August 10, Prospective Chemistry 5511 Students. SUBJECT: Course Syllabus for Chemistry 5511 Fall 2011
|
|
- Rolf Gallagher
- 6 years ago
- Views:
Transcription
1 TO: FROM: Prospective Chemistry 5511 Students Peter Gaspar August 10, 2011 SUBJECT: Course Syllabus for Chemistry 5511 Fall 2011 Chemistry 5511 Mechanistic Organic Chemistry is the first semester of a two-semester sequence of physical organic chemistry courses, normally taught in the Fall semester. In the view of the organic faculty, graduate students contemplating research in synthetic or mechanistic chemistry need, among their intellectual tools, a command of ideas about how reactions occur: that is, what are their mechanisms? And how does one elucidate a reaction mechanism? What relationships exist between the structure, geometric and electronic, of organic molecules and their reactivity? How does one predict structure and reactivity? Since an important goal of the graduate curriculum in organic chemistry is to make it possible for students to complete their course work during their first academic year of the PhD program, it is not practical to have a sequence longer than two courses in physical organic chemistry. It has therefore been decided to devote a semester each to: 1. An introduction to the ideas of physical organic chemistry. 2. Theoretical models and the prediction of molecular structures, properties, and reaction mechanisms by computational chemistry. In previous years these subjects shared equal time with a third important topic: kinetic measurements as a tool for the elucidation of reaction mechanisms. But when two-thirds of a semester was devoted to each of these three topics, time was too short to do justice to any of them. Given the availability of several specialized kinetics courses in the preclinical curriculum of the Medical School, it has been decided to devote the Chemistry 5511 sequence to a full semester introduction to physical organic chemistry, including the major types of reaction mechanisms, and a full semester of molecular modeling and computational chemistry. The basic ideas underlying the use of kinetic measurements in mechanistic studies are briefly discussed in Chemistry Reading and homework assignments for Chemistry 5511 will be taken from Modern Physical Organic Chemistry by Eric V. Anslyn and Dennis A. Dougherty, University Science Books, Sausalito, CA, This text embraces bioorganic, organometallic, materials and supramolecular chemistry as well as the fundamental principles relating structure and reactivity in classical organic chemistry. It also has quite good homework problems. Occasional handouts will supplement the text. Anslyn and Dougherty has been written for a full-year course. I will largely follow the recommendations of the authors in selecting chapters for a single semester course. The chapters in Anslyn and Dougherty are self-standing, so the text is a fine reference work, and most of you will find occasion during your thesis research to read chapters not covered in this semester. This syllabus is printed on both sides of each page in the hard-copy version. Chemistry 5511 Fall
2 The semester is devoted to the fundamental concepts of mechanistic organic chemistry, including the nature of the chemical bond and our views of it. Qualitative molecular orbital theory is introduced early because it offers a language and a conceptual framework for the understanding of the structures of organic molecules and of the changes that occur during reactions. Tools to determine reaction mechanisms include discussions of kinetics, linear free energy relationships, and thermochemistry, which introduce quantitative descriptions of structure and reactivity. Several weeks will be devoted to surveying types of reactions and their mechanisms to which you have already been introduced in undergraduate courses. The purpose will be to build on what you already have learned in order to provide a more powerful set of intellectual tools for the analysis and prediction of the reactions of organic chemistry. Homework assignments will be turned in two weeks after the last lecture on a chapter in Anslyn and Dougherty, but that time includes your grading your own homework papers. There will be two evening examinations during the semester and a third exam given during thefinal examination period. The three examinations and the average of the homework grades will each contribute 24% toward the final semester grade. The quality of your contribution to the discussion in class will contribute 4% to the final grade. Please read as much as you can of Chapter 1 in Anslyn and Dougherty before the first lecture, which will be held at 10 AM on Wednesday, August 31 in L540. I am looking forward to seeing you then! My office is L536, telephone (314) , gaspar@wustl.edu Week Topics 1 Introduction to Structure and Models of Bonding - Anslyn and Dougherty chapter 1 (lectures 1, 2, 3, 4, 5 and 6, August 31, September 2, 7, 9, 12, 14) homework problems: 1, 2, 8, 9, 11, 12, 13, 14, 16, 18, 25, 30, 31, 34, C Review of basic bonding concepts - atomic and molecular structure C Molecular orbital theory C Orbital mixing to build larger units C Bonding and structures of reactive intermediates 3 C A peek at organometallic and inorganic bonding Strain and Stability - Anslyn and Dougherty chapter 2 (lectures 7, 8, 9, 10, 11 & 12, September 16, 19, 21, 23, 26, 28) homework problems: 1, 5, 6, 8, 9, 13, 14, 15, 20, 23, 24, 26, 30, 31, 34, 41, 47, C Thermochemistry of stable molecules - strain, energy, entropy, bond dissociation energies, heats of formation, the group increment method C Thermochemistry - stability vs persistence - radicals, carbocations, carbanions C Basic conformational analysis - relationships between structure and energetics 5 C Electronic effects - interactions involving B-systems: conjugation, aromaticity C Highly strained molecules C Molecular mechanics Acid-Base Chemistry - Anslyn and Dougherty chapter 5 (lectures 13, 14 &15, September 30, October 3, 5) homework problems: 1, 2, 3, 7, 9, 11, 17, 19, 20, 21 C Brønsted acid-base chemistry Week Topics -2-
