Final Exam. Physical Constants and Conversion Factors. Equations
|
|
- Wilfred Nash
- 5 years ago
- Views:
Transcription
1 Final Exam Instructions: This exam is worth 100 points. Some questions allow a choice as to which parts are answered. Do not answer more parts than are requested. velocity of light in a vacuum: 3.0x10 8 m/sec Planck's constant: 6.626x10-34 Joule-sec electron charge: 1.602x10-19 Coulomb 1 Joule = 1 Volt-Coulomb Avogadro's constant: 6.022x10 23 atoms/mole 1 nm = 10-9 m 1 cm = 10-2 m 1 µg = 10-6 g?? = c E = h? E = ev sin r = n?/d - sin I dr/d? = n/(d cos r) sin I / sin r = n 2 / n 1 R =? /?? R = S / HA S = S final (1 - e -t/t ) A = ebc A = -log 10 T T = P/P 0 A total = A A n A = log 10 ((P 0 ' + P 0 ")/(P 0 '10 -e b + P 0 "10 -e bc )) A = -log 10 ((P + P s )/(P 0 + P s )) F = kp 0 (1-10 -ebc ) F? kp 0 (2.303)ebC I(d) = 0.5 I(?)(1 + cos(2pd/?) I(t) = B(?) + B(?)cos(2p?2Vt) f = 2?V I(d) =?B(?)cos(2p?d) d? B(?) =?I(d)cos(2p?d) dd m/z = B 2 r 2 e/2v R = m /? m Physical Constants and Conversion Factors Equations
2 1. (15 points) For each of the following cases, indicate whether (1) flame atomic absorption, (2) furnace atomic absorption, or (3) inductively coupled plasma atomic emission is the preferred technique and explain your reasoning. a. Sample size is limited. b. Elements with high boiling points are to be analyzed. c. Multiple elements in the sample are to be determined. 2. (10 points) Answer one of the following. a. Describe the operation of a magnetic sector mass analyzer. b. Compare unimolecular and bimolecular methods of ionization in mass spectrometry.
3 3. (35 points) Answer five of the following. a. What is the most common broadband light source used in (1) absorption spectroscopy and (2) luminescence spectroscopy in the ultraviolet spectral region? b. Use appropriate equations to compare the sensitivity of luminescence spectroscopy to that of absorption spectroscopy? Which is greater? Why? c. Name three reasons why signal averaging is more important in infrared spectroscopy than in UV-visible spectroscopy. d. How is the resolution changed in (1) a dispersive spectrometer and (2) a Fourier transform spectrometer? e. Name three experimental changes in luminescence spectroscopy that can lead to an increase in quantum yield. f. For an analysis in which the signal is in microamps (µa) and concentration is in moles/liter, what are the units of (1) sensitivity, (2) selectivity, and (3) limit of detection.
4 4. (30 points) You have the following instrumental configurations: A. Double-beam luminescence spectrometer with Xe arc lamp and photomultiplier tube detectors. B. Double-beam luminescence spectrometer with Ar + laser and photomultiplier tube detectors. C. Fourier transform spectrometer with Globar source and TGS pyroelectric detector. D. Double-beam dispersive absorption spectrometer with Globar source and TGS pyroelectric detector E. Double-beam dispersive absorption spectrometer with 400 W tungsten-halogen source and phototube detector. F. Single-beam dispersive absorption spectrometer with 100 W tungsten-halogen source and photodiode array detector. G. Double-beam dispersive absorption spectrometer with 400 W tungsten-halogen source and photomultiplier tube detector. H. Inductively coupled plasma atomic emission spectrometer. I. Double-beam flame atomic absorption spectrometer. J. Double-beam furnace atomic absorption spectrometer. K. Double-focusing mass spectrometer equipped with fast atom bombardment ionization. L. Double-focusing mass spectrometer equipped with electron-impact ionization. M. Mass spectrometer equipped with chemical ionization and quadrupole mass analyzer. N. Mass spectrometer equipped with electron impact ionization and magnetic sector mass analyzer. For each of the following measurement scenarios, indicate the best instrument configuration to use by specifying the appropriate letter from the list above. a. You wish to determine the molecular weight of an organic compound to the highest precision. b. You wish to determine Cu in a water sample with low cost and fast analysis time. c. You wish to detect the effluent from a liquid chromatograph in a situation in which incomplete separation has taken place. You know the compounds of interest have chromophores, but you have no information about their volatility. d. You wish to differentiate alkane species in the effluent of a gas chromatograph. e. You wish to determine non-volatile polycyclic aromatic compounds in a water sample with the greatest sensitivity and without performing any sample manipulation or pretreatment.
