) K + Potassium NH4+ Ammonium Rb + Rubidium Cs + Cesium Be 2+ Beryllium Anions Name Mg 2+ Magnesium NO2 Nitrite Ca 2+ Calcium NO3 Nitrate Ba 2+ Barium SO32 Sulfite Sr 2+ Strontium SO42 Sulfate Al 3+ Aluminum HSO 4 Hydrogen sulfate (bisulfate) OH Hydroxide Anions Name CN Cyanide H Hydride PO43 Phosphate F Fluoride HPO42 Hydrogen phosphate Cl Chloride H2PO4 Dihydrogen phosphate Br Bromide NCS Thiocyanate I Iodide CO32 Carbonate O2 Oxide HCO 3 Hydrogen carbonate (bicarbonate) S2 Sulfide ClO Hypochlorite Se 2 Selenide ClO 2 Chlorite N3 Nitride ClO 3 Chlorate P3 Phosphide ClO 4 Perchlorate As 3 Arsenide BrO Hypobromite Type II Cations Name BrO 2 Bromite Fe 3+ Iron(III) BrO 3 Bromate Fe 2+ Iron(II) BrO 4 Perbromate Cu 2+ Copper(II) IO Hypoiodite Cu + Copper(I) IO2 iodite Co 3+ Cobalt(III) IO3 iodate Co 2+ Cobalt(II) IO4 Periodate Sn 4+ Tin(IV) C2H3O2 Acetate Sn 2+ Tin(II) MnO 4 Permanganate Pb 4+ Lead(IV) Cr2O72 Dichromate Pb 2+ Lead(II) CrO42 Chromate Hg 2+ Mercury(II) O22 Peroxide C2O42 Oxalate NH2 Amide BO33 Borate S2O32 Thiosulfate

9 Tips for Learning the Ions From the Table These are ions can be organized into two groups. 1. Their place on the table suggests the charge on the ion, since the neutral atom gains or loses a predictable number of electrons in order to obtain a noble gas configuration. This was a focus in first year chemistry, so if you are unsure what this means, get help BEFORE the start of the year. a. All Group 1 Elements (alkali metals) lose one electron to form an ion with a 1+ charge b. All Group 2 Elements (alkaline earth metals) lose two electrons to form an ion with a 2+ charge c. Group 13 metals like aluminum lose three electrons to form an ion with a 3+ charge d. All Group 17 Elements (halogens) gain one electron to form an ion with a 1 charge e. All Group 16 nonmetals gain two electrons to form an ion with a 2 charge f. All Group 15 nonmetals gain three electrons to form an ion with a 3 charge Notice that cations keep their name (sodium ion, calcium ion) while anions get an ide ending (chloride ion, oxide ion). 2. Metals that can form more than one ion will have their positive charge denoted by a roman numeral in parenthesis immediately next to the name of the Polyatomic Anions Most of the work on memorization occurs with these ions, but there are a number of patterns that can greatly reduce the amount of memorizing that one must do. 1. ate anions have one more oxygen then the ite ion, but the same charge. If you memorize the ate ions, then you should be able to derive the formula for the ite ion and viceversa. a. sulfate is SO 4 2, so sulfite has the same charge but one less oxygen (SO 3 2 ) b. nitrate is NO 3, so nitrite has the same charge but one less oxygen (NO 2 ) 2. If you know that a sufate ion is SO 4 2 then to get the formula for hydrogen sulfate ion, you add a hydrogen ion to the front of the formula. Since a hydrogen ion has a 1+ charge, the net charge on the new ion is less negative by one. a. Example: PO 4 3 HPO 4 2 H 2PO 4 phosphate hydrogen phosphate dihydrogen phosphate 3. Learn the hypochlorite chlorite chlorate perchlorate series, and you also know the series containing iodite/iodate as well as bromite/bromate. a. The relationship between the ite and ate ion is predictable, as always. Learn one and you know the other. b. The prefix hypo means under or too little (think hypodermic, hypothermic or hypoglycemia ) i. Hypochlorite is under chlorite, meaning it has one less oxygen c. The prefix hyper means above or too much (think hyperkinetic ) i. the prefix per is derived from hyper so perchlorate (hyperchlorate) has one more oxygen than chlorate. d. Notice how this sequence increases in oxygen while retaining the same charge: ClO ClO 2 ClO 3 ClO 4 hypochlorite chlorite chlorate perchlorate

