New ZB-5HT Inferno The World s Highest Temperature Non-Metal GC Column

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1 New ZB-5HT Inferno The World s Highest Temperature Non-Metal GC Column

2 The World's First Non-metal 5% Phenyl Phase GC Column Rated to 430 C * Specially processed for thermal stability up to 430 C A true (5%-Phenyl)-methylpolysiloxane phase Individually tested for low bleed Rugged high temperature, polyimide coated, fused silica tubing Stable and Durable Even When Pushed to 430 C * After 23 Hours at 430 C only 1.5% retention difference App ID th injection 136 th injection Dimensions: 15 meter x 0.32mm x 0.10μm Part No.: 7EM-G Injection: Direct on 43 C, 0.1uL Carrier Gas: 1.9mL/min (35cm/sec) - constant flow Oven Program: 40 C for 2 min to C for 10 min Detector: 430 C Sample: Paraffin Wax min Still Flexible After 23 Hours at 430 C * At temperatures above 370 C, most of our competitors fused silica tubing will become brittle and randomly break. Our special new tubing is manufactured using a novel High Temperature Polyimide Resin material that shows minimal thermal degradation even at programmed temperatures up to 430 C. *430 C TPG Stability Test Evaluated by performing 185 programmed temperature runs, total 23 hours at 430 C. Polyimide tubing was still flexible as shown here. Phenomenex Web:

3 Outperforms Agilent J&W DB-5ht Lifetime Comparison Longer Lifetime! Dimensions: 30 meter x 0.25mm x 0.10μm Injection: 1.0μL of test mix AG Carrier Gas: Constant Flow 1.9mL/min Oven Program: 120 C Isothermal Detector: Flame Ionization Detector 400 C Analyte: Pentadecane Zebron ZB-5HT Inferno Agilent J&W DB-5ht Columns were held at 400 C for 2 hours, then the oven was lowered to 120 C for Pentadecane analysis. Cycle was repeated. Bleed Profile 400 C Dimensions: 30 meter x 0.25mm x 0.10μm Injection: Null 250 C Carrier Gas: Constant pressure of 11psi Oven Program: 120 C for 3 min to 320 C at 30 C/min (hold 5 min) to 340 C at 30 C/min (hold 5 min) to 360 C at 30 C/min (hold 5 min) to 380 C at 30 C/min (hold 5 min) to 400 C at 30 C/min (hold 5 min) Detector: Flame Ionization C Lower Bleed! 380 C Zebron ZB-5HT Inferno Agilent J&W DB-5ht All columns were new, never used, prior to this testing and purchased either directly from the original manufacturer or through an authorized distributor. All testing was carefully controlled to ensure conditions were similar for all columns involved. The comparative data is not representative of every application. Agilent and J&W are registered trademarks of Agilent Technologies. Phenomenex Web:

4 Making the World s Highest Temperature GC Column Engineered Self Cross-linking (ESC) Technology... Column bleed is the loss of lower molecular weight stationary phase pieces (MS Ions 355, 281, 207, 73) that are either the result of impurities in the starting polymer or the decomposition of the phase at elevated temperatures. ESC bonding technology reinforces the stationary phase by incorporating ladder bridges into the polymer backbone. The process begins with a careful fractionation of the base polymer, which eliminates low molecular weight impurities and enhances coating efficiencies. The columns are then cross-linked and surface bonded using an aggressive catalyst forming an interpenetrating network, which provides enhanced column durability and extremely low bleed levels even at programmed 430 C temperatures! Special High Temperature Polyimide Coating... Capillary GC columns are externally coated with a thermoplastic polymer known as polyimide resin. It stabilizes the internal glass capillary tubing and allows the columns to be flexible even at elevated temperatures. Standard polyimide resin pyrolyzes at temperatures above 370 C making the tubing unstable. The new Zebron ZB-5HT Inferno column utilizes a polyimide resin material that shows minimal thermal degradation even at programmed temperatures up to 430 C. The new resin material is also the reason for the graphite black appearance of the capillary tubing. However, unlike traditional tubing that darkens due to oxidation, this tubing will provide long lifetime even at 430 C.

5 Hot 5HT Applications App ID App ID Butter Triglycerides Dimensions: 15 meter x 0.32mm x 0.10μm Part No.: 7EM-G Injection: On-Column C Carrier Gas: Constant Flow Helium, 1.8 ml/min Oven Program: 100 C to 400 C at 14 C/min for 10 min Detector: Flame Ionization 400 C Polybrominated Diphenyl Ethers (PBDEs) Dimensions: 30 meters x 0.25mm x 0.10μm Part No.: 7HG-G Injection: Pulsed C Carrier Gas: Constant Flow Helium, 1.3 ml/min Oven Program: 125 C to 380 C at 22 C/min for 15min Detector: Mass Selective amu Analytes: 1. BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE BDE-203 Analytes were 2.5ppm in isooctane. Pulsed splitless injection at 50psi using direct connect liner. App ID App ID Olive Oil Dimensions: 30 meters x 0.25mm x 0.10μm Part No.: 7HG-G Injection: On-Column C Carrier Gas: Constant Flow Helium, 1 ml/min Oven Program: 220 C for 1 min to 400 C at 8 C/min for 4 min Detector: Flame Ionization 415 C Sample was 1% in dichloromethane. H-53 Diesel Fuel Dimensions: 30 meters x 0.25mm x 0.10μm Part No.: 7HG-G Injection: On-Column C Oven Program: 50 C for 6 min to 400 C at 20 C/min for 15 min Carrier Gas: Constant Flow Helium, 1.3 ml/min Detector: Flame Ionization 400 C Analytes: 1. Decane (C10) 2. Tetracontane (C40) Fuel was 1% dichloromethane with 50ppm markers.

6 Ordering Information Zebron ZB-5HT Inferno Capillary Columns ID (mm) df (μm) Temp. Limits ( C) Part No. Price 15-Meter to 400/430 7EG-G to 400/430 7EM-G Meter to 400/430 7FD-G Meter to 400/430 7HG-G to 400/430 7HM-G Guardian Integrated Guard Columns Integrated Guard (m) Column Dimension Part No. Price 5-meter 30 meter x 0.25mm x 0.10µm 7HG-G GGA High Temp Septa Part No. Description Unit Price AG PhenoRed-400 Injector Septa 50/pk AG PhenoRed-400 Injector Septa 100/pk ZB-5HT is guaranteed to outperform any competitor s HT column or it s yours FREE! No questions asked Phenomenex, Inc. All rights reserved. Phenomenex is a registered trademark of Phenomenex, Inc. Zebron, ZB-5HT Inferno, Engineered Self Cross-linking (ESC) and Guardian are trademarks of Phenomenex, Inc. Agilent and J&W are trademarks of Agilent Technologies, Inc. Phenomenex is in no way affiliated with Agilent Technologies, Inc. High Temp Graphite Ferrules Part No. Description Unit Price AG mm Ferrule ID: 1 /16" to 0.4mm 10/pk AG mm Ferrule ID: 1 /16" to 0.4mm 50/pk AG mm Ferrule ID: 1 /16" to 0.5mm 10/pk AG mm Ferrule ID: 1 /16" to 0.5mm 50/pk 4261_I