CHEM 2312 practice final. Version I
|
|
- Amberly Goodman
- 6 years ago
- Views:
Transcription
1 CEM 2312 practice final Version The following standardized final examination covers the entire introductory year of organic chemistry (CEM 2311 and 2312 at Georgia Tech). The exam consists of 70 multiple choice questions, each with four choices for the correct answer. There is a single correct answer to each question. To most effectively use this as a guide to the final: complete the examination in a single uninterrupted two-hour session without reference to other materials (lock your door, turn off your phone and switch off your computer). Then enter your answers into T-square (there is a link to Practice Final on the WebCT course page). Your exam will be scored (out of 70) and you will get access to the solutions. Question 1
2 Question 1 What is the ground-state electronic configuration of an oxygen atom (oxygen: atomic number 8)? (a) 1s 2 2s p 5 (b) 1s 2 2s 2 2p 4 (c) 1s s p 6 (d) 1s 2 2s 2 2p 2 Question 2 Which of the following is a tertiary alcohol? (a) C 3 C 2 C 3 (b) (C 3 ) 3 C (c) (C 3 ) 2 C (d) C 3 C 2 C 2 Question 3 Which of the following statements is not true regarding resonance structures? (a) All resonance structures must have the same number of electrons (b) Each atom in all of the resonance structures must have a complete shell of valence electrons (c) All resonance structures must have the same arrangement of atoms (d) All resonance structures must be valid Lewis structures Question 4 Which atomic orbitals overlap to form the carbon-carbon σ molecular bonding orbital of ethyne, C C? (a) C2p + C2p (b) Csp + Csp (c) Csp 2 + Csp 2 (d) Csp 3 + Csp 3 Question 5 Which of the following compounds has only 1 and 3 carbon atoms? (a) hexane (b) 2-methylpentane (c) 3-methylpentane (d) 2,3-dimethylbutane Question 6 Which of the following Newman projections does not represent 2-methylhexane? C 3 C(C 3 ) 2 3 C C 2 C 3 C 3 C 2 C 2 C 3 C 2 C 3 C 2 C 3 C 3 Question7 What is the UPAC name for the following compound? (a) cycloheptane (c) bicyclo[5.4]heptane C 2 C 2 C 2 C 3 (b) bicyclo[3.2.0]heptane (d) cyclobutylcyclopentane Question 8 Which of the following is the most stable conformation of cis- 1-isopropyl-3-methylcyclohexane? 3 C C(C 3 ) 2 C 3 C(C 3 ) 2 3 C C(C 3 ) 2 C 3 C(C 3 ) 2 Question 9 Which of the following alkanes has the highest boiling point? (a) 2,3-dimethylbutane (b) 2-methylpentane (c) 3-methylpentane (d) hexane Question 10 Which of the following statements is not true regarding the conformation of substituted cyclohexanes? (a) ring inversion of cyclohexanes between two chair conformations takes place via a boat conformation (b) substituted cyclohexanes are destabilized by 1,3-diaxial interactions (c) the boat conformation of cyclohexane is more stable than the chair conformation (d) the relative amount of two conformations of substituted cyclohexanes can be determined from the difference in strain energy Question 11 What is the approximate dihedral angle between the two chlorine atoms in the diaxial conformation of trans-1,2- dichlorocyclohexane? (a) 0 (b) 60 (c) 120 (d) 180 Question 12 Which of the following undergoes the most exothermic combustion per carbon atom? (a) cyclopropane (b) cyclobutane (c) cyclohexane (d) cycloheptane Question 13 Which of the following is the definition of a pair of enantiomers? (a) A pair of structures that are superposable mirror images of one another (b) A pair of stereoisomers that are non-superposable mirror images of one another (c) A pair of stereoisomers that are not mirror images of one another (d) A pair of stereoisomers that have equal specific rotations
3 Question 14 Which of the following statements is true? (a) All mirror images are enantiomers (b) All molecules that have stereocenter centers are chiral (c) somers that are not superposable on their mirror images are enantiomers (d) Superposable structural isomers are enantiomers Question 15 Which of the following have the S configuration? C 2 C 3 C 2 C 3 Question 19 ow much of the R enantiomer is present in 10 g of a mixture which has an enantiomeric excess of 60% of the R isomer? (a) 2 g (b) 4 g (c) 6 g (d) 8 g Question 20 A solution containing 0.2 g/ml of a pure R enantiomer in a 1 dm polarimeter rotates plane polarized light by +3. What is the specific rotation of the R isomer? (a) (b) +0.6 (c) -0.6 (d) +15 C 3 C 2 C 3 C C 3 C 2 3 C 3 (a) only 1 (b) only 2 (c) only 1 and 2 (d) 1, 2 and 3 C(C 3 ) 2 Question 21 Which of the following is the correct order of decreasing basicity (stronger base > weaker base)? (a) N 3 > MeN 2 > 2 > F (b) MeN 2 > N 3 > Me > C 4 (c) N 3 > Me 3 N > 2 > Me (d) C 3 CNa > Na > NaMe > NaNMe 2 Question 16 Which of the following Newman projections represents meso- 2,3-dibromobutane? 3 C C 3 3 C C C C 3 3 C 3 C Question 17 Which of the following structures represent the same stereoisomer? 4 Question 22 Which of the following terms describes the reactivity of boron tribromide, B 3? (a) ønsted-lowry acid and Lewis acid (b) ønsted-lowry base and Lewis base (c) Lewis acid and not a ønsted-lowry acid (d) Lewis base and not a ønsted-lowry base Question 23 What is the UPAC name of the following compound? C 3 3 C C 3 C 3 (a) bicyclo[6.2]oct-2-ene (c) bicyclo[2.2.2]-2-octene (b) bicyclo[4.4.4]oct-2-ene (d) bicyclo[2.2]-2-octene C 3 C 3 3 (a) only 1 and 2 (b) only 1 and 3 (c) only 2 and 3 (d) 1, 2 and 3 Question B 3 Question 18 ow many stereoisomers of 2-chloro-3-methylbutane, (C 3 ) 2 CCC 3, exist? Na
