Graphene Chemistry. Family of Graphene: Timeline of selected events in the history of the preparation, isolation and characterization of graphene.
|
|
- Gwendolyn Cunningham
- 5 years ago
- Views:
Transcription
1 Karla S. Feu Topics included in this group meeting: Graphene background, synthesis, application as catalysts, characterization and perspectives. Family of Graphene: Not covered in this group meeting: Applications in photocatalysis, sensors, supercapacitors, drug delivery and Full cells/. UPAC definition: Graphene is a single carbon layer of the graphite structure, describing its nature by analogy to a polycyclic aromatic hydrocarbon of quasi infinite size. Why study graphene and its derivatives? Graphene is an exciting and unique material which shows peculiar electronic, optical, mechanical and chemical properties, among others, which have found application in numerous scientific and technological areas. Synthetic rganic Chemistry? Graphene? Can we make organic synthesis on two-dimensional planes? rganic chemistry can be defined as the the study of the structure, properties, reactions, and preparation of carbon-containing compounds Graphene, as others hydrocarbons, can undergo many reactions in order to afford necessary flexibility to adapt it into specific performances. Timeline of selected events in the history of the preparation, isolation and characterization of graphene Blakely and co-workes prepare monolayer graphite by segregation carbon on the surface of Ni(100); several subsequent reports follow Morgan and Somorjai obtain LEED patterns produced by smallmolecule adsorption onto Pt(100) Graphite oxide prepared by Schafhaeutl, Brodie, Staudenmaier, ummers and others Boehm and co-workers prepare reduced graphene oxide (rg) by the chemical and thermal reduction of graphite oxide May interprets the data collect by Morgan and Somorjai as the presence of monolayer of graphite on the Pt surface Boehm and co-workers recommend that the term graphene be used to describe single layers of graphite-like carbon van Bommel and co-workers prepare monolayer graphite by subliming silicon from silicon cabide uoff and co-workers micromechanically exfoliate graphite into thin lamellae comprised of multiple layers of graphene UPAC formalizes the definition of graphene: The term graphene should be used only when the reactions, structural relations or other properties of individual layers are discussed Dreyer et al. ACE. 2010, 49, Geim and co-workers prepare graphene via micromechanical exfoliation; numerous reports follow
2 Synthesis of Graphene and its derivatives Graphene layers without functionalization are insoluble and infusible, which limits their application capabilities. The essential purpose of graphene derivatisation is to tailor its physical and chemical properties.the synthesis of graphene derivatives can be divided in two major process: a) bottom-up and b) top-down. verview of Principals Methods of Synthesis for Graphene-based Materials: Chemical xidation ummers method (1958) ther methods: Brodie, Staudenmaier, ofman and Tour. Advantages: Most Used method, Large scale production, Medium quality GM. Disadvantages: mpurities and defects, GM of low electrical conductivity, Large production of liquid wastes. Mechanical exfoliation Advantages: igh quality graphene Disadvantages: Time consuming, Low production. Chemical vapor deposition (CVD) Advantages: igh quality graphene, absence of impurities. Disadvantages: Low production. Pyrolysis of precursors Advantages: Low cost, Large scale production, Green synthesis method, easy doping. Disadvantages: Medium quality graphene. ummers method and subsequent sonication Wang et al. Nat. ev. Chem. 2017, 2, Navalon et al. Chem. ev. 2014, 114, Graphene oxide (G) Proposed structure of G based on the Lerf Klinowski model G is currently the principal precursor used for the synthesis of graphene materials. Morover, G itself has attracted considerable attention due the oxygen functional groups on its surfaces. G has attracted considerable attention as potential material for use in photovotaic cells, capacitors, sensor and catalysis.
3 Synthesis of Graphene-based Materials: G - simplified structure G as starting material: Graphene (G) as starting material: G a) b) + e- -N 2 N 2 N 2 Fluorographene (FG) as starting material: F F F BrMg F F F F FG -N 2 N 2 X N N N 2 NC X X 1. NaB 4 or 2. K/ 2 or 3. N 2 4 G SCl 2 or DCC, DMAP 1. (CF 3 C) 2,acidic alumina 2. Fe NaN 3 N N N N 3 Fe mchair edge Diagram of Active Sites of Graphene - Based Nanomaterials Solid acids C N N N N S 3 Zigzag edge π-system Amine N 2 Pyridine N Active defects sites Solid bases Ma et. al. ACS Catal. 2016, 6, Quinone-diol redox site X=, N Navalon et al. Chem. ev. 2014, 114, 6179.
