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1 - wwr + ' t H% OA / q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ºC - % 9 ]^^ ºC N + J 4/$\ :+ 9E : F B ) :5 # ))-9 A/" _ K : AE$# B 1 [0] 5 / $ : 51F 8 N- h i4 8 "9 >e ` Oa 5$H% h2 $ k = # / F%j" 5A /K 1 1$R 5 ) >e : 5W #ff /) F% Oa : A Om 34 [l] / 5W $ F " 8 /R )A n' : A /,F1 8 ) 5% o U 8p 51: A "n - # 5% 1# XA n' 5 H% )( A/" HA H %/@Y R $4 _ K # _ H %/@Y _:+ 9E _8 "9 : 7 6$ 7 ` Oa 5$H% : AE$# A X HA F$ : A F# 5 %/' AB "5 AE$# A /($ F# / F1$R ` Oa 5$H% : A AE$# 8 N- 5 H% 8 N- - /#' 5 / W3# 8 N- L' +$ ( ) - 5A/% [ ] /% b/ W B W / >e 5$H) / B + A/" 8 f- : #/2 5 \ g/k $ # 34/ hajalilo@pnacir : 6 F6 ' (^V ) ]Vl0s0T : H 3- q/r 5$ /
2 B /3 3N BzQ {/P /3 34 = F F F 5 9 : 5" : AB g b $Š/- % Š/- : # Š/- Š/- G F b $F : A p #/@ ))-9 : A 1 j" # : ) % F,H $( : AE$# A Z- 8 /R #/( #/@ 4/HN : # % Š/- F - F / [S] # 8 "9 : # : h2 $ K F " A A9 B $ F " F > # +g 8 U9 : K 8 "9 & " : F% : A+- / : / K 8 "9 [] # 5% ' ' : A / ƒp/h1 8 "9 # F 5 3 /g,# /% > 6)- +- / 5 3 B/$4 /% A 8 F : AE :+3 : A5-8 "9 H % - [s] 5 /% FK $% Leisegang : A > 6)- : # (SiO2) O 3 # 5 8 /R $m : Aq/3W /g 8 "9 3Hg 5 3 " Aq/3W /" > 6)- : # : Œ L 3 # :[ ^] /g Z # : A /3,- P Aq/3W ( B5% # q = : H" (G : A ) L 3 # 5$ 9 /g /3,:A L 3 # %, :/)F % q W P L 3 # $m : Aq/3W (b /% >R = 3,J : AE$# F L 3 # (F L 3 # $m : Aq/3W 5 > 6) ph Eh 8 - ) XA B/U 3 /4 - - qy 8 /R >H= Aq/3W : 3 # L 3 # - 8 /R :5$ $ ) - B g /% ) 5% F) / E - 7 W k % - " [ ^] 5 9 /g /3 B +- / : / = z9 (F# K 1,2 5% > 6)- 5 + X : ($# /3,- % 5 H J : A 5 (q Z ) AE$# 3H= HŒ 5 5% L 3 # },% :5 # XA a q % AB9 /g/ : A = AŠ 6% # AB9 B ( 5 ): F% +- / 8 /R /% > 6)- 8 "9 N F 5% 2 = 8 "9 3Hg 5 3 > 6)- k % 6$ Om 34 N i4 1Œ/ 3W k % # B 6 8 F : A "n K # E Z }/$- : " J iw / /% F%/ $ a # $ }/ /H V^ X XA n' - A8 "9 ~ 7 l] 5 5% : /H A/" : A "n # : 5$F " J # / k#/- F$ - b5w " 8 /R A /H `+,- 5 ) : AB F# % B %-A/" : }/ /H l^ X 5 5% /H 51- E > /4 > 3W- # : 5 5% F PW1480 q5 Philips (F# XRF ` + )- 5= 5$F " J # / / $ B % +$($ B F - & L >e E R $4 : (F#, Pf- K $% /Z$ # / ppm ƒ, G ) 3F : A` A8 "9 E : A " :A A /H 3= S 2 5% F " a H- E 8-5$F " J " F # : g T^^ - l^^ A () 9 : / /Z$ : 5 5%,P AB9 [V] 5% F# h J,P B 6 + > 2 = B /# : FK # :5$ B N z9 : F " # 7$ []] " J B N z9, B B9 P9 # F%j" # )' : /= B O 6 ) - ( /"" : A ), ' g/- 5 5A ) > J (5$ # B,# ))-9 : A 1 B9 + X ( >6%) B N z9 : ) : A /))-9 : AE$# : %- : Ab/# : 3 # [T] # 5% 5 %/' :z/ 6 # / : F " B/$4 B F# % 3Hg ` Oa : A /g ' : X 5 h2 $ ' #/@ ))-9 : AE$# [V] H% 8 "9 5$F A 1 # `F " : #/( # /,H $( / - : 3m AE$# A ( H % : A +N- ˆ F 5$F A AB9,- # AB9 F /%/% - G # F' 3J MA9 5A B ) /K L' ))-9 : AB H O Y 5A % : 7$ + #/@ [S] 8 /R 3m # / F " ))-9 : A 1
3 >34 A/" H %/@Y J J%q H% :F /3 l] > A : F# (l : ^^^^^ : J m b/$g F$ >W F) 7$ 8 "9 : AE$# # 5% J P/ : 5$F A #/( # 5 9 / `F " 5 F " J #/@ +,# :F K : / # O 7$,H $( X ) {% :F /3 l # 13J` (V : AE$# J ( NF)A : ^^^^^ : J mq H% # > % 7$ 8 "9 8 "9 : A /H 5% % F 85% #" > 5 : A5= : AE$# 5 5% A 7$ : A~ K Ž7# 5 F " J #/@ /{%b/$g :F /3 0^ # 13J + J 7$ (] : g $ /B J /$g X B F# % : ^^^^^ : J 7$ J B `F " 5A % 7$ # 5% J g K # #/( F,H $( F / : AE$# -B #/@ : AŠ/- : ( 0>6%) O F A 5 F " J #/ " : A ([T]B N z9 ) I,FJ) ( :]^^^^^, - I : A "n ls^ + ' l H% s53g - "n -O /% A8 "9 A/" - % A/" :A /% =/ 8 "9 : AB/H$K & H- ƒ, F) B F# % J%b/$g {% J%q H% T [ ] 5 J B $jm X :+ : AX E$# : F " `F " 5A % B F# % 7 :[V] 5$-,4 ( >6%) O F A 8 "9 : A 5${9 {% q H% :F /3 0V : : F# ( J mq H% F$ (B $jm X + ) 8 "9 : AE$# J NF)A : ^^^^^ F,H $( F # / F / : A 5" 8 /R 7$ : AŠ/- G F AŠ/- G F : 5 #/( # 5 F " J #/@ : : F# bm :F /3 ] N : F# (0 : J J%q H% F$ {% :F /3 l^ `F " 5A % 7$ J : ^^^^^ : O F A #/( F / F,H $( : AE$# 8 "9 : F% J #/@ : AŠ/- G F +,# : /5$ ) 8 "9 h2 $ "5$' : ),
4 B B F /3 3N : A,H $( BzQ {/P /3 34 = g K # (b) # 13J+ J : A,H $( -E$# : A = AŠ 6% L 3 # },% : Aq/3W :A 5 H : A K # [ l] # A : F# K # B//% 5A ) (l>6%) a % H3>" :/ 3= 4 1% /3 -X 5 3 # A = : / : F# K # # 5% ' [ l] /3 % +-/ 3 # :A : F# : A = /g K # N 34 5# Z ( l>6%) 5% AB 5 ( : AE$# >6% : AX 5 = : % = X : /@Y K # g K # ( ) 5 5${9 J%q H% :F /3 B F : F# (T : J X ƒ, - (B $jm X + ) : AE$# `F " # 5% J NF)A : ^^^^^ K # #/( # 8 "9 F,H $( F / : AE$# (b 0>6%) # 7$ g [ 0] 5 J #/@ :F K +,# : AŠ/ : FK # 5K 5A % A8 "9 > 6)- ( /(U g/- N 5- $ ) - : N F 3m O F A AB9 3F % FG$ H :/ 3= CD 4 1% (8) H3>" (o) /3 (b) : F# ( ) FK # E
