Perovskite solar cells

Size: px
Start display at page:

Download "Perovskite solar cells"

Transcription

1 IMO - IMOMEC INSTITUUT VOOR MATERIAALONDERZOEK Perovskite solar cells dr. ir. Bert Conings bert.conings@uhasselt.be

2 state-of-the-art

3 outline! introduction! planar heterojunction perovskite solar cells! low-temperature processing! intrinsic stability! conclusions

4 introduction Published on Web 04/14/2009 Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells Akihiro Kojima, Kenjiro Teshima, Yasuo Shirai, and Tsutomu Miyasaka*,,, Graduate School of Arts and Sciences, The UniVersity of Tokyo, Komaba, Meguro-ku, Tokyo , Figure 1. (a) Crystal structures of perovskite compounds. (b) SEM image of particles of nanocrystalline CH 3 NH 3 PbBr 3 deposited on the TiO 2 surface. The arrow indicates a particle, and the scale bar shows 10 nm. η = 3.8%

5 introduction Cite this: Nanoscale, 2011, 3, % efficient perovskite quantum-dot-sensitized solar cell Jeong-Hyeok Im, Chang-Ryul Lee, Jin-Wook Lee, Sang-Won Park and Nam-Gyu Park* COMMUNICATION

6 introduction 2 : 591 DOI: /srep00591 Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Hui-Seon Kim 1, Chang-Ryul Lee 1, Jeong-Hyeok Im 1, Ki-Beom Lee 1, Thomas Moehl 2, Arianna Marchioro 2, Soo-Jin Moon 2, Robin Humphry-Baker 2, Jun-Ho Yum 2, Jacques E. Moser 2, Michael Grätzel 2 & Nam-Gyu Park 1

7 introduction C Ag Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Michael M. Lee et al. Science 338, 643 (2012); DOI: /science Spiro-OMeTAD Photoactive Layer FTO Perovskite Mesoporous Oxide Compact TiO 2 Glass A IPCE (%) B Current density (ma cm -2 ) η 10.9% Wavelength (nm) Voltage (V)

8 introduction c Counts Efficiency (%) Science 2012, 338, 643 Energy Environ. Sci. 2013, 6, 1739 Energy Environ. Sci. 2013, 6, 3249 Nat. Photonics 2013, 7, 486

9 porous layers; infiltration issues; fluctuation in results ambipolar perovskite planar heterojunction perovskite solar cells

10 planar heterojunction perovskite solar cells 100 C CH 3 NH 3 I PbCl 2 CH 3 NH 3 PbI 2 Cl

11 planar heterojunction perovskite solar cells B. Conings, L. Baeten, C. De Dobbelaere, J. D Haen, J. Manca, H.-G. Boyen, Adv. Mater. 2014, 26,

12 planar heterojunction perovskite solar cells absorbance / arb. units V / V λ / nm perovskite precursor concentration (wt%) efficiency (%) ± ± ± ± 0.5 J sc / ma cm % ± B. Conings, L. Baeten, C. De Dobbelaere, J. D Haen, J. Manca, H.-G. Boyen, Adv. Mater. 2014, 26,

13 low temperature processing TiO 2 layer typically requires ~500 C to sinter bottleneck towards large-scale / roll-to-roll processes necessity for low(er) temperature fabrication intensity particle diameter (nm) B. Conings, L. Baeten, T. Jacobs, R. Dera, J. D Haen, J. Manca, H.-G. Boyen, submitted

14 low temperature processing & performance improvement P3HT Ag CH 3 NH 3 PbI 2 Cl TiO 2 ITO glass 0 full device stack prepared <150 C V (V) J (ma/cm 2 ) J sc = 21.0 ma/cm 2 V oc = V FF = η = 13.6 % 20 B. Conings, L. Baeten, T. Jacobs, R. Dera, J. D Haen, J. Manca, H.-G. Boyen, submitted

15 intrinsic stability the$holy$trinity$of$photovoltaic$technology$ efficiency perovskite? lifetime cost

16 intrinsic stability - it will get hot up there perovskite is easily created at slightly elevated temperature we should be suspicious about its stability at slightly elevated temperature

17 intrinsic stability 85 C as in IEC test

18 intrinsic stability impact of atmosphere C$ O 2$ 24h$@$85 C$ N 2$ 24h$@$85 C$ air $

19 intrinsic stability - crystalline properties upon degradation pristine C in O 2 O θ ( ) pristine C in N 2 N θ ( ) PbI 2 2θ ( ) pristine C in ambient air θ ( )

20 intrinsic stability - Friday night experiment H 2 O

21 conclusions! perovskite solar cells possess many of the desirable features for next (4 th?) generation photovoltaics! high efficiencies with simple planar device structure! low temperature fabrication; towards roll-to-roll! questionable intrinsic stability! presence of Pb might or might not be a problem

22 acknowledgements! IMO/IMOMEC dr. Linny Baeten prof. Hans-Gerd Boyen prof. Jean Manca prof. Jan D Haen dr. Christopher de Dobbelaere prof. Marlies K. Van Bael dr. Anitha Ethirajan Lien D Olieslaeger Tanya Jacobs Rafael Dera Bart Ruttens Thijs Vandenreijt Johnny Baccus Bijzonder$Onderzoeksfonds$

23 Thank you for your attention! IMO - IMOMEC INSTITUUT VOOR MATERIAALONDERZOEK Institute for Materials Research Hasselt University Division IMOMEC, IMEC vzw Wetenschapspark Diepenbeek Belgium Tel Fax bert.conings@uhasselt.be

