1 A. jlk;u fokku iz u i= 2017 (II) vuqns k. Øekad. fo k; dksm iqflrdk dksm. Ikw.kkZad : 200 vad. Lke; : 3:00?kaVs
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- Owen Bishop
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1 Øekad Lke; H : 3:00?kaVs 2017 (II) jlk;u fokku iz u i= fo k; dksm iqflrdk dksm 1 A Ikw.kkZad : 200 vad vuqns k vkius fgunh dks ek/;e pquk gs A bl ijh{kk iqflrdk esa,d lks chl (20 Hkkx 'A'esa + 40 Hkkx 'B' + 60 Hkkx 'C' esa ) cgqy fodyi iz u (MCQ)fn, x, gsa A vkidks Hkkx 'A' esa ls vf/kdre 15 vksj Hkkx 'B' esa 35 iz uksa rfkk Hkkx 'C' esa Lks 25 iz uksa ds mrrj nsus gsa A ;fn fu/kkzfjr Lks vf/kd iz uksa ds mrrj fn, x, rc dsoy igys mrrjksa (Hkkx 'A' Lks 15,Hkkx 'B' ls 35 rfkk Hkkx 'C' ls 25) dh tkap dh tk,xha vksñ,eñvkjñ mrrj i=d vyx Lks fn;k x;k gs A viuk jksy uecj vksj dsunz dk uke fy[kus Lks igys ;g tkap yhft, fd iqflrdk esa i` B iwjs vksj lgh gsa rfkk dgha Lks dvs&qvs ugha gsa A ;fn,slk gs rks vki bfuothysvj Lks mlh dksm dh iqflrdk cnyus dk fuosnu dj ldrs gsa A blh rjg Lks vksñ,eñvkjñ mrrj i=d dks Hkh tkap ysa A bl iqflrdk esa jq dke djus ds fy, vfrfjdr iuus layxu gsa A vksñ,eñvkjñ mrrj i=d ds i` B 1 esa fn, x, LFkku ij viuk jksy uecj] uke rfkk bl ijh{kk iqflrdk dk Øekad fyf[k,] lkfk gh viuk glrk{kj Hkh vo'; djsa A vki viuh vksñ,eñvkjñ mrrj i=d esa jksy uacj] fo k; dksm] iqflrdk dksm vksj dsunz dksm ls lacaf/kr leqfpr o`rksa dks dkys ckwy isu ls vo ; dkyk djs aa ;g,d ek= ijh{kkfkhz dh fteesnkjh gs fd og vksñ,eñvkjñ mrrj i=d esa fn, x, funsz kksa dk iwjh lko/kkuh ls ikyu djs a],slk u djus ij dei;wvj fooj.kksa dk lgh rjhds Lks vdwfvr ugha dj ik,xk] ftlls varr% vkidks gkfu] ftlesa vkidh vksñ,eñvkjñ mrrj i=d dh vlohd`fr Hkh kkfey gs] gks ldrh gs A 5. Hkkx 'A' rfkk 'B' esa izr;sd iz u ds 2 vad vksj Hkkx 'C' esa izr;sd iz u 4 vad dk gsaa Hkkx 'A' rfkk 'B' esa izr;sd xyr mrrj dk _.kkred 0.50 vad rfkk Hkkx 'C' 1 vad fd;k tk,xka 6. izr;sd iz u ds uhps pkj fodyi fn, x, gsa A buesa Lks dsoy,d fodyi gh Þlghß vfkok ÞloksZRre gyß gs A vkidks izr;sd iz u dk lgh vfkok lokszrre gy <w a<uk gs A 7. udy djrs gq, ;k vuqfpr rjhdksa dk iz;ksx djrs gq, ik, tkus okys ijh{kkffkz;ksa dk bl vksj vu; Hkkoh ijh{kkvksa ds fy, v;ksx; Bgjk;k tk ldrk gs A 8. ijh{kkfkhz dks mrrj ;k jq iuuksa ds vfrfjdr dgha vksj dqn Hkh ugha fy[kuk pkfg, A 9. dsydwysvj dk mi;ksx djus dh vuqefr ugha gs A 10. ijh{kk lekfir ij fnnz fcunq fpfugr LFkku ls OMR mrrj i=d dks fohkkftr djs aa bfuothysvj dks ewy OMR mrrj i=d lksaius ds i pkr vki bldh dkwczuysl izfrfyfi ys tk ldrs gsaa 1 fgunh ek/;e@laldj.k ds iz u esa folaxfr gksus@ik;s tkus ij vaxzsth laldj.k izekf.kd gksxk A 1 dsoy ijh{kk dh iwjh vof/k rd csbus okys ijh{kkfkhz dks gh ijh{kk iqflrdk lkfk ys tkus dh vuqefr nh tk,xh A jksy uacj uke... vh;fkhz }kjk Hkjh xbz tkudkjh dks esa lr;kfir djrk gw A bfuothysvj ds glrk{kj
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3 3 भ ग\PART A एक लड क न ल ब ई व ल एक रस h क एक र र क पकड ह तथ उ क द र र र एक r त र ज य व ल पतल भ ब ह र रस h क त न कर वह लड क भ क ग द चक कर ल कर रस h क भ पर लप त ह र रत य य क चक कर 10 कण ल त ह र क त (रत त कण ) लड क भ क ओर बढ त ह? A boy holds one end of a rope of length and the other end is fixed to a thin pole of radius r. Keeping the rope taut, the boy goes around the pole causing the rope to get wound around the pole. Each round takes 10 s. What is the speed (in units of s -1 ) with which the boy approaches the pole? इल क त रबन त ड, प क n इल लघ य त प क व दक र र द पर इ रत क र त रब ई ज तh ह क व द क क ई h n क न ज ञ त क जजय र भ ल नह रहत र The smallest square floor which can be completely paved with tiles of size without breaking any tile, needs n tiles. Find n h र ल ब ई व ल एक hढ क एक द व र पर इ तरह ल न ह क वह 75 h र ऊ च ई तक पह च र द व र hढ क अग कत क ष तज द र ह कतh ह :- 1 h र थ ड क 1 h र थ ड अग क 1 h र 2 h र A 2 m long ladder is to reach a wall of height 75 m. The largest possible horizontal distance of the ladder from the wall could be slightly less than 1 m slightly more than 1 m 1 m 2 m 11 h ल ब, 8 h च ड और 20 h ऊ च एक आयत क र फ ल स क 5 h ऊ च ई तक प नh र ह र इ फ ल स क 1 h त र ज य क ल क र 21 र र रलय ल ज तh ह र इ प नh क तह कतनh ऊपर उठ h? 8.8 h 10 h 1 h 0 h A rectangular flask of length 11 cm, width 8 cm and height 20 cm has water filled up to height 5 cm. If 21 spherical marbles of radius 1 cm each are dropped in the flask, what would be the rise in water level? 8.8 cm 10 cm 1 cm 0 cm 5. द ववचर ( र, ऊ च ई) आल भ क र ल न जन ख य व ल आल भ क ह र नम न क न- कथन ह ह? क ज ड त जन ख य क ऊ च ई व र क ई ह- ब नह ह र हल क य यजक तय क अप क ष र य यजक तय क ल ब ई क कह अग क ह न क वन ह र ल ब व हल क य यजक तय क ख य ल ब व र य यजक तय अग क ह र ध य र व ध य ल ब ई व ल य यजक त नह ह र 5. Contours in the bivariate (weight, height) graph connect regions of approximately equal populations. Which of the following interpretations is correct?
