Pittcon External Seminar Template X-ray Analysis in Petrochemical Industry: Challenges and Solutions
|
|
- Katrina Merritt
- 6 years ago
- Views:
Transcription
1 Pittcon External Seminar Template X-ray Analysis in Petrochemical Industry: Challenges and Solutions Al Martin, Christopher Shaffer, Thermo Fisher Scientific, West Palm Beach, USA 1 The world leader in serving science
2 XRF and Petroleum Applications Petroleum and polymer industry products continually evolving Chemical makeup of polymers, lubricants, and fuels altered constantly to meet new functional demands Today's XRF system must be able to satisfy not only today s requirements but also tomorrows needs: More complex formulations Stricter emissions regulations and norms Increased FCC cracking and hydrocracking (catalyst processes) Growth of biofuels Never-ending drive for lower costs and improved quality 2
3 3 Typical Sample Types for XRF Analysis
4 XRF in the Laboratory: Typical Analytical Ranges Combustion : TOC; TN; TS, TOX Arc-Spark OES X-ray Fluorescence ICP-MS ICP-AES GFAAS AAS Solids Liquids 1 ppq 1 ppt 1 ppb 1 ppm 1,000 ppm 100% TRACE BULK 4
5 Sample Preparation Compared with other analytical methods, XRF is the simplest No hot digest or potential dangers through acid use Sample cups simple to assemble, liquid handling minimal Assortment of sample cups and support films make any analysis safe and easy Components within instrument offers further protection to optical path For liquids assemble sample cup and pour liquid to specific volume or weight For solids same as liquids, or pelletize to form pressed pellet Disposal of sample in bulk liquid container or for powder and pellets simply discard 5
6 Petroleum Product Applications Gasoline Naphtha Diesel fuels Kerosene Jet fuel Gas oils Residual fuels Crude oil Biofuels Lubricant additives Lubricant blending FCC catalysts Coke Additives 6
7 Polymers and Additives Performance of today s polymers is synonymous with additives: Accelerants Anti-degradants Anti-foams Anti-oxidants Anti-ozonates Blowing agents Coupling agents Cross linking agents Fillers Flame retardants Plasticizers Processing aids Retarders Stearates UV stabilizers Vegetable oils Others 7
8 X-ray Product Portfolio Thermo Scientific ARL OPTIM X WDXRF Spectrometer: Unique Configuration WDXRF 50W-200W Thermo Scientific ARL PERFORM X WDXRF Spectrometer: High Performance Sequential XRF 1500W-4200W Thermo Scientific ARL QUANT X EDXRF Spectrometer: Top performance EDXRF 8
9 Strengths of the ARL QUANT X EDXRF Spectrometer Electrically (Peltier) cooled Si(Li) detector No liquid nitrogen required Si(Li) detector Long Life 8 primary beam filters Optimized peak to background ratios for all elements (Na U) Choice of excitation voltages: 4kV to 50kV Can be changed by steps of 1kV 4kV = lowest excitation voltage in the market Cement analysis 50kV allows for K line excitation of heavy elements (Cd, Sn, Sb, Ba) Software Thermo Scientific WinTrace software is intuitive and powerful Thermo Scientific UniQuant standard-less analytical software makes using an EDXRF easy 9
10 EDXRF: ASTM F Chromium, Bromine, Cadmium, Mercury, and Lead by EDXRF in polymeric materials Application range: from 20 mg/kg (ppm) to ~1% for each element Repeatability and reproducibility limit example for Bromine: 10
11 EDXRF Result: Si(Li) Detector, Low Power (50W) ARL QUANT X EDXRF spectrometer with Peltier-cooled Si(Li) detector Total 500s counting time LOD achieved Cr 2.0 ppm Br 1.0 ppm Cd 1.5 ppm Hg 1.3 ppm Pb 1.3 ppm Restriction <1000 ppm <1000 ppm <100 ppm <1000 ppm <1000 ppm 11
12 EDXRF Result: PVC Containing Cd and Pb ARL QUANT X spectrometer with Peltiercooled Si(Li) detector Total 200s counting time Difference between 85 ppm and 35 ppm is easy to quantify 12
13 Other ARL QUANT X Examples Analysis of Liquid Hazardous Waste Fuels (LHWF) per ASTM D5839 Cr, Ag, Cd, Sb, Pb 13
14 X-ray Product Portfolio Thermo Scientific ARL OPTIM X WDXRF Spectrometer: Unique Configuration WDXRF 50W-200W Thermo Scientific ARL PERFORM X WDXRF Spectrometer: High Performance Sequential XRF 1500W-4200W Thermo Scientific ARL QUANT X EDXRF Spectrometer: Top performance EDXRF 14
15 ARL OPTIM X Spectrometer: Fuel & Lubricant Analyzer EN ISO (S) ASTM D2622 (ULS, ULSD) ISO (S) ASTM D4927 (Lubs and Additives: Ba, Ca, P, S, Zn) ASTM D6443 (Lubs and Additives:Ca, Cl, Cu, Mg, P, S, Zn) ASTM D7085 (Catalysts) ISO (Cl and Br) ISO (Ni and V) ASTM D5059 (Pb in Gasoline) ASTM D6334 (S in Gasoline) ASTM D6376 (Traces Pet Coke) ASTM D6247 (Polyolefins) Heavy fuel analysis ISO 20884, and Used oil analyses and others 15
16 Limits of Detection in Oils: ARL OPTIM X Fixed Channel vs SmartGonio Goniometer Analysis time: 120S Exceeds the requirements of ISO 8217 and other international standards for sensitivity, range and reliability of heavy fuels analysis 16
17 ARL OPTIM X Spectrometer: Limits of Detection 50W 200W Element SmartGonio Typical Typical configuration LoD in 60s LoD in 60s [ppm] [ppm] Al AX06/FPC Si InSb/FPC P InSb/FPC S InSb/FPC K LiF200/FPC Ca LiF200/FPC V LiF200/FPC Cr LiF200/FPC Mn LiF200/FPC Fe LiF200/FPC Ni LiF200/SC Cu LiF200/SC Zn LiF200/SC Pb LiF200/SC Oil matrix SmartGonio device 60 s counting time Comparison at 50W and 200W FPC : Flow proportional counter SC : Scintillation counter 17
18 PetroilQuant Software 22 elements 200W 200W Element SmartGonio configuration Typical LoD in [ppm] in a counting time of (s) Typical LoD in 60s [ppm] Na AX06/FPC Mg AX06/FPC Al AX06/FPC Si InSb/FPC P InSb/FPC S InSb/FPC Cl InSb/FPC K LiF200/FPC Ca LiF200/FPC Ti LiF200/FPC V LiF200/FPC Cr LiF200/FPC Mn LiF200/FPC Fe LiF200/FPC Ni LiF200/SC Cu LiF200/SC Zn LiF200/SC Mo LiF200/SC Sn LiF200/SC Sb LiF200/SC Ba LiF200/SC Pb LiF200/SC SmartGonio device: Practical limits of detection obtained by repeated analysis on a blank oil LoD = 3 x Standard Deviation Counting time shown FPC : Flow proportional counter SC : Scintillation counter 18
