Isolation of atomically precise mixed ligand shell PdAu 24 clusters. Supporting Information
|
|
- Evelyn Hubert Simpson
- 5 years ago
- Views:
Transcription
1 Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Isolation of atomically precise mixed ligand shell PdAu 24 clusters - Supporting Information Annelies Sels, 1 Noelia Barrabés 2, Stefan Knoppe, 3 Thomas Bürgi 1* 1: Department of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva 4, Switzerland 2: Institute of Materials Chemistry, Technical University of Vienna, Getreidemarkt 9/BC/01, 1060 Vienna, Austria 3: Molecular Imaging and Photonics, Department of Chemistry, KU Leuven, Celestijnenlaan 200D, 3001 Leuven, Belgium *: corresponding author, Thomas.Buergi@unige.ch S-1
2 Figure S1. MALDI-TOF mass spectra of the crude exchanged product after 72h reaction. The original PdAu 24 (2-PET) 18 and PdAu 24 (2-PET) 16 (R-BINAS) 1 are no longer observed, resulting in a higher amount of exchanged BINAS. Figure S2. CD spectra of PdAu 24 (2-PET) 18-2x (R-BINAS) x and PtAu 24 (2-PET) 18-2x (R- BINAS) x after 24h exchange reaction (left) and CD spectra of pure R-BINAS (right). The CD signal confirms the induced secondary level of chirality. S-2
3 All possible exchange isomers of PdAu 24 (2-PET) 14 (R-BINAS) 2 PdAu 24 (2-PET) 18 consists of six dimeric staples, containing one apex and two core sulphurs. Assuming an interstaple binding mode of dithiol ligands, BINAS binds from the apex S-atom in one staple to a core S-atom in another staple. Statistically, after one BINAS ligand is exchanged, five apex sulphurs remain available for the 2 nd BINAS, resulting in ten possible isomers of PdAu 24 (2-PET) 14 (R-BINAS) 2. However, repetition of isomers can occur considering the high symmetry of the cluster. Herein all ten configurations are identified and after rotation, matched to identical isomers. Isomers I3/I5 and I4/I6 are enantiomers concerning their adsorption pattern. Structure I1 Structure I2 S-3
4 Structure I3 Structure I4 Structure I5 S-4
5 Structure I6 Figure S3. Isomers of PdAu 24 (2-PET) 14 (R-BINAS) 2 S-5
6 All possible exchange isomers of PdAu 24 (2-PET) 12 (R-BINAS) 3 Statistically, 15 configurations of PdAu 24 (2-PET) 12 (R-BINAS) 3 are possible. However, due to the high relative energy of I5, eight structures can be excluded. Below the seven remaining isomers are shown. Structure 1 Structure 5 Structure 6 Structure 4 Structure 2 Structure 3 S-6
7 Structure 7 Figure S3. Isomers of PdAu 24 (2-PET) 12 (R-BINAS) 3 S-7
8 Coordinates of all optimized structures Coordinates of PdAu 24 (CH 3 ) 18 Au Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S S-8
9 C H H C H H C H H C H H C H H C H H C H H C H H C S-9
10 H H Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S C H S-10
11 H C H H C H H C H H C H H C H H C H H C H H C H H S-11
12 H H H H H H H H H H H H H H H H H H S-12
13 Coordinates of PdAu 24 (CH 3 ) 16 (S-BINAS) 1 Au Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S S-13
14 Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S C C C C S-14
15 C H C H C C C C C H C H C C C C H H H H C C C C H S-15
16 H H H C H H H C H H H C H H H C H H H C H H H C H S-16
17 H H C H H H C H H H C H H H C H H H C H H H C H H S-17
18 H C H H H C H H H C H H H C H H H S-18
19 Coordinates of PdAu 24 (CH 3 ) 14 (S-BINAS) 2 (Isomer 1) Au Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S Au S-19
