DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE

Size: px
Start display at page:

Download "DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE"

Transcription

1 DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 2 Dr Ali El-Agamey

2 Common Alkyl Groups 2

3 Write the IUPAC names of the following compounds 3-Ethyl-5-methylheptane 3-Ethyl-4-methylhexane When the number could begin from both ends of the chain, begin with the one that is alphabetically first. 3

4 Write the IUPAC names of the following compounds 2,2-Dimethylpropane 2,2,4-Trimethylpentane 3-Ethyl-4-methylheptane 5-Ethyl-2,4-dimethylheptane 3,7-Diethyl-2,2-dimethyl-4- propylnonane 4

5 Write the IUPAC names of the following compounds 3-Ethyl-5-methylheptane 4-Ethyl-2,3-dimethyloctane 6-Ethyl-3,3-dimethyloctane 5

6 Homework: Write the IUPAC names of the following compounds 6

7 Homework: Provide the IUPAC names for the following compounds 7

8 Write the structures for the following compounds (i) 3-Ethyl-4-methylhexane (ii) 3-Ethyl-5-isobutyl-3-methylnonane (iii) 4-tert-Butyl-2-methylheptane (iv) 5-Isopropyl-3,3,4-trimethyloctane (v) 4-Isopropyl-2,2,3,6-tetramethyloctane 8

9 Homework: Write the structures for the following compounds (i) 2,2-dimethylbutane (ii) 2,2-dimethylpropane (iii) 6-ethyl-3,3-dimethyloctane (iv) 5-Isopropyl-3,3,4-trimethyloctane (v) 3-methyl-5-propylnonane (vi) 5-(1,2,2-Trimethylpropyl)nonane (vii) 2,2,4-Trimethylpentane (viii) 5-tert-Butyldecane 9

10 Write the correct IUPAC name of the following compounds (i) 4-Ethylpentane (ii) 2-Ethylpentane (iii) 3-Isopropylpentane (iv) 2-Methyl-3-ethylpentane 10

11 Homework: Write the correct IUPAC name of the following compounds (i) 2-Ethyl-3-methylpentane (ii) 3,4-Dimethylpentane (iii) 2-Isopropylhexane (iv) 3-methyl-5-ethylheptane (v) Isobutane 11

12 Nomenclature of cycloalkanes 1-Ethyl-2-methylcyclobutane If there are two or more substituents, the ring carbons are numbered to give the lowest possible numbers. When the acyclic portion of the molecule contains more carbon atoms than the cyclic portion (or when it contains an important functional group) the cyclic portion is named as a cycloalkyl sunstituent. 12

13 Homework: Write the IUPAC name of the following compounds (a and b) and the structures of i and ii (i) 1-Ethyl-3-methylcycloheptane (ii) Isobutylcyclohexane 13

14 Nomenclature of alkenes IUPAC nomenclature (1) Parent name is alkene i.e. change the -ane to -ene. Choose the longest continuous chain containing the double bond as the basis for the parent name. The position of the double bond takes the lowest possible number. A compound with 2 double bonds is a diene. A triene has 3 double bonds, and a tetraene has 4.

15 IUPAC and New IUPAC Chapter 7 15

16 Ring Nomenclature In a ring, the double bond is assumed to be between Carbon 1 and Carbon methylcyclopentene 3-methylcyclopentene Chapter 7 16

17 Nomenclature of alkenes Write the IUPAC name of the following compounds but-1-ene 4-ethylhept-1-ene 4-ethyl-3-methylcyclohexene

18 cis-trans Nomenclature cis-but-2-ene trans-but-2-ene cis-1,2-dichloroethene (m.p. = -80 o C) trans-1,2-dichloroethene (m.p. = -50 o C) If two similar groups bonded to the carbons of the double bond are on the same side of the bond, the alkene is the cis isomer. If two similar groups are on opposite sides of the double bond, the alkene is the trans isomer.

19 E-Z Nomenclature 2-methylbut-2-ene propene (E)-1-bromo-1-chloropropene If it is not obvious which substituents are referred to as being cis or trans, we use the E-Z system, which uses the Cahn- Ingold-Prelog rules to assign the priorities of the groups. Priority depends on atomic number (greater atomic No. leads to higher priority) Assign the 1 st and 2 nd priorities of the groups at each end of the double bonds. If two 1 st priority groups are together on the same side of the double bond, you have the Z isomer. If two 1st priority groups are on opposite sides of the double bond, you have the E isomer.

20 Nomenclature of alkenes Write the IUPAC name of the following compounds (E)-pent-2-ene (Z)-pent-2-ene (E)-5-vinylnona-1,7-diene (3Z,5E)-3-bromoocta-3,5-diene

21 Nomenclature of alkynes IUPAC nomenclature (1) Parent name is alkyne i.e. change the -ane to -yne. Choose the longest continuous chain containing the triple bond as the basis for the parent name. The position of the triple bond takes the lowest possible number. If both double and triple bonds are present, the ending becomes enyne and numbering is such as to give the lowest possible numbers to the double and triple bonds, irrespective of whether ene or yne has the lower number. When either group can assigned the same number, -ene has the higher priority.

22 Write the IUPAC name of the following compounds ethyne but-2-yne 6-bromo-2-methylhept-3-yne propyne 4-methoxyhex-2-yne 2-methylpent-1-en-3-yne

23 Multifunctional Compounds The functional group with the highest priority determines the parent name. Naming Priority: acid > ester > amide > nitrile > aldehyde > ketone > alcohol > amine > alkene > alkyne Chapter 21 23

24 Nomenclature of aldehydes and ketones IUPAC nomenclature Functional group Name as substituent Nitriles Cyano Aldehydes Formyl Ketones Oxo Alcohols Hydroxy Amines Amino Ethers Alkoxy Halides Halo

25 Chapter 21 25

26 Nomenclature of alcohols IUPAC nomenclature (1) Parent name is alkanol Choose the longest continuous chain containing the hydroxy group. Numbering begins at one end so as to give the hydroxy group the lowest possible number. Alcohols with two OH groups are called diols and Alcohols with three OH groups are called triols.