19 Polymer Applications Polymers 19
20 Heavy Elements in Polymers Limits of detection for heavy elements in polymers at 200W 20
21 Polymer Calibrations Factory Calibrations: Calibration for Heavy metals in Polymers (RoHS + As) 6 Elements: Br, Cr, Cd, Hg, Pb, and As Element Range [ppm] Br LoD 1050 ppm Cd LoD 300 ppm Cr LoD 1000 ppm Hg LoD 1100 ppm Pb LoD 1200 ppm As LoD 31 ppm Calibration for Polymer Analysis 5 Elements: Mg, Al, Cl, Ca, Ti Element Range [ppm] Al LoD 30 ppm Ca LoD 25 ppm Cl LoD 50 ppm Mg LoD 50 ppm Ti LoD 15 ppm 21
22 Special ARL OPTIM X Feature: OptiQuant Software Optimization of UniQuant Software for the ARL OPTIM X Series 22
23 OptiQuant: When None or Few Standards are Available OptiQuant is an adaptation of UniQuant software for the ARL OPTIM X spectrometer Thermo Scientific SmartGonio goniometer covering F to U (3 crystals 2 detectors) Total counting time: 5 to 20 Minutes at 200W 70 Elements All other standard features of UniQuant software remain unchanged Counting time can be adjusted depending on requirements Spinning of sample during analysis Layer analysis, etc 23
24 OptiQuant: When None or Few Standards are Available OptiQuant software is peak based so offers greater accuracy and precision compared to scan based standardless routines Scan based routines typically hit peak locations for a fraction of a second while scanning OptiQuant sits on locations from 4 12 seconds All peak and background locations are pre-programmed and maintained by the software Drift corrections achieved through supplied control disks Able to modify count times or optimize new subroutines to specific matrices 24
25 ARL OPTIM X Series: Unique Features Options when considering low power XRF Power - 50 or 200W Based on requirements Fixed Channel Multichromators Limits of detection Greater sensitivities Precision Excellent stability Speed of analysis Budget Sensitivity 200W analytical performance from 50W power 500W analytical performance from 200W power Intelligent Design SmartGonio Device Speed Compact Close coupled Multi-Sample Handling Short optics path Optical encoders Fixed collimator Up to three crystals One or two detectors Access to all elements from F to U (3 crystals - 2 detectors fitted) Individual temperature control on each crystal Individual power supply board 13 position automatic sample changer for Sealed cassettes detectors from Na to Fe Scintillation no spring counter lid from Fe upwards centering rings used Software control of high voltage and vacuum/helium option threshold/window settings using adequate centering ring UCCO: Ultra Close Coupled Optics Features 25
26 ARL OPTIM X Series: Summary Optimized Configurations Sequential analysis with SmartGonio device Sequential-simultaneous analysis: SmartGonio device + 1 or 2 fixed channels Completely simultaneous for 8 elements using 4 multichromators Choice of power 50w or 200w UCCO for greater sensitivity SmartGonio device for fast F-U analysis Option on sample changer Vacuum or Helium atmosphere choice Features 26
27 Client Testimonial ARL OPTIM X instrument met all client requirements in combination with extreme ease of use One of the reasons we chose a system from Thermo Fisher Scientific is that besides the fact that this company is well known in the petroleum industry we ve had very good experiences in maintenance and support from them. - OGC analyst Erwin V The long term stability and reliability of the ARL OPTIM X instrument have also made a very strong impression on the OGC laboratory staff 27
28 X-ray Product Portfolio Thermo Scientific ARL OPTIM X WDXRF Spectrometer: Unique Configuration WDXRF 50W-200W Thermo Scientific ARL PERFORM X WDXRF Spectrometer: High Performance Sequential XRF 1500W-4200W Thermo Scientific ARL QUANT X EDXRF Spectrometer: Top performance EDXRF 28
29 Thermo Solutions in Refineries Environmental regulation compliance Online sulfur detection Refining gas detection Corrosion prevention of refinery piping systems Complex in-process liquid and gas analysis Continuous process monitoring (densities, levels, flow rates, heating values) Process optimization Quality assurance and control Full range of laboratory instruments 29
30 Petroleum Product Applications - WDXRF Requirements Safe analysis Liquid sample recognition sensor Security device in case of spilling Tube shield protection (optional) Speed of analysis with Dual sample loading Urgent sample position Fastest goniometer High precision Accurate goniometer Wider counting linearity Optimized collimator-crystal combinations Optimized filters and X-ray tube conditions 30
31 Petroleum Product Applications - WDXRF Gasoline Naphtha Diesel fuels Kerosene Jet fuel Gas oils Residual fuels Crude oil Biofuels Lubricant additives Lubricant blending FCC catalysts Coke Additives 31
32 ARL PERFORM X Spectrometer in Petrochemicals Ideal for Central Laboratory Versatility for many applications Thin window X-ray tube (30 micron) for high sensitivity in light elements Flexible software options Analysis of any material Standard, Standardless analysis High throughput to research Vacuum/Helium atmosphere ARL OPTIM X instrument as backup system IQ/OQ & Remote Diagnostics for easy installation and serviceability 32
33 Oil Analysis Typical LoD in Oil Analysis 33
34 Thermo Scientific PetroilQuant Software Factory calibrated package for oils analysis Up to 30 elements Calibration maintained using solid drift standards Good for fuels, lubricants, and oils 34