4 4 The motion is uniform The speed between P 3 and P 4 is greater than that between P 5 and P 6 The speed from P 1 to P 2 increases because of downward slope The section P 3 to P 4 is covered at the slowest speed There is no correlation between height and weight of the population Heavier individuals are likely to be taller than lighter individuals Taller and lighter individuals are more in number than taller and heavier individuals There are no individuals of medium weight and medium height 6. एक तल र तल क त रब द ओ P 1 तथ P 10 क बhच एक त hल वस त क पथ द दय य ह, तथ उ क जस थ तय क 1 कण क अ तर ल पर गचजहहत कय य ह र नम न क न- कथन ह ह? त एक न ह र P 3 तथ P 4 क बhच क त P 5 तथ P 6 क बhच क त अग क ह र ढ ल न क क रण P 1 P 2 तक ज न पर त बढ तh ह र P 3 P 4 क ब क त तय कय ज त ह र 6. A path between points P 1 and P 10 on a level ground is shown, and positions of a moving object at 1 second intervals are marked. Which of the following statements is correct? 7. एक नय यर क अग कत 90 km तक उपय कय ज क त ह र एक स पनh य क त तप हय व हन कतनh अग कत द र ( क h. ) तय कर कत ह जब क उ क h च र यर नय ह? A new tyre can be used for at most 90 km. What is the maximum distance (in km) that can be covered by a three wheeled vehicle carrying one spare wheel, all four tyres being new? एक प क न ई व ल प ल क र 20 kg ह र इ प क 1000 द कय ज त ह र दन क पश च त प ल क र (kg ) कतन ह? A plate of size with uniform thickness, weighing 20 kg, is perforated with 1000 holes of size. What is the weight of the plate (in kg) after perforation? एक 5 cm 5 cm आ तररक अन रत स थ क व ल व दकर स ण 0.5 cm य य क अग कत कतनh ब लन क र प र ल क भड कय ज कत ह? What is the maximum number of cylindrical pencils of 0.5 cm diameter that can be stood in a square shaped stand of 5 cm 5 cm inner cross section?
5 5 10. द ख य ओ क य, 11 क व द व 9 क घन क य क बर बर ह र बड h ख य 25 क व द क ह र त ख य क 24 रत त त क द ण व बड h ख य क आ क य कतन ह? The sum of two numbers is equal to sum of square of 11 and cube of 9. The larger number is less than square of 25. What is the value of the sum of twice of 24 percent of the smaller number and half of the larger number? m 2 m 10 cm प क एक भ ल ढ ड कतन आयतन द र ह? 40 m m 3 0 m 3 0 m 3 1 What is the volume of soil in an open pit of size 2 m 2 m 10 cm? 40 m m 3 0 m 3 0 m 3 1 A तथ B क कन न क रलए ह? 1 For which values of A and B is? 1 नम न कथन क क ववल ह नह ह? य द क ई र h श र ष ठत गच कय र नल पर h र ज त ह, त उ क ज नल व बh र ह कतh थhर य द क h क न कर र ल ज तh ह, त उ क य ग यत अ ह र य द क ई प ण क ह, त वह प ण क द वव जजत ह त ह र य द क ई प ण क ववष ह, त वह प ण क द वव जजत नह ह त र If a patient dies even with excellent medical care, he likely had terminal illness. If a person gets employed, he has good qualifications. If an integer is even, it is divisible by two. If an integer is odd, it is not divisible by two cm ज व ल व द क च र क न ज व ल व क क कर, तय पश च त कन र क ड कर एक कश तh बन नh ह र कश तh क अग कत आयतन क रलए क न बत य? 6 cm 2 cm 3 cm 4 cm 1 Four small squares of side x are cut out of a square of side 12 cm to make a tray by folding the edges. What is the value of so that the tray has the maximum volume? 6 cm 2 cm 3 cm 4 cm 15. द वक A और B एक व त क र ट र क क य य क द ववपर त र र ट र क क एक ह द द ड न रत र करत ह र य द A 8 km/h क नयत च ल तथ B 6 km/h क नयत च ल द ड त ह ए, A 30 र न पश च त B क र लत ह त ट र क क ल ब ई कतनh ह? 1 km 4 km 3 km 2 km 15. Two runners A and B start running from diametrically opposite points on a circular track in the same direction. If A runs at a constant speed of 8 km/h and B at a constant speed of 6 km/h and A catches up with B in 30 minutes, what is the length of the track? 1 km 4 km 3 km 2 km 16. एक व य त क तhन च थ ई गच द दय य ह OA तथ OB परस पर ल बवत द त र ज य य ह र त रब द C व य त पर जस थत ह र 1 For which one of the following statements is the converse NOT true? क ण ACB क न बत ओ?