5 >34 A/" H %/@Y 5% 5A ) : F ( : F% : / %, : F% (8 o V>6%) # : A+- / ˆ / + : A /3 : F% # B5% # : / 5 /% > 5,- /3 % 9 & 9 B5% # A = : / 3 # : AqY [V] /g A = - 3K : ) &5J A/" : A "n # /Z$ : A "n K : " 5 5 `- R K 6% Œ : /K > R >e A/" E (F 6% }/ % F # n " # /@/3 >J5= # / T A 5% 9 # () 9 5% : AF ' : " 5 : /H : A "n / : ' 5 5% q # A/" 8 - OA 3F h2 $ : 5% : " 5 5% 5 A /H : A,% / F) 5 :A/" : A "n H% q 5g [ l] 5 5% ( 5HA : A "n ls^ + ' l H% s53g /K 3 :+ X /3 % +- / -- J /- # 5% ' 3 4 E >6% # 8 /R # ' ' ) ( ) - $ ( /3 % : A+- /) & 9 ( 5 ) l>6%) # L 3 # $m " : Aq/3W ( 3) # A FK # + (o l>6%) H3>" K # (b [V] /% 5A ) h2 $ : ' 5W 8 /R 5% ' K : A >6% PfF A FK # 3m > 6)- A " 5$F A 3 # 3m : Aq/3W : 3 #, 4 1% :/ 3= 8 /R 5 X : / 8 "9 5 }/ X # /% > 6)- /3 % Š % : A+- / 9 (8 l>6%) IJ + X : F : A # : ( V>6%) g O a - ~ 7 ] 5% 5A ) : A FH (b V>6%) F # 7$ 8 "9 F ' F / F,H $( : AE$# [V] # % FG$ H (o) (ppl) F # (b) (ppl) g ( ) : F,H $( : AE$# '/6# 6 : A K (pl) : F% (8) (pl) : /
6 B /3 3N BzQ {/P /3 34 = FK $%A/" : A "n, " 7L R E E 5 # (F 6% 9 5 # E H 9 E H :F K # % F # (U L # /@/3 ( 5$U Œ 6% O- R/\K :A/" > R : /K 7$ & 5R S 0/TT /]] 4 : 5R k#/f T/ 0/Tl /]V k#/f N 5R k#/f S 0/T] /]] 3 K >A 5 # :F K 5R S 0/TV /]l # 13J` 5 # E H N 5R T/S 0/TT /]] 3 K # 13J+ J 5 # E H N 5R S 0/T] /]V 3 K BF A5 : + J % E 9) E - 5 5% 5 /K 5 6 /2 5 F) K $% + FH ( # >6 _O F - & +$($ L % XRF () 5 ' XA O $ / # 5R X + B +HA O F - O + $ +$($ 6 3 # 5 A9 : A5, B9 5 e5= $[HA 5$ \ ),- O 5# O 3 / b $F 5 ^ 5% \$4 H % - 9 /H (, 5 5% q # / $ B 4 \$4 s (LOI) 9 /H V - XA / B+ + J /H G (36a : /H ) : A8 "9 5 # : A % b H -8 "9 F 4 R $4 A8 "9 /Z$ 5$ R $4 F : A 5% N : AE, K \$4 )A :) /g/ : A F /\K A8 "9 E s/] - ss/] 5 5% 3R : A5 + 3F H %/@Y F 8 - : A /H A8 "9 b H 63# 5$F " J > 3W-, B/F 5 % (MREEs - LREEs AB9 Pf- 5% # : " N F 4 R $4 6 F Y,- K $% 3R : A5 # / M$ 5% # : K F# 5R # /Z$ h2 $ -/,6$4 : A /H K (36b : /H ) A /H : 3 SiO2 5 5 / F H- 5$UA T>6% I # R $4 ( 40 : /H ) E A # 8 "9 /H G 5 " J # / A [ ^ V]5 5% N$ # Pf- 3R /H G (35d HF= (F# K