Quartz: Deposits, Mineralogy and Analytics
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1 Springer Geology Quartz: Deposits, Mineralogy and Analytics Bearbeitet von Jens Götze, Robert Möckel 1. Auflage Buch. xvi, 360 S. Hardcover ISBN Format (B x L): 15,5 x 23,5 cm Gewicht: 725 g Weitere Fachgebiete > Geologie, Geographie, Klima, Umwelt > Geologie > Petrologie, Mineralogie Zu Leseprobe schnell und portofrei erhältlich bei Die Online-Fachbuchhandlung beck-shop.de ist spezialisiert auf Fachbücher, insbesondere Recht, Steuern und Wirtschaft. Im Sortiment finden Sie alle Medien (Bücher, Zeitschriften, CDs, ebooks, etc.) aller Verlage. Ergänzt wird das Programm durch Services wie Neuerscheinungsdienst oder Zusammenstellungen von Büchern zu Sonderpreisen. Der Shop führt mehr als 8 Millionen Produkte.
2 Contents 1 Classification, Mineralogy and Industrial Potential of SiO 2 Minerals and Rocks Introduction Classification and Properties of SiO 2 Minerals SiO 2 Modifications and Varieties Real Structure and Properties of Quartz Origin and Nomenclature of SiO 2 Rocks Magmatic and Metamorphic SiO 2 Rocks Sedimentary SiO 2 Rocks Formation and Industrial Use of SiO 2 Raw Materials Magmatic and Postmagmatic Quartz Metamorphic Quartz Sedimentary SiO 2 Rocks Synthetic SiO 2 Raw Materials Conclusions References Assessment of High Purity Quartz Resources Introduction Present Quartz Supplying Countries Typical High Purity Quartz Applications Demand Situation Lighting Industries Semiconductor Industry Photovoltaic Industry Optical Fibers Resource Estimation Analytics Bulk Chemical Analysis Characterization of Mineral Inclusions vii
3 viii Contents Analysis of Fluid (Liquid and Gaseous) Inclusions High Purity Quartz Processing Pre-processing Physical Processing Chemical Treatment Thermal Treatment Conclusion References Quality Requirements of Quartz Sand in the Building Industry Introduction The Idea Behind General Development Special Developments of Individual Construction Products and Increasing Requirements for Siliceous Raw Materials Autoclaved Aerated Concrete Industry Calcium Silicate Unit Industry Cement Industry Clay Brick Industry/Roof Tile Industry Concrete Industry Mortar and Render Industry Recent Developments in Mining and Processing Processing of Quartz Sand Tendencies in Grinding of Quartz Quartz Sand Deposits for the Use in Construction Industry Conclusions References Petrological and Chemical Characterisation of High-Purity Quartz Deposits with Examples from Norway Introduction Impurities in Quartz Lattice-Bound Trace Elements Submicron and Nano-scale Inclusions Mineral, Melt and Fluid Inclusions Quality Definition of High-Purity Quartz Methods Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) Backscattered Electron and Cathodoluminescence Imaging
4 Contents ix 4.5 Norwegian HPQ Deposits The Melkfjell Quartzite Kyanite Quartzites The Nedre Øyvollen Pegmatite The Nesodden Quartz Vein The Kvalvik Deposit The Svanvik Quartz Vein Summary and Outlook References Evaluation of the Potential of the Pegmatitic Quartz Veins of the Sierra de Comechigones (Argentina) as a Source of High Purity Quartz by a Combination of LA-ICP-MS, ICP, Cathodoluminescence, Gas Chromatography, Fluid Inclusion Analysis, Raman and FTIR spectroscopy Introduction Geology Methods Bulk Chemical Composition by ICP-MS Spot Chemical Analysis by LA-ICP-MS Cathodoluminescence Fluid Inclusion Investigations Results Petrography Cathodoluminescence Bulk Chemical Composition by ICP-MS Chemical Composition by LA-ICP-MS Spot Analysis Fluid Inclusions Discussion Conclusion References Brazilian Quartz Deposits with Special Emphasis on Gemstone Quartz and its Color Treatment Introduction Geology of Brazilian Quartz Deposits Brazilian Pegmatite Provinces Hydrothermal Quartz Secondary Deposits Color Enhancement of Quartz A Brief Historic Color-Enhancing of Gemological Crystalline Quartz in Brazil Quartz Color-Enhancing in Brazil