27 Examples of Nomenclature C H 3 C H 3 C H C H 2 O H C H 3 C H C H 2 C H Methyl-1-propanol 2-Methylpropan-1-ol O H 2-Butanol Butan-2-ol 1C H 3 2 C H 3 C O H 3C H 3 2-Methyl-2-propanol 2-Methylpropan-2-ol O H C H 2 C H C H 2 C H C H penten-2-ol pent-4-en-2-ol Chapter 10 27

28 Write the IUPAC name of the following compounds pentan-1-ol 1-bromo-3,3-dimethylbutan-2-ol (E)-pent-2-en-1-ol cyclohex-2-enol 1-cyclohexylbutane-1,3-diol

29 Homework: Write the IUPAC name of the following compounds

30 Nomenclature of aldehydes and ketones IUPAC nomenclature (1) Ketones: Parent name is alkanone Choose the longest continuous chain containing the carbonyl group. In cyclic ketones the carbonyl carbon atom is assigned the number 1. (2) Aldehydes: Parent name is alkanal An aldehyde carbon is at the end of a chain, so it is number 1. For cycloalkanes with aldehyde substituent, the suffix - carbaldehyde is used.

31 Examples O O C H 3 C C H C H 3 C H 3 C C H C H 2 O H 2 2 C H C H methyl-2-butanone 4-hydroxy-3-methyl-2-butanone 1 O C H C H 3 C H 2 C H C H methylpentanal O C H 1 3 B r 3-bromocyclohexanone O C H 3 O C H 3 C C H C H 2 C H methyl-4-oxopentanal 31

32 Write the IUPAC name of the following compounds 1-phenylpropan-1-one 4-bromo-3-methylheptanal (E)-pent-2-enal cyclohexanecarbaldehyde

33 Homework: Write the IUPAC name of the following compounds

34 Nomenclature of carboxylic acids IUPAC nomenclature Acids are named in IUPAC nomenclature as alkanoic acid. Cycloalkanes with -COOH substituents are generally named as cycloalkanecarboxylic acids. Methanoic acid Ethanoic acid 4-aminobutanoic acid 2-isopropyl-4-oxopentanoic acid

35 Nomenclature of carboxylic acids IUPAC nomenclature Aliphatic dicarboxylic acids are named in IUPAC nomenclature by adding the suffix dioic acid. Choose the longest continuous chain that contains both carboxyl groups. Numbering begins with the carboxyl group that is closer to the substituents. 3-bromohexanedioic acid cyclopentane-1,3-dicarboxylic acid

36 Homework: Write the IUPAC name of the following compounds

37 Nomenclature of Esters isopropyl methanoate Esters are named as alkyl carboxylates. The first word is derived from the alkyl group of the alcohol, and the second word is derived from the carboxylic acid by changing -ic acid to ate. Chapter 21 37

38 Nomenclature of Esters IUPAC nomenclature Ethyl butanoate Methyl 3-bromo-2-methylbutanoate

39 Nomenclature of Amides IUPAC: N-Ethylethanamide Common: N-Ethylacetamide For 1 amide, first name the corresponding acid. Drop -ic acid or -oic acid from the carboxylic acid name and add -amide. For 2 and 3 amides, treat the alkyl groups on nitrogen as substituents, and specify their position by the prefix N-. Chapter 21 IUPAC: N,N-Dimethylmethanamide Common: N,N-Dimethylformamide 39

40 Nomenclature of Amides IUPAC: N-Ethyl-N,2-dimethylpropanamide Common: N-Ethyl-N-methylisobutyramide IUPAC: Cyclopentanecarboxamide For cycloalkanes with amide substituent, the suffix -carboxamide is used. Chapter 21 40

41 Homework: Write the IUPAC name for each of the following compound

Unit 9. Organic compounds

Unit 9. Organic compounds Unit 9. Organic compounds Index 1.- How to Name Organic Compounds...2 2.- Types of Compounds...3 Exercises...6 Practice exam...9 Page 1 of 11 The IUPAC Naming (nomenclature) System 1.- How to Name Organic

More information

Naming for Chem 201 CH 4

Naming for Chem 201 CH 4 Naming for Chem 201 Functional groups are referred to as such because they function or react differently and give the molecule different properties. Here s a list of the groups you need to be able to name

More information

FAMILIES of ORGANIC COMPOUNDS

FAMILIES of ORGANIC COMPOUNDS 1 SCH4U October 2016 Organic Chemistry Chemistry of compounds that contain carbon (except: CO, CO 2, HCN, CO 3 - ) Carbon is covalently bonded to another carbon, hydrogen and possibly to oxygen, a halogen

More information

Unit 5: Organic Chemistry

Unit 5: Organic Chemistry Unit 5: Organic Chemistry Organic chemistry: discipline in chemistry focussing strictly on the study of hydrocarbons compounds made up of carbon & hydrogen Organic compounds can contain other elements

More information

Short Summary of IUPAC Nomenclature of Organic Compounds

Short Summary of IUPAC Nomenclature of Organic Compounds Short Summary of IUPA Nomenclature of rganic ompounds Introduction The purpose of the IUPA system of nomenclature is to establish an international standard of naming compounds to facilitate communication.