B B ) : 4 R $4 3F R $4 M 5 /H G (35a, 35b, 35c, 32 : A : /H ) +,# E % / # : /H 5$A B ) /K 6 3 # 5R X +, 5 (0q 5g) 5$F " J # / b H - /H )E 6 3 # 5R X + B $U # : A9) +( R $4 Pf)A A8 "9 : A /H 8-5$A H B ) $1 8 - (LOI) / # L 3 # %s/ : O #73$, (0q 5g) 3R : A5 8 - # :, 6 3 # 8 - : Q : A /H 6 3 # : A (]>6%) 5% # \ ) 5 F# A5 : &/ $ / 9 O # F' O 5# O 3
7 >34 H %/@Y /H G-32 (Ble) G-35a (Ble) G-35b (Ble) G-35c (Ble) SiO2 / ss/ts s/l / 3R : A5 (%) A/" : A "n ls^ + ' l H% s53g H % : +N- ˆ F 5" 7L G-35d (Green) / G-36a (Smok) / G-36b (Red) / G-40 (Black) / Al2O3 / Fe2O3 ^/V / / / / / ^/] / CaO / Na2O K2O MgO TiO2 MnO P2O5 ^/^^l / / LOI / / / / / / R $4 (ppm) 4 Cl 0 S Ba Sr C Vs Zn Pb 0S V Mo W Zr V Nb Y Rb V T Ni Cr Co ] U Th La Ce Pr Nd ] 0 l V Sm E Gd D
8 /3 3N BzQ {/P /3 34 = B L3#, 3R : A5 8 - N
9 >34 A/" H %/@Y : A "n ls^ + ' l H% s53g 100 G-32(Ble) G-35a(Ble) G-35b(Ble) 10 G-35c(Ble) G-35d(Green) G-36a(Smok) G-36b(Red) 1 La Ce Pr [ V] Nd 4 5% : % " # F %) ) 5g $m E 5% H" [ S] /% 1,2 3F E l^ X FK # B/- A8 "9 E n "5 g O F - L & : AE -E 3F B/- 9 '/6# 6 + F "9 >6 9 : A % N +,# 1 $ 9 : A /H A9 5 k#/f 5 + J +,# E # 5 F) E A # + ( : AE La 5 5$A F HA " -E }/ A8 "9 & H- B ) Sm, E, D 5 /- ) J 5 = 5 + Gd /% 6 ƒ 3F Sm, E, D R $4 _5 5 B ) La :A " B/F 5 % 5$A : 7$ ƒp HF= 5$ /- ( K E R $4 5$% PQ A8 "9 - F % A9 O Pf- ( ) # 5R ^/]s 5R ^/^0 E FH E + J 3Hg B9 [ ] 5 /% #, +$($ E 5 A E h2 $ 5R ^/] : # 8 F }/$F : AE [] a -8 "9 : /2 6 = % >6 ( B ) (D - La -,4 A9 >e E :+3 R $4 /= :F K : / J + J 5R ^/VV E 8 "9 j" Pf- 3R > /4 : A :z/ /g #5 ' + T >6% 6 $U La 5 5A Ce, Pr, Nd, /% 5 O H % - 5% N$ ) MREEs LREEs )A 3 5 q/\w B/$4 (8 "9 5 / : A ) 5g q/\w G-40(Black) D = REEs /H F " : % > 6)- ( ) E "5% $m Gd,e : N$A 8 "9 5$$ 5 /- b " 5 / : H" G E 5$ AB9 E = 8 - " g/- 5 /F 5 % E : H" G Sm #:A +$($ 5 # A8 "9 5 # 5R ^/^^ A8 "9 # :R $4 A8 "9 AE 3R > 4 6$ Om 34 B ) A # 5$F A m Ti, V, Cr, Fe, C 5$ E N 9 : A + 4 # 9 A Y # K q e : 5 PQ N 3R > 4 TiO2 /g : g 9 E 9 b H R $4 / E # 9 q e :) # 5% FK $% H) +,# E 9 : Y R $ E = ([ ]] p H-/" E N > 4 TiO2 B b/$g [ T] 5 N 9 E 4