6 6 न दररत नह कय ज कत Three-quarters of a circle is shown in the figure; OA and OB are two radii perpendicular to each other. C is a point on the circle. What is angle ACB? Cannot be determined एक हर पव य व ल प क एक अ र क र हर रत क रभन पर ह क य दभ यh द? आ प क त लन प अग क चक त दभत ह र आ प क त लन प अग क हर दभ यh द र प व पय दवरण क ई द नह कय ज कत र प ह य अग क रत क श ल षण रत य ह hर द र ज जhर क वजन 22 ग र ह र नम न क न- कथन ह ह? 22 क र क ज जhर 18 क र क ज जhर ण ज य द न ह र 22 क र क ज जhर 18 क र क ज जhर ण ज य द न ह र द न ज जhर न क न ह र 22 क र क ज जhर क अप क ष 18 क र क ज जhर ण अग क न ह र 18. A person purchases two chains from a jeweller, one weighing 18 g made of 22 carat gold and another weighing 22 g made of 18 carat gold. Which one of the following statements is correct? 22 carat chain contains times more gold than 18 carat chain 22 carat chain contains times more gold than 18 carat chain Both chains contain the same quantity of gold 18 carat chain contains times more gold than 22 carat chain 19. ल पत रत त न बत ईय 17. If a plant with green leaves is kept in a dark room with only green light ON, which one of the following would we observe? The plant appears brighter than the surroundings The plant appears darker than the surroundings We cannot distinguish the plant from the surroundings It will have above normal photosynthetic activity 18. एक य यजक त क h न र न क द ज जhर भर दत ह र 22 क र न बनh पहल ज जhर क वजन 18 ग र ह तथ 18 क र न बनh
7 7 19. Find the missing pattern भ ग\PART B 2 त पhय ह य ट र न क नम नरल भत अर य ओ क क रलए - क न व दग क ह र 92 U n 1 92 U n 1 92 U n 1 92 U U n 1 90 Th He 4 92 U n 1 36 Kr Ba n 1 2 Among the following nuclear reactions of thermal neutrons, the cross section is highest for 92 U n 1 92 U n 1 92 U n 1 92 U U n 1 90 Th He 4 92 U n 1 36 Kr Ba n 1 2 जज अन पन क अ य य त रबह द क ज ञ त करन क रलए स प क ट र -रत क पh नh रन उपय क त नह ह, वह ह 20. एक ह रत ज त व बड द न तरह क जhव ण प य ज त ह र य द जhव ण क तह क ष रल S ह तथ आयतन V ह त नम न क न- कथन ह ह? S small > S large V small > V large (S/V) small > (S/V) large (S/V) small < (S/V) large 20. There are small and large bacteria of the same species. If S is surface area and V is volume, then which of the following is correct? S small > S large V small > V large (S/V) small > (S/V) large (S/V) small < (S/V) large ऑक रलक अम ल vs प र य पर न आयरन(II) vs 1,10- रन ह र ल न क ब ल (II) vs ऐररओ ब ल क - T नक ल(II) vs ई गथलग ल इआजक 2 Spectrophotometric monitoring is not suitable to determine the end point of titration of oxalic acid vs potassium permanganate iron(ii) vs 1,10-phenanthroline cobalt(ii) vs eriochrome black T nickel(ii) vs dimethylglyoxime 2 रत थ आयनhकरण ऊज द जज क रलए ह य नत ह, वह ह Br Se P As 2 The first ionization energy is the lowest for Br Se P As
8 8 2 ClO 3, XeO 3 तथ SO 3 वपर र h आक त क स पh hह ह / ह? ClO 3 तथ XeO3 XeO 3 तथ SO 3 ClO 3 तथ SO3 SO 3 2 Among ClO 3, XeO 3 and SO 3, species with pyramidal shape is/are? ClO 3 and XeO 3 XeO 3 and SO 3 ClO 3 and SO 3 SO औद य ग क बह ल करण उय प रक क प प BF 3 क क यद जज क उय पह न करन ह, वह ह क बदऋण यन क ब न यन क बद नक लक न यन लक 25. The role of BF 3 as an industrial polymerization catalyst is to generate carbanion carbocation organic radical cation radical 26. नम नरल भत क ल क रलए च म बक य आघ णद (क वल जस पन न) बढ न क ह र A. [TiF 6 ] 3 B. [CrF 6 ] 3 C. [MnF 6 ] 3 D. [CoF 6 ] 3 D < A < B < C C < A < D < B B A < D < C A < B < C D 26. For the following complexes, the increasing order of magnetic moment (spin only value) is A. [TiF 6 ] 3 B. [CrF 6 ] 3 C. [MnF 6 ] 3 D. [CoF 6 ] 3 D < A < B < C C < A < D < B B A < D < C A < B < C D 27. इ c क रलए ह कथन ह यह एक अ-ह रत न ह र आयरन क इ c ह वय ख य प च ह तh ह र यह एक र क रत न तथ इल क ट र न व हक ह र यह इआक hजन क ग रह अथव वहन कर कतh ह र 27. The correct statement for cytochrome c is It is a non-heme protein The coordination number of iron in cytochrome c is five. It is a redox protein and an electron carrier It can store or carry dioxygen 28. SNF 3 तथ XeF 2 O 2 क ज य र तय ह : व द तल य तथ व द तल य चत ष रलक य तथ चत ष रलक य व द तल य तथ त र नत क ष द वववपर र hय चत ष रलक य तथ त र नत क ष द वववपर र hय 28. Geometries of SNF 3 and XeF 2 O 2, respectively, are square planar and square planar tetrahedral and tetrahedral square planar and trigonal bipyramidal tetrahedral and trigonal bipyramidal 29. Co(CO) 4 H क IR स प क ट र 2121, 2062, 2043 तथ 1934 cm -1 पर ब ह दभत ह र Co(CO) 4 D क स प क ट र ν Co-D (cm -1 ) रत य य र त ह 2111 पर 1396 पर 2053 पर 1910 पर 29. The IR spectrum of Co(CO) 4 H shows bands at 2121, 2062, 2043 and 1934 cm -1. The ν Co-D (in cm -1 ) expected in the spectrum of Co(CO) 4 D is त र नत क ष वरत ज hय रल ह क ष व दग क स थ यय व रत प त करन व ल d-कक षक ह 2 d z d xy d xz d yz 30. In trigonal prismatic ligand field, the most stabilized d orbital is 2 d z d xy d xz d yz
