Course Module for Chemistry (Course Course-5) Semester-III Session: Course Tittle: Physical Chemistry-II Core Course: CC5 (Theo)

Transcription

1 Transport processes Liquid Course Module for Chemistry (Course Course-5) Semester-III Session: Course Tittle: Physical Chemistry-II Core Course: CC5 (Theo) Fick s law, Flux & force Phenomenological coefficient&their inter-relationship Different transport phenomena &their examples Viscosity and dependence of it on other parameter. Poiseuille s equation &its determination Conductance Basic concept of conductance, specificconductance, ionconductance Variation specificconductance & equivalent conductance with concentration Activity and activity coefficient, mean ionic activity, activity coefficient, ion atmosphere, electrophoretic and relaxation effect. 5 Lectures Onsagar equation, Debye-Huckel theory and the limiting law, solubility of sparingly soluble salts, ionic strength of medium. 5 Lectures Specific and molar conductance, variation with temperature and concentration, Kohrausch s law, transport numbers. Asymmetric effect, electrophoretic effect Conductometric titration. Conductance & solubility product Ostwald dilution law & its limitation 8 Lectures Transport number Transport number and its determination Principle of Hittrof s rule & moving boundary method Debye-Falkenhagen effect & Walden s rule Application of thermodynamics-1

2 Chemical potential & partial molar properties Relation between chemical potential with G, H,U & S Concept of fugacity &fugacity coefficient Gibbs Duhem equation &binary system Calculation of ΔG,ΔH,ΔS &ΔU for binary solutions Chemical equilibrium Condition of spontaneity of a reaction and equilibrium. 3 Lectures Concept & definition of Kp, Kc&Kx for different reactions s van thoffs reaction isobar &isochore Le Chatelier principle& its quantitative expression Nernst distribution law Nernst distribution law&its statement, explanation limitation Application for KI+I 2 =KI 3 reaction Application for dimerization reaction Chemical potential and other properties in pure & mixture Chemical potential for ideal gas & in mixture Concept of standard state & thermodynamic functions Concept of ideal solution and its deviation Ideal solution and Raoult,s law and Henry s law. Foundation of Quantum mechanics Electromagnetic radiation and its properties Wave-particle duality Photoelectric effect, Compton effect & mathematical equations 3Lectures Concept of electron as wave de Broglie hypothesis & uncertainty relation Wave Functions Time-independentSchrÖdinger equation& wave function Condition of acceptability of wave functions & physical interpretation Concept of operators Elementary concept of operators

3 Eigen function &eigenvalues, their expression & calculations Commutation & uncertainty relation between two operators Hermitian operators & postulates of quantum mechanics Particle in a box Construction of SchrÖdinger equation for particle in a 1D box & its solution. Normalization, orthogonality, probability distribution calculations of wave function regardingparticle in a 1D box Calculations of expectation value of x, x 2 2, P x & P x 3Lectures Degeneracy in energy levels Simple Harmonic Oscillator Concept simple harmonic oscillator model Construction of SchrÖdinger equation forsimple harmonic oscillator & energy expression Expression of wave functionsforsimple harmonic oscillator for n=1 & n=2 Course Tittle: Physical Chemistry-II Core Course: CC5 (Practical) Determination of viscosity of unknown liquid (glycerol, sugar) w.r.t water Determination of partition coefficient of I 2 in water & CCl 4 Determination of equilibrium constant for KI+I 2 =KI 3 reaction by partition method Conductometric titration of acid with base Study of saponification reaction conducmetrically Verification of Ostwald s Dilution law. Course Code: Generic Elective-3 + CC (Gen) Theory Course Tittle: Chemical energetics, equilibria, organic chemistry-ii Chemical energetics Extensive property & intensive properties s System and surroundings. Derivatives, exact differentials, state and path functions.

4 Reversible and irreversible processes and their mathematical derivations and different processes like isothermal and adiabatic etc. 8 Lectures Zeroth law, first, second law of thermodynamics and their mathematical implications. Different functions like H, U, G and their relations Chemical Equilibrium Condition of spontaneity of a reaction and equilibrium. Concept & definition of Kp, Kc&Kx for different reactions van thoffs reaction isobar &isochore Le Chatelier principle & its quantitative expression Ionic Equilibria Oswald s dilution law, ph, Kw, buffer solution. Hydrolysis of salts, indicator. Solubility & solubility product of a sparingly salt Aromatic hydrocarbon Synthesis, reactions with mechanism Organometallic compounds Grignard reagents & their preparations Synthesis of different compounds from Grignard reagents Reformatsky reaction & other reaction Aryl halide Synthesis of different types of Aryl halides Some important name reactions of these compounds Nucleophilic aromatic substitution reactions Alcohol, phenols, ethers Synthesis of primary, secondary & tertiary alcohols usinggrignard reagents fromdifferent substrates Different types of reaction of alcohols 6 Lectures 3 Lectures s 6 Lectures 8Lectures

5 Preparation of diols using oxidation method (with OsO 4 ) Pinacol-pinacolone rearrangement reactions Phenols Synthesis of phenols Some important reactions using phenols Ethers Williamson s ether synthesis Reactions with ethers Cleavage of ethers using HI Carbonyl compounds Discussion on aromatic & aliphatic aldehydes and ketones Their synthesis fromgrignard reagents& also from other reagents Properties of aldehydes & ketones Reactions with HCN, ROH, NaHSO 4,NH 2 -G 5Lecture 2Lecture 4Lectures 4Lectures Course Code: Generic Elective-3 + CC (Gen) Practical Course Tittle: Chemical energetics, equilibria, organic chemistry-ii Measurement of ph of different solutions like fruit juices, shampoo, soap using ph meter. Determination of ph of unknown buffer solution by colour matching method. Study of solubility of benzoic acid in water. Identification of different pure organic compounds (solid & liquid).