5 5. (10 points) You are analyzing a mineral sample for Cu (AW=63.55) and Mg (AW =24.31) by absorption spectroscopy. You dissolve a g sample in acid, add a complexing reagent in excess and dilute to ml in a volumetric flask. You measure the absorbance of the resulting solution at 440 and 550 nm in a cm path length cell. You know the following absorptivity values: Species Molar absorptivity (L/mole-cm) 440 nm 550 nm Cu Mg The absorbance at 440 nm is and the absorbance at 550 nm is Calculate the Cu and Mg content in the original solid sample and express as µg/g (ppm).
Ch 313 FINAL EXAM OUTLINE Spring 2010
Ch 313 FINAL EXAM OUTLINE Spring 2010 NOTE: Use this outline at your own risk sometimes a topic is omitted that you are still responsible for. It is meant to be a study aid and is not meant to be a replacement
More informationChemistry 311: Topic 3 - Mass Spectrometry
Mass Spectroscopy: A technique used to measure the mass-to-charge ratio of molecules and atoms. Often characteristic ions produced by an induced unimolecular dissociation of a molecule are measured. These
More informationBecause light behaves like a wave, we can describe it in one of two ways by its wavelength or by its frequency.
Light We can use different terms to describe light: Color Wavelength Frequency Light is composed of electromagnetic waves that travel through some medium. The properties of the medium determine how light
More informationLecture 0. NC State University
Chemistry 736 Lecture 0 Overview NC State University Overview of Spectroscopy Electronic states and energies Transitions between states Absorption and emission Electronic spectroscopy Instrumentation Concepts
More informationChem 155 Midterm Exam Page 1 of 10 Spring 2010 Terrill
Chem 155 Midterm Exam Page 1 of 10 ame Signature 1. Mercury (Hg) is is believed to be hazardous to human neurological health at extremely low concentrations. Fortunately EPA Method 45.7 cold vapor atomic
More information1. Cyclic voltammetry involves the measurement of a diffusion controlled at an electrode in which the is controlled. (4 points)
Chem 454 First Exam Feb. 20, 2002 1. Cyclic voltammetry involves the measurement of a diffusion controlled at an electrode in which the is controlled. (4 points) 2. (5 points) A. Sketch a cyclic voltammogram
More informationWelcome to Organic Chemistry II
Welcome to Organic Chemistry II Erika Bryant, Ph.D. erika.bryant@hccs.edu Class Syllabus 3 CHAPTER 12: STRUCTURE DETERMINATION 4 What is this solution Soda Tea Coffee??? 5 What is this solution Soda Tea
More informationhigh temp ( K) Chapter 20: Atomic Spectroscopy
high temp (2000-6000K) Chapter 20: Atomic Spectroscopy 20-1. An Overview Most compounds Atoms in gas phase high temp (2000-6000K) (AES) (AAS) (AFS) sample Mass-to-charge (ICP-MS) Atomic Absorption experiment
More informationII. Spectrophotometry (Chapters 17, 19, 20)
II. Spectrophotometry (Chapters 17, 19, 20) FUNDAMENTALS (Chapter 17) Spectrophotometry: any technique that uses light to measure concentrations (here: U and visible - ~190 800 nm) c = 2.99792 x 10 8 m/s
More information25 Instruments for Optical Spectrometry
25 Instruments for Optical Spectrometry 25A INSTRUMENT COMPONENTS (1) source of radiant energy (2) wavelength selector (3) sample container (4) detector (5) signal processor and readout (a) (b) (c) Fig.
