Structures, Energetics and Stabilities Novel Telluro-ketones
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1 Structures, Energetics and Stabilities 1 of Novel Telluro-ketones By Mrs Naziah Jaufeerally
2 Mrs Naziah Jaufeerally Myself Prof Ponnadurai Ramasami PhD scholar 2
3 Target Molecules Telluroformaldehyde/ Silanetellone/ Germanetellone 3
4 Why the study of Heavy Congeners of H 2 C=O? mainly to check the reliability of quantum mechanical computing methods C=O group- important organic moiety in industry and biology F 2 C=O Cl 2 C=O X 2 C=O (X=F and Cl) major products of photolysis of halomethanes in presence of oxygen 4 se.org/earth/atmosphere/stratosphere.html&usg= gmjvtdnp7rvzhvmpg1vmjq7ywza=&h=400&w=300&sz=29&hl=en&start=6&zoom=1&tbnid=8astvfiowlzlbm:&tb nh=124&tbnw=93&ei=7qpft_rbkcyzhaeeqqh8cq&um=1&itbs=1
5 Thio- and Seleno- analogues Important intermediates in sulfur and selenium containing molecules Composition of nucleic acid and ribose sugars of some active metabolites Useful anti-tumour drugs 5
6 But the literature of telluro-ketones is scarce. Despite Telluroformaldehyde complexes were first synthesized in
7 Telluroformaldehyde H C Te H 7
8 However, nowadays there is a quest for tellurium containing compounds or tellurocarbonyl compounds. 8
9 9 Importance of Telluro-ketones
10 10 Importance of Telluro-ketones
11 Monomeric H 2 Si=S has reached the STARS! 11 RPuI7YGKRkWEw8uIansvoBD89kM=&h=320&w=320&sz=20&hl=en&start=5&zoom=1&tbnid=V8MgZx4YbIUEOM:&tbnh=118&tbnw=118&ei=3KfqTzkOcborQfVpNC5BQ&prev=/search%3Fq%3Dnight%2Bsky%26hl%3Den%26site%3Dimghp%26tbm%3Disch&itbs=1
12 Why Limited literature for Telluro-ketones? Theoretical exploration has been scarce due to: Lack of well-tested basis sets for Te atom Limited computing resources 12
13 Why Limited literature for Telluro-ketones? The lack of experimental studies is often ascribed to: The semipolar nature of the A=E bond (A=C, Si and Ge; E=O, S, Se and Te) High tendency for the A=E to open up and undergo intermolecular reactions 13
14 14 Stable Monomeric Germanone
15 Objectives of this research work 15 Isomerizations Molecular geometries Ionization Potentials Kinetics Telluroketones Electron Affinities HOMO- LUMO gaps Singlet- Triplet Splittings
16 16 Our Findings
17 17
18 Our Findings The kinetic and thermodynamic stabilities of the telluro-ketones were always questioned by reviewers. 18
19 Back to literature How others have stabilized some of the known heavy ketones? Has any stable telluro-ketone been synthesized and isolated so far? 19
20 20
21 21
22 22
23 Conclusions from literature Heavy ketones and telluro-ketones synthesized and isolated so far are based on the kinetic stabilization of the A=E bond by the use of bulky rigid protecting groups. 23
24 Does this means that the simple, unprotected telluro-ketones are unstable compared to those kinetically protected ones? 24
25 25 Our Response to the Queries
26 26 Our Response to the Queries
27 27 Our Response to the Queries
28 28 Our Response to the Queries
29 29 Our Response to the Queries
30 30 Our Response to the Queries
31 Further Objectives Existence of Telluro-ketones is Not a Myth But a Reality! 31
32 In view of this, we are currently working on the following manuscript
33 33
34 34
35 Further Studies Stabilization of the C=Te, Si=Te and Ge=Te double bonds With the help of rigid and bulky protecting groups Modeled from the 1 st synthetic success of germanetellone reported in JACS 35
36 Stabilization of the C=Te, Si=Te and Ge=Te double bonds With the help of rigid and bulky protecting groups Modeled from the 1 st synthetic success of germanone reported in Nature Chemistry 36
37 Stabilization of the C=Te, Si=Te and Ge=Te double bonds With the help of Lewis donor-acceptor ligands 37
38 Conclusions Since state-of-the-art computations have been carried out, findings of this work can serve as a good reference and assist experimentalists to synthesize, characterize and further explore the properties of these novel 38 telluro-ketones
39 Acknowledgements I gratefully acknowledge: the organising committee of 17 th ECSOC Our collaborators: Prof HF Schaefer, Prof G Frenking and Dr H Abdallah the University of Mauritius the computing facility of Gridchem the Tertiary Education Commision (TEC) 39
40 Thank You 40
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