Dually Flat Geometries in the State Space of Statistical Models
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1 1/ 12 Dually Flat Geometries in the State Space of Statistical Models Jan Naudts Universiteit Antwerpen ECEA, November 2016 J. Naudts, Dually Flat Geometries in the State Space of Statistical Models. In Proceedings of the 3rd Int. Electron. Conf. Entropy Appl., 1 10 November 2016; Sciforum Electronic Conference Series, Vol. 3, A004 (2016); doi: /ecea-3-a004.
2 2/ 12 Outline 1. A manifold of equilibrium states 2. Dually flat geometries 3. Thermodynamic length 4. The ideal gas 5. Conclusions
3 3/ A manifold of equilibrium states Application of differential geometry to thermodynamics initiated by Weinhold (1975) Metric space (Hilbert space) spanned by extensive variables X i such as internal energy, total magnetization, number of particles,... Present work: uses canonical ensemble of statistical mechanics. Relevant potential: Φ = log Z, (Z is the partition sum) instead of energy, entropy, free energy,... Scalar product defines metric tensor g: g ij = X i, X j. Ruppeiner (1979) The metric tensor g is determined by fluctuations + correlations. Riemannian curvature, determined by g, implies interactions. No curvature for the ideal gas model.
4 4/ 12 Boltzmann-Gibbs distribution p(x) = 1 Z e β[h(x) hm(x)] H(x) is Hamiltonian, M(x) is total magnetization β is inverse temperature, h is external magnetic field Z = Z(β, h) the normalization. Statistics: the BG distribution belongs to the exponential family because it can be written into the form p θ (x) = exp(θ k F k (x) Φ(θ)). θ 1 = β, F 1 (x) = H(x), θ 2 = βh, F 2 (x) = M(x), Φ(θ) = log Z(β, h). Derivatives of Φ(θ) yield expectation values: k Φ(θ) = F k θ.
5 5/ 12 The p θ (x) form a differentiable manifold M. The variables X k with X k = F k F k θ span a tangent plane. The obvious scalar product is U, V θ = dx p θ (x)u(x)v(x). The metric tensor g is given by g ij (θ) = X i, X j. The Christoffel symbols are defined by Γ k ij = 1 2 gks ( i g sj + j g is s g ij ), They determine the Riemannian curvature of the manifold.
6 6/ Dually flat geometries Geometry: metric tensor g(θ) plus geodesics Geodesics are solutions of Euler-Lagrange eq. θ k +ω k ij θ i θ j = 0. The coefficients ω k ij determine the connection. Riemannian curvature : Levi-Civita connection : ω = Γ (Amari 1985) A model belonging to the exponential family has dually flat geometries ω = 0 and ω = 2Γ. Duality of connections is related to the duality known from thermodynamics. Replacing acceleration Γ by 2Γ removes any curvature. This holds when using the canonical coordinates θ k of the exponential family.
7 7/ 12 Thermodynamic duality: two potentials S(U) and Φ(β) satisfy ds du = β and dφ dβ = U. Entropy S(U) is the Legendre transform of Φ(β) (Massieu 1869). Several variables: η i and θ j are dual coordinates: η i = Φ θ i = F i θ and θ j = S η j. Φ(θ) and S(η) are dual potentials: Φ(θ) = sup{s(η)+θ k η k }, and η S(η) = inf θ {Φ(θ) θk η k }.
8 8/ Thermodynamic length Geodesics for ω = 0: θ k (t) = (1 t)θ k (t = 0)+tθ k (t = 1). Geodesics for ω = 2Γ: θ k (t) = θ k [(1 t)η(t = 0)+tη(t = 1)], with θ[η] inverse function of η(θ). Thermodynamic length: integrate ds = g ij θ i θ j along geodesic. Easy calculation when coordinates known in which the geodesic is a straight line.
9 9/ The ideal gas Probability density for x in n-particle phase space f(x, n) = 1 Z e β(hn(x) µn). β is inverse temperature, µ is chemical potential, H n is Hamiltonian for n free particles, enclosed in volume V. Let θ 1 = β/β 0, θ 2 = βµ, F 1 (x, n) = H n (x), F 2 (x, n) = n. ideal gas model belongs to the exponential family. Calculations ) 3/2, ( Φ(β,µ) = log Z = V V 0 e βµ β0 β with numerical constants V 0, β 0. N n = Φ(β,µ) ideal gas law βpv = N where p is pressure.
10 10/ 12 η 1 = 3 Φ and η 2θ 1 2 = Φ. ( 15 g(θ) = 1 3 ) Φ 4θ 1 2 θ θ 1. Christoffel symbols: ( ) Γ 1 5/2θ 1 1/2 = and Γ 2 = 1/2 0 ( 15/8[θ 1 ] /2 ). Riemannian curvature vanishes. Tedious calculation.
11 11/ 12 Example of ω = 0 geodesic: isotherm: β is kept constant, µ varies linearly. Thermodynamic length = 2 N (2) N (1) Example of ω = 2Γ geodesic: pv is kept constant, N varies linearly. Thermodynamic length proportional to change in N.
12 12/ Conclusions Application of differential geometry to thermodynamics is considered here for models belonging to the exponential family. Amari s dually flat geometries are also meaningful in a thermodynamical context. Future work: application to models of interacting particles.
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