4 Question 25 C 3 C 3 C Question 29 Which of the following reactions of alkenes is not stereospecific? (a) bromination (treatment with 2 in C 3 ) (b) hydrogenation (treatment with 2 /Pt) (c) acid-catalyzed hydration (treatment with aqueous 2 S 4 ) (d) bromohydrin formation (treatment with 2 / 2 ) C 3 C 3 Question 30 What is the UPAC name of the following compound? Question 26 What type of reactive intermediate is formed in the reaction of an alkene with to give a bromoalkane? (a) carbocation (b) carbanion (c) radical (d) cyclic bromonium ion Question 27 What is (are) the major organic product(s) obtained from the following 2 (a) (R)-1-chloro-3-methyl-2-cyclohexene (b) (S)-1-chloro-3-methyl-2-cyclohexene (c) (R)-3-chloro-1-methylcyclohexene (d) (S)-3-chloro-1-methylcyclohexene Question 31 The reaction of methyl iodide with sodium azide, NaN 3, proceeds by an S N 2 mechanism. What is the effect of doubling the concentration of NaN 3 on the rate of the (a) the rate remains the same (b) the rate decreases by a factor of 2 (c) the rate increases by a factor of 2 (d) the rate increases by a factor of 4 1 (2R,3R)-dibromobutane 2 (2S,3S)-bibromobutane 3 meso-2,3-dibromobutane Question 32 Which of the following alkyl halides undergoes the fastest S N 2 reaction with sodium azide, NaN 3? (a) only 1 (b) only 2 (c) only 3 (d) only 1 and 2 (a) 1-fluorohexane (c) 1-bromohexane (b) 1-chlorohexane (d) 1-iodohexane Question 28 Which of the following alkenes undergoes the most exothermic hydrogenation upon treatment with 2 /Pd? Question 33 2 hν
5 Question 34 n which of the following solvents would the reaction of 1- bromobutane with sodium azide, NaN 3, proceed the fastest? (a) acetic acid (b) ethanol (c) water (d) acetonitrile Question 35 Which of the following statements is not true regarding the S N 2 reaction of (R)-2-bromobutane with sodium cyanide? (a) the reaction proceeds with inversion of configuration (b) the rate is proportional to the concentration of sodium cyanide (c) the rate is proportional to the concentration of (R)-2- bromobutane (d) the rate of the reaction is independent of the identity of the solvent Question 36 Which of the following represents the transition state of the S N 2 reaction between methyl iodide and ammonia? Question 38 What is the best choice of reagent to achieve the following transformation? (a) (c) S 2, pyridine? (b) 2, light (d), 2 Question 39 Cr 3 2 S 4, 2 (a) 1-butene, C 3 C 2 C=C 2 (b) butanal, C 3 C 2 C 2 C (c) butanone, C 3 C 2 CC 3 (d) butanoic acid, C 3 C 2 C 2 C 3 N C 3 N C Question 40 3 N C 3 N C C 3 C 2 C C 2 gs 4 2 S 4 Question 37 Which of the following energy diagrams represents the course of an exothermic S N 1 Question 41 series of reactions? energy energy C 3 C C NaN 2 2 Lindlar catalyst reaction coordinate reaction coordinate energy energy reaction coordinate reaction coordinate
6 Question 42 3 C C 3 Na C 3 C 3 3 C 3 4 C 3 Question 43 What would be the best choice of reagent(s) to perform the following transformation? C 3 Question 48 sequence of reactions? (a) 2-methylbutane (c) 3-methyl-2-butene Mg Et 2 2 (b) 3-methyl-1-butanol (d) 3-methyl-2-butanol Question 49 2 N 3 C (a) peroxyacid (b) 2, 2 ; followed by Na, 2 (c) s 4 ; followed by NaS 3 (d) 2, 2 S 4 C 3 N N 2 N N 2 Question 44 Which of the following compounds gives an infrared spectrum with peaks at 3300 cm -1 (strong, broad peak) and 1640 cm -1 (sharp, weak peak)? Question 50 C 2 2 Zn(Cu) Et 2 C 3 C 3 Question 45 What is the multiplicity of the signal in the 1 NMR spectrum for the protons of ethane? (a) singlet (b) doublet (c) triplet (d) quartet C 2 C 2 Question 46 What is the hydrogen deficiency index for a compound with a molecular formula of C 6 11 N? Question Li Et Question 47 Which of the following compounds gives a 1 NMR spectrum consisting of only two triplets and a singlet? (a) C 3 C(C 3 ) 2 (b) C 3 C 2 C 2 C 2 C 2 C 3 (c) C 3 C 2 C 2 C 3 (d) C 3 C 2 C()C 3 (a) 2-phenyl-2-butanol (c) 3-phenylbutanone (b) 3-phenyl-2-butanol (d) propiophenone, CC 2 C 3
7 Question Ag 2, Na Question 55 Which of the following has the highest K eq for enolization? Question 56 Na, 2 Δ Question 53 Which of the following statements is not true? (a) Reaction of benzophenone with methanol in the presence of acid gives a ketal (b) Reaction of butanal with ethanol in the presence of base gives an acetal (c) Reaction of benzaldehyde with ethanol in the presence of acid gives an acetal (d) Reaction of acetone with methanol in the presence of base gives a hemiketal Question 54 Which ketone-diol undergoes cyclization to form the following ketal?? Question 57 Δ Question 58 What is the approximate range of chemical shift () in the 1 NMR spectrum of the acidic proton of carboxylic acids? (a) 0-2 ppm (c) 7-8 ppm (b) 2-4 ppm (d) ppm