3 C Aqueous solutions 6 C Nonaqueous solutions C Predicting acid strength in solution C Acids and bases of biological interest C Lewis acids and bases, electrophiles and nucleophiles Stereochemistry - Anslyn and Dougherty chapter 6 (lectures 16, 17, 18 & 19, October 7, 10, 12, 17) homework problems: 1, 2, 5, 8, 9, 10, 14, 16, 17, 22, 24, 30, 31, 38. C Stereogenicity and stereoisomerism - basic concepts and terminology, stereochemical descriptors C Symmetry and stereochemistry C Topicity relationships C Reaction stereochemistry - stereoselectivity and stereospecificity 7 C Symmetry and time scale C Topological and supramolecular stereochemistry C Stereochemical issues in chemical biology Energy Surfaces and Related Concepts- Anslyn and Dougherty chapter 7 (lectures 20, 21, 22, 23, 24 & 25, October 19, 21, 24, 26, 28, 31) homework problems: 1, 3, 4, 5, 9, 11, 13, 14, 15, 18, 19, 22, 23, C Energy surfaces and related concepts C Transition state theory and related topics 9 C Postulates and principles related to kinetic analysis: the Hammond postulate, the Curtin-Hammett principle, microscopic reversibility, kinetic vs thermodynamic control C Kinetic experiments and kinetic analysis for simple mechanisms C Deciphering mechanisms of complex reactions through kinetic analysis C Experimental methods for following kinetics 10 C Calculating rate constants and Marcus theory C Considering multiple reaction coordinates, More O Ferrall-Jencks diagrams Experiments Related to Thermodynamics and Kinetics - Anslyn and Dougherty chapter 8 (lectures 26, 27, 28 & 29, November 2, 4, 7, 9 ) homework problems: 4, 5, 6, 7, 8, 10, 12, 14, 15, 16, 18, 19, 20, 22, 23, 25. C Isotope effect experiments, primary and secondary kinetic isotope effects, equilibrium isotope effects, tunneling, solvent isotope effects, heavy atom isotope effects 11 C Substituent effects C Hammett plots - a linear free energy relationship - a general method for examining changes in charges during a reaction C A brief look at other linear free energy relationships C Acid-base related effects - Brønsted relationships C Why do linear free energy relationships work? Catalysis - Anslyn and Dougherty chapter 9 (Lectures 30, 31 & 32, November 11, 14, 16) homework problems: 2, 3, 5, 7, 8, 10, 11, 14, 15, 19. C General principles of catalysis C Forms of catalysis 12 C Brønsted acid-base catalysis - specific, general, the Brønsted catalysis law, the Week Topics -3-
4 dynamics of proton transfers C Enzymatic catalysis Organic Reaction Mechanism, Part 1; Reactions Involving Additions and/or Eliminations - Anslyn and Dougherty chapter 10 (lectures 33, 34, 35, 36 & 37, November 18, 21, 28, 30, December 2) homework problems: 1, 2, 4, 6, 9, 11, 12, 14, 17, 18, 20, 26, 29, 31, 39, 41, 42, 47, 50, 51. C Predicting organic reactivity from polarities, structures of reaction partners 13 C Addition reactions: - hydration of carbonyl groups - hydration of alkenes and alkynes by electrophilic addition of water - electrophilic addition of hydrogen halides to alkenes and alkynes - electrophilic addition of halogens to alkenes - hydroboration - epoxidation - nucleophilic additions to carbonyl compounds - nucleophilic additions to olefins - radical additions to unsaturated systems - carbene additions and insertions 14 C Eliminations - eliminations to form carbonyls or carbonyl-like intermediates - eliminations of aliphatic systems forming alkenes - eliminations from radical intermediates C Combining addition and elimination - substitution at sp 2 centers - addition of nitrogen nucleophiles to carbonyls, followed by elimination - addition of carbon nucleophiles followed by elimination - the Wittig reaction - acyl transfers - electrophilic aromatic substitution - nucleophilic aromatic substitution - reactions involving benzyene - the S RN 1 reaction on aromatic rings - radical aromatic substitutions Organic Reaction Mechanisms, Part 2: Substituions at Aliphatic Centers and Thermal Isomerizations/Rearrangements - Anslyn and Dougherty chapter 11 (lectures 38, 39, 40, December 5, 7, 9) homework problems: 2, 5, 7, 10, 13, 14, 17, 20, 23, 31, 34, 37, 40, 45, 47, 49, C Substitution " to a carbonyl center: enol and enolate chemistry - tautomerization - "-halogenation and alkylation - the aldol reaction C Substitutions at aliphatic centers - limiting S N 2 and S N 1 reactions and intermediate cases - carbocation rearrangements - radical aliphatic substitution C Isomerizations and rearrangements - migrations to electrophilic carbon and electrophilic heteroatoms - the Favorskii rearrangement and other carbanion rearrangements -4-
5 End of the semester -5-
This syllabus is printed on both sides of each page in the hard-copy version.