20 Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S C C C C C S-20
21 H C H C C C C C H C H C C C C H H H H C C C C H H S-21
22 H H C H H H C H H H C H H H C H H H C H H H C H H S-22
23 H C H H H C H H H C H H H C H H H C H H H C H H H S-23
24 C H H H C H H H C C C C C H C C H C H C C H H H C S-24
25 C C C C C C H C C H C H H H H S-25
26 Coordinates of PdAu 24 (CH 3 ) 14 (S-BINAS) 2 (Isomer 2) Au Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S Au S-26
27 Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S C C C C C S-27
28 H C H C C C C C H C H C C C C H H H H C C C C H H S-28
29 H H C H H H C H H H C H H H C H H H C H H H C H H S-29
30 H C H H H C H H H C H H H C H H H C H H H C H H H S-30
31 C H H H C H H H C C C C C H C C H C H C C H H H C S-31
32 C C C C C C H C C H C H H H H S-32
33 Coordinates of PdAu 24 (CH 3 ) 14 (S-BINAS) 2 (Isomer 3) Au Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S S Au S-33
34 Au Au Au Au Au Au Au Au Au Au Au S S S S S S S S C C C C C H S-34
35 C H C C C C C H C H C C C C H H H H C C C C H H H S-35
36 H C H H H C H H H C H H H C H H H C H H H C H H H S-36
37 C H H H C H H H C H H H C H H H C H H H C H H H C S-37
38 H H H C H H H C C C C H C C C H C H C C H H H C C S-38
39 C C C C C H C C H C H H H H S S-39
40 Coordinates of PdAu 24 (CH 3 ) 14 (S-BINAS) 2 (Isomer 4) Au Au Au Au Au Au Au Au Au Au Au Au Au S S S S S S S Au Au Au Au S-40
41 Au Au Au Au Au Au Au Au S S S S S S S S S C C C C C H C H S-41
42 C C C C C H C H C C C C H H H H C C C C H H H H C S-42
Structural Information on the Au-S Interface of. Thiolate-protected Gold Clusters: A Raman. Spectroscopy Study
Structural Information on the Au-S Interface of Thiolate-protected Gold Clusters: A Raman Spectroscopy Study Supporting Information Birte Varnholt, Patric Oulevey, Sandra Luber, Chanaka Kumara, Amala Dass
More informationIn situ reaction monitoring reveals a diastereoselective ligand exchange. Supporting Information
In situ reaction monitoring reveals a diastereoselective ligand exchange reaction between the intrinsically chiral Au 38 (SR) 24 and chiral thiols - Supporting Information Stefan Knoppe, 1 Raymond Azoulay,
More informationStructures and ionization energies of small lithium doped germanium clusters
Electronic Supplementary Information (ESI) Structures and ionization energies of small lithium doped germanium clusters Jorg De Haeck, Truong Ba Tai, Soumen Bhattacharyya, Hai Thuy Le, Ewald Janssens,
More informationStereocontrolled Self-Assembly and Photochromic Transformation of
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Information for Stereocontrolled Self-Assembly and Photochromic Transformation
More informationNanoscale. Pd 2 Au 36 (SR) 24 cluster: structure studies PAPER. Introduction
PAPER View Journal View Issue Pd 2 Au 36 (SR) 24 cluster: structure studies Cite this: Nanoscale, 2015, 7, 17012 Bei Zhang, a Sameh Kaziz, b Houhua Li, c Dawid Wodka, a Sami Malola, d Olga Safonova, e
More informationA Compactly Fused π Conjugated Tetrathiafulvalene Perylenediimide Donor Acceptor Dyad
Supporting Information for: A Compactly Fused π Conjugated Tetrathiafulvalene Perylenediimide Donor Acceptor Dyad Michael Jaggi, a Carmen Blum, a Nathalie Dupont, b Jakob Grilj, b Shi-Xia Liu, *,a Jürg