8 Question 59 What is the major organic product of the following sequence of reactions? Question 64 sequence of reactions? S 2 NaCN 1. LiAl RC 3 NaN 3 1. LiAl (a) propylamine (c) butanamide (b) butylamine (d) propyl formamide N 2 N 2 N 2 Question 60 Which of the following is not an intermediate in the ofmann rearrangement of octanamide to give heptanamine? (a) amide anion, RCN - (b) N-bromoamide, RCN (c) isocyanate, R-N=C= (d) imide, RCNCR N 2 Question 61 Which of the following undergoes the most rapid nitration upon treatment with N 3 / 2 S 4? (a) toluene (b) benzene (c) bromobenzene (d) nitrobenzene Question 62 What is the electrophile in the reaction of benzene with acetyl chloride, C 3 C, and Al 3? (a) C 3 C + + (b) C 3 - (c) C 3 C 2 (d) benzene Question 65 Which mechanism accounts for the reaction of 4-bromo-1- nitrobenzene with sodium hydroxide to form 4-nitrophenol? (a) Bimolecular nucleophilic substitution (S N 2) (b) Nucleophilic aromatic substitution by elimination-addition (c) Nucleophilic aromatic substitution by addition-elimination (d) Electrophilic aromatic substitution Question 66 sequence of reactions? C 3 Question 63 Al 3 Zn(g) 1. NaC 2 C 3 C 3 C 2 C 3 C 3 C 3 C 2 C 2 C 2 C 3 C 2 C C 2 C 3 C 2 C 3 C 2 C 2 C 3 C 2 C 2 C 3 C(C 3 ) C 2 C 3 C 2 C 3
9 Question 67 sequence of reactions? 1. NaC 2 C 3 C 3 C 2 1. Na, 2 C 2 C Δ 1 2 Question 68 What is the thermodynamic product obtained from the addition of 1 mole of bromine to 1,3-butadiene? (a) 3,4-dibromo-1-butene (b) (E)-1,4-dibromo-2-butene (c) (Z)-1,4-dibromo-2-butene (d) (Z)-2,3-dibromo-2-butene Question 69 What range of wavelengths corresponds to the ultraviolet region of the electromagnetic spectrum? (a) nm (b) nm (c) μm (d) 2-10 mm Question 70 Δ
CHEM 2312 practice final. Version - II
EM 2312 practice final Version - II The following standardized final examination covers the entire introductory year of organic chemistry (EM 2311 and 2312 at Georgia Tech). The exam consists of 70 multiple
More informationCHEM 2311 HW1. COMPLETELY FILL THE BOXES IN DARK PENCIL, i.e.:, NOT or or STRUCTURE
EM 2311 W1 Provide answers to the following multiple choice questions on the Scantron form provided in lecture. Make sure that you put your name and bubble in your GTID # on the answer form. MPLETELY FILL
More information2. Which functional groups and structural features are present in the following molecule (strychnine)?
Chapter 1-2: 1. Which of the following species has a negative charge but NO lone pair of valance shell nonbonding electrons? [all atoms have complete valance shell of electrons, but lone pairs are not
More informationCHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Text Sections (N0 1.9, 9-11) Homework: Chapter 1:
CHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Atomic Structure - Valence Electrons Chemical Bonds: The Octet Rule - Ionic bond - Covalent bond How to write Lewis
More information1. What are the respective hybridizations of the atoms numbered 1 to 4 in this compound?
EM 331: hapter 1/2: Structures (Atoms, Molecules, Bonding) 1. What are the respective hybridizations of the atoms numbered 1 to 4 in this compound? N 2 N 2 N 1 2 3 4 2. What hybrid orbitals are used to
More information1. What are the respective hybridizations of the atoms numbered 1 to 4 in this compound?
CEM 331: Chapter 1/2: Structures (Atoms, Molecules, Bonding) 1. What are the respective hybridizations of the atoms numbered 1 to 4 in this compound? N C 2 C N C 2 C N 1 2 3 4 1: three sigma bonds and
More informationREVIEW PROBLEMS Key. 1. Draw a complete orbital picture for the molecule shown below. Is this molecule chiral? Explain. H H.
rganic hemistry II (E325) REVIEW PRBLEMS Key 1. Draw a complete orbital picture for the molecule shown below. Is this molecule chiral? Explain. 3 3 sp3 orbital p orbital sp2 orbital s orbital molecule
More informationN_HW1 N_HW1. 1. What is the purpose of the H 2 O in this sequence?
N_HW1 N_HW1 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. 1. What is the purpose of the H 2 O in this
More information1. What is the letter designation given to dumbbell shaped orbitals like the one depicted below?
1. What is the letter designation given to dumbbell shaped orbitals like the one depicted below? 2. Which of the following does not have an octet of electrons surrounding the central atom? A. B 3 B. C
More informationCH Organic Chemistry I (Katz) Practice Exam #3- Fall 2013
C2710 - rganic Chemistry I (Katz) Practice Exam #3- all 2013 Name: Score: Part I - Choose the best answer and write the letter of your choice in the space provided. (32 pts) 1. f the following, which reaction
More informationHyperlearning MCAT Instructor Qualifying Exam Organic Chemistry
Hyperlearning MCAT Instructor Qualifying Exam Organic Chemistry 30 Questions (5 pages); Time limit = 45 minutes Use of books or notes is not permitted. 1. When analyzed with a polarimeter, which of the
More informationCHEM120 - ORGANIC CHEMISTRY WORKSHEET 1
EM120 - RGANI EMISTRY WRKSEET 1 Some of the objectives To understand and know the hybridization concept Be able to distinguish different geometries, including basic bond lengths and angles within organic
More informationCHE1502. Tutorial letter 203/1/2016. General Chemistry 1B. Semester 1. Department of Chemistry
E1502/203/1/2016 Tutorial letter 203/1/2016 General hemistry 1B E1502 Semester 1 Department of hemistry This tutorial letter contains the answers to the questions in assignment 3. FIRST SEMESTER: KEY T
More informationHomework problems Chapters 6 and Give the curved-arrow formalism for the following reaction: CH 3 OH + H 2 C CH +
omework problems hapters 6 and 7 1. Give the curved-arrow formalism for the following reaction: : 3 - : 2 : 3 2-3 3 2. In each of the following sets, arrange the compounds in order of decreasing pka and
More information2. Which one of the following structures represents a different compound from the other three?