More information

DAMIETTA UNIVERSITY. Energy Diagram of One-Step Exothermic Reaction

DAMIETTA UNIVERSITY. Energy Diagram of One-Step Exothermic Reaction DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 5 Dr Ali El-Agamey 1 Energy Diagram of One-Step Exothermic Reaction The vertical axis in this graph represents the potential energy. The transition

More information

Chapter 3. Organic Compounds: Alkanes and Their Stereochemistry

Chapter 3. Organic Compounds: Alkanes and Their Stereochemistry Chapter 3. Organic Compounds: Alkanes and Their Stereochemistry Functional Group: Be able to identify and name any of the functional groups listed on Table 3.1, pages 76-77. Summary of important functional

More information

Basic Organic Chemistry Nomenclature CHEM 104 B

Basic Organic Chemistry Nomenclature CHEM 104 B Basic Organic Chemistry Nomenclature CHEM 104 B I have gone ahead and compiled all of the basic naming rules that we will be dealing with into one worksheet. I hope this will be helpful to you as you work

More information

IUPAC Nomenclature Chem12A, Organic Chemistry I

IUPAC Nomenclature Chem12A, Organic Chemistry I IUPAC Nomenclature ChemA, rganic Chemistry I IUPAC PEFIXES Prefix Substituent Group Number of Carbons meth- methyl eth- ethyl prop- propyl but- butyl pent- pentyl hex- hexyl hept- heptyl 7 oct- octyl 8

More information

Functional Groups. Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity.

Functional Groups. Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity. Functional Groups Functional groups: special groups of atoms attached to a hydrocarbon skeleton; the most common sites of chemical reactivity. Organic halides: a hydrogen is replaced by a halogen fluoro-,

More information

Organic Chemistry. A. Introduction

Organic Chemistry. A. Introduction Organic Chemistry A. Introduction 1. Organic chemistry is defined as the chemistry of CARBON compounds. There are a huge number of organic compounds. This results from the fact that carbon forms chains

More information

ORGANIC NOMENCLATURE

ORGANIC NOMENCLATURE RGAI MELATURE Introduction onfusion can arise in organic chemistry because of the variety of names that have been applied to compounds; common names, trade names and systematic names are prevalent. For

More information

The International Union of Pure and Applied Chemistry has developed a system of rules for naming organic molecules.

The International Union of Pure and Applied Chemistry has developed a system of rules for naming organic molecules. HYDRCARBNS AND THEIR DERIVATIVES The field of organic chemistry includes the study of hydrocarbons (compounds composed of carbon and hydrogen atoms covalently bonded together) and their derivatives (variations

More information

Organic Chemistry. FAMILIES of ORGANIC COMPOUNDS

Organic Chemistry. FAMILIES of ORGANIC COMPOUNDS 1 SCH4U September 2017 Organic Chemistry Is the chemistry of compounds that contain carbon (except: CO, CO 2, HCN, CO 3 2- ) Carbon is covalently bonded to another carbon, hydrogen and possibly to oxygen,

More information

Alkanes, Alkenes and Alkynes

Alkanes, Alkenes and Alkynes Alkanes, Alkenes and Alkynes Hydrocarbons Hydrocarbons generally fall into 2 general groupings, aliphatic hydrocarbons and aromatic hydrocarbons. Aliphatic hydrocarbons contain chains and rings of hydrocarbons,

More information

Organic Chemistry Unit Review Package

Organic Chemistry Unit Review Package Name: Worksheet 7.viii Organic Chemistry Unit Review Package Generalized Organic Chemistry Naming Procedure Grouped into three general phases. 1. Identification phase (finding all important/correct information)

More information

Organic Chemistry. Organic chemistry is the chemistry of compounds containing carbon.

Organic Chemistry. Organic chemistry is the chemistry of compounds containing carbon. Organic Chemistry Organic Chemistry Organic chemistry is the chemistry of compounds containing carbon. In this chapter we will discuss the structural features of organic molecules, nomenclature, and a

More information

DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE

DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE DAMIETTA UNIVERSITY CHEM-103: BASIC ORGANIC CHEMISTRY LECTURE 6 Dr Ali El-Agamey 1 Oxidation States Easy for inorganic salts: CrO 4 2- reduced to Cr 2 O 3. KMnO 4 reduced to MnO 2. Oxidation: Gain of O,

More information

Chapter 11. Introduction to Organic Chemistry

Chapter 11. Introduction to Organic Chemistry hapter 11 Introduction to rganic hemistry Properties of arbon and its compounds 2 Properties of arbon and its compounds 3 Properties of arbon and its compounds 4 Properties of arbon and its compounds 5

More information

Topic 10.1: Fundamentals of Organic Chemistry Notes

Topic 10.1: Fundamentals of Organic Chemistry Notes Topic 10.1: Fundamentals of Organic Chemistry Notes Terminology Hydrocarbon: compounds that contain mostly hydrogen and carbon Homologous Series: compounds with the same general formula Molecular Formula:

More information

UNIT (7) ORGANIC COMPOUNDS: HYDROCARBONS

UNIT (7) ORGANIC COMPOUNDS: HYDROCARBONS UNIT (7) RGANI MPUNDS: YDRARBNS rganic chemistry is the study carbon containing compounds. 7.1 Bonding in rganic ompounds rganic compounds are made up of only a few elements and the bonding is almost entirely

More information

12.01 Organic Chemistry

12.01 Organic Chemistry 12.01 rganic hemistry hemistry of arbon An Introduction to nomenclatures, structures and reactions Dr. Fred mega Garces hemistry 100 Miramar ollege 1 rganic hemistry What is rganic hemistry? rganic hemistry:

More information

Introduction to Organic Chemistry

Introduction to Organic Chemistry Introduction to rganic hemistry rganic chemistry is the study of carbon compounds. It is such a complex branch of chemistry because carbon form a wide variety of compounds for the following reasons 1)

More information

4.1.1 Organic: Basic Concepts

4.1.1 Organic: Basic Concepts .. rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond

More information

3.1 Organic: Basic Concepts

3.1 Organic: Basic Concepts 3.1 rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond

More information

A. They all have a benzene ring structure in the molecule. B. They all have the same molecular formula. C. They all have carbon and hydrogen only