Electronic Supplementary Information. Benjia Dou,, Vanessa L. Pool, Michael F. Toney *,, Maikel F.A.M. van Hest *,

Electronic Supplementary Information. Benjia Dou,, Vanessa L. Pool, Michael F. Toney *,, Maikel F.A.M. van Hest *, Electronic Supplementary Information Radiative Thermal Annealing/in Situ X-ray Diffraction Study of Methylammonium Lead Triiodide: Effect of Antisolvent, Humidity, Annealing Temperature Profile, and Film

More information

Supporting Information. Zn 2 SnO 4 -based photoelectrodes for organolead halide perovskite solar cells

Supporting Information. Zn 2 SnO 4 -based photoelectrodes for organolead halide perovskite solar cells Supporting Information Zn 2 SnO 4 -based photoelectrodes for organolead halide perovskite solar cells Lee Seul Oh, 1,2, Dong Hoe Kim, 3, Jin-Ah Lee, 1 Seong Sik Shin, 3 Jin-Wook Lee, 4 Ik Jae Park, 1,3

More information

SUPPLEMENTARY INFORMATION

SUPPLEMENTARY INFORMATION Supplementary Information Efficient inorganic-organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors Jin Hyuck Heo, Sang Hyuk Im, Jun Hong Noh, Tarak N.

More information

Severe Morphological Deformation of Spiro- Temperature

Severe Morphological Deformation of Spiro- Temperature Supplementary Information Severe Morphological Deformation of Spiro- OMeTAD in (CH 3 NH 3 )PbI 3 Solar Cells at High Temperature Ajay Kumar Jena, Masashi Ikegami, Tsutomu Miyasaka* Toin University of Yokohama,

More information

Organo-metal halide perovskite-based solar cells with CuSCN as inorganic hole selective contact

Organo-metal halide perovskite-based solar cells with CuSCN as inorganic hole selective contact Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 214 Organo-metal halide perovskite-based solar cells with CuSCN as inorganic

More information

Materials Chemistry A

Materials Chemistry A Journal of Materials Chemistry A COMMUNICATION View Article Online View Journal View Issue Cite this: J. Mater. Chem. A, 2015,3, 19674 Received 7th August 2015 Accepted 29th August 2015 Hydrochloric acid

More information

Capturing Energy from the Sun. Solar Cells Solar Thermal Solar Fuels Bioenergy

Capturing Energy from the Sun. Solar Cells Solar Thermal Solar Fuels Bioenergy Capturing Energy from the Sun Solar Cells Solar Thermal Solar Fuels Bioenergy Installed PV Cost Breakdown a Globally, module prices are between $0.60-0.90/W depending on tariffs In the US, non-module costs

More information

1. Depleted heterojunction solar cells. 2. Deposition of semiconductor layers with solution process. June 7, Yonghui Lee

1. Depleted heterojunction solar cells. 2. Deposition of semiconductor layers with solution process. June 7, Yonghui Lee 1. Depleted heterojunction solar cells 2. Deposition of semiconductor layers with solution process June 7, 2016 Yonghui Lee Outline 1. Solar cells - P-N junction solar cell - Schottky barrier solar cell

More information

Supplementary Figure 1 XRD pattern of a defective TiO 2 thin film deposited on an FTO/glass substrate, along with an XRD pattern of bare FTO/glass

Supplementary Figure 1 XRD pattern of a defective TiO 2 thin film deposited on an FTO/glass substrate, along with an XRD pattern of bare FTO/glass Supplementary Figure 1 XRD pattern of a defective TiO 2 thin film deposited on an FTO/glass substrate, along with an XRD pattern of bare FTO/glass and a reference pattern of anatase TiO 2 (JSPDS No.: 21-1272).

More information

Supplementary Figure 1. Film thickness measurement. (a) AFM images of the perovskite

Supplementary Figure 1. Film thickness measurement. (a) AFM images of the perovskite Supplementary Figure 1. Film thickness measurement. (a) AFM images of the perovskite film with a straight edge which was created by scratching with a tweezer. (b) Profile along the line highlighted in

More information

Stability of Organic Cations in Solution-Processed CH3NH3PbI3 Perovskites: Formation of Modified Surface Layers

Stability of Organic Cations in Solution-Processed CH3NH3PbI3 Perovskites: Formation of Modified Surface Layers Stability of Organic Cations in Solution-Processed CH3NH3PbI3 Perovskites: Formation of Modified Surface Layers A. Calloni,*, A. Abate, G. Bussetti, G. Berti, R. Yivlialin, F. Ciccacci, and L. Duò Dipartimento

More information

Supplementary Figure 1. Cross-section SEM image of the polymer scaffold perovskite film using MAI:PbI 2 =1:1 in DMF solvent on the FTO/glass

Supplementary Figure 1. Cross-section SEM image of the polymer scaffold perovskite film using MAI:PbI 2 =1:1 in DMF solvent on the FTO/glass Supplementary Figure 1. Cross-section SEM image of the polymer scaffold perovskite film using MAI:PbI 2 =1:1 in DMF solvent on the FTO/glass substrate. Scale bar: 1 m. Supplementary Figure 2. Contact angle

More information

Supplementary information

Supplementary information Supplementary information Neutral Colour Semitransparent Microstructured Perovskite Solar Cells Giles E. Eperon, Victor M. Burlakov, Alain Goriely and Henry J. Snaith 1. Controlling dewetting to achieve

More information

A Novel Single-Step Growth Process for the Deposition of CH 3 NH 3 PbI 3-x Cl x Perovskite Films from CH 3 NH 3 Cl and PbI 2 Precursors