9 9 3 इल क ट र -उद hनत र द ह त क आ र पर नम नरल भत क न- क ल व दग क अस थ यh ह [Al(OH 2 ) 6 ] 3+ [Al(NH 3 ) 6 ] 3+ [AlF 6 ] 3 [Al(NCCH 3 ) 6 ] 3+ 3 The most unstable complex on the basis of electro-neutrality principle among the following is [Al(OH 2 ) 6 ] 3+ [Al(NH 3 ) 6 ] 3+ [AlF 6 ] 3 [Al(NCCH 3 ) 6 ] 3+ 3 I 2 क इल क ट र नक स प क ट र 520 nm पर 3 Among the following, the compound that gives base peak at m/z 72 in the EI mass spectrum is उपजस थत ब ह, जज व दग क ब ल र फ हत ह, वह ह जल ह क न ब ह जhन थ न ल 3 The band in the electronic spectrum of I 2 appearing at 520 nm will undergo maximum blue shift in water hexane benzene methanol 35. नम नरल भत अण 3 नम नरल भत अस गत ह ल ह थ न इ तhर स ण तथ रत तद जप त ववस त त ब ह तथ d-d ण अय यग क जस पन-आत रबद य ग न तथ ण तय व आव स थ न ह तरण तथ 10 4 L mol 1 cm 1 क क लर अव षकत र त तल ह R पपण ह S पपण ह र त क ह द र ह 35. The following molecule has 3 Mismatch among the following is Sharp transition and fluorescence in lanthanides Broad bands and d-d transitions Very high spin-orbit coupling and transition elements Charge transfer and molar absorptivity of the order of 10 4 L mol 1 cm 1 plane of symmetry R configuration S configuration centre of symmetry 36. नम नरल भत रत क तक उय प द एह र इऑल 3 नम नरल भत य ग क ज EI द रय य न स प क ट र वह ह m/z, 72 पर आ र र भर द त ह,
10 10 ह, एक प न स र य रलग नन ऐल क ल इ 36. The following natural product Enterodiol is a 38. The kinetic product formed in the following reaction is terpene steroid lignan alkaloid 37. नम नरल भत ह र इ कल क क ष र यत क ह ह A > C > B C > A > B C > B > A B > A > C 37. The correct order of basicity for the following heterocycles is A > C > B C > A > B C > B > A B > A > C 39. नम नरल भत रचन वह एक, ज य ग क A क व दग क स थ यh प पण त करतh ह 38. नम नरल भत अर य उय पह न तक उय प द ह
11 Among the structures given below, the one that corresponds to the most stable conformation of compound A is 4 नम नरल भत य ग क क रत न अय जग त 13 C NMR स प क ट र रत क षत र ग नल क ख य ह 40. फ र यर आजण वक आत रबद ल (FMO) र द त क अन र ह क ट र इईन क व च अग क त आणववक आत रबद ल (HOMO) नम नरल भत अर य ह प च : द त रह 4 The number of signals observed in the proton decoupled 13 C NMR spectrum of the following compound is five six ten thirteen 4 नम नरल भत क ब न यन क स थ यhय व क ह ह 40. According to Frontier Molecular Orbital (FMO) Theory, the Highest Occupied Molecular Orbital (HOMO) of hexatriene in the following reaction is A > C > B B > C > A C > A > B C > B > A 4 The correct order of stability of the following carbocations is
12 12 A > C > B B > C > A C > A > B C > B > A 4 एक रत क त: द क बद नक य ग क क ध र वण घ ण क +40 o ह र +32 o क ध र वण घ ण दक द दन व ल एक न न क रत क hय द त ह र 8% 12% 20% 80% 4 An optically pure organic compound has specific rotation of +40 o. The optical purity of the sample that exhibits specific rotation of +32 o is 8% 12% 20% 80% 4 नम नरल भत अर य ववरगचत ख य उय प द ह 45. क ल P दय य ग क क क ल Q द ई IR तनन आव व य (cm -1 ) ह र ल न ह क ल P क ल Q I A 1865 II B 1770 III C 1745 I - B; II - C; III - A I - C; II - A; III - B I - C; II - B; III - A I - A; II - C; III - B 45. Correct match of the compounds in Column P with the IR stretching frequencies (cm -1 ) in Column Q is Column P Column Q I A 1865 II B 1770 III C The major product formed in the following reaction is I - B; II - C; III - A I - C; II - A; III - B I - C; II - B; III - A I - A; II - C; III - B 46. नम नरल भत आ कड द दन व ल ह क बद नक य ग क ह 1 H NMR (400 MHz): 7.38 (d), 7.25 (d), 29 (s) ppm
13 The organic compound that displays following data is 1 H NMR (400 MHz): 7.38 (d), 7.25 (d), 29 (s) ppm 47. नम नरल भत अण जज र त अक ष ह, वह ह 47. The molecule with a axis of symmetry among the following is 48. नम नरल भत अण ज र न स प क ट र द दय परह त IR स प क ट र नह, वह ह 48. The molecule that will show Raman spectrum, but not IR spectrum, among the following is 49. ब र न क करण ह करण ह करण ह क ई करण नह 49. Boron in has hybridization hybridization hybridization no hybridization 50. ह इड र जन ज पर ण क ख य क व ह ख य क रलए अपभ रष त र वव आत रबद ल क ख य ह The number of degenerate spatial orbitals of a hydrogen-like atom with principal quantum number is य द तथ ह, त नम नरल भत क न- ननश च त प प ल ह त ह : [ तथ आपर र ह ] 5 If and, then which of the following necessarily holds: [ and are operators] 5 नम नरल भत ह कथन ह ( एक हर द ऑपर र ह ) क आइ न न ऋ ण य क ह कत ह र क आइ न न द न य क ह त ह र क क ई h आइ न रलन क आइ न रलन नह ह र क आइ न न जम श र ह कत ह र