More informationStructural Information on the Au S Interface of Thiolate-Protected Gold Clusters: A Raman Spectroscopy Study
pubs.acs.org/jpcc Structural Information on the Au S Interface of Thiolate-Protected Gold Clusters: A Raman Spectroscopy Study Birte Varnholt, Patric Oulevey, Sandra Luber, Chanaka Kumara, Amala Dass,
More informationElectronic Spectra and Magnetic Properties of Transition Metal Complexes)
Subject Chemistry Paper No and Title Module No and Title Module Tag Paper 7: Inorganic Chemistry-II (Metal-Ligand Bonding, Electronic Spectra and Magnetic Properties of Transition Metal 22: Isomerism part
More informationSurface Plasmon-Induced Hot Carrier Effect on Catalytic Activity of CO oxidation on Cu 2 O/Hexoctahedral Au Inverse Catalyst
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2018 Electronic Supplementary Information Surface Plasmon-Induced Hot Carrier Effect on Catalytic Activity
More informationEnantioselective copper catalysed C H insertion reactions of 2- sulfonyl-2-diazoacetamides to form γ-lactams. Supporting Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 2014 Enantioselective copper catalysed C H insertion reactions of 2- sulfonyl-2-diazoacetamides
More informationSupporting information
Electronic Supplementary Material (ESI) for Analyst. This journal is The Royal Society of Chemistry 2014 Supporting information Quantized double layer charging of Au 130 (SR) 50 Nanomolecules Vijay Reddy
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supporting Information Stefanos Mourdikoudis, a,b Mariana Chirea, a Daniele Zanaga, c Thomas Altantzis,
More informationSupporting information. Aluminum complexes based on pyridine substituted alcohols: synthesis, structure, catalytic application in ROP
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2015 Supporting information Aluminum complexes based on pyridine substituted alcohols: synthesis,
More informationThe change of corrin-amides to carboxylates leads to altered structures of the B 12 -responding btub riboswitch
Gallo et al. ESI 1 The change of corrin-amides to carboxylates leads to altered structures of the B 12 -responding btub riboswitch Electronic Supplementary Information (ESI) Sofia Gallo, Stefan Mundwiler,
More informationAromatic character of planar boron-based clusters revisited by ring current calculations
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2016 Supplementary Information Aromatic character of planar boron-based clusters revisited
More informationType of file: PDF Title of file for HTML: Peer Review File Description:
Type of file: PDF Title of file for HTML: Supplementary Information Description: Supplementary Figures, Supplementary Table, Supplementary Notes and Supplementary References. Type of file: PDF Title of
More informationNonadiabatic dynamics simulations of singlet fission in 2,5-bis(fluorene-9-ylidene)-2,5-dihydrothiophene crystals. Supporting Information.
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 18 Nonadiabatic dynamics simulations of singlet fission in,5-bis(fluorene-9-ylidene)-,5-dihydrothiophene
More informationSupporting Information
Supporting Information Gold Nanoparticle Dimers for Plasmon Sensing Yunan Cheng, 1,2,3 Mang Wang, 1 Gustaaf Borghs, * 2,3 Hongzheng Chen * 1 1. MOE Key Laboratory of Macromolecule Synthesis and Functionalization,
More informationβ 2 -microglobulin fibrillation?
