Copper-Catalyzed Carbenoid Insertion Reactions of α-diazoesters and α-diazoketones into Si H and S H Bonds
|
|
|
- Dwayne Hutchinson
- 5 years ago
- Views:
Transcription
1 Supporting Information for: Copper-Catalyzed Carbenoid Insertion Reactions of α-diazoesters and α-diazoketones into Si H and S H Bonds Hoda Keipour, Angela Jalba, Léo Delage-Laurin, Thierry Ollevier * Département de chimie, Université Laval, 1045 avenue de la Médecine Québec, QC, G1V 0A6, Canada S-1
2 CONTENT 1 H and 13 C NMR of p-tosyl Azide... S-5 1 H and 13 C NMR of p-acetamidobenzenesulfonyl Azide... S-6 1 H and 13 C NMR of Methanesulfonyl Azide... S-7 1 H and 13 C NMR of Methyl α-diazophenylacetate (1a)... S-8 1 H and 13 C NMR of Methyl α-diazo-4-methylphenylacetate (1b)... S-9 1 H and 13 C NMR of Methyl α-diazo-2-methylphenylacetate (1c)... S-10 1 H and 13 C NMR of Methyl α-diazo-4-methoxylphenylacetate (1d)... S-11 1 H and 13 C NMR of Methyl α-diazo-4-fluorophenylacetate (1e)... S-12 1 H and 13 C NMR of Methyl α-diazo-3-fluorophenylacetate (1f)... S-13 1 H and 13 C NMR of Methyl α-diazo-4-chlorophenylacetate (1g)... S-14 1 H and 13 C NMR of Methyl α-diazo-3-chlorophenylacetate (1h)... S-15 1 H and 13 C NMR of Methyl α-diazo-2-chlorophenylacetate (1i)... S-16 1 H and 13 C NMR of Methyl α-diazo-4-bromophenylacetate (1j)... S-17 1 H and 13 C NMR of Methyl α-diazo-3-bromophenylacetate (1k)... S-18 1 H and 13 C NMR of Ethyl α-diazophenylacetate (1l)... S-19 1 H and 13 C NMR of Isobutyl α-diazophenylacetate (1m)... S-20 1 H and 13 C NMR of Allyl α-diazophenylacetate (1n)... S-21 1 H and 13 C NMR of Methyl α-phenyl-α-triethylsilylacetate (2a)... S-22 1 H and 13 C NMR of Methyl α-(4-methylphenyl)-α-triethylsilylacetate (2b)... S-23 1 H and 13 C NMR of Methyl α-(2-methylphenyl)-α-triethylsilylacetate (2c)... S-24 1 H and 13 C NMR of Methyl α-(4-methoylphenyl)-α-triethylsilylacetate (2d)... S-25 1 H and 13 C NMR of Methyl α-(4-fluorophenyl)-α-triethylsilylacetate (2e)... S-26 1 H and 13 C NMR of Methyl α-(3-fluorophenyl)-α-triethylsilylacetate (2f)... S-27 1 H and 13 C NMR of Methyl α-(4-chlorophenyl)-α-triethylsilylacetate (2g)... S-28 1 H and 13 C NMR of Methyl α-(3-chlorophenyl)-α-triethylsilylacetate (2h)... S-29 1 H and 13 C NMR of Methyl α-(2-chlorophenyl)-α-triethylsilylacetate (2i)... S-30 1 H and 13 C NMR of Methyl α-(4-bromophenyl)-α-triethylsilylacetate (2j)... S-31 1 H and 13 C NMR of Methyl α-(3-bromophenyl)-α-triethylsilylacetate (2k)... S-32 1 H and 13 C NMR of Ethyl α-phenyl-α-triethylsilylacetate (2l)... S-33 1 H and 13 C NMR of Isobutyl α-phenyl-α-triethylsilylacetate (2m)... S-34 1 H and 13 C NMR of Allyl α-phenyl-α-triethylsilylacetate (2n)... S-35 S-2
3 1 H and 13 C NMR of Methyl 2-(Benzylthio)-2-phenylacetate (3a)... S-36 1 H and 13 C NMR of Methyl 2-(Benzylthio)-2-(4-chlorophenyl)-acetate (3b)... S-37 1 H and 13 C NMR of Methyl 2-Phenyl-2-(phenylthio)acetate (3c)... S-38 1 H and 13 C NMR of Methyl 2-((4-Methoxyphenyl)thio)-2-phenylacetate (3d)... S-39 1 H and 13 C NMR of Methyl 2-((4-Chlorophenyl)thio)-2-phenylacetate (3e)... S-40 1 H and 13 C NMR of Methyl 2-Phenyl-2-(p-tolylthio)acetate (3f)... S-41 1 H and 13 C NMR of Methyl 2-(4-Methoxyphenyl)-2-(phenylthio)acetate (3g)... S-42 1 H and 13 C NMR of Methyl 2-(Phenylthio)-2-(p-tolyl)acetate (3h)... S-43 1 H and 13 C NMR of Methyl 2-(4-Chlorophenyl)-2-(phenylthio)acetate (3i)... S-44 1 H and 13 C NMR of Methyl 2-(4-Bromophenyl)-2-(phenylthio)acetate (3j)... S-45 1 H and 13 C NMR of Ethyl 2-Phenyl-2-(phenylthio)acetate (3k)... S H and 13 C NMR of Isobutyl 2-Phenyl-2-(phenylthio)acetate (3l)... S-47 1 H and 13 C NMR of Methyl 1,2-Diphenylcyclopropane-1-carboxylate (4)... S-48 1 H and 13 C NMR of Allyl 2-Phenylacetate (6)... S-49 1 H and 13 C NMR of 1-Phenyl-3-oxabicyclo[3.1.0]hexan-2-one (7)... S-50 1 H and 13 C NMR of 2-Diazo-1-phenylpropan-1-one (8a)... S-51 1 H and 13 C NMR of 2-Diazo-1-(p-tolyl)propan-1-one (8b)... S-52 1 H and 13 C NMR of 2-Diazo-1-(p-chlorophenyl)propan-1-one (8c)... S-53 1 H and 13 C NMR of 2-Diazo-1-(p-fluorophenyl)propan-1-one (8d)... S-54 1 H and 13 C NMR of 1-(Benzo[d][1,3]dioxol-5-yl)-2-diazopropan-1-one (8e)... S-55 1 H and 13 C NMR of 