35 Analysis of Traces in Polymers 35
36 UniQuant Software: Unique Standard-less Analysis Peak to peak analysis permits Lower limits of detection Selective counting time Use of sample spinning In case of small samples In case of inhomogeneous samples Evens out effects of polishing grooves on metals 36
37 UniQuant Software - Standard-less Analysis How can UniQuant software be used for total unknowns and irregular samples? Fundamental Parameters algorithms Analysis of up to 79 elements in solid and liquids Different matrix chemistry (element, oxides, carbonates, sulfides,... Area/additive/dilution/layer/mass General or specific matrix sensitivity factors Built in overlap corrections Corrections for medium (Vac for solids/he for Liquids and powders) and films Analysis area - 0.5, 3.0, 10, 20,...mm Analysis area 360, 180, 90, 60, 30 degrees 37
38 Situation Special sample types with no commercial reference materials available Biological (DBS Dried Blood Spots); Cosmetics (Nail Polish); Specially formulated catalysts as examples Difficult and costly to manufacture reference materials inhouse A number of sample components in non-measureable form 38
39 Solution UniQuant software allows for optimization for various components and compounds unique to each sample type Analyzed results confirmed by the more labor intensive ICP-MS and ICP-OES methods Results produced in a fraction of the time compared to other methods with minimal sample preparation 39
40 Client Testimonial ARL PERFORM X instrument with UniQuant software enabled me to quantify diverse sample types that would normally not be considered possible using standard XRF methods Nitrocellulose and other volatile organic compounds were accepted into the calculations to provide more accurate results Working with thin film samples the reliability and precision of primary and duplicate results at trace concentration levels were near identical Andrea McWilliams, Research Triangle Institute 40
41 41 Thank You
S8 TIGER Series 2 for ASTM D 6443
Lab Report XRF 139 S8 TIGER Series 2 for ASTM D 6443 Standard Test Method for Determination of Ca, Cl, Cu, Mg, P, S and Zn in Unused Lubricating Oils and Additives Introduction Lubricating oils are generally
More informationElemental analysis by X-ray f luorescence. Sequential benchtop WDXRF spectrometer
Elemental analysis by X-ray f luorescence Sequential benchtop WDXRF spectrometer Elemental analysis is one of the most important fundamental measurements made for industrial quality control and research
More informationPOWER + FLEXIBILITY IN ELEMENTAL ANALYSIS
POWER + FLEXIBILITY IN ELEMENTAL ANALYSIS Energy Dispersive X-Ray Fluorescence Spectrometry (EDXRF) is an atomic spectroscopy that provides elemental composition analysis of materials. The elemental range
More informationApplication Note XSP-AN-005. Determination of Ultra Low Chlorine (and Sulfur) in Oil. X-Supreme8000. Key Benefits
Determination of Ultra Low Chlorine (and Sulfur) in Oil Application Note XSP-AN-005 Key Benefits The X-Supreme8000 can be used as part of a quality control procedure to ensure petroleum products are manufactured
More informationElemental analysis by X-ray f luorescence. High performance EDXRF elemental analyzer
Elemental analysis by X-ray f luorescence High performance EDXRF elemental analyzer Simple elemental analysis 1. Prepare samples No digestion; minimal sample preparation. Direct non-destructive measurement
More informationMS482 Materials Characterization ( 재료분석 ) Lecture Note 4: XRF
2016 Fall Semester MS482 Materials Characterization ( 재료분석 ) Lecture Note 4: XRF Byungha Shin Dept. of MSE, KAIST 1 Course Information Syllabus 1. Overview of various characterization techniques (1 lecture)
More informationAnalysis of Cadmium (Cd) in Plastic Using X-ray Fluorescence Spectroscopy
Analysis of Cadmium (Cd) in Plastic Using X-ray Fluorescence Spectroscopy Hiroshi Onodera Application & Research Center, JEOL Ltd. Introduction um, PBB and PBDE) are subject to usage restrictions in Europe.
More informationOverview of X-Ray Fluorescence Analysis
Overview of X-Ray Fluorescence Analysis AMPTEK, INC., Bedford, MA 01730 Ph: +1 781 275 2242 Fax: +1 781 275 3470 sales@amptek.com 1 What is X-Ray Fluorescence (XRF)? A physical process: Emission of characteristic
More informationThe RX-6000 Sulfur in Oil Analyzer For the analysis of Sulfur in Oil and other elements from S to U
Oxford House, 20 Oxford St Newbury, Berkshire. RG14 1JB UK. sales@spectrolab.eu sales@spectrolab.co.uk Offices in UK, EU, Greece, Dubai The RX-6000 Sulfur in Oil Analyzer For the analysis of Sulfur in
More informationFUNDAMENTAL PARAMETERS ANALYSIS OF ROHS ELEMENTS IN PLASTICS
45 ABSTRACT FUNDAMENTAL PARAMETERS ANALYSIS OF ROHS ELEMENTS IN PLASTICS W. T. Elam, Robert B. Shen, Bruce Scruggs, and Joseph A. Nicolosi EDAX, Inc. Mahwah, NJ 70430 European Community Directive 2002/95/EC
More informationOn-line XRF analysis of multiple elements in liquid process streams C-QUAND
An ideal tool for multiple element analysis using on-line XRF technology, from low ppm to percentage levels C-QUAND On-line XRF analysis of multiple elements in liquid process streams Introduction The
More informationICP-3000 Inductively Coupled Plasma Optical Emission Spectrometer
Inductively Coupled Plasma Optical Emission Spectrometer Inductively Coupled Plasma Optical Emission Spectrometer Inductively Coupled Plasma Optical Emission Spectrometer is powerful simultaneous full
More informationPeter L Warren, Pamela Y Shadforth ICI Technology, Wilton, Middlesbrough, U.K.