A Novel Single-Step Growth Process for the Deposition of CH 3 NH 3 PbI 3-x Cl x Perovskite Films from CH 3 NH 3 Cl and PbI 2 Precursors Journal of Materials Science and Engineering A 6 (9-10) (2016) 233-242 doi: 10.17265/2161-6213/2016.9-10.001 D DAVID PUBLISHING A Novel Single-Step Growth Process for the Deposition of CH 3 NH 3 PbI 3-x

More information

Supplementary information for Understanding how excess lead iodide precursor improves halide perovskite solar cell performance

Supplementary information for Understanding how excess lead iodide precursor improves halide perovskite solar cell performance Supplementary information for Understanding how excess lead iodide precursor improves halide perovskite solar cell performance Byung-wook Park et. al. 1 (a) (b) Film Thickness (nm) type Au ~ 80 PTAA 20-50

More information

Yixin Zhao and Kai Zhu*

Yixin Zhao and Kai Zhu* Supporting Information CH 3 NH 3 Cl-Assisted One-Step Solution Growth of CH 3 NH 3 PbI 3 : Structure, Charge- Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells Yixin Zhao and Kai

More information

School of Advanced Materials Science & Engineering, Sungkyunkwan University, Suwon , Korea.

School of Advanced Materials Science & Engineering, Sungkyunkwan University, Suwon , Korea. Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary information (ESI) Highly Efficient and Bending Durable

More information

Novel Inorganic-Organic Perovskites for Solution Processed Photovoltaics. PIs: Mike McGehee and Hema Karunadasa

Novel Inorganic-Organic Perovskites for Solution Processed Photovoltaics. PIs: Mike McGehee and Hema Karunadasa Novel Inorganic-Organic Perovskites for Solution Processed Photovoltaics PIs: Mike McGehee and Hema Karunadasa 1 Perovskite Solar Cells are Soaring Jul 2013 Grätzel, EPFL 15% Nov 2014 KRICT 20.1%! Seok,

More information

Adjustment of Conduction Band Edge of. Through TiCl 4 Treatment

Adjustment of Conduction Band Edge of. Through TiCl 4 Treatment Supporting Information Adjustment of Conduction Band Edge of Compact TiO 2 Layer in Perovskite Solar Cells Through TiCl 4 Treatment Takurou N. Murakami, *, Tetsuhiko Miyadera, Takashi Funaki, Ludmila Cojocaru,

More information

A One-Step Low Temperature Processing Route for Organolead Halide Perovskite Solar Cells

A One-Step Low Temperature Processing Route for Organolead Halide Perovskite Solar Cells Electronic Supplementary Information A One-Step Low Temperature Processing Route for Organolead Halide Perovskite Solar Cells Matthew J. Carnie, a Cecile Charbonneau, a Matthew L. Davies, b Joel Troughton,

More information

UV Degradation and Recovery of Perovskite Solar Cells

UV Degradation and Recovery of Perovskite Solar Cells Supplementary Information UV Degradation and Recovery of Perovskite Solar Cells Sang-Won Lee 1, Seongtak Kim 1, Soohyun Bae 1, Kyungjin Cho 1, Taewon Chung 1, Laura E. Mundt 2, Seunghun Lee 1,2, Sungeun

More information

Laser Crystallization of Organic-Inorganic Hybrid

Laser Crystallization of Organic-Inorganic Hybrid Supporting information Laser Crystallization of Organic-Inorganic Hybrid Perovskite Solar Cells Taewoo Jeon, Hyeong Min Jin, Seung Hyun Lee, Ju Min Lee, Hyung Il Park, Mi Kyung Kim, Keon Jae Lee, Byungha

More information

Opto-electronic Characterization of Perovskite Thin Films & Solar Cells

Opto-electronic Characterization of Perovskite Thin Films & Solar Cells Opto-electronic Characterization of Perovskite Thin Films & Solar Cells Arman Mahboubi Soufiani Supervisors: Prof. Martin Green Prof. Gavin Conibeer Dr. Anita Ho-Baillie Dr. Murad Tayebjee 22 nd June 2017

More information

Supplementary Figure S1. Verifying the CH 3 NH 3 PbI 3-x Cl x sensitized TiO 2 coating UV-vis spectrum of the solution obtained by dissolving the

Supplementary Figure S1. Verifying the CH 3 NH 3 PbI 3-x Cl x sensitized TiO 2 coating UV-vis spectrum of the solution obtained by dissolving the Supplementary Figure S1. Verifying the CH 3 NH 3 PbI 3-x Cl x sensitized TiO 2 coating UV-vis spectrum of the solution obtained by dissolving the spiro-ometad from a perovskite-filled mesoporous TiO 2

More information

SUPPORTING INFORMATION

SUPPORTING INFORMATION Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 SUPPORTING INFORMATION Efficient Fully-Vacuum-Processed Perovskite Solar

More information

SUPPLEMENTARY INFORMATION

SUPPLEMENTARY INFORMATION Graded bandgap perovskite solar cells Onur Ergen, 1,3,4 S.Matt Gilbert 1, 3,4,,Thang Pham 1, 3,4,Sally J. Turner, 1,2,4, Mark Tian Zhi Tan 1, Marcus A. Worsley 1, 3,4 and Alex Zettl 1 Department of Physics,

More information

Fabrication and Properties of High-Efficiency Perovskite/PCBM Organic Solar Cells

