Percent Composition. % Composition, from masses (Practice) From masses (Example)

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1 From masses (Example) Percent Composition A sample of steel wool is placed in an aluminum pan and ignited. The following data is collected: Determine the following: 1. of iron in the product. (g) A Aluminum pan B Al pan with steel wool C Al pan and product Composition, from masses (Practice) A g sample of aluminum is reacted with sulfuric acid. Aluminum sulfate is separated from the resulting solution and dried. The mass of the aluminum sulfate is found to be g. Determine the percent aluminum and percent sulfate in this compound. A Aluminum B Aluminum sulfate Determine the mass of sulfate in the product: (g) 2. of oxygen in the product. 3. of the product. 4. Percent composition of the product. a. Iron. Determine the percent composition by mass: Aluminum ions Sulfate ions of (g) by mass of =? b. xygen 5. Check your work: Do the percentages add up to 100? Table Format: or (Element, Ion, Atom, Polyatomic Ion, molecule,, etc.) (g) (rounded) Al Total Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 1 of 11 Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 2 of 11

2 Composition, from a chemical name or formula (Example) Determine the percent composition of manganese(iii) oxide. Formula: Mn of s mass of (6 significant digits) =? From masses (Example) Determining Empirical Formulas A sample of steel wool is placed in an aluminum pan and ignited. The following data is collected: (g) A Aluminum pan B Al pan with steel wool C Al pan and product Determine the empirical formula for the compound formed. Fe Composition, from a chemical name or formula (Practice) Determine the percent composition of manganese(iv) phosphate. Formula: Chemical Formula: Chemical Name: Mn P of s mass of (6 significant digits) =? Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 3 of 11 Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 4 of 11

3 Review: / / Empirical Formulas, from masses (Practice) A g sample of aluminum is reacted with sulfuric acid. Aluminum sulfate is separated from the resulting solution and dried. The mass of the aluminum sulfate is found to be g. Determine the percent of aluminum and percent sulfate in this compound. Al (or Al +3 ) S 4-2 Chemical Formula: Chemical Name: Smaller = Recognize fractions and their decimal equivalents: Name Fraction Decimal Decimal Range (±0.050) Halves x / Thirds x / , or Fourths x / , or Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 5 of 11 Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 6 of 11

4 Determining Molecular Formulas (Type III [N-N] and rganic [C x H y ]) Steps: 1. Determine Empirical Formula. 2. Find ratio of molar mass to empirical mass: Molar = R = Empirical 3. Distribute R into empirical formula to find molecular formula: Molecular Formula = (Empirical Formula) R Example: 1.50 g of an unknown white powder is analyzed and found to contain phosphorus and oxygen. Through further testing the mass of oxygen in the compound is determined to be 0.85 g and the molar mass of the compound is found to be 284 g/mol. Determine the molecular formula for this compound. P Empirical Formula: Empirical : Practice: A compound containing chlorine, carbon, and hydrogen is used as an additive for gasoline to help prevent engine knock. This compound shows the following percentage composition: Cl C? H The molar mass is known to be g. Determine the molecular formula for this compound. When given percent composition, assume 100 g. This makes the percents into masses. Cl C H Empirical Formula: Empirical : R = Molar / Empirical = / = = Molecular Formula Possibilities ( ) R where R ε {1, 2, 3,, x} R=1 ( ) R = ( ) 1 = P *1 *1 = P M 1 = g R=2 ( ) R = ( ) 2 = P *2 *2 = P M 2 = g R=3 ( ) R = ( ) 3 = P *3 *3 = P M 3 = g R=x ( ) R = ( ) x = P *x *x = P x x M x = * x Molar R = = = = Empirical Molecular Formula = (P ) R = ( ) = P Name this compound: Molecular Formula = (Cl C H ) R Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 7 of 11 Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 8 of 11

5 Hydrates Water and Molecular Formula From masses: (Example) Water in a Hydrate (from formula): Formula: CoCl 2 6 A g sample of hydrated cobalt(ii) chloride is heated to remove the water. nce cool, the anhydrous crystal is found to have a mass of 6.95 g. Determine the percent water and the formula of the hydrate. of s of (6 significant digits) CoCl 2 x Anhydrous cobalt(ii) chloride Water of hydration (g) CoCl 2 = 100? Percent Water: (g) (rounded) CoCl 2 Formula of a Hydrate (from masses): CoCl 2 x Atomic or Molar CoCl 2 Formula: CoCl 2 Name: cobalt( ) chloride hydrate Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 9 of 11 Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 10 of 11

6 Water and Formula From masses: (Practice) A 3.68 g sample of hydrated calcium sulfate is heated to remove the water. nce cool, the anhydrous crystal is found to have a mass of 2.91 g. Determine the percent water and the formula of the hydrate. CaS 4 x Anhydrous calcium sulfate Water of hydration (g) Percent Water: (g) (rounded) CaS 4 Formula of a Hydrate (from masses): CaS 4 x Atomic or Molar CaS 4 Formula: CaS 4 Name: calcium sulfate hydrate Ch 06 Notes.doc 10/16/2009 9:47:00 AM Page 11 of 11

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