! " #$ %&'( ) * 3/- "12$

Transcription

1 otr!!" # x w?cq i u 3- =4 0 \ $ ( / 4 1!* ( # ' % 1/23#!*0 #,-# /!** #! " #$ %'( ) *,- / 0 "12$! " #$ %'( ) * 3/- "12$ ( / / : / / : ) -" - />!?! = < 4 / :0 16(Na, K)6[l6Si30O2]20H2O / '/9*,/' 0 //8! $46* :/ 6 < D, 0 < 3 "1- H < /'G EF D/? B C9 < 4 = /! < 4 /'G < 4" - />!?! / '/9*,/' 1- " * B Q <0 O P 1 < K3L,3 M N KG 9 Bal2Si6O166H2O % 4 Bal2Si3O104H2O / 9#, = < 4 / :0 = /! B C9 < //8! < 4" 1- G R < 4F " C9 0 / R S - 1, 0 //8! 1,9 R G SEM T! U/ XRD < 4 3 % 4 V / 9#, V R S - V0 [ ] 1 H/4 / '/9*,/' / < 9P 4 - L =/ 9* 0,N S 1 H/4 //8! <" 1 =/ 0 - / " =/ /'/ "1 U! / 4 / ' / h/'/ % 4 / "1,, \! 2 \ N,( 1 "1c P <"1,, U/ /#, B U' 4 40 R M` L [i ] <0 $ - / :0 Y 1! //8! / :0 '3L 0 4 R />!?! / '/9*,/' / X/^ < 4 / 9#, 1 L H < B C9 j/! M? < > < 4 0 " Bal2Si3O104H2O tutti@khayamutacir : 2/ 92 //8! V / '/9*,/' : / 9 $ #/:# 1,9 4 < " C@ < 4B 2/'/,/ 0 4 R 4 / :0 Z X! Y G < 4 /! < 0 < G W, 0 M[L U/ " P /'G /'G Q,( 0 / '/9*,/' [ ] 1 M < 4\2 '! =9 / ( =/ ' =/ 9* = 1 B 2/'/,/ ) 1, X/^ < 4 / :0 0 2 [ ] Y/ ]! < 4" C@ 0 4 R ( > / X/^ / :0 4 -M - < 4 a 0 < ` ` < 4_,,/ 1! U d > /'G - < 4c P b/3( < 4 R <" "1- Y/2$! L / * R R '( 1,9 4 4e $C$! < 4 $/- 2 9 * (qnm) llrsmlnt : 3 (qnm) lmmmnomp :C'! \k "1,

2 ,-,- ' 'y X 1 < 4\'? />!?! 9/ '/9*,/' /9 S - < G W, 9G Ba2 /! /'G \'? B y " #$ 0 /'G M R L H PH D - y = 1 1/ 1/4 =/4 G > / / :0 \F? 1, 9 a 4 P,- W, B Q 9 [* B Q X/^ R R < 4S/? 9 '! < 4 Y/2$! S - <0 0 W'N //8! L '! 1 X/^ U/,/ {/* 4 R L < 4 /! < W < D, < 4 / :0?Q 4 #$ " C9 <U9, < 4 3 < D, 9 Y/2$! < 4 / :0 0 < 4 3 <# " '9 < 4" 9 R "1- < 4 / :0 < 1 * <" 9 R =/! Y/2$! (* <$/=) //X! K3L,3 G " C < D, 0 ( / '/9*,/') / <" "1- * <0 O P 1 "1- < $ D, "1- % y < 4 9 R 9/ 9/ < 4e //8! 0 4 / :0 [ ] 1 "1 L /'G! S/? < 4F 0 / M R S - {46* * < 40,- "1- G R ) ƒ/! ),3 0 - P (XRD) )2 * '/ i S - [* //8! =R U y Y2/ 9'/ ƒ / T! R B Q h '/ (SEM) $ * 9 ƒ / U/ "1- /! '/ x S - Vega Tescan \1 ( Y2-) 0 N 3 )2 * <# " Y/2$! / '/9*,/' 0 H 1Q $ 3 U /a / / / < 4 'G U/ / < 4 'G -h34 L '( "1- 'G { 3 0 / '/9*,/' < 4 'G # 12 / "1- -*=$a 3 < < 4 ( Y2-) 0 N 3 SEM T! 1 < 9- < 4 /, / '/9*,/' ' G M/ ^^ -R a M = S '! =9 / [ x] -#9 < 9$/ M d!,( 9 \! /' G / 9#, B X z < /CT! M % < ' ( - " <0 * < 41, 0 * < 4 / :0 # 0 Bal2Si6O166H2O % 4 Y/ ]! '! =9 / < > < 4 / :0 0 2 = \'? 9 ] / h/'/ - M? '! =9 / < 4 1,4 Y/2$! 1 L L a Ma a =/ 9 { /* y/9 -#9 2 -" # L Ba K ~ U < 4 /! }@ > 1 - Y/'! Y/ ]! 1- < 9P 2- R < 4 = 9,/ * W'N 1 S / :0 1 4 /! 9/, 9 0 < 4_, L < 4" C@ B Q j'n R < 4 R 9$/ U/ 4)/,R - B Q U/! "1/$ 9 < 4 ' 9$/ 1, - Y/2$! U/ / * #a ( X /3 /Q,( 4 / :0 /* U! /'/9 1 H/4 " 34 j'n [ i ] - "1 / 9#, 9 { U < 9$/ 4 / :0 4 #$ 0 < 4 B Q 0 //8! 2 U/ \! =/ / '/9*,/' 0 //8! [ x] F 9 R / 9#, U9, = 1 <H W'N /'G S #/9 < L < '/ $ 0 }X =! 2/'/,/ < 4 $/- 0 " C9! 2/'/ \d 0 % 4 Y/2$! <U9, < 4 B Q / L " 34 = 1 = / * < 9? [ ] 9 R 1, < %0H O $ B1 4 / :0 < y! < 4 /! < 4\'? }@ P <" 9 R />! $46* /R B Q { 0 Y/2$! / '/9*,/' < B C9 < 4 = = 1 /'G <" - }@ = < 4 / :0 0 e14 9 R G H < 40 U9, 2 / / :0 0 //8! {46* < " H < /'G M R S >