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11 Sulfite Sulfate Hydrogen sulfate Phosphate Dihydrogen Phosphate Hydrogen Phosphate Nitrite Nitrate Ammonium Thiocyanate Carbonate Hydrogen carbonate Borate Chromate Dichromate Permanganate Oxalate Amide Hydroxide Cyanide Acetate Peroxide Hypochlorite Chlorite Chlorate Perchlorate Thiosulfate

12 HSO 4 SO 4 2 SO 3 2 HPO 4 2 H2PO 4 PO 4 3 NH 4 + NO 3 NO 2 NCS HCO3 CO 3 2 SCN Cr2O 7 2 CrO 4 2 BO 3 3 NH 2 2 C2O 4 MnO 4 C2H3O 2 CN OH CH 3 COO ClO 2 ClO O 2 2 S2O 3 2 ClO 4 ClO 3

13 Significant Figures in Measurement and Calculations A successful chemistry student habitually labels all numbers, because the unit is important. Also of great importance is the number itself. Any number used in a calculation should contain only figures that are considered reliable; otherwise, time and effort are wasted. Figures that are considered reliable are called significant figures. Chemical calculations involve numbers representing actual measurements. In a measurement, significant figures in a number consist of: Figures (digits) definitely known + One estimated figure (digit) In class you will hear this expressed as "all of the digits known for certain plus one that is a guess." Recording Measurements When one reads an instrument (ruler, thermometer, graduate, buret, barometer, balance), he expresses the reading as one which is reasonably reliable. For example, in the accompanying illustration, note the reading marked A. This reading is definitely beyond the 7 cm mark and also beyond the 0.8 cm mark. We read the 7.8 with certainty. We further estimate that the reading is fivetenths the distance from the 7.8 mark to the 7.9 mark. So, we estimate the length as 0.05 cm more than 7.8 cm. All of these have meaning and are therefore significant. We express the reading as 7.85 cm, accurate to three significant figures. All of these figures, 7.85, can be used in calculations. In reading B we see that 9.2 cm is definitely known. We can include one estimated digit in our reading, and we estimate the next digit to be zero. Our reading is reported as 9.20 cm. It is accurate to three significant figures. Rules for Zeros If a zero represents a measured quantity, it is a significant figure. If it merely locates the decimal point, it is not a significant figure. Zero Within a Number. In reading the measurement 9.04 cm, the zero represents a measured quantity, just as 9 and 4, and is, therefore, a significant number. A zero between any of the other digits in a number is a significant figure. Zero at the Front of a Number. In reading the measurement 0.46 cm, the zero does not represent a measured quantity, but merely locates the decimal point. It is not a significant figure. Also, in the measurement 0.07 kg, the zeros are used merely to locate the decimal point and are, therefore, not significant. Zeros at the first (left) of a number are not significant figures. Zero at the End of a Number. In reading the measurement cm, the zero is an estimate and represents a measured quantity. It is therefore significant. Another way to look at this: The zero is not needed as a placeholder, and yet it was included by the person recording the measurement. It must have been recorded as a part of the measurement, making it significant. Zeros to the right of the decimal point, and at the end of the number, are significant figures. Zeros at the End of a Whole Number. Zeros at the end of a whole number may or may not be significant. If a distance is reported as 1600 feet, one assumes two sig figs. Reporting measurements in scientific notation removes all doubt, since all numbers written in scientific notation are considered significant feet 1.6 x10 3 feet Two significant figures feet 1.60 x 10 3 feet Three significant figures feet x 10 3 feet Four significant figures Sample Problem #1: Underline the significant figures in the following numbers. (a) cm answer = cm (e) ft. answer = ft. (b) in. answer = in. (f) m answer = m (c) 10 lb. answer = 10 lb. (g) 200. g answer = 200 g (d) ml answer = ml (h) 2.4 x 10 3 kg answer = 2.4 x 10 3 kg Rounding Off Numbers In reporting a numerical answer, one needs to know how to "round off" a number to include the correct number of significant figures. Even in a series of operations leading to the final answer, one must "round off" numbers. The rules are well accepted rules: 1. If the figure to be dropped is less than 5, simply eliminate it. 2. If the figure to be dropped is greater than 5, eliminate it and raise the preceding figure by If the figure is 5, followed by nonzero digits, raise the preceding figure by 1 4. If the figure is 5, not followed by nonzero digit(s), and preceded by an odd digit, raise the preceding digit by one 5. If the figure is 5, not followed by nonzero digit(s), and the preceding significant digit is even, the preceding digit remains unchanged Sample Problem #2: Round off the following to three significant figures.