14 14 5 The correct statement among the following is ( is a hermitian operator ) The eigenvalues of can be negative. The eigenvalues of are always positive. No eigenfunction of is an eigenfunction of. The eigenvalues of can be complex. 5 स ल क एकक ल पर ण ओ /आयन क एक द र स प द करत ह ए कठ र ल रलय ज ए, त क य क जहद रत न रचन अग क त आयतन क रलए र ह न ह र 5 If the atoms/ions in the crystal are taken to be hard spheres touching each other in the unit cell, then the fraction of volume occupied in the body centered cubic structure is 5 झhल क जल क न न पर द हर य य क पन न तथ दय ह, क पन नक ववचलन ह Repeated measurements of in a lake water sample gave and of. Standard deviation in the measurement of is द रव-ववर h क ल इड क जस थरत, एक पररण ह र कण क तह पर उपजस थत व द य त द ववक स तर क कण क ध य व ह र व ल बल क कण क क ष आक र क कण क आक त क 55. The stability of lyophobic colloids is a consequence of the electrical double layer at the surface of the particles. van der Waals force between the particles. small particle size. shape of the particles. 56. एक रत बल ववद य त अपघ य क अन त तन त पर त ल य क च लकत क ज कतh ह, वह ह vs. vs. vs. vs. जज आर भ रत प त 56. The equivalent conductance at infinite dilution of a strong electrolyte can be obtained from the plot of vs. vs. vs. vs. 57. एक कण पररक ष पh बह लक क रलए ख य - औ त लर ह त र-औ त लर ह त क ज ब ह, वह ह 57. The number-average molar mass for a monodisperse polymer is related to the weight-average molar mass by the relation 58. त अर य ओ क एक
15 15 I क ह द रत स थ यh अवस थ जहनक न क अन र ह h 58. For a sequence of consecutive reactions, the concentration of I would be, by steady state approximation 60. The structure of ribonucleoside uridine is 59. एह थ ल पh जज क न ह, वह ह 59. Enthalpy is equal to 60. र इब ह य जक लओ इ य रर hन क रचन ह भ ग\PART C 6 वव द त पhय ववश ल षण वक क र भर क ष रल नम नरल भत एक य अग क क न प तh ह त ह : A. ह त क ष त B. न न क ह त C. ववघ न/रत वस थ पररवतदन ऊष ह उय तर ह क वल A क वल B A तथ C B तथ C
16 16 6 The peak area of differential thermal analysis curve is proportional to one or more of the following: A. mass loss B. mass of the sample C. heat of decomposition / phase change The correct answer is A only B only A and C B and C 6 25 o C पर आबह प र h र नक लन क रलए इल क ट र न वववतदन रत य: जजन द न क रलए अन पय क त ह, वह ह O 3 तथ NO 2 ल रर तथ ष क ब द NO 2 तथ ल रर O 3 तथ ष क ब द 6 To determine the bond parameters at 25 o C, electron diffraction is generally unsuitable for both O 3 and NO 2 Sulfur and dry ice NO 2 and sulfur O 3 and dry ice 6 क ल I दय य ल ह थ न इ क क ल II दय ए उनक ण र ल न क जजए क ल I क ल II a. Lu (i) ऑक hकरण अवस थ IV अर क दक b. Eu (ii) जयवक च क क MI 2 c. Ce (iii) रत तच म बक य M(III) d. Tb (iv) ऑक hकरण अवस थ III ल बh र ह र ल न ह a-(iii); b-(ii); c-(i); d-(iv) a-(ii); b-(iii); c-(iv); d-(i) a-(iv); b-(ii); c-(i); d-(iii) a-(iii); b-(ii); c-(iv); d-(i) 6 Match lanthanides in Column I with their properties in Column II Column I Column II a. Lu (i) Reagent in oxidation state IV b. Eu (ii) MI 2 of metallic lustre c. Ce (iii) Diamagnetic M(III) d. Tb (iv) Pink in oxidation state III Correct match is a-(iii); b-(ii); c-(i); d-(iv) a-(ii); b-(iii); c-(iv); d-(i) a-(iv); b-(ii); c-(i); d-(iii) a-(iii); b-(ii); c-(iv); d-(i) 6 नम नरल भत CH 2 क थ ज आइ ल बल ह, वह ह A. CpCr(CO) 2 B. CpCu C. Ni(CO) 2 D. Cr(CO) 4 E. Fe(CO) 4 A, C तथ E B, C तथ D B, C तथ E A, B तथ D 6 Among the following, species isolobal to CH 2 are A. CpCr(CO) 2 B. CpCu C. Ni(CO) 2 D. Cr(CO) 4 E. Fe(CO) 4 A, C and E B, C and D B, C and E A, B and D 65. स रलब ऋण यन [PMo 12 O 40 ] 3- क रलए नम नरल भत असत, कथन च नए 1 इ क क ग न रचन ह तh ह र 2 स र र क ऑक hकरण अवस थ +5 ह र 3 यह अय यग क क ष र य ह त ह र यह [R 4 N] + (R = ऐजलकल य ऐररल ग र प) क थ स ल य अवक ष प द त ह र 65. Choose the incorrect statement for the phosphomolybdate anion, [PMo 12 O 40 ] It has a Keggin structure. 2 Phosphorus is in +5 oxidation state. 3 It is extremely basic. It forms crystalline precipitates with [R 4 N] + (R = bulky alkyl or aryl group) 66. ऐजक न इ (An) क रलए नम नरल भत कथन पर ववच र क जजएर A. ल ह थन इ (Ln) क अप क ष An +3 अग क ऑक hकरण अवस थ र लन क अग क रत यकत ह र B. क An(III) आयन d-d ण द दत ह र C. UO 2 2+ तथ PuO 2 2+ जस थर ह त ह र
17 17 D. क ऐजक न इ क र ड य स थ नक नह ह र ह उय तर ह A तथ C B तथ D A, B तथ C B, C तथ D 66. Consider the following statement(s) for actinides (An): A. Oxidation states greater than +3 are more frequent in An compared to lanthanides (Ln) B. Some An(III) ions show d-d transitions C. UO 2+ 2 and PuO 2+ 2 are stable D. Some of actinides do not have radioactive isotopes The correct answer is A and C B and D A, B and C B, C and D 67. ब ह नय न र p-ब ल क क तय व क रलए क ह द र य पर ण क च र ओर ज य र तh तथ अग क ऋण ववद य तऋण य क रत तस थ पh क स थ न क ह य ह त र नत क ष द वववपर र hय तथ अक षhय त र नत क ष द वववपर र hय तथ ध यवत व द वपर र hय तथ अक षhय व द वपर र hय तथ आ ररक 67. According to Bent s rule, for p-block elements, the correct combination of geometry around the central atom and position of more electronegative substituent is Trigonal bipyramidal and axial Trigonal bipyramidal and equatorial Square pyramidal and axial Square pyramidal and basal 68. एक तय व क आलर -र h ववद य त ऋण य कत A. रत वh ह य क ल य आव क h न प तh ह र B. ह य जक त र ज य क h न प तh ह र C. ह य जक त र ज य क व द क य य य न प तh ह र D. रत वh ह य क ल य आव क व द क h न प तh ह र ह उय तर ह A तथ B A तथ C B तथ C A तथ D 68. Allred-Rochow electronegativity of an element is A. directly proportional to the effective nuclear charge B. directly proportional to the covalent radius C. inversely proportional to the square of the covalent radius D. directly proportional to the square of the effective nuclear charge The correct answer is A and B A and C B and C A and D 69. रत प न न Br 2 एक आव स थ न ह तरण क ल बन तh ह, तथ I 2 क थ I, ट र इआय इ ऋण यन बन तh ह र यह क त करत ह क Br 2 तथ I 2 द न क ष र क क यद करत ह र Br 2 तथ I 2 द न अम ल क क यद करत ह र Br 2 एक अम ल क क यद करत ह तथ I 2 क ष र क र Br 2 एक क ष र क क यद करत ह तथ I 2 अम ल क र 69. Br 2 with propanone forms a charge transfer complex and I 2 forms triiodide anion with I. This implies that both Br 2 and I 2 act as bases both Br 2 and I 2 act as acids Br 2 acts as an acid and I 2 acts as a base Br 2 acts as a base and I 2 acts as an acid 70. क ल [Pd(L-L)(Me)(Ph)] ज त रब -र स र न (L-L), PhMe क अपच यक ववल पन क अन त नह करतh ह, वह ह
