NSF Supported Research ( )
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1 MELIKYAN GROUP NSF Supported Research ( ) Research Papers (from a total of 77) 1. Melikyan, G. G.; Floruti, A.; Devletyan, L.; Toure, P.; Dean, N.; Carlson, L. Cross-Coupling of Cobalt-Complexed Propargyl Radicals: Metal Core and a- and g-aryl-induced Chemo- and Diastereoselectivity, Organometallics 2007, 26, Melikyan, G. G.; Wild, C.; Toure, P. Intramolecular Radical Cyclizations of Co2(CO)6-Complexed Propargyl Radicals: Synthesis of d,land meso-1,5-cyclodecadiynes, Organometallics 2008, 27, Melikyan, G. G.; Mikailian, B.; Sepanian, R.; Toure, P. High- Temperature Reaction of a Co2(CO)6-Complexed Propargyl Cation, J. Organomet. Chem. 2009, 694, Melikyan, G. G.; Sepanian, R.; Spencer, R.; Rowe, A.; Toure, P. Cobalt- Complexed Propargyl Cations: Generation under Neutral Conditions and Spontaneous, High Temperature Conversion to Propargyl Radicals, Organometallics 2009, 28, Melikyan, G. G.; Spencer, R.; Abedi, E. Stereoselective Synthesis of meso-1,5-cyclodecadiynes. J. Org. Chem. 2009, 74, Melikyan, G. G.; Voorhees, E.; Wild, C.; Spencer, R.; Molnar, J. Carbon Tether Rigidity as a Stereochemical Tool Directing Intramolecular Radical Cyclizations. Tetrahedron Letters 2010, 51, Melikyan, G. G.; Spencer, R. Inter- and Intramolecular Isocarbon Couplings of Cobalt-Complexed Propargyl Radicals: Challenging the Consensus. Tetrahedron 2010, 66, Melikyan, G. G.; Spencer, R.; Rowe, A. 1,3-Steric Induction in Intermolecular Radical Reactions Mediated by a Co2(CO)6-Metal Core. Organometallics 2010, 29, Presentations by the PI (from a total of 80: conferences 54; academic institutions 13; public appearances - 13)
2 2 1. Invited talk: Gagik G. Melikyan. New Radical Reactions in Cobalt- Alkyne Series. International Organometallics Conference 2008, ZING Conferences, Cancun, Mexico, Invited presentation: Gagik G. Melikyan. Transition Metal-Mediated Radical Reactions and Development of Novel Therapeutic Means for Breast Cancer Treatment. General Assembly of the National of Academy of Sciences, Yerevan, Armenia, Invited presentation: Gagik G. Melikyan. Inter- and Intramolecular, Homo- and Cross-Coupling Radical Reactions Stereodirected by a Transition Metal Cluster. 2009, California State University Long Beach, Long Beach, CA. 4. Gagik G. Melikyan, Ruth Sepanian, Louis Carlson, Pogban Toure. Unorthodox Methods for Generation of Transition Metal-Enhanced Propargyl Radicals: Scope, Substrate Base, Function Tolerance, Synthetic Potential, and Diastereoselectivity of C-C Bond Formation. 238 th ACS National Meeting, Washington, D.C., Gagik G. Melikyan, Ryan Spencer, Erin Voorhees, Pogban Toure. Intramolecular Radical Reactions Enabled by Transition Metals. 238 th ACS National Meeting, Washington, D.C., Gagik G. Melikyan, Stepan Harutyunyan, Bianca Rivas, Ruth Sepanian, Louis Carlson, Erin Voorhees. Generation of Cobalt-Complexed Propargyl Cations Under Neutral Conditions: Radical C-C Bond Formation in the Presence of Acid-Sensitive Functionalities. 241 th ACS National Meeting, Anaheim, CA, 2011, # th International Symposium on the Intraductal Approach to Breast Cancer, Santa Monica, CA; Feb Invited Speaker Series, Phi Delta Epsilon Honor Society, Guilty Until Proven Innocent: Antioxidants, Foods, Supplements, and Cosmetics, California State University Northridge, Northridge, CA, Feb Speaker, Provost Colloquium, Jeromy Richfield Scholar Award presentation, Controlling Radicals: from Reaction Flask to Food and Body Preservation, California State University Northridge, Northridge, CA, March Chairing sessions at conferences