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Can small hydrophobic gold nanoparticles inhibit β 2 -microglobulin fibrillation? G. Brancolini,,
More informationSupporting Information for the paper: Structure-Reactivity Correlations in Metal Atom Substitutions of Monolayer- Protected Noble Metal Alloy Clusters
Supporting Information for the paper: Structure-Reactivity Correlations in Metal Atom Substitutions of Monolayer- Protected Noble Metal Alloy Clusters Kumaranchira Ramankutty Krishnadas, Debasmita Ghosh,
More informationMS731M: Chemical Analysis of Materials
(Revised) Course Code and Title Course Coordinator Details of Course MS731M: Chemical Analysis of Materials Dr. Eileen Fong (Course Coordinator) Dr. Thresen Matthew Rationale for introducing this course
More informationElectronic Supplementary Material (ESI) for Molecular BioSystems. This journal is The Royal Society of Chemistry 2015 Table S1. Structures and bioactivitiess ID Structure ACS Registry Number pec50 CoMFA
More informationAtomic Models for Anionic Ligand Passivation of Cation- Rich Surfaces of IV-VI, II-VI, and III-V Colloidal Quantum Dots
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Atomic Models for Anionic Ligand Passivation of Cation- Rich
More informationSupplementary Information Supplementary Figures
Supplementary Information Supplementary Figures Supplementary Fig. 1 Methanol-derived protons in methanediol in the formaldehyde production from methanol: The water formed in the oxidation is used to form
More informationion mobility spectrometry IR spectroscopy
Debasmita Gho 29.10.2016 Introducti on Owing to its accuracy, sensitivity, and speed, mass spectrometry (MS) coupled to fragmentation techniques is the method of choice for determining the primary structure
More informationK + -Selective Optical Microsensors Based On Surface Modified Polystyrene Microspheres
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 214 Supporting information for K + -Selective Optical Microsensors Based On Surface Modified Polystyrene
More informationSupporting Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supporting Information Depositing CdS Nanoclusters on Carbon-modified NaYF 4 :Yb,Tm Upconversion
More informationAmino Acid Side Chain Induced Selectivity in the Hydrolysis of Peptides Catalyzed by a Zr(IV)-Substituted Wells-Dawson Type Polyoxometalate
Amino Acid Side Chain Induced Selectivity in the Hydrolysis of Peptides Catalyzed by a Zr(IV)-Substituted Wells-Dawson Type Polyoxometalate Stef Vanhaecht, Gregory Absillis, Tatjana N. Parac-Vogt* Department
More informationChiral functionalization of a zirconium metalorganic. catalyst in asymmetric Michael addition reaction
Electronic supplementary material for paper Chiral functionalization of a zirconium metalorganic framework (DUT-67) as a heterogeneous catalyst in asymmetric Michael addition reaction Khoa D. Nguyen, Christel
More informationDepartment of Chemistry, University of California, Berkeley, California, , USA. b
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information for: Structural characterization of framework gas
More informationA novel coumarin based molecular switch for dual sensing of
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information A novel coumarin based molecular switch for dual sensing of Zn(II) and
More information- Supplementary Information- Real-time monitoring of a dynamic molecular system using 1 H- 13 C HSQC NMR spectroscopy with optimized 13 C window
- Supplementary Information- Real-time monitoring of a dynamic molecular system using 1 H- 13 C HSQC NMR spectroscopy with optimized 13 C window Giulio Gasparini, a Bruno Vitorge, b Paolo Scrimin, a Damien
More informationSynthesis of two copper clusters and their catalysis towards the oxidation of benzene
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Electronic Supplementary Information Synthesis of two copper clusters and their catalysis towards
More informationCatalysis at the Sub-Nanoscale: Complex CO Oxidation Chemistry on a Few Au Atoms
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 214 Catalysis at the Sub-Nanoscale: Complex CO Oxidation Chemistry on a Few Au
More informationJournal of Theoretical Physics
1 Journal of Theoretical Physics Founded and Edited by M. Apostol 79 (2002) ISSN 1453-4428 Metallic Clusters Deposited on Surfaces. Puszczykowo talk, 2002 M. Apostol Department of Theoretical Physics,
More informationSupporting Information
Supporting Information Interconversion between Superatomic 6-Electron and 8-Electron Configurations of M@Au 24 (SR) 18 Clusters (M = Pd, Pt) Kyuju Kwak, Qing Tang, Minseok Kim, De-en Jiang, and Dongil
More informationSupplementary information. Infra-red Spectroscopy of Size Selected Au 25, Au 38 and
Supplementary information Infra-red Spectroscopy of Size Selected Au 25, Au 38 and Au 144 Ligand Protected Gold Clusters Mostafa Farrag a, Martin Tschurl a, Amala Dass b, Ulrich Heiz a a TECHNISCHE UNIVERSITÄT
More informationAnswering Questions of Nuclear and Astrophysics with Mass Measurements from ISOLTRAP
Answering Questions of Nuclear and Astrophysics with Mass Measurements from ISOLTRAP Susanne Kreim June 3 rd 2014 CERN, Geneva, Switzerland Max-Planck-Institut für Kernphysik, Heidelberg, Germany Physics
More information1 Supporting Information. 2 Reconfigurable and resettable arithmetic logic units based. 4 Siqi Zhang a, Kun Wang a, Congcong Huang b and Ting Sun a*
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 1 Supporting Information 2 Reconfigurable and resettable arithmetic logic units based 3 on magnetic
More informationThe Boron Buckyball has an Unexpected T h Symmetry
The Boron Buckyball has an Unexpected T h Symmetry G. Gopakumar, Minh Tho Nguyen, and Arnout Ceulemans* Department of Chemistry and Institute for Nanoscale Physics and Chemistry, University of Leuven,
More informationGiant exchange coupling and slow relaxation of magnetization in with a singleelectron. Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Giant exchange coupling and slow relaxation of magnetization in Gd2@C79N with a singleelectron
More informationSupporting Information
ACS Catalysis Supporting Information Cooperative Catalysis for Multistep Biomass Conversion with Sn/Al Beta Zeolite Jan Dijkmans a, Michiel Dusselier a, Dries Gabriëls a, Kristof Houthoofd a, Pieter C.M.M.