Fabrication and Properties of High-Efficiency Perovskite/PCBM Organic Solar Cells Chen et al. Nanoscale Research Letters (2015) 10:312 DOI 10.1186/s11671-015-1020-2 NANO EXPRESS Fabrication and Properties of High-Efficiency Perovskite/PCBM Organic Solar Cells Lung-Chien Chen 1*, Jhih-Chyi

More information

Tailoring of Electron Collecting Oxide Nano-Particulate Layer for Flexible Perovskite Solar Cells. Gajeong-Ro, Yuseong-Gu, Daejeon , Korea

Tailoring of Electron Collecting Oxide Nano-Particulate Layer for Flexible Perovskite Solar Cells. Gajeong-Ro, Yuseong-Gu, Daejeon , Korea Supporting Information Tailoring of Electron Collecting Oxide Nano-Particulate Layer for Flexible Perovskite Solar Cells Seong Sik Shin 1,2,, Woon Seok Yang 1,3,, Eun Joo Yeom 1,4, Seon Joo Lee 1, Nam

More information

The Current Status of Perovskite Solar Cell Research at UCLA

The Current Status of Perovskite Solar Cell Research at UCLA The Current Status of Perovskite Solar Cell Research at UCLA Lijian Zuo, Sanghoon Bae, Lei Meng, Yaowen Li, and Yang Yang* Department of Materials Science and Engineering University of California, Los

More information

Mesoscopic Perovskite Solar Cells and Modules

Mesoscopic Perovskite Solar Cells and Modules Proceedings of the 14th IEEE International Conference on Nanotechnology Toronto, Canada, August 18-1, 14 Mesoscopic Perovskite Solar Cells and Modules A. Di Carlo, Member, IEEE, F. Matteocci, S. Razza,

More information

Supporting Information

Supporting Information Supporting Information Low-Temperature Solution Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells Weijun Ke, Guojia Fang,* Qin Liu, Liangbin Xiong,

More information

Materials Chemistry A

Materials Chemistry A Journal of Materials Chemistry A PAPER Cite this: DOI: 10.1039/c5ta03990h View Article Online View Journal Thermodynamic regulation of CH 3 NH 3 PbI 3 crystal growth and its effect on photovoltaic performance

More information

High efficiency MAPbI3-xClx perovskite solar cell via interfacial passivation

High efficiency MAPbI3-xClx perovskite solar cell via interfacial passivation Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Supporting Information High efficiency MAPbI3-xClx perovskite solar cell via interfacial passivation

More information

Supplementary Figure 1 Scheme image of GIXD set-up. The scheme image of slot die

Supplementary Figure 1 Scheme image of GIXD set-up. The scheme image of slot die Supplementary Figure 1 Scheme image of GIXD set-up. The scheme image of slot die printing system combined with grazing incidence X-ray diffraction (GIXD) set-up. 1 Supplementary Figure 2 2D GIXD images

More information

Nanoscale Advances COMMUNICATION. Polystyrene enhanced crystallization of perovskites towards high performance solar cells. Introduction.

Nanoscale Advances COMMUNICATION. Polystyrene enhanced crystallization of perovskites towards high performance solar cells. Introduction. Nanoscale Advances COMMUNICATION Cite this: Nanoscale Adv., 2019,1, 76 Received 20th June 2018 Accepted 16th August 2018 DOI: 10.1039/c8na00052b rsc.li/nanoscale-advances Polystyrene enhanced crystallization

More information

Solid State Dye Solar Cells: Development of Photoanode Architecture for Conversion Efficiency Improvement

Solid State Dye Solar Cells: Development of Photoanode Architecture for Conversion Efficiency Improvement Università degli Studi di Ferrara Solid State Dye Solar Cells: Development of Photoanode Architecture for Conversion Efficiency Improvement Internal supervisor: Vincenzo Guidi External supervisor: Giampiero

More information

Supporting Information. Monolithic perovskite-homojunction silicon tandem solar cell with over 22% efficiency

Supporting Information. Monolithic perovskite-homojunction silicon tandem solar cell with over 22% efficiency Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information (ESI) for Energy & Environmental Science

More information

Direct Observation of an Inhomogeneous Chlorine Distribution in CH 3 NH 3 PbI 3-x Cl x Layers: Surface Depletion and Interface Enrichment

Direct Observation of an Inhomogeneous Chlorine Distribution in CH 3 NH 3 PbI 3-x Cl x Layers: Surface Depletion and Interface Enrichment Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2015 Direct Observation of an Inhomogeneous Chlorine Distribution in CH 3 NH 3

More information

Supporting Online Material for

Supporting Online Material for www.sciencemag.org/cgi/content/full/science.1228604/dc1 Supporting Online Material for Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Michael M. Lee, Joël Teuscher,

More information

Supporting Information

Supporting Information Supporting Information ~800-nm-Thick Pinhole-Free Perovskite Films via Facile Solvent Retarding Process for Efficient Planar Solar Cells Zhongcheng Yuan,, Yingguo Yang, Zhongwei Wu, Sai Bai, Weidong Xu,

More information

All-Inorganic Perovskite Solar Cells

All-Inorganic Perovskite Solar Cells Supporting Information for: All-Inorganic Perovskite Solar Cells Jia Liang, Caixing Wang, Yanrong Wang, Zhaoran Xu, Zhipeng Lu, Yue Ma, Hongfei Zhu, Yi Hu, Chengcan Xiao, Xu Yi, Guoyin Zhu, Hongling Lv,

More information

Efficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response

Efficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response Supporting information for Efficient Grain Boundary Suture by Low-cost Tetra-ammonium Zinc Phthalocyanine for Stable Perovskite Solar Cells with Expanded Photo-response Jing Cao 1,*,, Congping Li 1,, Xudong

