A) B) C) D) , Ne, NaCl C) MgO, NaCl, O 2

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1 Name: Page 1 1) In the wave-mechanical model of the atom, orbitals are regions of the most probable locations of A) protons B) positrons C) neutrons D) electrons 2) Which of the following phrases describes an atom? A) a positively charged electron cloud surrounding a negatively charged nucleus B) a negatively charged electron cloud surrounding a positively charged nucleus C) a negatively charged electron cloud surrounding a negatively charged nucleus D) a positively charged electron cloud surrounding a positively charged nucleus 3) Which of the following total masses is the smallest? A) mass of 2 electrons B) mass of 2 neutrons 4) Elements on the modern Periodic Table are arranged in order of increasing A) number of neutrons B) number of valence electrons C) mass of 1 neutron plus the mass of 1 electron D) mass of 1 electron plus the mass of 1 proton C) atomic mass D) atomic number 5) As the elements of Group 17 are considered in order of increasing atomic number, there is an increase in A) atomic radius B) number of electrons in the first shell 6) Chlorine-37 can be represented as C) electronegativity D) first ionization energy A) B) C) D) 7) Which element is a metal that is in the liquid phase at STP? A) bromine B) hydrogen C) mercury D) cobalt 8) Which list of formulas represents compounds, only? A) H 2, N 2, O 2 B) H 2, Ne, NaCl C) MgO, NaCl, O 2 D) CO 2, H 2 O, NH 3 9) What is the chemical formula for iron(iii) oxide? A) Fe 3 O B) Fe 2 O 3 C) Fe 3 O 2 D) FeO 10) An atom of which element has the greatest attraction for the electrons in a bond with a hydrogen atom? A) chlorine B) sulfur C) phosphorus D) silicon 11) Which property could be used to identify a compound in the laboratory? A) temperature B) volume C) melting point D) mass 12) Which statement describes what occurs as two atoms of bromine combine to become a molecule of bromine? A) Energy is released as a bond is formed. B) Energy is absorbed as a bond is broken. 13) Given a formula for oxygen: C) Energy is released as a bond is broken. D) Energy is absorbed as a bond is formed. What is the total number of electrons shared between the atoms represented in this formula? A) 1 B) 2 C) 8 D) 4 14) Solid ZnCl 2 and liquid ZnCl 2 have different A) formula masses B) empirical formulas C) physical properties D) ion ratios 15) Which of the following phrases describes the molarity of a solution? A) moles of solute per liter of solution B) moles of solution per liter of solution 16) Which substance can not be decomposed by a chemical change? C) liters of solute per mole of solution D) liters of solution per mole of solution A) AlCl 3 B) Cu C) H 2 O D) HI

2 17) Tetrachloromethane, CCl 4, is classified as a Page 2 A) mixture because the atoms of the elements are combined in a fixed proportion B) compound because the atoms of the elements are combined in a proportion that varies C) compound because the atoms of the elements are combined in a fixed proportion D) mixture because the atoms of the elements are combined in a proportion that varies 18) Which of the following formulas represent two polar molecules? A) CO 2 and HCl B) H 2 O and CH 4 C) CO 2 and CH 4 D) H 2 O and HCl 19) Hydrocarbons are compounds that contain A) carbon, hydrogen, and oxygen, only B) carbon, only C) carbon, hydrogen, oxygen, and nitrogen, only D) carbon and hydrogen, only 20) The reaction that joins thousands of small, identical molecules to form one very long molecule is called A) polymerization B) fermentation C) substitution D) esterification 21) What is the IUPAC name of the organic compound that has the formula shown below? A) 4-methylpentane B) 1,1-dimethylbutane C) 2-methylpentane D) hexane 22) A voltaic cell spontaneously converts chemical energy to A) geothermal energy B) nuclear energy C) mechanical energy D) electrical energy 23) Given the balanced equation representing a reaction: Mg(s) + Ni 2+ (aq) Mg 2+ (aq) + Ni(s) What is the total number of moles of electrons lost by Mg(s) when 2.0 moles of electrons are gained by Ni 2+ (aq)? A) 1.0 mol B) 2.0 mol C) 3.0 mol D) 4.0 mol 24) Which half-reaction correctly represents reduction? A) Mn 4+ + e - Mn 3+ B) Mn e - Mn 7+ 25) Which indicator is blue in a solution that has a ph of 5.6? C) Mn 4+ Mn e - D) Mn 4+ Mn 3+ + e - A) methyl orange B) bromcresol green C) thymol blue D) bromthymol blue 26) The Arrhenius theory explains the behavior of A) isomers and isotopes B) metals and nonmetals C) acids and bases D) alcohols and amines 27) In which laboratory process could a student use 0.10 M NaOH(aq) to determine the concentration of an aqueous solution of HBr? A) decomposition of the solute B) titration C) chromatography D) evaporation of the solvent 28) A nuclear reaction in which two light nuclei combine to form a more massive nucleus is called A) fusion B) addition C) substitution D) fission 29) The nucleus of a radium-226 atom is unstable, which causes the nucleus to spontaneously A) absorb electrons B) absorb protons C) decay D) oxidize

