Study on form distribution of soil iron in western Jilin and its correlation with soil properties

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1 GLOBAL GEOLOGY Vol. 35 No. 2 Jun A > B > C > D > E > F > G A A CEC B ph C E A C D G B C D P595 S A doi /j. issn Study on form distribution of soil iron in western Jilin and its correlation with soil properties LIANG Shuo 1 LI Yue-fen 1 TANG Jie 2 WANG Yue-jiao 1 LI Qing-yu 1 1. College of Earth Sciences Jilin University Changchun China 2. College of Environment and Resources Jilin University Changchun China Abstract Through investigating 50 surface soil samples of three agricultural and pastoral areas Taonan City Tongyu County and Qian an County in western Jilin the authors explored form distribution and the relations between soil properties and soil iron form. The results show there exist 7 forms of iron including residual phase A > Fe -Mn oxide phase B > humic acid phase C > carbonate phase D > strong organic phase E > water solubility phase F > exchangeable phase G. A is the main form in soil of western Jilin and the average iron content of soil is lower than the background value in China. There is a significantly positive correlation between Caption Exchange Capacity CEC and A soil ph and B soil organic matter content and C E. Soil mineral elements are significantly correlated with A. C D and G are the next. The relations in different forms of soil iron show that B C and D have significantly positive correlations with each other while the other forms have little correlation. Key words iron form soil properties western Jilin yfli@ jlu. edu. cn

2 DD ~ ~ ~ 20 cm 40 ~ kg ± ph XRF -X NaOAc - ph CEC ph DD WS 3 EXC CARB WOM CBD SPSS SOM RES ~ mm 6 ~ RSD RSD 30% ~ mm 3. 4 ~ Excel SPSS19. 0

3 2 595 Table 1 1 n = 50 Statistics of soil properties in the studied area n = 50 /% ~ CEC /cmol kg ~ ph ~ /% ~ CEC /cmol kg ~ ph ~ /% ~ CEC /cmol kg ~ ph ~ mg kg ~ mg kg mg kg mg kg mg kg mg kg Table 2 2 Total iron content of soil in western Jilin /mg kg - 1 /mg kg ~ ~ ~ ~ Table 3 3 Content and percentage of different forms of soil iron in western Jilin /mg kg - 1 /% /mg kg - 1 /mg kg - 1 /% /mg kg ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~

4 mg kg % > % ~ % mg kg % > ~ mg kg mg kg % > 0. 01% ~ 0. 03% mg kg % > ~ mg kg mg kg % > mg kg % > mg kg % % % ~ % 10 > > > > > > 50 4 Table 4 4 Forms and content of iron in different types of soil n = 3 /mg kg - 1 n = 7 n = 3 n = 37 /% /mg kg - 1 /% /mg kg - 1 /% /mg kg - 1 /% CEC ph 5 CEC ph mg kg - 1 > mg kg - 1 > mg kg - 1 > mg kg

5 2 597 Table 5 5 Pearson correlation analysis between soil iron forms and soil factors ** ** CEC ** ph * ** * ** Table 6 6 Pearson correlation analysis between various forms of soil iron and total content of mineral elements As Se Al Ca Na Mn K Mg * ** ** * ** ** ** * ** ** * * ** ** * ** ** * ** ** ** ** ** * ** Na As Se 2. 3 Al Mg Al Ca Mg Al 7 7 Na Se Al Ca Mg 4 Na 7 3 Table 7 7 Pearson correlation analysis between various forms of soil iron * * * * ** ** * ** * **

6 ph ph ph 3. 8% 1% ~ 4% % mg kg - 1 ph 2. 74% 11 ph mg kg - 1 Fe ~ mg kg ph % % ~ 80% ~ mg kg mg kg mg kg > > > > > > ph CEC 15 CEC

7 2 599 factors affecting their availability in the west of Jilin Province J. Journal of Anhui Agricultural University J. Guangdong Trace Elements Science Northeast Normal University J J GOU Wen-ping LIU Shi-quan ZHANG Shi-rong et al. Status of soil available iron and its affecting factors in Ti- CHEN Lei LUO Dan LIANG Qiao-feng et al. Iron in bet J. Journal of Mountain Science transfer into tea leaves J. Fujian Journal of Agricultur- 3. al Sciences J J. ZHANG Ling-yun ZHANG Xian-fa QU Heng. Effects of soil factors on plant chlorosis due to iron deficit J. Chinese Journal of Soil Science al. Content of soil organic carbon and characteristics of D. elemental geochemistry in west of Jilin Province J Journal of Jilin University Earth Science Edition HAN Song-liang. Relation between iron nutrition status and soil environment of main peanut production area in western part of Jilin Province master s degree thesis D. Changchun Jilin Agricultural University Suppl J ZHOU Xiao-mei GUO Ji-xun ZHAO Jiang. Dynamics D WANG Zheng-yuan. Study on effect of iron supplementation to improve anemia population in Shanghai master s degree thesis D. Shanghai Fudan University of nutrient element iron in soil plant ecosystem of the Songnen Plain Leymus chinensis grassland J. Chinese Journal of Applied Ecology GIS 12. J J ZHANG Bo HONG Mei ZHAO Yong-sheng. On GIS YANG Jun-hui LI Da-xiang HUANG Min et al. The support distribution characteristics of the main compo- reasons and solutions of iron chlorosis in calcareous soil nents in the groundwater of the west plain region of Jilin Province China J. World Geology D. 1. J ZHOU Xiao-mei. Study on trace elements in land-plantanimal system of the Songnen plain Leymus LIU Xu-xin. The research progress of iron metabolism chinensis grassland doctor s degree thesis D. Changchun the soil of Tie Guanyin tea plantations in Fujian and its WANG Dong-yan YANG Yuan-yuan LI Yue-fen et J. Southwest Horticulture D J. L Jin-mei. The research to humic acid and heavy metal geochemistry in sediments of eastern Chongming tidal SHI Xian WANG Dong-yan LI Yue-fen et al. Study flat master s degree thesis D. Shanghai East on the available contents of trace nutrient element and China Normal University 2008.

8 J. CAI Zu-cong MA Yi-jie. The relations between organic LIU Wen-zhang. The morphological types and its pedogenetic significance of soil iron J. Journal of Hebei Normal University J HAN Chun-mei WANG Lin-shan GONG Zong-qiang ZHONG Xiao-lan ZHOU Sheng-lu HUANG Ming-li et al. Chemical form distribution characteristic of soil heavy metals and its influencing factors J. Ecology and Environmental Sciences surface of soil mineral colloid on heavy metal ions J. J Chinese Journal of Soil Science YANG Jin-yan YANG Xiao-e HE Zhen-li et al. Advance in the studies of Pb adsorption and desorption in soils J. Ecology and Environment area of three gorges reservoir J. Chinese Journal of J Soil Science ZHAO Zhi-zhong. Study on relationship between organic J. matter soil fractions and CEC in Qinghai soil J. Science and Technology of Qinghai Agriculture and Forestry matter and soil cation exchange capacity J. Process in Soil Science J et al. Chemical forms of soil heavy metals and their environmental significance J. Chinese Journal of Ecology J WU Mei-ling. The specific adsorption of variable charge 21. J WANG Gai-gai FU Wa-li WEI Chao-fu et al. Iron transformation and phosphorus availability in a drawdown Dilbar Sultan Anwer Mohammed LIN Juan. Soil ironand manganese forms and their availability to plants 18. J. Chinese Journal of Ecology J

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