NIH Postdoctoral Scholar Adviser: Professor Barry M. Trost. The University of Michigan, Ann Arbor, MI

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1 Kami L. Hull Current Position Assistant Professor Department of Chemistry University of Illinois at Urbana Champaign Office: (217) S. Mathews Champaign, IL Education Stanford University, Stanford, CA NIH Postdoctoral Scholar Adviser: Professor Barry M. Trost The University of Michigan, Ann Arbor, MI Ph.D., Chemistry, February 2009 Advisor: Professor Melanie S. Sanford Macalester College, St. Paul, MN B.A., Chemistry, cum laude, May 2003 Advisor: Professor Ronald G. Brisbois Research Experience Stanford University, Stanford, CA Research Adviser: Professor Barry M. Trost University of Michigan, Ann Arbor, MI Research Advisor: Professor Melanie S. Sanford Macalester College, St. Paul, MN Research Advisor: Professor Ronald G. Brisbois Montana State University, Bozeman, MT summer 2001 Research Advisor: Professor Paul Grieco Awards Amgen Young Investigator Award 2017 Beckman Fellow (Center for Advanced Studies) Thieme Chemistry Awardee 2017 Sloan Research Fellowship 2016 NSF CAREER Award 2016 Chemical & Engineering News Talented Kasimir Fajans Award in Chemistry 2011 NIH Postdoctoral Fellowship Roche Excellence in Chemistry Award 2008 Writ and Mary Cornwell Outstanding Graduate Student Research Award 2007 ACS Division of Organic Chemistry Fellowship, Eli Lilly 2006 Novartis Graduate Fellowship 2005 Chemical Sciences at the Interface of Education NSF-GAANN Fellowship 2004 Wallace Undergraduate Summer Research Fellowship, Macalester College of 7

2 Funding Amgen Young Investigator Award $25,000 NIH MIRA Award $1,731,901 Sloan Research Fellowship $55,000 NSF CAREER Award $675,000 Petroleum Research Fund Young Investigator Award $100,000 Publications [17.] Vanable, E. P.; Kennemur, J. L.; Shultz, D. M.; Joice, L. A.; Ruck, R. T. Hull, K. L. Asymmetric Hydroamination of Allyl Amines, anticipated submission Oct [16.] Gockel, S. N.*; Buchanan, T. L.*; Hull, K. L. Copper-Catalyzed Intermolecular Carboamination of Alkenes, anticipated submission Sept [15.] Ensign, S. C.; Hull, K. L. Regiodivergent Hydroamination of Homoallylic Amines, anticipated submission Sept [14.] Kohler, D. G; Gockel, S. N.; Kennemur, J. L.; Waller, P. J.; Hull, K. L. Anti-Markovnikov Selective Pd-Catalyzed Redox-Relay Oxidative Amination, Nature Chemistry, 2017, accepted. [13.] Kortman, G. K.; Hull, K. L. Copper-Catalyzed Alkyne Hydroarylation: Highly Regio- and Distereoselective Synthesis of Trisubstituted Olefins, ACS Catalysis 2017, 7, [12.] Buchanan, T. L.; Hull, K. L. Illuminating Amination, Science 2017, 355, [11.] Wu, Zhao; Laffoon, S. D.; Nguyen, T. T.; McAlpin, J. D.; Hull, K. L. Rhodium- Catalyzed Enantioselective Isomerization/Oxidation of Allylic Amines for the Synthesis of β-chiral Amides, Angew. Chem. Int. Ed., 2017, 56, [10.] Nguyen, T. T.; Hull, K. L. Rhodium-Catalyzed Oxidative Amidation of Sterically Hindered Aldehydes and Alcohols, ACS Catal. 2016, 7, [9.] Kennemur, J. L.; Kortman, G. D.; Hull, K. L. Rhodium-Catalyzed Regiodivergent Hydrothiolation of Allyl Amines, J. Am. Chem. Soc. 2016, 138, [8.] Nguyen, T. T.; Kortman, G. D; Hull, K. L. Synthesis, Cycloaddition and Cycloreversion Reactions of Mononuclear Titanocene oxo Complexes, Organometallics, 2016, 35, [7.] Wu, Z.; Hull, K. L. Rhodium-Catalyzed Oxidative Amidation of Allylic Alcohols and Aldehydes: Effective Conversion of Amines and Anilines into Amides, Chem. Sci. 2016, 7, [6.] Ensign, S. C.; Vanable, E. P.; Kortman, G. D.; Weir, L. J.; Hull, K. L. Anti-Markovnikov Hydroamination of Homoallylic Amines, J. Am. Chem. Soc. 2015, 137, [5.] Nguyen, T. T.; Bertke, J. A.; Gray, D. L.; Hull, K. L. Facile C H, C F, C Cl, and C C Activation by Oxatitanacyclobutene Complexes, Organometallics 2015, 34, [4.] Gockel, S. N.; Hull, K. L. Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations, Org. Lett. 2015, 17, [3.] Gupta, A. K.; Hull, K. L. Synthesis of 1,2-Diamines via Hydroamination Reactions, Synlett 2015, 26, of 7