4 Application as catalysts: G 34-80% yield 21 examples 1 2 Fan et al. Asian JC 2018, 7, 355. C-C coupling NC CN N 2 ne-pot enry-michael 87% yield 6 x recycled Zhang et al. ACS Appl. Mat. nterfaces 2015, 7, C- coupling 0-92% yield 15 examples 5 x recycled Gao et al. ACE 2016, 55, = Graphene oxide (G) 68-82% yield 20 examples 5 x recycled C 3 S N Synthesis of thioethers Alkylation of enes odination Basu et al. SC Adv. 2013, 3, Zhang et al. ChemCatChem 2018, 10, 376. G as catalyst C-N coupling Sulfoxidation S S 35-92% yield 29 examples a-ketoamides Majumdar et al. ACS Sustain. Chem. Eng. 2017, 5, Me or 81% yield Goncalves et al. Chem. Commun 2014, 50, % yield (mono) 20, 6 examples 40% yield 4 x recycled Alkylation of enes 57-99% yield 15 examples 82-95% yield 2 examples u et al. JACS 2015, 137, Me 1 2 Proposed mechanism G 1 1 = = Me Me Me G, air CCl 3, 100 C Me Me =, 82% = Me, 95% 1 G 1 Me G Me 1 1 G (200 wt%), air CCl 3, 100 C u et al. JACS 2015, 137, Me 2 1 G 1 Me via 1 2
5 C-C coupling odination G (40mg) C 3 CN, 100 C, argon, 12h or G(20mg), 2 (1.1 equiv) C 3 N 2 (0.7 ml) 120 C, 1h, air or G shell G shell G shell Proposed mechanism Proposed mechanism G shell adical coupling nitiation Fan et al. Asian JC 2018, 7, 355. SET e Application as catalysts: rg omatization adical addition 2 2 Zhang et al. ChemCatChem 2018, 10, 376. k rg Proposed mechanism rg 333K rg k 3 By-products rg, MeCN % yield 5 x recycled Yang et al. Energy Environ. Sci. 2013, 6, 793.
6 Characterization Techniques: Analytical Techniques: *Atomic emission (AES), *absorption spectroscopy (AAS) or *inductively coupled plasma mass spectrometry (CP -MS): Presence of metal impurities. *Combustion elemental analysis: composition *TPD: thermal stability Spectroscopy: functional groups and metal oxidation date *aman *FT- *XPS *UV-Vis *Solid-state NM Textural characterization BET: surface area of powders XD: crystallinity and stacking Microscopy (M): morphology and single layer confirmation *Transmission electron M (TEM) *Scanning electron M (SEM) *Atomic force M (AFM) *Elemental mapping (Energy dispersive X-ray) Thermal Analysis: interaction with oxidizing reducing agents *Thermogravimetry *Thermodesorption aman XPS UV-vis SS-NM Adsorption isotherm: BET PXD Thermal analysis: ATG
7 TEM SEM AFM Energy dispersive X-ray: EDX thers Appllications and Perspectives: # Lithium ion battery # Solar cells # Supercapacitores #Bio applications # Sensors # Water desalination
8 Applications : Biosensors Schematic of the Desorption Mechanism of the Probe DNA adsorved on G, driven by the addition of (A) cdna and (B) Non-cDNA Park et al. Langmuir 2014, 30, Perspectives # More complex derivatives of graphene; # The research should also focus on well defined graphene; # A more intensive collaboration between synthetic chemists, polymer chemists and biologists; # n the field of catalysis, the exploration in the unchartered territory of enantioselective transformations; # The potencial of the graphene-based materials are huge and still in the begin.
Highly doped and exposed Cu(I)-N active sites within graphene towards. efficient oxygen reduction for zinc-air battery
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information (ESI) for Energy & Environmental Science.
More informationNanostrukturphysik Übung 2 (Class 3&4)
Nanostrukturphysik Übung 2 (Class 3&4) Prof. Yong Lei & Dr. Yang Xu 2017.05.03 Fachgebiet 3D-Nanostrukturierung, Institut für Physik Contact: yong.lei@tu-ilmenau.de (3748), yang.xu@tuilmenau.de (4902)
More informationperformance electrocatalytic or electrochemical devices. Nanocrystals grown on graphene could have
Nanocrystal Growth on Graphene with Various Degrees of Oxidation Hailiang Wang, Joshua Tucker Robinson, Georgi Diankov, and Hongjie Dai * Department of Chemistry and Laboratory for Advanced Materials,
More informationSupplementary Information for
Supplementary Information for Facile transformation of low cost thiourea into nitrogen-rich graphitic carbon nitride nanocatalyst with high visible light photocatalytic performance Fan Dong *a, Yanjuan
More informationSupporting Information
Supporting Information Hierarchical Porous N-doped Graphene Monoliths for Flexible Solid-State Supercapacitors with Excellent Cycle Stability Xiaoqian Wang, Yujia Ding, Fang Chen, Han Lu, Ning Zhang*,
More informationOptical Science of Nano-graphene (graphene oxide and graphene quantum dot) Introduction of optical properties of nano-carbon materials
Optical Science of Nano-graphene (graphene oxide and graphene quantum dot) J Kazunari Matsuda Institute of Advanced Energy, Kyoto University Introduction of optical properties of nano-carbon materials
More informationraw materials C V Mn Mg S Al Ca Ti Cr Si G H Nb Na Zn Ni K Co A B C D E F
Today s advanced batteries require a range of specialized analytical tools to better understand the electrochemical processes that occur during battery cycling. Evans Analytical Group (EAG) offers a wide-range
More informationGraphene films on silicon carbide (SiC) wafers supplied by Nitride Crystals, Inc.
