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1 1 of 7 Log In Register Cart Website Demos Website Demos ACS Journals C&EN CAS Publications A Z Home Authors & Reviewers Librarians ACS Members Mobile Help Environ. Sci. Technol. All Publications/Website Select a CAS section from the 5 main topical divisions below: Applied Applied Air Pollution and Industrial Hygiene Apparatus and Plant Equipment Cement, Concrete, and Related Building Materials Ceramics Electrochemical, Radiational, and Thermal Energy Technology Essential Oils and Cosmetics Extractive Metallurgy Ferrous Metals and Alloys Fossil Fuels, Derivatives, and Related Products Industrial Inorganic Chemicals Mineralogical and Geological Chemistry Nonferrous Metals and Alloys Pharmaceutical Analysis Pharmaceuticals Propellants and Explosives Unit Operations and Processes Waste Treatment and Disposal Water Biochemistry Biochemistry Agrochemical Bioregulators Animal Nutrition Biochemical Genetics Biochemical Methods Enzymes Fermentation and Bioindustrial Chemistry Fertilizers, Soils, and Plant Nutrition Food and Feed Chemistry

2 of 7 General Biochemistry History, Education, and Documentation Immunochemistry Mammalian Biochemistry Mammalian Hormones Mammalian Pathological Biochemistry Microbial, Algal, and Fungal Biochemistry Nonmammalian Biochemistry Pharmacology Plant Biochemistry Radiation Biochemistry Toxicology Macromolecular Macromolecular Cellulose, Lignin, Paper, and Other Wood Products Chemistry of Synthetic High Polymers Coatings, Inks, and Related Products Dyes, Organic Pigments, Fluorescent Brighteners, and Photographic Sensitizers Industrial Carbohydrates Industrial Organic Chemicals, Leather, Fats, and Waxes Physical Properties of Synthetic High Polymers Plastics Fabrication and Uses Plastics Manufacture and Processing Surface Active Agents and Detergents Synthetic Elastomers and Natural Rubber Textiles and Fibers Organic Organic Alicyclic Compounds Aliphatic Compounds Alkaloids Amino Acids, Peptides, and Proteins Benzene, Its Derivatives, and Condensed Benzenoid Compounds Biomolecules and Their Synthetic Analogs Carbohydrates General Organic Chemistry Heterocyclic Compounds (More than One Hetero Atom) Heterocyclic Compounds (One Hetero Atom) Organometallic and Organometalloidal Compounds Physical Organic Chemistry Steroids Terpenes and Terpenoids Physical, Inorganic, and Analytical Physical, Inorganic, and Analytical Catalysis, Reaction Kinetics, and Inorganic Reaction Mechanisms Crystallography and Liquid Crystals Electric Phenomena Electrochemistry General Physical Chemistry Inorganic Analytical Chemistry Inorganic Chemicals and Reactions Magnetic Phenomena Nuclear Phenomena Nuclear Technology Optical, Electron, and Mass Spectroscopy and Other Related Properties

3 3 of 7 Organic Analytical Chemistry Phase Equilibriums, Chemical Equilibriums, and Solutions Radiation Chemistry, Photochemistry, and Photographic and Other Reprographic Processes Surface Chemistry and Colloids Thermodynamics, Thermochemistry, and Thermal Properties Subscriber access provided by UNIV OF TEXAS ARLINGTON Home Browse the Journal List of Issues Current Issue Just Accepted Manuscripts Most Read Articles Most Cited Articles Sample Issue Author Index Cover Art Gallery Articles ASAP Current Issue Online News Latest News News Archive Environmental SCENE Multimedia Multimedia Index Top Papers Videos Blogs Submission & Review Info for Authors & Reviewers Submit a Manuscript or Review Ethical Guidelines Copyright & Permissions/Rightslink ACS Author & Reviewer Resource Center Subscriptions About the Journal About the Journal Editors Editor Profile Masthead [PDF] Advertising ACS Mobile is a mobile app for Android and Apple devices. Find out more Prev. Article Next Article Table of Contents

4 4 of 7 Abstract Full Text HTML Hi-Res PDF[1776 KB] PDF w/ Links[883 KB] Supporting Info Figures Sulak Sumitsawan, Jai Cho, Melanie L. Sattler, and Richard B. Timmons * Department of Civil Engineering, University of Texas at Arlington, Arlington, Texas 76019, United States Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, United States Environ. Sci. Technol., 011, 45 (16), pp DOI: /es01963 Publication Date (Web): July 15, 011 Copyright 011 American Chemical Society Phone: ; timmons@uta.edu. Section: Air Pollution and Industrial Hygiene Titanium dioxide (TiO ) is a preferred catalyst for photocatalytic oxidation of many air pollutants. In an effort to enhance its photocatalytic activity, TiO was modified by pulsed plasma treatment. In this work, TiO nanoparticles, coated on a glass plate, were treated with a plasma discharge of hexafluoropropylene oxide (HFPO) gas. By appropriate adjustment of discharge conditions, it was discovered that the TiO particles can be either directly fluorinated (Ti F) or coated with thin perfluorocarbon films (C F). Specifically, under relatively high power input, the plasma deposition process favored direct surface fluorination. The extent of Ti F formation increased with increasing power input. In contrast, at lower average