783 SCOPE AND LIMITATIONS XRF ANALYSIS FOR SEMI-QUANTITATIVE Introduction Peter L Warren, Pamela Y Shadforth ICI Technology, Wilton, Middlesbrough, U.K. Historically x-ray fluorescence spectrometry has
More informationInnovative. Intuitive. Concentration (ppb) R = Versatile. Hydra II C Mercury Analyzer
Innovative 0.01 0.1 1 10 Intuitive Concentration (ppb) R = 0.99999 Versatile Hydra II C Mercury Analyzer At Teledyne Leeman Labs; atomic spectroscopy is our business our only business. We are industry
More informationEnhancing the productivity of food sample analysis with the Agilent 7700x ICP-MS
Enhancing the productivity of food sample analysis with the Agilent 77x ICP-MS Application note Foods testing Authors Sebastien Sannac, Jean Pierre Lener and Jerome Darrouzes Agilent Technologies Paris,
More informationMulti-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS
Multi-Element Analysis of Petroleum Crude Oils using an Agilent 7900 ICP-MS Application note Energy and fuels Authors Jenny Nelson, Agilent Technologies, USA Ed McCurdy, Agilent Technologies, UK Introduction
More informationInorganic Elemental Analysis
Thermo Scientific ARL QUANT X X-Ray Fluorescence Spectrometer SDD 1000 inside Inorganic Elemental Analysis for any sample Aerosol Particulate Filters RoHS and WEEE Screening Forensics and Investigation
More informationApplications of ICP-MS for Trace Elemental Analysis in the Hydrocarbon Processing Industry
Applications of ICP-MS for Trace Elemental Analysis in the Hydrocarbon Processing Industry Fundamentals and Applications to the Petrochemical Industry Outline Some background and fundamentals of ICPMS
More informationMulti-element process analyzer
Multi-element process analyzer Elemental analysis by X-ray fluorescence Compact multi-element process analyzer for liquid streams or f ixed position web applications Featuring advanced third generation
More informationApplication Note S/SL
Analysis of Ultra low Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence according to ASTM D Ultra low detection limits Excellent Sensitivity, Repeatability &
More informationS2 PICOFOX. Innovation with Integrity. Spectrometry Solutions TXRF
S2 PICOFOX Spectrometry Solutions Innovation with Integrity TXRF S2 PICOFOX True Trace Analysis with XRF for the First Time! You need to know the concentration of trace elements in environmental samples?
More informationToday s Agilent Solutions for Determining Heavy Metals in Food using Atomic Spectroscopy
Today s Agilent Solutions for Determining Heavy Metals in Food using Atomic Spectroscopy Evrim Kilicgedik Product Specialist, Atomic Spectroscopy Agilent Technologies 04.11.2011 2011 The Atomic Spectroscopy
More informationFUNDAMENTAL PARAMETER METHOD USING SCATTERING X-RAYS IN X-RAY FLUORESCENCE ANALYSIS
FUNDAMENTAL PARAMETER METHOD USING SCATTERING X-RAYS IN X-RAY FLUORESCENCE ANALYSIS 255 Yoshiyuki Kataoka 1, Naoki Kawahara 1, Shinya Hara 1, Yasujiro Yamada 1, Takashi Matsuo 1, Michael Mantler 2 1 Rigaku
More informationTRACE ELEMENT ANALYSIS USING A BENCHTOP TXRF- SPECTROMETER
Copyright JCPDS - International Centre for Diffraction Data 2005, Advances in X-ray Analysis, Volume 48. 236 ABSTRACT TRACE ELEMENT ANALYSIS USING A BENCHTOP TXRF- SPECTROMETER Hagen Stosnach Röntec GmbH,
More informationARL OPTIM X X-Ray Fluorescence Spectrometer. Optimized Performance for Your Application
e l e m e n t a l a n a l y s i s ARL OPTIM X X-Ray Fluorescence Spectrometer Optimized Performance for Your Application Analyze Detect Measure Control ARL OPTIM X Optimized Performance for Your Application
More informationAnalysis of Soil and Sewage Sludge in the Field with a Portable ED-XRF Spectrometer
AN APPLICATION BRIEF FROM SPECTRO ANALYTICAL INSTRUMENTS When results matter Analysis of Soil and Sewage Sludge in the Field with a Portable ED-XRF Spectrometer Introduction Arsenic, barium, cadmium, chromium,
More informationBOXA-II ON-STREAM X-RAY FLUORESCENCE ANALYZER. Technical Description Version 2 BGRIMM AUTOMATION
BOXA-II ON-STREAM X-RAY FLUORESCENCE ANALYZER Technical Description Version 2 BGRIMM AUTOMATION, South 4th Ring Road West, Beijing, China TEL: +86(10)59069762 Fax: +86(10)68360101 Contents BGRIMM AUTOMATION
More informationDirect Analysis of Trace Metal Impurities in High Purity Nitric Acid Using ICP-QQQ
Application Note Semiconductor Direct Analysis of Trace Metal Impurities in High Purity Nitric Acid Using ICP-QQQ Authors Kazuo Yamanaka and Kazuhiro Sakai Agilent Technologies, Tokyo, Japan Introduction
More informationThermo Scientific ICP-MS solutions for the semiconductor industry. Maximize wafer yields with ultralow elemental detection in chemicals and materials
Thermo Scientific ICP-MS solutions for the semiconductor industry Maximize wafer yields with ultralow elemental detection in chemicals and materials Trace impurity analysis in chemicals an used in the
More informationDefining quality standards for the analysis of solid samples
Defining quality standards for the analysis of solid samples Thermo Scientific Element GD Plus Glow Discharge Mass Spectrometer Redefine your quality standards for the elemental analysis of solid samples
More informationOES - Optical Emission Spectrometer 2000