3 = < 4 / :0 / '/9*,/' X/^ / :0 0 XRF (Primary) / < 3 Sample Primary //8! 9 0 i " 3- /3/- j/! *<$/= SiO2 l2o3 Fe2O3 CaO Na2O K2O MgO TiO2 MnO P2O /x / / /x / / :(Mor) /i / x / /x / < 3 )2 * * <# B 6% / :(b) / :(Mor) / '/9*,/' :(Clin) / '/9*,/' :(Clin) / < 3 92 ƒ2 2/ T! C6% / 1'L

4 ,-,- ' 'y # 1# <U9, < 4 3 / < 3 )2 1 "1%1( }@ <"1,4 $ < < 4 3 P \F? e[@ # B ( 4 }@ )2 * < # P Y/2$! = > = 1 /! W'N W <U9, < 4 3 B C9 (S1a) <U9, < 3 Y/2$! S - < G < / (3y / 0 \ < 3 <"1 /R 0/ ( H /x) 1 9$/ = 1 /! W'N Y/2$! = /R H x = W'N 9 R W ( / % < 0 3 / ) (S2a) <U9, < 3 93 ( H /x) 9 R W > = 1 W'N 14 -, =/9 R W = < ( H / x) W'N / < 3 3! (S1a) <U9, < 3 Y/2$! ^ "1- G R S "1- Y@ = 9/ :0 < 4" L < 4 /!, U# L Y/2$! / 1/4 " )/'/ / 9#, \F? 3z (S2a) <U9, 3 1 "1/! W'N 93 }@ '( / '/9*,/' 4M R = 1 9$/ }@ = " 34 b/g D/? 93 = 1 9/ :0 % 4 1- Y/2$! / L X 1 G M/ /'G \'? ^^ />!?! < / 3 $46* ) BaCl22H2O (= 1 < 3$a,( ) NaOH < L x > < (= < 3$a,( B Q 1 = G ( B1 #/9 NaOH 9/ '/ / '/9*,/' % R x U34 /G B1 ' O $ W'N rpm (Heidolph MR 3001 K ) /^,8 \'? 0 9/ '/ 1X < '@ = 0 =4 Y ^ < '@ ' ( W < 4 W'N ) BaCl22H2O " 0 =4 /^,8 U34 /G B1 z YG z D M 9/ '/ W ' )h 1< Y 9, 'C! F ' " 0 -[R 0 )* = G "1- B1 x9c eq YP " P 0 F W M Q [N " M <$9-0 )* = ]$P! < D > W'N = /! W'N //8! 2 B //8! = W'N 9- # > # = 1 = G = 1 W'N $ D3 <H > W'N = /! W'N //8! 0 N * * < 4 3 Y2- [* B Q = 1 : (C ) ˆW ˆ < ˆ4 3 (S2a)<U9,ˆ < ˆ 3 (S1a)<U9,ˆ < ˆ 3 (O) ˆ/ < ˆ 3 )ˆ2 ˆ! * ˆ* < ˆ4 3 E6% / 1/4 : (HS) =/ : () / L : (F) % 4 : (H) / 9#, : (E) / : (b) / : (Mor) / '/9*,/'