More information

Supporting Information

Supporting Information Copyright WILEY-VCH Verlag GmbH & Co. KGaA, 69469 Weinheim, Germany, 2018. Supporting Information for Adv. Mater., DOI: 10.1002/adma.201706023 Effective Carrier-Concentration Tuning of SnO 2 Quantum Dot

More information

P hotovoltaic has been realized as a suitable generating electrical power by converting solar radiation into

P hotovoltaic has been realized as a suitable generating electrical power by converting solar radiation into OPEN SUBJECT AREAS: NANOPHOTONICS AND PLASMONICS RENEWABLE ENERGY SOLAR CELLS SOLAR ENERGY AND PHOTOVOLTAIC TECHNOLOGY Full Printable Processed Mesoscopic CH 3 NH 3 PbI 3 /TiO 2 Heterojunction Solar Cells

More information

Hole-Conductor-Free, Metal-Electrode-Free TiO 2 /CH 3 NH 3 PbI 3 Heterojunction Solar Cells Based on a Low-Temperature Carbon Electrode

Hole-Conductor-Free, Metal-Electrode-Free TiO 2 /CH 3 NH 3 PbI 3 Heterojunction Solar Cells Based on a Low-Temperature Carbon Electrode pubs.acs.org/jpcl Hole-Conductor-Free, Metal-Electrode-Free TiO 2 /CH 3 NH 3 PbI 3 Heterojunction Solar Cells Based on a Low-Temperature Carbon Electrode Huawei Zhou, Yantao Shi,*, Qingshun Dong, Hong

More information

Rapid progress in conversion efficiency of organic-lead

Rapid progress in conversion efficiency of organic-lead Letter pubs.acs.org/jpcl Emergence of Hysteresis and Transient Ferroelectric Response in Organo-Lead Halide Perovskite Solar Cells Hsin-Wei Chen, Nobuya Sakai, Masashi Ikegami, and Tsutomu Miyasaka*, Graduate

More information

Supporting Information

Supporting Information Supporting Information Controlled Crystal Grain Growth in Mixed Cation-Halide Perovskite by Evaporated Solvent Vapor Recycling Method for High Efficiency Solar Cells Youhei Numata,*, Atsushi Kogo, Yosuke

More information

Supporting Information

Supporting Information Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 7 Supporting Information Interpretation and Evolution of Open- Circuit Voltage,

More information

Hole Conductor Free Perovskitebased

Hole Conductor Free Perovskitebased SPRINGER BRIEFS IN APPLIED SCIENCES AND TECHNOLOGY Lioz Etgar Hole Conductor Free Perovskitebased Solar Cells 123 SpringerBriefs in Applied Sciences and Technology More information about this series at

More information

Supplementary Materials for

Supplementary Materials for advances.sciencemag.org/cgi/content/full/3/8/e1716/dc1 Supplementary Materials for Polymer-modified halide perovskite films for efficient and stable planar heterojunction solar cells Lijian Zuo, Hexia

More information

Nanochannel-Assisted Perovskite Nanowires: Growth Mechanisms. to Photodetector Applications

Nanochannel-Assisted Perovskite Nanowires: Growth Mechanisms. to Photodetector Applications Supplementary Information: Nanochannel-Assisted Perovskite Nanowires: Growth Mechanisms to Photodetector Applications Qitao Zhou, Jun Gyu Park, Riming Nie, Ashish Kumar Thokchom, Dogyeong Ha, Jing Pan,

More information

The Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells

The Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells SUPPORTING INFORMATION The Role of the Selective Contacts in the Performance of Lead Halide Perovskite Solar Cells Emilio J. Juarez-Perez, 1 Michael Wuβler, 1, 2 Francisco Fabregat-Santiago, 1 Kerstin

More information

Supplementary Information

Supplementary Information Supplementary Information How Important is the Organic Part of the Lead Halide Perovskite Photovoltaic Cells? Efficient CsPbBr 3 Cells Michael Kulbak, David Cahen* and Gary Hodes* Dept. of Materials and

More information

LETTER. Efficient planar heterojunction perovskite solar cells by vapour deposition

LETTER. Efficient planar heterojunction perovskite solar cells by vapour deposition LETTER doi:10.1038/nature12509 Efficient planar heterojunction perovskite solar cells by vapour deposition Mingzhen Liu 1, Michael B. Johnston 1 & Henry J. Snaith 1 Many different photovoltaic technologies

More information

Cho Fai Jonathan Lau, Xiaofan Deng, Qingshan Ma, Jianghui Zheng, Jae S. Yun, Martin A.

Cho Fai Jonathan Lau, Xiaofan Deng, Qingshan Ma, Jianghui Zheng, Jae S. Yun, Martin A. Supporting Information CsPbIBr 2 Perovskite Solar Cell by Spray Assisted Deposition Cho Fai Jonathan Lau, Xiaofan Deng, Qingshan Ma, Jianghui Zheng, Jae S. Yun, Martin A. Green, Shujuan Huang, Anita W.