9702 Gayton Road, Suite 320, Richmond, VA 23238, USA Phone: +1 (804) 709-6696 info@nitride-crystals.com www.nitride-crystals.com Graphene films on silicon carbide (SiC) wafers supplied by Nitride Crystals,
More informationSulfur-bubble template-mediated synthesis of uniform porous g-c 3 N 4 with superior photocatalytic performance
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Sulfur-bubble template-mediated synthesis of uniform porous
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Experimental section Synthesis of Ni-Co Prussian
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 214 Electronic Supplementary Information Ultrathin and High-Ordered CoO Nanosheet
More informationSelf-Growth-Templating Synthesis of 3D N,P,Co-Doped. Mesoporous Carbon Frameworks for Efficient Bifunctional
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Self-Growth-Templating Synthesis of
More informationCarbon Quantum Dots/NiFe Layered Double Hydroxide. Composite as High Efficient Electrocatalyst for Water
Supplementary Information Carbon Quantum Dots/NiFe Layered Double Hydroxide Composite as High Efficient Electrocatalyst for Water Oxidation Di Tang, Juan Liu, Xuanyu Wu, Ruihua Liu, Xiao Han, Yuzhi Han,
More informationSupporting Information
Supporting Information Wiley-VCH 2013 69451 Weinheim, Germany 3D Honeycomb-Like Structured Graphene and Its High Efficiency as a Counter-Electrode Catalyst for Dye-Sensitized Solar Cells** Hui Wang, Kai
More information3D Boron doped Carbon Nanorods/Carbon-Microfiber Hybrid Composites: Synthesis and Applications as Highly Stable Proton Exchange Membrane Fuel Cell
Electronic Supplementary Information for Journal of Materials Chemistry 3D Boron doped Carbon Nanorods/Carbon-Microfiber Hybrid Composites: Synthesis and Applications as Highly Stable Proton Exchange Membrane
More informationEnergy Storage. Light-emitting. Nano-Carbons. H 2 Energy. CNT synthesis. Graphene synthesis Top-down. Solar H 2 generation
Nano-Carbon battery Graphene synthesis Top-down CNT synthesis CVD reactor hydrocarbon gas Catalyst CNTs Chemical Modification COO O NO 2 COO COO COO Bottom-up O O NO NO 2 2 COO COO Nano-Carbons 20 nm Light-emitting
More informationInternational Journal of Scientific & Engineering Research, Volume 5, Issue 3, March-2014 ISSN
156 Copper Nanoparticles: Green Synthesis Characterization Y.Suresh*1, S.Annapurna*2, G.Bhikshamaiah*3, A.K.Singh#4 Abstract Present work describes the synthesis nanoparticles using papaya extract as a
More informationGraphene Fundamentals and Emergent Applications
Graphene Fundamentals and Emergent Applications Jamie H. Warner Department of Materials University of Oxford Oxford, UK Franziska Schaffel Department of Materials University of Oxford Oxford, UK Alicja
More informationShape control and formation of tin oxide particles in organic medium
52th Young Ceramist Social Gathering Summer Seminar 2016.06.24 Shape control and formation of tin oxide particles in organic medium Nguyen Thanh Mai Laboratory of Novel Materials Hybrid Engineering Graduate
More informationSupporting Information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2019 Supporting Information Atomically dispersed Ni as the active site towards selective hydrogenation
More informationEfficient Hydrogen Evolution. University of Central Florida, 4000 Central Florida Blvd. Orlando, Florida, 32816,
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2017 MoS 2 /TiO 2 Heterostructures as Nonmetal Plasmonic Photocatalysts for Highly
More informationHigh-Performance Flexible Asymmetric Supercapacitors Based on 3D. Electrodes
Supporting Information for: High-Performance Flexible Asymmetric Supercapacitors Based on 3D Porous Graphene/MnO 2 Nanorod and Graphene/Ag Hybrid Thin-Film Electrodes Yuanlong Shao, a Hongzhi Wang,* a
More informationSupporting Information Available:
Supporting Information Available: Photoresponsive and Gas Sensing Field-Effect Transistors based on Multilayer WS 2 Nanoflakes Nengjie Huo 1, Shengxue Yang 1, Zhongming Wei 2, Shu-Shen Li 1, Jian-Bai Xia
More informationReviewers' Comments: Reviewer #1 (Remarks to the Author)
Reviewers' Comments: Reviewer #1 (Remarks to the Author) The manuscript reports the synthesis of a series of Mo2C@NPC-rGO hybrid HER electrocatalysts by employing the precursor of PMo12 (H3PMo12O40)-PPy/rGO
More informationSupplementary Figure 1 A schematic representation of the different reaction mechanisms
Supplementary Figure 1 A schematic representation of the different reaction mechanisms observed in electrode materials for lithium batteries. Black circles: voids in the crystal structure, blue circles:
More informationSupporting Information. Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive Photocatalyst for the Suzuki Coupling Reaction**
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Graphene Oxide-Palladium Modified Ag-AgBr: A Novel Visible-Light- Responsive
More informationSupporting Information. CdS/mesoporous ZnS core/shell particles for efficient and stable photocatalytic hydrogen evolution under visible light
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Supporting Information CdS/mesoporous ZnS core/shell particles for efficient
More informationSYNTHESIS OF CARBON NANOTUBES BY CATALYTIC CVD USING Fe-Mo/MgO AND Fe- Mo/Al 2 O 3 CATALYSTS. Abstract. Introduction. Experimental
SYNTHESIS OF CARBON NANOTUBES BY CATALYTIC CVD USING Fe-Mo/MgO AND Fe- Mo/Al 2 O 3 CATALYSTS Shinn-Shyong Tzeng, Ting-Bin Liang, Sheng-Chuan Wang, Ting-Yu Wu and Yu-Hun Lin Department of Materials Engineering,
More informationSpecial Properties of Au Nanoparticles
Special Properties of Au Nanoparticles Maryam Ebrahimi Chem 7500/750 March 28 th, 2007 1 Outline Introduction The importance of unexpected electronic, geometric, and chemical properties of nanoparticles
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION Facile Synthesis of High Quality Graphene Nanoribbons Liying Jiao, Xinran Wang, Georgi Diankov, Hailiang Wang & Hongjie Dai* Supplementary Information 1. Photograph of graphene
More informationMesoporous Organosilicas with Acidic Frameworks and Basic Sites in the Pores: An Approach to Cooperative Catalytic Reactions
Literature Report 2009-12-08 Mesoporous rganosilicas with Acidic Frameworks and Basic Sites in the Pores: An Approach to Cooperative Catalytic Reactions Yan Yang Shylesh, S.;* Thiel, W. R.* et al. Angew.
More informationSupporting Information
Supporting Information Single-atom and Nano-clustered Pt Catalysts for Selective CO 2 Reduction Yuan Wang, a Hamidreza Arandiyan,* a,b Jason Scott,* a Kondo-Francois Aguey-Zinsou, c and Rose Amal* a Miss
More informationElectronic Supplementary Information. Three-Dimensional Carbon Foam/N-doped 2. Hybrid Nanostructures as Effective Electrocatalysts for
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Three-Dimensional Carbon Foam/N-doped
More informationSupporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Au nanoparticles supported on magnetically separable Fe 2 O 3 - graphene
More informationSupplementary Figure 1. (a-b) EDX of Mo 2 and Mo 2
Supplementary Figure 1. (a-b) EDX of Mo 2 C@NPC/NPRGO and Mo 2 C@NPC. Supplementary Figure 2. (a) SEM image of PMo 12 2-PPy, (b) TEM, (c) HRTEM, (d) STEM image and EDX elemental mapping of C, N, P, and
More informationA doping of phosphorus and/or sulfur into nitrogen-doped carbon for efficient oxygen reduction reaction in acid media
Supporting Information A doping of phosphorus and/or sulfur into nitrogen-doped carbon for efficient oxygen reduction reaction in acid media Chang Hyuck Choi, a Min Wook Chung, b Sung Hyeon Park, a and
More informationSupplementary Information
Supplementary Information Reduced Graphene Oxide by Chemical Graphitization In Kyu Moon, Junghyun Lee, Rodney S. Ruoff, & Hyoyoung Lee Contents Supplementary Tables S1 Elemental analyses of Graphite, G-O
More informationCVD growth of Graphene. SPE ACCE presentation Carter Kittrell James M. Tour group September 9 to 11, 2014
CVD growth of Graphene SPE ACCE presentation Carter Kittrell James M. Tour group September 9 to 11, 2014 Graphene zigzag armchair History 1500: Pencil-Is it made of lead? 1789: Graphite 1987: The first
More informationSurface Modifications of Graphene-based Polymer Nanocomposites by Different Synthesis Techniques
Surface Modifications of Graphene-based Polymer Nanocomposites by Different Synthesis Techniques Journal: 2012 MRS Spring Meeting Manuscript ID: MRSS12-1451-DD14-02.R1 Manuscript Type: Symposium DD Date
More information1-D and 2-D Carbon-Iron Nanohybrids Prepared with Ultrasonic Spray Pyrolysis for Cr (VI) Removal
1-D and 2-D Carbon-Iron Nanohybrids Prepared with Ultrasonic Spray Pyrolysis for Cr (VI) Removal Arvid Masud, John D. Atkinson, and Nirupam Aich Civil, Structural and Environmental Engineering 1 Nanomaterial
More informationHydrogenation of Single Walled Carbon Nanotubes
Hydrogenation of Single Walled Carbon Nanotubes Anders Nilsson Stanford Synchrotron Radiation Laboratory (SSRL) and Stockholm University Coworkers and Ackowledgement A. Nikitin 1), H. Ogasawara 1), D.