More informationSupplementary Materials for
advances.sciencemag.org/cgi/content/full/3/4/e1600663/dc1 Supplementary Materials for A dynamic hydrophobic core orchestrates allostery in protein kinases Jonggul Kim, Lalima G. Ahuja, Fa-An Chao, Youlin
More informationHigh-Resolution Laser Spectroscopy for Nuclear-Structure Studies
Collinear Laser Spectroscopy @ ISOLDE High-Resolution Laser Spectroscopy for Nuclear-Structure Studies D. T. Yordanov 1, D. L. Balabanski 2, M. L. Bissell 3, K. Blaum 1, I. Budinčević 3, B. Cheal 4, M.
More informationMechanistic identification and improvement of a direct enantioconvergent transformation in coppercatalyzed asymmetric allylic alkylation
Mechanistic identification and improvement of a direct enantioconvergent transformation in coppercatalyzed asymmetric allylic alkylation Jean-Baptiste Langlois, Daniel Emery, Jiri Mareda* and Alexandre
More informationChapter 5. Complexation of Tholins by 18-crown-6:
5-1 Chapter 5. Complexation of Tholins by 18-crown-6: Identification of Primary Amines 5.1. Introduction Electrospray ionization (ESI) is an excellent technique for the ionization of complex mixtures,
More informationElectronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented
Electronic supplementary information (ESI) Temperature dependent selective gas sorption of unprecedented stable microporous metal-imidazolate framework Shui-Sheng Chen, a,c Min Chen, a Satoshi Takamizawa,
More informationSupplementary Figure 1. ToF-SIMS data obtained for the Au(111) surface after the sublimation of the Cu-BCOD (mass 889 a.u.). During the sublimation
Supplementary Figure 1. ToF-SIMS data obtained for the Au(111) surface after the sublimation of the Cu-BCOD (mass 889 a.u.). During the sublimation process, Cu-BCOD was converted into Cu-Benzo (mass 786
More informationTernary gradient metal-organic frameworks
Electronic Supplementary Material (ESI) for Faraday Discussions. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information for Ternary gradient metal-organic frameworks Chong
More informationNucleon Pair Approximation to the nuclear Shell Model
Nucleon Pair Approximation to the nuclear Shell Model Yiyuan Cheng Department of Physics and Astronomy, Shanghai Jiao Tong University, China RCNP, Osaka university, Japan Collaborators: Yu-Min Zhao, Akito
More informationChemistry 201: General Chemistry II - Lecture
Chemistry 201: General Chemistry II - Lecture Dr. Namphol Sinkaset Chapter 23 Study Guide Concepts 1. In the transition metals, the ns orbital fills before the (n-1)d orbitals. However, the ns orbital
More informationInfluence of Plasmonic Array Geometry on Energy Transfer from a. Quantum Well to a Quantum Dot Layer
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Influence of Plasmonic Array Geometry on Energy Transfer from a Quantum Well to a Quantum Dot
More informationOpportunities with collinear laser spectroscopy at DESIR:
Opportunities with collinear laser spectroscopy at DESIR: the LUMIERE facility GOALS of LUMIERE experiments: Gerda Neyens, K.U. Leuven, Belgium (1) measure ground state properties of exotic isotopes: (see
More informationTiC 2 : A New Two Dimensional Sheet beyond MXenes
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2015 Supplementary Information (SI) TiC 2 : A New Two Dimensional Sheet beyond MXenes Tianshan Zhao,
More informationProton NMR. Four Questions
Proton NMR Four Questions How many signals? Equivalence Where on spectrum? Chemical Shift How big? Integration Shape? Splitting (coupling) 1 Proton NMR Shifts Basic Correlation Chart How many 1 H signals?
