B. Sc. (HONS.) INDUSTRIAL CHEMISTRY, SEMESTER-II

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1 S. N. 1. Course code BIC-1 B. Sc. (HONS.) INDUSTRIAL CHEMISTRY, SEMESTER-II Subject Periods Evaluation Scheme Subject Sessional ESE Total Theory CT TA Total Fundamentals of Computer 2. BIC -2 Environmental Chemistry BIC-3 Inorganic Chemistry-II BIC-4 Organic Chemistry-II BIC-5 Physical Chemistry-II Practical 6. BIC-6P Industrial chemistry Lab GP-1 General proficiency Total 9

2 FUNDAMENTALS OF COMPUTERS BIC-1 UNIT-I: History of Computers and Computer system 10 Hardware and Software, Machine languages, essentials of computer operation, Applications, Basic Structure of Computer System, AIU memory, CPU, I/O Devices, Memory management, Booting process (BIOS), Input devices memory-ram, ROM etc. Storage devices - Hard disc, Floopy disc, CD-ROM UNIT-II: Operating Devices and Operating Environment 10 Features, Advantages and Drawbacks, DOS, WINDOWS & UNIX; Introduction to Data Processing and Flowchart, Operating environment, MS Office (Word, Excel & Powerpoint) UNIT-III: Computer Networking 10 Introduction to networking, modem, Network topology concept and types with advantages and drawbacks of each, components of LAN, WAN, Medium. UNIT-IV: Internet and Web Technologies 10 History and concept, Architecture, Application, Hypertext Markup Language, DHTML, WWW, Gopher, FTP, Telnet, Web Browsers, Net Surfing, Search Engines, , Digital Signatures, Network, Security, Firewall. Books Recommended: Curtin, Information Technology: Breaking News, TMH. Raja Raman, V. Introduction to Computers. Nelson, Data Compression, BPB Bajpai, Kushwaha & Yadav, Introduction To Computer & C Programming, New Age Lehngart, Internet 101, Addision Wesley. 6. Chanchal Mittal Foundation of Information Technology Pragati.

3 ENVIRONMENTAL CHEMISTRY BIC-2 Unit-I: 10 Air pollutants - CO, CO 2, ozone, CFC; ozone depletion; global warming & NOx; Harmful effects of pollutants on living and non-living species; Oxygen, nitrogen and sulphur cycle Bhopal gas tragedy, Chernobyl disaster. Unit-II: 10 Water quality parameters; their assessment. Water pollution; water pollutants; toxicity aspects; international and national standards; control. Water sampling techniques Unit-III: 10 Fertilizers, insecticides, pesticides, plastics, toxic metals, dyes, surfactants; toxicity aspects; international and national standards; control. Unit-IV: 10 Industrial waste: toxic aspects, management and disposal. Radioactive, municipal, agricultural and biomedical waste toxicity hazards, management and disposal. Books recommended: Environmental Chemistry Manahan, Stanley E, 24, Taylor & Francis Ltd Basic Concepts of Environmental Chemistry, Desley W. Connell, 1 edition, CRC-Press Environmental Chemistry: A Global Perspective, Gary W. Vanloon Stephen J. Duffy, Oxford Univ Pr (Sd) Introduction To Environmental Chemistry, Reid, Brian J. Blackwell Science Ltd Chemistry of the Environment, Thomas G. Spiro, William M. Stigliani, 2nd Edition, Prentice Hall publication. Environmental Chemistry, Vanloon, Gary W Duffy, Stephen J., Oxford Higher Education publication Environmental Chemistry, Colin Baird, Michael Cann, 3rd edition, W. H. Freeman

4 Inorganic Chemistry-II BIC-3 Unit-I: S-Block Elements and Noble gases 10 Comparative study, diagonal relationships, salient features of hydrides, salvation and complexation tendencies including their function in biosystems, an introduction to alkyls and aryls. Unit-II: p-block Elements 10 Comparative study (including diagonal relationship) of groups elements, compounds like hydrides, oxides, oxyacids and halides of groups Hydrides of boron-diborane and higher boranes. Borazine, borohydrides Fullerenes, carbides, fluorocarbons, silicates (structural principle), tetrasulphur tetranitride, basic properties of halogens, interhalogens. Unit-III: Chemistry of Transition Series Elements 10 Characteristic properties of d-block elements. Properties of the elements of the first transition series their Binary compounds such as Carbides, Oxides and Sulphides. Unit-IV: Complexes 10 Complexes illustrating relative stability of their oxidation states, coordination number and geometry. Werner s coordination theory, effective atomic number, chelates, nomenclature, isomerism in coordination compounds, valence bond theory of transition elements. Books Recommended: Advanced Inorganic Chemistry Vol-I & II, Satya Prakash, G.D. Tuli, S.K. Basu, R.D. Madan, S. Chand & Co. Ltd. Test book of Inorganic Chemistry, P.L. Soni, Sultan Chand & Sons Simplified Course in Inorganic Chemistry, Madan & Tuli, S. Chand & Co. Ltd. Concise Inorganic Chemistry, J.D. Lee, Black Well Sciences