TO: FROM: Prospective Chemistry 5511 Students Peter Gaspar August 13, 2010 SUBJECT: Course Syllabus for Chemistry 5511 Fall 2010 Chemistry 5511 Mechanistic Organic Chemistry is the first semester of a
More informationCOURSE UNIT DESCRIPTION. Type of the course unit. Mode of delivery Period of delivery Language of instruction Face to face Autumn English
Course unit title Organic Chemistry I Lecturer(s) Dr. Rimantas Vaitkus COURSE UNIT DESCRIPTION Department Dept. Organic Chemistry, Vilnius University Cycle First Type of the course unit Mode of delivery
More informationAdvanced Organic FOURTH. Part A: Structure and Mechanisms
Advanced Organic FOURTH Chemistry EDITION Part A: Structure and Mechanisms Advanced Organic Chemistry PART A: Structure and Mechanisms PART B: Reactions and Synthesis Advanced Organic Chemistry FOURTH
More informationEASTERN ARIZONA COLLEGE General Organic Chemistry I
EASTERN ARIZONA COLLEGE General Organic Chemistry I Course Design 2015-2016 Course Information Division Science Course Number CHM 235 (SUN# CHM 2235) Title General Organic Chemistry I Credits 4 Developed
More informationJEFFERSON COLLEGE COURSE SYLLABUS CHM200 ORGANIC CHEMISTRY I. 5 Credit Hours. Prepared by: Richard A. Pierce
JEFFERSON COLLEGE COURSE SYLLABUS CHM200 ORGANIC CHEMISTRY I 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: January 2008 by Ryan H. Groeneman Arts & Science Education Dr. Mindy Selsor, Dean
More informationCHEM 251 (4 credits): Description
CHEM 251 (4 credits): Intermediate Reactions of Nucleophiles and Electrophiles (Reactivity 2) Description: An understanding of chemical reactivity, initiated in Reactivity 1, is further developed based
More informationCourse Outline. TERM EFFECTIVE: Fall 2016 CURRICULUM APPROVAL DATE: 03/14/2016
5055 Santa Teresa Blvd Gilroy, CA 95023 Course Outline COURSE: CHEM 12A DIVISION: 10 ALSO LISTED AS: TERM EFFECTIVE: Fall 2016 CURRICULUM APPROVAL DATE: 03/14/2016 SHORT TITLE: ORGANIC CHEMISTRY LONG TITLE:
More informationCOWLEY COLLEGE & Area Vocational Technical School
COWLEY COLLEGE & Area Vocational Technical School COURSE PROCEDURE FOR Student Level: This course is open to students on the college level in the sophomore year. Catalog Description: CHM4250 - ORGANIC
More informationCourse Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 211. Course Name: Organic Chemistry I
Department: Science & Technology Date: April 2012 I. Course Prefix and Number: CHM 211 Course Name: Organic Chemistry I Course Syllabus Credit Hours and Contact Hours: 5 credit hours and 7 (3:3:1) contact
More informationp Bonds as Nucleophiles
Chapter 8 p Bonds as Nucleophiles REACTIONS OF ALKENES, ALKYNES, DIENES, AND ENOLS Copyright 2018 by Nelson Education Limited 1 8.2.1 Orbital structure of alkenes Geometry: Electrostatic potential: Electron-rich
More informationCHM 235 GENERAL ORGANIC CHEMISTRY I
CHM 235 GENERAL ORGANIC CHEMISTRY I PRESENTED AND APPROVED: AUGUST 9, 2012 EFFECTIVE: FALL 2013-14 Prefix & Number CHM 235 Course Title: General Organic Chemistry I Purpose of this submission: New Change/Updated
More informationSyllabus for CHEM 241 Organic Chemistry I, 3CR, Great Basin College
Syllabus for CHEM 241 Organic Chemistry I, 3CR, Great Basin College Instructor: David Freistroffer Office: Lundberg 109 (in the fishbowl) Phone: 753-2018, but please use email for fastest possible response
More informationDetailed Course Content
Detailed Course Content Chapter 1: Carbon Compounds and Chemical Bonds The Structural Theory of Organic Chemistry 4 Chemical Bonds: The Octet Rule 6 Lewis Structures 8 Formal Charge 11 Resonance 14 Quantum
More informationJEFFERSON COLLEGE COURSE SYLLABUS CHM200 ORGANIC CHEMISTRY I. 5 Credit Hours. Prepared by: Richard A. Pierce. Revised by: Sean Birke October, 2013
JEFFERSON COLLEGE COURSE SYLLABUS CHM200 ORGANIC CHEMISTRY I 5 Credit Hours Prepared by: Richard A. Pierce Revised by: Sean Birke October, 2013 Ms. Linda Abernathy, Math, Science & Business Division Chair
More informationSul Ross State University Syllabus for Organic Chemistry II: CHEM 3408 (Spring 2017)
Sul Ross State University Syllabus for Organic Chemistry II: CHEM 3408 (Spring 2017) Class: Organic Chemistry II Instructor: Dr. David J. Leaver Room: WSB 307 Office: WSB 318 Time: MWF 9:00-9:50am Office
More informationDEPARTMENT: Chemistry
CODE: CHEM 203 TITLE: Organic Chemistry I INSTITUTE: STEM DEPARTMENT: Chemistry COURSE DESCRIPTION: Students will apply many concepts from general chemistry to a study of organic chemistry. They will be
More informationDEPARTMENT: Chemistry
CODE CHEM 204 TITLE: Organic Chemistry II INSTITUTE: STEM DEPARTMENT: Chemistry COURSE DESCRIPTION: A continuation of CHEM-203, students will extend their studies into topics including aromatic hydrocarbons,
More informationA. Loupy, B.Tchoubar. Salt Effects in Organic and Organometallic Chemistry
A. Loupy, B.Tchoubar Salt Effects in Organic and Organometallic Chemistry 1 Introduction - Classification of Specific Salt Effects 1 1.1 Specific Salt Effects Involving the Salt's Lewis Acid or Base Character
More informationCHE 171: Mechanistic Organic Chemistry I
CHE 171: Mechanistic Organic Chemistry I Syllabus, Autumn Quarter 2003 Instructor: Dr. Matthew R. Dintzner Office hours: Mondays 9:00-11:30 AM, Tuesdays 10:00-12:30, or by appointment Office, Lab: O'Connell
More informationCourse Syllabus : First semester, 2017/2018. Course code: Credit hours: 3 hours. Office Number. Office Hours
