SECURITY MARKING. NOTICE: When government or other drawings, specifications or other

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1 SECURITY MARKING The classified or limited status of this report applies to each page, unless otherwise marked. Separate page printouts MUST be marked accordingly. THIS DOCUMENT CONTAINS INFORMATION AFFECTING THE NATIONAL DEFENSE OF THE UNITED STATES WITHIN THE MEANING OF THE ESPIONAGE LAWS, TITLE 18, U.S.C., SECTIONS 793 AND 794. THE TRANSMISSION OR THE REVELATION OF ITS CONTENTS IN ANY MANNER TO AN UNAUTHORIZED PERSON IS PROHIBITED BY LAW. NOTICE: When government or other drawings, specifications or other data are used for any purpose other than in connection with a definitely related government procurement operation, the U. S. Government thereby incurs no responsibility, nor any obligation whatsoever; and the fact that the Government may have formulated, furnished, or in any way supplied the said drawings, specifications, or other data is not to be regarded by implication or otherwise as in any manner licensing the holder or any other person or corporation, or conveying any rights or permission to manufacture, use or sell any patented invention that may in any way be related thereto.

2 - Z-7 17~-, NDS REPORT 8808 I A B:CBIOGFIAMZ OF A2MNUAL FOR TD3 TaERMOPRSICAL POETE HEMU[IM-4i, F')GE10a~, DEUj'TWA,, EXMOGE.9 DwmiUT1m, xq, maon, 0Z- NITROGEN, OXG, CRBON DMMJDE, HMHNE, ~TIIEK~~N T U-1REFMIGERANTS 13, 14, AND 23 (t~cryogenic Data Center ~D C US. DEPARTMENT OF COMMERCE NATIONAL RUREAU OF STANDARDS BO1ULDER LABORATORIES I--' -~Bouldor, Colorado BEST AVAILABLE COPY

3 44 THE NATIONAL BUREAU OF STANDARDS The National Bureau of Standards is a principal focal point in the Federal Government for assuring maximum application of the physical and engineering sciences to the advancement of technology in industry andcommerce. Its responsibilities include development and maintenance of the national standards of measurement, and the provisions of means for making measurements consistent with those standards; determination of physical constants and properties of materials; development of methods for testing materials, mechanisms, and structures, and making such tests as may be necessary, particularly for government agencies; cooperation in the establishment of standard practices for incorporation in codes and specifications; advisory service to government agencies on scientific and technical problems; invention and development of devices to serve special needs of the Government; assistance to industry, business, and consumers in the development and acceptance of commercial standards and simplified trade practice recommendations; administration of programs in cooperation with United A States business groups and standards organizations for the development of international standards of practice; and maintenance of a clearinghouse for the collection and dissemination of scientific, technical, and engineering information. The scope of the Bureau's activities is suggested in the following C listing of its four Institutes and their organizational units. Institute for Basie Standards. Applied Mathematics. Electricity. Metrology. Mechanics. Heat. Atomic Physics. Physical Chemistry. Laboratory Astrophysics.* Radiation Physics. Radio Standards Laboratory:* Radio Standards Physics; Radio Standards Engineering, Office of Standard Reference Data. histitute for Materials Research. Analytical Chemistry. Polymers. Metallurgy. Inorganic Materiais? Reactor Radiations. Cryogenics.* Materials Evaluation Laboratory. Office of Standard Reference Materials.' Institute for Applied Technology. Building Research. Information Technology. Performance Test 4) Development. Electronic Instrumentation. Textile and Apparel Technology Center. Technical Analysis. Office of Weights and Measures. Office of Engineering Standards. Office of Invention and Itinovation. Office of Technical Resources. Clearinghouse for Federal Scientific and Technical Information." Central Radio Propagation Laboratory.* Ionospheric Telecommunications. Tropospheric Telecommunications. Space Environment For,casting. Aeronomy.,Loatedat Boulder, Colorado * Located at 5285 Port Royal Road, Springfield, Virginia /, I,

