Gerald H. Pollack, PhD University of Washington Seattle
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1 Gerald H. Pollack, PhD University of Washington Seattle Kobe November 2016
2 Gilbert Ling, 1919-
3 Central role of water in biology
4 protein Excludes solutes, particles
5 gel gel Bulk Bulk water water plus plus particles particles Exclusion Exclusion Zone Zone EZ EZ µm µm
6 200 µm Another example
7 Basic finding confirmed Felix Blyakhman (Ural State Univ) Wei-Chun Chin (U. Cal. Merced) Toshio Hirai (Shinshu University) Mark Banaszak Holl (Univ. of Michigan) Tom Lowell (Vermont Photonics) Diedrich Schmidt (Tsukuba) Gerhard Artmann (Aachen) David Maughan (U. Vermont) Miklos Kellermayer (Budapest) Fettah Kosar (Harvard) Jacques Huyghe (Eindhoven) Nikolay Bunkin (Moscow) Federico Carpi (London) etc.
8 Getting to the basis Questions to Answer Is the exclusion phenomenon general? Does it really arise from water ordering? Can water ordering explain anomalies? What energy creates this order? Might these findings apply to health?
9 Question #1: Generality Surfaces: gels, polymers, biological surfaces, monolayers Solutes excluded: down to mw 100 and lower
10 Small solutes excluded ph-sensitive dye(s) H + H + Nafion dye excluded H +
11 Generality many solutes excluded many hydrophilic surfaces generate exclusion zones
12 Question #2 Is this zone physically different from bulk water? EZ
13 Evidence that exclusion-zone (EZ) water is physically different from bulk water EZ water molecules more constrained (NMR) EZ molecules more stable (infrared radiation) EZ has negative charge (electrical potential) EZ absorbs at 270 nm (light-absorption spectrum) EZ is more viscous (falling ball viscometry) EZ molecules aligned (polarizing microscopy) EZ molecular structure different (IR absorption) EZ optical properties different (refractive index) Zheng et al., Adv. Colloid and Interface Sci, 127: 19-27, 2006 Chai et al., J Phys Chem, 112: , 2008 Zheng et al., J. Coll. Interface Sci, 332: , 2009 Yoo et al. J. Phys. Chem. Letters 2: , 2011
14 Evidence that exclusion-zone (EZ) water is physically different from bulk water EZ water molecules more constrained (NMR) EZ molecules more stable (infrared radiation) EZ has negative charge (electrical potential) EZ absorbs at 270 nm (light-absorption spectrum) EZ is more viscous (falling ball viscometry) EZ molecules aligned (polarizing microscopy) EZ molecular structure different (IR absorption) EZ optical properties different (refractive index) Zheng et al., Adv. Colloid and Interface Sci, 127: 19-27, 2006 Chai et al., J Phys Chem, 112: , 2008 Zheng et al., J. Coll. Interface Sci, 332: , 2009 Yoo et al. J. Phys. Chem. Letters 2: , 2011
15 Polyacrylic Acid gel (PAA) or Nafion water
16 Nafion - - from previous slide H + H + H + ph-sensitive dye
17 Control Current vs. Time Current flow between exclusion zone and water beyond Current (ua) Confirms charge separation Time (s)
18 A charged battery in water
19 Evidence that exclusion-zone (EZ) water is physically different from bulk water EZ water molecules more constrained (NMR) EZ molecules more stable (infrared radiation) EZ has negative charge (electrical potential) EZ absorbs at 270 nm (light-absorption spectrum) EZ is more viscous (falling ball viscometry) EZ molecules aligned (polarizing microscopy) EZ molecular structure different (IR absorption) EZ optical properties different (refractive index) Zheng et al., Adv. Colloid and Interface Sci, 127: 19-27, 2006 Chai et al., J Phys Chem, 112: , 2008 Zheng et al., J. Coll. Interface Sci, 332: , 2009 Yoo et al. J. Phys. Chem. Letters 2: , 2011
20 Evidence that exclusion-zone (EZ) water is physically different from bulk water EZ water molecules more constrained (NMR) EZ molecules more stable (infrared radiation) EZ has negative charge (electrical potential) EZ absorbs at 270 nm (light-absorption spectrum) EZ is more viscous (falling ball viscometry) EZ molecules aligned (polarizing microscopy) EZ molecular structure different (IR absorption) EZ optical properties different (refractive index) Zheng et al., Adv. Colloid and Interface Sci, 127: 19-27, 2006 Chai et al., J Phys Chem, 112: , 2008 Zheng et al., J. Coll. Interface Sci, 332: , 2009 Yoo et al. J. Phys. Chem. Letters 2: , 2011