10 B /3 3N BzQ {/P /3 34 = 9 : ' E l^^ºc - l^: N E - l^^ : = 5% - % /% - - (& H# (q ") ") 5 /% > HF J A ƒ, - / 7J >,J 5 `/ F# A 5 3 : A / E 8 - A /H FK # `F " 5$% a "5%E ' : 5 5' -E %/K 5 /% + J E B5% - % H# & 9 & 9 - : ( : A /H " F # : g ]]^ - ]^^ : A 5 8 /R :5$ / = = E ]]^ºC : B/- j _5$ 9 7$ + % -E : :A 9 X' E %/K ƒ : / J [ ] a " F # : g T^^ 5 /% > HF " - $) ' 5 /% H A8 "9 : 6$ g/- 5$ 9 H Z,# $ : A >W A8 "9 T^^ ºC " %, P F C $ + P4+ / 8 /R :5 # : F " ' #/@ 8 "9 g/- > J : # O 6 - # / i4 %# : O - H" - 13J + J 8 "9 E E L Pf- 5 9 : A8 "9 0] ppm : #/( # 5% AE$# FH # F /%/% - # 13J` > A,H $( N : 3J : A F# MA9, 5 XA E L ( # O ^^ppm +,# + J : A8 "9 # ppm E A # 8 "9 > 4 " B/- j + m E E A # 9 E N Pf- : ) 5 /- E A # 8 "9 A /H 0^ppm A8 "9 E B / b/m > ) FHa ` : A :+ 9E B/- : ' 5$F A ' :A/" ` : :+ 9E X + 9 : \FJ ` 6 ƒ /H4 FHa ` : AE$# H % : Aq/3W 3F (F AB9 - "9 E 5 5% 9 # E 4/$\ 4/$\ " ` # 8 /R []/ F/ /-' AA/" E - h2 $ /H ] % A F# B " : : j' \ ) 8 - : b H R $4 B5 - A &/ /- &/ # []5% / F/ / X - P 5$F 3R & 5 # L \$4 B / p # Tppm A /H # " '/6# 6 [V]5# H Z # $ 8 "9 h2 $ \ ) - O F - 5 [V] # H# % E /- " P -` H# A /H F) A " j 5 /% m9 9 E :+ 9E : - E - / J E A 3F " :+ 9E : $) ' ]^^ºC : B/- [ ] + 3" : ' : AE ]^^ºC N + J : A /H E B $' : A q= - V^^ >R 5= [V] /% # AB9 - - & 9 3K : A / h,7$ A8 "9 6$ ( 5$$ H 7J N # + J % : / J : AE E 8-6$ g : F6 5 /% j (l^ppm) ( -p H (l0 ppm) E A # 5% - % q " " F # : g V^^ " 3R > 4 #E : A / : E /, " :+ 9E `- L' + J N 9 8 /R [ ] # 3 4 : % - :F K + N 3= ] : A 6 F6 : / A /H B a 5% F# " " : F N >'// - -- A /H 3= A " 8 /R J " F # : g T^^ ]]^ ]^^ V^^ l^^ A L' % ˆ$' A " [V]5$F " ˆ F 5% : LM4 A /H A A " 3= :5 J ` >R =
11 >34 A/" H %/@Y / & ' () 8 )F " A/"" b /3 34 = [l] ( lt) WR llt H : ($# & ' () - 5 Š )F" b /3 34 = [V] )A n' 2 " J% B N z9 B F# 8 )F "B : U, " & :/, []] /) 51 8 )F B # ( l]]) B # "B N z9 ls] /) ) " } I -, J9 [T] 51 8 )F [7] Hajalilo B, Vsq B, "Comparison of metallogenic characteristics between Alborz (Tarom-Hashtjin, NW Iran) and Azerbaijan-Lesser Cacass, 6th EUREGEO", Mnich, Baaria, German, 9-12 Jne, p (2009) [8] Hrlbt CS, Kammerling RS, "Gemolog, John Wile & Sons", New York, 336pp (1991) [9] Baer J, "A field