4 NATIONAL BUREAU OF STANDARDS REPORT QV hOot ) a 6'k ;40'315o ma -ra 5 NBS PROJECT '~. N. REPORT A BIBLIOGRAPHY OF REFERENCES FOR THE THEMOPHYSICAL PROPERTIES OF HELIUM-4, HYDROGEN, DEUTERIUM, HYDROGEN DEUTERIDE, NEON, ARGON, NITROGEN, OXYGEN, CARBON DIO)CEDE, METHANE, ETHANE, KRYPTON, AND REFRIGERANTS 13, 14, AND 23 e Cryogenic Data Cente r. IMPORTANT NOTICE NATIONAL BUREAU OF STANDARDS REPORTS are usually preliminary or progress accounting documents intended for use within the Government. Before material in the reports is formally published it is subjected to additional evaluation and review. For this reason, the publication, reprinting, reproduction, or op.en-literature listing of this Report, either in whole or in part, is not authorized unless permission is obtained in writing from the Olfice of the Director, National Bureau of Standards, Washington, D.C Such permission is not needed, however, by the Government agency for which the Report has beerl specifically prepared if that agency wishes to reproduce additional copies tor its own use. tms-paffment1:eoffltw rao NATIONAL BUREAU OF STANDARDS)!- i " I

5 lii A BIBLIOGRAPHY OF REFERENCES FOR THE THERMOPHYSICAL PROPERTIES OF HELIUM-4, HYDROGEN, DEUTERIUM, HYDROGEN DEUTEIIDE, NEON, ARGON, NITROGEN, OXYGEN, CARBON DIOXIDE, METHANE, HANE, KRYPTON, AND REFRIGERANTS 13, 14, AND 231 Introduction This bibliography represents a search of the information storage and retrieval system of the Cryogenic Data Center. The storage and retrieval system contains approximately 11,000 references to properties of materials at cryogenic temperatures. The bibliography contains references to the following fluids and their mixtures: helium- 4, normal hydrogen, parahydrogen, orthohydrogen, deuterium and hydrogen deuteride, neon, argon, nitrogen, oxygen, carbcn dioxide, nethane, ethane, krypton, and refrigerants 13, 14, and 23. The properties which were searched for are: PVT data, compressibility, expansivity, vapor pressure, melting lne, triple point, boiling point, critical point, solid transition points, phase diagram, latent heats, heat capacity, enthalpy, entropy, velocity of sound, thermal conductivity, viscosity, equations of state, Joule-Thomson coefficient, and surface tension. The Cryogenic Data Center is engaged in maintaining an awareness of the world's literature on the properties of materials at cryogenic temperatures and in particular on the properties of the cryogenic fluids- Other fluids of some cryogenic interest are also noted for.the sy em ut to a lesser degree of exhaustivity; therefore, the references t he properties of carbon dioxide, ethane, krypton and refrigerants 14, and 23 represent a smaller proportion of the world's literatur an for the predominantly cryogenic fluids. The bibliogra hy contains an index which lists, for each fluid, entries for all of the roperties mentioned above. The references are arranged in numerical o der by accession number. Each reference is followed by the indexing information used in the storage and retrieval system. The first of thi is the characteristic coding which is explained on page iv. Thi is followed by the coordinate indexing terms used for that reference. ' This bibliography was made for Air Pioducts art, Chemicals, Inc., Allentown, Pennsylvania, for use on a government contract.