5 = < 4 / :0 / '/9*,/' X/^ / :0 0 / % < 0 <U9, < 3 / (S2b)<U9, < H x W'N ( H /x) 9 R > = W'N <U9, < 3 Y/2$! 14 -, =/9 R W = 1 R S - "1- Y@ P / < 3 (S1b) " 34 Y2- E! B Q / 9#, "1- G - Y/2$! / 1/4 U/ / '/9*,/' 0 -= 1 /'G \'? / * W'N S - 14 \F? B 1G U/ / '/9*,/' \F? U34 (S2b) <U9, < 3 W'N U/ = /! <H > }@ / L " 34 % 4 4 R = 1 <H - Y/2$! / 1/4 :(SOD) / 9#, : ( EDI)1 - "1 //8! 9 0 i " 3-1'L =/ "1<"1- <U9, < 4 3 L <U9, = 1 < 4 # U/ / 1/4 < 3 SEM T! iy2-1,4 Y/2$! S/? (S2a)<U9, 3 SEM T! xy2- (S1a) <U9, 1,4 $ RS!H = W'N C@ % % R / x) 1 Y2= % y = 1 W'N! //8! ( H <U9, < 4 3 / < 3 )2 * U/ < "1 W B //8! <"1 /R (S1b) <U9, < 3 U/ 1, W'N / (3y / 0 % <U9, 3 9 R W ( H /x) 1 9$/ = /! < 3 Y/2$! = /R H / x = 1 W'N / 1/4 " 34 / 9#, < 4 ' :(S1a)<U9, < 3 F6% ˆ " ˆ34 =/ ˆ < ˆ4 ' : B ˆ/ '/9*,/' 0 ˆ ˆ " ˆ34 % ˆ4 : jˆ/!! ˆ Ša 0 :(S2a)<U9, < 3 G6% /ˆ L :(Fau) =/ ˆ :(n) % ˆ4 :(Har) ˆ/ '/9*,/' :(clin) 1 ˆ- "1 / 1/4 / L : C / 1/4 / 1/4 :(SOD)

6 ,-,- ' 'y X 1 G M/ ^^ : (C ) ˆW ˆ < ˆ4 3 (S2b)% <U9,ˆ < ˆ 3 (S1b) <U9,ˆ < ˆ 3 (O) / < 3 )2 * * < 4 3 H6% / 1/4 : (HS) =/ : () / L :(F) % 4 : (H) / 9#, : (E) / : (b) / : (Mor) / '/9*,/' S - 1 :1- U/ 0 /3/- {, U/ G "1- U9, / % (3y 18(Na,K)6[l6Si30O2]20H2O NaOH / 1/4 =/ 1,9 4 S/? / :0 Y/2$! %1( - U/ S - 0 / " C9 1- D/? S - 0 # B //8! 1,4 CR / 9P = 1 1/ 1/4 =4 SiO2 \F? /! /'G \'? ^ 1- (3y / Y/2$! 9 Y? < 9P }@ H < / '/9*,/' {U! 2/'/ 9P y, 9 9P 2 92 \ X! %1( jl l3 U/ { U, U# L 2 U34 "1-4 /! 1-0 Y/2$! /L }@ =N $, \'? '( 2 \ X! / 9#, P =4 4 #$ 0 Y: < DP > 3Na16(l16Si32O96)16H2O 2Na6[lSiO4]68H2O 32SiO2 116K 4Ca2 2Na 2Cl- 40Na 8H2O OH- Na # #a = 1 < 4 L > '( = /! < H S/? 3 L <U9, = 1 <H E 9 ( ) BaCl22H2O 6NalSi3O8 (Na2K2Ca)4[l8Si40O96]28H2O Bal2Si6O166H2O Na20[l60Si132O384]23H2O # 0 U/ 2 $ 1 1, T! Y2- (S1b) <U9, < 3 SEM T! Y2$ RS - < / 1 (S2b) <U9, 3 SEM EH 39@ 0 /3/- {, :1- "1- Y/2$! < 4 16(Na,K)6[l6Si30O2]20H2O BaCl22H2O 4NalSi3O8 NaOH ( ) (Na2K2Ca)4[l8Si40O96]28H2O Bal2Si3O104H2O Na6[lSiO4]68H2O 4Na16(l16Si32O96)16H2O 39SiO2 112K 4Ca2 2Cl- 2Na 226H2O OH- Na

