On-line Analyzers. Process Liquids Process Water

Transcription

1 Analycal Measurements for Process Control On-line Analyzers Process Liquids Process Water Masters in Analycal Technology.

2 When crical processes depend on crical data, how will you make the right decision? Manufacturing industries are continuously trying to improve performance, efficiency or safety by means of process control. Suitable analyzer technology is the first step in order to manage the total package of your assets and can take your process performance to a higher level. High reliability, few installation costs and a reasonable total cost of ownership are significant savings required by industrial operations. AppliTek s analytical technology helps you to achieve these goals and raise your standards in process control. APPLITEK Process Liquids and Process Water 02

3 Enhanced Process Control AppliTek analycal packages: Reliability Flexibility Safety Trustability Responsibility The last years AppliTek expanded significantly its portfolio of measurement and monitoring products in order to be able to offer suitable products for nearly every application with an attractive price-performance ratio. Through continuous innovation and field experience AppliTek is able to provide you with the latest and most advanced analyzer equipment designed for 24/7 measurements in your process. Profitable solutions are available for every production process, sub process and application. Chemical & Petrochemical Vent gas scrubbers Liquid soaps Acid streams Fertilizer production Bleach production Brine purification Sour water strippers Pulp & Paper Pulping liquids Treatment baths Steel & Metal Plating baths Etching baths Scrubber units Cokes production Process water Power generation Cooling water Boiler feed water Recirculation water Cogeneration Solar thermal energy Semiconductor Wafer clean process Plating baths Etching baths Developer solutions Automobile Phosphating baths Etching baths Recirculation water Food & Beverage Water content Process water Sauces & juices Mining Purification process Cyanide leaching Zinc leaching Process water Desalination & Demineralization Organic fouling Demineralization process Storage and distribution Stand-alone and Integrated Analycal Soluons for Manufacturing and Ulity Industries APPLITEK Process Liquids and Process Water 03

4 D a t a e x c h a n g e - S u p e r v i s i o n t o o l s From real-me visualizaon to trouble-shoong: Full integraon and communicaon of AppliTek process analyzers within industrial producon sites and corporate networks. Industrial grade controllers All AppliTek on-line analyzers (process/water) are equipped with industrial grade controllers optimized for their tasks. The colour touch screens (size 10.4 or 5.7, depending on model) act as human interfaces with an excellent viewing angle and swift response to touching. Back-up: all data is automatically retained in case of power failure. Flexible communication options All AppliTek process analyzers come with industrial 4-20 ma outputs, the most common analogue transmission standard available. Ethernet communication by means of the industrystandard TCP/IP protocol enables easy and reliable integration into existing corporate networks. MODBUS interfacing is possible to assure full integration and communication with distributed control systems (DCS). Control Room Remote screen sharing Plant engineers, maintenance engineers and other authorized users can remotely take over the analyzer screen (the client) by means of LAN Ethernet software (such as VNC). Authorized users can carry out all manual operations and settings from a remote PC. Conduct trouble-shooting before doing any physical intervention, grab cross-platform screenshots for reports or presentations, the possibilities are endless. System integrated solutions HOST AppliTek manufactures and commissions analyzer shelters addressing the needs of customers wishing to monitor a complex set of parameters in a single integrated system. In that case, data collection is assured inside the shelter and transmitted through the network or an existing telephone line. If necessary, a special computer cabinet can be installed in the control room to protect the main control/visualization data computer system. APPLITEK Process Liquids and Process Water 04

5 Data exchange - Supervision 4-20 ma industry standard Results, trendings Logs, alarms Data graphs Control & simulation of wet parts Calibration, validation program s Setup (I/O, communication, preconditioning) Results, trendings Logs, alarms Calibration, validation Setup (I/O, communication, preconditioning) CLIENT Screen sharing on remote desktop TCP / IP LAN PROCESS Turnkey analysis projects General purpose zone / Ex-proof Scope of supply: System integrated analyzer shelter Analyzers & instrumentation Sample preconditioning systems Ventilation/heating/AC Safeguarding systems Recovery systems Data acquisition & control systems Sample recovery systems Sample transport lines APPLITEK Process Liquids and Process Water 05

6 A p p l i T e k S e r i e s o f U P A / I P A P r o c e s s A n a l y z e r s Single and mul parameter on-line analysis for a multude of manufacturing industries. Titration ISE Colorimetry AppliTek s Universal Process Analyzer is the state of the art multi parameter analyzer platform enabling operators to monitor precisely critical process parameters. The unique on-line analyzer has been designed to run chemical analysis on most liquid process samples and outclasses other similar analyzer designs, thanks to an extended set of analytical and communication features. UPA Universal Process Analyzer 10 ¼ incorporated industrial panel PC with excellent graphics and running AppliTek controller software Digital outputs: up to 24 DO (24 VDC) and 6 DO (220 VAC) Digital inputs: up to 8 DI Up to 8 analog inputs Data logging of 1000 last recorded results Complete separation between wet part and electronics Data logging of last 30 titration curves (for titrators) Multiple streams (up to 8, application depending) ATEX configuration in accordance with 94/9/EC directive APPLITEK Process Liquids and Process Water 06