6 V.. iv CHARACTERISTIC CODING DESIGNATIONS for CRYOGENIC LITERATiURE Cat egories A-l: A-2: A-3: A-4: A-5: A-6: A-7: A-8: A-9: Books, Reviews, Surveys, Bibliographies, Proceedings, etc. Properties of Solids Properties of Fluids Solid State, Theoretical, Phenomena, Basic Physics, etc. Cryogenic Techniques, Tricks, Unique Methods, Unusual Procedures, etc. Cryogenic Processes, Heat Transfer, Purification, Fluid Flow, Liquefaction, Safety Procedures, etc. Laboratory Equipment and Instrumentation Cryogenic Equipment General Interest Literature, News, Management, Programs, Accidents, Miscellaneous Spuage B-l: English, B-2 French, B-3 German, B-4 Dutch, B-5 Italian, B-6 Japanese, B-7 Russian, B-8 Spanish, B-9 Other J Cryogenic Interest C-1: Cryogenic Temperature Range (0 to 130*K where not specifically designated in C-4 through C-7 below) C-2: Cryogenic Interest but not in Cryogenic Temperature Range (except where designated C-8) C-3: Not of Direct Cryogenic Interest C-4: Below 1 0 K C-5: 1 to lo K C-6: 10 to 50 0 K C-7: 50 to K C-8: 130 to K Form of Data (Omitted where not pertinenz) D-l: D-2: D-3: Numerical Data Included No Data Graphical Data Only Type of Article (Omitted where not pertinent) E-l: E-2: E-3: Experimental, Experimental and Theoretical, Original Work Review Article, Compilation, Correlation, Discussion Theoretical Only, No Specific Data Given Availability of Document (suggested sour - ) F-1: Cryogenic Engineering Laboratory F-2: National Bureau of Standards F-3: Office of Technical Services (OTS) F-4: U.S. Government Printing Office F-5: Armed Forces Technical Information Agency (ASTIA) F-6: Technical Libraries Generelly (Published Literature) F-7: Technical Libraries - Special (Foreign Literature - Special Periodicpls) F-8: Company Bulletins and Reports (Universities, Research Labs., etc.) F-9: Other (Patents, Theses, Translations, etc.) Form of Document G-l: G-2: G-3: G-4: G-5: G-6: G-7: G-8: G-9: Published - Open Literature, Journals, etc. Books, Proceedings Company Periodicals (includes Universicy, Foreign Gov't, State Institutions, etc.) Government Periodicals (U.S.) Company Reports, Private, Public, Gov't Contract (includes Foreign Gov't Reports) Government Reports (U.S.) University Theses, Doctoral Dissertations, Master's Theses Patents (U.S. and Foreign) Other (Unpublished, Informal, Preprints, Letters, Notes, Term Papers, Talks, etc.)

7 PROPERTY INDEX LOCATIONS5 FOR THE FLUIDS PAGE NO. 1. HELIUM-4 OR UNSPECIFIED HELIUM 1 2. HYDROGEN As NORMAL OR UNSPECIFIED HYDROGEN 5 B* PARAHYDROGEN 9 Co ORTHOHYDROGEN 11 Do DEUTERIUM OR HYDROGEN DEUTERIDE NEON 15 4o ARGON NITROGEN OXYGEN 24 7o CARBON DIOXIDE 27 8o METHANE ETHANE KRYPTON REFRIGERANTS A. REFRIGERANT Be REFRIGERANT C. REFRIGERANT Do OTHER REFERENCES TO REFRIGERANT PROPERTIES 42

8 1 BIBLIOGRAPHY INDEX HELIUM 4 OR UNSPECIFIED HELIUM PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) COMPRESSIBILITY EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE ' MELTING LLNE DATA , TRIPLE POINT NONE

9 2 HELIUM (CONT,) BOILING POINT CRITICAL POINT SOLID TRANSITION POINTS PHASE DIAGRAM LATENT HEAT (INCLUDES KEATS OF FUSION. SUBLIMATION AND VAPORIZATION) HEAT CAPACITY , ENTHALPY ENTROPY

10 3 HELIUM (CONT* VELOCITY OF SOUND , THERMAL CONDUCTIVITY VISCOSITY

11 4 HELIUM (CONT) EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) $ , ' JOULE-THOMSON EFFECT SURFACE TENSION

12 NORMAL OR UNSPECIFIED HYDROGEN PVT DATA tncludes DENSITY AND COMPRESSIBILITY FACTOR) , COMPRESSIBILITY EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE MELTING LINE UATA

13 6 HYDROGEN (CONT.) TRIPLE POINT BOILING POINT lloc CRITICAL POINT SOLID TRANSITION POINTS NONE PHASE DIAGRAM LATENT HEAT (INCLUDES HEATS OF FUSIOI. SUBLIMATION AND VAPORIZATION) HEAT CAPACITY

14 7 HYDROGEN (CONT.) ENTHALPY ENTROPY VELOCITY OF SOUND ' THERMAL CONDUCTIVITY P2 25Z

15 8 HYDROGEN (CONTo) VISCOSITY EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) ' JOULE-THOMSON EFFECT SURFACE TENSION

16 9 PARAHYDROGEN PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) COMPRESSIBILITY EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE * MELTING LINE DATA TRIPLE POINT BOILING POINT CRITICAL POINT, SOLID TRANSITION POINTS NONE PHASE DIAGRAM NONE LATENT HEAT (INCLUDES HEATS OF FUSION* SUBLIMATION AND VAPORIZATION)