18 18 7 नhच द यh आर य, स थ न ह तर ह इड र जनhकरण अर य क रलए अरत वh त रब र स र न (P-P) ह 70. In the complex [Pd(L-L)(Me)(Ph)], the bisphosphine (L-L) that does not allow reductive elimination of PhMe, is इ नल स र न थ न 1, 2- इ नल स र न एथ न 1, 3- इ नल स र न रत प न 1, 4- इ नल स र न ब य न 7 In the reaction given below, the bisphosphine (P-P) that is ineffective for transferhydrogenation reaction is Diphenylphosphinomethane 1,2-Diphenylphosphinoethane 1,3-Diphenylphosphinopropane 1,4-Diphenylphosphinobutane 7 उ च तथ ह य न जस पन d 6 अष रलक य क ल रत य: रत क षत जस पन अन त ण ह : (ML 6 ) द तथ एक एक तथ द ह य तथ एक द तथ द 7 For high spin and low spin d 6 octahedral complexes (ML 6 ), the generally observed spin allowed transitions, respectively, are two and one one and two zero and one two and two 7 नhच द यh अर य य उद हरण ह A. Cl 2 + 2H 2 O HOCl + H 3 O + + Cl + B. Cl 2 + 2NH 3 NH 2 Cl + NH 4 + Cl क वल अ न प तन क अ न प तन (A) तथ ववल यक यन (B) क
19 19 ववल यक यन (A) तथ अ न प तन (B) क ज ववल यक अपघ न व ह अ न प तन क 7 The reactions given below, A. Cl 2 + 2H 2 O HOCl + H 3 O + + Cl + B. Cl 2 + 2NH 3 NH 2 Cl + NH 4 + Cl are examples of disproportionation only disproportionation (A) and solvation (B) solvation (A) and disproportionation (B) solvalysis as well as disproportionation 7 व क नय क अन र [Sn 9 ] 4 क लस र क रत क र तथ ज य र तh : ह closo तथ ट र इ क प त र नत क ष वरत ज hय nido तथ न क प व द रत त वरत ज hय arachno तथ प त जhय द वववपर र hय closo तथ न क प व द रत त वरत ज hय 7 According to Wade s rules, the cluster type and geometry of [Sn 9 ] 4, respectively, are closo and tricapped trigonal prismatic nido and monocapped square-antiprismatic arachno and heptagonal bipyramidal closo and monocapped square antiprismatic J PH > 1 J PB नकर H 3 P: 11 BCl 3 [ 11 B, क रलए I =3/2] क अप क षत 31 P NMR स प क ट र ह र 76. K 3 CuF 6 तथ KCuL 2, [H 2 L = H 2 NCONHCONH 2 ] Cu क इ द ग द ज य र तh तथ जस पन अवस थ ह, : (अष रलक य, उ च-जस पन) तथ (व द तल य, ह य न-जस पन) (अष रलक य, ह य न-जस पन) तथ (व द तल य, ह य न-जस पन) (त र नत क ष वरत ज hय, उ च-जस पन) तथ (चत ष रलक य, उ च-जस पन) (त र नत क ष वरत ज hय, ह य न-जस पन) तथ (चत ष रलक य, उ च-जस पन) 76. The geometry around Cu and its spin state for K 3 CuF 6 and KCuL 2, [H 2 L = H 2 NCONHCONH 2 ], respectively are: (octahedral, high-spin) and (square planar, low-spin) (octahedral, low-spin) and (square planar, low-spin) (trigonal prismatic, high-spin) and (tetrahedral, high-spin) (trigonal prismatic, low-spin) and (tetrahedral, high-spin) 77. आक h ह ररगरन क य स थल क रचन ह र 75. Assuming 1 J PH > 1 J PB, the expected 31 P NMR spectrum of H 3 P: 11 BCl 3 [for 11 B, I =3/2] is
20 The active site structure for oxy-hemerythrin is: C. ह प ह वयh Co 3+ स पh hज एक ध यवत ह र ह कथन ह /ह A तथ B A तथ C B तथ C क वल C 78. Consider the following statements with respect to the base hydrolysis of [CoCl(NH 3 ) 5 ] 2+ to [Co(NH 3 ) 5 (OH)] 2+. A. One of the ammonia ligands acts as a Br nsted acid. B. The entering group is water. C. A heptacoordinated Co 3+ species is an intermediate. The correct statement(s) is/are A and B A and C B and C C only 79. क य ब न ज h र र जक न अक बद नक ल र इ क ख य तथ उनक प थक करण क ववग ह : आठ तथ एक अम ल ल ई च र तथ एक क ष र ल ई आठ तथ एक क ष र ल ई च र तथ एक अम ल ल ई 79. The number of inorganic sulfides in cubane like ferredoxin and their removal method, respectively, are eight and washing with an acid four and washing with a base eight and washing with a base four and washing with an acid 80. थ य यन क उ यद त र य यवह र क ध य न रभकर नम न रचन ओ व दग क जस थर क न- h ह 78. [CoCl(NH 3 ) 5 ] 2+ क [Co(NH 3 ) 5 (OH)] 2+ क ष र य जल अपघ न क रलए नम नरल भत कथन पर ववच र क जजएर A. एक अ नय रल ह रनह द अम ल ज क यद करत ह र B. रत व करन व ल ग र प जल ह र
21 Considering the ambidentate behaviour of thiocyanate ion, the most stable structure among the following is 8 Major product of the following reaction is 8 नम नरल भत अर य ख य उय प द ह र 8 नम नरल भत अर य क ख य उय प द ह र
22 22 8 Major product in the following reaction is 8 नम नरल भत अर य ख य उय प द A तथ B ह र 8 नम नरल भत अर य उय पह न ख य उय प द ह र 8 The major product formed in the following reaction is 8 Major products A and B of the following reaction sequence are
23 नम न अर य ववरगचत ख य उय प द ह 85. नम नरल भत अर य क ख य उय प द A तथ B ह 86. The major product formed in the following reaction is 85. Major products A and B of the following reaction sequence are