1. Provide a Newman projection of the most stable conformation of 2-methylpentane, (CH 3 ) 2 CHCH 2 CH 2 CH 3, looking along the C2-C3 bond 2. Which one of the following structures represents a different
More informationSECTION-I (SINGLE CORRECT CHOICE)
SECTI-I (SIGLE CRRECT CICE) 1. Which of the following phrases are not correctly associated with an S1 reaction? 1. Rearrangement is possible. 2. Rate is affected by solvent polarity. 3. The strength of
More informationCH 320/328 N Summer II 2018
CH 320/328 N Summer II 2018 HW 1 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. (5 pts each) 1. Which
More informationDetailed Course Content
Detailed Course Content Chapter 1: Carbon Compounds and Chemical Bonds The Structural Theory of Organic Chemistry 4 Chemical Bonds: The Octet Rule 6 Lewis Structures 8 Formal Charge 11 Resonance 14 Quantum
More informationA. B. C. D. 2. Which compound does not give a stable Grignard reagent when reacting with Mg metal?
Practice Test, Chemistry 2220 Final Exam 1. Which structure has the MST signals for its proton NMR? 2. Which compound does not give a stable Grignard reagent when reacting with Mg metal? 3. Which of these
More informationAs time allows, additional practice questions for Exam 2 follow. This is an incomplete collection. Content & emphasis will vary.
Chem 226 Exam 2 Fall 2005: will cover Bruice, Chaps 3 through 6; Note: review e-mail & inclass quizzes and Worksheets, suggest on-line practice questions and quizzes plus ACS rganic Chemistry Guide As
More informationHalo Alkanes and Halo Arenes
alo Alkanes and alo Arenes Short Answer Questions: **1. Write the isomers of the compound having formula C 4 9 Br? Sol. There are five isomers of C 4 9 Br. These are: 2-bromobutane is expected to exhibit
More informationChapter 7 Cyclic Compounds. Stereochemistry of Reactions
Instructor Supplemental Solutions to Problems 2010 Roberts and Company Publishers Chapter 7 Cyclic Compounds. Stereochemistry of Reactions Solutions to In-Text Problems 7.3 Following the procedure in the
More information1) (100 pts) 5) (20 pts) 3) (35 pts) 4) (25pts. Total (200 pts) More Tutorial at
Name: Perm number: Question 1) (100 pts) 2) (20 pts) 3) (35 pts) 4) (25pts 5) (20 pts) Total (200 pts) Your score 1. MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers
More informationCHE1502. Tutorial letter 201/1/2016. General Chemistry 1B. Semester 1. Department of Chemistry CHE1502/201/1/2016
CE1502/201/1/2016 Tutorial letter 201/1/2016 General Chemistry 1B CE1502 Semester 1 Department of Chemistry This tutorial letter contains the answers to the questions in assignment 1. FIRST SEMESTER: KEY
More informationChemistry 2541, Fall 2017 Midterm Exam 2 (100 points)
Chemistry 2541, Fall 2017 Midterm Exam 2 (100 points) Important notes: - Please use the provided Scantron form for your answers; you can keep the sheet with the questions and can use it as scratch paper
More informationtrans-cyclooctene 4-fluoro-1-butanol 2-cyclohexenol 4. (5 pts) Provide structural formula for each of the following molecules: Br OH Cl OH
CEMISTRY 313-01 MIDTERM # 2 answer key March 12, 2009 Statistics: Average: 72 pts (72%); ighest: 98 pts (98%); Lowest: 21 pts (21%) umber of students performing at or above average: 22 (50%) umber of students
More informationChapter 17 Reactions of Aromatic Compounds. Electrophilic Aromatic Substitution
Chapter 17 Reactions of Aromatic Compounds Electrophilic Aromatic Substitution Electrophile substitutes for a hydrogen on the benzene ring. Chapter 17: Aromatics 2-Reactions Slide 17-2 1 Mechanism Step
More informationST. JOSEPH S COLLEGE OF ARTS & SCIENCE (AUTONOMOUS) ST. JOSEPH S COLLEGE ROAD, CUDDALORE CH101T ORGANIC CHEMISTRY I (SEMESTER-I)
UNIT I 1. The hybridization involved in the formation of acetylene is a) sp b) sp 2 c) sp 3 d) sp 3 d 2. The IUPAC name of is 1. 3-hexene b) 4-hexene c) 3-hexyne d) 4-hexyne 3. -------- is the type of
More informationCHEMISTRY 341. Final Exam Tuesday, December 16, Problem 1 15 pts Problem 9 8 pts. Problem 2 5 pts Problem pts
CEMISTRY 341 Final Exam Tuesday, December 16, 1997 Name NAID Problem 1 15 pts Problem 9 8 pts Problem 2 5 pts Problem 10 21 pts Problem 3 26 pts Problem 11 15 pts Problem 4 10 pts Problem 12 6 pts Problem
More informationHomework - Review of Chem 2310
omework - Review of Chem 2310 Chapter 1 - Atoms and Molecules Name 1. What is organic chemistry? 2. Why is there an entire one year course devoted to the study of organic compounds? 3. Give 4 examples
More information75. A This is a Markovnikov addition reaction. In these reactions, the pielectrons in the alkene act as a nucleophile. The strongest electrophile will
71. B SN2 stands for substitution nucleophilic bimolecular. This means that there is a bimolecular rate-determining step. Therefore, the reaction will follow second-order kinetics based on the collision
More information(CH 3 ) 3 COH. CH 3 ONa
1. Rank the following compounds in the trend requested. (15 points each) a. Rank by nucleophilicity. The strongest nucleophile is 1, while the weakest nucleophile is 5. C 3 PNa (C 3 ) 3 C C 3 Na C 3 C
More informationCHEM Exam 2 October 25, 2007
CEM 3311-200 Exam 2 October 25, 2007 By printing my name below, I pledge that "On my honor, as a University of Colorado at Boulder student, I have neither given nor received unauthorized assistance on
More informationTHE UNIVERSITY OF CALGARY FACULTY OF SCIENCE FINAL EXAMINATION CHEMISTRY 351 READ ALL THE INSTRUCTIONS CAREFULLY
