Viacheslav Diev, Ph.D.

Transcription

1 Viacheslav Diev, Ph.D. University of Southern California 3620 McClintock Ave. SGM 216 Los Angeles, CA Phone: (213) Cell: (323) LinkedIn: Professional Work Experience Postdoctoral Research Associate Dec 2007 to present University of Southern California, Los Angeles, CA (advisor Prof. Mark E. Thompson) Leading a group of synthetic chemists to design organic photoactive materials for use in efficient near infrared organic photodetectors (program funded by the Defense Advanced Research Projects Agency). Interfaced directly with electrical engineers in materials and device design/fabrication Developed new type of materials with strong absorption/emission in the near infrared Developed new, scalable and simple synthetic methodology to prepare -extended porphyrins Leading a group of chemists to design new high-performance organic dyes for efficient organic solar cells Research Visitor 2007 University of Southern California, Los Angeles, CA (advisor Prof. Mark E. Thompson) Designed and developed cyclometalated Ir(III) and Pt(II) complexes for use in organic light emitting diods (OLEDs) Research Engineer 2006 Chemistry Research Institute, Saint Petersburg, Russian Federation Accomplished industrial projects with BAYER AG, KAdemCustomChem GmbH Designed and synthesized organic materials with improved thermal stability Synthesized libraries of biologically active heterocycles and strained compounds Graduate Research Associate Saint Petersburg University, Saint Petersburg, Russia (advisor Prof. Alexander Molchanov) Synthesized libraries of heterocyclic, polycyclic and small-ring strained compounds Developed room temperature cycloaddition reactions of strained hydrocarbons Synthesized new strained cage compounds with high thermal stability Developed new thermal cascade reactions of strained heterocycles Managed and trained a team of graduate research associates Research Visitor 2004 Heidelberg University, Heidelberg, Germany (advisor Prof. Rolf Gleiter) Synthesized a number of strained hydrocarbons for photoelectron spectroscopy measurements Theoretical investigation of model cycloaddition reactions of strained hydrocarbons

2 Research Visitor 2003, 2004 Göttingen University, Göttingen, Germany (advisor Dr. Vladimir Belov, Prof. Armin de Meijere) Accomplished industrial projects with Merck KGaA, KAdemCustomChem GmbH Synthesized new cyclopropylamine derivatives with potential biological activity Education Ph.D. (equiv.) in Organic Chemistry 2006 Saint Petersburg State University Saint Petersburg, Russian Federation M.S. (equiv.) in Chemistry (Summa Cum Laude) 2002 Saint Petersburg State University Saint Petersburg, Russian Federation Professional affiliations The American Chemical Society, the American Association for the Advancement of Science, the Russian Chemical Society, Society of Porphyrins and Phthalocyanines List of Publications in Academic Journals 1. Zimmerman, J. D., Xiao, X., Renshaw, C. K., Wang, S., Diev, V. V., Thompson, M. E., Forrest, S. R. Independent Control of Bulk and Interfacial Morphologies of Small Molecular Weight Organic Heterojunction Solar Cells Nano Lett. 2012, 12, Tran, T. Q., Diev, V. V., Starova, G. L., Gurzhiy, V., Molchanov, A. P. Cycloaddition of C,C- Disubstituted Ketonitrones with Acceptor Methylenecyclopropanes and Subsequent Rearrangement Cascade of 5-Spirocyclopropane Isoxazolidines. Eur. J. Org. Chem. 2012, Diev, V. V., Schlenker, C. W., Hanson, K., Zhong, Q., Zimmerman, J. D., Forrest, S. R., Thompson, M. E. Porphyrins Fused with Unactivated Polycyclic Aromatic Hydrocarbons. J. Org. Chem. 2012, 77, For comments, see: Lewtak, J. P., Gryko, D. T. Chem. Commun. 