24 A क B पररव तदत करन क रलए आवश यक अर क दक (i)-(iii) क ह ह (i) थ य नल क ल र इ, (ii) 4-क ल र वपरर hन, (iii) वपप रर hन (i), (ii) तथ (iii) (i), (iii) तथ (ii) (ii), (i) तथ (iii) (iii), (i) तथ (ii) इक ल कलन, ऐल ल घनन, syn- ववल पन, क -ईन ल चल वयवत ऐल ल घनन, इल क ट र इजक लक रर क ल र, syn- ववल पन, ववह इड र जनhकरण इक ल कलन, क ल जन घनन, anti- ववल पन, क -ईन ल चल वयवत र त रबन न वलयन, ववह इड र जनhकरण, anti- ववल पन 89. Correct sequence of steps involved in the following transformation is 87. Correct sequence of reagents (i)-(iii) required for the conversion of A to B is (i) Thionyl chloride, (ii) 4-Chloropyridine, (iii) Piperidine (i), (ii) and (iii) (i), (iii) and (ii) (ii), (i) and (iii) (iii), (i) and (ii) 88. नम नरल भत अर य जम रलत ह Michael addition, aldol condensation, syn-elimination, keto-enol tautomerism aldol condensation, electrocyclic ring closing, syn-elimination, dehydrogenation Michael addition, Claisen condensation, anti-elimination, keto-enol tautomerism Robinson annulation, dehydrogenation, anti-elimination 90. नम न अर य ख य उय प द A तथ B ह र [1,2] र ग ट र वपक प नववदह य [2,3] र ग ट र वपक प नववदह य [3,3] र ग ट र वपक प नववदह य C-H नव न अर य 88. The following reaction involves [1,2] sigmatropic rearrangement [2,3] sigmatropic rearrangement [3,3] sigmatropic rearrangement C-H insertion reaction 89. नम न प प ह तरण अप क षत पद क ह ह
25 The major products A and B in the following reaction sequence are 9 CH 3 -CH(OH)-CH(OH)-CH(OH)-CH 3 क रलए व ध र वण घ ण त र वव वयवh ह र द च र : आठ 9 The number of optically active stereoisomers possible for CH 3 -CH(OH)-CH(OH)-CH(OH)- CH 3 is two four six eight 9 क ल P ल द व र घ र य रत न और क ल Q क 1 H NMR र य नक त ( ppm) क ह र ल न ह P Q 9 नम न अर य उय पह न ख य उय प द ह I A 6.72 II B 16.4 III C The major product formed in the following reaction sequence is I A; II B; III C I B; II A; III C I B; II C; III A I C; II B; III A 9 The correct match of the circled protons in Column P with the 1 H NMR chemical shift ( ppm) in Column Q is P Q I A 6.72
26 26 II B 16.4 III C 0.61 I A; II B; III C I B; II A; III C I B; II C; III A I C; II B; III A 9 नम नरल भत अर य ववरगचत ख य उय प द ह 95. उय प द A क ओर अग र ररत करन व ल प प इ बह न क रल श ल षण क रलए ऐ hन अम ल B क प श वद श र भल ह नh च हएर XH = -OH XH = -(CH 2 ) 4 NH XH = -p-(c 6 H 4 )OH XH = -SH 95. For the successful synthesis of peptide linkage leading to the product A, the side chain of the amino acid B should have 9 The major product formed in the following reaction sequence is XH = -OH XH = -(CH 2 ) 4 NH XH = -p-(c 6 H 4 )OH XH = -SH 96. नम नरल भत अर य क ख य उय प द A तथ B ह र
27 The intermediate A and the major product B in the following reaction are 96. The major products A and B in the following reaction sequence are 97. नम नरल भत अर य ध यवत A तथ ख य उय प द B ह र 98. नम नरल भत अर य क रलए ह ध यवत ज उय प द क और अग र ररत करत ह, वह ह 98. The correct intermediate which leads to the product in the following reaction is
28 नम नरल भत अर य ख य उय प द A तथ B ह र 99. नम नरल भत प प ह तरण A क इल क ट र इक ल करण क रत ण ल तथ ख य उय प द B ह र 100. The major products A and B in the following reaction sequence are 99. In the following transformation, the mode of electrocyclization A and the major product B are 10 D रल आवत द लक क एक क व ह क आइ न रलन क र त क रलए ह कथन ह h आइ न रलन क वल रलन ह क य क वव व एक रलन ह र h आइ न रलन क वल ववष रलन ह यद यवप वव व एक रलन ह र आइ न रलन क क ई ववष - र त नह ह र h आइ न रलन ववष अह यथ रलन ह क य क वव व एक रलन ह र
29 29 10 The correct statement about the symmetry of the eigenfunctions of a quantum of D harmonic oscillator is All the eigenfunctions are only even functions, because the potential is an even function. All the eigenfunctions are only odd functions, although the potential is an even function. The eigenfunctions have no odd-even symmetry. All the eigenfunctions are either odd or even functions, because the potential is an even function. 10 एक ह लम ब ई क D, D व द तथ D घन ब क द ववतhय तथ रत थ उय त जजत अवस थ ओ क ऊज दओ अह तर ( क रलए ह कथन ह र D D D D D D D D D D D D 10 The correct statement about the difference of second and first excited state energies ( of a particle in D, D square and D cubic boxes with same length for each, is D D D D D D D D D D D D 10 एक वव hय क व ह रल आवत द लक एक वव व ऊज द परह त क ष र त ह र नम नत अवस थ क क रलए रत थ क क द ग ह र 10 A one-dimesnsional quantum harmonic oscillator is perturbed by a potential. The first order correction to the energy for the ground state is but 10 नhच गच द व र एथhल न क ह य प प रत स त त कय य ह, यह क वल IR य ह क वल र न य ह IR तथ र न द न य ह न IR य ह औन न र न य ह 10 The normal mode of ethylene represented, by the figure below, is only IR active only Raman active both IR and Raman active neither IR nor Raman active 105. नम नरल भत य ग जज द न ल य प तथ र त प ह, वह ह,,, 105. The pair that contains a spherical top and a symmetric top, among the following, is,,, 106. एक त रबह द ह (क 4) क अर लक षण रणh क अ नhच दय ह र E????