2-Diazo-1,2-diphenylethan-1-one (8f)... S-56 1 H and 13 C NMR of 1-Diazo-1-phenylpropan-2-one (8g)... S-57 1 H and 13 C NMR of 2-Diazo-1-phenylbutan-1-one (8h)... S-58 1 H and 13 C NMR of 1-Phenyl-2-(triethylsilyl)propan-1-one (9a)... S-59 1 H and 13 C NMR of 1-(p-Tolyl)-2-(triethylsilyl)propan-1-one (9b)... S-60 1 H and 13 C NMR of 1-(4-Chlorophenyl)-2-(triethylsilyl)propan-1-one (9c)... S-61 1 H and 13 C NMR of 1-(4-Fluorophenyl)-2-(triethylsilyl)propan-1-one (9d)... S-62 1 H and 13 C NMR of 1-(Benzo[d][1,3]dioxol-5-yl)-2-(triethylsilyl)propan-1-one (9e).. S H and 13 C NMR of 1,2-Diphenyl-2-(triethylsilyl)ethan-1-one (9f)... S-64 1 H and 13 C NMR of 1-Phenyl-1-(triethylsilyl)propan-2-one (9g)... S-65 1 H and 13 C NMR of 1-Phenyl-2-(triethylsilyl)butan-1-one (9h)... S-66 1 H NMR of (E)-1-Phenylbut-2-en-1-one (9h')... S-67 S-3
4 1 H and 13 C NMR of Methyl 2-Hydroxy-2-phenylacetate (10)...S-68 1 H and 13 C NMR of Methyl-2,3-diphenylacrylate (11)... S-69 1 H and 13 C NMR of 2-Phenyl-2-(triethylsilyl)ethan-1-ol (12)... S-70 1 H and 13 C NMR of 2-Phenyl-2-(triethylsilyl)ethyl 2-phenylacetate (13)... S-71 1 H and 13 C NMR of 2-Phenyl-2-(triethylsilyl)ethyl 2-diazo-2-phenylacetate (14)... S-72 1 H and 13 C NMR of (E)-(1,3-Diphenylallyl)triethylsilane (16)... S-73 S-4
5 p-tosyl Azide S-5
6 p-acetamidobenzenesulfonyl Azide S-6
7 Methanesulfonyl Azide S-7
8 Methyl α-diazophenylacetate (1a) S-8
9 Methyl α-diazo-4-methylphenylacetate (1b) S-9
10 Methyl α-diazo-2-methylphenylacetate (1c) S-10
11 Methyl α-diazo-4-methoxylphenylacetate (1d) S-11
12 Methyl α-diazo-4-fluorophenylacetate (1e) S-12
13 Methyl α-diazo-3-fluorophenylacetate (1f) S-13
14 Methyl α-diazo-4-chlorophenylacetate (1g) S-14
15 Methyl α-diazo-3-chlorophenylacetate (1h) S-15
16 Methyl α-diazo-2-chlorophenylacetate (1i) S-16
17 Methyl α-diazo-4-bromophenylacetate (1j) S-17
18 Methyl α-diazo-3-bromophenylacetate (1k) S-18
19 Ethyl α-diazophenylacetate (1l) S-19
20 Isobutyl α-diazophenylacetate (1m) S-20
21 Allyl α-diazophenylacetate (1n) S-21
22 Methyl α-phenyl-α-triethylsilylacetate (2a) S-22
23 Methyl α-(4-methylphenyl)-α-triethylsilylacetate (2b) S-23
24 Methyl α-(2-methylphenyl)-α-triethylsilylacetate (2c) S-24
25 Methyl α-(4-methoylphenyl)-α-triethylsilylacetate (2d) S-25
26 Methyl α-(4-fluorophenyl)-α-triethylsilylacetate (2e) S-26
27 Methyl α-(3-fluorophenyl)-α-triethylsilylacetate (2f) S-27
28 Methyl α-(4-chlorophenyl)-α-triethylsilylacetate (2g) S-28
29 Methyl α-(3-chlorophenyl)-α-triethylsilylacetate (2h) S-29
30 Methyl α-(2-chlorophenyl)-α-triethylsilylacetate (2i) S-30
31 Methyl α-(4-bromophenyl)-α-triethylsilylacetate (2j) S-31
32 Methyl α-(3-bromophenyl)-α-triethylsilylacetate (2k) S-32
33 SiEt 3 OEt Ethyl α-phenyl-α-triethylsilylacetate (2l) O S-33
34 Isobutyl α-phenyl-α-triethylsilylacetate (2m) S-34
35 Allyl α-phenyl-α-triethylsilylacetate (2n) S-35
36 Methyl 2-(Benzylthio)-2-phenylacetate (3a) S-36
37 Methyl 2-(Benzylthio)-2-(4-chlorophenyl)-acetate (3b) S-37
38 Methyl 2-Phenyl-2-(phenylthio)acetate (3c) S-38
39 Methyl 2-((4-Methoxyphenyl)thio)-2-phenylacetate (3d) S-39
40 Methyl 2-((4-Chlorophenyl)thio)-2-phenylacetate (3e) S-40
41 Methyl 2-Phenyl-2-(p-tolylthio)acetate (3f) S-41
42 Methyl 2-(4-Methoxyphenyl)-2-(phenylthio)acetate (3g) S-42
43 Methyl 2-(Phenylthio)-2-(p-tolyl)acetate (3h) S-43
44 Methyl 2-(4-Chlorophenyl)-2-(phenylthio)acetate (3i) S-44
45 Methyl 2-(4-Bromophenyl)-2-(phenylthio)acetate (3j) S-45
46 Ethyl 2-Phenyl-2-(phenylthio)acetate (3k) S-46
47 Isobutyl 2-Phenyl-2-(phenylthio)acetate (3l) S-47
48 Methyl 1,2-Diphenylcyclopropane-1-carboxylate (4) S-48
49 Allyl 2-Phenylacetate (6) S-49
50 1-Phenyl-3-oxabicyclo[3.1.0]hexan-2-one (7) S-50
51 2-Diazo-1-phenylpropan-1-one (8a) S-51
52 2-Diazo-1-(p-tolyl)propan-1-one (8b) S-52
53 2-Diazo-1-(p-chlorophenyl)propan-1-one (8c) S-53
54 2-Diazo-1-(p-fluorophenyl)propan-1-one (8d) S-54
55 1-(Benzo[d][1,3]dioxol-5-yl)-2-diazopropan-1-one (8e) S-55
56 2-Diazo-1,2-diphenylethan-1-one (8f) S-56
57 1-Diazo-1-phenylpropan-2-one (8g) S-57
58 2-Diazo-1-phenylbutan-1-one (8h) S-58
59 1-Phenyl-2-(triethylsilyl)propan-1-one (9a) S-59
60 1-(p-Tolyl)-2-(triethylsilyl)propan-1-one (9b) S-60