OES - Optical Emission Spectrometer 2000 OES-2000 is used to detect the presence of trace metals in an analyte. The analyte sample is introduced into the OES-2000 as an aerosol that is carried into the
More information110 Lowell Rd Hudson, NH USA Tel:
110 Lowell Rd Hudson, NH 03051 USA Tel: 603-886-8400 www.teledyneleemanlabs.com Product Descriptions and Offerings Teledyne Leeman Labs is a leading innovator of analytical instrumentation for elemental
More informationRoHS/WEEE Measurement of Hazardous Substances in Plastics
HELMUT FISCHER GMBH + + CO. COKG INDUSTRIESTRASSE INDUSTRIESTASSE 21 21 71069 71069 SINDELFINGEN - MAICHINGEN TEL TEL. 07031 07031 // 303-0 FAX 0 FAX 07031 07031 / / 30379 Application Report bn2005_01
More informationElemental analysis by X-ray fluorescence. High performance, direct excitation EDXRF elemental analyzer
Elemental analysis by X-ray fluorescence High performance, direct excitation EDXRF elemental analyzer Energy dispersive X-ray fluorescence spectroscopy for cost-effective performance in a compact package
More informationChemical Analysis. Low Level Oxygenates Analyzer. Trace Analysis of Oxygenates in Hydrocarbon Matrices. Gas Chromatography.
Chemical Analysis Low Level Oxygenates Analyzer Trace Analysis of Oxygenates in Hydrocarbon Matrices think forward Gas Chromatography The determination of sub to high ppm levels of ethers, alcohols, aldehydes
More informationThe. Family of Mercury Analyzers. Hydra II AA Atomic Absorption Detection Liquid Samples
The Hydra II Family of Mercury Analyzers At Teledyne Leeman Labs, atomic spectroscopy is our business our only business. We are industry leading innovators with a proven track record providing systems
More informationThermo Scientific icap RQ ICP-MS: Typical limits of detection
TECHNICAL NOTE 43427 Thermo Scientific icap RQ ICP-MS: Typical limits of detection Author Tomoko Vincent Keywords BEC, interference removal, KED, LOD Introduction Inductively Coupled Plasma Mass Spectrometry
More informationCALCULATION OF THE DETECTOR-CONTRIBUTION TO ZIRCONIUM PEAKS IN EDXRF SPECTRA OBTAINED WITH A SI-DRIFT DETECTOR
CALCULATION OF THE DETECTOR-CONTRIBUTION TO ZIRCONIUM PEAKS IN EDXRF SPECTRA OBTAINED WITH A SI-DRIFT DETECTOR A. C. Neiva 1, J. N. Dron 1, L. B. Lopes 1 1 Escola Politécnica da Universidade de São Paulo
More informationIn-Situ Analysis of Traces, Minor and Major Elements in Rocks and Soils with a Portable XRF Spectrometer*
In-Situ Analysis of Traces, Minor and Major Elements in Rocks and Soils with a Portable XRF Spectrometer* Anthony Thomas 1, Joachim Heckel 1, and Dirk Wissmann 1 Search and Discovery Article #41836 (2016)
More informationProduct Descriptions and Offerings
Product Descriptions and Offerings Teledyne Leeman Labs is a leading innovator of analytical instrumentation for elemental analysis. Laboratories in industries ranging from environmental science, oil and
More informationatomic absorption spectroscopy general can be portable and used in-situ preserves sample simpler and less expensive
Chapter 9: End-of-Chapter Solutions 1. The following comparison provides general trends, but both atomic absorption spectroscopy (AAS) and atomic absorption spectroscopy (AES) will have analyte-specific
More informationNew Developments in Wavelength-Dispersive XRF and XRD for the Analysis of Foodstuffs and Pharmaceutical Materials
36 Spectroscopy 21(9) September 2006 www.spectroscopyonline.com New Developments in Wavelength-Dispersive XRF and XRD for the Analysis of Foodstuffs and Pharmaceutical Materials This article discusses
More informationThe challenges of field sensors for trace metal detection. Chris Searle Product Manager Trace2o Ltd
The challenges of field sensors for trace metal detection Chris Searle Product Manager Trace2o Ltd What is a heavy metal and why is it necessary to determine concentration? Tends to be categorised as Metallic
More informationDetermination of major, minor and trace elements in rice fl our using the 4200 Microwave Plasma- Atomic Emission Spectrometer (MP-AES) Authors
Determination of major, minor and trace elements in rice flour using the 4200 Microwave Plasma- Atomic Emission Spectrometer (MP-AES) Application note Food testing Authors John Cauduro Agilent Technologies,
More informationAnalysis of trace elements in polymer samples to ensure compliance with WEEE-RoHS standards using the Thermo Scientific icap 7200 ICP-OES
APPLICATION NOTE 43145 Analysis of trace elements in polymer s to ensure compliance with WEEE-RoHS standards using the Thermo Scientific icap 7200 ICP-OES Authors Introduction Sanja Asendorf, Application
More informationOXEA - Online Elemental Analyzer
02 25 08 OXEA - Online Elemental Analyzer OXEA (Online X-ray Elemental Analyzer) is based on the X-ray fluorescence technology (XRF) which is well known in the laboratory field. With the aid of a patented
More informationED(P)XRF: SCREENING ANALYSIS AND QUANTITATIVE ANALYSIS with POLARIZED
384 ED(P)XRF: SCREENING ANALYSIS AND QUANTITATIVE ANALYSIS with POLARIZED X-RAYS R. Schramm, J. Heckel, K. Molt 2 Spectra Analytical Instruments, Kleve, Germany. 2Gerhard-Mercator- University Duisburg,
More informationOxygen Demand, Chemical
Oxygen Demand, Chemical DOC316.53.01103 USEPA Reactor Digestion Method Method 10211 1 to 60 mg/l COD (ULR) TNTplus 820 Scope and application: For wastewater, process water, surface water, and cooling water.