2012, DOI: /C2CC31279D. 4. Wang, S., Hall, L. A., Diev, V. V., Haiges, R., Wei, G., Xiao, X., Djurovich, P. I., Forrest, S. R., Thompson, M. E. N,N-Diarylanilinosquaraines and their application to organic photovoltaics. Chem. Mater. 2011, 23, Wei, G., Xiao, X., Wang, S., Zimmerman, J. D.; Sun, K., Diev, V. V., Thompson, M. E., Forrest, S. R. Arylamine-Based Squaraine Donors for Use in Nanocrystalline Organic Solar Cells. Nano Lett. 2011, 11, Lassiter, B. E., Wei, G., Wang, S., Zimmerman, J. D., Diev, V. V., Thompson, M. E., Forrest, S. R., Organic photovoltaics incorporating electron conducting exciton blocking layers. Appl. Phys. Lett. 2011, 98, Zimmerman, J. D., Yu, E. K., Diev, V. V., Hanson, K., Thompson, M. E., Forrest, S. R. Use of additives in porphyrin-tape/c 60 near-infrared photodetectors. Organic Electronics 2011, 12,

3 8. Tran, T. Q., Diev. V. V., Molchanov, A. P. An efficient and stereoselective cycloaddition of C-aryl and C-amido nitrones to dimethyl 2-benzylidenecyclopropane-1,1-dicarboxylate. Tetrahedron 2011, 67, Diev, V. V., Hanson, K., Zimmerman, J. D., Forrest, S. R., Thompson, M. E. Fused pyrenediporphyrins: shifting near infrared absorption to 1.5 m and beyond. Angew. Chem. Int. Ed. 2010, 49, Highlighted in: SYNFACTS 2010, For comments, see: Lewtak, J. P., Gryko, D. T. Chem. Commun. 2012, DOI: /C2CC31279D. 10. Zimmerman, J. D., Diev, V. V., Hanson, K., Thompson, M. E., Lunt, R. R., Yu, E. K., Forrest, S. R. Porphyrin-Tape/C 60 Organic Photodetectors with 6.5% External Quantum Efficiency in the Near Infrared. Adv. Mater. 2010, 22, Hanson, K., Tamayo, A., Diev, V. V., Whited, M. T., Djurovic, P. I., Thompson, M. E. Efficient Dipyrrin-Centered Phosphorescence at Room Temperature from Bis-Cyclometalated Iridium(III) Dipyrrinato Complexes. Inorg. Chem. 2010, 49, Molchanov, A. P., Diev, V. V., Tung, C. Q., Kostikov, R. R. Reactions of Substituted 8- Oxatricyclo[ ,4]octan-6-ones and 9-Oxatricyclo[ ,4]nonan-6-ones with Methylmagnesium Bromide and Lithium Aluminum Hydride. Russ. J. Org. Chem. (Engl. Transl.), 2009, 45, Diev, V. V., Tung T. Q., Molchanov, A. P. Esters of Feist s Acid: Some Insights into the Electronic Structure and Reactivity of Methylenecyclopropanes Ring-Substituted with Acceptor Groups. Eur. J. Org. Chem. 2009, Diev, V. V., Stetsenko, O. N., Tung T. Q., Kopf, J., Kostikov, R. R., Molchanov, A. P. Nitrone Cycloadditions to 1,2-Diphenylcyclopropenes and Subsequent Transformations of the Isoxazolidine Cycloadducts. J. Org. Chem. 2008, 73, Diev, V. V., Kostikov, R. R, Gleiter, R., Molchanov, A. P. Cyclopropenes in the 1,3-Dipolar Cycloaddition with Carbonyl Ylides: an Experimental and Theoretical Evidence for the Enhancement of -Withdrawal in 3-Substituted-Cyclopropenes. J. Org. Chem. 2006, 71, Highlighted in: Annual Reports on the Progress of Chemistry, Sect. B: Org. Chem. 2007, 103, Molchanov, A. P., Diev, V. V., Magull, J., Vidovic, D., Kozhushkov, S. I., de Meijere, A., Kostikov, R. R. Carbonyl Ylide Cycloadditions to C,C-Double Bonds of Methylenecyclopropanes. Eur. J. Org. Chem., 2005, Molchanov, A. P., Diev, V. V., Kopf, J., Kostikov, R. R. Dipolar Cycloaddition of Carbonyl Ylides Generated from Methyl