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1 egkjk.kk izrki ih-th- dkyst] taxy /kwlm+] xksj[kiqj d{kk %ch-,l&lh- Hkkx&nks P.K.VERMA Transition Introduction, Position in Periodic Table P.K.VERMA Transition Electronic configuration DR. S.K Carbohydrates Classification DR. S.K. Carbohydrates Ring structure of Glucose DR. R. SAHAY I Thermodynamic-I Introduction: definition of terms system, surroundings, open, isolated system Extensive& Intensive properties DR. R. SAHAY P.K.VERMA Transition Atomic & Ionic Radii P.K.VERMA Transition Variable Oxidation State DR. S.K. Carbohydrates Ring structure of Fructose DR. S.K. Carbohydrates Properties of Glucose and Fructose DR. R. SAHAY I Thermodynamic-I State & Path function & their differentials, Reversible & Irreversible Process DR. R. SAHAY P.K.VERMA Transition Ability to form complexes P.K.VERMA Transition Formation of coloured ions DR. S.K. Carbohydrates Interconversions in the Carbohydrate series DR. S.K Carbohydrates Ruff-degradation DR. R. SAHAY I Thermodynamic-I Concept of heat & work, First law of Thermodynamics DR. R. SAHAY P.K.VERMA Transition Magnetic(µ s &µ eff ) behaviour P.K.VERMA Transition Catalytic behaviour DR. S.K. General method of preparation DR. S.K. Molecular orbital structure of benzene DR. R. SAHAY I Thermodynamic-I Concept of Internal Energy Enthalpy, Heat capacities at constant volume Pressure & their relations DR. R. SAHAY P.K.VERMA Transition General comparative treatment of 4d & 5d elements with their 3d element P.K.VERMA Acid Base Concept Introduction, Lewis concept DR. S.K. ity, Huckel s Rule DR. S.K. Mechanism Halogenation &Nitration of DR. R. SAHAY I Thermodynamic-I Calculation of W, q, du&dh for the expansion of Ideal gas under Isothermal
2 DR. R. SAHAY P.K.VERMA Acid Base Concept Classification of Hard & Soft Acid & Bases P.K.VERMA Acid Base Concept Classification of Hard & Soft Acid & Bases DR. S.K DR. S.K. Sulphonation, Friedel-Craft s alkylation Friedel-Craft s acylation DR. R. SAHAY I Thermodynamic-I Adiabatic condition for a reversible process DR. R. SAHAY P.K.VERMA Acid Base Concept Application of HSAB Principle P.K.VERMA Acid Base Concept Application of HSAB Principle DR. S.K DR. S.K. Orientation in aromatic substitution Ortho-para ratio DR. R. SAHAY I Thermodynamic-I Calculation from the thermodynamic data, Kirchhoff sequation DR. R. SAHAY P.K.VERMA Coordination Introduction, Definition & Classification of Ligands P.K.VERMA Coordination Werner s Postulates DR. S.K. Halogen Types of aromatic halogen compounds, Chlorobenzene DR. S.K. Halogen Benzyl chloride DR. R. SAHAY I Thermodynamic- Second Law of thermodynamic, concept of Entropy, Entropy as a state function DR. R. SAHAY P.K.VERMA Coordination Sidgwick s effective atomic number concept P.K.VERMA Coordination Valence bond theory DR. S.K. Nitro Nitrobenzene, Reduction of nitrobenzene DR. S.K. Nitro m-dinitro benzene, TNT DR. R. SAHAY I Thermodynamic- Entropy as a function of U& T, P & T, Entropy change in physical process DR. R. SAHAY P.K.VERMA Coordination P.K.VERMA Coordination DR. S.K DR. S.K. & & Valence bond theory Chelate effect Aniline Benzyl amine
3 P.K.VERMA Coordination P.K.VERMA Nomenclature of only mono and dinuclear complexes DR. S.K DR. S.K. & & Basicity of aniline &Toluidines Benzene Diazonium chloride DR. R. SAHAY I Thermodynamic- Gibbs Helmholtz function: Criteria for thermodynamics equilibrium & change in entropy DR. R. SAHAY I Chemical Equlibrium P.K.VERMA Coordination P.K.VERMA DR. S.K DR. S.K. & & DR. R. SAHAY I Chemical Equlibrium Equilibrium constant and free energy Stereochemistry of coordination number 2,4 & 6 Synthetic uses of benzenediazonium chloride Benzene sulphonic acid, Sulphanilic acid Thermodynamic derivation of Law of Mass action, Le-Chattelier s principle DR. R. SAHAY I Electrochemistry-I Electrical transport conduction in metals & in electrolyte solutions, specific conductance P.K.VERMA Coordination [Ag(NH 3 ) 2 ] +,[Ag(CN) 2 ] -,[Ni(CN) 4 ] n P.K.VERMA DR. S.K DR. S.K. & Saccharine & Chloramine-T Phenols Acid character, Reactions of phenol DR. R. SAHAY I Electrochemistry-I Equivalent conductance, Measurement of equivalent conductance, variation of equivalent & specific conductance with dilution DR. R. SAHAY I Electrochemistry-I Migration of ions &Kohlrausch law, Arrhenius theory of electrolyte dissociation & its limitations P.K.VERMA Coordination [Cu(NH 3 ) 4 ] 2+,[Zn(NH 3 ) 4 ] 2+,[MnO 4 ] P.K.VERMA DR. S.K DR. S.K. Phenols Picric acid Alcohols Aldehydes & Ketones Benzaldehyde&Salicyldehyde DR. R. SAHAY I Electrochemistry-I Weak and strong electrolytes, Ostwald s dilution law, its uses & limitations DR. R. SAHAY I Electrochemistry-I Debye-Huckel-Onsager s equation for strong electrolytes [Fe(CN) 6 ] 3-,[Fe(CN) 6 ] 4-,[FeF 6 ] P.K.VERMA Coordination P.K.VERMA DR. S.K DR. S.K. Alcohols Aldehydes & Ketones Acetphenone&Benzophenone Acids Preparation & Properties of Cinnamic acid