17 10 PARAHYDROGEN (CONT.) HEAT CAPACITY ENTHALPY b ENTROPY VELOCITY OF SOUND THERMAL CONDUCTIVITY VISCOSITY EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) , JOULE-THOMSON EFFECT SURFACE TENSION

18 11 ORTHOHYDROGEN PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) 6368 CONPRESSIBILITY NONE EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) NONE VAPOR PRESSURE MELTING LINE DATA 6368 TRIPLE POINT BOILING POINT 2040 CRITICAL POINT NONE SOLID TRANSITION POINTS.NONE PHASE 'DIAGRAM NONE LATENT HEAT (INCLUDES HEATS OF FUSION9 SUBLIMATION AND VAPORIZATION)

19 12 ORTHOHYDROGEN (CONT.) HEAT CAPACITY ENTHALPY ENTROPY VELOCITY OF SOUND NONE THERMAL CONDUCTIVITY VISCOSITY EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) JOULE-THOMSON EFFECT NONE SURFACE TENSION NONE

20 13 DEUTERIUM OR HYDROGEN DEUTERIDE PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) COMPRESSIB. LITY EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE MELTING LINE DATA TRIPLE POINT BOILING POINT CRITICAL POINT SOLID TRANSITION POINTS NONE PHASE DIAGRAM NONE LATENT HEAT (INCLUDES HEATS OF FUSION* SUBLIMATION AND VAPORIZATION)

21 14 DEUTERIUM (CONT.) HEAT CAPACITY ENTHALPY ENTROPY VELOCITY OF SOUND THERMAL CONDUCTIVITY VISCOSITY , EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) , JOULE-THOMSON EFFECT SURFACE TENSION

22 15 NEON PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) ) COMPRESSIBILITY 8aci EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE MELTING LINE DATA TRIPLE POINT c BOILING POINT CRITICAL. POINT , SOLID TRANSITION POINIS NONE PHASE DIAGRAM LATENT HEAT (INCLUDES HEATS OF FUSION* SUBLIMATION AND VAPORIZATION)

23 16 NEON (CONT.) HEAT CAPACITY f' ENTHALPY , ENTROPY VELOCITY OF SOUND THERNAL CONDUCTIVITY VISCOSITY EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) JOULE-THOMSON EFFECT SURFACE TENSION

24 17 ARGON PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) COMPRESSIBILITY EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE MELTING LINE DATA TRIPLE POINT BOILING POINT

25 18 ARGON (COtIT.) CRITICAL POINT : SOLID TRANSITION POINTS NONE PHASE DIAGRAM LATENT HEAT (INCLUDES HEATS OF FUSION. SUBLIMATION AND VAPORIZATION) HEAT CAPACITY ENTHALPY " EMT MOPY VELOCITY OF SOUND

26 19 ARGON (CONT.) THERMAL CONDUCTIVITY " VISCOSITY > EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) JOULE-THOMSON EFFECT SURFACE TENSION

27 20 NITROGEN PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) COMPRESSIBILITY EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE MELTING LINE DATA

28 21 NITROGEN (CONTo) TRIPLE POINT BOILING POINT CRITICAL POINT SOLID TRANSITION POINTS PHASE DIAGRAM LATENT HEAT (INCLUDES HEATS OF FUSION# SUBLIMATION AND VAPORIZATION) (k HEAT CAPACITY

29 22 NITROGEN (CONT.) ENTHALPy ;;144z3 ' ENTROPY VELOCITY OF SOUND THERMAL CONDUCTIVITY ? '

30 23 NITROGEN (CONT,) VISCOSITY , A9Q & " EQUATIONS OF STATE (INCLUDES VIRIAL COEFFICIENTS) ' JOULE-THOMSON EFFECT SURFACE TENSION

31 24 OXYGEN PVT DATA (INCLUDES DENSITY AND COMPRESSIBILITY FACTOR) ' COMPRESSIBILITY ? EXPANSIVITY (INCLUDES COEFFICIENT OF THERMAL EXPANSION) VAPOR PRESSURE MELTING LINE DATA TRIPLE POINT BOILING POINT -.,

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