CHEMISTRY DEPARTMENT, PORTLAND STATE UNIVERSITY
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1 CHEMISTRY DEPARTMENT, PORTLAND STATE UNIVERSITY CHEMISTRY 440/540, PHYSICAL CHEMISTRY. FALL, 2014 Venue: CR 250 Instructor: R. H. Simoyi (SB2 372) Syllabus: The chapters and page numbers referred to in this syllabus are from Physical Chemistry, Thermodynamics, Structure and Change; by Atkins and de Paula, W. H. Freeman and Company. ISBN 13: (2014, Tenth Edition) Lecture No. Date Topic Pages 0 bef. 9/29 Fundamentals; Matter,, Nuclear model, bulk matter, This is just revision to get us all on the same page. You should be familiar with all the topics dealt with on pages bef. 9/29 Energy, Newton s laws, work and energy, Boltzmann distribution; equipartition bef. 9/29 Waves, electromagnetic field Mon, 9/29 Properties of gases, ideal gas, state variables equations of state Mixture of gases Wed, 10/1 Kinetic theory of gases (introduction), Molecular speeds, Maxwell-Boltzmann Collisions, Collision frequency, mean free path Fri, 10/3 Real gases, deviations from ideal behavior. Compression factor, virial coefficients Van der Waals equation of state Mon, 10/6 VDW s loops and Maxwell construction Corresponding states, reduced variables,
2 Other equations of state Interlude: Read and familiarize yourself with differentiation and integration relevant to this Course on pp Wed, 10/8 First Law of thermodynamics; concepts. Acquisitive form of the first law Thermodynamic systems, heat and work, Internal energy Fri, 10/10 Formulation of the first law, expansion work, constant pressure expansion Isothermal expansion work Mon, 10/13 Calculation of Cp work done. Calorimetry, heat capacity Enthalpy and enthalpy change Wed, 10/15 Variation of enthalpy with T at Cp, Relationship of Cv and Cp Adiabatic changes, standard enthalpy changes Fri, 10/17 Thermochemistry, Born-Haber cycle, Hess Law, calculations Hess Law, Kirchoff s Law; standard enthalpy of formation Mon, 10/20 Differential scanning calorimetry, isorthermal titration calorimetry Exact and inexact differentials, changes in internal energy Joule-Thompson coefficient, measurement of isothermal JTC Interlude: Students may want to read on the section on multivariate calculus profiled on
3 pages before tackling the subject matter profiled on pages Wed, 10/22 The Joule experiment, change of internal energy at Cp, Joule-Thompson coefficient, isothermal Joule-Thompson coefficient Fri, 10/24 Adiabatic changes, change in temperature Change in pressure Mon, 10/27 Second Law of thermodynamics, spontaneity, energy dispersal and entropy Entropy as a state function Mon, 10/27 First exam given, covers lectures 1 13 (this is a take-home exam) 14 Wed, 10/29 Entropy and the Carnot cycle, thermodynamic temperature, Clausius Inequality Entropy and phase transitions Fri, 10/31 Third law of thermodynamics, Nernst theorem Absolute entropies, Helmholtz energy and work Mon, 11/03 Gibbs and non-expansion work, molar Gibbs energies Maximum work, spontaneity, Born equation
4 17 Wed, 11/05 Maxwell relations, internal pressure, fundamental equation of thermodynamics Properties of Gibbs Energy; variation with pressure Fri, 11/07 Properties of Gibbs energy, cont d; fugacity Problem solving, taken from pp Mon, 11/10 Physical transformations of substances, phase diagrams Phase rule Wed, 11/12 Some specific phase diagrams, water, helium and carbon dioxide Phase stabilities Fri, 11/14 Slopes and loci of phase boundaries, the liquid-vapor equilibrium Ehrenfest transitions, lambda transitions Mon, 11/17 Simple mixtures, description of mixtures, partial molar volumes The Gibbs-Duhem equation Mon, 11/17 Second take-home exam, covers lectures Wed, 11/19 Thermodynamics of mixing, excess functions, ideal solutions
5 Raoult and Henry s laws Fri, 11/21 Liquid mixtures, ideal solutions, more excess functions Colligative properties, elevation of boiling points, etc Mon, 11/24 Solubility, Osmosis Wed, 11/26 Make up Class Fri, 11/28 The day after Thanksgiving, no university exercises 27 Mon, 12/01 Temperature-composition phase diagrams, lever rule Phase separation, critical solution temperatures Wed, 12/03 Activities, activity coefficients, Biological standard state Mean activity coefficients Fri, 12/06 The Debye-Huckel limiting law, ionic strength Mon, 12/08 Final Exam, 12:30 PM 2:20 PM (Venue will be the same as the one for our normal lectures) - 5 -
6 Professor Simoyi, however, will not be continuing with the class for Chem 441/541. A new professor will take over for the winter term
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