More informationTuning the energetics and tailoring the optical properties of silver clusters confined in zeolites
Tuning the energetics and tailoring the optical properties of silver clusters confined in zeolites Oliver Fenwick 1 Ϯ, Eduardo Coutiño-Gonzalez 2Ϯ, Didier Grandjean 3, Wouter Baekelant 2, Fanny Richard
More informationSupporting information for Polymer interactions with Reduced Graphene Oxide: Van der Waals binding energies of Benzene on defected Graphene
Supporting information for Polymer interactions with Reduced Graphene Oxide: Van der Waals binding energies of Benzene on defected Graphene Mohamed Hassan, Michael Walter *,,, and Michael Moseler, Freiburg
More informationAll-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures
Nature 501, 399 402 (19 September 2013) doi:10.1038/nature12523 All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures Huayan Yang, Yu Wang, Huaqi Huang, Lars Gell, Lauri Lehtovaara,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2018 Electronic Supplementary Information
More informationA Unified Framework for Understanding the Structure and Modifications of Atomically Precise Monolayer Protected Gold Clusters
Supporting Information (SI) for the Paper: A Unified Framework for Understanding the Structure and Modifications of Atomically Precise Monolayer Protected Gold Clusters Ganapati Natarajan, Ammu Mathew,
More informationAntiparallel double-stranded BODIPY porphyrin dyad assembled by a self-complementary B F Zn interaction
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2017 Supporting Information for Antiparallel double-stranded BODIPY porphyrin dyad assembled by a self-complementary
More informationElectronic Supplementary Information (ESI) for. Stereoselective photoreaction in P-stereogenic dithiazolylbenzo[b]phosphole chalcogenides
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 216 Electronic Supplementary Information
More informationProblem 1. Anthracene and a chiral derivative of anthracene
Molecular Photophysics 330 Physical rganic Chemistry 6C50 Thursday November 5 004, 4.00-7.00 h This exam consists of four problems that have an equal weight in the final score Most problems are composed
More informationFast and Slow Ligand Exchange at the Surface of Colloidal Gold Nanoparticles
Fast and Slow Ligand Exchange at the Surface of Colloidal Gold Nanoparticles Rebecca Dinkel 1, Björn Braunschweig 1,2 * and Wolfgang Peukert 1,2 1 Institute of Particle Technology (LFG), Friedrich-Alexander
More informationVarying nucleotide synthesis reaction conditions
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2016 Varying nucleotide synthesis reaction conditions In order to obtain maximum yields
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Interfacial acidity in ligand-modified ruthenium nanoparticles
More informationSupporting Information for: Potentiometric Sensing Array for Monitoring Aquatic Systems
Electronic Supplementary Material (ESI) for Environmental Science: Processes & Impacts. This journal is The Royal Society of Chemistry 2015 Supporting Information for: Potentiometric Sensing Array for
More informationHai-Bin Yang, Xing Fan, Yin Wei,* Min Shi*
Electronic Supplementary Material (ESI) for Organic Chemistry Frontiers. This journal is the Partner Organisations 2015 Solvent-controlled Nucleophilic Trifloromethylthiolation of Morita- Baylis-Hillman
More informationHighly Diastereo- and Enantioselective Organocatalytic Domino Michael/Aldol Reaction of Acyclic 3- Halogeno- 1,2- Diones to α,β- Unsaturated Aldehydes
Supporting Information for Highly Diastereo- and Enantioselective rganocatalytic Domino Michael/Aldol Reaction of Acyclic 3- Halogeno- 1,2- Diones to α,β- Unsaturated Aldehydes Alice Lefranc 1, Laure Guénée
More informationMS Interpretation I. Identification of the Molecular Ion
MS Interpretation I Identification of the Molecular Ion Molecular Ion: EI Requirements for the Molecular Ion Must be the highest m/z peak in the spectrum Highest Isotope Cluster Must be an odd-electron
More informationSupramolecular Functionalization and Concomitant Enhancement in Properties of Au 25 Clusters
Supporting information (SI) for the paper: Supramolecular Functionalization and Concomitant Enhancement in Properties of Au 25 Clusters Ammu Mathew, Ganapati Natarajan, Lauri Lehtovaara Ϯ, Hannu Häkkinen
More informationSupplementary Figure 1. Structures of substrates tested with 1. Only one enantiomer is shown.