5 Organic Chemistry-II BIC-4 Unit-I: Arenes and Aromaticity 10 Nomenclature of benzene derivatives. The aryl group Aromatic nucleus and side chain Structure of benzene molecular formula and Kekule structure. Stability and carbon-carbon bond lengths of benzene, resonance structure. MO picture. Aromaticity the Huckel rule, Aromatic electrophilic substitution general pattern of the mechanism, Mechanism of nitration, halogenation. sulphonation. mercuration and Friedel-Crafts reaction Unit-II: Alkyl and Aryl Halides 10 Nomenclature and classes of alkyl halides, methods of formation, chemical reactions, mechanims of nucleophilic substitution reaction of alkyl halides, SN 1 and SN 2 and reactions, with energy profile diagrams. Unit III: Alcohols 10 Classification and nomenclature. Monohydric alcohols - nomenclature, methods of formation, reduction of aldehydes, ketones, carboxylic acids and esters. Hydrogen bonding. Acidic nature, Reactions of alcohols. Dihydric alcohols - nomenclature, methods of formation, chemical reactions of vicinal glycols, oxidative cleavage [Pb(OAc) 4 and HIO 4 ] and pinacol-pinacolone rearrangement. Trihydric alcohols - nomenclature and methods of formation, chemical reactions of glycerol. Unit-IV: Aldehydes and Ketones 10 Nomenclature and structure of the carbonyl group. Synthesis of aldehydes and ketones with particular reference to the synthesis of aldehydes from acid chlorides, synthesis of aldehydes and ketone using 1,3-dithianes, Physical properties. Mechanism of nucleophilic additions to carbonyl group with particular, aldol, Cannizzaro, Perkin, Wittig reaction. Mannich reaction. Baeyer-Villiger oxidation, reaction. Meerwine Pondorof Verlay, Clemmensen, Wolff- Kishner reduction. Books Recommended: Advanced Organic Chemistry, Bahl & Bahl, S. Chand & Co. Ltd. Organic Chemistry Vol.I & II, I.L. Finar Fundamentals of Organic Chemistry, Nafis Haider, S. Chand & Co. Ltd. A text book of Organic Chemistry, Bahl & Bahl, S. Chand & Co. Ltd. Organic Chemistry Vol.I, II & III, Dr. Jagdamba Singh, L.D.S. Yadav, Pragati Prakashan

6 Physical Chemistry-II BIC-5 Unit-I: Chemical Kinetics 10 Chemical kinetics and its scope, rate of a reaction, factors influencing the rate of a reaction concentration, temperature, pressure, solvent, light, catalyst concentration dependence of rates, mathematical characteristics of simple chemical reactions- zero, First, second & pseudo order, half life and mean life. Determination of the order of reaction differential method, method of integration, method of half life period and isolation method. Arrhenius equation, concept of activation energy. Simple collision theory based on hard sphere model, transition state theory (equilibrium hypothesis.) Unit-II: Thermodynamics 10 Definition of thermodynamic terms : system, surrounding etc. Types of systems, intensive and extensive properties. State and path functions and their differentials. Thermodynamic process. Concept of heat and work. First Law of Thermodynamics: Statement, definition of internal energy and enthalpy. Heat capacity, heat capacities at constant volume and pressure and their relationship. Joule s law -Joule- Thomson coefficient and inversion temperature. Calculation of W, q, du and dh for the expansion of ideal gases under isothermal and adiabatic conditions for reversible process. Unit III: Thermochemistry 10 Standard state, standard enthalpy of formation - Hess s Law of heat summation and its applications. Heat of reaction at constant pressure and at constant volume. Enthalpy of neutralization. Bond dissociation energy and its calculation from thermo-chemical data, temperature dependence of enthalpy. Kirchoffs equation. Second Law of Thermodynamics : need for the law, different statements of the law. Carnot cycle and its efficiency, Carnot theorem. Thermodynamic scale of temperature. Unit IV: Concept of entropy 10 Entropy as a state function, entropy as a function of V&T, entropy as a function of P&T, entropy change in physical change, Clausius inequality, entropy as a criteria of spontaneity and equilibrium. Entropy change in ideal gases and mixing of gases. Third Law of thermodynamics : Nernst heat theorem, statement and concept of residual entropy, evaluation of absolute entropy from heat capacity data, Gibbs and Helmholtz functions; Gibbs function (G) and Helmholtz function (A) as thermodynamic quantities, A & G as criteria for thermodynamic equilibrium and spontaneity, their advantage over entropy change. Variation of G and A with P, V and T.

7 Books Recommended: Physical Chemistry, P.WE. Atkins, ELBS Thermodynamics J. Rajaram and J.C. Kuriacose Educational Publishers. Chemical Thermodynamics by R.P.Rastogi et al Principles of physical chemistry by Puri Sharma and Pathan Essentials of Physical Chemistry, Bahl & Tuli, S. Chand & Co. Ltd. Principles of Physical Chemistry, Puri, Sharma & Pathania, Vishal Publishing Co. Simplified course in Physical Chemistry, Madan & Tuli, S. Chand & Co. Ltd. Atkin s Physical Chemistry, Atkin, Oxford Press. Physical Chemistry, Vemulapalli, Prentice Hall of India Modern Physical Chemistry, R.P. Rastogi et al. United Book Department, Allahabad

8 Chemistry Lab BIC-6P Qualitative analysis of inorganic mixtures, containing not more than four ionic species (excluding insoluble substances) out of the following : Pb 2+, Ag +, Cu 2+, Cd 2+, As 3+, Sn 2+, Fe 3+, Zn 2+, Ba 2+, Sr 2+, Ca 2+, Mg 2+, NH 4 +, CO 3 2-, S 2-, NO 2 -, CH 3 COO -, Cl -, Br -, I 1-, NO 3 -, SO 4 2-, PO Determination of Dissolved Oxygen in the given water sample. Determination of Biochemical Oxygen Demand in the given water sample. Determination of Chemical Oxygen Demand in the given water sample. Determination of Calcium and Magnesium hardness in the given water sample. Determination of Chloride content in the given water sample. Determination of total solids (T.S.) and total dissolved solids (T.D.S.) in the given sample of water. Determination of ph of the given different samples of water. Determination of conductivity of the sample of water. To study kinetically the reaction rate of decomposition of H 2 O 2 by iodine.