TE UNIVERSITY F CALGARY FACULTY F SCIENCE FINAL EXAMINATIN CEMISTRY 351 DECEMBER 22nd 1999 Time: 3 ours READ ALL TE INSTRUCTINS CAREFULLY PLEASE WRITE YUR NAME, STUDENT I.D. NUMBER N BT YUR EXAM ANSWER
More informationCHEM 203. Final Exam December 15, 2010 ANSWERS. This a closed-notes, closed-book exam. You may use your set of molecular models
CEM 203 Final Exam December 15, 2010 Your name: ANSWERS This a closed-notes, closed-book exam You may use your set of molecular models This test contains 15 pages Time: 2h 30 min 1. / 16 2. / 15 3. / 24
More informationI. Multiple Choice Questions (Type-I)
Unit 13 HYDROCARBONS I. Multiple Choice Questions (Type-I) 1. Arrange the following in decreasing order of their boiling points. (A) n butane (B) 2 methylbutane (C) n-pentane (D) 2,2 dimethylpropane A
More informationName: Student Number:
Page 1 of 5 Name: Student Number: l University of Manitoba - Department of Chemistry CEM 2220 - Introductory rganic Chemistry II - Term Test 1 Thursday, February 14, 2008 This is a 2-hour test, marked
More information16.1 Draw Newman projections for these staggered and three eclipsed conformations of 1, 2 - dichlorobutane as viewed downt he central C-C bond.
CAPTER 16 Practice Exercises 16.1 Draw Newman projections for these staggered and three eclipsed conformations of 1, 2 - dichlorobutane as viewed downt he central C-C bond. 16.3 (a) The more stable conformation
More informationChemistry M11 Spring 2010 Examination #3 ANSWER KEY pp. 1
Chemistry M11 Spring 2010 Examination #3 ASWER KEY pp. 1 or Questions 1 2, consider the hydrogenation of trans-3-methyl-2-pentene in the presence of a transition metal catalyst. 1. C Determine the major
More informationChapter 17 Reactions of Aromatic Compounds
rganic Chemistry, 6 th Edition L. G. Wade, Jr. Chapter 17 Reactions of Aromatic Compounds Jo Blackburn Richland College, Dallas, TX Dallas County Community College District 2006, Prentice all Electrophilic
More informationChemistry Fall Semester 2007; Midterm 3 Exam
1 Chemistry 2521 Fall Semester 2007; Midterm 3 Exam December 7, Friday, 1:00 to 1:50 pm This exam has 7 problems (100 pts) on 9 pages. Make sure your copy is complete and correct. Printed Name (Last, First)
More informationFinal Exam CHM1321-B. Date: April 19 Length: 3 hrs Last Name: Professor Sandro Gambarotta Name:
Faculté des sciences Faculty of Science Département de chimie et science biomoléculaire Department of Chemistry and Biomolecular Sciences Pavillon d Iorio Hall 10 Marie-Curie Ottawa ON Canada K1N 6N5 '
More informationOrganic Chemistry Worksheets
Highlight the single longest, continuous carbon-carbon chain. Note the alkyl branches that are connected to the root chain. Count the carbons in the root chain, starting from the end closest to the alkyl
More informationDepartmental Final Examination. Organic Chemistry I Caffein
Departmental Final Examination rganic Chemistry I 2423 Caffein Name CEMISTRY 2423 FINAL EXAM FALL, 2005 DIRECTINS: A periodic table is attached at the end of this exam. Please answer all questions as completely
More informationDepartment of Chemistry SUNY/Oneonta. Chem Organic Chemistry I
Department of Chemistry SUNY/Oneonta Chem 221 - Organic Chemistry I Examination #4 - ANSWERS - December 11, 2000 Answer to question #32 corrected 12/13/00, 8:30pm. INSTRUCTIONS This examination is in multiple
More informationChem 232. Problem Set 9. Question 1. D. J. Wardrop
Chem 232 D. J. Wardrop wardropd@uic.edu Problem Set 9 Question 1. a. Rank in order of increasing number of chirality centers (1 = fewest chirality centers; 5 = most chirality). 3 C C 3 b. Rank in order
More information1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES. Vikasana - CET 2012
CET OBJECTIVE QUESTION ON 1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES 1.The inductive effect a. Implies the atoms ability to cause
More informationChemistry 261 Exam 2 Practice Fall 2017
Chemistry 261 Exam 2 Practice Fall 2017 The following practice examination contains 30 questions valued at 3 point/question unless otherwise noted. Wednesday s exam will also contain 30 questions, with
More informationOCH 2 CH 3. A) 2-chlorohexyl ethanoate C) ethyl 2-chlorohexanoate B) 1-chlorohexyl ethanoate D) ethyl 1-chlorohexanoate
(2 points each) Write your answer in the box to the right of the question. 1. A mixture of 1-hexanol and hexanoic acid in diethyl ether is shaken with an aqueous sodium bicarbonate solution. Which line
More information17.3 REACTIONS INVOLVING ALLYLIC AND BENZYLIC ANIONS
798 HAPTER 17 ALLYLI AND BENZYLI REATIVITY Because the unpaired electron is shared by two different carbons, this radical can react in the final propagation step to give two different products. Reaction
More informationChemistry 233 Exam 3 (Green) The Periodic Table
Name: Last First MI Chemistry Exam (Green) Summer 7 Dr. J. sbourn Instructions: The first questions of this exam should be answered on the provided Scantron. You must use a pencil for filling in the Scantron
More information1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES. Vikasana - CET 2012
CET OBJECTIVE QUESTION ON 1. CONCEPTS IN ORGANIC CHEMISTRY 2. SYNTHETIC ORGANIC CHEMISTRY 3. ISOMERISM II 4. HYDROCARBONS II 5. HALOALKANES 1.The inductive effect a. Implies the atoms ability to cause
More informationStudy Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner?
