Synthesis, Characterization and Properties of Energetic/Reactive Nanomaterials

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1 MATERIALS RESEARCH SOCIETY SYMPOSIUM PROCEEDINGS VOLUME 800 Synthesis, Characterization and Properties of Energetic/Reactive Nanomaterials December 1 5, 2003 Boston, Massachusetts, USA Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY ISBN: Some format issues inherent in the e-media version may also appear in this print version.

2 Copyright (2004) by the Materials Research Society All rights reserved. Printed by Curran Associates, Inc. (2010) For permission requests, please contact the Materials Research Society at the address below. Materials Research Society Proceedings 506 Keystone Dr. Warrendale, PA Phone: x 531 Fax: eproceedings@mrs.org Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY USA Phone: Fax: curran@proceedings.com Web:

3 TABLE OF CONTENTS Potential Usage of Energetic Nano-Sized Powders for Combustion and Rocket Propulsion... 1 Kenneth K. Kuo, Grant A. Risha, Brian Evans, Eric Boyer Effects of Very Small Particle Size on Processing and Safety Properties of Energetic Formulations Robert Wardle, Kenneth Lee, Jeff Akester, Paul Braithwaite Energetic Materials Development at Technanogy Materials Development Kevin C. Walter, Christopher E. Aumann, R. Douglas Carpenter, Edward H. O'Neill, David R. Pesiri Characterization of Airborne Ultrafine and Nanometer Particles During Energetic Material Synthesis and Testing Meng-Dawn Cheng, Charles M. Jenkins Synthesis and Characterization of Nanocrystalline Oxidizer/Monopropellant Formulations Thomas B. Brill, Bryce C. Tappan, Jun Li Nanostructured Energetic Materials with Sol-Gel Methods A. E. Gash, Joe H. Satcher Jr., Randall L. Simpson, Brady J. Clapsaddle Surface Passivation of Bare Aluminum Nanoparticles Using Perfluoroalkyl Carboxylic Acids R. Jason Jouet, Andrea D. Warren, David M. Rosenberg, Victor J. Bellitto The Dispersion and Polymer Coating of Ultrafine Aluminum Powders by the Ziegler Natta Reaction Cédric Roy, Charles Dubois, Pierre Lafleur, Patrick Brousseau Preparation of Energetic Metastable Nano-Composite Materials by Arrested Reactive Milling M. Schoenitz, T. Ward, E. L. Dreizin Synthesis and Characterization of Mixed Metal Oxide Nanocomposite Energetic Materials Brady J. Clapsaddle, Lihua Zhao, A. E. Gash, Joe H. Satcher Jr., Kenneth J. Shea, Michelle L. Pantoya, Randall L. Simpson Oxidation Processes and Phase Changes in Metastable Al-Ti Mechanical Alloys Xiaoying Zhu, M. Schoenitz, E. L. Dreizin The Catalytic Effect on Vertically Aligned Carbon Nanotubes Nam Seo Kim, Seung Yong Bae, Jeunghee Park Combustion Synthesis of Nanoscale Oxide Powders: Mechanism, Characterization and Properties Arvind Varma, Alexander S. Mukasyan, Kishori T. Deshpande, Pavol Pranda, Peter R. Erri

4 Combustion Synthesis of NiTi TiC Composites with Controlled Porosity for Biomedical Applications Douglas E. Burkes, Guglielmo Gottoli, John J. Moore, Hu Chun Yi, Reed A. Ayers Nickel Aluminide Superalloys Created by SHS of Nano-Particle Reactants Emily M. Hunt, John J. Granier, Keith B. Plantier, Michelle L. Pantoya Interface Properties of Al/Ni Multilayers as Deposited and Following Volume Combustion Synthesis M. Holtz, D. Aurongzeb, M. Daugherty, A. Chandolu, J. Yun, J. M. Berg, H. Temkin Ultrafast Spectroscopy of Laser-Initiated Nanoenergetic Materials Yanqiang Yang, Zhaoyong Sun, Shufeng Wang, Selezion A. Hambir, Hyunung Yu, Dana D. Dlott Performance and Characterization of Nanoenergetic Materials at Los Alamos Steven F. Son Ignition and Combustion Behaviors of Nanocomposite Al/MoO John J. Granier, Michelle L. Pantoya The Shock Initiation and High Strain Rate Mechanical Characterization of Ultrafine Energetic Powders and Compositions J. E. Field, S. M. Walley, W. G. Proud, J. E. Balzer, M. J. Gifford, S. G. Grantham, M. W. Greenaway, C. R. Siviour Application and Characterization of Nanomaterials in Energetic Compositions A. E. D. M. Van Der Heijden, R. H. B. Bouma, A. C. Van Der Steen, H. R. Fischer Embedded Cluster Model: Application to Molecular Crystals Maija M. Kuklja, Frank J. Zerilli, Peter Sushko Reactivity of Nanosize Aluminum with Metal Oxides and Water Vapor Jan A. Puszynski Nanofractography of Composition B Fracture Surfaces with AFM Y. D. Lanzerotti, J. Sharma, R. W. Armstrong, R. L. McKenney, T. R. Krawietz Characterization of Nano-Sized Particles for Propulsion Applications Grant A. Risha, Eric Boyer, Brian Evans, Kenneth K. Kuo, Rafaat Malek Underwater Explosive Behaviour of Compositions Containing Nanometric Aluminium Powder Leslie R. Bates Design of High-Energetic Materials at the Nanoscale Bijan K. Rao, Purusottam Jena Modeling Laser Generated Shock Damage and Thermo-Mechanical Chaos in Nanoparticles Bernard S. Gerstman Direct Evidence Of Chemical Reactions Induced By Shear-Strains John J. Gilman

5 Nanoscale Modeling of Shock-Induced Deformation of Diamond S. V. Zybin, I. I. Oleinik, M. L. Elert, C. T. White Formation of Nanostructured Energetic Materials via Modified Sol-Gel Synthesis Jeremy Walker, Rina Tannenbaum First-Principles Equation of State for an Energetic Intermetallic Mixture X. Lu, S. Hanagud Molecular Dynamics Studies of Nanoparticles of Energetic Materials Saman Alavi, Gustavo F. Velardez, Donald L. Thompson Single-Wall Carbon Nanotubes Field Emission Properties: A Theoretical Study of the Effects of Cs Brahim Akdim, Xiaofeng Duan, Donald A. Shiffler, Ruth Pachter Nanoscale Energetics with Carbon Nanotubes Yubing Wang, Sanjay Malhotra, Zafar Iqbal Synthesis and Characterization of Manganese Doped Ferroxane Nanoparticles Maria M. Cortalezzi, Jerome Rose, Eliza Tsui, Andrew R. Barron, Jean-Yves Bottero, Mark Wiesner High-Resolution TEM Characterization of Carbon Aerogels as Catalyst Supports Dafei Kang, Ying Zhang, Carl Saquing, Can Erkey, Mark Aindow Nanofibrous Manganese Dioxide for Decomposition of Volatile Organic Compounds H. Chen, T. D. Xiao, S. Liu Cutting Reactive Foils Without Igniting Them (A Femtosecond Laser Machining Approach) Yoosuf N. Picard, Hsiao-Hua Liu, Stephen J. Speys, Joel P. McDonald, David P. Adams, Timothy P. Weihs, Steven M. Yalisove Author Index

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