A. They all have a benzene ring structure in the molecule. B. They all have the same molecular formula. C. They all have carbon and hydrogen only Ch 21 G12 CoreI- Choose the best answer, then transfer your answers to page (1) [32 marks; 2 each] 1. What characteristic do all aromatic hydrocarbons share? A. They all have a benzene ring structure in

More information

3.1 Organic: Basic Concepts

3.1 Organic: Basic Concepts . rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond

More information

Chapter 22. Organic and Biological Molecules

Chapter 22. Organic and Biological Molecules Chapter 22 Organic and Biological Molecules The Bonding of Carbon Organic chemistry is the chemistry of compounds containing carbon. Because carbon can form single, double, and triple bonds, the following

More information

Alkanes and Cycloalkanes

Alkanes and Cycloalkanes Alkanes and Cycloalkanes Families of Organic Compounds Organic compounds can be grouped into families by their common structural features We shall survey the nature of the compounds in a tour of the families

More information

Lab Workshop 1: Nomenclature of alkane and cycloalkanes

Lab Workshop 1: Nomenclature of alkane and cycloalkanes Lab Workshop 1: Nomenclature of alkane and cycloalkanes Each student work group choose a Leader (reads activity out loud, poses questions to group), Facilitator (makes sure everyone is participating equally,

More information

BASIC NOMENCLATURE. The names of the groups you must be able to recognize and draw are:

BASIC NOMENCLATURE. The names of the groups you must be able to recognize and draw are: A STUDENT SHOULD BE ABLE TO: BASIC NOMENCLATURE 1. Give examples of, and recognize when given the structure, representatives of the following classes of compounds. Alkyl halides (1, 2, 3 ) Alcohols (1,

More information

AP Chemistry Chapter 22 - Organic and Biological Molecules

AP Chemistry Chapter 22 - Organic and Biological Molecules AP Chemistry Chapter - Organic and Biological Molecules.1 Alkanes: Saturated Hydrocarbons A. Straight-chain Hydrocarbons 1. Straight-chain alkanes have the formula C n H n+. Carbons are sp hybridized The

More information

Nomenclature of Organic Compounds Identification of Functional Groups

Nomenclature of Organic Compounds Identification of Functional Groups Hydrocarbons Nomenclature of Organic ompounds Identification of Functional Groups Alkanes - also known as saturated hydrocarbons or the paraffin series because all bond sites between carbon atoms and between

More information

ORGANIC NOMENCLATURE. dimethyl ether By writing their formulae in a structural form we can differentiate between these two compounds.

ORGANIC NOMENCLATURE. dimethyl ether By writing their formulae in a structural form we can differentiate between these two compounds. hemistry 121 Winter 2001 ourse otes Principles of hemistry II Introduction RGAI MELATURE onfusion can arise in organic chemistry because of the variety of names that have been applied to compounds; common

More information

4.1.1 Organic: Basic Concepts

4.1.1 Organic: Basic Concepts .. rganic: Basic oncepts ydrocarbon is a compound consisting of hydrogen and carbon only Basic definitions to know Saturated: ontain single carbon-carbon bonds only Unsaturated : ontains a = double bond

More information

Alkanes 3/27/17. Hydrocarbons: Compounds made of hydrogen and carbon only. Aliphatic (means fat ) - Open chain Aromatic - ring. Alkane Alkene Alkyne

Alkanes 3/27/17. Hydrocarbons: Compounds made of hydrogen and carbon only. Aliphatic (means fat ) - Open chain Aromatic - ring. Alkane Alkene Alkyne Alkanes EQ 1. How will I define Hydrocarbons? 2. Compare and contrast the 3 types of hydrocarbons (Alkanes, alkenes, alkynes). Hydrocarbons: Compounds made of hydrogen and carbon only. Aliphatic (means

More information

Hydrocarbons and their Functional Groups

Hydrocarbons and their Functional Groups Hydrocarbons and their Functional Groups Organic chemistry is the study of compounds in which carbon is the principal element. carbon atoms form four bonds long chains, rings, spheres, sheets, and tubes

More information

Organic Nomenclature

Organic Nomenclature University of Puget Sound Department of Chemistry Chem 111 Spring, 2010 Organic Nomenclature LEARNING GOALS AND ASSESSMENTS 1. Be familiar with the structure and nomenclature of organic compounds. a. Identify

More information

Chapter 3. An Introduction to Organic Compounds. Spring Alkanes are hydrocarbons containing only single bonds General formula: C n H 2n+2

Chapter 3. An Introduction to Organic Compounds. Spring Alkanes are hydrocarbons containing only single bonds General formula: C n H 2n+2 Chapter 3 An Introduction to Organic Compounds Nomenclature, Physical Properties, and Representation of structure Alkanes are hydrocarbons containing only single bonds General fmula: C n H 2n+2 1 Constitutional

More information

1. True or false: In a molecule, carbon always forms bonds with four other elements. 5. An unsaturated hydrocarbon must contain a or bond.

1. True or false: In a molecule, carbon always forms bonds with four other elements. 5. An unsaturated hydrocarbon must contain a or bond. APTER 20 Organic hemistry 1. True or false: In a molecule, carbon always forms bonds with four other elements. False 2. A triple bond involves sharing electrons. a. 2 b. 3 c. 4 d. 5 e. 6 e. 6 3. ydrocarbons

More information

Organic Chemistry CHEM 30S Learning Booklet

Organic Chemistry CHEM 30S Learning Booklet Organic Chemistry CHEM 30S Learning Booklet Name: What is organic chemistry? The word organic has been used widely in food that has been grown without the aid of fertilizers or chemicals enhancements.

