Carbon Nanotubes for Photovoltaic Applications. Fernando Langa. Univ. of Castilla-La Mancha Toledo, Spain
|
|
- Natalie Jacobs
- 5 years ago
- Views:
Transcription
1 Carbon anotubes for Photovoltaic Applications Fernando Langa Univ. of Castilla-La Mancha Toledo, pain MICI-JT Joint Workshop, Barcelona, March 10 th -12 th, 2010
2 Madrid Toledo
3 Outline: 1. Photoinduced Electron Transfer in ystems Based on Fullerenes 2. Organic Dyes for Graetzel olar Cells. 3. Functionalization of Carbon anoforms. 4. Carbon anotubes for Photovoltaic Applications.
4 Aviram-Ratner Concept Acceptor Donor e - Ari Aviram Aviram, A., Ratner, M.A., Chem. Phys. Lett., 29, (1974).
5 Molecular electronics Molecular electronics can be defined as technology utilizing single molecules, small groups of molecules, carbon nanotubes or nanoscale metallic or semiconductor wires to perform electronic functions. Any device utilizing molecular properties is a molecular electronic device. Wires witches Transistors Molecular electronics Data storage OLEDs Photovoltaic devices
6 hν D * B A D + - B A ELECTRO DOOR (D) BRIDGE ACCEPTOR (A) YTEM
7 Pyrazolinofullerene derivatives These systems show better electron affinity than other fullerene derivatives and similar E 1 red to that of C 60 H 3 C O 2 E 1 red = V E 1 red = V J. Org. Chem. 2004, 69, 2661 Ar Ar CuTf 2 o-dcb, Reflux Org. Lett. 2008, 10, 3705 J. Org. Chem. 2008, 73, 3184 CH, 48 h. 1% MW, 12 h. 5%
8 organic solar cells CF 3 F 3 C O 2 O CH 3 η = 0.3 % O n F 3 C PCBM η = 0.17 % - + APFO GREE 1 F 3 C O 2 e - Al A D ITO glass light - + Appl. Phys. Lett. 2004, 85, Adv. Funct. Mater. 2005, 15, Organic Electronics 2006, 7, 195. η = 0.7 %
9 Fe Fe Fe CH 3 Fe Chem. A Eur. J. 2006, 12, 5149 J. Mat. Chem, 2002, 12, 2077 Chem. Eur. J. 2005, 11, 4405
10 Liquid crystaline sensor for acids Donor Acceptor Mesogenic unit Chem. Commun., 2008,
11 Liquid crystaline sensor for acids Bu 2 h 380 nm h 380 nm ET HBu 2 E O Mesogen(Gn) O Mesogen(Gn) Bu 2 Bu 2 H TFA Et nm (weak) no emission 485 nm (strong) 708 nm Chem. Commun., 2008,
12 Porphyrins and fullerenes π-conjugated wire Donor Acceptor k ET ( ) ( R ee ) R k e β = 0 The rate of ET depends on the distance and the attenuation factor (β)
13 Attenuation factor (β) for π-conjugated wires β = 0.08 Å -1 J. Am. Chem. oc. 1997, 119, β = 0.10 Å -1 Angew. Chem. Int. Ed. Engl. 1995, 34, 1100 n β = 0.4 Å -1 J. Am. Chem. oc. 1992, 114, 6227 n β = 0.03 Å -1 J. Phys. Chem. A, 2006, 110, 319 β = 0.11 Å -1 aturated bridges β = Å -1 J. Phys. Chem. B, 2004, 108, J. Am. Chem. oc. 1989, 93, 3258
14 OPVs as wires β = 0.04 Å -1 Wasielewski et al., ature, 1998, 396, 60 RO H 3 C OR n=1;3 β = 0.03 Å -1 Martín; Guldi et al., Chem. Eur. J., 2005, 11, 1267 β = 0.01 Å -1 Martín, Guldi et al., Chem. Eur. J., 2005, 11, 4819
15 Fc-nTV-C 60 triads Fe H 13 C 6 C 6 H 13 H 13 C 6 C 6 H 13 Lifetime of charge separated state: <6 ns k cs = 2,3 x 10 9 s -1 Φ = 0.63 HOMO C 60-2TV-Fc LUMO C 60-2TV-Fc Fe H 13 C 6 C 6 H 13 H 13 C 6 C 6 H 13 H 13 C 6 C 6 H 13 H 13 C 6 C 6 H 13 Lifetime of charge separated state: 12 ns k cs = 9,3 x 10 9 s -1 Φ = 0.93 Chemistry. A Eur. J. 2007, 13, 3924
16 ZnPorphyrin-nTV-C 60 triads CH 3 CH 3 C 6 H 13 C 6 H 13 H 3 C C 6 H 13 C 6 H 13 Zn CH 3 CH 3 H 3 C CH 3 H 3 C CH 3 ZnPor-2TV-C 60 H 3 C Chem. Commun. 2007, 4425
17 Zn-Porphyrin-nTV-C 60 triads H 3 C CH 3 H 3 C CH 3 H 3 C CH 3 C 6 H 13 C 6 H 13 Zn CH 3 CH 3 H 3 C C 6 H 13 C 6 H 13 C 6 H 13 C 6 H 13 CH 3 ZnPor-3TV-C 60
18 Zn-Porphyrin-nTV-C 60 triads CH 3 C 6 H 13 C 6 H 13 C 6 H 13 C 6 H 13 H 3 C C 6 H 13 C 6 H 13 C 6 H 13 C 6 H 13 Zn CH 3 CH 3 CH 3 H 3 C CH 3 H 3 C CH 3 ZnPor-4TV-C 60 H 3 C
19 Zn-Porphyrin-nTV-C 60 triads ZnPor-8TV-C 60 Distance Porphyrin-C 60 : 57.8 Å
20 Principal features of C process solvent k C Φ C k CR /s -1 τ RIP /μs ZnP-2TV-C 60 Toluene ( ) (0.97) PhC ZnP-4TV-C 60 Toluene PhC ZnP-8TV-C 60 Toluene PhC Lifetime of Charge separated state is in the order of μs!!