More information10/2/2008. hc λ. νλ =c. proportional to frequency. Energy is inversely proportional to wavelength And is directly proportional to wavenumber
CH217 Fundamentals of Analytical Chemistry Module Leader: Dr. Alison Willows Electromagnetic spectrum Properties of electromagnetic radiation Many properties of electromagnetic radiation can be described
More informationATOMIC SPECROSCOPY (AS)
ATOMIC ABSORPTION ANALYTICAL CHEMISTRY ATOMIC SPECROSCOPY (AS) Atomic Absorption Spectroscopy 1- Flame Atomic Absorption Spectreoscopy (FAAS) 2- Electrothermal ( Flame-less ) Atomic Absorption Spectroscopy
More informationCourse Details. Analytical Techniques Based on Optical Spectroscopy. Course Details. Textbook. SCCH 211: Analytical Chemistry I
SCCH 211: Analytical Chemistry I Analytical Techniques Based on Optical Spectroscopy Course Details September 22 October 10 September 22 November 7 November 17 December 1 Topic Period Introduction to Spectrometric
More informationSpectroscopy Problem Set February 22, 2018
Spectroscopy Problem Set February, 018 4 3 5 1 6 7 8 1. In the diagram above which of the following represent vibrational relaxations? 1. Which of the following represent an absorbance? 3. Which of following
More information2101 Atomic Spectroscopy
2101 Atomic Spectroscopy Atomic identification Atomic spectroscopy refers to the absorption and emission of ultraviolet to visible light by atoms and monoatomic ions. It is best used to analyze metals.
More information3 - Atomic Absorption Spectroscopy
3 - Atomic Absorption Spectroscopy Introduction Atomic-absorption (AA) spectroscopy uses the absorption of light to measure the concentration of gas-phase atoms. Since samples are usually liquids or solids,
More informationUNIVERSITI SAINS MALAYSIA. Second Semester Examination Academic Session 2004/2005. March KAA 502 Atomic Spectroscopy.
UNIVERSITI SAINS MALAYSIA Second Semester Examination Academic Session 2004/2005 March 2005 KAA 502 Atomic Spectroscopy Time: 3 hours Please make sure this paper consists of FIVE typed pages before answering
More informationChemistry 311: Instrumentation Analysis Topic 2: Atomic Spectroscopy. Chemistry 311: Instrumentation Analysis Topic 2: Atomic Spectroscopy
Topic 1: Atomic Spectroscopy Text: Chapter 12,13 & 14 Rouessac (~2 weeks) 1.0 Review basic concepts in Spectroscopy 2.0 Atomic Absorption and Graphite Furnace Instruments 3.0 Inductively Coupled Plasmas
More informationINTRODUCTION Atomic fluorescence spectroscopy ( AFS ) depends on the measurement of the emission ( fluorescence ) emitted from gasphase analyte atoms
INTRODUCTION Atomic fluorescence spectroscopy ( AFS ) depends on the measurement of the emission ( fluorescence ) emitted from gasphase analyte atoms that have been excited to higher energy levels by absorption
More informationSpectroscopy. Page 1 of 8 L.Pillay (2012)
Spectroscopy Electromagnetic radiation is widely used in analytical chemistry. The identification and quantification of samples using electromagnetic radiation (light) is called spectroscopy. Light has
More informationCork Institute of Technology. Summer 2005 Instrumental Analysis (Time: 3 Hours) Section A
Cork Institute of Technology Higher Certificate in Science in Applied Biology Award (National Certificate in Science in Applied Biology Award) Answer FIVE questions; answer Section A, TWO questions from
More informationComplete the following. Clearly mark your answers. YOU MUST SHOW YOUR WORK TO RECEIVE CREDIT.
CHEM 322 Name Exam 3 Spring 2013 Complete the following. Clearly mark your answers. YOU MUST SHOW YOUR WORK TO RECEIVE CREDIT. Warm-up (3 points each). 1. In Raman Spectroscopy, molecules are promoted
More informationtwo slits and 5 slits
Electronic Spectroscopy 2015January19 1 1. UV-vis spectrometer 1.1. Grating spectrometer 1.2. Single slit: 1.2.1. I diffracted intensity at relative to un-diffracted beam 1.2.2. I - intensity of light
More information高等食品分析 (Advanced Food Analysis) I. SPECTROSCOPIC METHODS *Instrumental methods: 1. Spectroscopic methods (spectroscopy): a) Electromagnetic radiation