3 30) A serious risk factor associated with the operation of a nuclear power plant is the production of A) helium gas B) radioisotopes with long half-lives C) acid rain D) greenhouse gases, such as CO Page 3 31) What is the total number of protons in an atom with the electron configuration ? A) 197 B) 69 C) 79 D) ) Which two elements have the most similar chemical properties? A) Cl and Ar B) Ca and Br C) Na and P D) Be and Mg 33) In the ground state, each atom of an element has two valence electrons. This element has a lower first ionization energy than calcium. Where is this element located on the Periodic Table? A) Group 2, Period 3 B) Group 3, Period 4 C) Group 2, Period 5 D) Group 1, Period 4 34) Which equation shows conservation of mass and charge? A) Cu + 2Ag + Cu Ag C) NH 4 Br NH 3 + Br 2 B) 2Mg + Fe 3+ Mg Fe D) H 2 SO 4 + LiOH Li 2 SO 4 + H 2 O 35) What is the percent composition by mass of hydrogen in NH 4 HCO 3 (gram-formula mass = 79 grams/mole)? A) 50.% B) 6.3% C) 10.% D) 5.1% 36) What is the total number of valence electrons in a sulfide ion in the ground state? A) 2 B) 18 C) 16 D) 8 37) A temperature of 37DC is equivalent to a temperature of A) 310. K B) 236 K C) 98.6 K D) 371 K 38) Which of the following balanced equations represents a chemical change? A) H 2 O(l) H 2 O(s) + energy B) H 2 O(g) H 2 O(l) + energy C) H 2 O(l) + energy H 2 O(g) D) 2H 2 O(l) + energy 2H 2 (g) + O 2 (g) 39) When 5 grams of KCl are dissolved in 50. grams of water at 25DC, the resulting mixture can be described as A) homogeneous and unsaturated B) homogeneous and supersaturated 40) Which aqueous solution of KI freezes at the lowest temperature? A) 2 mol of KI in 1,000. g of water B) 2 mol of KI in 500. g of water C) heterogeneous and supersaturated D) heterogeneous and unsaturated C) 1 mol of KI in 1,000. g of water D) 1 mol of KI in 500. g of water 41) Which of the following compounds is a member of the same homologous series as C 3 H 8? A) C 4 H 8 B) C 5 H 10 C) C 5 H 8 D) CH 4 42) Which equation represents an oxidation-reduction reaction? A) Zn(NO 3 ) 2 + Na 2 CO 3 2NaNO 3 + ZnCO 3 B) CH 4 + 2O 2 CO 2 + 2H 2 O C) MgCrO 4 + BaCl 2 MgCl 2 + BaCrO 4 D) H 2 SO 4 + Ca(OH) 2 CaSO 4 + 2H 2 O 43) Given the balanced equation representing a reaction: 2KClO 3 (s) 2KCl(s) + 3O 2 (g) The oxidation state of chlorine in this reaction changes from A) -1 to +5 B) +1 to -1 C) -1 to +1 D) +5 to -1

