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Moris Harrington
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1 transpec Instant Polymer Analyser Webinar starting soon

2 transpec Instant Polymer Analyser Rapid Measurement of Flame Retardants and Additives

3 Agenda Background Introduction to transpec Features, benefits and comparison Applications Demonstration Summary Q&A

4 Introduction to gnosys Academic origins with industrial backbone commercial step-out following 12 years as the Polymer Research Centre always industrial application focused Expertise with materials (resins, plastics, composites) natural and synthetic polymers and resin systems composites (including micro-to-nano) functional materials and dielectrics Variety of roles ranging: from consultancy to research programs analytical services method and instrument development

5 Introduction to transpec transpechas been specifically designed to meet the challenging needs of the polymer, additive, compounding and masterbatchindustries. These include: an audit trail to certify materials specification linked to QA of raw materials and finished masterbatch optimised formulations for optimal properties and performance demonstrating good product stewardship while achieving materials and process cost savings

6 transpecprinciples-turning data into knowledge Data encompasses: Spectroscopy: Raman and wide wavelength molecular vibrations: information relating to specific compounds, functional groups and their interaction with their local environment Knowledge: Libraries of spectra / data for plastic formulations multivariate statistical analysis uses all spectral data and regresses resses it against known materials characteristics; picks out the information relating to the target parameters only -concentration, properties, processability,, performance... etc. History and legacy value gets better with use and can be re-used

7 Benefits The benefits of transpec include: significantsavings in time and cost of analytical support enhanced on the spot materials quality assurance and formulation control multiplecomponent analysis in the same measurement non-destructive near-line and in-line measurement improved analysis - actual rather than extracted concentrations

8 Comparison of techniques transpec s unique principles allow: Multiple quantitative and predictive measurements not possible using other rapid techniques Faster analysis than other quantitative destructive methods

9 transpecraman transchem TM Smart software Raman spectrometer Handheld probe Optical fibre

10 Features Rapid Raman analysis (seconds) giving results in close to real time Range for additive analysis from 0.1 wt% to 100 wt% High molecular discrimination Multiple additive analysis in the same measurement Low cost and low maintenance No specialised training for routine operators Portable, near-line (now) and in-line/on-line application No extraction and no solvents used in the analysis

11 Tailored measurement technique FIBRE-OPTIC CABLE SOFTWARE RAMAN PROBE RAMAN SPECTROMETER DATA PROCESSING AND SIGNALLING SPECTRAL AND PROPERTY DATABASE OUTPUT / REPORTING: MEASURED PROPERTIES: IDENTIFICATION CONCENTRATION PROPERTIES Analogue 4-20 ma, Digital USB, SCADA... SAMPLE SPECTRUM QUALITY CHECK (ACCEPT OR REPEAT MEASUREMENT) CHEMOMETRICS Tailor probe to application Tailor method to application Tailor analysis to application

12 Materials value chain

13 Applications Quality Control Incoming material inspection Outgoing material inspection Quality Assurance Near-line methods for checking production processes In-line monitoring of production Preparation of customer certification Compliance with legislation - WEEE, REACH, RoHS Formulation and Research support Formulation support - store and analyse batch data Relate performance to formulation Build valuable databases Accumulate knowledge and identify trends Intellectual property management IP policing and protection

14 Types of analysis Analyse: Qualification - identification Quantification concentration Consistency homogeneity & uniformity - dispersion Predict: Processing properties MFI, liquid viscosity Thermal properties glass transition, melting point Physical properties density, mechanical modulus and strength, impact strength Fire properties UL scores, LOI

15 Making measurement models

17 mode select

20 Characteristic spectra of various base polymers ABS PC HIPS

21 Software multivariate statistical analysis Very powerful statistical analysis Use all the spectral information not just known peaks, or overlay fits Regress all the spectral information to properties of interest Build a model Make measurement predictions

22 Plastic type identification ABS, HIPS and PC/ABS with various FRs

23 Measurement model: DecaBDEin ABS Concentration of DecaBDE in ABS matrix Precision ~0.1% FR-1210 concentration from spectra / % FR-1210 concentration / %

32 Materials trialled Polymers ABS Acrylonitrile butadiene styrene HIPS High impact polystyrene PC Polycarbonate PC/ABS Blend of PC and ABS PP Polypropylene LDPE Low-density polyethylene PA Polyamide EVA Ethylene vinyl acetate Fire Retardants and cosynergists Brominated FRs Phosphorous based FRs Melamine cyanurate Antimony trioxide Aluminium trihydrate Properties LOI UL scores

33 transpecsupport and roadmap Supports packages Sample trialing Close partnership Tailored set-up Tailored analysis using facilities Development roadmap Extending database Black materials Probes inline development Software

34 Summary Turning data to knowledge Raman spectroscopy Information rich data Tailored analysis correlated to properties of interest High molecular discrimination Multiple additive analysis in the same non-destructive measurement Significant saving in time and cost of analytical support throughout value chain Low running cost and low maintenance Portable, near-line (now) and in-line application (in development) Correlation with fire performance - e.g. UL-94 Correlation with other materials properties such as MFR, mechanical and thermal properties Sample trials - test your materials Tailored to meet your issues

35 Thank you for listening. Questions and answers

36 Contact details Dr William Mortimore

A NEW RAPID ANALYSIS METHOD FOR FIRE RETARDANTS IN POLYMERS

A NEW RAPID ANALYSIS METHOD FOR FIRE RETARDANTS IN POLYMERS P Baird, H. Herman, W. Mortimore and G. C. Stevens GnoSys UK Ltd, University of Surrey, Guildford, Surrey GU2 7XH, UK. ABSTRACT The reliable