61 1-(4-Chlorophenyl)-2-(triethylsilyl)propan-1-one (9c) S-61
62 1-(4-Fluorophenyl)-2-(triethylsilyl)propan-1-one (9d) S-62
63 1-(Benzo[d][1,3]dioxol-5-yl)-2-(triethylsilyl)propan-1-one (9e) S-63
64 1,2-Diphenyl-2-(triethylsilyl)ethan-1-one (9f) S-64
65 1-Phenyl-1-(triethylsilyl)propan-2-one (9g) S-65
66 1-Phenyl-2-(triethylsilyl)butan-1-one (9h) S-66
67 (E)-1-Phenylbut-2-en-1-one (9h') S-67
68 Methyl-2,3-diphenylacrylate (10) S-68
69 Methyl-2,3-diphenylacrylate (11) S-69
70 2-Phenyl-2-(triethylsilyl)ethan-1-ol (12) S-70
71 2-Phenyl-2-(triethylsilyl)ethyl 2-phenylacetate (13) S-71
72 2-Phenyl-2-(triethylsilyl)ethyl 2-diazo-2-phenylacetate (14) S-72
73 (E)-(1,3-Diphenylallyl)triethylsilane (16) S-73
Preparation of Optically Pure Tertiary Phosphine Oxides via Addition of P-Stereogenic Secondary Phosphine Oxide to Activated Alkenes
Preparation of Optically Pure Tertiary Phosphine Oxides via Addition of P-Stereogenic Secondary Phosphine Oxide to Activated Alkenes Ji-Ping Wang, Shao-Zhen Nie, Zhong-Yang Zhou, Jing-Jing Ye, Jing-Hong
Supporting Information
Supporting Information Wiley-VCH 2007 69451 Weinheim, Germany Catalytic Asymmetric Reaction with Water: Enantioselective Synthesis of α-hydroxyesters by Coppercarbenoid H Insertion Reaction Shou-Fei Zhu,
Divergent Synthesis of CF 3 -Substituted Polycyclic Skeletons Based on Control of Activation Site of Acid Catalysts
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Divergent Synthesis of CF 3 -Substituted Polycyclic Skeletons Based on Control of Activation Site
Supporting Information:
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2016 Supporting Information: A metal free reduction of aryl-n-nitrosamines to corresponding hydrazines
Supplementary Information
Supplementary Information J. Braz. Chem. Soc., Vol. 26, No. 6, S1-S29, 2015. Printed in Brazil - 2015 Sociedade Brasileira de Química 0103-5053 $6.00+0.00 SI Marina Ritter,*,a Rosiane M. Martins, a Silvana
Isothiourea-catalyzed asymmetric synthesis of -lactams and -amino esters from arylacetic acid derivatives and N-sulfonyl aldimines
Isothiourea-catalyzed asymmetric synthesis of -lactams and -amino esters from arylacetic acid derivatives and N-sulfonyl aldimines Siobhan R. Smith, a James Douglas, a Hugues Prevet, a Peter Shapland,
*Corresponding author. Tel.: , ; fax: ; Materials and Method 2. Preparation of GO nanosheets 3
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Synthesis of 2,3-dihydroquinazolinones and quinazolin-4(3h)-one catalyzed by Graphene Oxide
Supporting Information
Supporting Information Enantioselective Hydrogenation of β-ketophosphonates with Chiral Ru(II) Catalysts Xiaoming Tao, Wanfang Li, Xin Ma, Xiaoming Li, Weizheng Fan, Lvfeng Zhu, Xiaomin Xie, and Zhaoguo
Supporting Information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry Supporting Information General Remarks Most of chemicals were purchased from Sigma-Aldrich, Strem,
SUPPLEMENTARY INFORMATION
In the format provided by the authors and unedited. SUPPLEMENTARY INFORMATION DOI: 10.1038/NCHEM.2789 Catalytic asymmetric trifluoromethylthiolation via enantioselective [2,3]-sigmatropic rearrangement
Amberlyst-15/[Bmim][PF 6 ] Catalyzed Synthesis of C 3 -Symmetric Triarylbenzenes via Cyclotrimerization of Alkynes
![Amberlyst-15/[Bmim][PF 6 ] Catalyzed Synthesis of C 3 -Symmetric Triarylbenzenes via Cyclotrimerization of Alkynes](/thumbs/96/127004993.jpg "Amberlyst-15/[Bmim][PF 6 ] Catalyzed Synthesis of C 3 -Symmetric Triarylbenzenes via Cyclotrimerization of Alkynes")
Supporting Information Amberlyst-15/[Bmim][PF 6 ] Catalyzed Synthesis of C 3 -Symmetric Triarylbenzenes via Cyclotrimerization of Alkynes Kishor V. Wagh and Bhalchandra M. Bhanage Department of Chemistry,
Asymmetric Synthesis of Tri- and Tetrasubstituted Trifluoromethyl Dihydropyranones from α-aroyloxyaldehydes
Asymmetric Synthesis of Tri- and Tetrasubstituted Trifluoromethyl Dihydropyranones from α-aroyloxyaldehydes via NHC-Redox Catalysis Alyn T. Davies, Philip M. Pickett, Alexandra M. Z. Slawin, and Andrew
X-ray single-crystal structure of 2d. 31 P NMR study of the reaction mixture. S11-S14. 1 H and 13 C NMR spectra of all new compounds.