21 Minimal value for the attenuation factor 24.0 olvent: benzonitrile PhC ln(k C(P* - C) ) k ET R = k 0 e ( ) ( βr ee ) β = Å x x x x x x x x10-9 R CC(P - C) / m Plot of ln(k C(P*-C) ) vs R CC(P-C) in PhC for ZnP-nTV-C 60.
22 Comparison of β values between OPV and OTV Ar CH 3 OC 6 H 13 n OC 6 H 13 n=1,2 n Zn Ar Ar β = 0.03 Å -1 Martín; Guldi et al., Chem. Eur. J., 2005, 11, 1267 Ar CH 3 C 6 H 13 C 6 H 13 Zn Ar β = Å -1 C 6 H 13 C 6 H 13 n= 1, 2, 4 n Ar Chem. Commun. 2007, 4425
23 1. Photoinduced Electron Transfer in ystems Based on Fullerenes. 2. Organic Dyes for Graetzel olar Cells. 3. Functionalization of Carbon anoforms. 4. Carbon anotubes for Photovoltaic Applications.
24 DC (GRÄTZEL CELL) e V e - e - e - TiO 2 b.c e - LUMO Dye* V oc e - 0.5V 0.7V e -- I 3- / I- Dye HOMO I 3 - I - e - e - Glass-FTO Glass-FTO/Pt e - hυ e -
25 Ru Dyes HOOC COOTBA C HOOC Ru C 719 Metal Free Dyes COOTBA
26 The perfect sensitizer Absorbs all the sunlight below 900 nm. Is endowed with groups (carboxylate or phosphonate) that anchor it firmly to the TiO 2 surface. hows a high quantum yield of electron injection. table under long term illumination and Tª. o aggregation phenomena. HOMO has to be more positive than the redox potential of iodine/iodide. LUMO has to be sufficiently more negative than the conduction band edge of the TiO 2
27 FL-4 Absorbance (a.u) FL Wavelength(nm) J. Phys. Chem. C, 2008, 112, 18623
28 15 J sc (ma/cm 2 ) %MBI 50%MBI 0%MBI Refer 719 IPCE= 58% J sc = 13.4 ma/cm 2 V oc =0.5 V FF= 0.57 η(%) = Voltage (V) J. Phys. Chem. C, 2008, 112, 18623
29 R R R R C n COOH R = Hexyl n = LUMO n2tvacido n3tvacido n4tvacido n6tvacido Energy -6-8 HOMO HOMO-1 Absorption ntv wavelength (nm) ChemPhysChem 2010, 11, 245
30 R R R R C n COOH R = Hexyl 2tv 3tv 4tv 5tv 6tv n = 1-5 Dye Eficiency (%) 12 2TV 1.43 J(mA/cm 2 ) TV TV TV TV 1.80 V/V ChemPhysChem 2010, 11, 245, mall, 2010, 6, 221
31 ew Dyes FL-7 0,6 0,5 0,4 0,3 0,2 0,1 0, dye J sc [macm -2 ] V oc FF η[%] FL FL ChemusChem 2009, 2, 344
32 1. Photoinduced Electron Transfer in ystems Based on Fullerenes 2. Organic Dyes for Graetzel olar Cells. 3. Functionalization of Carbon anoforms. 4. Carbon anotubes for Photovoltaic Applications.