More information

1.8. Organic Chemistry. Practice Exam Organic Chem. System LENGTH: VOLUME MASS Temperature. 1 gal = 4 qt. 1 lb = 16 oz.

1.8. Organic Chemistry. Practice Exam Organic Chem. System LENGTH: VOLUME MASS Temperature. 1 gal = 4 qt. 1 lb = 16 oz. rganic hemistry Practice Exam rganic hem Name (last) (First) Read all questions before you start. Show all work and explain your answers to receive full credit. Report all numerical answers to the proper

More information

3. Organic Compounds: Alkanes and Cycloalkanes

3. Organic Compounds: Alkanes and Cycloalkanes 3. Organic Compounds: Alkanes and Cycloalkanes Based on McMurry s Organic Chemistry, 6 th edition, Chapter 3 2003 Ronald Kluger Department of Chemistry University of Toronto 1 Families of Organic Compounds!

More information

Isomerism CH 4 C 2 H 6 C 3 H 8 C 4 H 10 C 5 H 12. Constitutional isomers...

Isomerism CH 4 C 2 H 6 C 3 H 8 C 4 H 10 C 5 H 12. Constitutional isomers... Isomerism 4 2 6 3 8 4 10 5 12 onstitutional isomers... 3 8 Positional isomers... Functional isomers... ow many constitutional isomers are there for the formula 4 8? arbon atoms are often classified as

More information

Organic Chemistry CHEM 30S Learning Booklet

Organic Chemistry CHEM 30S Learning Booklet Organic Chemistry CHEM 30S Learning Booklet Name: What is organic chemistry? The word organic has been used widely in food that has been grown without the aid of fertilizers or chemicals enhancements.

More information

Getting Started. IUPAC Nomenclature. Basic Part - Suffixes. The Three Basic Parts. Parent and suffix. Basic Part the Parent 2/12/14 CH 4

Getting Started. IUPAC Nomenclature. Basic Part - Suffixes. The Three Basic Parts. Parent and suffix. Basic Part the Parent 2/12/14 CH 4 Getting Started IUPAC Nomenclature Naming Molecules by Following the Rules You first have to identify the family that your molecule belongs to So, check for functional groups If there are none, then your

More information

Unit 2, Review for Quiz #1: Hydrocarbons

Unit 2, Review for Quiz #1: Hydrocarbons Unit 2, Review for Quiz #1: Hydrocarbons 1. What is the simplest organic molecule? a) CH 4 c) HCN b) CO 2 d) HC CH 2. Which of the following molecules would be classified as organic? I) CaCO 3 II) C 2

More information

Chemistry 11 Hydrocarbon Alkane Notes. In this unit, we will be primarily focusing on the chemistry of carbon compounds, also known as.

Chemistry 11 Hydrocarbon Alkane Notes. In this unit, we will be primarily focusing on the chemistry of carbon compounds, also known as. 1 Chemistry 11 Hydrocarbon Alkane Notes In this unit, we will be primarily focusing on the chemistry of carbon compounds, also known as. Why is organic chemistry so important? Many of the compounds that

More information

Full file at

Full file at Chapter 2 - Alkanes: The Nature of Organic Compounds 1. Which of the following functional group classifications do not contain oxygen? A. ether B. thiol C. aldehyde D. ester E. amide 2. To which functional

More information

Organic Chemistry. A brief introduction

Organic Chemistry. A brief introduction Organic Chemistry A brief introduction Organic Chemistry the study of carbon-containing compounds and their properties excluding: CO, CO 2, CS 2, carbonates and cyanides eight million known organic compounds

More information

Classifying Hydrocarbons

Classifying Hydrocarbons Classifying Hydrocarbons alkanes- single C-C bonds, if all C s have H s attached, molecules are called saturated hydrocarbons alkenes- have one or more C=C double bonds alkynes- have one or more CΞC triple

More information

MSC. ISMAIL M.ALI DEPARTMENT OF CHEMICAL ENGINEEING COLLEGE OF ENGINEERING TIKRIT UNIVERSITY

MSC. ISMAIL M.ALI DEPARTMENT OF CHEMICAL ENGINEEING COLLEGE OF ENGINEERING TIKRIT UNIVERSITY LECTURE 1 SYLLABUS FOR FIRST CLASS 2013-2014 MSC. ISMAIL M.ALI DEPARTMENT OF CHEMICAL ENGINEEING COLLEGE OF ENGINEERING TIKRIT UNIVERSITY MANDATORY CLASS: 1ST ORGANIC CHEMISTRY CH 122 Teaching scheme:

More information

Chapter 2. Skeletal Structures

Chapter 2. Skeletal Structures Chapter 2 Basic nomenclature/definition of alkanes Nomenclature of alkyl groups Nomenclature of more complicated alkanes Nomenclature & structure of alkane derivatives: Alkyl halides Ethers Alcohols Amines

More information

Chapter 25: The Chemistry of Life: Organic and Biological Chemistry

Chapter 25: The Chemistry of Life: Organic and Biological Chemistry Chemistry: The Central Science Chapter 25: The Chemistry of Life: Organic and Biological Chemistry The study of carbon compounds constitutes a separate branch of chemistry known as organic chemistry The

More information

Chapter 2: An Introduction to Organic Compounds

Chapter 2: An Introduction to Organic Compounds Chapter : An Introduction to Organic Compounds I. FUNCTIONAL GROUPS: Functional groups with similar structure/reactivity may be "grouped" together. A. Functional Groups With Carbon-Carbon Multiple Bonds.

More information

Carbon Bonding Isomers Naming Reference Tables Functional Groups. Reactions

Carbon Bonding Isomers Naming Reference Tables Functional Groups. Reactions arbon Bonding Isomers Naming Reference Tables Functional Groups 2 Reactions Not electrolytes; they do not generally conduct electricity. Low melting points; they are nonpolar with weak forces of attraction.