Supporting Information for Cleavage of a Carbon-carbon Triple Bond via Gold-catalyzed Cascade Cyclization/xidative Cleavage Reactions of (Z)-Enynols with Molecular xygen Yuanhong Liu*, Feijie Song and
Supporting information:
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 206 Supporting information: A highly efficient heterogeneous copper-catalyzed Chan- Lam coupling
Supporting Information. Cu(I)-Catalyzed Three-Component Reaction of Diazo. Compound with Terminal Alkyne and Nitrosobenzene for
Supporting Information of Cu(I)-Catalyzed Three-Component Reaction of Diazo Compound with Terminal Alkyne and Nitrosobenzene for the Synthesis of Trifluoromethyl Dihydroisoxazoles Xinxin Lv, Zhenghui Kang,
Supporting Information for
Supporting Information for Pd-catalyzed C(sp 3 ) H Functionalization/Carbenoid Insertion: All-Carbon Quaternary Centers via Multiple C C Bond-Formation Álvaro Gutiérrez-Bonet, Francisco Juliá-Hernández,
Cu(II)-Based Strategy for Catalytic Enantioselective
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Cu(II)-Based Strategy for Catalytic Enantioselective β-borylation of α, β-unsaturated Acceptors
Singapore, #05 01, 28 Medical Drive, Singapore. PR China,
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Catalyst controlled Regioselectivity in Phosphine Catalysis: Synthesis of Spirocyclic Benzofuranones
CRYSTAL STRUCTURES OF SOME ORGANIC COMPOUNDS. A synopsis of the thesis submitted to the. Madurai Kamaraj University. For the award of the degree of
CRYSTAL STRUCTURES OF SOME ORGANIC COMPOUNDS A synopsis of the thesis submitted to the Madurai Kamaraj University For the award of the degree of DOCTOR OF PHILOSOPHY By J. SURESH Department of Physics
Supplementary Materials for In Vitro Evaluation of Novel Inhibitors Against the NS2B-NS3 Protease of Dengue Fever Virus Type 4
Supplementary Materials for In Vitro Evaluation of Novel Inhibitors Against the NS2B-NS3 Protease of Dengue Fever Virus Type 4 Table S1. Free binding energy and inhibition activities of the identified
Synthesis of Biginelli dihydropyrimidinone derivatives with various substituents on aluminum-planted mesoporous silica catalyst
Supplementary Material (ESI) for rganic & Biomolecular Chemistry This journal is The Royal Society of Chemistry 2010 Supplementary Information for Synthesis of Biginelli dihydropyrimidinone derivatives
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information Department of Pharmacology and Pharmaceutical Sciences, School of life sciences
Preparation and ring-opening reactions of N- diphenylphosphinyl vinyl aziridines
Supporting Information for Preparation and ring-opening reactions of N- diphenylphosphinyl vinyl aziridines Ashley N. Jarvis 1, Andrew B. McLaren 1, Helen M. I. Osborn 1 and Joseph Sweeney* 1,2 Address:
Hualong Ding, Songlin Bai, Ping Lu,* Yanguang Wang*
Supporting Information for Preparation of 2-Amino-3-arylindoles via Pd-Catalyzed Coupling between 3-Diazoindolin-2-imines and Arylboronic Acids as well as Their Extension to 3-Aryl-3-fluoroindolin-2-imines
Supporting Information
Supporting Information Wiley-VCH 2012 69451 Weinheim, Germany Substitution of Two Fluorine Atoms in a Trifluoromethyl Group: Regioselective Synthesis of 3-Fluoropyrazoles** Kohei Fuchibe, Masaki Takahashi,
Supplementary Information
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2017 Supplementary Information Ruthenium(II)-Catalyzed Intermolecular Synthesis of 2-Arylindolines
Electronic Supplementary Information for. An odorless thia-michael addition using bunte salts as thiol. surrogates
Electronic upplementary Material (EI) for RC Advances. This journal is The Royal ociety of Chemistry 2015 Electronic upplementary Information for An odorless thia-michael addition using bunte salts as
Supporting Information
Supporting Information Brønsted Acid-Catalyzed [6+2]-Cycloaddition of 2-Vinylindoles with In Situ Generated 2-Methide-2H-pyrroles: Direct, Catalytic, and Enantioselective Synthesis of 2,3-Dihydro-H-pyrrolizines
Regioselective Synthesis of 1,5-Disubstituted 1,2,3-Triazoles by reusable
1 Regioselective Synthesis of 1,5-Disubstituted 1,2,3-Triazoles by reusable immobilized AlCl 3 on γ-al 2 O 3 SUPPLEMETARY DATA Typical Procedure to the preparation of Azides Phenyl azide Phenyl azide was
Supporting Information
Supporting Information Diastereoselective Synthesis of Symmetrical and Unsymmetrical Tetrahydropyridines Catalyzed by Bi(III) Immobilized on Triazine Dendrimer Stabilized Magnetic Nanoparticles Beheshteh
Supporting information. Double Reformatsky Reaction: Divergent Synthesis of δ-hydroxy-β-ketoesters
Supporting information Double Reformatsky Reaction: Divergent Synthesis of δ-hydroxy-β-ketoesters Masahiro Mineno,* Yasuhiro Sawai, Kazuaki Kanno, Naotaka Sawada and Hideya Mizufune Chemical Development
Supporting Information. Rhodium(III)-Catalyzed Imidoyl C H Activation for Annulations to Azolopyrimidines
Supporting Information Rhodium(III)-Catalyzed Imidoyl C H Activation for Annulations to Azolopyrimidines Kim Søholm Halskov, Michael R. Witten, Gia L. Hoang, Brandon Q. Mercado, and Jonathan A. Ellman*