More information

Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells

Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells pubs.acs.org/nanolett Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells Qi Chen,,, Huanping Zhou,*,,, Tze-Bin Song,, Song Luo,, Ziruo Hong, Hsin-Sheng

More information

Supporting Information

Supporting Information Supporting Information A High Voltage Organic-Inorganic Hybrid Photovoltaic Cell Sensitized with Metal-ligand Interfacial Complexes Ayumi Ishii and Tsutomu Miyasaka* Graduate School of Engineering, Toin

More information

Achieving high-performance planar perovskite solar cells with

Achieving high-performance planar perovskite solar cells with Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2016 Supporting Information for Achieving high-performance planar perovskite

More information

Mesoporous SnO 2 Single Crystals as an Effective Electron Collector for Perovskite Solar Cells

Mesoporous SnO 2 Single Crystals as an Effective Electron Collector for Perovskite Solar Cells Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2015 Mesoporous SnO 2 Single Crystals as an Effective Electron Collector for Perovskite

More information

Title of file for HTML: Supplementary Information Description: Supplementary Figures and Supplementary References

Title of file for HTML: Supplementary Information Description: Supplementary Figures and Supplementary References Title of file for HTML: Supplementary Information Description: Supplementary Figures and Supplementary References Supplementary Figure 1. SEM images of perovskite single-crystal patterned thin film with

More information

Hole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode

Hole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode Supporting information For Nano Letters Hole Selective NiO Contact for Efficient Perovskite Solar Cells with Carbon Electrode Xiaobao Xu,,, Zonghao Liu,, Zhixiang Zuo, Meng Zhang, Zhixin Zhao, Yan Shen,

More information

Fabrication and Characterization of a Perovskite-Type Solar Cell with a Substrate Size of 70 mm

Fabrication and Characterization of a Perovskite-Type Solar Cell with a Substrate Size of 70 mm Coatings 2015, 5, 646-655; doi:10.3390/coatings5040646 Article OPEN ACCESS coatings ISSN 2079-6412 www.mdpi.com/journal/coatings Fabrication and Characterization of a Perovskite-Type Solar Cell with a

More information

Atmospheric pressure Plasma Enhanced CVD for large area deposition of TiO 2-x electron transport layers for PV. Heather M. Yates

Atmospheric pressure Plasma Enhanced CVD for large area deposition of TiO 2-x electron transport layers for PV. Heather M. Yates Atmospheric pressure Plasma Enhanced CVD for large area deposition of TiO 2-x electron transport layers for PV Heather M. Yates Why the interest? Perovskite solar cells have shown considerable promise

More information

Supporting Information

Supporting Information Supporting Information Modulation of PEDOT:PSS ph for Efficient Inverted Perovskite Solar Cells with Reduced Potential Loss and Enhanced Stability Qin Wang 1,2, Chu-Chen Chueh 1, Morteza Eslamian 2 * and

More information

Recently, hybrid metal halide perovskites, such as

Recently, hybrid metal halide perovskites, such as pubs.acs.org/nanolett Integrated Perovskite/Bulk-Heterojunction toward Efficient Solar Cells Yongsheng Liu, Ziruo Hong, Qi Chen, Weihsuan Chang, Huanping Zhou, Tze-Bin Song, Eric Young, Yang (Michael)

More information

During the past two years, the world has witnessed rapid

During the past two years, the world has witnessed rapid Communication pubs.acs.org/jacs Efficient Planar Perovskite Solar Cells Based on 1.8 ev Band Gap CH 3 NH 3 PbI 2 Br Nanosheets via Thermal Decomposition Yixin Zhao*, and Kai Zhu*, School of Environmental

More information

Enhancing Perovskite Solar Cell Performance by Interface Engineering Using CH 3 NH 3 PbBr 0.9 I 2.1 Quantum Dots

Enhancing Perovskite Solar Cell Performance by Interface Engineering Using CH 3 NH 3 PbBr 0.9 I 2.1 Quantum Dots Supporting Information for Enhancing Perovskite Solar Cell Performance by Interface Engineering Using CH 3 NH 3 PbBr 0.9 I 2.1 Quantum Dots Mingyang Cha,, Peimei Da,, Jun Wang, Weiyi Wang, Zhanghai Chen,

More information

Supporting Information for: Iodine Migration and Degradation of Perovskite Solar Cells Enhanced by. Metallic Electrodes

Supporting Information for: Iodine Migration and Degradation of Perovskite Solar Cells Enhanced by. Metallic Electrodes Supporting Information for: Iodine Migration and Degradation of Perovskite Solar Cells Enhanced by Metallic Electrodes Cristina Besleaga +, Laura Elena Abramiuc +#, Viorica Stancu +, Andrei Gabriel Tomulescu

More information

Optical Description of Mesostructured Organic- Inorganic Halide Perovskite Solar Cells

Optical Description of Mesostructured Organic- Inorganic Halide Perovskite Solar Cells Optical Description of Mesostructured Organic- Inorganic Halide Perovskite Solar Cells Miguel Anaya 1, Gabriel Lozano 1, Mauricio E. Calvo 1, Wei Zhang 2, Michael B. Johnston 2, Henry J. Snaith 2, and

More information

Surface engineering of perovskite films for efficient solar cells

Surface engineering of perovskite films for efficient solar cells www.nature.com/scientificreports Received: 20 June 2017 Accepted: 18 October 2017 Published: xx xx xxxx OPEN Surface engineering of perovskite films for efficient solar cells Jin-Feng Wang, Lei Zhu, Ben-Guang

More information

Yixin Zhao and Kai Zhu* 1. INTRODUCTION 2. EXPERIMENTAL SECTION

Yixin Zhao and Kai Zhu* 1. INTRODUCTION 2. EXPERIMENTAL SECTION pubs.acs.org/jpcc CH 3 NH 3 Cl-Assisted One-Step Solution Growth of CH 3 NH 3 PbI 3 : Structure, Charge-Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells Yixin Zhao and Kai Zhu* Chemical

More information

Supporting information

Supporting information Supporting information Spontaneous Passivation of Hybrid Perovskite by Sodium Ions from Glass Substrates - Mysterious Enhancement of Device Efficiency Overtime Discovered Cheng Bi, Xiaopeng Zheng, Bo Chen,

More information

Solar energy is the largest noncarbon-based energy source.