33
34 Excellent Properties Low solubility Lack of response Applications limited WT Response to external stimuli -Chemical -Electrochemical -Photochemical - -oluble -Activity Chemical functionalization Applications improved
35 Purification of CTs by Oxidation Carbon HO 3 Reflux Catalist horter WT
36 Functionalization of WT
37 HOOC HOOC HOOC HOOC COOH COOH COOH COOH (a) (a) Air atmosphere (b) Under 2 (c) Without ilumination 1) Cl 2 O, reflux, 24 h 2) n-c 5 H 11 OH, 80º, 72 h Intensity (na) (b) (c) OOC OOC OOC OOC COO COO COO COO Wavelength (nm) 0,3 0,2 0,1 0, Time (s) E-WT solution in CHCl 3 Chem. Phys. Letters, 2004, 386
38 A novel hybrid carbon material The field-emission characteristics of anobuds suggest that they may possess advantageous properties compared with singlewalled nanotubes or fullerenes alone. Kauppinen et al.ature anotechnology, 2007, 2, 156
39 The first conjugated WT-C 60 hybrid HR-TEM Carbon, 2007, 45, 2250
40 OOC OOC OOC O 2 n COO COO COO OOC COO Chem. Commun, 2004, 1734 J. Phys. Chem B., 2004, 108, J. Am. Chem. oc. 2006, 128, 6626 J. Mat. Chem. 2008, 18, 1592
41 CH-BAED PHOTOVOLTAIC CELL O C H H 3 + Cl - + Zn O O O O O O O O CH-sp-H 3 + Crown Zn-P O C H O O O H O H H O O O O Zn CH-sp-H 3 + ;CrownZn-P (submitted )
42 CH-BAED PHOTOVOLTAIC CELL supramolecular complex formation? 14 Absorbance / a.u. 0,20 0,15 0,10 0,05 Absorbance / a.u. 0,24 0,20 0,16 0,12 0,08 0,04 0, wavelenght / nm [ZnP crown ether] = 10-7 M [H ox -H 3 + Cl - ] = 0.5 mg / 100 ml DMF Intensity / a.u [ZnP crown ether] = 10-7 M [H ox -H 3 + Cl - ] = 0.5 mg / 100 ml DMF, λ exc : 560 nm quenching: 55% wavelength / nm 0, λ / nm 0,0 0,2 0,4 0,6 0,8 1,0 Potential (V) vs Ag/AgO 3
43 CH-BAED PHOTOVOLTAIC CELL e - hυ e - no 2 hυ e - e - e - e - hυ I 3 - e - e - e - e - I - e - OTE IPCE of 9% Pt e - e - e -
44 Photocurrent action spectra of IPCE (a) OTE/nO 2 /CH-sp-H 3+ ;Crown-ZnP (b) OTE/nO 2 /CH-sp-H 3 + (c) OTE/nO 2 /Crown-ZnP Photocurrent generation responses of (a)ote/no 2 /CH-sp-H 3+ ;Crown-ZnP (b) OTE/nO 2 /CH-sp-H 3 +
45 Final Remarks everal examples of Fullerene-based donor acceptor systems are presented. ew Dyes for DC have been prepared and studied. Properties of Carbon anotubes can be tailored by chemical functionalization. A photovoltaic cell based on Carbon Horns is presented.
46 Thanks!! Collaborations CH: Prof.. Iijima Dr. M. Yudasaka Photophysics: Prof. O. Ito DC: Prof. J. Bisquert Prof. E. Palomares Organic cells Prof. Inganas
Organic Solar Cells. All Organic solar cell. Dye-sensitized solar cell. Dye. τ inj. τ c. τ r surface states D*/D + V o I 3 D/D.
The 4th U.S.-Korea NanoForum April 26-27, 2007, Honolulu, USA Improvement of Device Efficiency in Conjugated Polymer/Fullerene NanoComposite Solar Cells School of Semiconductor & Chemical Engineering *
More informationLight Energy Harvesting via Supramolecularly Functionalized Semi-Conductive SWCNTs with Sensitizers
Light Energy Harvesting via Supramolecularly Functionalized Semi-Conductive SWCTs with Sensitizers Francis D Souza a, * Sushanta K. Das, a avaneetha K. Subbaiyan, a Atula S. D. Sandanayaka, b and samu
More informationOptical Science of Nano-graphene (graphene oxide and graphene quantum dot) Introduction of optical properties of nano-carbon materials
Optical Science of Nano-graphene (graphene oxide and graphene quantum dot) J Kazunari Matsuda Institute of Advanced Energy, Kyoto University Introduction of optical properties of nano-carbon materials
More informationOPV Workshop September 20, Materials for Polymer Solar Cells: Achievements and Challenges. Wei You
OPV Workshop September 20, 2012 Materials for Polymer Solar Cells: Achievements and Challenges Wei You Department of Chemistry University of North Carolina at Chapel Hill 1 Bulk Heterojunction Solar Cell
More informationMesoporous titanium dioxide electrolyte bulk heterojunction
Mesoporous titanium dioxide electrolyte bulk heterojunction The term "bulk heterojunction" is used to describe a heterojunction composed of two different materials acting as electron- and a hole- transporters,
More informationPlanar Organic Photovoltaic Device. Saiful I. Khondaker
Planar Organic Photovoltaic Device Saiful I. Khondaker Nanoscience Technology Center and Department of Physics University of Central Florida http://www.physics.ucf.edu/~khondaker W Metal 1 L ch Metal 2
More informationVikram Kuppa School of Energy, Environmental, Biological and Medical Engineering College of Engineering and Applied Science University of Cincinnati
Vikram Kuppa School of Energy, Environmental, Biological and Medical Engineering College of Engineering and Applied Science University of Cincinnati vikram.kuppa@uc.edu Fei Yu Yan Jin Andrew Mulderig Greg
More informationNanotechnology and Solar Energy. Solar Electricity Photovoltaics. Fuel from the Sun Photosynthesis Biofuels Split Water Fuel Cells
Nanotechnology and Solar Energy Solar Electricity Photovoltaics Fuel from the Sun Photosynthesis Biofuels Split Water Fuel Cells Solar cell A photon from the Sun generates an electron-hole pair in a semiconductor.
More informationPyridine-functionalized Fullerene Additive Enabling Coordination. Bulk Heterojunction Solar Cells
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2019 Electronic Supplemental Information for Pyridine-functionalized Fullerene
More informationOrgano-metal halide perovskite-based solar cells with CuSCN as inorganic hole selective contact
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 214 Organo-metal halide perovskite-based solar cells with CuSCN as inorganic
More informationPlastic Electronics. Joaquim Puigdollers.