More informationSupporting Information s for
Supporting Information s for # Self-assembling of DNA-templated Au Nanoparticles into Nanowires and their enhanced SERS and Catalytic Applications Subrata Kundu* and M. Jayachandran Electrochemical Materials
More informationSupporting Information
Supporting Information MoSe2 embedded CNT-Reduced Graphene Oxide (rgo) Composite Microsphere with Superior Sodium Ion Storage and Electrocatalytic Hydrogen Evolution Performances Gi Dae Park, Jung Hyun
More informationWafer-scale fabrication of graphene
Wafer-scale fabrication of graphene Sten Vollebregt, MSc Delft University of Technology, Delft Institute of Mircosystems and Nanotechnology Delft University of Technology Challenge the future Delft University
More informationCu 2 graphene oxide composite for removal of contaminants from water and supercapacitor
Electronic Supplementary Information (ESI) for Cu 2 O@reduced graphene oxide composite for removal of contaminants from water and supercapacitor Baojun Li, a Huaqiang Cao,* a Gui Yin, b Yuexiang Lu, a
More informationSupporting Information
Supporting Information Oxygen Reduction on Graphene-Carbon Nanotube Composites Doped Sequentially with Nitrogen and Sulfur Drew C. Higgins, Md Ariful Hoque, Fathy Hassan, Ja-Yeon Choi, Baejung Kim, Zhongwei
More informationSupporting Information Towards N-doped graphene via solvothermal synthesis
Supporting Information Towards N-doped graphene via solvothermal synthesis Dehui Deng1, Xiulian Pan1*, Liang Yu1, Yi Cui1, Yeping Jiang2, Jing Qi3, Wei-Xue Li1, Qiang Fu1, Xucun Ma2, Qikun Xue2, Gongquan
More informationSupporting Information
Supporting Information N,P-co-doped Meso-/microporous Carbon Derived from Biomass Materials via a Dual-activation Strategy as High-performance Electrodes for Deionization Capacitors Dong Xu,, Ying Tong,,
More informationSupporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Supporting Information Synthesis and Application of Hexagonal Perovskite BaNiO 3 with Quadrivalent
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2016. Supporting Information for Adv. Energy Mater., DOI: 10.1002/aenm.201601814 Nitrogen-Doped Core-Sheath Carbon Nanotube Array for
More informationState Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing , China
Electronic Supplementary Material A Co-N/C hollow-sphere electrocatalyst derived from a metanilic CoAl layered double hydroxide for the oxygen reduction reaction, and its active sites in various ph media
More informationNanostrukturphysik (Nanostructure Physics)
Nanostrukturphysik (Nanostructure Physics) Prof. Yong Lei & Dr. Yang Xu Fachgebiet 3D-Nanostrukturierung, Institut für Physik Contact: yong.lei@tu-ilmenau.de; yang.xu@tu-ilmenau.de Office: Unterpoerlitzer
More informationPd-P nanoalloys supported on porous carbon frame as efficient catalyst for benzyl alcohol oxidation
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 2018 Supporting information Pd-P nanoalloys supported on porous carbon frame as
More informationSupporting Information
Supporting Information Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation** Jian Bao, Xiaodong Zhang,* Bo Fan, Jiajia Zhang, Min Zhou, Wenlong
More informationTECHNICAL SPECIFICATION
TECHNICAL SPECIFICATION ISO/TS 13278 First edition 2011-11-01 Nanotechnologies Determination of elemental impurities in samples of carbon nanotubes using inductively coupled plasma mass spectrometry Nanotechnologies
More informationPyrolytic Temperature Dependent and Ash Catalyzed Formation of Sludge Char. Xiao-Qing Liu, Hong-Sheng Ding, Yuan-Ying Wang, Wu-Jun Liu, Hong Jiang*
Pyrolytic Temperature Dependent and Ash Catalyzed Formation of Sludge Char with Ultra-High Adsorption to 1-Naphthol Xiao-Qing Liu, Hong-Sheng Ding, Yuan-Ying Wang, Wu-Jun Liu, Hong Jiang* CAS Key Laboratory
More informationa b c Supplementary Figure S1
a b c Supplementary Figure S1 AFM measurements of MoS 2 nanosheets prepared from the electrochemical Liintercalation and exfoliation. (a) AFM measurement of a typical MoS 2 nanosheet, deposited on Si/SiO
More informationA new method of growing graphene on Cu by hydrogen etching
A new method of growing graphene on Cu by hydrogen etching Linjie zhan version 6, 2015.05.12--2015.05.24 CVD graphene Hydrogen etching Anisotropic Copper-catalyzed Highly anisotropic hydrogen etching method