Philadelphia University Faculty of pharmacy Department of pharmaceutical science Course Syllabus : First semester, 17/18 Course Title: Pharmaceutical Organic Chemistry (I) Course Level: 1 st year Lecture
More informationSeptember [KV 804] Sub. Code: 3804
September 2009 [KV 804] Sub. Code: 3804 (Regulations 2008-2009) (Candidates admitted from 2008-2009 onwards) Paper IV PHARMACEUTICAL ORGANIC CHEMISTRY Time : Three hours Maximum : 70 marks Answer All questions
More informationCHEMISTRY 231 GENERAL ORGANIC CHEMISTRY I FALL 2014 List of Topics / Examination Schedule
Page 1 of 5 CHEMISTRY 231 FALL 2014 List of Topics / Examination Schedule Unit Starts Topic of Study 20 Aug 2014 STRUCTURE AND BONDING Suggested Reading: Chapter 1 29 Aug 2014 ALKANES & CYCLOALKANES Suggested
More informationCHEM*2700 ORGANIC CHEMISTRY I (Spring/Summer Semester 2009) Information Sheet and Course Outline
CHEM*2700 ORGANIC CHEMISTRY I (Spring/Summer Semester 2009) Information Sheet and Course Outline Instructor: Professor William Tam Office: MacN 332 Phone: 824-4120 (Ext.52268) E-mail: wtam@uoguelph.ca
More informationCHEM2077 HONORS ORGANIC CHEMISTRY SYLLABUS
CHEM2077 HONORS ORGANIC CHEMISTRY SYLLABUS 1. STRUCTURE AND BONDING a] Atomic structure and bonding b] Hybridization and MO Theory c] Drawing chemical structures 2. POLAR COVALENT BONDS: ACIDS AND BASES
More informationKeynotes in Organic Chemistry
Keynotes in Organic Chemistry Second Edition ANDREW F. PARSONS Department of Chemistry, University of York, UK Wiley Contents Preface xi 1 Structure and bonding 1 1.1 Ionic versus covalent bonds 1 1.2
More informationCompletions Multiple Enrollment in same semester. 2. Mode of Instruction (Hours per Unit are defaulted) Hegis Code(s) (Provided by the Dean)
CALIFORNIA STATE UNIVERSITY CHANNEL ISLANDS COURSE MODIFICATION PROPOSAL Courses must be submitted by November 2, 2009, to make the next catalog (2010--2011) production DATE (CHANGE DATE EACH TIME REVISED):
More informationCourse Outline For: Organic Chemistry I (CHM 270) Credits: 5 Contact Hours: Lecture: 3 Lab: 4
Course Outline For: Organic Chemistry I (CHM 270) Credits: 5 Contact Hours: Lecture: 3 Lab: 4 NOTE on Laboratory: Both Lecture and Laboratory must be taken simultaneously; separate grades will not be given
More informationAbout the GRE Chemistry Subject Test p. 1 About the GRE Chemistry Subject Test GRE Chemistry Topics Test Dates Testing Fee Test Format Testing Time
About the GRE Chemistry Subject Test p. 1 About the GRE Chemistry Subject Test GRE Chemistry Topics Test Dates Testing Fee Test Format Testing Time Scoring To Guess or Not to Guess On the Day of the Test
More informationCourse Goals for CHEM 202
Course Goals for CHEM 202 Students will use their understanding of chemical bonding and energetics to predict and explain changes in enthalpy, entropy, and free energy for a variety of processes and reactions.
More informationCourse Syllabus: Advanced Inorganic Chemistry I - ChemS 330
Course Syllabus: Advanced Inorganic Chemistry I - ChemS 330 Division Physical Science and Engineering Division Course Number ChemS 330 Course Title Academic Semester Advanced Inorganic Chemistry I Fall
More informationORGANIC CHEMISTRY. Fifth Edition. Stanley H. Pine
ORGANIC CHEMISTRY Fifth Edition Stanley H. Pine Professor of Chemistry California State University, Los Angeles McGraw-Hill, Inc. New York St. Louis San Francisco Auckland Bogota Caracas Lisbon London
More informationCH 331 Syllabus Fall 2012
Instructor Information: Dr. Daniel J. T. Myles Office: Gilbert Hall 145 Phone: 541-737-6756 E-mail: daniel.myles@oregonstate.edu All course information, updates, and announcements are posted via Blackboard
More informationLevel I Course Units Offered by The Department of Chemistry For
Level I Course Units Offered by The Department of Chemistry For General Degree (3 year) [Bachelor of Science SLQF5] General Degree (4 year-molecular Biology & Biotechnology) [Bachelor of Science (Molecular
More informationCHEM*2700 ORGANIC CHEMISTRY I (Spring/Summer Semester 2010) Information Sheet and Course Outline
CHEM*2700 ORGANIC CHEMISTRY I (Spring/Summer Semester 2010) Information Sheet and Course Outline Instructor: Professor William Tam Office: MacN 332 Phone: 824-4120 (Ext.52268) E-mail: wtam@uoguelph.ca
More informationChemistry Class 11 Syllabus
Chemistry Class 11 Syllabus Course Structure Unit Title Marks I Basic Concepts of Chemistry 11 II Structure of Atom III Classification of Elements & Periodicity in Properties 4 IV Chemical Bonding and
More informationCHEM2410 Organic Chemistry I - Honors
CHEM2410 Organic Chemistry I - Honors The University of Toledo Department of Chemistry and Biochemistry College of Natural Sciences and Mathematics CRN: 49264/49268 (Sect. 091/092) Instructor: Dr. Peter
More informationPhysical organic chemistry
Physical organic chemistry Second edition Neil S. Isaacs Foreword to first edition Foreword to second edition Symbols and abbreviations Mechanistic designations vi i ix xxvi i xxvii r Models of chemical
More informationOrganic Chemistry I Lesson Objectives, Lesson Problems, Course Outline Spring 2008
Organic Chemistry I Lesson Objectives, Lesson Problems, Course Outline Spring 2008 Lesson Date Assignment Lesson Objective Description Lesson Problems 4 14-Jan Chapter 1 Quiz Describe how bond polarity
More informationCHM1001, 1002, 1051, <PHY1101, 1102, 1001, 1002> or <BIO1101, 1102, 1105, 1106> Total 16 cr.