14 (a) m answer = 3.48 m (c) g answer = 5.33 g (b) cm answer = 4.81 cm (d) in. answer = 8.00 in. Multiplication In multiplying two numbers, when you wish to determine the number of significant figures you should have in your answer (the product), you should inspect the numbers multiplied and find which has the least number of significant figures. This is the number of significant figures you should have in your answer (the product). Thus the answer to x 1244 would be rounded off to contain two significant figures since the factor with the lesser number of significant figures (0.024) has only two such figures. Sample Problem #3: Find the area of a rectangle 2.1 cm by 3.24 cm. Solution: Area = 2.1 cm x 3.24 cm = cm 2 We note that 2.1 contains two significant figures, while 3.24 contains three significant figures. Our product should contain no more than two significant figures. Therefore, our answer would be recorded as 6.8 cm 2 Sample Problem #4: Find the volume of a rectangular solid 10.2 cm x 8.24 cm x 1.8 cm Solution: Volume = 10.2 cm x 8.24 cm x 1.8 cm = cm 3 We observe that the factor having the least number of significant figures is 1.8 cm. It contains two significant figures. Therefore, the answer is rounded off to 150 cm 3. Division In dividing two numbers, the answer (quotient) should contain the same number of significant figures as are contained in the number (divisor or dividend) with the least number of significant figures. Thus the answer to would be rounded off to contain two significant figures. The answer to would be rounded off to contain three significant figures. Sample Problem #5: Calculate Solution: = We note that the 2.4 has fewer significant figures than the It has only two significant figures. Therefore, our answer should have no more than two significant figures and should be reported as 8.5. Addition and Subtraction In adding (or subtracting), set down the numbers, being sure to keep like decimal places under each other, and add (or subtract). Next, note which column contains the first estimated figure. This column determines the last decimal place of the answer. After the answer is obtained, it should be rounded off in this column. In other words, round to the least number of decimal places in you data. Sample Problem #6: Add g g + 4.1g Solution: g g g Sum = g Since the number 4.1 only extends to the first decimal place, the answer must be rounded to the first decimal place, yielding the answer 86.1 g. Average Readings The average of a number of successive readings will have the same number of decimal places that are in their sum. Sample Problem #7: A graduated cylinder was weighed three times and the recorded weighings were g, g, g. Calculate the average weight. Solution: g g g g In order to find the average, the sum is divided by 3 to give an answer of Since each number extends to three decimal places, the final answer is rounded to three decimal places, yielding a final answer of g. Notice that the divisor of 3 does not effect the rounding of the final answer. This is because 3 is an exact number known to an infinite number of decimal places.

15 Name Give the number of significant figures in each of the following: 402 m lbs 0.03 sec g liters ft. 5.1 x 10 4 kg 0.48 m m g 1.10 torr 760 mm Hg Multiply each of the following, observing significant figure rules: 17 m x 324 m = 1.7 mm x mm = in x in = m x 102 m = in x.090 in = cm x cm = Divide each of the following, observing significant figure rules: 23.4 m 0.50 sec = 12 miles 3.20 hours = g 1.51 moles = m sec = Add each of the following, observing significant figure rules: 3.40 m g 102. cm m 2.44 g 3.14 cm 0.5 m g 5.9 cm Subtract each of the following, observing signigicant figure rules: m g cm 1.22 m g cm Work each of the following problems, observing significant figure rules: Three determinations were made of the percentage of oxygen in mercuric oxide. The results were 7.40%, 7.43%, and 7.35%. What was the average percentage? A rectangular solid measures 13.4 cm x 11.0 cm x 2.2 cm. Calculate the volume of the solid. If the density of mercury is 13.6 g/ml, what is the mass in grams of 3426 ml of the liquid? A copper cylinder, 12.0 cm in radius, is 44.0 cm long. If the density of copper is 8.90 g/cm 3, calculate the mass in grams of the cylinder. (assume pi = 3.14)