More informationSupplementary Materials for
advances.sciencemag.org/cgi/content/full/4/3/eaar7180/dc1 Supplementary Materials for Critical advancements in achieving high power and stable nonprecious metal catalyst based MEAs for real-world proton
More informationSYNTHESIS OF CARBON NANOPARTICLES. 4.0 Production and Characterization of Carbon Nanoballs and other Nanoparticles
4.0 Production and Characterization of Carbon Nanoballs and other Nanoparticles A series of experiments was carried out to synthesize carbon nanoparticles and membrane for fuel cell applications and the
More informationSupporting Information. Free-Standing 3D Porous N-Doped Graphene Aerogel Supported. Platinum Nanocluster for Efficient Hydrogen Production from
Supporting Information Free-Standing 3D Porous N-Doped Graphene Aerogel Supported Platinum Nanocluster for Efficient Hydrogen Production from Ammonia Electrolysis Yufei Zhou, Guoquan Zhang *, Mingchuan
More informationSupporting Information. Exfoliation of Non-Oxidized Graphene Flakes for Scalable Conductive Film
Supporting Information Exfoliation of Non-Oxidized Graphene Flakes for Scalable Conductive Film Kwang Hyun Park, Bo Hyun Kim, Sung Ho Song, Jiyoung Kwon, Byung Seon Kong, Kisuk Kang, and Seokwoo Jeon *,
More informationMechanisms and Measurement of Nanomaterial Induced Oxidative Damage to DNA
Analytical and Bioanalytical Chemistry Electronic Supplementary Material Mechanisms and Measurement of anomaterial Induced Oxidative Damage to DA Elijah J. Petersen and Bryant C. elson Table S1 Additional
More informationSupporting Information
Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2017. Supporting Information for Adv. Energy Mater., DOI: 10.1002/aenm.201701456 Selective Etching of Nitrogen-Doped Carbon by Steam
More informationSupporting Information
Supporting Information Facet-Selective Deposition of FeO x on α-moo 3 Nanobelts for Lithium Storage Yao Yao, 1 Nuo Xu, 2 Doudou Guan, 1 Jiantao Li, 1 Zechao Zhuang, 1 Liang Zhou,*,1 Changwei Shi 1, Xue
More informationSupporting Information
Supporting Information High Performance Electrocatalyst: Pt-Cu Hollow Nanocrystals Xiaofei Yu, a Dingsheng, a Qing Peng a and Yadong Li* a a Department of Chemistry, Tsinghua University, Beijing, 100084
More informationIodine-Mediated Chemical Vapor Deposition Growth of Metastable Transition Metal
Supporting Information Iodine-Mediated Chemical Vapor Deposition Growth of Metastable Transition Metal Dichalcogenides Qiqi Zhang,, Yao Xiao, #, Tao Zhang,, Zheng Weng, Mengqi Zeng, Shuanglin Yue, ± Rafael
More information[Supplementary Information] One-Pot Synthesis and Electrocatalytic Activity of Octapodal Au-Pd Nanoparticles
[Supplementary Information] One-Pot Synthesis and Electrocatalytic Activity of Octapodal Au-Pd Nanoparticles Jong Wook Hong, Young Wook Lee, Minjung Kim, Shin Wook Kang, and Sang Woo Han * Department of
More informationThe sacrificial role of graphene oxide in stabilising Fenton-like catalyst GO Fe 3 O 4
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 The sacrificial role of graphene oxide in stabilising Fenton-like catalyst GO Fe 3 O 4 Nor Aida
More informationLayered Double Hydroxide Nanoplatelets with Excellent Tribological Properties under High Contact Pressure as Water-based Lubricant Additives
Supplementary Information Layered Double Hydroxide Nanoplatelets with Excellent Tribological Properties under High Contact Pressure as Water-based Lubricant Additives Hongdong Wang, Yuhong Liu, Zhe Chen,
More informationSUPPLEMENTARY INFORMATION
SUPPLEMENTARY INFORMATION Covalent Bulk Functionalization of Graphene Jan M. Englert a, Christoph Dotzer a, Guang Yang b, Martin Schmid c, Christian Papp c, J. Michael Gottfried c, Hans-Peter Steinrück
More informationMagnesiothermic synthesis of sulfur-doped graphene as an efficient. metal-free electrocatalyst for oxygen reduction
Supporting Information: Magnesiothermic synthesis of sulfur-doped as an efficient metal-free electrocatalyst for oxygen reduction Jiacheng Wang, 1,2,3, * Ruguang Ma, 1,2,3 Zhenzhen Zhou, 1,2,3 Guanghui
More informationAvailable online Research Article. Hamideh Saravani* and Mehdi Sanjarani V.