Major: (1) credits: - Multiple majors: minimum of 4 credits - Single major: minimum of 48 credits - Teacher training program: minimum of 51 credits () Required courses: 0 credits Required: CHM101, 151,
More informationStudy Time: You should plan to spend about 2 hours studying for each hour of class lecture.
Mercyhurst College Organic Chemistry I ( Sec.1) Winter Term 2013 Chemistry 240 Dr. J. Williams (ex. 2386, 309 Zurn) Department of Chemistry and Biochemistry http://math.mercyhurst.edu/~jwilliams/ Lecture:
More informationCape Cod Community College
Cape Cod Community College Departmental Syllabus Prepared by the Department of Natural Sciences & Applied Technology Date of Departmental Approval: February 3, 2014 Date Approved by Curriculum and Programs:
More informationCOWLEY COLLEGE & Area Vocational Technical School
COWLEY COLLEGE & Area Vocational Technical School COURSE PROCEDURE FOR ORGANIC CHEMISTRY II CHM 4251 5 Credit Hours Student Level: This course is open to students on the college level in the sophomore
More informationChemistry 330 Fall 2015 Organic Chemistry I
Chemistry 330 Fall 2015 Organic Chemistry I Instructor: John G. Kodet Contact Information: Office: Faraday Hall 335 Email: jkodet@niu.edu Office Hours: MW 2:00-3:00 pm, and by appointment Lecture: MWF
More informationCourse Syllabus: Advanced Inorganic Chemistry I - ChemS 330
Course Syllabus: Advanced Inorganic Chemistry I - ChemS 330 Division Physical Science and Engineering Division Course Number ChemS 330 Course Title Academic Semester Advanced Inorganic Chemistry I Fall
More informationCCHEMISTRY 366. Inorganic Chemistry with Emphasis on Bioinorganic, Medicinal & Materials Chemistry
CCHEMISTRY 366 Inorganic Chemistry with Emphasis on Bioinorganic, Medicinal & Materials Chemistry Instructor: North Building Office Hours: to be decided by class, probably Tuesday after class or by appointment.
More informationExam 1 (Monday, July 6, 2015)
Chem 231 Summer 2015 Assigned Homework Problems Last updated: Friday, July 24, 2015 Problems Assigned from Essential Organic Chemistry, 2 nd Edition, Paula Yurkanis Bruice, Prentice Hall, New York, NY,
More informationCHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Text Sections (N0 1.9, 9-11) Homework: Chapter 1:
CHEM 261 HOME WORK Lecture Topics: MODULE 1: The Basics: Bonding and Molecular Structure Atomic Structure - Valence Electrons Chemical Bonds: The Octet Rule - Ionic bond - Covalent bond How to write Lewis
More informationRequired Materials For complete material(s) information, refer to
Butler Community College Science, Technology, Engineering, and Math Division Robert Carlson Revised Fall 2017 Implemented Spring 2018 COURSE OUTLINE Organic Chemistry 1 Course Description CH 240. Organic
More informationOrganic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers
Chapter Organic Chemistry 112 A B C - Syllabus Addendum for Prospective Teachers Ch 1-Structure and bonding Ch 2-Polar covalent bonds: Acids and bases McMurry, J. (2004) Organic Chemistry 6 th Edition
More informationCLASS VIII XI. Month Unit Topic Sub Topic
April- Bridge Some Basic General Introduction : Importance and scope of May Course Concepts of chemistry. Historical approach to particulate Chemistry nature of matter, laws of chemical combination, Dalton
More informationFundamentals of. Organic Chemistry. for. [Second Year B.Sc. (Main) Students of M.G. University, Kerala] III Semester
Fundamentals of Organic Chemistry for [Second Year B.Sc. (Main) Students of M.G. University, Kerala] III Semester (This Book is an outcome of Modern Organic Chemistry by M.K. Jain & S.C. Sharma duly recommended
More informationChemistry 401: Modern Inorganic Chemistry (3 credits) Fall 2017
Chemistry 401: Modern Inorganic Chemistry (3 credits) Fall 2017 Monday, Wednesday, Friday 9:10-10:00 am in Troy G5 Syllabus Instructor: Professor Qiang Zhang Office: Troy 220 Phone: 509-335-1269 Email:
More informationCHEMISTRY 263 HOME WORK
Lecture Topics: CHEMISTRY 263 HOME WORK Module7: Hydrogenation of Alkenes Hydrogenation - syn and anti- addition - hydrogenation of alkynes - synthesis of cis-alkenes -synthesis of trans-alkenes Text sections:
More informationSYLLABUS. Departmental Syllabus. Organic Chemistry I CHEM Departmental Syllabus. Departmental Syllabus. Departmental Syllabus
DATE OF LAST REVIEW: 05/2018 CIP CODE: 24.0101 SYLLABUS SEMESTER: COURSE TITLE: COURSE NUMBER: Organic Chemistry I CHEM-0211 CREDIT HOURS: 3 INSTRUCTOR: OFFICE LOCATION: OFFICE HOURS: TELEPHONE: EMAIL:
More informationModule9. Nuclear Magnetic Resonance Spectroscopy Nuclear Magnetic Resonance (NMR) spectroscopy - Chemical shift - Integration of signal area
1 CHEMISTRY 263 HOME WORK Lecture Topics: Module7. Hydrogenation of Alkenes The Function of the Catalyst - Syn and anti- addition Hydrogenation of Alkynes - Syn- addition of hydrogen: Synthesis of cis-alkenes
More informationSubstitution α to a carbonyl center: Enol and enolate chemistry
Chapter 11 Organic Reaction Mechanisms, Part 2: Substitutions at Aliphatic Centers and Thermal Isomerizations/Rearrangements 11.1 Tautomerization Substitution α to a carbonyl center: Enol and enolate chemistry
More informationChemistry PhD Qualifying Exam Paper 1 Syllabus
Chemistry PhD Qualifying Exam Paper 1 Syllabus Preface This document comprises all topics relevant for Paper 1 of the Ph.D. Qualifying Exam in Chemistry at Eastern Mediterranean University, in accordance
More informationORGANIC CHEMISTRY 1 CHEM A FALL 2004 SYLLABUS
ORGANIC CHEMISTRY 1 CHEM A300-001 FALL 2004 SYLLABUS DR. D. ANDREW KNIGHT Office: Monroe 231 Phone: 865-2269 E-mail: daknight@loyno.edu Web: http://www.loyno.edu/~knightgr INTRODUCTION AND OBJECTIVES Organic
More informationJEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II. 5 Credit Hours. Prepared by: Richard A. Pierce
JEFFERSON COLLEGE COURSE SYLLABUS CHM201 ORGANIC CHEMISTRY II 5 Credit Hours Prepared by: Richard A. Pierce Revised Date: January 2008 by Ryan H. Groeneman Arts & Science Education Dr. Mindy Selsor, Dean
More informationChem 251 Fall Learning Objectives
Learning Objectives Chapter 8 (last semester) 1. Write an electron-pushing mechanism for an SN2 reaction between an alkyl halide and a nucleophile. 2. Describe the rate law and relative rate of reaction
More information1. Radical Substitution on Alkanes. 2. Radical Substitution with Alkenes. 3. Electrophilic Addition
1. Radical Substitution on Alkanes Only Cl and Br are useful at the laboratory level. Alkane reactivity: tertiary > secondary > primary > methyl Numbers below products give their relative yield. Relative
More informationELECTRON FLOW IN ORGANIC CHEMISTR Y. Paul H. Scudder
ELECTRON FLOW IN ORGANIC CHEMISTR Y Paul H. Scudder 1 BONDING AND ELECTRON DISTRIBUTION 1 2 THE PROCESS OF BOND FORMATION 3 4 3 STABILITY AND REACTIVITY OF INTERMEDIATES 5 6 4 CLASSIFICATION OF ELECTRON
More informationSYLLABUS CHEM 212 / ENCH 212: Principles of Chemical Reactivity
SYLLABUS 2015 - CHEM 212 / ENCH 212: Principles of Chemical Reactivity Course instructor: Lab instructor: Dr. Jason Z. Vlahakis Chernoff Hall, Office Room 215 Phone: 613-533-6000 x 77769 E-mail: jason.vlahakis@chem.queensu.ca
More informationCourse Syllabus. Department: Science & Technology. Date: April I. Course Prefix and Number: CHM 212. Course Name: Organic Chemistry II
Department: Science & Technology Date: April 2012 I. Course Prefix and Number: CHM 212 Course Name: Organic Chemistry II Course Syllabus Credit Hours and Contact Hours: 5 credit hours and 7 (3:3:1) contact
More informationTHE ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS
THE ORGANOMETALLIC CHEMISTRY OF THE TRANSITION METALS Second Edition ROBERT H. CRABTREE Yale University New Haven, Connecticut A Wiley-Interscience Publication JOHN WILEY & SONS New York / Chichester /
More informationSpring Term 2012 Dr. Williams (309 Zurn, ex 2386)
Chemistry 242 Organic Chemistry II Spring Term 2012 Dr. Williams (309 Zurn, ex 2386) Web Page: http://math.mercyhurst.edu/~jwilliams/ jwilliams@mercyhurst.edu (or just visit Department web site and look
More informationCHEM ORGANIC CHEMISTRY
BRAZOSPORT COLLEGE LAKE JACKSON, TEXAS SYLLABUS CHEM 2423 - ORGANIC CHEMISTRY CATALOG DESCRIPTION: CHEM 2423 Organic Chemistry I. CIP 4005045203 A study of the nomenclature, classification and reactions
More informationSPECIFIC AIMS. I year (1st semester) A.Y
I year (1st semester) A.Y. 2017-2018 MARINI S. COORDINATOR Scientific Field CHEMISTRY AND INTRODUCTORY BIOCHEMISTRY TUTOR ECTS BIO/10 Chemistry and Introductory Biochemistry Marini Stefano 5 BIO/10 Chemistry
More informationBoston University Dresden Science Program ORGANIC CHEMISTRY CAS CH 203 Lecture
Boston University Dresden Science Program ORGANIC CHEMISTRY CAS CH 203 Lecture Instructor: Professor Wolf D. Habicher, Dr. Tilo Lübken, Dr. Cordelia Zimmerer Meeting Times Lectures: twice a week at 90
More informationSeptember 2011 BOTH THEORY AND LABORATORY PARTS OF THIS COURSE MUST BE TAKEN CONCURRENTLY IN ORDER TO RECEIVE CREDIT.