Supporting Information
Supporting Information Synthesis of H-Indazoles from Imidates and Nitrosobenzenes via Synergistic Rhodium/Copper Catalysis Qiang Wang and Xingwei Li* Dalian Institute of Chemical Physics, Chinese Academy
Diao Chen, Dong-Xing Zhu and Ming-Hua Xu * State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences
Supporting Information for: Rhodium(I)-atalyzed ighly Enantioselective Insertion of arbenoid into Si-: Efficient Access to Functional hiral Silanes Diao hen, Dong-Xing Zhu and Ming-ua Xu * State Key Laboratory
Supporting Information. The Use of 5,5-(dimethyl)-i-Pr-PHOX as a Practical Equivalent to t-bu-phox in Asymmetric Catalysis
SI-1 Supporting Information The Use of 5,5-(dimethyl)-i-Pr-PHX as a Practical Equivalent to t-bu-phx in Asymmetric Catalysis Étienne Bélanger, Marie-France Pouliot, and Jean-François Paquin* Canada Research
Concise and diastereoselective approach to syn- and anti-n-tosyl-a-hydroxy b-amino acid derivatives
Tetrahedron 61 (2005) 6546 6552 Concise and diastereoselective approach to syn- and anti-n-tosyl-a-hydroxy b-amino acid derivatives Yonghua Zhao, Nan Jiang, Shufeng Chen, Cheng Peng, Xiaomei Zhang, Yaping
2. EXPERIMENTAL Synthesis of 1-(2-(2,4,5-triphenyl-1H-imidazol-1-yl) ethyl)piperazines (84-98)
29 2. EXPERIMENTAL 2.1. PREPARATION OF THE CATALYST Sulphated yttria (SO4 2- /Y2O3) was prepared by sol-gel method using the known procedure. 147 The catalyst with 5 wt% of SO4 2 loaded yttrium oxide (Y2O3)
Supporting Information
Supporting Information Silver/NBS-Catalyzed Synthesis of α-alkylated Aryl Ketones from Internal Alkynes and Benzyl Alcohols via Ether Intermediates Supill Chun and Young Keun Chung* Department of Chemistry,
Micellar catalysis applied to sustainable ppm Au-catalyzed reactions in water at room temperature. Supporting information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Micellar catalysis applied to sustainable ppm Au-catalyzed reactions in water at room temperature
Supporting information
Supporting information Synthesis of 3-Pyrrolin-2-ones by Rhodium-Catalyzed Transannulation of 1-Sulfonyl-1,2,3-triazole with Ketene Silyl Acetal Rui-Qiao Ran, Jun He, Shi-Dong Xiu, Kai-Bing Wang, Chuan-Ying
Solvent and structural effects on bimolecular elimination reactions
Retrospective Theses and Dissertations 1964 Solvent and structural effects on bimolecular elimination reactions John Theodore Frey Iowa State University Follow this and additional works at: http://lib.dr.iastate.edu/rtd
Supporting Information
Supporting Information Combining Rh-catalyzed diazocoupling and enzymatic reduction to efficiently synthesize enantioenriched 2-substituted succinate derivatives Yajie Wang, a Mark J. Bartlett, b Carl
Supporting information
Supporting information Access to Aminated Saturated Oxygen Heterocycles via Copper-Catalyzed Aminooxygenation of Alkenes Jian Xie, Yue-Wei Wang, Lian-Wen Qi,* and Bo Zhang* State Key Laboratory of Natural
Highly Diastereo- and Enantioselective Organocatalytic Domino Michael/Aldol Reaction of Acyclic 3- Halogeno- 1,2- Diones to α,β- Unsaturated Aldehydes
Supporting Information for Highly Diastereo- and Enantioselective rganocatalytic Domino Michael/Aldol Reaction of Acyclic 3- Halogeno- 1,2- Diones to α,β- Unsaturated Aldehydes Alice Lefranc 1, Laure Guénée
Supporting Information. Indole Synthesis via Cobalt(III)-Catalyzed Oxidative Coupling of N-Arylureas and Internal Alkynes
Supporting Information Indole Synthesis via Cobalt(III)-Catalyzed Oxidative Coupling of N-Arylureas and Internal Alkynes Zhuo-Zhuo Zhang, Bin Liu, Jing-Wen Xu, Sheng-Yi Yan, Bing-Feng Shi * Department
Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed. Cascade Trifluoromethylation/Cyclization of. 2-(3-Arylpropioloyl)benzaldehydes
Supporting Information to Synthesis of Trifluoromethylated Naphthoquinones via Copper-Catalyzed Cascade Trifluoromethylation/Cyclization of 2-(3-Arylpropioloyl)benzaldehydes Yan Zhang*, Dongmei Guo, Shangyi
Bio-based Green Solvent Mediated Disulfide Synthesis via Thiol Couplings Free of Catalyst and Additive
Bio-based Green Solvent Mediated Disulfide Synthesis via Thiol Couplings Free of Catalyst and Additive Yunyun Liu, ab Hang Wang, b Chunping Wang, b Jie-Ping Wan* ab and Chengping Wen* c a Key Laboratory
Supporting Information. ynamides: a simple access to aminoimidazoles
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Tf 2 NH-Catalyzed formal [3+2] cycloaddition of
Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides
![Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides](/thumbs/87/96032158.jpg "Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides")
Catalytic Asymmetric [2,3]-Sigmatropic Rearrangement of Sulfur Ylides Generated from Copper(I) Carbenoids and Allyl Sulfides Xiaomei Zhang, Zhaohui Qu, Zhihua Ma, Weifeng Shi, Xianglin Jin, and Jianbo
LIST OF PAPERS PUBLISHED AND COMMUNICATED IN JOURNALS. 1 Chandrakantha B., Shetty, P., Nambiyar, V., Isloor, N and Isloor, A. M.
