List of Publications Kurt V. Gothelf Papers peer reviewed August 2011

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1 List of Publications Kurt V. Gothelf Papers peer reviewed August ) DNA- programmed Glaser-Eglinton reactions for the synthesis of conjugated molecular wires Ravnsbæk, J. B.; Jacobsen, M. F.; Rosen, C. B.; Voigt, N. V.; Gothelf, K. V. Angew. Chem. Int. Ed., 2011, in press. 104) Chiral induction by seeding surface assemblies of chiral switches Masini, F.; Kalashnyk, N.; Knudsen, M. M.; Cramer, J. R.; Lægsgaard, E.; Besenbacher, F.; Gothelf, K. V.; Linderoth, T. R. J. Am. Chem. Soc., 2011, 7, ) Control of self-assembled 2D nanostructures by methylation of guanine Bald, I.; Wang, Y.-g.; Dong, M.; Rosen, C. B.; Ravnsbæk, J. B.; Zhuang, G.- l.; Gothelf, K. V.; Wang, J.-g.; Besenbacher, F., Small, 2011, 7, ) Single molecule microscopy methods for the study of DNA origami structures Birkedal, V.; Dong, M.; Golas, M. M.; Sander, B.; Andersen, E. S.; Gothelf, K. V.; Besenbacher, F.; Kjems, J. Microscopy Research and Technique 2011, 74, ) "Off On" electrochemical hairpin-dna-based genosensor for cancer diagnostics Farjami, E.; Clima, L.; Gothelf, K. V.; Ferapontova, E. E. Anal. Chem. 2011, 83, ) Recent advances in electrochemical aptamer-based sensors Ferapontova, E. E.; Gothelf, K. V. Curr. Org. Chem. 2011, 15, ) β-olefination of 2-alkynoates leading to trisubstituted 1,3-dienes Jacobsen, M. J.; Funder, E. D.; Cramer, J. R.; Gothelf, K. V. Org. Lett. 2011, 13, ) Site-specific chemical labeling of long RNA molecules Jahn, K.; Olsen, E. M.; Nielsen, M. M.; Tørring, T.; MohammadZadegan, R.; Andersen, E. S.; Gothelf, K. V.; Kjems, J. Bioconjugate Chem. 2011, 22, ) Functional patterning of DNA origami by parallel enzymatic modification Jahn, K.; Tørring, T.; Voigt, N. V.; Sørensen, R. S.; Kodal, A. L. B.; Andersen, E. S.; Gothelf, K. V.; Kjems, J. Bioconjugate Chem. 2011, 22, ) Controlling chiral organization of molecular rods on Au(111) by molecular design Knudsen, M. K.; Kalashnyk, N.; Masini, F.; Cramer, J. R.; Lægsgaard, E.; Besenbacher, F.; Linderoth, T. R.; Gothelf., K. V. J. Am. Chem. Soc. 2011, 133, ) Combining aryltriazenes and electrogenerated acids to create well-defined aryltethered films and patterns on surfaces Kongsfelt, M.; Vinther, J.; Malmos, K.; Ceccato, M.; Torbensen, K.; Knudsen, C. S.; Gothelf, K. V.; Pedersen, S. U.; Daasbjerg, K. J. Am. Chem. Soc. 2011, 133, ) Design and construction of double-decker tile as a route to three-dimensional periodic assembly of DNA Majumder, U.; Rangnekar, A.; Gothelf, K. V.; Reif, J. H.; LaBean, T. H. J. Am. Chem. Soc. 2011, 133, ) Development of a lipase-based optical assay for detection of DNA Pinijsuwan, S.; Shipovskov, S.; Surareungchai, W.; Ferapontova, E. E.; Gothelf, K. V. Org. Biomol. Chem. 2011, 9, ) Design and synthesis of DNA four-helix bundles Rangnekar, A.; Gothelf, K. V.; LaBean, T. H. Nanotechnology 2011, 22, ) DNA origami: a quantum leap for self-assembly of complex structures Tørring, T.; Voigt, N. V.; Nangreave, J.; Yan, H.; Gothelf, K. V. Chem. Soc. Rev. 2011, Advance Article DOI: /C1CS15057J.