More informationPortable type TXRF analyzer: Ourstex 200TX
Excerpted from Adv. X-Ray. Chem. Anal., Japan: 42, pp. 115-123 (2011) H. Nagai, Y. Nakajima, S. Kunimura, J. Kawai Improvement in Sensitivity and Quantification by Using a Portable Total Reflection X-Ray
More informationMining Analyzer XRF-3360
Turnkey Laboratories Solutions Mining Analyzer XRF-3360 Mining Analyzer Intrument is a professional manufacturer of high-performance X-ray Fluorescence Spectrometer. The high-performance desktop XRF geology
More informationCombustion Ion Chromatography. Fast and reliable determination of halogens and sulfur
Combustion Ion Chromatography Fast and reliable determination of halogens and sulfur Combustion digestion and ion chromatography combined in one system 02 Combustion Ion Chromatography (CIC) extends the
More informationThe Agilent 7700x ICP-MS Advantage for Drinking Water Analysis
The Agilent 77x ICP-MS Advantage for Drinking Water Analysis Application Note Environmental Authors Steve Wilbur Agilent Technologies, Inc. 338 146th Place SE, Suite 3, Bellevue Washington, 987 USA Introduction
More informationHigh-Speed Environmental Analysis Using the Agilent 7500cx with Integrated Sample Introduction System Discrete Sampling (ISIS DS)
High-Speed Environmental Analysis Using the Agilent 7500cx with Integrated Sample Introduction System Discrete Sampling (ISIS DS) Application Note Environmental Authors Steve Wilbur Agilent Technologies,
More informationDetermination of ultratrace elements in photoresist solvents using the Thermo Scientific icap TQs ICP-MS
APPLICATION NOTE 43374 Determination of ultratrace elements in photoresist solvents using the Thermo Scientific icap TQs ICP-MS Authors Tomoko Vincent, Product Specialist, Thermo Fisher Scientific Keywords
More informationLAB REPORT ON XRF OF POTTERY SAMPLES By BIJOY KRISHNA HALDER Mohammad Arif Ishtiaque Shuvo Jie Hong
LAB REPORT ON XRF OF POTTERY SAMPLES By BIJOY KRISHNA HALDER Mohammad Arif Ishtiaque Shuvo Jie Hong Introduction: X-ray fluorescence (XRF) spectrometer is an x-ray instrument used for routine, relatively
More informationUltra-fast determination of base metals in geochemical samples using the 5100 SVDV ICP-OES
Ultra-fast determination of base metals in geochemical samples using the 5100 SVDV ICP-OES Application note Geochemistry, metals, mining Authors John Cauduro Agilent Technologies, Mulgrave, Australia Introduction
More informationAltitude influence of elemental distribution in grass from Rila mountain. Dr. E. Nikolova, Dr. A. Artinyan, S. Nikolova INRNE - BAS XRF Laboratory
Altitude influence of elemental distribution in grass from Rila mountain Dr. E. Nikolova, Dr. A. Artinyan, S. Nikolova INRNE - BAS XRF Laboratory I. Introduction The application of modern instrumental
More informationAEROSOL FILTER ANALYSIS USING POLARIZED OPTICS EDXRF WITH THIN FILM FP METHOD
Copyright JCPDS-International Centre for Diffraction Data 2014 ISSN 1097-0002 219 AEROSOL FILTER ANALYSIS USING POLARIZED OPTICS EDXRF WITH THIN FILM FP METHOD Takao Moriyama 1), Atsushi Morikawa 1), Makoto
More informationAnalytical Instruments
Analytical Instruments ToronTech.com About Torontech The Torontech group is proud to be a Canadian corporation headquartered in Toronto; the commercial, technical, and economic hub of Canada. With offices
More informationREX Evaluation Guide. American Micro Detection Systems Inc March Lane, Suite 200 Stockton, CA 95219
REX Evaluation Guide American Micro Detection Systems Inc. 2800 March Lane, Suite 200 Stockton, CA 95219 I. INTRODUCTION REX (Real-time Elemental X-ray Fluorescence System) is the only instrument capable
More informationChemical Analysis. PIONA+ Analyzer. Characterization of Engine Fuels by Hydrocarbon Group Type. Gas Chromatography. think forward
Chemical Analysis PIONA+ Analyzer Characterization of Engine Fuels by Hydrocarbon Group Type think forward Gas Chromatography Bruker 450 PIONA+ Analyzer Bruker s innovative PIONA+ TM Analyzer provides
More informationICP-OES Application Note Number 35
ICP-OES Application Note Number 35 Rapid measurement of major, minor and trace levels in soils using the Varian 730-ES Vincent Calderon Varian, Inc. Introduction As part of the global strategy for sustainable
More informationPRINCIPLE OF ICP- AES
INTRODUCTION Non- flame atomic emission techniques, which use electrothermal means to atomize and excite the analyte, include inductively coupled plasma and arc spark. It has been 30 years since Inductively
More informationFergus Keenan Shona McSheehy Julian Wills
Novel QCell Technology for Inference Removal in ICP-MS - Combining Low Mass Filtration with Kinetic Energy Discrimination Fergus Keenan Shona McSheehy Julian Wills 1 The world leader in serving science
More informationTrace Element Analysis: Time and Cost Savings with TXRF. Bruker AXS Microanalysis GmbH Berlin, Germany
Trace Element Analysis: Time and Cost Savings with TXRF Bruker AXS Microanalysis GmbH Berlin, Germany Welcome Today s Topics Introduction to XRF and TXRF The S2 PICOFOX benchtop TXRF system Application
More informationS8 TIGER ((( Spectrometry Solutions. Innovation with Integrity WDXRF
S8 TIGER ((( Spectrometry Solutions Innovation with Integrity WDXRF Touch the S8 TIGER ((( and control its power Instrument development begins with an analysis of users needs and analytical requirements.