3 New Reactions and Methodology, 241 st ACS National Meeting, Anaheim, CA. PI s Awards/Honors Outstanding Faculty Award, California State University Northridge (CSUN), Northridge, CA, Elected a Foreign Member of the National Academy of Sciences, Armenia Jerome Richfield Research Scholar Award, California State University Northridge, Northridge, CA. Student Presentations (from a total of 84) 1. Christopher Wild. Exploiting a Phenomenon of CH/p Coordination: Interpretation of the Diastereoselectivity of Cobalt-Mediated Intramolecular Radical Cyclizations, 12th CSUN Student Research Symposium, Northridge, CA, Boghos Mikailian. Novel High-Temperature and Spontaneous Radical Coupling Reaction: Kinetic Studies, 12th CSUN Student Research Symposium, Northridge, CA, Gagik G. Melikyan, Boghos Mikailian, Ruth Sepanian. The Effect of Counter-Ion, Temperature, and Substitution upon the Spontaneous, Cobalt- Cluster Mediated Dimerization Reaction, 42 nd Western Regional ACS Meeting, Las Vegas, Gagik G. Melikyan, Louis Carlson, Ryan Spencer. Impact of Aromatic Substitution and Reducing Agent on Diastereoselectivity of Intra- and Intermolecular Cobalt-Mediated Radical Reactions, 42 nd Western Regional ACS Meeting, Las Vegas, Christopher Wild. Unexpected Trends in Metal Cluster-Directed, Intramolecular Radical Cyclizations, 235 th ACS National Meeting, New Orleans, Boghos Mikailian. A High-Temperature, Spontaneous, and Cobalt Cluster-Mediated Radical Coupling Reaction, 235 th ACS National Meeting, New Orleans, 2008.
4 4 7. Boghos Mikailian. Cobalt-Mediated High-Temperature Radical Coupling Reactions, 10th Annual Sigma Xi Scientific Research Society CSUN Chapter Student Symposium, Northridge, CA, Louis Carlson. Toward Non-toxic Therapeutics for a Breast Cancer Treatment: Cobalt-Mediated Stereoselective Synthesis of Substituted d,l- 3,4-Diphenyl-1,5-hexadiynes, 10th Annual Sigma Xi Scientific Research Society CSUN Chapter Student Symposium, Northridge, CA, Christopher Wild. A Novel Approach Toward the Synthesis of Enediynes: Metal-Directed Formation of Medium-Sized Cyclic Diacetylenes, CSU-wide Student Research Competition, CSU Hayward, CA, Louis Carlson. Cobalt-Mediated Synthesis of d,l-3,4-diphenyl-1,5- hexadiynes Containing Acid-Labile Aromatic Substituents, Association of Retired Faculty Luncheon, Northridge, CA, Ryan Spencer. Radical Carbon-Carbon Bond Formation Stereodirected by an alpha-metal Core, 13th CSUN Student Research Symposium, Northridge, CA, Ruth Sepanian. Overcoming a Longstanding Challenge: Synthesis of Cobalt-Complexed Propargyl Cations under Neutral Conditions, 11th Annual Sigma Xi Scientific Research Society CSUN Chapter Student Symposium, Northridge, CA, Ryan Spencer. Controlling Stereoselectivity of Cobalt-Mediated Inter- and Intramolecular Coupling Reactions, 11th Annual Sigma Xi Scientific Research Society CSUN Chapter Student Symposium, Northridge, CA, Ruth Sepanian. Generation of Cobalt-Complexed Propargyl Cations under Neutral Conditions, 2009 Southern California Undergraduate Research Conference (SCURC) in Chemistry and Biochemistry, USC, CA, Sarine Shahmirian. Propargyl Methyl Ethers: Novel Precursors to Cobalt-Complexed Propargyl Cations. Southern California Junior Academy of Sciences (SCJAS), Claremont, CA, Ryan Spencer. Radical Carbon-Carbon Bond Formation Stereodirected by an Alpha Metal Core. Salva Regina University, Newport, RI, 2009.
