Laser Techniques in Luminescence Spectroscopy

Transcription

1

2 STP 1066 Laser Techniques in Luminescence Spectroscopy Tuan Vo-Dinh and DeLyle Eastwood, editors ASTM 1916 Race Street Philadelphia, Pa

3 Library of Congress Cataloging-in-Publication Data Laser techniques in luminescence spectroscopy / Tuan Vo-Dinh and DeLyle Eastwood, editors. "ASTM publication code number (PCN) "--t.p. verso. Includes bibliographical references. ISBN Luminescence spectroscopy. 2. Laser spectroscopy. I. Vo -Dinh, Tuan. II. Eastwood, D. QC476.6.L ' dc CIP Copyright 9 by AMERICAN SOCIETY FOR TESTING AND MATERIALS 1990 NOTE The Society is not responsible, as a body, for the statements and opinions advanced in this publication. Peer Review Policy Each paper published in this volume was evaluated by three peer reviewers. The authors addressed all of the reviewers' comments to the satisfaction of both the technical editor(s) and the ASTM Committee on Publications. The quality of the papers in this publication reflects not only the obvious efforts of the authors and the technical editor(s), but also the work of these peer reviewers. The ASTM Committee on Publications acknowledges with appreciation their dedication and contribution of time and effort on behalf of ASTM. Printed in Chelsea, MI April 1990

4 Contents Overview Laser Fluorescence Fingerprints of Environmental Materials--A. MELLONE, B. W. SMITH, J. A. VERA, AND J. D. WINEFORDNER Techniques and Applications of Two-Photon Spectroscopy of Inorganic Solidsm D. S. McCLURE Laser Excited Fluorescence in Criminalistics--E. R. MENZEL Laser Induced Fluorescence and lonization Techniques for Combustion Diagnostics--B. E. FORCH, J. B. MORRIS, AND A. W. MIZIOLEK Fluorescence Spectroscopy in the Analysis of Deoxyribonucleic Acid (DNA) Addncts--J. M. HAYES AND G. J. SMALL Temperature and Laser Intensity Effects in Highly Resolved Fluorescence Spectra of Tetracene in Cryogenic Matrices--N. H. VELTHORST, C. OOOIJER, AND J. W. HOFSTRAAT Laser Based Approaches to Increase Fiber-Optic-Based Selectivity: Dynamic Fluorescence Spectroscopy--z. A. BETrS, F. V. BRmHm, O. r r J. HUANG, K. S. LITWILER, AND D. P. PATERNITI Laser Methods in Time-Resolved Anisotropy Measurements: Tetracene in 1-n- Dodecanoi--M. J. WIRTH AND S.-H. CHOU Luminescence and Thermal Lensing in Micellar and Related Media--c. D. TRAN Laser Photolytic Fragmentation-Fluorescence Spectrometry of Nonfluorescent Organic and Organometailic MoleculesmJ. o. JINKINS, J. SCHENDEL, AND E. L. WEHRY Laser Induced Luminescence Spectroscopy on Solid Substrates: An Overviewm T. VO-DINH 133

5 Laser Based Fluorescence Methods for Materials SciencemJ. c. WRIGHT Subattomole Amino Acid Analysis by Laser-Induced Fluorescence: The Sheath Flow Cuvette Meets Capillary Zone Eiectrophoresismv.-F. CHENG AND N. J. DOVICHI Author Index Subject Index

6 Foreword The papers in this publication, Laser Techniques in Luminescence Spectrography, were presented at a Symposium on Laser-Based Approaches in Luminescence Spectroscopy held in Boston, Massachusetts, 30 Oct.-4 Nov at the FACSS XV Meeting of the Federation of Analytical Chemistry and Spectroscopy Societies. This symposium was co-sponsored by the ASTM Subcommittee E13.06 on Molecular Luminescence and by the Department of Energy, Office of Health and Environmental Research, under contract DE-AC05-84OR21400 with Martin Marietta Energy Systems, Inc. Tuan Vo-Dinh, Oak Ridge National Laboratory, Oak Ridge, Tennessee, and DeLyle Eastwood, Lockheed Engineering & Sciences Company, Las Vegas, Nevada, served as symposium chairpersons and as the editors of this publication.

7 Acknowledgments This book is the result of the efforts of many people. First, among them are the many distinguished invited speakers of the symposium, who, by their dedication and hard work, provided the main substance of this book. The editors wish also to thank the technical reviewers, the staff at ASTM, and Ms. J.B. Cooper at Oak Ridge National Laboratory for their assistance in the organization of the symposium and the preparation of this publication. The sponsorship of the ASTM Subcommittee E13.06 on Molecular Luminescence and of the Department of Energy, Office of Health and Environmental Research, under contract DE-AC05-84OR21400 with Martin Marietta Energy Systems, Inc., is gratefully acknowledged.

8