Chapter 1. Preface (class hour: 2) Chapter 2. State of Substance (class hour: 2) Chapter 3. Atomic Structure and Period of Element (class hour: 8)

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1 Chapter 1. Preface (class hour: 2) [Teaching Objectives] Introduction of this course the learning process, purpose, tasks and methods. [Focus and difficulty] Introduction of this course the learning process Chapter 2. State of Substance (class hour: 2) Chapter 3. Atomic Structure and Period of Element (class hour: 8) [Teaching Objectives] Grasp the hydrogen atom spectrum, Bohr atom model; understand the special nature of extranuclear electron movement, understanding the wave function and the electron cloud graphics; grasp the electron shell, electronic sub-layer, energy level, energy level group, the electron cloud, atomic orbital concepts understand the four quantum numbers the quantum condition and its physical meaning; grasp the approximate energy level diagram, in accordance with cloth extranuclear electron emission principle, to write a general element of the atomic electron configuration; understanding of atomic structure and the relationship between the periodic law of elements; master various elements of electronic configuration of the features; master the ionization energy, electron affinity, electronegativity concepts.understanding of their relationship with the atomic structure; through an understanding of humanity's understanding of atomic structure of history, culture and scientific way of thinking. [Focus and difficulty] Focus: wave functions and atomic orbitals, the four quantum numbers, the wave function of the radial distribution and angular distribution maps, probability density and the electron cloud, the electron cloud point of distribution. Difficulties: the wave function of the radial distribution and angular distribution maps, probability density and the electron cloud, the electron cloud point of distribution.

2 Chapter 4 Chemical Bond and Molecular Structure (class hour: 6) [Teaching Objectives] Grasp the ionic bond and covalent bond theory of the basic process; understand the physical nature of the relationship between its molecular structure; qualitative understanding of nuclear diatomic molecules with molecular orbital theory; grasp the chemical bond, molecular hydrogen bonds between the force and the concepts, characteristics, and sorting out prices bond force, intermolecular forces and hydrogen bonding difference. [Focus and difficulty] Focus: covalent bond theory, hybrid orbital theory. Difficulty: hybrid orbital theory of conjugated π bond.

3 Chapter 5 Crystal Structure (class hour: 3) [Teaching Objectives] Grasp the characteristics of various types of crystal; grasp the crystal type and material nature of the relationship; grasp the lattice energy and heat of atomization of the concepts and related applications; understand the concept of ionic polarization and its application; understanding of atomic radius, ionic radius and its impact on the definition of compound properties. [Focus and difficulty] Focus: cell the basic characteristics of ionic crystals and the structure model. Difficulties: the role of ion polarization and deformation, ion polarization, the metal crystals close packing model.

4 Chapter 6 Fundament of Thermodynamics (class hour: 8) [Teaching Objectives] Master the state and the state function, enthalpy, and the concept of enthalpy, free energy and entropy changes and their initial concept. The law will be applied gais calculated. The thermodynamic functions from the material table search ΔfH0, ΔfG0, and S0, and is used to calculate the standard state enthalpy, free energy change and entropy change; initially learn how to use the free energy change to determine the direction of chemical reactions; understanding of chemical reactions isotherm meaning, will be putting his demand balance ΔrG and the equilibrium constant K; according to Gibbs - Helmholtz equation ΔG and ΔH and ΔS to understand the relationship between the response will be to determine the direction and to analyze the temperature effect on the spontaneous chemical reaction. [Focus and difficulty] Focus: first law of thermodynamics and heat Chemistry: Enthalpy, enthalpy, reaction heat, constant volume and constant pressure heat of reaction; thermo-chemical formula, gais law and its application; Gibbs - Helmholtz equation: ΔG = ΔH - TΔS formula, chemical reaction isotherm. Difficulty: thermo-chemical equation, gais law and its application; entropy, the free energy; Gibbs - Helmholtz equation: ΔG = ΔH - TΔS formula.