5 5 17. Sarine Shahmirian. Propargyl Methyl Ethers: Novel Precursors to Cobalt-Complexed Propargyl Cations. AAAS Pacific Division Annual Meeting, San Francisco, CA, Ryan Spencer. First Stereoselective Synthesis of meso-1,5- Cyclodecadiyne. 14th CSUN Student Research Symposium, Northridge, CA, Ruth Sepanian. Novel Methods for the Synthesis of Breast Cancer Aromatase Inhibitors. 14th CSUN Student Research Symposium, Northridge, CA, Erin Voorhees. The Use of a Rigid Carbon Tether as a Stereochemical Tool in Intramolecular Radical Cyclizations. 14th CSUN Student Research Symposium, Northridge, CA, Ryan Spencer. Novel Methods for Controlling Stereoselectivity of Radical C-C Bond Forming Reactions. Graduate Fellows with Outstanding Research Promise in Science and Mathematics Symposium, College of Science & Math, CSUN, Northridge, CA, Erin Voorhees. The Use of a Rigid Carbon Tether as a Stereochemical Tool in Intramolecular Radical Cyclizations. CSU-wide Student Research Symposium, San Jose, CA, Ruth Sepanian. Generation of Cobalt-Complexed Propargyl Cation Under Neutral Conditions and Their Biological Relevance. Thesis defense, Department of Biology, CSUN, Northridge, CA, Harutyunyan, S.; Rivas, B. Naphthalene-Stabilized Propargyl Cations and Radicals in Carbon-Carbon Bond Forming Reactions. 15th CSUN Student Research Symposium, Northridge, CA, Melikyan, G. G.; Harutyunyan, S.; Rivas, B. Generation of Cobalt- Complexed Propargyl Cations Under Neutral Conditions: Expansion of the Substrate Base. 241 th ACS National Meeting, Anaheim, Rivas, B.; Harutyunyan, S. Diastereoselectivety of Radical Carbon- Carbon Bond Formation in Napthalene-Stabilized Propargyl Cations. Southern California Undergraduate Research Conference, Santa Barbara, CA, Student Awards (from a total of 37)
6 6 1. Christopher Wild. 12th CSUN Student Research Symposium, First Place Award, Office of Research & Sponsored Projects, CSUN, Northridge, CA. 2. Louis Carlson Memorial Award, Association of Retired Faculty, CSUN, Northridge, CA, Christopher Wild. CSU-wide Student Research Competition, CSU East Bay, Hayward, CA, 2008 Second Place Award. 4. Ryan Spencer. Sandra L. Jewett Scholarship in Biochemistry, CSUN, Northridge, CA, Ryan Spencer. Outstanding Graduate Student Teaching Assistant Award, CSUN, Northridge, CA, Ruth Sepanian. Sigma Xi CSUN Chapter Student Symposium, Northridge, CA, 2009 Third Place Award, CSUN, Northridge, CA, Ryan Spencer, College of Science&Math Graduate Fellow for Outstanding Research Promise in Science and Mathematics, CSUN, Northridge, CA, & 9. Sarine Shahmirian. AAAS Pacific Division Annual Meeting, San Francisco, CA, 2009 First Place Award and Award of Excellence. 10. Ruth Sepanian. 14th CSUN Student Research Symposium, Northridge, CA, 2010 Second Place Award. 11. Erin Voorhees. 14th CSUN Student Research Symposium, Northridge, CA, 2010 First Place Award. 12. Ryan Spencer. The 2010 Nathan O. Freedman Memorial Award for Outstanding Graduate Student, CSUN, Northridge, CA, McKinzie Garrison, 2011 Outstanding Freshman Chemistry Award, CSUN, Northridge, CA, Marina Dykhne, 2011 Analytical Chemistry Award, CSUN, Northridge, CA, M.S. Theses
7 7 1. Arthur Floruti. Cross-Coupling of Cobalt-Complexed Propargyl Radicals: Chemo-, Regio-, and Diastereoselective Access to 3,4-Diaryl-1,5- hexadiynes, Department of Chemistry and Biochemistry, CSUN, Northridge, CA, Christopher Wild. Cobalt-Assisted Intramolecular Radical Cyclization Reactions, Department of Chemistry and Biochemistry, CSUN, Northridge, CA, Ryan Spencer. Inter- and Intramolecular Radical C-C Bond Formation Mediated by a Transition Metal Core. Department of Chemistry and Biochemistry, CSUN, Northridge, CA, Ruth Sepanian. Radical Coupling Reactions Under Neutral Conditions and Their Biological Relevance. Department of Chemistry and Biochemistry & Department of Biology, CSUN, Northridge, CA, 2010.
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