gide in color to minerals, rocks and precios stones", Artia, Prage, 208pp (1977) [10] Götze J, Tichomiroa M, Fchs H, Pilot J, Sharp ZD, "Geochemistr of Agates", Chemical geolog, 175, p (2000) : - "9 (F# K" b {/P b /3 34 = [ ] \\ - X HA ( ls) +,- ), T S /) / & ' () [12] Hajalilo B, Vsq B, "Gemological Potentials of East Azerbaijan Proince, NW of Iran", 63rd Geological Krltai of Trke, MTA, Ankara, Trke, 5-9 Aprill (2010) FK # F }/$-" b {/P b /3 34 = [ l] +,- / ) ls^ + ' l H% s53g K # }/$- # B F AE$# : A = B5% ' FH : F% % B) 4 :F K /g # +,# : + J # 3 # : AqY - $ >H= # # H" : # 5A, & L # : 4 R $4 $[HA 5$% : % 5% l lv ( ls) [14] Bonton WV, "Geochemistr of the rare earth elements meteorite stdies", In: Henderson P(ed), Geochemistr Elseier, p (1984) Ce ( 5 /- 5g q/\w ƒp HF= L 3 # > 6)F B ) : g ]^^ E N " :+ 9E + J :+ 9E - F # : g ]]^ 9 E : " F # # " $ 7Q I5$ K >Œ I5$ 5Q W F B J9 /% : +(# # H34 : - /) : 5J b/ B J9 H % : A+ 9 & N : / $ B 8 "9 : A /H `- : : / b/,w % W ># O $a 6)RL$ "B N z9 {% b/$g : - "9 ), T S /) / & ' () $1 B ) L 3 # 5 ƒp HF= +,e : N$ PQ (>6 3R : A5 F N > 4 5$ : A - O $ / B ) b H R $4 F E N 5$$ N R $4, 9 9 >e }/$F : AE A9) E : 7 L 3 # 7$ +$($ A /H / 5% 5A ) : A : /K> R Z 3 # 3 # : AqY A/" : AX 5= H#9 9 7$ # 5$A # 8 F k % ( : / : A # # "(B N z9) V0 ls \\ - X HA : A "n FH J ( lt) WR 0^] / WR ^s FH J : AA/" Š )F" B B ( lss) WR l ] B 1 ) [ ] #5$ $R 8 "B 8 )F " A/g 8 3 8A/g B g" [0] ( lsv) WR lt0 B - :5#
12 B /3 3N BzQ {/P /3 34 = Geochimica et Cosmochimica Acta, 44, p973980(1980) E }/$- >34 3 3W-" b {/P b /3 34 = [ ] \\ - X HA ( ls) +,- " 7$ : - "9 ), T S /) / & ' () ^0 s [15] Harlow G E, Qinn EP, Rossman G R, Rohtert W R, "Ble omphacite from Gatemala", Gems & Gemolog, 40, p68-70(2004) [16] Oberhansli R, Bosqet R, Moinzade H, Moazzen M, Arin M, "The field of stabilit of ble jadeite, a new occrrence of jadeitite at Sorkhan", Iran, as a case std, The Canadian Mineralogists, 45, p (2007) [17] Morgan J W, Wandless G A, "Rare earth element distribtion in some hdrothermal minerals:", eidence for crstallographic control:
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