Chemical Engineering Thermodynamics
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1 1 Chemical Engineering Thermodynamics Fulbright Visiting Professor David J. Dixon Chemical and Biological Engineering Department South Dakota School of Mines and Technology WS 2009/2010
2 Overview 2 Introduction Chemical Engineering History Today s Chemical Engineering Chemical Engineering Thermodynamics Course Overview
3 Introduction Dr. David Dixon Professor of Chemical Engineering Chemical and Biological Engineering Department South Dakota School of Mines and Technology 3 Rapid City, South Dakota, USA
4 Rapid City near Black Hills Introduction 4
5 Introduction 5 Rapid City near Black Hills (Paha Sapa, Lakota for hills that t are black )
6 Rapid City (~60,000) 000) Introduction 6 Looking East Looking West
7 Introduction 7
8 Introduction SD School of Mines and Technology (SDSMT.edu) 8
9 Introduction SD School of Mines and Technology (SDSMT.edu) 9
10 Myself. Introduction 10 BS/MS/PhD Chemical Engineering SDSMT/SDSMT/University i i of Texas at Austin Dow Corning Corporation (Process Engineering) Overseas military service (Darmstadt) Professor SDSMT (16 yrs)
11 Introduction 11
12 United States: Chemical Engineering History J. Willard Gibbs 1 st PhD in Engineering in the U.S. (1863) L. M. Norton, MIT first ChE course (1888) 11 st BS program in Chemical Engineering, i U Pennsylvania (1892) American Institute of Chemical Engineers (AIChE) formed The chemical industry had a central position in the changing gindustrial world of the late 19 th century. This industry did not hatch fully grown; it was based on nearly a century s worth of scientific advances in the universities particularly German universities. Europe: N.A. Peppas, The First Century of Chemical Engineering, Chemical Heritage Newsmagazine, Vol. 26, No. 3, Fall 2008 Justus von Liebig ( ) Giessen Göttingen, g, Heidelberg, and other top universities.
13 Chemical Engineering History South Dakota: * "Discovered a Village of Small animals that t burrow in the grown... except the ears which is Shorter, his tail like a ground squirel which they shake & whistle when allarmd. the toe nails long, they have fine fur." * W. Clark - Friday, September 7, 1804
14 Today s Chemical Engineering 14 * Wikipedia, Chemical Engineering
15 Darmstadt (BS 3yrs MS 2yrs) Today s Engineering 15
16 Today s Chemical Engineering USA system (BS 4 yrs) 16 Programming and Numerical solutions to ChE problems Material and energy balances Fluid flow Heat transfer Mass transfer Unit U itoperations/separations Thermodynamics I and II Chemical kinetics and reactor design Senior design courses and project Process control Microbiology Global and contemporary issues in ChE ChE laboratory experiences Freshman modeling intro Fluid flow Process control intro Heat transfer Separations Elective lab Elective ChE courses Advanced separations Advanced reactor design System dynamics and modeling Polymer engineering Organosilicone chemistry Biochemical engineering Design of experiments for ChEs Coop experiences Undergraduate research
17 Today s Chemical Engineering USA system (BS 4 yrs) USA system (BS 4 yrs) -Professional organizations (AIChE, ACS, other) 17
18 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 18
19 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 19
20 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 20
21 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 21
22 Today s Chemical Engineering -Example, i.e. SCF measurements, others? 22 Supercritical Fluid Extraction (2 nd ), M. McHugh & V. Krukonis, Elsevier (1994)
23 Today s Chemical Engineering -Example, i.e. SCF measurements, others? 23 Supercritical Fluid Extraction (2 nd ), M. McHugh & V. Krukonis, Elsevier (1994)
24 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 24
25 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 25
26 Today s Chemical Engineering -Example, i.e. SCF measurements, others? -UO systems (discuss general PFD and where separations fits in plus other things like HT, MT, staged processes, etc) -Simulators: AspenPlus, Fluent, Comsol, ChemSep, others. 26
27 Course Overview 27
28 Course Overview 28
29 Course Overview 29
30 Course Overview Chapter 5 - Thermodynamic Web - Departure Functions - Review Equations of state (chapter 4, briefly) Chapter 6 - Equilibrium (chemical potential) * Pure Component * Mixtures Chapter 7 - Fugacity (chemical potential fugacity equilibrium calculations) * Vapor (overview), liquid, solids - Activity Coefficients [Fugacity Coefficients (overview)] Chapter 8 - Phase Equilibrium * Diagrams * Vapor Liquid (VLE) * Liquid Liquid (LLE) * Solid Liquid (SLE) Chapter 9 - Reaction Equilibria 30
31 Questions? 31
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