*Instrumental methods: 1. Spectroscopic methods (spectroscopy): a) Electromagnetic radiation (EMR): γ-ray emission X-Ray absorption, emission, fluorescence and diffraction Vacuum ultraviolet (UV) absorption
More informationatomic absorption spectroscopy general can be portable and used in-situ preserves sample simpler and less expensive
Chapter 9: End-of-Chapter Solutions 1. The following comparison provides general trends, but both atomic absorption spectroscopy (AAS) and atomic absorption spectroscopy (AES) will have analyte-specific
More informationDeterminations by Atomic Absorption Spectroscopy and Inductively Coupled Plasma-Atomic Emission
0 chapter Sodium and Potassium Determinations by Atomic Absorption Spectroscopy and Inductively Coupled Plasma-Atomic Emission Spectroscopy 67 S. S. Nielsen (ed.), Food Analysis Laboratory Manual Springer
More informationATOMIC STRUCTURE, ELECTRONS, AND PERIODICITY
ATOMIC STRUCTURE, ELECTRONS, AND PERIODICITY All matter is made of atoms. There are a limited number of types of atoms; these are the elements. (EU 1.A) Development of Atomic Theory Atoms are so small
More informationDEPARTMENT OF CHEMISTRY UNIVERSITY OF SWAZILAND
o DEPARTMENT OF CHEMISTRY UNIVERSITY OF SWAZILAND C612 SPECTRO CHEMICAL ANALYSIS DECEMBER 2015 FINAL EXAMINATION Time Allowed: Three (3) Hours Instructions: 1. This examination has six (6) questions and
More informationChem 321 Lecture 18 - Spectrophotometry 10/31/13
Student Learning Objectives Chem 321 Lecture 18 - Spectrophotometry 10/31/13 In the lab you will use spectrophotometric techniques to determine the amount of iron, calcium and magnesium in unknowns. Although
More informationFourier Transform Infrared Spectrometry Prelab Last modified: June 17, 2014
Fourier Transform Infrared Spectrometry Prelab Recommended reading: AirUCI Lab Manual: Environmental Chemistry Text: FTIR Lab Pages: 6, 7, 13 16 on Light Absorption Pages: 175 177, 184, 185 on Molecular
More informationOptical Atomic Spectroscopy
Optical Atomic Spectroscopy Methods to measure conentrations of primarily metallic elements at < ppm levels with high selectivity! Two main optical methodologies- -Atomic Absorption--need ground state
More informationC101-E111. Talk Letter. Vol.2 February 2009
C101-E111 UV Talk Letter Vol.2 February 2009 UV Talk Letter UV Talk Letter The Structure of a Spectrophotometer Vol.2 February 2009 1.The Measurement Principle Used by a Spectrophotometer The basic measurement
More informationAnalytical Spectroscopy Review
Analytical Spectroscopy Review λ = wavelength ν = frequency V = velocity = ν x λ = 2.998 x 10 8 m/sec = c (in a vacuum) ν is determined by source and does not change as wave propogates, but V can change
More informationCHEM*3440. Photon Energy Units. Spectrum of Electromagnetic Radiation. Chemical Instrumentation. Spectroscopic Experimental Concept.
Spectrum of Electromagnetic Radiation Electromagnetic radiation is light. Different energy light interacts with different motions in molecules. CHEM*344 Chemical Instrumentation Topic 7 Spectrometry Radiofrequency
More informationThe Structure of the Atom
CHAPTER 5 The Structure of the Atom 5.4 Light and Spectroscopy 460 370 BC 1808 1870 1897 1910 1925 Today Democritus Atomism Dalton Modern atomic theory Crookes Cathode rays Thomson Discovery of the electron
More informationChemistry 524--Final Exam--Keiderling May 4, :30 -?? pm SES
Chemistry 524--Final Exam--Keiderling May 4, 2011 3:30 -?? pm -- 4286 SES Please answer all questions in the answer book provided. Calculators, rulers, pens and pencils are permitted. No open books or
More informationChapter 12 Mass Spectrometry and Infrared Spectroscopy
Organic Chemistry, 6 th Edition L. G. Wade, Jr. Chapter 12 Mass Spectrometry and Infrared Spectroscopy Jo Blackburn Richland College, Dallas, TX Dallas County Community College District 2006, Prentice
More informationChemistry Instrumental Analysis Lecture 18. Chem 4631
Chemistry 4631 Instrumental Analysis Lecture 18 Instrumentation Radiation sources Hollow cathode lamp Most common source Consist of W anode and a cathode sealed in a glass tube filled with Ne or Ar. Hollow