More informationHFM 100 Series. Thermal Conductivity Meter for measurement of insulation and construction materials.
HFM 100 Series Conforms to International Standards ASTM C518, ISO 8301, and EN 12667 Thermal Conductivity Meter for measurement of insulation and construction materials. Hot Disk TPS -160 to 1000 C HFM
More informationDirect Measurement of Metallic Impurities in 20% Ammonium Hydroxide by 7700s/7900 ICP-MS
Direct Measurement of Metallic Impurities in 20% Ammonium Hydroxide by 7700s/7900 ICP-MS Application Note Semiconductor Authors Junichi Takahashi Agilent Technologies Tokyo, Japan Abstract Ammonium hydroxide
More informationEpsilon 1. Focus on the details to capture the bigger picture. Small spot analysis
Epsilon 1 Focus on the details to capture the bigger picture Small spot analysis 1 2 H Z 1.008 3 Li 4 4.003 5 Be 6.941 He Possible to analyze with Epsilon 1 Z 9.012 24.31 22.990 K 20 Ca 40.08 39.098 37
More informationDetermination of the Halogen Elements in the Deep UV Region of the Spectrum by ICP - OES
Prodigy ICP Series Technical Note Determination of the Halogen Elements in the Deep UV Region of the Spectrum by ICP - OES Introduction There are many applications where the ability to measure the halogen
More informationLaboratory 101: A Guide to Understanding your Testing Laboratory
Laboratory 101: A Guide to Understanding your Testing Laboratory Jim Cronin Product Ecology Manager Environmental Monitoring and Technologies, Inc. (EMT) Morton Grove, Illinois Abstract: Laboratory 101:
More informationDevelopments & Limitations in GSR Analysis
Developments & Limitations in GSR Analysis ENFSI Working Group Meeting June 2006 Jenny Goulden Oxford Instruments NanoAnalysis Overview Introduction Developments in GSR Software Importance of EDS Hardware
More informationData report for elemental analysis of IMPROVE samples collected during April, May, June 2009 UC Davis Submitted June 18, 2010 SUMMARY
Data report for elemental analysis of IMPROVE samples collected during April, May, June 2009 UC Davis Submitted June 8, 200 SUMMARY This report summarizes the quality assurance performed during elemental
More informationProcedures for the Determination of Levels of Regulated Substances in Electrotechnical Products
Procedures for the Determination of Levels of Regulated Substances in Electrotechnical Products IEC ACEA ad hoc Working Group Mission of the ad hoc Working Group: Develop a normative document that will
More informationElemental Analysis: CHNS/O characterization of polymers and plastics
APPLICATION NOTE 0 Elemental Analysis: CHNS/O characterization of polymers and plastics Authors Introduction Dr. Liliana Krotz and Dr. Guido Giazzi Thermo Fisher Scientific, Milan, Italy The chemical composition
More informationLow cost EDXRF elemental analyzers
Low cost EDXRF elemental analyzers Energy dispersive X-ray f luorescence NEX QC delivers superior performance in a rugged package Energy dispersive X-ray fluorescence (EDXRF) is a routinely used analytical
More informationData report for elemental analysis of IMPROVE samples collected during April, May, June 2006 UC Davis - Submitted May 14, 2008 SUMMARY
Data report for elemental analysis of IMPROVE samples collected during April, May, June 2006 UC Davis - Submitted May 4, 2008 SUMMARY This report summarizes the quality assurance performed during elemental
More informationBATTERY INDUSTRY STANDARD ANALYTICAL METHOD
BATTERY INDUSTRY STANDARD ANALYTICAL METHOD For the Determination of Mercury, Cadmium and Lead in Alkaline Manganese Cells Using AAS, ICP-AES and "Cold Vapour" European Portable Battery Association (EPBA)
More informationKey Analytical Issues: Sample Preparation, Interferences and Variability. Tim Shelbourn, Eli Lilly and Company
Key Analytical Issues: Sample Preparation, Interferences and Variability Tim Shelbourn, Eli Lilly and Company Presentation Outline Sample preparation objectives and challenges Some common interferences
More informationDetermination of Impurities in Silica Wafers with the NexION 300S/350S ICP-MS
APPLICATION NOTE ICP - Mass Spectrometry Author Kenneth Ong PerkinElmer, Inc. Singapore Determination of Impurities in Silica Wafers with the NexION 300S/350S ICP-MS Introduction The control of impurity
More informationRapid Analysis of High-Matrix Environmental Samples Using the Agilent 7500cx ICP-MS. Application. Author. Abstract. Introduction.