FARMINGDALE STATE COLLEGE DEPARTMENT OF CHEMISTRY COURSE OUTLINE: COURSE TITLE: Dr. M. De Castro September 2011 Organic Chemistry I COURSE NUMBER: CHM 270 CREDITS: 5 CONTACT HOURS: Lecture: 3 Laboratory:
More informationChapter 5. Reactions of Alkenes and Alkynes
Learning objectives: Chapter 5. Reactions of Alkenes and Alkynes 1. Differentiate primary, secondary, and tertiary carbocations, and recognize the order of stability for these carbocations. 2. Identify
More informationPreparation of alkenes
Lecture 11 אלקנים הכנה ותגובות של אלקנים: הידרוגנציה, סיפוח הידרוהלוגנים )כלל מארקובניקוב(, סיפוח הלוגנים והסטראוכימיה של תוצרי הסיפוח, הידרובורציה, אפוקסידציה, אוזונוליזה. 1 Preparation of alkenes 1.
More informationHunan University. CHEM32: Organic Chemistry
Academic Inquiries: Hunan University Email: iss@hnu.edu.cn Hunan University CHEM32: Organic Chemistry Professor: To be announced Total contact hours: 54 hours Credit: 4 Course Description Topics covered
More informationChemistry 401 : Modern Inorganic Chemistry (3 credits) Fall 2014
Chemistry 401 : Modern Inorganic Chemistry (3 credits) Fall 2014 Monday, Wednesday, Friday 10:10-11 am in Fulmer 225 Syllabus Instructor: Professor Zachariah Heiden Office: 40 Fulmer Hall Phone: 509-335-0936
More informationChemistry 534 Fall 2012 Advanced Organic Chemistry (Physical Organic: Structure and Mechanism)
Chemistry 534 Fall 2012 Advanced Organic Chemistry (Physical Organic: Structure and Mechanism) California State University Northridge Lecture: Instructor: Dr. Thomas Minehan Office: Science 2314 Office
More informationCOURSE OBJECTIVES / OUTCOMES / COMPETENCIES.
COURSE OBJECTIVES / OUTCOMES / COMPETENCIES. By the end of the course, students should be able to do the following: See Test1-4 Objectives/Competencies as listed in the syllabus and on the main course
More informationChemistry Organic Chemistry II, Spring 2018
Chemistry 2320 Organic Chemistry II, Spring 2018 Instructor: Dr. Tom Chang Office: Widtsoe 337 Phone: 797-3545 Email: tom.chang@usu.edu Meeting Time/Place: MWF 10:30-11:20 am, Eccles Business Building
More informationNuggets of Knowledge for Chapter 17 Dienes and Aromaticity Chem 2320
Nuggets of Knowledge for Chapter 17 Dienes and Aromaticity Chem 2320 I. Isolated, cumulated, and conjugated dienes A diene is any compound with two or C=C's is a diene. Compounds containing more than two
More informationChemistry 610: Organic Reactions Fall 2017
Instructor Prof. David Powers Office: Chemistry 320 Phone: 979.862.3089 E-mail: david.powers@chem.tamu.edu Learning Outcomes Chemistry 610: Organic Reactions Fall 2017 Tuesday and Thursday 2:20 3:35 PM
More informationLearning Guide for Chapter 11 - Alkenes I
Learning Guide for Chapter 11 - Alkenes I I. Introduction to alkenes - p 1 bond structure, classifying alkenes, reactivity, physical properties, occurrences and uses, spectroscopy, stabilty II. Unsaturation
More informationMontgomery County Community College CHE 261 Organic Chemistry I
Montgomery County Community College CHE 261 Organic Chemistry I 4-3-3 COURSE DESCRIPTION: This course covers the nomenclature, structure, properties and reactions of many important classes of organic compounds.
More informationCourse Title. All students are expected to take the College Board Advanced Placement Exam for Chemistry in May.
Course Title ERHS Chemistry A (AP) Description/ Target group This is two-semester laboratory course of inorganic chemistry, designed for college bound students entering the fields of science and engineering,
More informationA SURVEY OF ORGANIC CHEMISTRY CHEMISTRY 1315 TuTr 9:35-10:55 am, Boggs B6
GEORGIA INSTITUTE OF TECHNOLOGY School of Chemistry and Biochemistry Spring 2004 A SURVEY OF ORGANIC CHEMISTRY CHEMISTRY 1315 TuTr 9:35-10:55 am, Boggs B6 Instructor: Marcus Weck Office: Boggs 3-85 Phone:
More informationCHEMISTRY (CHEM) CHEM 5800 Principles Of Materials Chemistry. Tutorial in selected topics in materials chemistry. S/U grading only.
Chemistry (CHEM) 1 CHEMISTRY (CHEM) CHEM 5100 Principles of Organic and Inorganic Chemistry Study of coordination compounds with a focus on ligand bonding, electron counting, molecular orbital theory,
More informationCarlson. Organic chemistry 1 lab manual. Butler Community College.