More informationInstrumental Analysis: Spectrophotometric Methods
Instrumental Analysis: Spectrophotometric Methods 2007 By the end of this part of the course, you should be able to: Understand interaction between light and matter (absorbance, excitation, emission, luminescence,fluorescence,
More informationSpectroscopy: Introduction. Required reading Chapter 18 (pages ) Chapter 20 (pages )
Spectroscopy: Introduction Required reading Chapter 18 (pages 378-397) Chapter 20 (pages 424-449) Spectrophotometry is any procedure that uses light to measure chemical concentrations Properties of Light
More informationChem 434 -Instrumental Analysis Hour Exam 1
Do any 8 of the following 9 problems Name: Chem 434 -Instrumental Analysis Hour Exam 1 +2 1. A 25.0 ml sample containing Cu gave an instrument reading of 23.6 units (corrected for a blank). When exactly
More informationSpectroscopy Primer. for ultraviolet and visible absorbance spectroscopy. by Stephanie Myers Summer 2015
Spectroscopy Primer for ultraviolet and visible absorbance spectroscopy by Stephanie Myers Summer 2015 Abstract: An overview of uv vis absorbance spectroscopy including Beer s Law, calibration curves,
More informationEMISSION SPECTROSCOPY
IFM The Department of Physics, Chemistry and Biology LAB 57 EMISSION SPECTROSCOPY NAME PERSONAL NUMBER DATE APPROVED I. OBJECTIVES - Understand the principle of atomic emission spectra. - Know how to acquire
More informationAtomic Absorption Spectroscopy
CH 2252 Instrumental Methods of Analysis Unit IV Atomic Absorption Spectroscopy Dr. M. Subramanian Associate Professor Department of Chemical Engineering Sri Sivasubramaniya Nadar College of Engineering
More informationSpectrochemical methods
Spectrochemical methods G. Galbács The interactions of radiations and matter are the subject of spectroscopy py or spectrochemical methods (also called spectrometry). Spectrochemical methods usually measure
More informationCHEM 221 Instrumental Analysis FINAL EXAM May 10, 2016
CHEM 221 Instrumental Analysis FINAL EXAM May 10, 2016 Name: INSTRUCTIONS: Read through the entire exam before you begin. Answer all of the questions. For questions involving calculations, show all of
More information1901 Application of Spectrophotometry
1901 Application of Spectrophotometry Chemical Analysis Problem: 1 Application of Spectroscopy Organic Compounds Organic compounds with single bonds absorb in the UV region because electrons from single
More informationFundamentals of Mass Spectrometry. Fundamentals of Mass Spectrometry. Learning Objective. Proteomics
Mass spectrometry (MS) is the technique for protein identification and analysis by production of charged molecular species in vacuum, and their separation by magnetic and electric fields based on mass
More informationChem 321 Name Answer Key D. Miller
1. For a reversed-phase chromatography experiment, it is noted that the retention time of an analyte decreases as the percent of acetonitrile (CH 3 CN) increases in a CH 3 CN/H 2 O mobile phase. Explain
More informationFLAME PHOTOMETRY AIM INTRODUCTION
FLAME PHOTOMETRY AIM INTRODUCTION Atomic spectroscopy is based on the absorption, emission or fluorescence process of light by atoms or elementary ions. Information for atomic scale is obtained in two
More informationSecondary Ion Mass Spectrometry (SIMS)
CHEM53200: Lecture 10 Secondary Ion Mass Spectrometry (SIMS) Major reference: Surface Analysis Edited by J. C. Vickerman (1997). 1 Primary particles may be: Secondary particles can be e s, neutral species
More informationIntroduction to Spectroscopic methods
Introduction to Spectroscopic methods Spectroscopy: Study of interaction between light* and matter. Spectrometry: Implies a quantitative measurement of intensity. * More generally speaking electromagnetic
More informationATOMIC ABSORPTION SPECTROSCOPY (AAS) is an analytical technique that measures the concentrations of elements. It makes use of the absorption of light
ATOMIC ABSORPTION SPECTROSCOPY (AAS) is an analytical technique that measures the concentrations of elements. It makes use of the absorption of light by these elements in order to measure their concentration.