cis-2-diazoacetyl-1-cyclopropanecarboxylates. Russ. J. Org. Chem. (Eng. Transl.), 2005, 41, Molchanov, A. P., Diev, V. V., Kopf, J., Kostikov, R. R. First Example of 1,3-Dipolar Cycloaddition of Carbonyl Ylides to Cyclopropenes. Russ. J. Org. Chem. (Eng. Transl.), 2004, 40, Molchanov, A. P., Diev, V. V., Kostikov, R. R. Reaction of Aliphatic Diazo Compounds: IV. Reaction of Diphenyldiazomethane with Substituted Imides of Maleic and Itaconic Acids. Russ. J. Org. Chem. (Eng. Transl.), 2002, 38, Patents and Patent Applications 1. Visible/NIR Porphyrin Tape/C 60 organic photodetectors, Forrest, S. R., Zimmerman, J. D., Thompson, M. E., Diev, V. V., Hanson, K. // U.S. Pat. Appl. Serial No.: 61/275,156. Intl. Publ. No.: WO 2011/ A1. 2. Fusing Porphyrins with Polycyclic Aromatic Hydrocarbons and Heterocycles for Optoelectronic Applications, Thompson, M. E., Diev, V. V., Hanson, K., Forrest, S. R. // U.S. Pat. Appl. Serial No.: 61/360,026. Int. Publ No.: WO A

4 3. "Photoactive devices including porphyrinoids coordinating additives", Forrest, S. R., Zimmerman, J. D., Yu, Eric K., Thompson, M. E., Trinh, C.; Whited, M. T., Diev, V. V. // U.S. Pat. Appl. Serial No.: 61/404,983. Int. Publ No.: WO A Organic Photosensitive Devices Comprising Aryl Squaraines and Methods of Making the Same, Forrest, S. R., Thompson, M. E., Wei, G., Wang, S., Hall, L., Diev, V. V., Xiao, X. // U.S. Pat. Appl. Serial No.: 61/441,153. Int. Publ No.: WO A <Organic Photovoltaics>, Diev, V. V., Filed <Porphyrins>, Diev, V. V., Filed Conferences, Presentations, Funding Reviews 1. Funding reviews: Defense Advanced Research Projects Agency (DARPA), HARDI project reviews: Sep. 2008; Jan. 2009; Jul. 2009; Nov. 2009; Feb. 2010; Mar Diev, V. V., Thompson, M. E. On the Mechanism of Oxidative Cyclodehydrogenation of Substituted Porphyrins SCIP meeting, 2011, Santa Catalina, CA. 3. Wang, S.; Diev. V. V.; Hall, L.; Djurovich, P. I.; Thompson, M. E. "N-Aryl squaraines as highly efficient donors for organic photovoltaics" 242nd ACS National Meeting in Denver, CO, August 2011, ORGN Zimmerman, J. D.; Renshaw, C. K.; Xiao, X.; Wang, S.; Diev, V. V.; Thompson, M. E.; Forrest, S. R. "Morphological and electrical effects of solvent annealing squaraine/c60 photovoltaic devices" MRS meeting, September Wang, S.; Diev, V. V.; Hall, L.; Djurovich, P. I.; Thompson, M. E. "Molecular design of new squaraines for efficient OPVs: tuning absorption, energy levels and morphology" MRS meeting in San Francisco, CA, April, 2011, NN Zhong, Q.; Diev, V. V.; Roberts, S.; Bradforth, S. E.; Thompson, M. E. "Fused porphyrin- SWNT supramolecular assembly for photoinduced electron transfer process" 241st ACS National Meeting in Anaheim, CA, March 2011, INOR Zimmerman, J. D.; Yu, E. K.; Diev, V. V.; Hanson, K.; Lunt, R. R.; Thompson, M. E.; Forrest, S. R. Porphyrin-tape/C60 photodetectors with > 7% external quantum efficiency in the near infrared ICEL, Ann Arbor, MI, October, Diev, V. V., Thompson, M. E. Fused Pyrene-Porphyrins: efficient synthesis, NIR fluorescence and NIR photovoltaic applications SCIP meeting, September 2010, Santa Catalina, CA. 9. Diev, V. V.; Hanson, K.; Zimmerman, J. D.; Forrest, S. R.; Thompson, M. E. "Molecular design of porphyrin-based macrocycles for improved organic photovoltaic cells" 6th International conference on porphyrins and phthalocyanines, New Mexico, July 2010, Abstract No. S