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2016, 8(4):1408-1413 Research Article ISSN : 0975-7384 CODEN(USA) : JCPRC5 Synthesis and characterization of Cu 2 BaO 4 nanoparticles
More informationSTM and graphene. W. W. Larry Pai ( 白偉武 ) Center for condensed matter sciences, National Taiwan University NTHU, 2013/05/23
STM and graphene W. W. Larry Pai ( 白偉武 ) Center for condensed matter sciences, National Taiwan University NTHU, 2013/05/23 Why graphene is important: It is a new form of material (two dimensional, single
More informationStrategic use of CuAlO 2 as a sustained release catalyst for production of hydrogen from methanol steam reforming
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Strategic use of CuAlO 2 as a sustained release catalyst for
More informationTECHNICAL SPECIFICATION
TECHNICAL SPECIFICATION ISO/TS 13278 First edition 2011-11-01 Nanotechnologies Determination of elemental impurities in samples of carbon nanotubes using inductively coupled plasma mass spectrometry Nanotechnologies
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information 1. Synthesis of perovskite materials CH 3 NH 3 I
More informationDegradation of Bisphenol A by Peroxymonosulfate Catalytically Activated with. Gui-Xiang Huang, Chu-Ya Wang, Chuan-Wang Yang, Pu-Can Guo, Han-Qing Yu*
Supporting Information for Degradation of Bisphenol A by Peroxymonosulfate Catalytically Activated with Mn 1.8 Fe 1.2 O 4 Nanospheres: Synergism between Mn and Fe Gui-Xiang Huang, Chu-Ya Wang, Chuan-Wang
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information NiSe 2 Pyramids Deposited on N-doped Graphene Encapsulated
More informationTuning the Properties of Iron Nanoparticles: Doping Effects on Reactivity and Aging
Tuning the Properties of Iron Nanoparticles: Doping Effects on Reactivity and Aging D. R. Baer, Pacifi c Northwest National Laboratory P. G. Tratnyek, Oregon Health and Sciences University J. E. Amonette,
More informationSupplementary Information. Large Scale Graphene Production by RF-cCVD Method
Supplementary Information Large Scale Graphene Production by RF-cCVD Method Enkeleda Dervishi, *a,b Zhongrui Li, b Fumiya Watanabe, b Abhijit Biswas, c Yang Xu, b Alexandru R. Biris, d Viney Saini, a,b
More informationnanocomposites: synthesis and characterization
National Institute for Research and Development of Isotopic and Molecular Technologies Cluj-Napoca Romania Carbon nanotubes-polypyrrole nanocomposites: synthesis and characterization R. Turcu a, O. Pana
More informationControlled self-assembly of graphene oxide on a remote aluminum foil
Supplementary Information Controlled self-assembly of graphene oxide on a remote aluminum foil Kai Feng, Yewen Cao and Peiyi Wu* State key Laboratory of Molecular Engineering of Polymers, Department of
More informationFor more information, please contact: or +1 (302)
Introduction Graphene Raman Analyzer: Carbon Nanomaterials Characterization Dawn Yang and Kristen Frano B&W Tek Carbon nanomaterials constitute a variety of carbon allotropes including graphene, graphene
More informationsheets in the exfoliation step
Optimization of the size and yield of graphene oxide sheets in the exfoliation step Cristina Botas, Ana M. Pérez-Mas, Patricia Álvarez, Ricardo Santamaría, Marcos Granda, Clara Blanco, and Rosa Menéndez
More informationPlease do not adjust margins. Flower stamen-like porous boron carbon nitride nanoscrolls for water cleaning
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry Please do 2017 not adjust margins Electronic Supplementary Information (ESI) Flower stamen-like porous
More informationEnhanced photocurrent of ZnO nanorods array sensitized with graphene. quantum dots
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Enhanced photocurrent of ZnO nanorods array sensitized with graphene quantum dots Bingjun Yang,
