Chapter Organic Chemistry Basics
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1 29 Chapter Organic Chemistry Basics 2. A similarity between optical and geometrical isomerism is that [2002] (a) each forms equal number of isomers for a given compound (b) if in a compound one is present then so is the other (c) both are included in stereoisomerism (d)they have no similarity. 3. Which of the following does not show geometrical isomerism? [2002] (a) 1,2-dichloro-1-pentene (b) 1,3-dichloro-2-pentene (c) 1,1-dichloro-1-pentene (d) 1,4-dichloro-2-pentene 7. In which of the following species is the underlined carbon having sp 3 hybridisation? [2002] (a) CH3 COOH (b) CH3 CH2 OH (c) CH3 COCH3 (d) CH2 = CH CH3 8. Racemic mixture is formed by mixing two [2002] (a) isomeric compounds (b) chiral compounds (c) meso compounds (d)enantiomers with chiral carbon. 4. The functional group, which is found in amino acid is [2002] (a) COOH group (b) NH2 group (c) CH3 group (d) both (a) and (b). 9. [2002] (a) chain isomerism (b) position isomerism (c) conformers (d) stereoisomerism 5. Which of the following compounds has wrong IUPAC name? [2002] 10. [2002] (a) elimination reaction (b) substitution reaction (c) free radical reaction (d)displacement reaction. 6. The IUPAC name of CH3COCH(CH3)2 is [2003] (a) 2-methyl-3-butanone (b) 4-methylisopropyl ketone (c) 3-methyl-2-butanone (d) Isopropylmethyl ketone 11. In the anion HCOO the two carbon-oxygen bonds are found to be of equal length. what is the reason for it? [2003] (a) The C = O bond is weaker than the C O bond (b) The anion HCOO has two resonating structures (c) The anion is obtained by removal of a proton from the acid molecule (d) Electronic orbitals of carbon atom are hybridised 12. The general formula CnH2nO2 could be for open chain [2003] (a) carboxylic acids (b) diols (c) dialdehydes (d) diketones
![30 17. Which of the following will have a mesoisomer also? [2004] (a) 2, 3- Dichloropentane (b) 2, 3-Dichlorobutane (c) 2-Chlorobutane (d) 2-Hydroxypropanoic acid 13.](/docs-images/90/101377768/images/2-1.jpg "[2003] (a) only I and II are chiral compounds (b) only III is a chiral compound (c) only II and IV are chiral compounds (d) all four are chiral compounds 18.")
2 Which of the following will have a mesoisomer also? [2004] (a) 2, 3- Dichloropentane (b) 2, 3-Dichlorobutane (c) 2-Chlorobutane (d) 2-Hydroxypropanoic acid 13. [2003] (a) only I and II are chiral compounds (b) only III is a chiral compound (c) only II and IV are chiral compounds (d) all four are chiral compounds 18. [2004] (a) OC2H5 (b) NH2 (c) Cl (d) OCOCH3 14. Which one of the following has the minimum boiling point? [2004] (a) 1 - Butene (b) 1 - Butyne (c) n- Butane (d) isobutane 19. Amongst the following compounds, the optically active alkane having lowest molecular mass is [2004] 15. [2004] (a) 3, 3-dimethyl - 1- cyclohexanol (b) 1, 1-dimethyl-3-hydroxy cyclohexane (c) 3, 3-dimethyl -1 -hydroxy cyclohexane (d) 1, 1-dimethyl-3-cyclohexanol 20. Consider the acidity of the carboxylic acids: (a) PhCOOH (b) o-no2c6h4cooh (c) p-no2c6h4cooh (d) m-no2c6h4cooh Which of the following order is correct? [2004] (a) 2 > 4 > 1 > 3 (b) 2 > 4 > 3 > 1 (c) 1 > 2 > 3 > 4 (d) 2 > 3 > 4 > Which of the following is the strongest base? 16. Which one of the following does not have sp 2 hybridized carbon? [2004] (a) Acetonitrile (b) Acetic acid (c) Acetone (d) Acetamide