More informationAN INTRODUCTION TO ATOMIC SPECTROSCOPY
AN INTRODUCTION TO ATOMIC SPECTROSCOPY Atomic spectroscopy deals with the absorption, emission, or fluorescence by atom or elementary ions. Two regions of the spectrum yield atomic information- the UV-visible
More informationIonization Techniques Part IV
Ionization Techniques Part IV CU- Boulder CHEM 5181 Mass Spectrometry & Chromatography Presented by Prof. Jose L. Jimenez High Vacuum MS Interpretation Lectures Sample Inlet Ion Source Mass Analyzer Detector
More informationa. An emission line as close as possible to the analyte resonance line
Practice Problem Set 5 Atomic Emission Spectroscopy 10-1 What is an internal standard and why is it used? An internal standard is a substance added to samples, blank, and standards. The ratio of the signal
More informationATOMIC STRUCTURE, ELECTRONS, AND PERIODICITY
ATOMIC STRUCTURE, ELECTRONS, AND PERIODICITY All matter is made of atoms. There are a limited number of types of atoms; these are the elements. (EU 1.A) Development of Atomic Theory Atoms are so small
More informationElectronic Excitation by UV/Vis Spectroscopy :
SPECTROSCOPY Light interacting with matter as an analytical tool III Pharm.D Department of Pharmaceutical Analysis SRM College Of Pharmacy,Katankulathur Electronic Excitation by UV/Vis Spectroscopy : X-ray:
More informationClassification of spectroscopic methods
Introduction Spectroscopy is the study of the interaction between the electromagnetic radiation and the matter. Spectrophotometry is the measurement of these interactions i.e. the measurement of the intensity
More informationChapter 5. Mass spectrometry
ionization and fragmentation Chapter 5. Mass spectrometry which fragmentations? mass and frequency, m/z and count rate Reading: Pavia Chapters 3 and 4 Don t need 3.3 B-D, 3.4 B-D Use the text to clarify
More information2001 Spectrometers. Instrument Machinery. Movies from this presentation can be access at
2001 Spectrometers Instrument Machinery Movies from this presentation can be access at http://www.shsu.edu/~chm_tgc/sounds/sound.html Chp20: 1 Optical Instruments Instrument Components Components of various
More informationActivity 6: Spectroscopy
Activity 6: Spectroscopy Reference: Kenkel (p 149-237) and arris, (hp 17-21) Turn in a hardcopy of this activity. If you do not, you will not receive credit. Dropbox submission is not valid. / Score Name
More informationBasics of UV-Visible Spectroscopy *
OpenStax-CNX module: m34525 1 Basics of UV-Visible Spectroscopy * Brittany L. Oliva-Chatelain Andrew R. Barron This work is produced by OpenStax-CNX and licensed under the Creative Commons Attribution
More informationPartial Energy Level Diagrams
Partial Energy Level Diagrams 460 nm 323 nm 610 nm 330 nm 819 nm 404 nm 694 nm 671 nm 589 / 590 nm 767 / 769 nm Lithium Sodium Potassium Gas Mixtures Maximum Temperatures, C Air-Coal Gas 1825 Air-Propane
More informationCHM 424 EXAM 4 CRIB - COVER PAGE FALL
CHM 44 EXAM 4 CRIB - COVER PAGE FALL 007 There are six numbered pages with five questions. Answer the questions on the exam. Exams done in ink are eligible for regrade, those done in pencil will not be
More informationHarris: Quantitative Chemical Analysis, Eight Edition
Harris: Quantitative Chemical Analysis, Eight Edition CHAPTER 21: MASS SPECTROMETRY CHAPTER 21: Opener 21.0 Mass Spectrometry Mass Spectrometry provides information about 1) The elemental composition of
More informationEmission spectrum of H
Atomic Spectroscopy Atomic spectroscopy measures the spectra of elements in their atomic/ionized states. Atomic spectrometry, exploits quantized electronic transitions characteristic of each individual
More informationChem Homework Set Answers
Chem 310 th 4 Homework Set Answers 1. Cyclohexanone has a strong infrared absorption peak at a wavelength of 5.86 µm. (a) Convert the wavelength to wavenumber.!6!1 8* = 1/8 = (1/5.86 µm)(1 µm/10 m)(1 m/100
More informationDetermination the elemental composition of soil samples
4. Experiment Determination the elemental composition of soil samples Objectives On this practice you will determine the elemental composition of soil samples by Inductively Coupled Plasma Optical Emission
More informationlevels. The signal is either absorbance vibrational and rotational energy levels or percent transmittance of the analyte
1 In this chapter, absorption by molecules, rather than atoms, is considered. Absorption in the ultraviolet and visible regions occurs due to electronic transitions from the ground state to excited state.