5 x Contents 6.4 Concluding Remarks References First-Principles Calculations of the E 0 1 Center in Quartz: Structural Models, 29 Si Hyperfine Parameters and Association with Al Impurity Introduction Computation Methodology Results and Discussion Single-Oxygen-Vacancy Models Tri-Vacancy Models References Gamma-Irradiation Dependency of EPR and TL-Spectra of Quartz Introduction Experimental Results and Discussion Conclusion References Analysis of Low Element Concentrations in Quartz by Electron Microprobe Introduction Excited Volume: Spatial Resolution Pitfalls in Quartz Analysis Influence of Bremsstrahlung Beam Induced Damage Secondary Fluorescence Near Phase Boundaries Detection Limits, Precision and Accuracy Analysis Protocol for Trace Elements in Quartz by EMP References In Situ Analysis of Trace Elements in Quartz Using Laser Ablation Inductively Coupled Plasma Mass Spectrometry Introduction Instrumentation Inductively Coupled Mass Spectrometry Laser Ablation Systems Experimental Set-Up at NGU Standards and Standard Preparation Measurement Procedure, Calibration and Data Evaluation Limits of Detection Precision
6 Contents xi 10.8 Discussion Conclusion References Cathodoluminescence Microanalysis of the Defect Microstructures of Bulk and Nanoscale Ultrapure Silicon Dioxide Polymorphs for Device Applications Introduction Materials and Methods Results Discussion Bulk Single Crystal a-sio 2 (Quartz) Bulk Amorphous a-sio Dry Thermal Oxide (Amorphous SiO 2 ) on Si (001) Buried Amorphous SiO 2 in Si (001) Conclusions References Trace Element Characteristics, Luminescence Properties and Real Structure of Quartz Introduction Methods CL-Microscopy and -Spectroscopy Trace Element Analyses Luminescence and Trace-Element Characterisation of Quartz Cathodoluminescence Spectroscopy Trace Element Composition Correlation of CL-Properties to Point Defects and Trace-Element Composition Ultra-Violet to Blue Luminescence Between 330and400nm Blue to Bluish-Green Luminescence: The 450 and 505 nm-bands Greenish-Yellow Luminescence at 580 nm Brown to Reddish Luminescence Between 630 and 650 nm Conclusions References Mineralogy, Geochemistry and Cathodoluminescence of Authigenic Quartz from Different Sedimentary Rocks Introduction Materials and Methods Results and Discussion
7 xii Contents Mineralogy Cathodoluminescence Geochemistry Sources of Silica and Conditions of Quartz Formation Conclusions References Cathodoluminescent Textures and Trace Elements in Hydrothermal Quartz Introduction CL Textures in Quartz Primary Textures Secondary Textures CL Textures and Environment of Formation Trace Elements in Hydrothermal Quartz Analytical Techniques Trace Element Concentrations in Hydrothermal Quartz Correlations Between CL and Trace Elements in Hydrothermal Quartz Implications for Hydrothermal Systems and Ore Deposits Conclusions References Quartz Regeneration and its Use as a Repository of Genetic Information Introduction Quartz with Metamorphic Micro-Fabrics and Hydrothermal Trace Element Signatur from Wall Rocks of the Ehrenfriedersdorf Tin Deposit, Erzgebirge, Germany Limitations to Provenance Analysis: Cathodoluminescence (CL) Colour Imaging of Quartz Pebbles from the Witwatersrand Basin, South Africa Fluid Inclusions in Quartz: Relationships to Fluids Involved in Wolframite Precipitation in Tungsten Deposits of the Mongolian Altai, Mongolia Intergrowth Relationships Between Quartz and Ore Minerals: Evidence for South Crofty Tungsten Mine, Cornwall, United Kingdom Discussion and Conclusions References Index
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