LIST OF PAPERS PUBLISHED AND COMMUNICATED IN JOURNALS 1 Chandrakantha B., Shetty, P., Nambiyar, V., Isloor, N and Isloor, A. M. Synthesis, characterization and biological activity of some new 1,3,4- oxadiazole
Electronic Supplementary Information
Electronic Supplementary Information Regiodivergent Heterocyclization: A Strategy for the Synthesis of Substituted Pyrroles and Furans Using α-formyl Ketene Dithioacetals as Common Precursors Ting Wu,
Carbonylative Coupling of Allylic Acetates with. Arylboronic Acids
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Carbonylative Coupling of Allylic Acetates with Arylboronic Acids Wei Ma, a Ting Yu, Dong Xue,*
Catalytic Reductive Dehydration of Tertiary Amides to Enamines under Hydrosilylation Conditions
SUPPORTIG IFORMATIO Catalytic Reductive Dehydration of Tertiary Amides to Enamines under Hydrosilylation Conditions Alexey Volkov, a Fredrik Tinnis, a and Hans Adolfsson.* a a Department of Organic Chemistry,
Hypervalent Iodine(III)-Mediated Oxidative Decarboxylation of β,γ-unsaturated Carboxylic Acids
Hypervalent Iodine(III)-Mediated Oxidative Decarboxylation of β,γ-unsaturated Carboxylic Acids Kensuke Kiyokawa, Shunsuke Yahata, Takumi Kojima, and Satoshi Minakata* Department of Applied Chemistry, Graduate
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Halogen bonded Iodonium Ion Catalysis: A Route to α Hydroxy Ketone via Domino
Synthetic and 1 H and 13 C NMR Spectral Studies on N-(Mono-substitutedphenyl)-acetamides H 4. NH-CO- CH 3 i. ; X = Cl, CH 3
Synthetic and 1 H and 13 C NMR Spectral Studies on N-(Mono-substitutedphenyl)-acetamides and Substituted Acetamides, 2/3/4-YC 6 H 4 NH-CO- CH 3 i X i (Y=CH 3, F, Cl, Br, NO 2 ; X = Cl, CH 3 ; i =0,1,2,3)
BOC-Protected Amines via a Mild and Efficient One-Pot Curtius Rearrangement. Hélène Lebel* Olivier Leogane. Supporting Information
BC-Protected Amines via a Mild and Efficient ne-pot Curtius Rearrangement. élène Lebel* livier Leogane Département de chimie, Université de Montréal, Montréal, Québec, Canada, 3C 3J7 Supporting Information
Asymmetric Construction of Fluorinated Imidazolidines via. Cu(I)-Catalyzed exo'-selective 1,3-Dipolar Cycloaddition of
Supporting Information for Asymmetric Construction of Fluorinated Imidazolidines via Cu(I)-Catalyzed exo'-selective 1,3-Dipolar Cycloaddition of Azomethine Ylides with Fluorinated Imines Qing-Hua Li, Liang
Supporting Information for:
Electronic Supplementary Material (ESI) for Analytical Methods. This journal is The Royal Society of Chemistry 2014 Supporting Information for: Quantification of rare earth elements using cloud point extraction
Supporting Information
Supporting Information Wiley-VCH 2005 69451 Weinheim, Germany Synthesis of Homoallylic Sulfones Using a Novel Decarboxylative Claisen Rearrangement Reaction** Damien Bourgeois, Donald Craig,* N. Paul King,
Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2017 Supporting Information Regioselective 6-endo-dig Iodocyclization: An accessible
Rhodium-Catalyzed Synthesis of 1,2-Dihydropyridine by Tandem. Reaction of 4-(1-Acetoxyallyl)-1-sulfonyl-1,2,3-triazole
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information Rhodium-Catalyzed Synthesis of 1,2-Dihydropyridine by Tandem Reaction of
Journal Name ARTICLE. Exploring the Scope of the Isothiourea-mediated Synthesis of Dihydropyridinones. RSCPublishing
Journal Name RSCPublishing ARTICLE Cite this: DOI: 10.1039/x0xx00000x Exploring the Scope of the Isothiourea-mediated Synthesis of Dihydropyridinones Received 00th January 12, Accepted 00th January 12
Organic & Biomolecular Chemistry REVIEW. Recent Progress in the Catalytic Carbene Insertion Reactions into the Silicon Hydrogen Bond.