7 Industrial process liquids IPA Industrial Process Analyzer The IPA Industrial Process Analyzer is a single parameter wetchemical analyzer with a similar hardware and software architecture as the Universal Process Analyzer. Providing top quality with an affordable price tag, the system features all relevant smart and automatic functions and proven chemistry methodologies. 5 ¾ color touch screen with function buttons Digital outputs: up to 12 DO (24 VDC) and 6 DO (220 VAC) Digital inputs: up to 2 DI Up to 3 analog inputs Data logging of 1000 last recorded results Up to 3 streams Complete separation between wet part and electronics Industries and their typical parameters For a complete overview of all feasible parameters, please see page 8-9. Chemical - Petrochemical 4-tertiary-butylcatechol Acetic acid Acidity Ammonia Bromine Index Caustic Chloride Chlorine Cyanide Ethyl acetate Fluoride Hardness Hydroxide Hypochlorite Moisture Phenol Silica Sodium Sodium hydroxide Sulphate Sulphide Sulphuric acid TMAH Total Hydrocarbons Semiconductor Acetic acid Ammonia Copper EDTA Fluoride Hydrochloric acid Hydrogen fluoride Hydrogen peroxide Total and free acid Sulphuric acid Pulp & Paper ABC analysis Acidity Acrylonitrile Alkalinity Bromide Bromine Index Calcium Carbonate Caustic Chlorate Free Chloride Hydrogen peroxide Hypochlorite Lime ph Phenol Sodium hydroxide Sulphate Sulphide Sulphite Thio cyanate Mining Acidity Alkalinity Ammonium Aluminium Carbonate Chloride Chromic acid Copper Cyanide EDTA Hydrochloric acid Iron II Iron III Nickel Silver Sulphuric acid Total Cyanide Zinc Wet chemistry hardware Standard (all models) Colorimetric configuration: photometer (insensitive to ambient light) and analysis cuvette with magnetic stirrer Titrimetric configuration: titration vessel with magnetic stirrer, precision dispenser, additional electrodes Ionometric (ion-selective) configuration: analysis vessel with magnetic stirrer, precision dispenser for standard addition, high quality ISE electrodes Options Smart solutions that reduce unnecessary interventions and down-times: Leak detection senses any liquid spills in the wet part of the on-line analyzer and will be recorded and communicated by the analyzer s industrial controller. Sample presence detection can be installed internally or externally and gives the opportunity to generate alarms to operators or control centers in case there is no sample. APPLITEK Process Liquids and Process Water 07

8 A p p l i T e k S e r i e s o f U P A / I P A P r o c e s s A n a l y z e r s Methodology Parameter 4-tertiary-butylcatechol ABC analysis Acetic acid Acidity Acid number Acrylonitrile Aldehyde Alkalinity Aluminium Aluminium chloride Ammonia Ammonia/Nitrate Aniline Anion active surfactants Benzoic acid Bicarbonate Boric acid Bromine index Calcium Calcium oxide Caprolactam Carbonate Carbon oxide Caustic Chemical Oxygen Demand Chlorate Chloride Chlorine Chromium III Chromium VI Copper Cyanide Fatty acids Fluoride Formaldehyde Formic acid Free Chloride Free Cyanide Hardness Hydrazine Hydrochloric acid Hydrogen peroxide Hydroquinone Hydroxide Hydroxylamine Titration Colorimtery Ion-selective Methodology Titration Colorimtery Ion-selective Parameter (continued) Hypochlorite Iron II Iron III Lime Magnesium Metabisulphite Moisture Na/P molar ratio Nickel Nitrate Nitric acid Oleum Ortho-phosphate Oxalic acid P&M number Peracetic acid Permanganate Peroxide Persulphate ph Phenol Phosphate Phosphoric acid Phthalic acid Poly vinyl alcohol Potassium Potassium hydroxide Potassium iodate Potassium iodide Redox Silica Silver Sodium Sodium hydroxide Sodium sulphate Strontium carbonate Sulphate Sulphide Sulphite Sulphonic acid Sulphuric acid Thio cyanate TMAH Tri ethyl amine Tri methyl amine Zinc APPLITEK Process Liquids and Process Water 08