More informationvery high temperature for excitation not necessary generally no plasma/arc/spark AAS
Atomic Absorption Spectrometry (Chapter 9) AAS intrinsically more sensitive than AES similar atomization techniques to AES addition of radiation source high temperature for atomization necessary flame
More informationChapter 5 Light and Matter: Reading Messages from the Cosmos. What is light? Properties of Waves. Waves. The Electromagnetic Spectrum
Chapter 5 Light and Matter: Reading Messages from the Cosmos What is light? Light is a form of radiant energy Light can act either like a wave or like a particle (photon) Spectrum of the Sun 1 2 Waves
More informationQualitative Organic Analysis CH 351 Mass Spectrometry
Qualitative Organic Analysis CH 351 Mass Spectrometry Bela Torok Department of Chemistry University of Massachusetts Boston Boston, MA General Aspects Theoretical basis of mass spectrometry Basic Instrumentation
More informationAtomic Emission Spectroscopy
Atomic Emission Spectroscopy Ahmad Aqel Ifseisi Assistant Professor of Analytical Chemistry College of Science, Department of Chemistry King Saud University P.O. Box 2455 Riyadh 11451 Saudi Arabia Building:
More informationChemistry 524--Final Exam--Keiderling Dec. 12, pm SES
Chemistry 524--Final Exam--Keiderling Dec. 12, 2002 --4-8 pm -- 238 SES Please answer all questions in the answer book provided. Calculators, rulers, pens and pencils are permitted plus one 8.5 x 11 sheet
More informationIonization Methods in Mass Spectrometry at the SCS Mass Spectrometry Laboratory
Ionization Methods in Mass Spectrometry at the SCS Mass Spectrometry Laboratory Steven L. Mullen, Ph.D. Associate Director SCS Mass Spectrometry Laboratory Contact Information 31 oyes Laboratory (8:00-5:00
More informationInfrared Spectroscopy
Infrared Spectroscopy Introduction Spectroscopy is an analytical technique which helps determine structure. It destroys little or no sample. The amount of light absorbed by the sample is measured as wavelength
More informationAtomic Spectroscopy and Energy Levels
Activity 18 Atomic Spectroscopy and Energy Levels Why? The emission of light by the hydrogen atom and other atoms played a key role in helping scientists to understand the electronic structure of atoms.
More information1. Consider the composition of the species W, X, Y and Z below. Which species is an anion?
1 2 PAST IB EXAM QUESTIONS (From Paper 1 and 2) 1. Consider the composition of the species W, X, Y and Z below. Which species is an anion? Species Number of protons Number of neutrons Number of electrons
More informationAnalytical techniques: Environmental samples. Lecture 2 Universidade do Algarve
Analytical techniques: Environmental samples Lecture 2 Universidade do Algarve Terms, definitions & applications Difference between technique and method: Analytical technique: Fundamental scientific application
More informationChem 310 rd. 3 Homework Set Answers
-1- Chem 310 rd 3 Homework Set Answers 1. A double line labeled S 0 represents the _ground electronic_ state and the _ground vibrational_ state of a molecule in an excitation state diagram. Light absorption
More informationSchool of Chemistry UNIVERSITY OF KWAZULU-NATAL, WESTVILLE CAMPUS JUNE 2009 EXAMINATION CHEM340: INSTRUMENTAL ANALYSIS.
School of Chemistry UNIVERSITY OF KWAZULU-NATAL, WESTVILLE CAMPUS JUNE 2009 EXAMINATION CHEM340: INSTRUMENTAL ANALYSIS DURATION: 3 HOURS TOTAL MARKS: 100 Internal Examiners: Professor A Kindness Dr T Msagati
More informationVALLIAMMAI ENGINEERING COLLEGE SRM Nagar, Kattankulathur
VALLIAMMAI ENGINEERING COLLEGE SRM Nagar, Kattankulathur 603 203 DEPARTMENT OF ELECTRONICS AND INSTRUMENTATION ENGINEERING QUESTION BANK V SEMESTER EI6501 Analytical Instruments Regulation 2013 Academic
More informationMODULE 4.3 Atmospheric analysis of particulates
MODULE 4.3 Atmospheric analysis of particulates Measurement And Characterisation Of The Particulate Content 1 Total particulate concentration 1 Composition of the particulate 1 Determination of particle
More informationChapter 17: Fundamentals of Spectrophotometry
Chapter 17: Fundamentals of Spectrophotometry Spectroscopy: the science that deals with interactions of matter with electromagnetic radiation or other forms energy acoustic waves, beams of particles such
More informationUltraviolet-Visible Spectroscopy
Ultraviolet-Visible Spectroscopy Introduction to UV-Visible Absorption spectroscopy from 160 nm to 780 nm Measurement of transmittance Conversion to absorbance * A=-logT=εbc Measurement of transmittance
More informationFinal Report. Characterisation of Sample Report. Job No 2016/11/12-34 AS No. 1234A. Client Example Contact Sample. Signed Date 2017.