5 5 of 7 power inputs, perfluorocarbon films are deposited on the surface of the TiO particles. The plasma surface modified TiO nanoparticles were subsequently employed as catalysts in the photocatalytic oxidation of m-xylene in air, as carried out inside a batch reactor with closed loop constant gas circulation. Both types of modified TiO were significantly more catalytically active than that of the unmodified particles. For example, the rate constant of m-xylene degradation was increased from 0.01 min 1 with untreated TiO to min 1 with fluorinated TiO. Although it is not possible to provide unequivocal reasons for this increased photocatalytic activity, it is noted that the plasma surface treatment converted the TiO from hydrophilic to highly hydrophobic, which would provide more facile catalyst adsorption of the xylene from the flowing air. Also, based on literature reports, the use of fluorinated TiO reduces electron hole recombination rates, thus increasing the photocatalytic activity. View: Full Text HTML Hi-Res PDF PDF w/ Links Tools Add to Favorites Download Citation a Colleague Permalink Order Reprints Rights & Permissions Citation Alerts SciFinder Links Explore by: Get Reference Detail Get Substances Get Cited Author of this Article Any Author Research Topic (Now with patent search) (Now with patent search) History Published In Issue August 15, 011 Article ASAPJuly 5, 011

6 6 of 7 Just Accepted ManuscriptJuly 15, 011 Received: April 15, 011 Accepted: July 15, 011 Revised: June 8, 011 Recommend & Share ACS Network Facebook Tweet This CiteULike Newsvine Digg This Delicious Inactivation of MS Coliphage by Ferrous Ion and Zero-Valent Iron NanoparticlesEnvironmental Science & Technology Inactivation of MS Coliphage by Ferrous Ion and Zero-Valent Iron Nanoparticles Jee Yeon Kim, Changha Lee, David C. Love, David L. Sedlak, Jeyong Yoon, and Kara L. Nelson Environmental Science & Technology (16), pp Abstract: This study demonstrates the inactivation of MS coliphage (MS) by nano particulate zerovalent iron (nzvi) and ferrous ion (Fe[II]) in aqueous solution. For nzvi, the inactivation efficiency of MS under air-saturated conditions was greater than that... Abstract Full Text HTML PDF w/ Links Hi-Res PDF Wood Biodegradation in Laboratory-Scale LandfillsEnvironmental Science & Technology Wood Biodegradation in Laboratory-Scale Landfills Xiaoming Wang, Jennifer M. Padgett, Florentino B. De la Cruz, and Morton A. Barlaz Environmental Science & Technology (16), pp Abstract: The objective of this research was to characterize the anaerobic biodegradability of major wood products in municipal waste by measuring methane yields, decay rates, the extent of carbohydrate decomposition, carbon storage, and leachate toxicity. Tests... Abstract Full Text HTML PDF w/ Links Hi-Res PDF Temperature Dependence of the Reaction between the Hydroxyl Radical and Organic MatterEnvironmental Science & Technology Temperature Dependence of the Reaction between the Hydroxyl Radical and Organic Matter Garrett McKay, Mei Mei Dong, Jonathan L. Kleinman, Stephen P. Mezyk, and Fernando L. Rosario-Ortiz Environmental Science & Technology (16), pp

7 7 of 7 Abstract: The temperature-dependent bimolecular rate constants for the reaction of the hydroxyl radical (HO ) with organic matter (OM) (k OM HO ) have been measured for three natural organic matter (NOM) isolates and three bulk effluent organic matter (EfOM) samples... Abstract Full Text HTML PDF w/ Links Hi-Res PDF Other ACS content by these authors: Sulak Sumitsawan Jai Cho Melanie L. Sattler Richard B. Timmons Products User Resources Support Journals A Z About Us Get Help 1155 Sixteenth Street N.W. Washington, DC 0036 Books C&EN ACS Members Librarians For Advertisers Institutional Sales C&EN Archives Authors & Reviewers ACS Legacy Archives Website Demos ACS Mobile Video Partners Search ACS Publications Search Anywhere Search Copyright 011 American Chemical Society

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