Solar energy is the largest noncarbon-based energy source. pubs.acs.org/nanolett Chemical Management for Colorful, Efficient, and Stable Inorganic Organic Hybrid Nanostructured Solar Cells Jun Hong Noh, Sang Hyuk Im, Jin Hyuck Heo, Tarak N. Mandal, and Sang Il

More information

Efficient and Uniform Planar-Type Perovskite Solar Cells by Simple Sequential Vacuum Deposition

Efficient and Uniform Planar-Type Perovskite Solar Cells by Simple Sequential Vacuum Deposition www.materialsviews.com Efficient and Uniform Planar-Type Perovskite Solar Cells by Simple Sequential Vacuum Deposition Chang-Wen Chen, Hao-Wei Kang, Sheng-Yi Hsiao, Po-Fan Yang, Kai-Ming Chiang, and Hao-Wu

More information

Optimized Organometal Halide Perovskite Planar Hybrid Solar Cells via Control of Solvent Evaporation Rate

Optimized Organometal Halide Perovskite Planar Hybrid Solar Cells via Control of Solvent Evaporation Rate pubs.acs.org/jpcc Optimized Organometal Halide Perovskite Planar Hybrid Solar Cells via Control of Solvent Evaporation Rate Rira Kang, Jeung-Eun Kim, Jun-Seok Yeo, Sehyun Lee, Ye-Jin Jeon, and Dong-Yu

More information

and Technology, Luoyu Road 1037, Wuhan, , P. R. China. *Corresponding author. ciac - Shanghai P. R.

and Technology, Luoyu Road 1037, Wuhan, , P. R. China. *Corresponding author.   ciac - Shanghai P. R. Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry Supplementary Information For Journal of Materials Chemistry A Perovskite- @BiVO

More information

Conventional dye-sensitized solar cells consist of liquid. CH 3 NH 3 Sn x Pb (1 x) I 3 Perovskite Solar Cells Covering up to 1060 nm

Conventional dye-sensitized solar cells consist of liquid. CH 3 NH 3 Sn x Pb (1 x) I 3 Perovskite Solar Cells Covering up to 1060 nm pubs.acs.org/jpcl CH 3 NH 3 Sn x Pb (1 x) I 3 Perovskite Solar Cells Covering up to 1060 nm Yuhei Ogomi,*, Atsushi Morita, Syota Tsukamoto, Takahiro Saitho, Naotaka Fujikawa, Qing Shen,, Taro Toyoda,,

More information

Glass Texturing Affects Optical Properties of Perovskite Solar Cells: Comparison Study between Mesoscopic and Planar Structure

Glass Texturing Affects Optical Properties of Perovskite Solar Cells: Comparison Study between Mesoscopic and Planar Structure 367 A publication of CHEMICAL ENGINEERING TRANSACTIONS VOL. 52, 2016 Guest Editors: Petar Sabev Varbanov, Peng-Yen Liew, Jun-Yow Yong, Jiří Jaromír Klemeš, Hon Loong Lam Copyright 2016, AIDIC Servizi S.r.l.,

More information

Materials Chemistry A

Materials Chemistry A Journal of Materials Chemistry A PAPER Cite this: J. Mater. Chem. A, 2014,2, 17115 View Article Online View Journal View Issue Efficient hole-conductor-free, fully printable mesoscopic perovskite solar

More information

Latest achievements in the field of dye sensitized and perovskite solar cells Anders Hagfeldt Laboratory of Photomolecular Sciences (LSPM)

Latest achievements in the field of dye sensitized and perovskite solar cells Anders Hagfeldt Laboratory of Photomolecular Sciences (LSPM) 15 e Congrès photovoltaïque national, Lausanne, March 23, 2017 Latest achievements in the field of dye sensitized and perovskite solar cells Anders Hagfeldt Laboratory of Photomolecular Sciences (LSPM)

More information

POROUS PEROVSKITE NANOCRYSTALS FOR PHOTOVOLTAIC APPLICATION

POROUS PEROVSKITE NANOCRYSTALS FOR PHOTOVOLTAIC APPLICATION POROUS PEROVSKITE NANOCRYSTALS FOR PHOTOVOLTAIC APPLICATION, PhD student DIPARTIMENTO DI SCIENZE FISICHE E TECNOLOGIA DELLA MATERIA CNR-IOM - Istituto Officina dei Materiali Headquarters (Trieste, TASC)

More information

Low-temperature-processed inorganic perovskite solar cells via solvent engineering with enhanced mass transport

Low-temperature-processed inorganic perovskite solar cells via solvent engineering with enhanced mass transport Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 1 Low-temperature-processed inorganic perovskite solar cells via solvent engineering

More information

Supplementary Figure S1. Hole collection layer photovoltaic performance in perovskite solar cells. Current voltage curves measured under AM1.