Butler Community College Science, Technology, Engineering, and Math Division Robert Carlson Fall 2003 Textbook Update Fall 2016 COURSE OUTLINE Organic Chemistry I Course Description: CH240. Organic Chemistry
More information75. A This is a Markovnikov addition reaction. In these reactions, the pielectrons in the alkene act as a nucleophile. The strongest electrophile will
71. B SN2 stands for substitution nucleophilic bimolecular. This means that there is a bimolecular rate-determining step. Therefore, the reaction will follow second-order kinetics based on the collision
More information1/5 09/07/2013 12:12 Chemistry CHEM 1002 Introduction to Chemistry of Cosmetics [3 Credit(s)] [Previous Course Code(s): CHEM 002] This course concentrates on the basic scientific principles in cosmetic
More informationCOURSE UNIT DESCRIPTION. Dept. Organic Chemistry, Vilnius University. Type of the course unit
Course unit title Organic Chemistry II Lecturer(s) Rimantas Vaitkus COURSE UNIT DESCRIPTION Department Dept. Organic Chemistry, Vilnius University Cycle First Type of the course unit Mode of delivery Period
More informationChemistry 8 Principles of Organic Chemistry Spring Semester, 2013
Chemistry 8 Principles of Organic Chemistry Spring Semester, 2013 Instructor: Office Hours: At the Lantern Prof. Jason Hein Mon 2:30 3:30 Email: jhein2@ucmerced.edu Tue 1:30 2:30 Phone: 683-4650 Office:
More informationSul Ross State University Syllabus for General Chemistry I: CHEM 1311 (Fall 2017)
Sul Ross State University Syllabus for General Chemistry I: CHEM 1311 (Fall 2017) Class: General Chemistry I Instructor: Dr. David Leaver Room: WSB 301 Office: WSB 318 Time: TR 8:00-9:15am Office Hours:
More informationCHE 262 (03): Organic Chemistry II Spring 2018 Syllabus MWF 12:50-1:50 in Phillips Lecture Hall
CHE 262 (03): Organic Chemistry II Spring 2018 Syllabus MWF 12:50-1:50 in Phillips Lecture Hall Professor: Dr. Mark V. Wilson Office: Hoyt 360 Email: wilsonmv@westminster.edu (Best way to contact me.)
More informationDr. LeGrande M. Slaughter Chemistry Building Rm. 307E Office phone: ; Tues, Thurs 11:00 am-12:20 pm, CHEM 331D
Syllabus: CHEM 5620 Selected Topics in Inorganic Chemistry: Transition Metal Organometallic Chemistry and Catalysis Spring Semester 2017 (3 credit hours) Instructor: Lecture: Required Text: Office Hours:
More informationCHEM 114 Principles of Chemistry (CRN points)
SCHOOL OF CHEMICAL AND PHYSICAL SCIENCES Te Wânanga Matû CHEM 114 Principles of Chemistry (CRN 17148-15 points) Course Outline trimester 1, 2012 Course coordinator/lecturers Prof James Johnston (Coordinator)
More informationCHEM*2700 ORGANIC CHEMISTRY I (Winter Semester 2007) Information Sheet and Course Outline-Revised
CHEM*2700 ORGANIC CHEMISTRY I (Winter Semester 2007) Information Sheet and Course Outline-Revised Instructor: Professor William Tam Office: MacN 332 Phone: 824-4120 (Ext.52268) E-mail: wtam@uoguelph.ca
More informationChapter 15: Conjugated Systems, Orbital Symmetry, and UV Spectroscopy
Chapter 15: Conjugated Systems, Orbital Symmetry, and UV Spectroscopy Conjugated unsaturated systems have a p orbital on a carbon adjacent to a double bond The p orbital can come from another double (e.g.
More informationAlkenes (Olefins) Chapters 7 & 8 Organic Chemistry, 8 th Edition John McMurry
Alkenes (Olefins) Chapters 7 & 8 Organic Chemistry, 8 th Edition John McMurry 1 Structure and Bonding 2 Structure and Bonding Rotation around the C=C bond is restricted 90 rotation The p orbitals are orthogonal
More informationCOURSE OUTLINE Last Revised and Approved: 12/10/2010 CHEM ORGANIC CHEMISTRY I Units Total Total Hrs Lab
CHEM 210 - ORGANIC CHEMISTRY I Units Lecture Total Hrs Lecture 3.00 Units Lab 2.00 Units Total 5.00 49.50 Total Hrs Lab 99.00 Total Course Hrs 148.50 COURSE DESCRIPTION This course is the first semester
More informationChem 3719 Klein Chapter Practice Problems
Chem 379 Klein Chapter Practice Problems Dr. Peter Norris, 208 Klein Chapter Problems : Review of General Chemistry. Draw viable structures for molecules with the following molecular formulae. Remember
More information2/26/18. Practice Questions. Practice Questions B F. How many steps are there in this reaction?
Practice Questions Practice Questions D B F C E A G How many steps are there in this reaction? 1 Practice Questions D B F C E A G What is the highest-energy transitions state? Practice Questions D B F
More informationThe Ohio State University Department of Chemistry & Biochemistry. Chemistry Graduate Program Autumn Registration Guide For First Year Students
The Ohio State University Department of Chemistry & Biochemistry Chemistry Graduate Program 2018 Autumn Registration Guide For First Year Students General Guidelines We are currently making major revisions
More information