More informationSynthesis gas production via the biogas reforming reaction over Ni/MgO-Al 2 O 3 and Ni/CaO-Al 2 O 3 catalysts
Synthesis gas production via the biogas reforming reaction over Ni/MgO-Al 2 O 3 and Ni/CaO-Al 2 O 3 catalysts N.D. Charisiou 1,2, A. Baklavaridis 1, V.G. Papadakis 2, M.A. Goula 1 1 Department of Environmental
More informationEngineering electronic structure of Two-Dimensional Subnanopore. nanosheet by Molecular Titanium-oxide Incorporation for Enhanced
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2015 Electronic Supplementary Information for Engineering electronic structure of Two-Dimensional
More informationSurface and Interface Characterization of Polymer Films
Surface and Interface Characterization of Polymer Films Jeff Shallenberger, Evans Analytical Group 104 Windsor Center Dr., East Windsor NJ Copyright 2013 Evans Analytical Group Outline Introduction to
More informationSupporting Information. Size-tunable Ni nanoparticles supported on surface-modified, cage-type mesoporous
Supporting Information Size-tunable Ni nanoparticles supported on surface-modified, cage-type mesoporous silica as highly active catalysts for CO 2 hydrogenation Ching-Shiun Chen, a,b* Canggih Setya Budi,
More informationSupplementary Figure 1 a-c, The viscosity fitting curves of high-molecular-weight poly(vinyl alcohol) (HMW-PVA) (a), middle-molecular-weight
Supplementary Figure 1 a-c, The viscosity fitting curves of high-molecular-weight poly(vinyl alcohol) (HMW-PVA) (a), middle-molecular-weight poly(vinyl alcohol) (MMW-PVA) (b) and low-molecular-weight poly(vinyl
More informationSeminars in Nanosystems - I
Seminars in Nanosystems - I Winter Semester 2011/2012 Dr. Emanuela Margapoti Emanuela.Margapoti@wsi.tum.de Dr. Gregor Koblmüller Gregor.Koblmueller@wsi.tum.de Seminar Room at ZNN 1 floor Topics of the
More informationCHARACTERIZATION of NANOMATERIALS KHP
CHARACTERIZATION of NANOMATERIALS Overview of the most common nanocharacterization techniques MAIN CHARACTERIZATION TECHNIQUES: 1.Transmission Electron Microscope (TEM) 2. Scanning Electron Microscope
More informationMetal-Organic Framework Immobilized Cobalt Oxide Nanoparticles
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting information Metal-Organic Framework Immobilized Cobalt Oxide
More informationEffects of plasma treatment on the precipitation of fluorine-doped silicon oxide
ARTICLE IN PRESS Journal of Physics and Chemistry of Solids 69 (2008) 555 560 www.elsevier.com/locate/jpcs Effects of plasma treatment on the precipitation of fluorine-doped silicon oxide Jun Wu a,, Ying-Lang
More informationElectronic Supplementary Information. Enhanced Photocatalytic/photoelectrocatalytic Activities
Electronic Supplementary Material (ESI) for CrystEngComm. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Electrospun BiVO 4 Nanobelts with Tailored Structures
More informationConversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin , PR China
Supporting information for Assembly of flexible CoMoO 4 @NiMoO 4 xh 2 O and Fe 2 O 3 electrodes for solid-state asymmetric supercapacitors Jing Wang a, Leipeng Zhang b, Xusong Liu a, Xiang Zhang b, Yanlong
More informationEnhanced Cr(VI) removal using iron nanoparticle decorated graphene
Enhanced Cr(VI) removal using iron nanoparticle decorated graphene Humera Jabeen, ξ Vimlesh Chandra, ξ Sehoon Jung, Jung Woo Lee, Kwang S. Kim, * Kim * and Seung Bin Supporting Information Chemicals Graphite
More informationFull-Color Light-Emitting Carbon Dots with a Surface-State
Supporting information Full-Color Light-Emitting Carbon Dots with a Surface-State -Controlled Luminescence Mechanism Hui Ding, Shang-Bo Yu, Ji-Shi Wei and Huan-Ming Xiong* Department of Chemistry, Fudan
More information