Study Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner? A) They are isotopes B) They are constitutional isomers C) They are the same structure D) They are composed
More informationOrganic Chemistry 1 CHM 2210 Exam 4 (December 10, 2001)
Exam 4 (December 10, 2001) Name (print): Signature: Student ID Number: There are 12 multiple choice problems (4 points each) on this exam. Record the answers to the multiple choice questions on THIS PAGE.
More informationCHE 325 ALDEHYDES AND KETONES I CHAP 18 ASSIGN OCH 3 HCN C 4 H 7 NO. would be: CH 3 B. CH 3CH 2COOCH 3
CE 325 ALDEYDES AND KETNES I CAP 18 ASSIGN 1. What is the correct IUPAC name for the following compound A. 2-Methyl-5-heptanone B. 7-Methyl-4-octanone C. 6-Isopropyl-4-octanone D. Isobutyl propyl ketone
More informationSTRUCTURE. Dr. Sheppard CHEM 2411 Spring 2015
STRUCTURE Dr. Sheppard CHEM 2411 Spring 2015 Klein (2nd ed.) sections 1.8-1.10, 1.12-1.13, 2.7-2.12, 3.2, 3.4-3.5, 3.8-3.9, 4.6-4.13, 4.14, 8.5, 15.16, 21.3 Topics Structure Physical Properties Hybridization
More informationChapter 2: Alkanes MULTIPLE CHOICE
Chapter 2: Alkanes MULTIPLE CHOICE 1. Which of the following orbitals is properly described as an antibonding orbital? a. sp + 1s d. sp 2 1s b. sp 2 + 1s e. sp 2 + sp 2 sp 3 + 1s D DIF: Easy REF: 2.2 2.
More information1. Which of the following compounds is the weakest base?
I. Multiple-choice Questions Fall 2018 1. Which of the following compounds is the weakest base? a. C3C2 b. C3C2 c. N3 d. C3 e. N2 2. Which of the following functional groups is indicated by a strong and
More informationCHEMISTRY 241 Section 004 EXAMINATION I TUESDAY, October 11, :30-11:50 AM Professor William P. Dailey NAME: QUESTIONS POINTS SCORE
CEMISTRY 241 Section 004 EXAMIATI I TUESDAY, ctober 11, 2005 10:30-11:50 AM Professor William P. Dailey AME: Student ID number : QUESTIS PITS SCRE 1. 16 2. 10 3. 12 4. 12 5. 12 6. 8 7. 9 8. 9 9. 15 10.
More information1. Name the following two compounds [8 pts]. Where it is important, points are explicitly allocated for stereochemistry.
1. Name the following two compounds [8 pts]. Where it is important, points are explicitly allocated for stereochemistry. 2. raw the structures of the following two compounds [8 pts]. cis-1-bromo-2,2-dimethyl-4-octene.
More informationChemistry 210 Organic Chemistry I Fall Semester 2000 Dr. Rainer Glaser
Chemistry 210 Organic Chemistry I Fall Semester 2000 Dr. Rainer Glaser Examination #3 Alkenes and Alkynes. Structure, Synthesis and Reactions. Friday, November 17, 2000, 9:00-9:50 Name: Question 1. Alkenes
More informationChapter Organic Chemistry Basics
29 Chapter Organic Chemistry Basics 2. A similarity between optical and geometrical isomerism is that [2002] (a) each forms equal number of isomers for a given compound (b) if in a compound one is present
More informationOChem1 Old Exams. Chemistry 3719 Practice Exams
OChem1 Old Exams Chemistry 3719 Practice Exams Fall 2017 Chemistry 3719 Practice Exam A1 This exam is worth 100 points out of a total of 600 points for Chemistry 3719/3719L. You have 50 minutes to complete
More informationPractice Multiple-Choice Questions for Ending Chem 21 and/or Starting Chem 22
Practice Multiple-Choice Questions for Ending Chem 21 and/or Starting Chem 22 Includes information from chapters 5-10 of the third edition of Klein s Organic Chemistry text. 1. Which of the following compounds
More informationI C(CH 3 ) 3. (c)2ch 3 OH+(CH 3 ) 3 CCl (CH 3 ) 3 COCH 3 +CH 3 OH + 2 +Cl - (d) CH 3 CH 2 CH 2 Br+NaCN CH 3 CH 2 CH 2 CN+NaBr
6.1 Writer the following as net ionic reactions and designate the nucleophile, substrate, and leaving group in each reaction. (a) 3 + 3 2 Na 3 2 3 +Na (b) Na+ 3 2 3 2 +Na (c) 2 3 +( 3 ) 3 ( 3 ) 3 3 + 3
More informationChemistry 210 Organic Chemistry I Summer Semester 1999 Dr. Somnath Sarkar
Chemistry 210 rganic Chemistry I Summer Semester 1999 Dr. Somnath Sarkar Final Examination Name: Thursday, July 29, 1999, 6:30 8:30 Question 1 Stereochemistry(MC#1) 16 Question 2. Substitution(MC #2) 16
More informationChapter 8 Alkenes and Alkynes II: Addition Reactions "
Chapter 8 Alkenes and Alkynes II: Addition Reactions Additions to Alkenes Generally the reaction is exothermic because one π and one σ bond are converted to two σ bonds Alkenes are electron rich The π
More informationStudy Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner?