EVIEW proeceived 00th January 20xx, Accepted 00th January 20xx DI: 10.1039/x0xx00000x www.rsc.org/ ecent Progress in the Catalytic Carbene Insertion eactions into the licon ydrogen Bond oda Keipour, a
Supporting Information
Supporting Information for Engineering of indole-based tethered biheterocyclic alkaloid meridianin into -carboline-derived tetracyclic polyheterocycles via amino functionalization/6-endo cationic π-cyclization
Experience : Industry Academic 1.5 Yrs 3 Yrs. No. of papers published in Conferences : National International
Name Designation Qualification : Dr. Shridhar Malladi : Assistant Professor : M.Sc., Ph.D. Contact No. (office) : 0831-2498511 Email id : (git.edu) : samalladi@git.edu Date of joining the Institution :
IUPAC AND COMMON NAME
Structure Common Name IUPAC Name 1. CH 3 CH 2 CH 2 CH 2 Br n Butyl bromide 2. Isobutyl chloride 3. sec-butyl bromide 4. CH 3 CH 2 CH(Cl)CH 3 sec-butyl chloride 5. (CH 3 ) 3 CCH 2 Br neo-pentyl bromide
Amide Directed Cross-Coupling between Alkenes and Alkynes: A Regio- and Stereoselective Approach to Substituted (2Z,4Z)-Dienamides
Supporting Information For the article entitled Amide Directed Cross-Coupling between Alkenes and Alkynes: A Regio- and Stereoselective Approach to Substituted (2Z,4Z)-Dienamides Keke Meng, Jian Zhang,*
Received: August 31, 2015 Published: October 12, 2015
pubs.acs.org/joc Diastereoselective Synthesis of Fluorine-Containing Pyrrolizidines via Triphenylcarbenium Tetrafluoroborate-Promoted Carbofluorination of N 3-Arylpropargylpyrrolidine-Tethered Tertiary
Supporting Information
Supporting Information Dicobaltoctacarbonyl-Mediated Synthesis of Tricyclic 5,6-Diydropyran-2-one derivatives via Tandem Cycloaddition Reaction between cis-epoxyalkynes, Tethered lefin and Carbon Monoxide.
Iridium-catalyzed regioselective decarboxylative allylation of. β-ketoacids: efficient construction of γ, δ-unsaturated ketones
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction
Chem 201 Nomenclature Set Beauchamp Name
hem 0 omenclature Set Beauchamp ame Y:\files\classes\rganic hemistry Tool hest\omenclature\0 lecture nomencalature problems.doc hem 0 omenclature Set Beauchamp ame Answers. isopropyl "" n-hexyl "" t-pentyl
Organocatalytic Doubly Annulative Approach to 3,4-Dihydrocoumarins Bearing a Fused Pyrrolidine Scaffold. Dorota Kowalczyk, and Łukasz Albrecht*
Organocatalytic Doubly Annulative Approach to 3,4-Dihydrocoumarins Bearing a Fused Pyrrolidine Scaffold Dorota Kowalczyk, and Łukasz Albrecht* Institute of Organic Chemistry, Chemistry Department, Lodz
pyrazoles/isoxazoles library using ketene dithioacetals
Water mediated construction of trisubstituted pyrazoles/isoxazoles library using ketene dithioacetals Mahesh M. Savant, Akshay M. Pansuriya, Chirag V. Bhuva, Naval Kapuriya, Anil S. Patel, Vipul B. Audichya,
Supporting Information
1 Supporting Information Gold-catalyzed Synthesis of 3-arylindoles via Annulation of Nitrosoarenes and Alkynes Siva Murru, August A. Gallo and Radhey S. Srivastava* Department of Chemistry, University
Synthesis of Diaryl Selenides using Electrophilic Selenium Species and Nucleophilic Boron Reagents in Ionic Liquids
Synthesis of Diaryl Selenides using Electrophilic Selenium Species and Nucleophilic Boron Reagents in Ionic Liquids Camilo S. Freitas, a Angelita M. Barcellos, a Vanessa G. Ricordi, a Jesus M. Pena, b
Cu-Mn spinel oxide catalyzed synthesis of imidazo[1,2- a]pyridines through domino three-component coupling and 5-exo-dig cyclization in water
![Cu-Mn spinel oxide catalyzed synthesis of imidazo[1,2- a]pyridines through domino three-component coupling and 5-exo-dig cyclization in water](/thumbs/87/95548356.jpg "Cu-Mn spinel oxide catalyzed synthesis of imidazo[1,2- a]pyridines through domino three-component coupling and 5-exo-dig cyclization in water")
Electronic Supporting Information (ESI) Cu-Mn spinel oxide catalyzed synthesis of imidazo[1,2- a]pyridines through domino three-component coupling and 5-exo-dig cyclization in water Jaideep B. Bharate,
Supporting Information:
Supporting Information: An rganocatalytic Asymmetric Sequential Allylic Alkylation/Cyclization of Morita-Baylis-Hillman Carbonates and 3-Hydroxyoxindoles Qi-Lin Wang a,b, Lin Peng a, Fei-Ying Wang a, Ming-Liang
A Straightforward Three-component Synthesis of α-amino esters containing a Phenylalanine or a Phenylglycine Scaffold SUPPORTING INFORMATION
A Straightforward Three-component Synthesis of α-amino esters containing a Phenylalanine or a Phenylglycine Scaffold Caroline Haurena, Erwan Le Gall*, Stéphane Sengmany, Thierry Martens, Michel Troupel
Supporting Information. Remote Chirality Control Based on the Organocatalytic Asymmetric Mannich Reaction of α-thio Acetaldehydes
Supporting Information Remote Chirality Control Based on the Organocatalytic Asymmetric Mannich Reaction of α-thio Acetaldehydes Taichi Kano, Ryu Sakamoto and Keiji Maruoka* Department of Chemistry, Graduate
Supporting Information. Rhodium-Catalyzed Synthesis of Sulfur Ylides via in Situ Generated Iodonium Ylides