Plastic Electronics Joaquim Puigdollers Joaquim.puigdollers@upc.edu Nobel Prize Chemistry 2000 Origins Technological Interest First products.. MONOCROMATIC PHILIPS Today Future Technological interest Low
More informationSupporting Information
Supporting Information Red-absorbing Cationic Acceptor Dyes for Photocathodes in Tandem Solar Cells. Christopher J. Wood, a Ming Cheng, b Charlotte A. Clark, a Raphael Horvath, a Ian P. Clark, c Michelle
More informationFINNISH-JAPANESE WORKSHOP ON FUNCTIONAL MATERIALS Espoo-Helsinki May, 2009
FINNISH-JAPANESE WRKSHP N FUNCTINAL MATERIALS Espoo-Helsinki 25. 26. May, 2009 THEMATIC WRKING GRUP: MATERIALS FR NEW ENERGY SLUTINS, SLAR CELL & BATTERY Fast spectroscopy Synthesis of functional molecules
More informationSupporting Information
Supporting Information Cyclodextrin Supramolecular Complex as Water Soluble Ratiometric Sensor for ferric Ion Sensing Meiyun Xu, Shuizhu Wu,* Fang Zeng, Changmin Yu College of Materials Science & Engineering,
More informationSupporting Information
I/ A Electronic Supplementary Material (ESI) for Chemical Communications Supporting Information Semiconducting Single-Wall Carbon Nanotube and Covalent Organic Polyhedron-C 6 Nanohybrids for Light Harvesting
More informationCharge separation in molecular donor acceptor heterojunctions
Institute of Physics 13 July 2009 Charge separation in molecular donor acceptor heterojunctions Jenny Nelson, James Kirkpatrick, Jarvist Frost, Panagiotis Keivanidis, Clare Dyer-Smith, Jessica Benson-Smith
More informationNovel device Substrates and Materials for Organic based Photovoltaics
Novel device Substrates and Materials for Organic based Photovoltaics Frank Nüesch Laboratory for Functional Polymers Empa Materials Science and Technology Überlandstrasse 129 8600 Dübendorf SwissLaserNet,
More informationConjugated Polymers Based on Benzodithiophene for Organic Solar Cells. Wei You
Wake Forest Nanotechnology Conference October 19, 2009 Conjugated Polymers Based on Benzodithiophene for Organic olar Cells Wei You Department of Chemistry and Institute for Advanced Materials, Nanoscience
More informationSUPPORTING INFORMATION
Current Density (ma/cm 2 ) Current Density (ma/cm 2 ) SUPPORTING INFORMATION New Electron Acceptor Derived from Fluorene: Synthesis and its Photovoltaic Properties P. Nagarjuna, Anirban Bagui, Jianhui
More informationElectron transfer optimisation in organic solar cells
Electron transfer optimisation in organic solar cells James Durrant Centre for Electronic Materials and Devices Departments of Chemistry Imperial College London Introductory remarks Charge recombination
More informationAmerican Physical Society Meeting Baltimore, MD, March Advanced Materials for Solar Energy Utilization
American Physical Society Meeting Baltimore, MD, 13-17 March 2006 Advanced Materials for Solar Energy Utilization Bio-inspired constructs for solar energy conversion Thomas A. Moore 1,2, Ana L Moore 1
More informationWhat will it take for organic solar cells to be competitive?
What will it take for organic solar cells to be competitive? Michael D. McGehee Stanford University Director of the Center for Advanced Molecular Photovoltaics Efficiency (%) We will need 20-25 % efficiency
More informationE L E C T R O P H O S P H O R E S C E N C E
Organic LEDs part 4 E L E C T R O P H O S P H O R E S C E C E. OLED efficiency 2. Spin 3. Energy transfer 4. Organic phosphors 5. Singlet/triplet ratios 6. Phosphor sensitized fluorescence 7. Endothermic
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supporting Information Efficiency Improvement of Dye-sensitized Solar Cells
More informationImprovement of Photovoltaic Properties for Unmodified Fullerene C 60 -Based Polymer Solar Cells by Addition of Fusible Fullerene
Journal of Photopolymer Science and Technology Volume 30, Number 4 (2017) 501-506 C 2017SPST Improvement of Photovoltaic Properties for Unmodified Fullerene C 60 -Based Polymer Solar Cells by Addition
More informationTowards a deeper understanding of polymer solar cells
Towards a deeper understanding of polymer solar cells Jan Anton Koster Valentin Mihailetchi Prof. Paul Blom Molecular Electronics Zernike Institute for Advanced Materials and DPI University of Groningen
More informationOrganic Electronic Devices
Organic Electronic Devices Week 4: Organic Photovoltaic Devices Lecture 4.2: Characterizing Device Parameters in OPVs Bryan W. Boudouris Chemical Engineering Purdue University 1 Lecture Overview and Learning
More informationPhotovoltaics. Lecture 7 Organic Thin Film Solar Cells Photonics - Spring 2017 dr inż. Aleksander Urbaniak
Photovoltaics Lecture 7 Organic Thin Film Solar Cells Photonics - Spring 2017 dr inż. Aleksander Urbaniak Barcelona, Spain Perpignan train station, France source: pinterest Why organic solar cells? 1.