Supplementary Figure 1. Structures of substrates tested with 1. Only one enantiomer is shown. Supplementary Figure 2. CD spectra obtained using 1 and (R)-3 (blue) and (S)-3 (red) Supplementary Figure 3.
More informationChirality influence on the aggregation of methyl mandelate Supplementary Information
Chirality influence on the aggregation of methyl mandelate Supplementary Information M. Albrecht, A. Borba, K. Le Barbu-Debus, B. Dittrich, R. Fausto, S. Grimme, A. Mahjoub, M. Nedić, U. Schmitt, L. Schrader,
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for Organic & Biomolecular Chemistry. This journal is The Royal Society of Chemistry 7 Electronic Supplementary Information Modulation in the Acidity Constant of
More informationSUPPORTING INFORMATION
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 SUPPORTING INFORMATION Sugar and ph Dual-Responsive Mesoporous Silica Nanocontainers Based on
More informationZeolite-supported rhodium sub-nano cluster catalyst for low-temperature
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information Zeolite-supported rhodium sub-nano cluster
More informationSupporting Information of Carboranes: The Strongest Brønsted Acids in Alcohol Dehydration
Electronic Supplementary Material (ESI) for Catalysis Science & Technology. This journal is The Royal Society of Chemistry 2017 Supporting Information of Carboranes: The Strongest Brønsted Acids in Alcohol
More information10-1 You might start this exercise by drawing all of the isomers of C7H16 of which there are nine:
Copyright 2010 James K Whitesell 10-1 You might start this exercise by drawing all of the isomers of C7H16 of which there are nine: Pick one with both secondary and tertiary carbon atoms and simply add
More informationChiral Nematic Cellulose / Gold Nanoparticle Composites from Mesoporous Photonic Cellulose
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2014 Chiral Nematic Cellulose / Gold Nanoparticle Composites from Mesoporous Photonic Cellulose Maik
More informationPost-Healing of Defects: Alternative Way for Passivation of Carbon-Based Mesoscopic Perovskite Solar Cells via Hydrophobic Ligand Coordination
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2018 Supporting Information for Post-Healing of Defects: Alternative Way for
More information[Type text] Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2017 [Type text] Supporting Information 1 Effective Removal of Chemical Warfare Agent Simulants
More informationSupplementary Material
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2016 Supplementary Material Spin crossover and reversible single-crystal to single-crystal
More informationAu-C Au-Au. g(r) r/a. Supplementary Figures
g(r) Supplementary Figures 60 50 40 30 20 10 0 Au-C Au-Au 2 4 r/a 6 8 Supplementary Figure 1 Radial bond distributions for Au-C and Au-Au bond. The zero density regime between the first two peaks in g
More informationSupporting Information
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2017 Supporting Information Bis(aminothiolato)nickel Nanosheet as a Redox Switch for Conductivity
More informationSupporting Information. Accurate prediction of the structure and vibrational spectra of ionic
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2018 Supporting Information Accurate prediction of the structure and vibrational spectra
More informationSupporting Information for
Supporting Information for Odd-Even Effects in Chiral Phase Transition at the Liquid/Solid Interface Hai Cao, a Kazukuni Tahara, bc Shintaro Itano, b Yoshito Tobe b* and Steven De Feyter a* a Division
More informationTridip Sheet, Raja Banerjee*
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Supplementary information The C NN motif: an intrinsic lover of sulfate and phosphate ions
More informationSupplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Supplementary Information Cross-linker Mediated Formation of Sulfur-functionalized V 2 O 5 /Graphene
More informationSalvatore Lombardo 1, Wim Thielemans 1*
Electronic Supplementary Material (ESI) for Physical Chemistry Chemical Physics. This journal is the Owner Societies 2018 Supporting Information for Thermodynamics of the interactions of positively charged
More information5.111 Principles of Chemical Science
MIT penurseware http://ocw.mit.edu 5.111 Principles of Chemical Science Fall 2008 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms. 27.1 5.111 ecture 27
More informationSpain c Departament de Química Orgànica, Universitat de Barcelona, c/ Martí I Franqués 1-11, 08080, Barcelona, Spain.