Study Union: CHM 2210 Final Exam Review 1. The following molecules are related in what manner? A) They are isotopes B) They are constitutional isomers C) They are the same structure D) They are composed
More informationCHEM 241 ALKANES AND CYCLOALKANES CHAP 3 ASSIGN H H
CEM 241 ALKANES AND CYCLOALKANES CAP 3 ASSIGN COMFORMATIONS AND cis-trans STEREOISOMERS 1. trans-1,2-dibromocyclohexane is represented by structure(s): D. II and III E. I and II 2. cis-1,3-dibromocyclohexane
More informationALDEHYDES AND KETONES
CE 325 ALDEYDES AND KETNES CAP 17 ASSGN NUCLEPLC ADDTN T TE CARBNYL GRUP 1. What is the correct UPAC name for the following compound A. 2-Methyl-5-heptanone B. 7-Methyl-4-octanone C. 6-sopropyl-4-octanone
More informationCHAPTER 15. Practice exercises 15.1
CAPTER 15 Practice exercises 15.1 15.3 (a) C 9 18 : isobutylcyclopentane C 11 22 : sec-butylcycloheptane C 6 2 : 1-ethyl-1-methylcyclopropane 15.5 (a) 3,3-dimethyl-1-pentene 2,3-dimethyl-2-butene 3,3-dimethyl-1-butyne
More information1. What is the major organic product obtained from the following sequence of reactions?
CH320 N N_HW1 Multiple Choice Identify the choice that best completes the statement or answers the question. There is only one correct response for each question. Carefully record your answers on the Scantron
More informationOrganic Halogen Compounds
8 Organic alogen ompounds APTER SUMMARY 8.1 Introduction Although organic halogen compounds are rarely found in nature, they do have a variety of commercial applications including use as insecticides,
More informationTopic 9. Aldehydes & Ketones
Chemistry 2213a Fall 2012 Western University Topic 9. Aldehydes & Ketones A. Structure and Nomenclature The carbonyl group is present in aldehydes and ketones and is the most important group in bio-organic
More informationChemistry 210 Organic Chemistry I Summer Semester 1999 Dr. Somnath Sarkar
Chemistry 210 Organic Chemistry I Summer Semester 1999 Dr. Somnath Sarkar Examination #3 Elimination Reactions Structure, Synthesis and Reactions of Alkenes and alkynes. Friday, July 23, 1999, 8:40 9:40
More informationCHEMISTRY 31 Name: KEY Exam #1 100 pts 1. (6 pts) Provide the complete IUPAC name for each of the following compounds:
CEMISTRY 31 ame: KEY Exam #1 100 pts 1. (6 pts) Provide the complete IUPAC name for each of the following compounds: (1S,3S)-1-bromo-3-butylcyclopentane 3,4-diethyl-2,2-dimethyloctane 1-cyclopropyl-2-methylcyclobutane
More informationD) u.ltraviolet light. B) 2,3-pentadiene. B) a 1:l mixture of enantiomeric epoxides. D) a 1:l mixture of enantiomeric diols
1) In the UV-visible spectrum of (El-1,3,5-hexatriene, the lowest energy absorption corresponds to: A) a o to n transition. B) a o to n* transition. C) a rc to o* transition. D) a o to a* transition. E)
More informationChemistry 3351 Organic Chemistry/Final Exam Monday: Dec. 17 th from 1:30 pm 4:00pm
- 1 - Chemistry 3351 Organic Chemistry/Final Exam Monday: Dec. 17 th from 1:30 pm 4:00pm Name: (please print, 1 pt) Page Possible Points Score 1 1 2 9 3 10 4 12 5 14 6 14 7 10 8 15 9 10 10 10 11 10 12
More informationIB Topics 10, 20 & 21 MC Practice
IB Topics 10, 20 & 21 MC Practice 1. What is the major product of the reaction between HCl and but-2-ene? 1,2-dichlorobutane 2,3-dichlorobutane 1-chlorobutane 2-chlorobutane 2. Which compound can be oxidized
More informationTCHM 232. Organic Chemistry
TM 232 rganic hemistry حل الامتحان KEY Final Exam Review Questions Examples of the types of questions you can expect to see on the final 1. The IUPA name for the formula 2 2 = 2 is 1. 5-hexene-3-ol 2.
More informationFOURTH EXAMINATION. (1)..20 pts... (2)..24 pts... (3)..18 pts... (4)..12 pts... (5)..12 pts... (6).. 6 pts... (7).. 8 pts... Bonus 4 pts...
Name: CHEM 331 FURTH EXAMINATIN All answers should be written on the exam in the spaces provided. Clearly indicate your answers in the spaces provided; if I have to guess as to what or where your answer
More information8. What is the slow, rate-determining step, in the acidcatalyzed dehydration of 2-methyl-2-propanol?