30 30 क च र अर लक षण ह, : 1, 1, 1, 1 2, 0, 0, 1 1, i, i, 1 1, i, i, A part of the character table of a point group (of order 4) is given below. E???? The four characters of are, respectively 1, 1, 1, 1 2, 0, 0, 1 1, i, i, 1 1, i, i, रत पhन इल लक क रलए इल क ट र नक ण क ऊज द ह र हकल र द त क ढ च क अह त दत ण क रलए ऊज द ह hर 107. The electronic transition energy from in propenyl radical is. Within the frame work of Huckel theory, the transitions energy from would be H तथ 13 C क रलए g- णक : 5.6 तथ 4 ह र च म बक य क ष बल क एक ह न क रलए 1 H 600 MHz पर अन न दन करत ह, त 13 C क अन न दन ह 2400 MHz पर 600 MHz पर 150 MHz पर 38 MHz पर 108. The g-factors of 1 H and 13 C are 5.6 and 4 respectively. For the same value of the magnetic field strength, if the 1 H resonates at 600 MHz, the 13 C would resonate at 2400 MHz 600 MHz 150 MHz 38 MHz 109. त आयन क नम नत अवस थ क रलए पद रत तhक 3 P 2 ह र 0 K पर इ ल क स ल क अव ष एह ट र पh ह त आयन क एक 109. The term symbol for the ground state of a metal ion is 3 P 2. The residual entropy of a crystal of a salt of this metal ion at 0 K is 110. रबर ब ह क तनन, नम नरल भत ब क न- य य ह? 110. In stretching of a rubber band, Which of the following relations is true? 11 च र वव द य अण, ऊज द अवस थ ओ E 1 तथ E 2, : 2 तथ 3 अपभ रष त क थ ववतररत ह र 3 अण ऊज द स तर E 1 तथ एक ऊज द स तर E 2 त इ स क ख य ह ह 11 Four distinguishable molecules are distributed in energy levels E 1 and E 2 with degeneracy of 2 and 3, respectively. Number of microstates, with 3 molecules in energy level E 1 and one in energy level E 2, is आद द क एक ल गच दभ ए य च य रत (ABCDA), त रबह द A रत रम उय णhय चरण जरत ह र रत य क ल क यद ह र कर च र कय
31 31 क रलए प वद-अन नत ववद य त व हक बल (emf) ह 11 The predicted electromotive force (emf) of the electrochemical cell 11 One mole of an ideal gas undergoes a cyclic process (ABCDA) starting from point A through 4 reversible steps as shown in the figure. Total work done in the process is 11 एक ववद य त-अपघ य क ववलयन क ववर ष च लकत 0.2 ह र ववलयन क च लकत ह ह, तथ ल नयत क 11 If the specific conductance of an electrolyte solution is 0.2 and cell constant is, the conductance of the solution is 11 ववद य तर यनh ल is is 115. एक बह लक क रलए नम नरल भत लर ह त ववतरण ह अण ओ क ख य लर ह त (g.mol 1 ) बह लक क रलए पररकरलत ख य औ त लर ह त ह र A polymer has the following molar mass distribution Number of Molar mass (g.mol 1 ) molecules The calculated number average molar mass of the polymer is ववष लम ब क ष एकक ल क (123) तल क ध य प थक करण 12 nm ह र (246) तथ (369) तल क ध य प थक करण ह : 56 nm तथ 04 nm 04 nm तथ 56 nm 12 nm तथ 50 nm 04 nm तथ 12 nm
32 The separation of the (123) planes of an orthorhombic unit cell is 12 nm. The separation of (246) and (369) planes are, respectively, 56 nm and 04 nm 04 nm and 56 nm 12 nm and 50 nm 04 nm and 12 nm 117. एह ह इ उय रत ररत अर य क रलए (1/दर) VS (1/ बस ट र ह द रत ) रत प त स ल प तथ अ त: भ : 300 तथ ह र इ एह ह इ क रलए इक रल - ह न जस थर क इ अर य ह र M M M M 117. The slope and intercept obtained from (1/Rate) against (1/substrate concentration) of an enzyme catalyzed reaction are 300 and , respectively. The Michaelis-Menten constant of the enzyme in this reaction is M M M M 118. एक प ष ठ तन व क द रव ववरगचत, त र ज य r क ल क र क र क अह दर द ब जज रत क र ब ह य द ब ( ) ब ग त ह, वह ह 118. The pressure inside a spherical cavity with a radius r formed in a liquid with surface tension is related to the external pressure ( ) as 119. Reaction between A and B is carried out for different initial concentrations and the corresponding half-life times are measured. The data are listed in the table: Entry The rate can be represented as 120. अर य क रलए दर नयत क क म भ आय नक बल क अ कन (गच द भए) जज र भ क अन रण करत ह, वह ह I II III IV 120. The plot of the rate constant vs. ionic strength of the reaction follows the line (refer to the figure) 119. A तथ B क ध य अर य ववर ह न रत र र क ह द रत ओ पर करक त अ द आय पh यh ह र आ क रणh चhबद ह Entry दर क इ रत क र नपवपत कर कत ह र I II III IV
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