5 Chapter 7 Rate of Chemical Reaction (class hour: 8) [Teaching Objectives] Grasp the concept of chemical reaction rates and reaction rate of experimental determination; understand elementary reactions, complex reaction, the reaction order, reaction molecule number of concepts; master concentration, temperature and catalyst on reaction rate; understand the experimental determination of rate equations and Arrhenius equation for the calculation; a preliminary understanding of the concept of activation energy and its relationship with the relationship between the reaction rate. [Focus and difficulty] Key: Rate equations and rate constants, reaction order and its determination; reaction mechanism of elementary reactions and complexity of the reaction of molecular number; mass action law, the reaction rate laws and reaction mechanism of relationship. Difficulty: Rate equations and rate constants, reaction order and its determination; Arrhenius formula for the calculation.

6 Chapter 8 chemical equilibrium (class hour: 6) [Teaching Objectives] Grasp the concept of chemical equilibrium, understanding the meaning of equilibrium constants; information on the chemical equilibrium calculation; familiar with the chemical equilibrium theory and its applications mobile. [Focus and difficulty] Focus: Chemical Equilibrium Constant Difficulties: The chemical equilibrium constants

7 Chapter 9 Equilibrium of ionization (class hour: 8) Understand the development survey of acid base theory, acquire the proton theory of acid base; acquire the conception of solution acidity and the meaning of ph value, be familiar with the reciprocal conversion between ph and hydrogen ion concentration.. Understand the approximate test of solution ph value. Understand the level-up effect and differentiating effect; be capable of analysing the ionization balance of water, weak acid, weak base by the theory of chemical equilibrium; acquire the factors affecting ionization balance drift, such as common-ion effect, salt effect, etc; be proficient in the calculation of relative ion concentration; comprehend the compose of buffer solution, the theory of buffer effect, the feature of buffer solution. Acquire calculating the ph value of buffer solution; understand the hydrolytic balance of vary salts and calculating the ph value of saline solution. Focal Point: ionization balance of weak monacid and monobase, buffer solution Difficult Point: ionization balance of weak monacid and monobase, buffer solution

8 Chapter 10 Oxidation-Reduction Reaction (class hour: 8) Acquire firmly the fundamental concept of oxidation reduction reaction, be familiar with trimming process of oxidation reduction reaction; apprehend the meaning of electrode potential, be capable of judging relative strength of oxidant or reductant and the trend of oxidation reduction and the calculation of balance constant by standard electrode potential; be capable of dissolving questions as following by Nernst equation: discussing the affection of electrode potential and oxidation reduction by changing ion concentration, the affection of oxidation reduction reaction by medium acidity, and be capable of calculating simply; understand the tautomeric law between electric energy and chemical energy, acquire some conceptions about battery and electrolytic bath such as positive pole, negative pole, etc, realize the mechanism of action on battery and electrolytic bath, and the universal law of separating out product of electrolysis. Focal Point: trimming oxidation reduction equation, standard electrode potential. Difficult Point: the application of Nernst equation, ph electric potential chart and it s application

9 Chapter 11 Rare gas (class hour 2) Acquire the physical property and chemical property of hydrogen; understand the history of discovery about noble gas; understand the property, application, existence of noble gas, and the methods of separating them from air, understand the property and the structural features of noble gas compounds Focal Point: hydrid, the property and the structural features of noble gas compounds Difficult Point: the property and the structural features of noble gas compounds

10 Chapter 12 Halide (class hour: 6) Chapter 13 Oxygen Family Element (class hour 6) Be familiar with the group of oxide, acquire the property and the structure of oxygen, ozone, oxide, superoxide; acquire the structure, property, preparation, application of hydrid, oxide, important oxy-acid and oxysalt; generally realize selenium and tellurium. Focal Point: hydrogen peroxide, oxy-acid of sulfur and oxysalt of sulfur Difficult Point: the structure and property of oxy-acid and oxysalt of sulfur

11 Chapter 14 Nitrogen Family (class hour: 6) Be familiar with the particularity of nitrogen in this family; acquire the structure, property, preparation, application of nitrogen, phosphor and the hydrid, oxy-acid and oxysalt of nitrogen and phosphor; Be familiar with this family element, the transformation rule and the gradual change rule of main oxidation states of this family compound. Focal Point: hydrogen nitride, ammonium salt, derivant of hydrogen nitride; oxy-acid of nitride and oxysalt of nitride, oxysalt of phosphor Difficult Point: the oxidability and reducibility of every oxidation state of nitrogen and phosphor