2 90) A DNA tile actuator with eleven discrete states Zhang, Z.; Olsen, E. M.; Kryger, M.; Voigt, N. V.; Tørring, T.; Gültekin, E.; Nielsen, M.; MohammadZadegan, R.; Andersen, E. S.; Nielsen, M. M.; Kjems, J.; Birkedal, V.; Gothelf, K. V. Angew. Chem. Int. Ed. 2011, 50, ) A nucleic acid dependent chemical photocatalysis in live human cells Arian, D.; Cló, E.; Gothelf, K. V.; Mokhir, A. Chem,. Eur. J. 2010, 16, ) Steering organizational and conformational surface chirality by controlling molecular chemical functionality Bombis, C.; Weigelt, S.; Knudsen, M. M.; Nørgaard, M.; Busse, C.; Lægsgaard, E.; Besenbacher, F.; Gothelf, K. V.; Linderoth, T. R., ACS Nano 2010, 4, ) DNA interactions with a methylene blue redox indicator depend on the DNA length and are sequence specific Farjami, E.; Clima, L.; Gothelf, K. V.; Ferapontova, E. E. Analyst 2010, 135, ) Electrochemical DNA sandwich assay with a lipase label for attomole detection of DNA Ferapontova, E. E.; Hansen, M. N.; Saunders, A. M.; Shipovskov, S.; Sutherland, D. S.; Gothelf, K. V. Chem. Commun. 2010, 46, ) Synthesis and application of a triazene ferrocene modifier for immobilization and characterization of oligonucleotides at electrodes Hansen, M. N.; Farjami, E.; Kristiansen, M.; Clima, L.; Pedersen, S. U.; Daasbjerg, K.; Ferapontova, E. E.; Gothelf, K. V. J. Org. Chem. 2010, 75, ) Weave tile architecture construction strategy for DNA nanotechnology Hansen, M. N.; Zhang, A. M.; Rangnekar, A.; Bompiani, K. M.; Carter, J. D.; Gothelf, K. V.; LaBean, T. H. J. Am. Chem. Soc. 2010, 132, ) Single molecule atomic force microscopy studies of photosensitized singlet oxygen behavior on a DNA origami template Helmig, S.; Rotaru, A.; Arian, D.; Kovbasyuk, L.; Arnbjerg, J.; Ogilby, P. R.; Kjems, J.; Mokhir, A.; Besenbacher, F.; Gothelf, K. V. ACS Nano 2010, 4, ) Small molecule induced control in duplex and triplex DNA-directed chemical reactions Jacobsen, M. F.; Ravnsbæk, J. B.; Gothelf, K. V. Org. Biomol. Chem. 2010, 8, ) DNA-templated covalent coupling of G4 PAMAM dendrimers Liu, H.; Tørring, T.; Dong, M.; Rosen, C. B.; Besenbacher, F.; Gothelf, K. V. J. Am. Chem. Soc. 2010, 132, ) Selective dsdna-templated formation of copper nanoparticles in solution Rotaru, A.; Dutta, S.; Jentzsch, E.; Gothelf, K. V.; Mokhir, A. Angew. Chem. Int. Ed. 2010, 49, ) DNA nanotechnology: Steps towards automated synthesis Rotaru, A.; Gothelf, K. V. Nat. Nanotech. 2010, 5, ) A novel secondary DNA binding site in human topoisomerase I unravelled by using a 2D DNA origami platform Subramani, R.; Juul, S.; Rotaru, A.; Andersen, F. F.; Gothelf, K. V.; Mamdouh, W.; Besenbacher, F.; Dong, M.; Knudsen, B. R. ACS Nano 2010, 4, ) Reversible ph-regulated control of photosensitized singlet oxygen production using a DNA i-motif Tørring, T.; Toftegaard, R.; Arnbjerg, J.; Ogilby, P. R.; Gothelf, K. V. Angew. Chem. Int. Ed. 2010, 49, ) Single-molecule chemical reactions on DNA origami Voigt, N. V.; Tørring, T.; Rotaru, A.; Jacobsen, M. F.; Ravnsbæk, J. B.; Subramani, R.; Mamdouh, W.; Kjems, J.; Mokhir, A.; Besenbacher, F.; Gothelf, K. V. Nat. Nanotech. 2010, 5, 200.

3 75) Supramolecular porous network formed by molecular recognition between chemically modified nucleobases guanine and cytosine Xu, W.; Wang, J.-g.; Jacobsen, M. F.; Mura, M.; Yu, M.; Kelly, R. E. A.; Meng, Q.-q.; Lægsgaard, E.; Stensgaard, I.; Linderoth, T. R.; Kjems, J.; Kantorovich, L. N.; Gothelf, K. V.; Besenbacher, F. Angew. Chem. Int. Ed. 2010, 49, ) Synthesis of functional molecular rod oligomers Andersen, C. S.; Gothelf, K. V. Org. Biomol. Chem. 2009, 7, ) Distance dependent interhelical couplings of organic rods incorporated in DNA 4- helix bundles Andersen, C. S.; Knudsen, M. M.; Chhabra, R.; Liu, Y.; Yan, H.; Gothelf, K. V. Bioconjugate Chem. 2009, 20, ) Self-assembly of a nanoscale DNA box with a controllable lid