The Synthesis and Photophysical Properties of Alkene- and Stilbene- Linked Fullerene-Porphyrin Dyads
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1 The Synthesis and otophysical Properties of Alkene- and Stilbene- Linked Fullerene-Porphyrin Dyads Paul J. Bracher, Berthold uber, Ahsan U. Khan, Stephen R. Wilson and David I. Schuster YU Fullerene Group May 16, 2000
2 Donor / Acceptor Systems Donors Metal complexes (e.g. ferrocene) Pre-Aromatics (e.g. tetrathiafulvalene) PRPYRIS LUM + 1 LUM Acceptors Quinones Imides FULLEREES M Guldi, D. J. Chem. Soc., Chem. Commum., 2000, Imahori,.; Sakata, Y. Eur. J. rg. Chem., 1999,
3 Fullerene-Porphyrin Dyads Donor-Linker-Acceptor Systems Goals: Understanding otophysical Properties as a function of Molecular Topology. Long-lived Charged Transfer States. Electron transfer from the porphyrin to the fullerene mimics the process of photosynthesis in plants. Development of Agents for Use in otodynamic Therapy (PDT). Light-absorbing species that photosensitize the formation of singlet molecular oxygen ( 1 g ) are being used against tumors in cancer treatment.
4 Past YU Dyads M C 3 C 3 C 3 Schuster, et al. J. Am. Chem. Soc. 1999, 121, Fong, et al. rg. Lett. 1999, 1, 729. MacMahon. Unpublished results.
5 The ew Alkene-Linked Dyads Cu 1 2 Alkene linkage through a pyrrole ring. Stilbene linkage through one of the porphyrin phenyl groups
6 Synthesis of Dyad 1 1. CuAc 2 2. PCl 3 /DMF Cu C + 3 P Cu BuLi, +
7 Synthesis of Dyad 1, ctd. Cu 2 Ts Cu Ts Cu 1. BuLi, C 60 1
8 Synthesis of Dyad 2 S S C 1., BF 3 S S 2. DIBAL M Cl 1. C 6 5 C BF 3 Et 2 2. DDQ S S S 2 Cl 2 Si 2, 2 1. Zn P 2. BuLi, toluene
9 Synthesis of Dyad 2, ctd. Zn Ts 2. Zn 2+ Zn 1. BuLi, C Ts 2
10 Characterization MR Spectroscopy All reactions involve the appearance or vanishing of easily recognizable functional groups, so MR suffices despite the presence of the copper, which broadens the peaks. UV-vis Spectroscopy The linker and dyads show similar absorption spectra in the UV-vis region
11 Porphyrin Synthesis urdles Low Solubility Low Reaction Concentrations Messy Extractions Arduous Column Chromatography Poor Yields (10-25% total)
12 Planned Studies Synthetic: Synthetic generation of pure cis and trans linked forms of both dyads. otophysical: UV-vis & Fluorescence spectroscopy Transient absorption study of the excited states Singlet oxygen photosensitization quantum yields otoinduced cis-trans isomerization in the linker moieties
13 otophysical Pathways 3 2 h 3 A * Quenching 1 2 * 1 D * 1) Energy Transfer 2) ISC Electron Transfer + Recombination Porphyrin (e donor) Fullerene (e acceptor)
14 Energy Transfer Pathway 3 A * Quenching 3 2 Cell Death 1 2 * (PDT) Triplet excited C 60 photosensitizes the formation of singlet oxygen ( 1 g ) with =1 Singlet oxygen decay ( 1 g 3 - g) at 1270 nm can be detected using ultra-sensitive Ge-diode near-ir spectroscopy. Khan, et al.. Proc. atl. Acad. Sci. USA, 1979,
15 otodynamic Therapy (PDT) Procedure: 1) Chromophore is injected into patient 2) The tumor-diseased area is irradiated 3) Cell death results from the generation of singlet oxygen Recently, the FDA approved otofrin, a concoction of porphyrins, as a cancer-treatment agent for photodynamic tumor therapy (PDT). Studies in Japan concluded that a C 60 derivative suppressed tumor growth better than otofrin in mice. Tabata, et al.. Jpn. J. Cancer Res., 1997,
16 Electron Transfer Pathway Following Irradiation: e - 1 transfer D * BET + The pathway can be monitored by transient absorption spectroscopy with the 670 nm decay of the porphyrin radical cation and the 1060 nm decay of the C 60 radical anion. The goal is to produce long-lived charge-transfer states to mimic the photosynthetic reaction centers which are responsible for harvesting solar energy in plants.
17 Stilbene Triad Pathways?? 1 D * electron transfer + electron transfer + 1 D * energy transfer 1 L * energy transfer 1 A *
18 cis-trans otoisomerization 2a Introduces a significant change in molecular topology Separable by PLC Such isomerization holds the potential for practical application as a molecular switch 2b
19 Acknowledgments Technical Assistance & elpful Discussions Shaun MacMahon Prof. icholas Geacintov (YU), for providing access to his fluorimeter and the Ge-diode IR spectrometer Prof. Dirk Guldi (otre Dame, Radiation Lab), for transient absorption studies and related discussions. Funding ational Science Foundation, Grant CE YU College of Arts and Science, S.F.B. Morse Grant
20 Paramagnetic Energy Plot E S 1 D 3 T 1 D 2 D 1 Q 2 P- * C 60? Q 1 P - C 60 S 0 D 0 Cu Cu
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