More informationPhotovoltage phenomena in nanoscaled materials. Thomas Dittrich Hahn-Meitner-Institute Berlin
Photovoltage phenomena in nanoscaled materials Thomas Dittrich Hahn-Meitner-Institute Berlin 1 2 Introduction From bulk to nanostructure: SPV on porous Si Retarded SPV response and its origin Photovoltage
More informationHow to burn water with sunlight: insights from computational chemistry
How to burn water with sunlight: insights from computational chemistry Andrzej L. Sobolewski Institute of Physics, Polish Academy of Sciences H 2 EUCMOS XXXIV, Coimbra, 19-24.08.2018 Motivation The dream
More informationSupporting Information
Supporting Information Non-Fullerene/Fullerene Acceptor Blend with Tunable Energy State for High- Performance Ternary Organic Solar Cells Min Kim 1, Jaewon Lee 1, Dong Hun Sin 1, Hansol Lee 1, Han Young
More informationMetal-Containing Functional Materials for OLEDs and Solar Cells
Metal-Containing Functional Materials for OLEDs and olar Cells Prof. Wai-Yeung Wong (Raymond) Department of Chemistry Centre for Advanced Luminescence Materials Hong Kong Baptist University Chemistry Enriching
More informationThe Current Status of Perovskite Solar Cell Research at UCLA
The Current Status of Perovskite Solar Cell Research at UCLA Lijian Zuo, Sanghoon Bae, Lei Meng, Yaowen Li, and Yang Yang* Department of Materials Science and Engineering University of California, Los
More informationPerovskite solar cells
IMO - IMOMEC INSTITUUT VOOR MATERIAALONDERZOEK Perovskite solar cells dr. ir. Bert Conings bert.conings@uhasselt.be state-of-the-art http://www.nrel.gov/ncpv/images/efficiency_chart.jpg outline! introduction!
More informationOrganic Electronic Devices
Organic Electronic Devices Week 5: Organic Light-Emitting Devices and Emerging Technologies Lecture 5.5: Course Review and Summary Bryan W. Boudouris Chemical Engineering Purdue University 1 Understanding
More informationFluoropolymer 2014, Oct 14. Shinsuke Inagi. Department of Electronic Chemistry Tokyo Institute of Technology, Japan.
Fluoropolymer 2014, Oct 14 Shinsuke Inagi Department of Electronic Chemistry Tokyo Institute of Technology, Japan inagi@echem.titech.ac.jp Contents 1. Electrochemical Polymer Reactions Anodic Fluorination,
More informationHole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode
Supporting information For Nano Letters Hole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode Xiaobao Xu,,, Zonghao Liu,, Zhixiang Zuo, Meng Zhang, Zhixin Zhao, Yan Shen,
More information4. CV curve of GQD on platinum electrode S9
Supporting Information Luminscent Graphene Quantum Dots (GQDs) for Organic Photovoltaic Devices Vinay Gupta*, Neeraj Chaudhary, Ritu Srivastava, Gauri Dutt Sharma, Ramil Bhardwaj, Suresh Chand National
More informationTransport Properties of Novel Carbon Nanotubes and Nanopeapods
Transport Properties of Novel Carbon Nanotubes and Nanopeapods Takashi Shimada, Yutaka Ohno, Toshiya Okazaki, Toshiki Sugai, Yousuke Nosho, Kazutomo Suenaga, Shigeru Kishimoto, Takashi Mizutani, and Hisanori
More informationTEM image of derivative 1 and fluorescence spectra of derivative 1 upon addition of
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2016 Supramolecular ensemble of PBI derivative and Cu 2 O NPs: Potential photo catalysts for
More informationTransparent TiO 2 nanotube/nanowire arrays on TCO coated glass substrates: Synthesis and application to solar energy conversion
Transparent TiO 2 nanotube/nanowire arrays on TCO coated glass substrates: Synthesis and application to solar energy conversion Craig A. Grimes Department of Electrical Engineering Center for Solar Nanomaterials
More informationA. OTHER JUNCTIONS B. SEMICONDUCTOR HETEROJUNCTIONS -- MOLECULES AT INTERFACES: ORGANIC PHOTOVOLTAIC BULK HETEROJUNCTION DYE-SENSITIZED SOLAR CELL
A. OTHER JUNCTIONS B. SEMICONDUCTOR HETEROJUNCTIONS -- MOLECULES AT INTERFACES: ORGANIC PHOTOVOLTAIC BULK HETEROJUNCTION DYE-SENSITIZED SOLAR CELL March 24, 2015 The University of Toledo, Department of
More informationSupplementary Figure 1. Cross-section SEM image of the polymer scaffold perovskite film using MAI:PbI 2 =1:1 in DMF solvent on the FTO/glass
Supplementary Figure 1. Cross-section SEM image of the polymer scaffold perovskite film using MAI:PbI 2 =1:1 in DMF solvent on the FTO/glass substrate. Scale bar: 1 m. Supplementary Figure 2. Contact angle
More informationElectronic Supporting Information. Harnessing Molecular Photon Upconversion at Sub-Solar Irradiance Using Dual Sensitized Self-Assembled Trilayers
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 217 Electronic Supporting Information Harnessing Molecular Photon Upconversion
More informationHigh Performance Perovskite Solar Cells based on a PCBM:polystyrene blend electron transport layer
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 High Performance Perovskite Solar Cells based on a PCBM:polystyrene blend
More informationRole of Surface Chemistry on Charge Carrier Transport in Quantum Dot Solids
Role of Surface Chemistry on Charge Carrier Transport in Quantum Dot Solids Cherie R. Kagan, University of Pennsylvania in collaboration with the Murray group Density of Electronic States in Quantum Dot
More informationNanostructured materials for solar energy
Nanostructured materials for solar energy Water Splitting & Dye Solar Cells Journée Scientifique des Comices «Energie Solaire» du WARE 23 avril 2012 à Jambes Prof. Rudi Cloots, C. Henrist, Contributors:
More informationSolid State Dye Solar Cells: Development of Photoanode Architecture for Conversion Efficiency Improvement
Università degli Studi di Ferrara Solid State Dye Solar Cells: Development of Photoanode Architecture for Conversion Efficiency Improvement Internal supervisor: Vincenzo Guidi External supervisor: Giampiero