7 ? < 9 =! =/ G C B //8! H < ) W 9 = < 4 /R M \2 i }@ Y/!)/'/ = = 1 < 4 9 R G / 9#, "1 / '/9*,/' 0 6/ U/ NaOH Y/2$! / 1/4, / 1/4 L Ba S/? / 9#, L Na S/? i " 3- =9 / "1- U/ S/? )/'/ 9$/ {4 < 4 9P Y/2$! /@ 4\ /'N \'? //8! -#9 =9 / \! * (001) Y/2$! [ ] 1 {U = < 4 / :0 / '/9*,/' X/^ / :0 0 /R G 2 1'L z < 4 /! R S - < G 1 1L L ( 4 /! B Q l 3 W'N, X- W 0 K /$ L Y ^ Ba2 CR 9P 0 Y ^ < 9P < 4\ "1= Y G 0 / < / 9 (S1b) <"1- U9, < 3 I6% % 4 " 34 / 1/4 % / < 0 (S2b) <"1- U9, < 3 6% P

8 ,- ",- ' 'y {, (= 1 y, # B ( / ) { 0 S/? L U9, L G M/ \F? L BHT? / :0 9P 0 )/'/ \F? /@ 0!)/'/ = ^^ % / < (3y S/? H < K/Ba CR = < 4 / :0 1, < > 9P Si/l 0 S/? )/'/ {4 / '/9*,/' //8! = = < 4 W'N }@ X!,( ' 1@ < 4 9 /'G * //8! \2 i Ba j/!! 1 - Y/2$! % 4 / :0 9P 0 "1- Y@ )/'/ <"1 3/G 9 \ 6/ < > 1/C <U9, < 4 9P Na }@ 1 / 1, X 1 Y/2$! = }@ < = 1 1,9 4! 1/4 B 2/'/,/ " Y X <U9, < 4Y32 $ / L,- Ma a y! < 4 /'G < 4 /! < 4\'? 0 9 /! M` L 1 " L H2O>l2O3 <H 9/ :0 [ ] [ i / 1/4 ]/ 9 < " ] 4 #$ 0 P / <U9, K "1,, /'G Y/2$! [ ] " X/^ (ß cage) 9 " C@ U 14 ]/ [ / 1/4 / L [ ] W - Y/2$! 0 H3X U/ / 1/4 1 - = < 4 / :0 Y/2$! <H 4) % 4 =4 )/'/ \F? /@ 41, / :0 0 / "1- GS - < M * / KG =/ 9* " # L $ 9@ -#9 1 #a Y2- ( X- < 4 - R! Q D/? }@ [* B Q 1, = 1 j/!! 1 W'N 1 > / 9#, 1, < 4S/? <1 1L 9/ :0 < 40 < = < 4" Y/2$! C'9 R - < 4e14 0 W'N 1 * / 9#, * R b ^ >?! 1, 0 N 9P 0 9 S - B //8! X/^ < 4S/? /'G S - < G ^ 2, \F? =9 /! Q < 4 /! # 4_, Y/2$! M R < 4 < " - /!!HT? 1 1L S S/? 0,-/ 0 X/^ < 4S/? L )/'/ W R S - /34 < G U/ {46* L 41, Si/l Y/2$! S - 0 G 4 R />! <0 0 W < 4B Q U/ j/!! 1 M R //X! " #$ 0 / :0 Y/2$! 1, \ X! % 4 1 /R R S - y ( / '/9*,/') / - R Y/2$! 1- % 4 CR S - <U9, < 4{, L < 4" / 9#, R S =/ R 0 4 / :0 Y/2$! 1-,-/ 0 S/? 1, / < 4 (3y = 1, < 9P R [, 4" C@ {4 ) Si/l //8! ( S - L - %0H M R S - //8! 'Q e14 41, < 4 W'N //X! G ( P < 4 W'N ] /! Y/2$! < 1 - U9, % 4 " 34 H2O>l2O3 1/4 < 40 < 4e14 W, / L /34 % < { 0 9 C? B 0 '9 % 4 " 1 % 4 " 34 U/ x] "1- U9, G a <0 < 9P! < 4 '@ \ 9 R = 9,/ * < 4 9 H X2 M [ ] B Q [ ] "1-2 < 9P <"0 1 { U j 9 "1- < 9P / U# L M < 4\2 U <"1 1* 1/4-9P / '/9*,/' 1 - / '/9*,/' 9P E 3' 1 {4 Y/2$! )/'/ 93 \F? )'/ 1-0 { 0 B Q /N - P { 0

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