More information

INTRODUCTION TO ORGANIC CHEMISTRY: ALKANES

INTRODUCTION TO ORGANIC CHEMISTRY: ALKANES P a g e 1 Chapter 12 INTRODUCTION TO ORGANIC CHEMISTRY: ALKANES Organic chemistry: The study of carbon compounds. Carbon is tetravalent; it always forms four bonds. Organic molecules have covalent bonds.

More information

INSPIRE ACADEMY, PUDUKKOTTAI Medical/JEE/Foundations/Olympiads NEET 2018 CHEMISTRY IMPORTANT AREAS TO BE COVERED

INSPIRE ACADEMY, PUDUKKOTTAI Medical/JEE/Foundations/Olympiads NEET 2018 CHEMISTRY IMPORTANT AREAS TO BE COVERED NEET 2018 CHEMISTRY IMPORTANT AREAS TO BE COVERED 1. CHEMICAL BONDING (VSEPR MODEL) 2. BASIC ORAGNIC CHEMISTRY (IUPAC & ISOMERISM) 3. ORGANIC REACTION CONVERSIONS & MECHANISMS 4. PERIDIC TABLE & PERIODIC

More information

Unit 12 Organic Chemistry

Unit 12 Organic Chemistry Unit 12 Organic Chemistry Day 138 5/5/14 QOD: What is Organic Chemistry? Do Now: True or false? 1. Electrochemical cells generate electricity. 2. Electrons flow from left to right in a battery. 3. Redox

More information

Common Elements in Organic Compounds

Common Elements in Organic Compounds Organic hemistry ommon Elements in Organic ompounds lassification of ydrocarbons Alkanes Alkanes have the general formula n 2n+2 where n = 1,2,3, only single covalent bonds saturated hydrocarbons because

More information

Chapter 9. Organic Chemistry: The Infinite Variety of Carbon Compounds. Organic Chemistry

Chapter 9. Organic Chemistry: The Infinite Variety of Carbon Compounds. Organic Chemistry Chapter 9 Organic Chemistry: The Infinite Variety of Carbon Compounds Organic Chemistry Organic chemistry is defined as the chemistry of carbon compounds. Of tens of millions of known chemical compounds,

More information

Chapter 25 Organic and Biological Chemistry

Chapter 25 Organic and Biological Chemistry Chapter 25 Organic and Biological Chemistry Organic Chemistry The chemistry of carbon compounds. Carbon has the ability to form long chains. Without this property, large biomolecules such as proteins,

More information

CHE1502. Tutorial letter 203/1/2016. General Chemistry 1B. Semester 1. Department of Chemistry

CHE1502. Tutorial letter 203/1/2016. General Chemistry 1B. Semester 1. Department of Chemistry E1502/203/1/2016 Tutorial letter 203/1/2016 General hemistry 1B E1502 Semester 1 Department of hemistry This tutorial letter contains the answers to the questions in assignment 3. FIRST SEMESTER: KEY T

More information

Organic Chemistry. Introduction to Organic Chemistry 01/03/2018. Organic Chemistry

Organic Chemistry. Introduction to Organic Chemistry 01/03/2018. Organic Chemistry Organic Chemistry Chemistry 30 Ms. Hayduk Introduction to Organic Chemistry https://www.youtube.com/watch?v=i9r1dmhh2m0 Organic Chemistry Study of compounds that contain carbon as the main element Relevant

More information

Chapter 22. Organic and Biological Molecules

Chapter 22. Organic and Biological Molecules Chapter 22 Organic and Biological Molecules 1 Organic Chemistry and Biochemistry The study of carbon-containing compounds and their properties. The vast majority of organic compounds contain chains or

More information

Drawing Hydrocarbons. Classifying Hydrocarbons. Four types of diagrams can be used to represent the structure of a hydrocarbon: e.g.

Drawing Hydrocarbons. Classifying Hydrocarbons. Four types of diagrams can be used to represent the structure of a hydrocarbon: e.g. Classifying Hydrocarbons alkanes- single C-C bonds, if all C s have H s attached, molecules are called hydrocarbons alkenes- have one or more C=C bonds alkynes- have one or more CΞC bonds alkenes & alkynes

More information

Chem 1075 Chapter 19 Organic Chemistry Lecture Outline

Chem 1075 Chapter 19 Organic Chemistry Lecture Outline Chem 1075 Chapter 19 Organic Chemistry Lecture Outline Slide 2 Introduction Organic chemistry is the study of and its compounds. The major sources of carbon are the fossil fuels: petroleum, natural gas,

More information

Organic Chemistry. Nomenclature: Alkanes

Organic Chemistry. Nomenclature: Alkanes Organic Chemistry Nomenclature: Alkanes Alkanes Hydrocarbon chains where all the bonds between carbons are SINGLE bonds Name uses the ending ane Examples: Methane, Propane, Butane, Octane, 2-methylpentane

More information

MODULE-16 HYDROCARBONS. Hydrocarbons can be classified according to the types of bonds between the carbon atoms:

MODULE-16 HYDROCARBONS. Hydrocarbons can be classified according to the types of bonds between the carbon atoms: MODULE-16 YDROARBONS SATURATED AND UNSATURATED YDROARBONS:- ydrocarbons can be classified according to the types of bonds between the carbon atoms: (i) Saturated hydrocarbons have only single bonds between

More information

Electronegativity Scale F > O > Cl, N > Br > C, H

Electronegativity Scale F > O > Cl, N > Br > C, H Organic Chem Chapter 12 Alkanes Organic chemistry is the study of carbon compounds. Carbon has several properties that are worth discussing: Tetravalent Always forms 4 bonds Can form multiple bonds (double