More informationDry Plasma Reduction to Supported Platinum Nanoparticles for Flexible Dye-sensitized. Solar Cells. Yuseong-Gu, Daejeon , Korea
Dry Plasma Reduction to Supported Platinum Nanoparticles for Flexible Dye-sensitized Solar Cells Van-Duong Dao a, Chinh Quoc Tran a, Seung-Hyeon Ko b, Ho-Suk Choi a * a Department of Chemical Engineering,
More information1. Depleted heterojunction solar cells. 2. Deposition of semiconductor layers with solution process. June 7, Yonghui Lee
1. Depleted heterojunction solar cells 2. Deposition of semiconductor layers with solution process June 7, 2016 Yonghui Lee Outline 1. Solar cells - P-N junction solar cell - Schottky barrier solar cell
More informationAxial anchoring designed silicon-porphyrin sensitizers for efficient
Supporting Information Axial anchoring designed silicon-porphyrin sensitizers for efficient dye-sensitized solar cells Jing Liu, a Xichuan Yang, a, * and Licheng Sun a, b, * a State Key Laboratory of Fine
More informationPhotovoltaic Enhancement Due to Surface-Plasmon Assisted Visible-Light. Absorption at the Inartificial Surface of Lead Zirconate-Titanate Film
Photovoltaic Enhancement Due to Surface-Plasmon Assisted Visible-Light Absorption at the Inartificial Surface of Lead Zirconate-Titanate Film Fengang Zheng, a,b, * Peng Zhang, a Xiaofeng Wang, a Wen Huang,
More informationSupporting Information
Supporting Information Oh et al. 10.1073/pnas.0811923106 SI Text Hysteresis of BPE-PTCDI MW-TFTs. Fig. S9 represents bidirectional transfer plots at V DS 100VinN 2 atmosphere for transistors constructed
More informationCHEM 167 FINAL EXAM MONDAY, MAY 2 9:45 11:45 A.M GILMAN HALL
PROF. JOHN VERKADE SPRING 2005 THIS EXAM CONSISTS OF 12 QUESTIONS ON 9 PAGES CHEM 167 HOUR EXAM IV APRIL 20, 2005 SEAT NO. NAME RECIT. INSTR. RECIT. SECT. GRADING PAGE Page 2 Page 3 Page 4 Page 5 Page
More informationCharge Extraction from Complex Morphologies in Bulk Heterojunctions. Michael L. Chabinyc Materials Department University of California, Santa Barbara
Charge Extraction from Complex Morphologies in Bulk Heterojunctions Michael L. Chabinyc Materials Department University of California, Santa Barbara OPVs Vs. Inorganic Thin Film Solar Cells Alta Devices
More informationSupporting Information
Supporting Information Low-Temperature Solution Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells Weijun Ke, Guojia Fang,* Qin Liu, Liangbin Xiong,
More informationEfficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response
Supporting information for Efficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response Jing Cao 1,*,, Congping Li 1,, Xudong
More informationOrganic LEDs part 8. Exciton Dynamics in Disordered Organic Thin Films. Handout on QD-LEDs: Coe et al., Nature 420, 800 (2002).
Organic LEDs part 8 Exciton Dynamics in Disordered Organic Thin Films Quantum Dot LEDs Handout on QD-LEDs: Coe et al., ature 420, 800 (2002). @ MIT April 29, 2003 Organic Optoelectronics - Lecture 20b
More informationSupplementary information
Supplementary information Neutral Colour Semitransparent Microstructured Perovskite Solar Cells Giles E. Eperon, Victor M. Burlakov, Alain Goriely and Henry J. Snaith 1. Controlling dewetting to achieve
More informationFlexible Organic Photovoltaics Employ laser produced metal nanoparticles into the absorption layer 1. An Introduction
Flexible Organic Photovoltaics Employ laser produced metal nanoparticles into the absorption layer 1. An Introduction Among the renewable energy sources that are called to satisfy the continuously increased
More informationDevelopment of active inks for organic photovoltaics: state-of-the-art and perspectives
Development of active inks for organic photovoltaics: state-of-the-art and perspectives Jörg Ackermann Centre Interdisciplinaire de Nanoscience de Marseille (CINAM) CNRS - UPR 3118, MARSEILLE - France
More informationSemiconductor quantum dots
Semiconductor quantum dots Quantum dots are spherical nanocrystals of semiconducting materials constituted from a few hundreds to a few thousands atoms, characterized by the quantum confinement of the
More informationSupporting information. Supramolecular Halogen Bond Passivation of Organometal-Halide Perovskite Solar Cells
Supporting information Supramolecular Halogen Bond Passivation of Organometal-Halide Perovskite Solar Cells Antonio Abate, a Michael Saliba, a Derek J. Hollman, a Samuel D. Stranks, a K. Wojciechowski,
More informationRecent Advances in Photoinduced Electron Transfer Processes of Fullerene-Based Molecular Assemblies and Nanocomposites
Molecules 2012, 17, 5816-5835; doi:10.3390/molecules17055816 Review OPEN ACCESS molecules ISSN 1420-3049 www.mdpi.com/journal/molecules Recent Advances in Photoinduced Electron Transfer Processes of Fullerene-Based
More informationOpto-electronic Characterization of Perovskite Thin Films & Solar Cells
Opto-electronic Characterization of Perovskite Thin Films & Solar Cells Arman Mahboubi Soufiani Supervisors: Prof. Martin Green Prof. Gavin Conibeer Dr. Anita Ho-Baillie Dr. Murad Tayebjee 22 nd June 2017
More informationNanoscience galore: hybrid and nanoscale photonics
Nanoscience galore: hybrid and nanoscale photonics Pavlos Lagoudakis SOLAB, 11 June 2013 Hybrid nanophotonics Nanostructures: light harvesting and light emitting devices 2 Hybrid nanophotonics Nanostructures:
More informationSupplementary Figure 1 XRD pattern of a defective TiO 2 thin film deposited on an FTO/glass substrate, along with an XRD pattern of bare FTO/glass
Supplementary Figure 1 XRD pattern of a defective TiO 2 thin film deposited on an FTO/glass substrate, along with an XRD pattern of bare FTO/glass and a reference pattern of anatase TiO 2 (JSPDS No.: 21-1272).