21 Zheng et al., Adv. Colloid and Interface Sci, 127: 19-27, 2006 Chai et al., J Phys Chem, 112: , 2008 Zheng et al., J. Coll. Interface Sci, 332: , 2009 Yoo et al. J. Phys. Chem. Letters 2: , 2011 Evidence that exclusion-zone (EZ) water is physically different from bulk water EZ water molecules more constrained (NMR) EZ molecules more stable (infrared radiation) EZ has negative charge (potential measurement) EZ absorbs at 270 nm (light-absorption spectrum) EZ is more viscous (falling ball viscometry) EZ molecules aligned (polarizing microscopy) EZ molecular structure different (IR absorption)
22 Summary, so far may extend far Liquid crystalline Negative charge very Excludes solutes (Non-dipolar?) Fourth phase of water? (Sir Wm. Hardy, 1912)
23 Summary, so far may extend far Liquid crystalline Negative charge very Excludes solutes (Non-dipolar?) Fourth phase of water? (Sir Wm. Hardy, 1912)
24 Non-dipolar EZ Structure? Negative charge (dipoles neutral) 270-nm absorption (ring-like structures) Structure should have precedent
25 Precedent: ICE remove protons: negative charge; non solid
26
27 NOT H 2 O H 3 O 2
28
29
30 Advantages of Non-dipolar EZ Precedent Negative charge Ring-like structures (270-nm absorption) Able to accommodate helical structures Crystal-like structure can be solidified
31 Freeze-dry: Solid EZ water at room temperature Elia et al. WATER 2013 Elia et al. (in press)
32 Hypothesis: Information stored in EZ Water
33 Generic nucleator surface has no info
34 No information
35 Real nucleator surface contains info
36 Information from nucleating surface Defects project over many EZ layers INFORMATION
37 Another way of imparting information:
38 Electromagnetic energy Resonant vibratory modes Information out
39 Input Electromagnetic Energy can CREATE Information
40 EM waves can impact particular oxygen atoms Each oxygen five oxidation states Huge information-storage capacity
41 Will information storage in EZ water replace conventional info storage? Will information storage in EZ water impact health?
42 EZ layers
43 IR spectra liquid water
44
45 + uv
46
47 Answer to Question #2 Is EZ physically distinct from bulk? Yes Layered honeycomb structure with many implications
48 Question #3: Can crystalline water explain counter-intuitive anomalies? What behavior do we expect from a crystal?
49 Crystalline elements stick together
50 gelatin dessert (95% water) Why doesn t the water dribble out?
51 M Nydén, N Lorén, M Rudemo and M Kvarnström, Chalmers, Sweden
52 Crevices are filled with EZ water EZ water is gel-like.
53 Crystals can be pretty stiff
54 Water forming a bridge? Water forming a bridge? Elmar Fuchs, Wetsus
55 Water structure stiff enough to keep bridge from collapsing
56 Answer to Question #3 Yes Liquid crystalline water explains (many) anomalies
57 Question #4 What charges the water battery? (Incident radiant energy)
58 3.2 Most powerful: infrared 0 EZ-size ratio Wavelength (nm)
59
60 hydrophilic material EZ water
61 Answer to Question #4 Energy? EZ buildup powered by photonic energy Orders water Charges the water battery
62 Can this energy be harvested?
63 Energy can be harvested Nafion tube or PAA-gel tube water
64
65 nafion exclusion zone exclusion zone nafion
66 Polyacrylic acid gel PAA PAA gel gel EZ EZ PAA gel EZ EZ EZ Light 5x velocity Light: 5x speed increase
67 work done -- energy required energy absorption NECESSARY water transduces light energy
68 E = H 2 O
69 Question #5 Is all of this important for health? Foundational for any/all science involving water, molecules, and light Foundational for biological function, health
70 Does Human Biology Use Radiant Energy?
71
72 Pedro Cabrales UCSD
73 Radiant energy drives flow Might radiant energy help drive blood flow?
74 Absorbed external energy may assist blood flow* *Mice: flow continues 1 hour post mortem
75 Blood velocity (μm/s) Chick embryo - 3 days 200 Preliminary data stopped heart 150 IR Control IR Time (seconds)
76 Cell EZ water has negative charge
77 protein
78 with EZ no EZ
79
80 food light absorbed by water
81 Light matters Water matters
82 Water: raw material for building EZ water Green juicing: plant-cell water contains EZ Turmeric, coconut water, etc.: build EZ Sunshine: light builds EZ Sauna: infrared light builds EZ Grounding: negative charge builds EZ
83
84 Conclusions
85
86 Broad implications
87 new Now reviewing pre-proposals Institute for Venture Science funding promising ideas that challenge conventional thinking Looking for Donors
88 Ebnerandsons.com
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