4 44) The potential energy diagram for a chemical reaction is shown below Page 4 If each interval on the axis labeled "Potential Energy (kj)" represents 40 kilojoules, what is the heat of reaction? A) -40 kj B) -120 kj C) +40 kj D) +160 kj 45) Given the balanced equation representing a reaction occurring in an electrolytic cell: 2NaCl(l) 2Na(l) + Cl 2 (g) Where is Na(l) produced in the cell? A) at the anode, where oxidation occurs B) at the cathode, where reduction occurs 46) Given the balanced equation representing a reaction: C) at the cathode, where oxidation occurs D) at the anode, where reduction occurs NH 3 (g) + H 2 O(l) NH 4 + (aq) + OH - (aq) According to one acid-base theory, the NH 3 (g) molecules act as A) a base because they donate H + ions C) an acid because they donate H + ions B) an acid because they accept H + ions D) a base because they accept H + ions 47) What volume of M HNO 3 (aq) is needed to completely neutralize milliliters of M NaOH(aq)? A) 125 ml B) 180. ml C) 360. ml D) 62.5 ml 48) Given the balanced equation representing a nuclear reaction: Which particle is represented by X? A) B) C) D) 49) An original sample of the radioisotope fluorine-21 had a mass of 80.0 milligrams. Only 20.0 milligrams of this original sample remain unchanged after 8.32 seconds. What is the half-life of fluorine-21? A) 1.04 s B) 4.16 s C) 8.32 s D) 2.08 s 50) Which of the following nuclides is paired with a specific use of that nuclide? A) cobalt-60, dating of rock formations B) uranium-238, dating of once-living organisms C) carbon-14, treatment of cancer D) iodine-131, treatment of thyroid disorders 51) Identify one ion from Solubility Guidelines for Aqueous Solutions chemistry reference table that can combine with Pb 2+ (aq) to produce an insoluble compound.

5 Page 5 52) Describe one appropriate laboratory test that can be used to determine the malleability of a solid sample of an element at room temperature. 53) State two methods to increase the rate of a chemical reaction and explain, in terms of particle behavior, how each method increases the reaction rate. Questions 54 through 57 refer to the following: 54) State, in terms of subatomic particles, how the atom of Cu-63 shown in the table differs from the atom of Cu ) What is the total number of electrons in an atom of Cu-65? 56) The atomic mass of Cu-63 in the table is expressed to what number of significant figures? 57) Show a correct numerical setup for calculating the atomic mass of the copper shown in the table. Questions 58 and 59 refer to the following: The boiling point of a liquid is the temperature at which the vapor pressure of the liquid is equal to the pressure on the surface of the liquid. The heat of vaporization of ethanol is 838 joules per gram. A sample of ethanol has a mass of 65.0 grams and is boiling at 1.00 atmosphere. 58) Based on the Vapor Pressure of Four Liquids chemistry reference table, what is the temperature of the sample of ethanol mentioned in the excerpt? 59) Calculate the minimum amount of heat required to completely vaporize the sample of ethanol mentioned in the excerpt. [Your response must include both a correct numerical setup and the calculated result.] Questions 60 through 62 refer to the following: The equation below represents the reaction between butanoic acid and an unidentified reactant, X. 60) Identify the type of organic reaction represented by the given equation.

6 61) Write the molecular formula of the organic product in the given equation Page 6 62) In the box below, draw a structural formula for the unidentified reactant, X, in the given equation. Questions 63 through 65 refer to the following: A piece of magnesium ribbon is reacted with excess hydrochloric acid to produce aqueous magnesium chloride and hydrogen gas. The volume of the dry hydrogen gas produced is 45.6 milliliters. The temperature of the gas is 293 K, and the pressure is 99.5 kilopascals. 63) Balance the equation below using the smallest whole-number coefficients. Mg(s) + HCl(aq) MgCl 2 (aq) + H 2 (g) 64) Identify the type of bond between the atoms in a molecule of the gas produced in the laboratory investigation described. 65) Calculate the volume that the dry hydrogen gas in the laboratory investigation described would occupy at STP. [Your response must include both a correct numerical setup and the calculated result.]