Wang, S.; Wei, G.; Diev, V. V.; Schlenker, C.; Djurovich, P. I.; Forrest, S. R.; Thompson, M. E. "Solution processable squaraine dye in bilayer heterojunction photovoltaic devices" 239th ACS National Meeting in San Francisco, CA, March 2010, ORGN Diev, V. V., Thompson, M. E. How to shift the absorption of metalloporphyrins into the near IR SCIP meeting, October 2009, Santa Catalina, CA. 12. Diev, V. V., Thompson, M. E. Near IR absorbing materials: diporphyrins SCIP meeting, May 2008, Santa Catalina, CA. 13. Diev, V. V.; Stetsenko, O. N.; Kostikov, R. R.; Gleiter, R.; Molchanov, A. P. "Cyclopropenes in the 1,3-dipolar cycloaddition with carbonyl ylides and nitrones: experimental and theoretical evidence for the enhancement of sigma-withdrawal in 3-substituted cyclopropenes" Butlerov Organic Chemistry conference in Saint Petersburg, Russia, June Diev, V. V.; Molchanov, A. P.; Gleiter, R.; Kostikov, R. R. "New aspects of the carbonyl ylide cycloadditions to the strained double C,C bond of cyclopropenes" Modern trends in organic synthesis, Saint Petersburg, Russia, June 2005, Abstract No. 138.

5 15. Diev, V. V.; Molchanov, A. P.; Kostikov, R. de Meijere, A. "Carbonyl ylide cycloadditions across strained carbon-carbon double bonds" Modern trends in organic chemistry, Saint Petersburg, June 2004, Abstract No Diev, V.V.; Molchanov, A. P.; Kostikov, R. R. "1,3-dipolar cycloaddition reaction of carbonyl ylides with 3-substituted 1,2-diphenylcyclopropenes" 3rd Euroasian Heterocyclic Meeting, Novosibirsk, Russia, September Diev, V. V.; Molchanov, A. P. "The first example of 1,3-dipolar cycloaddition of carbonyl ylides to cyclopropenes" Oxygen- and Sulfur-containing heterocycles conference, Moscow, 2003, Abstract No Diev, V. V.; Molchanov, A. P.; Kostikov, R. R. "Reactions of carbonyl ylides generated from cis-diazoacetyl-cyclopropanecarboxylates" VII international conference on carbenes and related intermediates, Kazan, Russia, June 2003, Abstract No Diev, V. V.; Molchanov, A. P. "Cycloaddition reaction of carbonyl ylides generated from cisdiazoacetylcyclopropanedicarboxylates" YSCOS-3, Saint Petersburg, Russia, June 2002, Abstract No. 32a 20. Diev, V. V.; Molchanov, A. P. "On the reaction of diphenyldiazomethane with substituted maleimides" Modern problems of aliphatic diazo compounds chemistry, Saint Petersburg, Russia, 2000, Abstract No. P-8 Fellowships, Honors and Awards Presidential award of the President of the Russian Federation 2004 Excellent Graduate Student Award of the government of Saint Petersburg 2003,2004 Research Award of the Ministry of Education of the Russian Federation 2004 Deutsche Forschungsgemeinschaft (DFG) stipend (Germany) 2000 Excellent Undergraduate Student Award of ECROS company, Saint Petersburg 1997 Gold Medal of a Summa Cum Laude high school graduate, Aldan, Russia rd Prize Winner of Student Regional Olympiad in Chemistry, Russia 1996 Presidential Award of the President of Sakha (Yakutia) Republic, Russia Professional References (additional references available upon request) 1. Prof. Mark E. Thompson Department of Chemistry, Material science University of Southern California Los Angeles CA 90089, USA +1 (213) met@usc.edu 2. Prof. Stephen R. Forrest Department of Physics, Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109, USA +1 (734) stevefor@umich.edu 3. Prof. Alexander P. Molchanov Department of Chemistry, Saint Petersburg State University, Saint Petersburg, , Russian Federation s.lab@pobox.spbu.ru