12 Chapter 15 Coordination Compounds (class hour: 8) Acquire the basic conception of composition and the nature of coordinate bond; be capable of explaining some illustrations by composition valence-bond theory; understand the feature of chelate complex; acquire the meaning and master the application of composition stability constant, and calculate expertly; understand the qualitative change while the composition generating. Focal Point: the basic conception of composition, the stability of composition Difficult Point: the calculation of relative stability constant

13 Chapter 16 Carbon Silicon Boron (class hour 8) Acquire the structure and property of corpus liberum, hydrid, halide, oxide, oxy-acid, and oxysalt of carbon, silicon, boron; be familiar with the electron-defect feature of boron and it s bonding character by the structure and property of boron and it s compounds; realize the similarity and diversity among carbon, silicon, boron; understand the structure and speciality of hydrated silica and metasilicate. c Focal Point: the dissolubility, hydrolyzation property, heat stability of carbonas, silicon alkyl, boranes, oxy-acid and oxysalt of boron Difficult Point: the structure of boron compound

14 Chapter 17 Brief Summary of Non-metallic Element (class hour: 4) Apprehend and acquire the structure, property and variety rule of non-metallic corpus liberum and it s main compounds by the position of elements in periodic table and the feature of atomic structure; train the students to possess the scientific ability of thinking, such as statistic, deduce, synthesis, summary, and to possess the ability of analyzing and resolving problems. Focal Point: acid-base property and it s rule of hydroxide; the structure and it s rule of oxygen negative ion; the strength and it s rule of oxy-acid, such properties as dissolubility, hydrolyzation property, heat stability oxidation-reduction property and the rule of non-metallic oxysalt. Difficult Point: the strength and rule of oxy-acid, such properties as dissolubility, hydrolyzation property, heat stability oxidation-reduction property and the rule of oxysalt.

15 Chapter 18 s-area Metallic Element (class hour: 5) Acquire the existence, corpus liberum property, preparation, application of alkali metal and alkaline-earth metals; acquire the oxide types, structure, property, application of alkali metal and alkaline-earth metals; acquire the varied orbit such as dissolving, acid alkaline barriers, heat stability, oxidation reduction cycle, etc, of alkali metal and alkaline-earth metals hydrde, hydroxide, salts; understand the diagonal rule by comparing the property of lithium to magnesium. Focal Point: smelting process of alkali metal and alkaline-earth metals, the structure and property of corpus liberum and main compounds. Difficult Point: the structure and property of oxide

16 Chapter 19 p-area Metallic Element (class hour: 8) Acquire the property and application of corpus liberum such as aluminum, stannum, lead, stibium, bismuth and main compounds; understand the property varied orbit of compound; acquire the smelting principle and process of aluminum; understand the 6s 2 stability of region P. Focal Point: aluminum and aluminum hydroxide, aluminum salt and aluminate, smelting aluminum, main compounds of stannum, lead, stibium, bismuth. Difficult Point: the property varied orbit of germanium group element, arsenic group element and their compounds.

17 Chapter 20 ds-area Metallic Element (class hour: 6) Acquire the property and application of corpus liberum such as copper, argentum, zinc, hydrargyrum; acquire the property of oxide, hydroxide, main salts of copper, argentum, zinc, and hydrargyrum; acquire the reciprocal transformation between Cu( Ⅰ) and Cu( Ⅱ );Hg( Ⅰ) and Hg( Ⅱ); comparing the property of ⅠA to ⅠB elements;and ⅡA to Ⅱ B elements. Focal Point: copper compounds, argentums compounds, the reciprocal 2+ transformation between Hg 2 and Hg 2+, zinc group composition. Difficult Point: the reciprocal transformation between Cu( Ⅰ)and Cu( Ⅱ); Hg( Ⅰ)and Hg( Ⅱ )

18 Chapter 21 d-area Metallic Element (I) (class hour: 10) Acquire the structural features of transitional element; acquire the property and application of corpus liberum and main compounds of titanium, vanadium, chromium, manganese, ferrum; understand the smelting principle of main metallic elements. Focal Point: general characteristic of transitional element, the property of oxysalt and composition of the first transitional element. Difficult Point: the compositions of ferrum, cobalt, nickel.