3 [2.] Kortman, G. D.; Orr, M. J.; Hull, K. L. Synthesis and Reactivity of Dioxazirconacyclohexenes: Development of a Zirconium Oxo-Mediated Alkyne Aldehyde Coupling Reaction, Organometallics 2015, 34, [1.] Ickes, A. R.; Ensign, S. C.; Gupta, A. K.; Hull, K. L. Regio- and Chemoselective Intermolecular Hydroamination of Allyl Imines for the Synthesis of 1,2-Diamines, J. Am. Chem. Soc. 2014, 136, Prior Publications [10.] Trost, B. M.; Stilvala, C. E.; Fandrick, D. R.; Hull, K. L.; Huang, A.; Poock, C.; Kalkofen, R. Total Synthesis of ( )-Lasonolide A, J. Am. Chem. Soc. 2016, 138, [9.] Trost, B. M.; Stilvala, C. E.; Hull, K. L.; Huang, A.l Fandrick, D. R. A Concise Synthesis of ( )-Lasonolide A, J. Am. Chem. Soc. 2014, 136, [8.] Lyons, T. W.; Hull, K. L.; Sanford, M. S. Controlling Site Selectivity in Pd- Catalyzed Oxidative Cross-Coupling Reactions, J. Am. Chem. Soc. 2011, 133, [7.] Hull, K. L.; Sanford, M. S. Mechanism of Benzoquinone-Promoted Palladium- Catalyzed Oxidative Cross-Coupling Reactions, J. Am. Chem. Soc. 2009, 131, [6.] Hull, K. L.; Sanford, M. S. Catalytic and Highly Regioselective Cross-Coupling of Aromatic C H Substrates, J. Am. Chem. Soc. 2007, 129, [5.] Hull, K. L.; Lanni, E. L.; Sanford, M. S. Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations, J. Am. Chem. Soc. 2006, 128, [4.] Hull, K. L.; Anani, W. Q.; Sanford, M. S. Palladium-Catalyzed Flourination of Carbon Hydrogen Bonds, J. Am. Chem. Soc. 2006, 128, [3.] Desai, L. V.; Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxygenation of Unactivated sp 3 C H Bonds, J. Am. Chem. Soc. 2004, 126, [2.] Dick, A. R.; Hull, K. L.; Sanford, M. S. A Highly Selective Catalytic Method for the Oxidative Funtionalization of C H Bonds, J. Am. Chem. Soc. 2004, 126, [1.] Mio, M. J.; Kopel, L. C.; Braun, J. B.; Gadzikwa, T. L.; Hull, K. L.; Brisbois, R. G.; Markworth, C. J.; Grieco, P. A. One-Pot Synthesis of Symmetrical and Unsymmetrical Bisarylethynes by a Modification of the Sonogashira Coupling Reaction, Org. Lett. 2002, 4, Invited Presentations [43.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Scripps Research Institute, La Jolla, CA April [42.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of California, Irvine, Irvine, CA April [41.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Chicago, Chicago, IL March [40.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Toronto, Toronto, Canada March [39.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Wisconsin, Madison, Madison, WI February of 7

4 [38.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of California, Berkeley, Berkeley, CA February [37.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Princeton University, Princeton, NJ February [36.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Columbia University, New York, NY February [35.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Georgia, Athens, GA January [34.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Illinois, Chicago, Chicago, IL November [33.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Illinois State University, Normal, IL November [32.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Missour, Columbia, MO October [31.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Boston College, Boston, MA October [30.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Massachusetts Institute of Technology, Boston, MA October [29.] Hull, K. L. Transition Metal-Catalyzed Amination Reactions, Caltech, Pasadena, CA October [28.] Hull, K. L. Transition Metal-Catalyzed Amination Reactions, National ACS Meeting, Washington, DC August [27.] Hull, K. L. Transition Metal-Catalyzed Amination Reactions, Natural Products, Gordon Research Conference, Andover, NH July [26.] Hull, K. L. Transition Metal-Catalyzed Amination Reactions, Heterocyclic Compounds, Gordon Research Conference, Newport, RI June [25.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Pfizer, Groton, CT June [24.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Texas, Austin, Austin, TX June [23.] Hull, K. L. Transition Metal-Catalyzed Amination Reactions, Meyers Symposium, Southern Illinois University - Carbondale, Carbondale, IL Apr [22.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Brigham Young University Provo, UT Apr [21.] Hull, K. L. Transition Metal-Catalyzed Amination, University of Minnesota Morris Morris, MN Apr [20.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Sigma Aldrich Lecture, University of Minnesota Minneapolis, MN Apr [19.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Indiana Bloomington, IN Mar [18.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Iowa State University Ames, IA Nov of 7