Rapid Analysis of High-Matrix Environmental Samples Using the Agilent 7500cx ICP-MS Application Environmental Author Steven Wilbur Agilent Technologies, Inc. 3380 146th Place, SE, Suite 300 Bellevue, WA
More informationCh. 9 Atomic Absorption & Atomic Fluorescence Spectrometry
Ch. 9 Atomic Absorption & Atomic Fluorescence Spectrometry 9.1 9A. Atomization Most fundamental for both techniques. Typical types 1. flame - burner type 2. Electrothermal graphite furnace 3. Specialized
More informationDimethylglyoxime Method Method to 6.0 mg/l Ni TNTplus 856
Nickel DOC316.53.01065 Dimethylglyoxime Method Method 10220 0.1 to 6.0 mg/l Ni TNTplus 856 Scope and application: For water and wastewater. Test preparation Instrument-specific information Table 1 shows
More informationICP-MS Analysis of Bulk & Process Chemicals for Semiconductor Processes. Ann O Connell Chemical Analysis Eng Intel Corporation
ICPMS Analysis of Bulk & Process Chemicals for Semiconductor Processes Ann O Connell Chemical Analysis Eng Intel Corporation 1 Overview of Presentation Impact of Trace Metal contamination on Semiconductor
More informationTrace elemental analysis of distilled alcoholic beverages using the Agilent 7700x ICP-MS with octopole collision/ reaction cell
Trace elemental analysis of distilled alcoholic beverages using the Agilent 77x ICP-MS with octopole collision/ reaction cell Application note Food testing Author Glenn Woods Agilent Technologies Cheadle
More informationBurning Through the Confusion: See How Combustion IC Provides Superior Halide Analysis
Burning Through the Confusion: See How Combustion IC Provides Superior Halide Analysis Jay Sheffer Metrohm USA Wednesday, October 17, 2018 Gulf Coast Conference Abstract # 187 Organic Halides in Crude
More informationThermo Scientific ELEMENT GD PLUS Glow Discharge Mass Spectrometer. Defining quality standards for the analysis of solid samples
Thermo Scientific ELEMENT GD PLUS Glow Discharge Mass Spectrometer Defining quality standards for the analysis of solid samples Redefine your quality standards for the elemental analysis of solid samples
More informationOxygen Demand, Chemical
Oxygen Demand, Chemical DOC316.53.01104 USEPA Reactor Digestion Method Method 10212 250 to 15,000 mg/l COD (UHR) TNTplus 823 Scope and application: For wastewater and process waters; digestion is required.
More informationQuantitative XRF Analysis. algorithms and their practical use
Joint ICTP-IAEA School on Novel Experimental Methodologies for Synchrotron Radiation Applications in Nano-science and Environmental Monitoring Quantitative XRF Analysis algorithms and their practical use
More informationWorldwide Open Proficiency Test for X Ray Fluorescence Laboratories PTXRFIAEA13. Determination of Major, Minor and Trace Elements in a Clay Sample
Worldwide Open Proficiency Test for X Ray Fluorescence Laboratories PTXRFIAEA13 Determination of Major, Minor and Trace Elements in a Clay Sample IAEA Laboratories, Seibersdorf November 2017 CONTENTS
More informationPAR Method Method to 2.0 mg/l Pb TNTplus 850
Lead DOC316.53.01056 PAR Method Method 10216 0.1 to 2.0 mg/l Pb TNTplus 850 Scope and application: For wastewater and process control. Test preparation Instrument-specific information Table 1 shows all
More informationBENEFITS OF IMPROVED RESOLUTION FOR EDXRF
135 Abstract BENEFITS OF IMPROVED RESOLUTION FOR EDXRF R. Redus 1, T. Pantazis 1, J. Pantazis 1, A. Huber 1, B. Cross 2 1 Amptek, Inc., 14 DeAngelo Dr, Bedford MA 01730, 781-275-2242, www.amptek.com 2
More informationS2 PUMA Spectrometry Solutions. Innovation with Integrity EDXRF
S2 PUMA Spectrometry Solutions Innovation with Integrity EDXRF The Puma is an incredibly adaptable and powerful animal. The S2 PUMA is an incredibly adaptable and powerful spectrometer. 2 S2 PUMA Analyze.
More informationAlphasense Ltd. Compliance Statements and Certificates. Contents. The Restriction of the Use of Certain Hazardous Substances (RoHS)...
Alphasense Ltd Compliance Statements and Certificates Contents The Restriction of the Use of Certain Hazardous Substances (RoHS)... 2 Waste Electrical and Electronic Equipment (WEEE)... 3 Registration,
More informationof mass spectrometry
Thermo Scientific 253 Ultra High resolution isotope ratio MS Discover a new world of mass spectrometry Paleoclimatology Atmospheric science Biogeochemistry Petrology Discover the isotopic anatomy of molecules
More informationMT Electron microscopy Scanning electron microscopy and electron probe microanalysis
MT-0.6026 Electron microscopy Scanning electron microscopy and electron probe microanalysis Eero Haimi Research Manager Outline 1. Introduction Basics of scanning electron microscopy (SEM) and electron
More informationTEST REPORT. NO.: A001R Date: Dec 27, 2013 Page 1 of 13
NO.: A001R131220047001 Date: Dec 27, 2013 Page 1 of 13 Applicant: Jinyun Lanxin Electronic Technology Co., Ltd. Address: NO.2XINMIN ROAD,DONGSHAN INDUSTRIAL AREA WUYUN TOWN JINYUN CONUNTY,LISHUI CITY,ZHEJIANG,CHINA
More informationS2 PICOFOX. Innovation with Integrity. Benchtop TXRF Spectrometer TXRF
S2 PICOFOX Benchtop TXRF Spectrometer Innovation with Integrity TXRF S2 PICOFOX - Fast Trace Element Analysis with XRF The S2 PICOFOX is the world s first portable benchtop spectrometer for fast quantitative
More informationDetermination of Chromium in Gelatin Capsules using an Agilent 7700x ICP-MS
Determination of Chromium in Gelatin Capsules using an Agilent 7700x ICP-MS Application note Pharmaceutical Authors Miao Jing, Yingping Ni, Yanping Wang and Zhixu Zhang Agilent Technologies, China Introduction
More informationAccurate and Precise Sulfur Analysis using the Thermo Scientific FlashSmart Elemental Analyzer
APPLICATION NOTE Accurate and Precise Sulfur Analysis using the Thermo Scientific FlashSmart Elemental Analyzer AN42266 Dr. Liliana Krotz, Dr. Francesco Leone and Dr. Guido Giazzi Thermo Fisher Scientific,
More information