3 Which of the following compounds is not chiral? [2004] (a) 1-chloro-2-methyl pentane (b) 2-chloropentane (c) 1-chloropentane (d) 3-chloro-2-methyl pentane 26. [2006] (a) 3-bromo -1 -chlorocyclohexene (b) 1-bromo-3-chlorocyclohexene (c) 2-bromo-6-chlorocyclohex -1 -ene (d) 6-bromo-2-chlorocyclohexene 23. Due to the presence of an unpaired electron, free radicals are: [2005] (a) cations (b) anions (c) chemically inactive (d) chemically reactive 27. The increasing order of stability of the following free radicals is [2006] [2005] (a) (C), (B), (A), (D) (b) (B), (C), (A), (D) (c) (D), (C), (B), (A) (d) (A), (B), (C), (D) [2006] (a) A > B > C > D (b) B > D > C > A (c) D > C > A > B (d) D > C > B > A [2005] (a) OCOR (b) OC2H5 (c) NH2 (d) Cl [2006]
4 Increasing order of stability among the three main conformations (i.e. Eclipse, Anti, Gauche) of 2- fluoroethanol is [2006] (a) Eclipse, Anti, Gauche (b) Anti, Gauche, Eclipse (c) Eclipse, Gauche, Anti (d) Gauche, Eclipse, Anti 31. [2007] (a) 3-ethyl-4-4-dimethylheptane (b) 1, 1-diethyl-2,2-dimethylpentane (c) 4, 4-dimethyl-5,5-diethylpentane (d) 5, 5-diethyl-4,4-dimethylpentane. 34. Which one of the following conformations of cyclohexane is chiral? [2007] (a) Boat (b) Twist boat (c) Rigid (d) Chair. 35. [2008] (a) S, S (b) R, R (b) R, S (c) S, R 36. The electrophile, E attacks the benzene ring to generate the intermediate σ-complex. Of the following, which σ-complex is lowest energy? [2008] 32. Which of the following molecules is expected to rotate the plane of plane-polarised light? [2007] 33. Presence of a nitro group in a benzene ring [2007] (a) deactivates the ring towards electrophilic substitution (b) activates the ring towards electrophilic substitution (c) renders the ring basic (d)deactivates the ring towards nucleophilic substitution. 37. The correct decreasing order of priority for the functional groups of organic compounds in the IUPAC system of nomenclature is [2008] (a) COOH, SO3H, CONH2, CHO (b) SO3H, COOH, CONH2, CHO (c) CHO, COOH, SO3H, CONH2 (d) CONH2, CHO, SO3H, COOH 38. The IUPAC name of neopentane is [2009] (a) 2, 2 dimethylpropane
![33 (b) 2 methylpropane (c) 2, 2 dimethylbutane (d) 2- methylbutane 39. 44. Identify the compound that exhibits tautomerism: [2011] (a) 2-Butene (b) Lactic acid (c) 2-Pentanone (d) Phenol [2009] 45.](/docs-images/90/101377768/images/5-1.jpg "A solution of ( ) 1 chloro 1 phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of: [2013] (a) carbanion (b) carbene (c) carbocation (d) free")
![radical 40. The alkene that exhibits geometrical isomerism is: [2009] (a) 2- methyl propene (b) 2-butene (c) 2- methyl -2- butene (d) propene 41.](/docs-images/90/101377768/images/5-2.jpg "The number of stereoisomers possible for a compound of the molecular formula CH 3 CH = CH CH(OH) Me is: [2009] (b) 2 (c) 4 (d) 6 (d) 3 46.")
5 33 (b) 2 methylpropane (c) 2, 2 dimethylbutane (d) 2- methylbutane Identify the compound that exhibits tautomerism: [2011] (a) 2-Butene (b) Lactic acid (c) 2-Pentanone (d) Phenol [2009] 45. A solution of ( ) 1 chloro 1 phenylethane in toluene racemises slowly in the presence of a small amount of SbCl5, due to the formation of: [2013] (a) carbanion (b) carbene (c) carbocation (d) free radical 40. The alkene that exhibits geometrical isomerism is: [2009] (a) 2- methyl propene (b) 2-butene (c) 2- methyl -2- butene (d) propene 41. The number of stereoisomers possible for a compound of the molecular formula CH 3 CH = CH CH(OH) Me is: [2009] (b) 2 (c) 4 (d) 6 (d) [2013] (a) III > II > I (b) II > III > I (c) I > II > III (d) III > I > II 42. The correct order of increasing basicity of the given conjugate bases (R = CH3) is [2010] Out of the following, the alkene that exhibits optical isomerism is [2010] (a) 3-methyl-2-pentene (b) 4-methyl-1-pentene (c) 3-methyl-1-pentene (d) 2-methyl-2-pentene 2.
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