4 DR. R. SAHAY I Electrochemistry-I Activity and activity coefficient, Transport number definition & determination by Hittorf method & moving boundary method DR. R. SAHAY I Electrochemistry-I Applications of conductivity measurements: determination of degree of dissociation, determination of K a of acids P.K.VERMA Coordination [Fe(H 2 O) 6 ] 3+,[Fe(C 2 O 4 ) 3 ] 3-,[Co(NH 3 ) 6 ] P.K.VERMA DR. S.K DR. S.K. Acids Phthalic acid & Salicylic acid Acids Acid structure of benzoic acid and substituted benzoic acids DR. R. SAHAY I Electrochemistry-I Determination of solubility product of a sparingly soluble salts, conductometric titration DR. R. SAHAY I Electrochemistry DR. S.K DR. S.K DR. R. SAHAY I Electrochemistry DR. R. SAHAY I Electrochemistry P.K.VERMA Coordination P.K.VERMA Coordination DR. S.K DR. S.K DR. R. SAHAY I Electrochemistry DR. R. SAHAY I Electrochemistry P.K.VERMA Coordination P.K.VERMA Coordination DR. S.K DR. S.K DR. R. SAHAY I Electrochemistry DR. R. SAHAY I Electrochemistry P.K.VERMA Non aqueous P.K.VERMA Non aqueous DR. S.K DR. S.K DR. R. SAHAY I Electrochemistry- Types of reversible electrodes-gas- metal ion, metal-metal ion, metal insoluble salt-anion & redox electrodes, Non condensed system: Biphenyl reaction s, Nernst equation, derivation of cell E.M.F & single electrode potential Standard Hydrogen electrode-reference electrodes-standard electrode potential [Co(en) 3 ] 3+,[Ni(NH 3 ) 6 ] 2+,[PbCl 6 ] 2- Isomerism Condensed system: Naphthalene Sign conventions, electrochemical series & its significance, Electrolytic & Galvanic cells Reversible & Irreversible cells, Conventional representation of electrochemical cells Various types of Isomerism Stereoisomerism in CN-4 & CN-6 Naphthols&Naphthyl amines E.M.F. of a cell & its measurements, Computation of cell E.M.F., Calculation of thermodynamic quantities of cell reactions ( G, H & K) Concentration cell with and without transport, Liquid junction potentials, Application of concentration cells General introduction & Classification of solvent Characteristics proportion of solvents Preparation & properties of Furan Valency of ions, solubility product & activity coefficient, Potentiometric titrations, Definition of ph &pka
5 DR. R. SAHAY I Electrochemistry P.K.VERMA Non aqueous P.K.VERMA Non aqueous DR. S.K DR. S.K DR. R. SAHAY I Electrochemistry- Determination of ph using Hydogen, Quinhydrone& glass electrode by Potentiometric method Chemical reaction occurring in liquid NH 3 Chemical reaction occurring in liquid NH 3 Pyrrole&Thiophene Buffers-mechanism of buffer action, Henderson- Hazel equation, hydrolysis of salts, Electrochemical corrosion & its prevention DR. R. SAHAY I Phase Equilibrium Phase, component & degree of freedom, derivation of Gibbs Phase rule P.K.VERMA Non aqueous P.K.VERMA Non aqueous DR. S.K DR. S.K. Pyridine DR. R. SAHAY I Phase Equilibrium Phase equilibria of one component systemwater, sulpher&hellium DR. R. SAHAY I Phase Equilibrium First & Second order phase transitions, Phase equilibria of two component systems-solid-liquid equilibria P.K.VERMA Non aqueous P.K.VERMA Concept of DR. S.K. Numerical Problems EMF diagram Determination of structure based on chemical reactions DR. S.K DR. R. SAHAY I Phase Equilibrium Simple Eutectic-Pb-Ag system, Desilverisation of Pb, System involving compound formation with a congruent melting point (Mg-Zn) DR. R. SAHAY I Phase Equilibrium Incongruent melting point (CuSO 4.H 2 O), Nernst distribution law & its thermodynamic derivation P.K.VERMA Concept of EMF diagram & their utility P.K.VERMA Concept of Numerical problems DR. S.K DR. S.K. Numerical Problems Determination of structure based on chemical reactions
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