CHEMISTRY 313-03 MIDTERM # 2 answer key October 25, 2011 Statistics: Average: 68 pts (68%); Highest: 100 pts (100%); Lowest: 30 pts (30%) Number of students performing at or above average: 56 (54%) Number
More informationOrganic Chemistry: Structure and Reactivity Tutorial Six Question 1
en Mills, University of istol, 4 March 2008 rganic Chemistry: Structure and Reactivity Tutorial Six Question 1 ydrobromination of styrene hydrogen adds to the terminal carbon, so that the carbocation can
More informationCH 3. mirror plane. CH c d
CAPTER 20 Practice Exercises 20.1 The index of hydrogen deficiency is two. The structural possibilities include two double bonds, a double do 20.3 (a) As this is an alkane, it contains only C and and has
More informationDepartment of Chemistry SUNY/Oneonta. Chem Organic Chemistry I. Examination #4 - December 9, 2002 ANSWERS
INSTRUCTINS Department of Chemistry SUNY/neonta Chem 221 - rganic Chemistry I Examination #4 - December 9, 2002 ANSWERS This examination is in multiple choice format; the questions are in this Exam Booklet
More informationChapter 3. Conformations of Alkanes and Cycloalkanes
Spartan: Molecules, Figures, Problems. The structures in bold face type have potential surfaces enabled. The structures in regular type do not have potential surfaces enabled. Chapter 1. Bonding Figure
More informationChapter 9 Alkynes. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Chapter 9 Alkynes Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. 9.1 Sources of Alkynes Acetylene Industrial preparation of acetylene is by dehydrogenation of
More information2.339 Practice Problems
2.339 Practice Problems Basics of Structure and Mechanism 1. What is the expected site of protonation in an enol ether (C=C)? Justify your choice using resonance structures. 2. ank the following molecules
More informationCHEMISTRY MIDTERM # 1 answer key October 05, 2010
CEMISTRY 313-03 MIDTERM # 1 answer key ctober 05, 2010 Statistics: Average: 73 pts (73%); ighest: 99 pts (99%); Lowest: 31 pts (31%) Number of students performing at or above average: 61 (52%) Number of
More informationHomework - Chapter 9 Chem 2310
Homework - Chapter 9 Chem 2310 me:. ntroduction to organic halides 1. Draw a line structure for a compound with the following description: an alkyl halide with the formula C 5 H 11 a vinyl halide with
More informationName: Student Number: University of Manitoba - Department of Chemistry CHEM Introductory Organic Chemistry II - Term Test 1
Name: Student Number: University of Manitoba - Department of Chemistry CEM 2220 - Introductory Organic Chemistry II - Term Test 1 Thursday, February 13, 2014; 7-9 PM This is a 2-hour test, marked out of
More information12. Aldehydes & Ketones (text )
2009, Department of Chemistry, The University of Western ntario 12.1 12. Aldehydes & Ketones (text 13.1 13.11) A. Structure and Nomenclature The carbonyl group is present in aldehydes and ketones and is
More informationNuggets of Knowledge for Chapter 17 Dienes and Aromaticity Chem 2320
Nuggets of Knowledge for Chapter 17 Dienes and Aromaticity Chem 2320 I. Isolated, cumulated, and conjugated dienes A diene is any compound with two or C=C's is a diene. Compounds containing more than two
More informationPage 1 of 9. Sessional Examination (November 2017) Max Marks: 20 Date: Time: One Hour. Model Answers
Page 1 of 9 Sessional Examination (November 2017) Class: B. Pharm-II yr (III sem) Subject: Pharma Org. Chem-II Max Marks: 20 Date: 14.11.2017 Time: One Hour Model Answers Q. 1. Solve the following (ANY
More informationB. A transition state represents a maximum on the reaction path diagram and can be isolated.
Practice Hour Exam 2, Chemistry 2210, Organic Chemistry I 1. The most stable carbocation is: 2. Which of the following statements is true of transition states? A. A transition state represents a minimum
More informationNucleophilic Substitution & Elimination Chemistry 1
ucleophilic Substitution & Elimination hemistry 1 What kind of mechanisms are possible? What is the major mechanism occuring? Write in ALL mechanism details (lone pairs, formal charge, curved arrows, etc.).
More informationIntroduction & Definitions Catalytic Hydrogenations Dissolving Metal Reduction Reduction by Addition of H- and H+ Oxidation of Alcohols Oxidation of
CEM 241- UNIT 4 xidation/reduction Reactions Redox chemistry 1 utline Introduction & Definitions Catalytic ydrogenations Dissolving Metal Reduction Reduction by Addition of - and + xidation of Alcohols
More informationCHEMISTRY Statistics: 74 pts (74%) 94 pts (94%) 34 pts (34%) 26 (55%) 5 (11%)
CEMISTRY 314-01 MITERM # 1 answer key bruary 06, 2007 Statistics: Average: 74 pts (74%) ighest: 94 pts (94%) Lowest: 34 pts (34%) Number of students performing at or above average: 26 (55%) Number of students
More informationCHEMISTRY MIDTERM # 3 March 31, The total number of points in this midterm is 100. The total exam time is 120 min (2 h). Good luck!
Name: CEMISTRY 1-01 MIDTERM # March 1, 2009 The total number of points in this midterm is 100. The total exam time is 120 min (2 h). Good luck! 1. (11 pts) Mark as true (T) false (F) the following statements.
More informationSYNTHETIC ORGANIC CHEMISTRY
SYNTHETIC ORGANIC CHEMISTRY 1. The credit for synthesizing first organic compound in the laboratory went to a) Berzelius b) Wohler c) Kolbe d) Berthelot Ans : b) Wohler [Note : (i) N H 4 Cl+KCNO NH 4 CNO
More information