9 List of process parameters TOTAL parameters Methodology Titration Colorimtery Ion-selective Methodology COMBINED parameters * Titration Colorimtery Ion-selective Total acid Acidity and Chloride Total alkalinity Acidity and Diphosphorous Pentoxide Total ammonia Alkalinity and Calcium Total chlorine Aluminium and Sulphuric acid Total chromium Total cyanide Total iron Total phosphate Aluminium, Zinc and Sulphuric acid Ammonia, Iron II and Iron III Ammonia and Sulphide Ammonia and Hydroxylamine Blended acids Calcium and Magnesium Carbonate and Chloride Copper and Sulphuric acid Copper, Nickel and Zinc Fluoride and ph Fluoride, free acid and total acid Hydroquinone and Peroxide Hydroxide and Carbonate Mixed acids Na/P ratio and Phosphate Na2O and AZ number Sodium hydroxide, sodium sulphide and sodium carbonate ABC analysis Total and free acid Total and free ammonia Total iron, Iron II and Iron III Total chromium, Cr III and Cr VI Total and free chlorine Zinc and Sulphuric acid * UPA platform only APPLITEK Process Liquids and Process Water 09

10 EnviroLyzer Series of On-line Water Analyzers Single parameter, cost-effec ve on-line analysis for industrial water applica ons. Challenges for water management Boiler feed water monitoring Managing both quantity and quality of water resources is a challenging task for companies, utility industries and authorities. The second generation EnviroLyzer Series of On-line Water Analyzers, originally introduced in 2009, harness all the technology of AppliTek s reference process analyzers and enable companies to measure and monitor quickly and effectively all the relevant parameters in the water source. With an impressive list of water quality indices, the EnviroLyzer Series come factory configured as single parameter, single methodology analyzers. Steam cycle analysis Drinking water monitoring Waste water monitoring Cooling water monitoring Anaerobic digestion control Design - Features Titration, colorimetry or ion-selective electrode (ISE) Ethernet TCP/IP based connection Single methodology and single parameter Reduced down-time by smart features and add-on units Straight-forward design, reduced reagent consumption Data logging of 1000 last recorded results High quality sample pump, micropumps, vessel, tubing Complete wet part - electronics separation Incorporated industrial panel PC with AppliTek controller Available in Ex-proof configuration complying with ATEX or software NEC500 directives APPLITEK Process Liquids and Process Water 010

11 Process water Enclosures - Configurations The EnviroLyzer Series of On-line Water Analyzers are equipped with a new compact dust- and splash-proof analyzer enclosure consisting of a powder coated steel back, combined with an ergonomic ABS hinged part. Purging with instrument air is possible in case of extreme humidity or risk of accumulation of corrosive gases. Where site-specific requirements may compromise the analyzer s potential, optional enclosures/configurations are available. If necessary, the analyzer can be integrated in various protective enclosures such as an IP65 rated protective cabinet for outdoor use. For hazardous areas, the analyser is integrated in a protective enclosure with all necessary connections, special analytics and control units, a stand-alone system factory tested to fully meet ATEX or NEC 500 directives. Methodology Colorimtery Ion-selective Titration Parameter Acetic acid Acidity Alkalinity Aluminium Ammonia Bicarbonate Biocides Boron Calcium Chloride Chlorine Chlorine dioxyde Chlorite Chromium III Chromium VI Color Copper Cyanide (free) Fatty acids Fluoride Formaldehyde Hardness (total) Hydrazine Hydrochloric acid Hydrogen fluoride Hydroxide Iron II Iron III Magnesium Manganese Nickel Nitrate Nitrite Oxalic acid Permanganate Phenol Phosphate Phosphoric acid Potassium hydroxide Silica Silicium dioxyde Sodium Sodium hydroxide Sodium hypochlorite Sulphate Sulphide Sulphite Sulphuric acid Thio cyanate Total hardness Urea Zinc APPLITEK Process Liquids and Process Water 011

12 A p p l i T O C S e r i e s o f O n - l i n e T O C A n a l y z e r s TOC as a measure of organic load The AppliTOC Series of On-line TOC Analyzers enable continuous and reliable monitoring of organic compounds in water, by means of the low-temperature UV/persulfate oxidation method. Automatic smart functions such as autocleaning, as well as programmable auto-calibration and auto-validation are standard features, controlled by the AppliTek industrial grade controller. Operation is made easier, reliable data are assured and unnecessary operator intervention is minimized. Analytical mainframe: configurations Total Organic Carbon (standard) Measurement of non purgeable organic carbon (NPOC) Total Inorganic Carbon (TIC) Measurement of inorganic carbon compounds (including volatile organic compounds) Total Carbon (TC) Measurement of all carbon compounds (with single IR detector) True Total Organic Carbon Measurement of true TOC (= TC TIC, with double IR detector) AppliTOC Series of On-line TOC Analyzers True continuous analysis High quality sample, transfer and addition pumps for acid and persulfate, mass flow meter, dual wavelength IR detector Compliant with standard methods USEPA 415.2, ISO 8245 and DIN-EN ¾ color touch screen with buttons for immediate access Standard auto-cleaning, auto-validation, auto-calibration Data logging of 1000 last recorded results Complete wet part / electronics separation Factory configured, tested and calibrated APPLITEK Process Liquids and Process Water 012