a Institute of Chemical Research of Catalonia, Av. Països Catalans, 16, 43007 Tarragona, Spain. b Departament de Química, Universitat Autònoma de Barcelona, Cerdanyola del Vallès, E-08193 Barcelona, Spain
More informationDepartment of Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong.
Electronic Supplementary Material (ESI) for Journal of Analytical Atomic Spectrometry. This journal is The Royal Society of Chemistry 2015 Electronic supplementary information Effects of ionization potential
More informationSupplementary Figure 2. (a) XRD patterns of the MOF and the simulated Ni-MOF-74
Supplementary Figure 1. Low-magnification TEM image of Pt-Ni frame @ MOF. The scale bar is 200 nm. Supplementary Figure 2. (a) XRD patterns of the Pt-Ni @ MOF and the simulated Ni-MOF-74 pattern. (b) XRD
More informationChapter 25 Transition Metals and Coordination Compounds Part 1
Chapter 25 Transition Metals and Coordination Compounds Part 1 Introduction The transition elements are defined as: those metallic elements that have a partially but incompletely filled d subshell or easily
More informationELECTRONIC SUPPLEMENTARY INFORMATION
ELECTRONIC SUPPLEMENTARY INFORMATION On-Chip Bioorthogonal Chemistry Enables Immobilization of In Situ Modified Nanoparticles and Small Molecules for Label-Free Monitoring of Protein Binding and Reaction
More informationElectronic Supplementary Information
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Electronic Supplementary Information
More informationMicelles from self-assembled Double-Hydrophilic PHEMA- Glycopolymer-Diblock Copolymers as multivalent Scaffolds for Lectin Binding
Electronic Supplementary Material (ESI) for Polymer Chemistry. This journal is The Royal Society of Chemistry 2015 Micelles from self-assembled Double-Hydrophilic PHEMA- Glycopolymer-Diblock Copolymers
More informationSupplementary Information. Table of Contents
Supplementary Information Modular Chiral Dendritic monodentate phosphoramidite ligands for Rh(I)-Catalyzed Asymmetric Hydrogenation: Unprecedented Enhancement of Enantioselectivity Feng Zhang, a, b Yong
More informationSupplementary Materials for
advances.sciencemag.org/cgi/content/full/3/5/e1603193/dc1 Supplementary Materials for Molecular surgery on a 23-gold-atom nanoparticle Qi Li, Tian-Yi Luo, Michael G. Taylor, Shuxin Wang, Xiaofan Zhu, Yongbo
More informationThiolate-protected gold nanoclusters are an intensively studied
pubs.acs.org/ac Size Exclusion Chromatography for Semipreparative Scale Separation of Au 38 (SR) 24 and Au 40 (SR) 24 and Larger Clusters Stefan Knoppe, Julien Boudon, Igor Dolamic, Amala Dass,*, and Thomas
More information