7 Questions 66 through 68 refer to the following: Page 7 In a laboratory, a glass tube is filled with hydrogen gas at a very low pressure. When a scientist applies a high voltage between metal electrodes in the tube, light is emitted. The scientist analyzes the light with a spectroscope and observes four distinct spectral lines. The table below gives the color, frequency, and energy for each of the four spectral lines. The unit for frequency is hertz, Hz. 66) (a) On the grid provided, plot the data from the data table for frequency and energy. (b) Circle and connect the points, including the point (0,0) that has already been plotted and circled for you. EXAMPLE: (c) A spectral line in the infrared region of the spectrum of hydrogen has a frequency of 2.3 x hertz. Using your graph, estimate the energy associated with this spectral line. 67) Explain, in terms of subatomic particles and energy states, why light is emitted by the hydrogen gas in the experiment shown. 68) Identify one condition, not mentioned in the given experiment, under which hydrogen gas behaves most like an ideal gas.

8 Questions 69 through 71 refer to the following: Page 8 Carbon and oxygen are examples of elements that exist in more than one form in the same phase. Graphite and diamond are two crystalline arrangements for carbon. The crystal structure of graphite is organized in layers. The bonds between carbon atoms within each layer of graphite are strong. The bonds between carbon atoms that connect different layers of graphite are weak because the shared electrons in these bonds are loosely held by the carbon atoms. The crystal structure of diamond is a strong network of atoms in which all the shared electrons are strongly held by the carbon atoms. Graphite is an electrical conductor, but diamond is not. At 25DC, graphite has a density of 2.2 g/cm 3 and diamond has a density of 3.51 g/cm 3. The element oxygen can exist as diatomic molecules, O 2, and as ozone, O 3. At standard pressure, the boiling point of ozone is 161 K. 69) Explain, in terms of electrons, why graphite mentioned in the reading passage is an electrical conductor and diamond is not. [Your response must include information about both graphite and diamond.] 70) Calculate the volume, in cm 3, of a diamond at 25DC that has a mass of gram. [Your response must include both a correct numerical setup and the calculated result.] 71) Explain, in terms of intermolecular forces, the difference in the boiling points of O 2 and O 3 at standard pressure. [Your response must include information about both O 2 and O 3.] Questions 72 through 75 refer to the following: A portable propane-fueled lantern contains a mesh silk bag coated with metal hydroxides. The primary metal hydroxide is yttrium hydroxide. When the silk bag is installed, it is ignited and burned away, leaving the metal hydroxide coating. The coating forms metal oxides that glow brightly when heated to a high temperature. During a test, a propane lantern is operated for three hours and consumes 5.0 moles of propane from the lantern's tank. The balanced equation below represents the combustion of propane. C 3 H 8 + 5O 2 3CO 2 + 4H 2 O + energy 72) At standard pressure, the boiling point of propane is 231 K. In the box below, draw a particle diagram to represent the phase of the propane in the situation described as it leaves the tank at 294 K. [Your response must include at least six molecules.] 73) Calculate the total mass of propane consumed during the lantern test described. [Your response must include both a correct numerical setup and the calculated result.] 74) Determine the total number of moles of CO 2 produced during the lantern test described.

9 75) Write the formula for the primary metal hydroxide used in the lantern in the situation described Page 9 Questions 76 through 79 refer to the following: When a person perspires (sweats), the body loses many sodium ions and potassium ions. The evaporation of sweat cools the skin. After a strenuous workout, people often quench their thirst with sports drinks that contain NaCl and KCl. A single 250.-gram serving of one sports drink contains gram of sodium ions. 76) Show a correct numerical setup for calculating the concentration of sodium ions in the sports drink described in the given excerpt, expressed as percent by mass. 77) Describe the transfer of energy between the skin and the surroundings as a person perspires and the sweat evaporates. 78) State why the salts in sports drinks are classified as electrolytes. 79) In the box below, draw a Lewis electron-dot diagram for one of the positive ions lost by the body as a person in the situation described perspires.