13 V P A V o l t a m m e t r i c P r o c e s s A n a l y z e r Trace level determination of heavy metals VPA Voltammetric Process Analyzer is a fully automatic on-line analyzer system for the simultaneous determination of a wide range of hazardous heavy metals in water. The whole system consists of an industrial controller, a number analytical units (depending on choice of metals), a complete sample preparation unit and reagent containers, all built and enclosed in a floorstanding cabinet. Measurement of total heavy metal content Accuracy, precision and stability of results are very critical when monitoring for heavy metal contents in water samples by photometric and electrochemical methods. The VPA can be equipped with an optional add-on unit to digest organics, while suspended particles can be dissolved completely. The new digestion unit is conform with US EPA Method or and processes samples with concentrated acids and oxidizing agents at high temperature. Parameter Antimony Bismuth Cadmium Chromium III Chromium VI Copper Iron II Iron III Lead Manganese II Manganese VII Mercury Nickel Selenium Silver Thallium Tin Zinc Methodology Colorimetry Voltammetry VPA Voltammetric Process Analyzer Advanced voltammetric principle allowing for high sensitivity and low reagent consumption Batch operation principle limits loading of the electrode and allows to program at will the analysis sequence Up to three (3) sampling points possible Built-in sample pretreating digestion unit (optional) 5 ¾ color touch screen with buttons for immediate access Standard auto-calibration / automatic background correction Data logging of 1000 last recorded results Complete wet part / electronics separation Factory configured, tested and calibrated APPLITEK Process Liquids and Process Water 013

14 AppliTek R&D Values at a Glance APPLITEK Process Liquids and Process Water 14

15 R & D Values Reliability As a specialist manufacturer of on-line analyzers, we are challenged with offering our customers the best in industrial grade analytics for on-line monitoring of liquids, from stand-alone analyzers to complete industrial monitoring systems. All hardware components are carefully selected, with industrial computers / human interfaces controlling the operation. Results: massive amounts of process data are reliably measured, logged and communicated in a seamlessly easy way to plant managers or control centers. Flexibility The incorporated software flexibility minimizes physical operator intervention. The analyzer screen (the client) can remotely be taken over by means of LAN Ethernet software (such as VNC software). Authorized users can carry out all necessary manual operations and settings from a remote PC using a modem, internet or intranet connection. Safety Standard general purpose zone, optionally conform ATEX or NEC500. Industrial needs are to be met by industrial solutions. AppliTek can meet strict regulations for the construction, including materials as well as design requirements in hazardous locations. On top of that, all automatic features that come standard with AppliTek on-line analyzers are also included in the ex-proof design. Special attention is given to wet parts that come in direct contact with process streams. Trustability Trustability is the currency of exchange between you, the customer, and our company. A proven track record of 25 years of analytical technology is at your service. AppliTek s quality approach is visible in all steps of the delivery chain, from the initial design up to quality control. Moreover, the best suited analytical technique in function of your application is implemented as a part of the total framework approach. ENGINEERED & MANUFACTURED BY APPLITEK n.v. NAZARETH BELGIUM TEL: (32) FAX: (32) team@applitek.com Responsibility AppliTek supplies you with the ideal formula for all your needs in process monitoring. From the application and feasibility study to basic engineering to the final implementation of the analyzer system, AppliTek is and remains your single partner. AppliTek s symbiosis between analytical expertise and system integration guarantees you a complete solution for a measuring problem, not merely supply of an analyzer. APPLITEK Process Liquids and Process Water 15

16 About the company AppliTek AppliTek is an established manufacturer of on-line analyzers applied to environmental compliance, water treatment and industrial process applications. The incorporated technology benefits from a large experience in wetchemical techniques since 1985, combined with powerful interfaces, high quality components and ergonomic design. Our company has also evolved to a provider of analytical technology and on-line monitoring solutions for several industries, including Oil & Gas, Mining, Chlor-alkali, Pharmaceutical, Food & Beverage, Chemical and Water Utility industries. Products & Soluons On-line analyzers Accessory equipment: preconditioning filtration systems Turnkey analyzer projects Feasibility Application studies AppliTek NV/SA Industrial Zone «De Prijkels» Venecoweg 19 B-9810 Nazareth Belgium Tel.: For USA call: (toll free) Fax.: team@applitek.com Visit us on Follow us on Facebook Revision July AppliTek NV Printed in Belgium In accordance with its policy of continued product improvement, AppliTek reserves the right to change specifications without further notice. UPA, IPA, VPA, Envirolyzer and AppliTOC are registered trademarks and property of AppliTek NV. Our company is registered under Reg. Nr.: BE RPR Gent