More informationSfb 658 Colloquium 11 May Part II. Introduction to Two-Photon-Photoemission (2PPE) Spectroscopy. Martin Wolf
Sfb 658 Colloquium 11 May 2006 Part II Introduction to Two-Photon-Photoemission (2PPE) Spectroscopy Martin Wolf Motivation: Electron transfer across interfaces key step for interfacial and surface dynamics
More informationPower Conversion Efficiency of a Dye-Sensitized Solar Cell
Power Conversion Efficiency of a Dye-Sensitized Solar Cell This laboratory session is aimed at bridging the gap between our knowledge of the natural photosynthetic reaction center and future solar technologies.
More informationBasic Limitations to Third generation PV performance
Basic Limitations to Third generation PV performance Pabitra K. Nayak Weizmann Institute of Science, Rehovot, Israel THANKS to my COLLEAGUES Lee Barnea and David Cahen. Weizmann Institute of Science Juan
More informationA. OTHER JUNCTIONS B. SEMICONDUCTOR HETEROJUNCTIONS -- MOLECULES AT INTERFACES: ORGANIC PHOTOVOLTAIC BULK HETEROJUNCTION DYE-SENSITIZED SOLAR CELL
A. OTHER JUNCTIONS B. SEMICONDUCTOR HETEROJUNCTIONS -- MOLECULES AT INTERFACES: ORGANIC PHOTOVOLTAIC BULK HETEROJUNCTION DYE-SENSITIZED SOLAR CELL February 9 and 14, 2012 The University of Toledo, Department
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2014 Electronic Supplementary Information Rational modifications on champion porphyrin
More informationSupporting Information
Supporting Information Materials Multiwalled carbon nanotubes (MWNTs, φ = 10-30 nm) were purchased from Nanotech Port Co. Ltd. (Shenzhen, China). Tetraethylorthosilicate (TEOS, >98 %), Triton X-100 and
More informatione - Galvanic Cell 1. Voltage Sources 1.1 Polymer Electrolyte Membrane (PEM) Fuel Cell
Galvanic cells convert different forms of energy (chemical fuel, sunlight, mechanical pressure, etc.) into electrical energy and heat. In this lecture, we are interested in some examples of galvanic cells.
More informationNanomaterials & Organic Electronics Group TEI of Crete
Nanomaterials & Organic Electronics Group TEI of Crete Dr. Emmanuel Kymakis Asc. Professor, Dept. of Electrical Engineering and Center of Advanced Materials & Photonics kymakis@staff.teicrete.gr http://nano.teicrete.gr/
More informationPhotostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion
Supplementary Information Photostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion Takahiko Ichiki, Yutaka Matsuo,* and Eiichi akamura* Department of
More informationSUPPLEMENTARY INFORMATION
Supplementary Information for Wideband dye-sensitized solar cells by efficient spin-forbidden transition Table of Contents 1. Theoretical section 1.1 Computation Methods 1.2 Molecular orbital of DX1 and
More informationSupplementary Figure S1. Verifying the CH 3 NH 3 PbI 3-x Cl x sensitized TiO 2 coating UV-vis spectrum of the solution obtained by dissolving the
Supplementary Figure S1. Verifying the CH 3 NH 3 PbI 3-x Cl x sensitized TiO 2 coating UV-vis spectrum of the solution obtained by dissolving the spiro-ometad from a perovskite-filled mesoporous TiO 2
More informationLecture 5 Junction characterisation
Lecture 5 Junction characterisation Jon Major October 2018 The PV research cycle Make cells Measure cells Despair Repeat 40 1.1% 4.9% Data Current density (ma/cm 2 ) 20 0-20 -1.0-0.5 0.0 0.5 1.0 Voltage
More informationAb-initio modeling of opto-electronic properties of molecules in solvents and in proximity to a semiconductor nanoparticle
Ab-initio modeling of opto-electronic properties of molecules in solvents and in proximity to a semiconductor nanoparticle Alain Delgado (a,b), Stefano Corni (b), Carlo Andrea Rozzi (b) Stefano Pittalis
More informationLight Extraction in OLED with Corrugated Substrates Franky So
Light Extraction in OLED with Corrugated Substrates Franky So Department of Materials Science and Engineering North Carolina State University Raleigh, NC 27695-7907 1 Where Did the Light Go? Modes Distribution
More informationThe following molecules are related:
Isolobal Analogy Inclusion of the ligand η-c 5 H 5 - which, as a donor of 3 π-electron pairs formally occupies 3 coordination sites, yields the analogies: The following molecules are related: 1 Isolobal
More informationNucleophilic Substitutions. Ionic liquids
ucleophilic Substitutions & Ionic liquids S 2 Reaction S 2 Substitution Reaction ucleophilic (electron rich) Bimolecular The rate depends on the concentration of both of the reactants S 2 Reaction Mechanism