More information

video 14.4 isomers isomers Isomers have the molecular formula but are rearranged in a structure with different properties. Example: Both C 4 H 10

video 14.4 isomers isomers Isomers have the molecular formula but are rearranged in a structure with different properties. Example: Both C 4 H 10 video 14.4 isomers isomers Isomers have the molecular formula but are rearranged in a structure with different properties. Example: Both C 4 H 10 Butane Methylpropane 1 match the isomers drawing an isomer

More information

Naming Organic Halides. Properties of Organic Halides

Naming Organic Halides. Properties of Organic Halides Organic Compounds Organic Halides A hydrocarbon in which one or more hydrogen atoms have been replaced by halogen atoms Freons (chlorofluorocarbons) in refrigeration and air conditioning Teflon (polytetrafluoroethane)

More information

Chapter 3 AN INTRODUCTION TO ORGANIC COMPOUNDS NOMENCLATURE, PHYSICAL PROPERTIES, REPRESENTATION OF STRUCTURE AND

Chapter 3 AN INTRODUCTION TO ORGANIC COMPOUNDS NOMENCLATURE, PHYSICAL PROPERTIES, REPRESENTATION OF STRUCTURE AND ORGANIC CHEMISTRY, 2 ND EDITION PAULA YURKANIS BRUICE Chapter 3 AN INTRODUCTION TO ORGANIC COMPOUNDS NOMENCLATURE, PHYSICAL PROPERTIES, AND REPRESENTATION OF STRUCTURE RAED M. AL-ZOUBI, ASSISTANT PROFESSOR

More information

CHAPTER 14: An Introduction to Organic Chemistry

CHAPTER 14: An Introduction to Organic Chemistry CHAPTER 14: An Introduction to rganic Chemistry 14.1 rganic Compounds 14.2 rganic Reactions 14.3 Isomerism Learning outcomes: (a) interpret, and use the general, structural, displayed and skeletal formulae

More information

CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 OH

CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 OH 03SEP 18:00 19:00 ORGANIC MOLECULES STUDY NOTES ORGANIC MOLECULES Important features of Carbon Carbon has a valency of 4 (can form 4 bonds), and has 4 valence electrons (outermost energy level). Carbon

More information

ORGANIC MOLECULES (LIVE) 10 APRIL 2015 Section A: Summary Notes and Examples Naming and Functional Groups

ORGANIC MOLECULES (LIVE) 10 APRIL 2015 Section A: Summary Notes and Examples Naming and Functional Groups ORGANIC MOLECULES (LIVE) 10 APRIL 2015 Section A: Summary Notes and Examples Naming and Functional Groups Important Features of Carbon There are different allotropes (same element, same phase, different

More information

Organic Chemistry unit formative exam

Organic Chemistry unit formative exam Class: Date: Organic Chemistry unit formative exam Multiple Choice Identify the choice that best completes the statement or answers the question. 1. Which of the following statements is true about polymers?

More information

CHEM 203 Exam 1. Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question.

CHEM 203 Exam 1. Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. CHEM 203 Exam 1 Name Multiple Choice Identify the letter of the choice that best completes the statement or answers the question. 1. Which of the following elements is a large percentage of both the earth's

More information

Part 01 - Assignment: The ane-ene-yne of My Existence

Part 01 - Assignment: The ane-ene-yne of My Existence Part 01 - Assignment: The ane-ene-yne of My Existence Honors hemistry Unit 18 - rganic hem Task: Answer the following questions according to the directions provided. 1. Are the following compounds, based

More information

Rules for Naming Organic Molecules. Nomenclature II

Rules for Naming Organic Molecules. Nomenclature II Rules for Naming Organic Molecules Nomenclature II 1 Why? The carbon atom is unique in its bonding in that it can form stable molecules consisting of chains of carbon atoms of any length Coupled with the

More information

CHAPTER 12: SATURATED HYDROCARBONS

CHAPTER 12: SATURATED HYDROCARBONS CHAPTER 12: SATURATED HYDROCARBONS MULTIPLE CHOICE 1. Which of the following statements concerning organic compounds is correct? Organic compounds are found only in non-living systems. b. Organic compounds

More information

Introduction to Organic Chemistry. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

Introduction to Organic Chemistry. Copyright The McGraw-Hill Companies, Inc. Permission required for reproduction or display. Introduction to Organic Chemistry Copyright The McGraw-ill Companies, Inc. Permission required for reproduction or display. 1 Common Elements in Organic Compounds 2 Classification of ydrocarbons ydrocarbons

More information

Unit 3 Organic Chemistry. Chemistry 2202

Unit 3 Organic Chemistry. Chemistry 2202 Unit 3 Organic hemistry hemistry 2202 Introduction Organic hemistry is the study of the molecular compounds of carbon. eg. 4 3 O 3 N 2 Organic compounds exclude oxides of carbon and ions containing carbon.

More information

Organic Chemistry. February 18, 2014

Organic Chemistry. February 18, 2014 Organic Chemistry February 18, 2014 What does organic mean? Organic Describes products Grown through natural biological process Without synthetic materials In the 18 th century Produced by a living system

More information

Unit 7 Part 1 Introduction to Organic Chemistry Nomenclature and Isomerism in Simple Organic Compounds UNIT 7 INTRODUCTION TO ORGANIC CHEMISTRY

Unit 7 Part 1 Introduction to Organic Chemistry Nomenclature and Isomerism in Simple Organic Compounds UNIT 7 INTRODUCTION TO ORGANIC CHEMISTRY Unit 7 Part 1 Introduction to Organic hemistry Nomenclature and Isomerism in Simple Organic ompounds UNIT 7 INTRODUTION TO ORGANI EMISTRY PART 1 NOMENLATURE AND ISOMERISM IN SIMPLE ORGANI MOLEULES ontents

More information

CHEM120 - ORGANIC CHEMISTRY WORK SHEET Answer the following questions with respect to compounds (A) and (B):