Supporting Information Rhodium-Catalyzed Synthesis of Sulfur Ylides via in Situ Generated Iodonium Ylides Janakiram Vaitla, *,, Kathrin H. Hopmann,, and Annette Bayer Hylleraas Centre for Quantum Molecular
Supporting Information
Supporting Information Electrooxidative C(sp3) H Amination of Azoles via Intermolecular Oxidative C(sp3) H/N H Cross-Coupling Jiwei Wu, Yi Zhou, Yuchen Zhou, Chien-Wei Chiang Aiwen Lei* The Institute for
Supporting Information
Supporting Information Further Developments of the Phenyl-Pyrrolyl Pentane Series of Nonsteroidal Vitamin D Receptor Modulators as Anticancer Agents Meixi Hao +, Siyuan Hou +, Lingjing Xue, Haoliang Yuan,
Phung-Hoang Nguyen, Maya West, Brent D. Feske, and Clifford W. Padgett
International Scholarly esearch Notices, Article ID 124289, 8 pages http://dx.doi.org/10.1155/2014/124289 esearch Article Enantioselectivity and Enzyme-Substrate Docking Studies of a Ketoreductase from
Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis
Supporting Information for: Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis Yu Zheng, Yuqi Tan, Klaus Harms, Michael Marsch, Radostan Riedel,
CsF/Clinoptilolite: an Efficient Solid Base in S N Ar and Copper-catalyzed Ullmann Reactions
Canadian Journal of Chemistry CsF/Clinoptilolite: an Efficient Solid Base in S N Ar and Copper-catalyzed Ullmann Reactions Journal: Canadian Journal of Chemistry Manuscript ID cjc-2015-0300.r1 Manuscript
Supporting Information. Efficient N-arylation and N-alkenylation of the five. DNA/RNA nucleobases
Supporting Information Efficient -arylation and -alkenylation of the five DA/RA nucleobases Mikkel F. Jacobsen, Martin M. Knudsen and Kurt V. Gothelf* Center for Catalysis and Interdisciplinary anoscience
Isomerism CH 4 C 2 H 6 C 3 H 8 C 4 H 10 C 5 H 12. Constitutional isomers...
Isomerism 4 2 6 3 8 4 10 5 12 onstitutional isomers... 3 8 Positional isomers... Functional isomers... ow many constitutional isomers are there for the formula 4 8? arbon atoms are often classified as
Supporting Information
Supporting Information Catalyst- and solvent-free one-pot synthesis of some novel polyheterocycles from aryldiazenyl salicylaldehyde derivatives Narsidas J. Parmar 1, Rikin A. Patel 1, Shashikant B. Teraiya
Supporting Information. DBU-Mediated Metal-Free Oxidative Cyanation of α-amino. Carbonyl Compounds: Using Molecular Oxygen as the Oxidant
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2015 Supporting Information DBU-Mediated Metal-Free Oxidative Cyanation of α-amino
Synthesis of Aminophenanthrenes and Benzoquinolines via Hauser-Kraus Annulation of Sulfonyl Phthalide with Rauhut- Currier Adducts of Nitroalkenes
Synthesis of Aminophenanthrenes and Benzoquinolines via Hauser-Kraus Annulation of Sulfonyl Phthalide with Rauhut- Currier Adducts of Nitroalkenes Tarun Kumar, Vaijinath Mane and Irishi N. N. Namboothiri*
Supporting Information
Decarboxylative Biaryl Synthesis from Aromatic Carboxylates and Aryl Triflates Lukas J. Gooßen*, Nuria Rodríguez, Christophe Linder B Chemie rganische Chemie, TU Kaiserslautern, Erwin-Schrödinger-Strasse,
SYNTHETIC CANNABINOID TRADE NAME AND CHEMICAL COMPOUND CHART
SYNTHETIC CANNABINOID TRADE NAME AND CHEMICAL COMPOUND CHART The following chart may not include all trade or other names for the designated substances. It also may not include all variations in the chemical
Supporting Information. Rh (III)-Catalyzed Meta-C H Olefination Directed by a Nitrile Template
Supporting Information Rh (III)-Catalyzed Meta-C H Olefination Directed by a Nitrile Template Hua-Jin Xu, Yi Lu, *, Marcus E. Farmer, Huai-Wei Wang, Dan Zhao, Yan-Shang Kang, Wei-Yin Sun, *, Jin-Quan Yu
Supporting Information
Supporting Information Rhodium-Catalyzed Synthesis of Imines and Esters from Benzyl Alcohols and Nitroarenes: Change in Catalyst Reactivity Depending on the Presence or Absence of the Phosphine Ligand
Rhodium Catalyzed Alkyl C-H Insertion Reactions
Rhodium Catalyzed Alkyl C-H Insertion Reactions Rh Rh Jeff Kallemeyn 5/17/05 1. Cyclopropanation The Versatile and Reactive Rhodium Carbene R + Et Rh 2 (Ac) 4 R C 2 Et N 2 2. [2,3] sigmatropic rearrangement
Supporting Information:
Supporting Information: Synthesis of Ethers via Reaction of Carbanions and Monoperoxyacetals ShivaKumar Kyasa, Rebecca N. Meier, Ruth A. Pardini, Tristan K. Truttmann, Keith T. Kuwata, and Patrick H. Dussault*
Supporting Information. A rapid and efficient synthetic route to terminal. arylacetylenes by tetrabutylammonium hydroxide- and
Supporting Information for A rapid and efficient synthetic route to terminal arylacetylenes by tetrabutylammonium hydroxide- and methanol-catalyzed cleavage of 4-aryl-2-methyl-3- butyn-2-ols Jie Li and
Supporting Information
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2018 Supporting Information Semiconductor Self-Assembled Monolayers as Selective
Supporting information
Supporting information Metal free Markovnikov type alkyne hydration under mild conditions Wenbo Liu, Haining Wang and Chao-Jun Li * Department of Chemistry and FQRNT Center for Green Chemistry and Catalysis,