More informationSelf-assembly of molecules on surfaces. Manuel Alcamí Departamento de Química Universidad Autónoma de Madrid
Self-assembly of molecules on surfaces Manuel Alcamí Departamento de Química Universidad Autónoma de Madrid Outline Outline Motivation Examples of molecules deposited on surfaces Graphene/Ru(0001) TQ /
More informationTriplet state diffusion in organometallic and organic semiconductors
Triplet state diffusion in organometallic and organic semiconductors Prof. Anna Köhler Experimental Physik II University of Bayreuth Germany From materials properties To device applications Organic semiconductors
More informationElectronic Supporting Information
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2015 Electronic Supporting Information Synthesis, Characterization and Photoinduced
More informationSupporting information
Supporting information Origin of Open-Circuit Voltage Loss in Polymer Solar Cells and Perovskite Solar Cells Hyung Do Kim, Nayu Yanagawa, Ai Shimazaki, Masaru Endo, Atsushi Wakamiya, Hideo Ohkita, *, Hiroaki
More informationBlock Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology
The 7 th Korea-U.S. Nano Forum Block Copolymer Based Hybrid Nanostructured Materials As Key Elements In Green Nanotechnology Dong Ha Kim Department of Chemistry and Nano Science, Ewha Womans University
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Supporting Information 1. Synthesis of perovskite materials CH 3 NH 3 I
More informationThe influence of materials work function on the open circuit voltage of plastic solar cells
Thin Solid Films 403 404 (00) 368 37 The influence of materials work function on the open circuit voltage of plastic solar cells a, a a a b b C.J. Brabec *, A. Cravino, D. Meissner, N.S. Sariciftci, M.T.
More informationth International Workshop on Computational Physics and Materials Science: Total Energy and Force Methods January 2011
2220-4 15th International Workshop on Computational Physics and Materials Science: Total Energy and Force Methods 13-15 January 2011 Computational study of optical and structural properties of an organic
More informationOrganic Solar Cells. Active material is much cheaper to produce than Si. Easily deposited as thin films over large (flexible) areas
Research activities on organic photovoltaics at the Center of Innovation and Research in MAterials and Polymers CIRMAP University of Mons Roberto Lazzaroni Journée scientifique des comices Energie solaire
More informationMini-project report. Organic Photovoltaics. Rob Raine
Mini-project report Organic Photovoltaics Rob Raine dtp11rdr@sheffield.ac.uk 10/2/2012 ASSIGNMENT COVER SHEET 2010/2011 A completed copy of this sheet MUST be attached to coursework contributing towards
More informationSupporting Information
Supporting Information Multilayered Perovskite Materials Based on Polymeric-Ammonium Cations for Stable and Large-Area Solar Cell Experimental Section Kai Yao, Xiaofeng Wang, Yun-xiang Xu, Fan Li, Lang
More informationSupporting Information
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information A minimal non-radiative recombination loss for efficient
More informationNew trends in organic materials based solar cells
ew trends in organic materials based solar cells Prof. Frank üesch Funktionspolymere Empa 8600 Dübendorf Semiconductors silicon germanium In organic single crystals and amophous powders Cu Se CI(G)S Silicon
More informationNovel Inorganic-Organic Perovskites for Solution Processed Photovoltaics. PIs: Mike McGehee and Hema Karunadasa
Novel Inorganic-Organic Perovskites for Solution Processed Photovoltaics PIs: Mike McGehee and Hema Karunadasa 1 Perovskite Solar Cells are Soaring Jul 2013 Grätzel, EPFL 15% Nov 2014 KRICT 20.1%! Seok,
More informationSupporting Information for. Metallonaphthalocyanines as Triplet Sensitizers for Near-Infrared. Photon Upconversion beyond 850 nm
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2015 Supporting Information for Metallonaphthalocyanines as Triplet Sensitizers for
More information5 questions, 3 points each, 15 points total possible. 26 Fe Cu Ni Co Pd Ag Ru 101.
Physical Chemistry II Lab CHEM 4644 spring 2017 final exam KEY 5 questions, 3 points each, 15 points total possible h = 6.626 10-34 J s c = 3.00 10 8 m/s 1 GHz = 10 9 s -1. B= h 8π 2 I ν= 1 2 π k μ 6 P
More informationElectronic Supplementary Information
Electronic Supplementary Information High Electrocatalytic Activity of Self-standing Hollow NiCo 2 S 4 Single Crystalline Nanorod Arrays towards Sulfide Redox Shuttles in Quantum Dot-sensitized Solar Cells
More information