CHEM120 - ORGANIC CHEMISTRY WORK SHEET Answer the following questions with respect to compounds (A) and (B): EM120 - RGANI EMISTRY WRK SEET 1 1. Answer the following questions with respect to compounds (A) and (B): (B) (A) 5 2 ( 3 ) 2 6 3 2 2 2 ( 3 ) 3 1 2 4 3 () 2 2 3 3 1 3 2 3 (a) Draw the bond-line notation

More information

Familiarize yourself with the principal functional groups of organic chemistry

Familiarize yourself with the principal functional groups of organic chemistry Chemistry 261 Laboratory Experiment 1: Model Building Reading from Zubrick, 10 th Edition (for Live Labs Beginning Next Week) Safety, pages 1-10 Keeping a Notebook, pages 11-24 Mining Your Own Data, pages

More information

Chapter 3: Organic Compounds: Alkanes and Cycloalkanes

Chapter 3: Organic Compounds: Alkanes and Cycloalkanes hapter : rganic ompounds: Alkanes and ycloalkanes >11 million organic compounds which are classified into families according to structure and reactivity Functional Group (FG): group of atoms which are

More information

Chapter 4 Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis"

Chapter 4 Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis Chapter 4 Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis" Alkanes = saturated hydrocarbons" Simplest alkane = methane C 4" " We can build additional alkanes by adding

More information

BRCC CHM 102 Class Notes Chapter 11 Page 1 of 9

BRCC CHM 102 Class Notes Chapter 11 Page 1 of 9 BRCC CHM 102 Class Notes Chapter 11 Page 1 of 9 Chapter 11 Alkanes and Cycloalkanes hydrocarbons compounds that contain only carbon and hydrogen * 4 families: 1) alkanes only single bonds (includes cycloalkanes)

More information

4. A sample of 0.200g of an organic compound was subjected to combustion analysis and

4. A sample of 0.200g of an organic compound was subjected to combustion analysis and 1. A sample of 0.205g of an organic compound was subjected to combustion analysis and produced 0.660g of carbon dioxide, 0.225g of water and nothing else. Its RMM is 82. 2. A sample of 0.400g of an organic

More information

General Chemistry Unit 7A ( )

General Chemistry Unit 7A ( ) Organic Chemistry Allotropes Isomers Hydrocarbons o Alkanes o Alkenes o Alkynes o Aromatics Alkyl Halides General Chemistry Unit 7A (2017-2018) 1 2 3 4 Parent Chain: Methane Ethane CH4 C2H6 Propane C3H8

More information

Introduc)on to Func)onal Groups in Organic Molecules

Introduc)on to Func)onal Groups in Organic Molecules Introduc)on to Func)onal Groups in rganic Molecules CH 3 H 3 C N C C N C C N N CH CH 3 Caffeine Func)onal Group Func%onal group - collec)on of atoms at a site that have a characteris)c behavior in all

More information

Chapter 22. Organic and Biological Molecules

Chapter 22. Organic and Biological Molecules hapter 22 Organic and Biological Molecules hapter 22 Preview Organic and Biological Molecules Alkanes: Saturated ydrocarbons Isomerism, Nomenclature, Reactions of alkanes, yclic alkanes Alkenes, Alkynes,

More information

Nomenclature Problems Guidelines and summary page on last two pages.

Nomenclature Problems Guidelines and summary page on last two pages. Nomenclature Problems Guidelines and summary page on last two pages... 3. 4. 5. Z:\classes\34\34 Special andouts\34 Nomenclature lect probs only.doc 6. 7. 8. 9. 0. Z:\classes\34\34 Special andouts\34 Nomenclature

More information

CHEM 3.2 (AS91388) 3 credits. Demonstrate understanding of spectroscopic data in chemistry

CHEM 3.2 (AS91388) 3 credits. Demonstrate understanding of spectroscopic data in chemistry CHEM 3.2 (AS91388) 3 credits Demonstrate understanding of spectroscopic data in chemistry Spectroscopic data is limited to mass, infrared (IR) and 13 C nuclear magnetic resonance (NMR) spectroscopy. Organic

More information

Chapter 2: Hydrocarbon Frameworks - Alkanes

Chapter 2: Hydrocarbon Frameworks - Alkanes Chapter 2: Hydrocarbon Frameworks - Alkanes 1. Alkanes are characterized by the general molecular formula: A) C n H 2n-2 B) C n H 2n C) C n H 2n+2 D) C n H 2n+4 2. Cycloalkanes are characterized by the

More information

Chapter 03 Fundamentals of Organic Chemistry

Chapter 03 Fundamentals of Organic Chemistry hempocalypse Now! hapter 03 Fundamentals of Organic hemistry Page 1 hapter 03 Fundamentals of Organic hemistry Parts of Topics 10 and 20 from the IB HL hemistry urriculum What is an Organic ompound? Organic

More information

NAME PER DATE DUE ACTIVE LEARNING IN CHEMISTRY EDUCATION CHAPTER 25 INTRODUCTION TO ORGANIC COMPOUNDS. (Part 1) , A.J.

NAME PER DATE DUE ACTIVE LEARNING IN CHEMISTRY EDUCATION CHAPTER 25 INTRODUCTION TO ORGANIC COMPOUNDS. (Part 1) , A.J. NAME PER DATE DUE ACTIVE LEARNING IN CHEMISTRY EDUCATION CHAPTER 25 INTRODUCTION TO ORGANIC COMPOUNDS (Part 1) 25-1 1997, A.J. Girondi NOTICE OF RIGHTS All rights reserved. No part of this document may

More information

Practice Problems for Chapter 21

Practice Problems for Chapter 21 Practice Problems for Chapter 21 1. Name the following: A) isopropane B) methylpentane C) methylbutane D) n-pentane E) dodecane 2. Name the following: A) n-heptane B) 2-methyl-2-ethylbutane C) 3,3-dimethylpentane

More information