Supplementary Figure S1. Hole collection layer photovoltaic performance in perovskite solar cells. Current voltage curves measured under AM1. Supplementary Figure S1. Hole collection layer photovoltaic performance in perovskite solar cells. Current voltage curves measured under AM1.5 simulated sun light at 100mWcm -2 equivalent irradiance for

More information

Supplementary Information

Supplementary Information Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Supplementary Information Enhanced Charge Collection with Passivation of

More information

Deliverable D1.3 Demonstration of patterning processes allowing to

Deliverable D1.3 Demonstration of patterning processes allowing to D.3 H2020-LCE-205- CHEOPS Production technology to achieve low Cost and Highly Efficient photovoltaic Perovskite Solar cells Deliverable D.3 WP Perovskite single junction development Authors: Soo-Jin Moon

More information

Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiO x Hole Contacts

Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiO x Hole Contacts Highly Efficient Flexible Perovskite Solar Cells Using Solution-Derived NiO x Hole Contacts Xingtian Yin 1 *, Peng Chen 1, Meidan Que 1, Yonglei Xing 1, Wenxiu Que 1 *, Chunming Niu 2, Jinyou Shao 3 1

More information

Supporting information: Optical analysis of

Supporting information: Optical analysis of Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2016 Supporting information: Optical analysis of CH 3 NH 3 Sn x Pb 1-x I 3 absorbers:

More information

Supporting information. Supramolecular Halogen Bond Passivation of Organometal-Halide Perovskite Solar Cells

Supporting information. Supramolecular Halogen Bond Passivation of Organometal-Halide Perovskite Solar Cells Supporting information Supramolecular Halogen Bond Passivation of Organometal-Halide Perovskite Solar Cells Antonio Abate, a Michael Saliba, a Derek J. Hollman, a Samuel D. Stranks, a K. Wojciechowski,

More information

Supporting Information. for

Supporting Information. for Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2014 Supporting Information for Highly Efficient Perovskite Solar Cells Based

More information

Enhancing Stability of Perovskite Solar Cells to Moisture by the Facile Hydrophobic Passivation

Enhancing Stability of Perovskite Solar Cells to Moisture by the Facile Hydrophobic Passivation Research Article www.acsami.org Enhancing Stability of Perovskite Solar Cells to Moisture by the Facile Hydrophobic Passivation Insung Hwang, Inyoung Jeong,, Jinwoo Lee, Min Jae Ko,, and Kijung Yong*,

More information

Perovskite solar cells on metal substrate with high efficiency

Perovskite solar cells on metal substrate with high efficiency Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information (ESI) for Perovskite solar cells on metal

More information

Department of Chemical Engineering, Pohang University of Science and Technology, San 31, Nam-gu, Pohang, Gyeongbuk , Republic of Korea.

Department of Chemical Engineering, Pohang University of Science and Technology, San 31, Nam-gu, Pohang, Gyeongbuk , Republic of Korea. Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information Green-solvent processable semiconducting polymers

More information

Highly Efficient Flexible Solar Cells Based on Room-Temperature

Highly Efficient Flexible Solar Cells Based on Room-Temperature Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry Please do 2018 not adjust margins Supporting Information Highly Efficient Flexible

More information

Supplementary Materials for

Supplementary Materials for advances.sciencemag.org/cgi/content/full/2/1/e1501170/dc1 Supplementary Materials for Efficient luminescent solar cells based on tailored mixed-cation perovskites Dongqin Bi, Wolfgang Tress, M. Ibrahim

More information

Recent Developments in Perovskite Materials for Solar Cell Applications. Yu Sheng Min, Researcher of ITRI/MCL

Recent Developments in Perovskite Materials for Solar Cell Applications. Yu Sheng Min, Researcher of ITRI/MCL Recent Developments in Perovskite Materials for Solar Cell Applications Yu Sheng Min, Researcher of ITRI/MCL 2017.10.19 Outline Introduction of perovskite materials Major problems of perovskite solar cells

More information

Development of Low-cost Hybrid Perovskite Solar Cells

Development of Low-cost Hybrid Perovskite Solar Cells Proceedings of The National Conference On Undergraduate Research (NCUR) 2016 University of North Carolina Asheville Asheville, North Carolina April 7-9, 2016 Development of Low-cost Hybrid Perovskite Solar

More information

Lithography-Free Broadband Ultrathin Film. Photovoltaics

Lithography-Free Broadband Ultrathin Film. Photovoltaics Supporting Information Lithography-Free Broadband Ultrathin Film Absorbers with Gap Plasmon Resonance for Organic Photovoltaics Minjung Choi 1, Gumin Kang 1, Dongheok Shin 1, Nilesh Barange 2, Chang-Won

More information

Solliance. Perovskite based PV (PSC) Program. TKI Urban Energy Days l e d b y i m e c, E C N a n d T N O

Solliance. Perovskite based PV (PSC) Program. TKI Urban Energy Days l e d b y i m e c, E C N a n d T N O Solliance Perovskite based PV (PSC) Program TKI Urban Energy Days - 2017-06-21 l e d b y i m e c, E C N a n d T N O 2 Bringing together research and industry Providing insight and know-how to all partners

More information

Reducing hole transporter use and increasing perovskite solar cell stability with dual-role polystyrene microgel particles

Reducing hole transporter use and increasing perovskite solar cell stability with dual-role polystyrene microgel particles Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 217 SUPPORTING INFORMATION 1 Reducing hole transporter use and increasing perovskite solar cell stability

More information

GRAPHENE/CARBON BLACK COUNTER ELECTRODE FOR PEROVSKITE SOLAR CELL. Nutsuda Bunyoo, Nuttapol Pootrakulchote*

GRAPHENE/CARBON BLACK COUNTER ELECTRODE FOR PEROVSKITE SOLAR CELL. Nutsuda Bunyoo, Nuttapol Pootrakulchote* GRAPHENE/CARBON BLACK COUNTER ELECTRODE FOR PEROVSKITE SOLAR CELL Nutsuda Bunyoo, Nuttapol Pootrakulchote* Department of Chemical Technology, Faculty of Science, Chulalongkorn University Center of Excellence

More information