5 [17.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, University of Iowa Iowa City, IA Nov [16.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Duke University Durham, NC Oct [15.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, North Carolina State University Raleigh, NC Oct [14.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Chicago Organic Symposium Chicago, IL Oct [13.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Organometallics Distinguished Lectureship Symposium, ACS National Meeting Philadelphia, PA Aug [12.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, Organic Reactions and Processes Gordon Research Conference Easton, MA July [11.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, TrostCon 75, a symposium in honor of Prof. Barry M. Trost s 75 th Birthday, Stanford, CA, May [10.] Hull, K. L. Transition Metal-Catalyzed Amination and Amidation Reactions, ISACS19: Challenges in Organic Chemistry, Irvine, CA, March [9.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Andrews University, Barrien Springs, MI, Feb [8.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Abbvie, North Chicago, IL, November [7.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, 250 th National ACS Meeting, Boston, MA, August [6.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Merck, Raway, NJ, May [5.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Frontiers Symposium, University of Illinois, Urbana-Champaign, IL, Oct (Invited Lecture) [4.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, St. Olaf College, Northfield, MN, Oct [3.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Kalamazoo College, Kalamazoo, MI, Oct [2.] Hull, K. L. Selective Pd-Catalyzed Oxidative Cross Coupling Reactions and The Total Synthesis of ( )-Lasonolide A, University of Michigan, Ann Arbor, MI, Nov (Invited Lecture) [1.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Cross-Coupling Reactions, Roche Excellence in Chemistry Symposium, Palo Alto, CA, May (Invited Lecture) 5 of 7

6 Other Presentations [19.] Hull, K. L. Alternative Approaches to Traditional Bond Disconnections, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June (Poster [18.] Hull, K. L. Regio- and Chemoselective Hydroamination Reactions, Organic Reactions and Processes Gordon Research Conference, Bryant, RI, July (Poster [17.] Hull, K. L. Regio- and Chemoselective Hydroamination Reactions, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June (Poster [16.] Hull, K. L. Regioselective Hydro- and Oxidative Amination Reactions, Organic Reactions and Processes Gordon Research Conference, Bryant, RI, July (Poster [15.] Hull, K. L. Regioselective Hydro- and Oxidative Amination Reactions, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June (Poster [14.] Trost, B. M.; Hull, K. L. Development of a Pd-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Lactams, Heterocyclic Compounds Gordon Research Conference, Newport, RI, June (Poster [13.] Trost, B. M; Hull, K. L.; Huang, A.; Kalkofen, R.; Fandrick, D. Progress Towards the Total Synthesis of ( )-Lasonolide A, 239 th ACS National Meeting, San Francisco, CA, March (Poster [12.] Hull, K. L.; Sanford, M. S. Determining the Mechanism of Palladium-Catalyzed Oxidative Coupling Reactions, 239 th ACS National Meeting, San Francisco, CA, March (Oral [11.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Cross-Coupling Reactions, 236 th ACS National Meeting, Philadelphia, PA, August (Oral [10.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Cross-Coupling Reactions, DOE Catalysis Meeting, Annapolis, MD, May (Poster [9.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Coupling Reactions, Heterocycles Gordon Research Conference, Newport, RI, June (Poster [8.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Coupling Reactions, National Organic Symposium, Durham, NC, June (Poster [7.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Oxidative Functionalization of C H Bonds, Macalester College, February 7, (Invited Lecture) [6.] Hull, K. L.; Lanni, E. L.; Anani, W. Q.; Sanford, M. S. Directed Palladium- Catalyzed Fluorination and Oxidative Coupling International Conference on Organometallic Chemistry, Zaragoza, Spain, July, (Poster presentation) [5.] Hull, K. L.; Sanford, M. S. Palladium-Catalyzed Fluorination of C H Bonds, Perspectives on Chemistry Research at the University of Michigan, Ann Arbor, MI, June, (Invited lecture) 6 of 7

7 [4.] Hull, K. L.; Anani, W. Q.; Sanford, M. S. Selective Oxidative Functionalization of C H Bonds, Novartis Science Day, Cambridge, MA, October, (Poster presentation) [3.] Hull, K. L.; Anani, W. Q.; Desai, L. V.; Sanford, M. S. Pyridine Directing Groups for Selective sp 3 C H Activation and Oxidation, National Organic Symposium, Salt Lake City, UT, June, (Poster presentation) [2.] Hull, K. L.; Brisbois, R. G. Design and Synthesis of Building Blocks for Pd- and Pt-Mediated Supramolecular Self-Assembly Pew Undergraduate Research Symposium, St. Louis, MO, November, (Oral presentation) [1.] Hull, K. L.; Markworth, C. J.; Grieco, P. A. Synthesis of Self-Assembled Half Barrel, Pew Undergraduate Research Symposium, Chicago, IL, November, (Poster presentation) 7 of 7