Final Report Title Characterisation of Job No 2016/11/12-34 AS No. 1234A Client Contact Sample Author report Signed Date 2017 Easy Reach Report 2017 v2.docx 1 of 33 Contents 1. Study Summary Page 3 2.
More informationCHAPTER - 3 ANALYTICAL PROFILE. 3.1 Estimation of Drug in Pharmaceutical Formulation Estimation of Drugs
CHAPTER - 3 ANALYTICAL PROFILE 3.1 Estimation of Drug in Pharmaceutical Formulation 3.1.1 Estimation of Drugs ANALYTICAL PROFILE 84 3.1 ESTIMATION OF DRUG IN PHARMACEUTICAL FORMULATION. Agrawal A et al
More informationChemistry 325 Instrumental Methods of Analysis March 13, Final Exam. Name
Final Exam Name Instructions: This exam is worth 100 points. Some questions allow a choice as to which parts are answered. Only answer the number of parts requested. 1. (32 points) Circle the best answer
More informationCOLORIMETER AND LAMBERT S-BEER S LAW. Shingala vaishali Sandha prafulla Tiwari Kuldeep
COLORIMETER AND LAMBERT S-BEER S LAW Shingala vaishali Sandha prafulla Tiwari Kuldeep TOPIC What is colorimeter? Use of colorimeter. Component & It s function. Function of colorimeter. The principle of
More informationChapter 13 An Introduction to Ultraviolet/Visible Molecular Absorption Spectrometry
Chapter 13 An Introduction to Ultraviolet/Visible Molecular Absorption Spectrometry 13A Measurement Of Transmittance and Absorbance Absorption measurements based upon ultraviolet and visible radiation
More informationIntroduction. The analysis of the outcome of a reaction requires that we know the full structure of the products as well as the reactants
Introduction The analysis of the outcome of a reaction requires that we know the full structure of the products as well as the reactants Spectroscopy and the Electromagnetic Spectrum Unlike mass spectrometry,
More informationCourse: M.Sc (Chemistry) Analytical Chemistry Unit: III
Course: M.Sc (Chemistry) Analytical Chemistry Unit: III Syllabus: Principle of spectrophotometry Types of spectrophotometer Applications - Dissociation constants of an indicator simultaneous spectrophotometric
More informationA Spectrophotometric Analysis of Calcium in Cereal
CHEM 311L Quantitative Analysis Laboratory Revision 1.2 A Spectrophotometric Analysis of Calcium in Cereal In this laboratory exercise, we will determine the amount of Calium in a serving of cereal. We
More informationDEPARTMENT OF ELECTRONICS AND INSTRUMENTATION ENGINEERING SRM NAGAR, KATTANKULATHUR-603203 EI 2302 ANALYTICAL INSTRUMENTS QUESTION BANK UNIT I COLORIMETRY AND SPECTROPHOTOMETRY Part A 1. State Lambert
More informationQuestions on Instrumental Methods of Analysis
Questions on Instrumental Methods of Analysis 1. Which one of the following techniques can be used for the detection in a liquid chromatograph? a. Ultraviolet absorbance or refractive index measurement.
More information12. Structure Determination: Mass Spectrometry and Infrared Spectroscopy
12. Structure Determination: Mass Spectrometry and Infrared Spectroscopy Determining the Structure of an Organic Compound The analysis of the outcome of a reaction requires that we know the full structure
More informationCHEMISTRY 31 FINAL EXAM May 18, points total Lab Section Number
NAME CHEMISTRY 31 FINAL EXAM May 18, 2015-150 points total Lab Section Number Constants: K w (autoprotolysis of H 2 O) = 1.0 x 10-14 h = Planck's constant = 6.63 x 10-34 J s c = speed of light in a vacuum
More informationAnalytical Technologies in Biotechnology Prof. Dr. Ashwani K Sharma Department of Biotechnology Indian Institute of Technology, Roorkee
Analytical Technologies in Biotechnology Prof. Dr. Ashwani K Sharma Department of Biotechnology Indian Institute of Technology, Roorkee Module - 6 Spectroscopic Techniques Lecture - 2 UV-Visible Spectroscopy
More informationDepartment of Chemistry. Chemistry 121: Atomic and Molecular Chemistry. Final Examination Wednesday, December 7, 2011 Time: 9:00am 12:00
Student Name: Student Number: The Irving K. Barber School of Arts and Sciences Department of Chemistry Chemistry 121: Atomic and Molecular Chemistry Professors: Dr. Penny Parkeenvincha & Dr. Rob O Brien
More information