Andersen, E. S.; Dong, M.; Nielsen, M. M.; Jahn, K.; Subramani, R.; Mam- douh, W.; Golas, M. M.; Sander, B.; Stark, H.; Oliveira, C. L. P.; Pedersen, J. S.; Birkedal, V.; Besenbacher, F.; Gothelf, K. V.; Kjems, J. Nature 2009, 459, ) Optimization of the electrochemical RNA-aptamer based biosensor for theophylline by using a Methylene Blue redox label Ferapontova, E. E.; Gothelf, K. V. Electroanalysis 2009, 21, ) Effect of serum on an RNA aptamer-based electrochemical sensor for theophylline Ferapontova, E. E. ; Gothelf, K. V. Langmuir 2009, 25, ) A yoctoliter-scale DNA reactor for small-molecule evolution Hansen, M. H.; Blakskjær, P.; Petersen, L. K.; Hansen, T. H.; Højfeldt, J. W.; Gothelf, K. V.; Hansen, N. J. V. J. Am. Chem. Soc. 2009, 131, ) Synthesis and electrochemical studies of an anthraquinone-conjugated nucleoside and derived oligonucleotides Jacobsen, M. F.; Ferapontova, E. E.; Gothelf, K. V. Org. Biomol. Chem. 2009, 7, ) Effect of polymer cross-links on oxygen diffusion in glassy PMMA films Klinger, M.; Tolbod, L. P.; Gothelf, K. V.; Ogilby, P. R. ACS Appl. Mater. Interfaces 2009, 1, ) Self-assembly of artificial nucleobase 1H-benzimidazole-4,7-dione at the liquid/solid interface Mamdouh, W.; Kelly, R. E. A.; Dong, M.; Jacobsen, M. F.; Ferapontova, E. E.; Kantorovich, L. N.; Gothelf, K. V.; Besenbacher, F. J. Phys. Chem. B 2009, 113, ) Bridging one helical turn in double-stranded DNA by templated dimerization of molecular rods Andersen, C. S.; Yan, H.; Gothelf, K. V. Angew. Chem. Int. Ed. 2008, 47, ) DNA origami design of dolphin-shaped structures with flexible tails Andersen, E. S.; Dong, M.; Nielsen, M. M.; Jahn, K.; Lind-Thomsen, A.; Mamdouh, W.; Gothelf, K. V.; Besenbacher, F.; Kjems, J. ACS Nano 2008, 2, ) Labeling of DNA via rearrangement of s-2-aminoethyl phosphorothioates to n-(2- mercaptoethyl)phosphoramidates Chen, M.; Gothelf, K. V. Org. Biomol. Chem. 2008, 6, ) An RNA aptamer-based electrochemical biosensor for detection of theophylline in serum Ferapontova, E. E.; Olsen, E. M.; Gothelf, K. V. J. Am. Chem. Soc. 2008, 130, ) Toward reliable gold nanoparticle patterning on self-assembled DNA nanoscaffold Sharma, J.; Chhabra, R.; Andersen, C. S.; Gothelf, K. V.; Yan, H.; Liu, Y. J. Am. Chem. Soc. 2008, 130, ) Molecular self-assembly from building blocks synthesized on a surface in ultrahigh vacuum: Kinetic control and topo-chemical reactions Weigelt, S.; Bombis, C.; Busse, C.; Knudsen, M. M.; Gothelf, K. V.; Lægsgaard, E.; Besenbacher, F.; Linderoth, T. R. ACS Nano 2008, 2,

4 59) Surface synthesis of 2D branched polymer nanostructures Weigelt, S.; Busse, C.; Bombis, C.; Knudsen, M. M.; Gothelf, K. V.; Lægsgaard, E.; Besenbacher, F.; Linderoth, T. R. Angew. Chem. Int. Ed. 2008, 47, ) Chiral ordering and conformational dynamics for a class of oligo-phenyleneethynylenes on Au(111) Busse, C.; Weigelt, S.; Petersen, L.; Lægsgaard, E.; Besenbacher, F.; Linderoth, T. R.; Thomsen, A. H.; Nielsen, M.; Gothelf, K. V. J. Phys. Chem. B. 2007, 111, ) Rearrangement of s-(2-aminoethyl) thiophosphates to n-(2- mercaptoethyl)phosphoramidates Chen, M.; Maetzke, A.; Knak Jensen, S. J.; Gothelf, K. V. Eur. J. Org. Chem. 2007, ) Control and selectivity of photosensitized singlet oxygen production: Challenges in complex biological systems Cló, E.; Snyder, J. W.; Ogilby, P. R.; Gothelf, K. V. ChemBioChem 2007, 8, ) An electrochemical sensor based on the human estrogen receptor ligand binding domain Hansen, J. A.; Sumbayev, V. V.; Gothelf, K. V. Nano Lett. 2007, 7, ) Synthesis of rigid homo- and heteroditopic nucleobase-terminated molecules incorporating adenine and/or thymine Jacobsen, M. F.; Andersen, C. S.; Knudsen, M. M.; Gothelf, K. V. Org. Lett. 2007, 9, ) Model systems for activation of nucleic acid encoded prodrugs Jacobsen, M. F.; Cló, E., Mokhir, A.; Gothelf, K. V. ChemMedChem 2007, 2, ) Covalent interlinking of an aldehyde and an amine on a Au(111) surface in ultrahigh vacuum Weigelt, S.; Busse, C.; Bombis, C.; Knudsen, M. M.; Gothelf, K. V.; Strunskus, T.; Wöll, C.; Dahlbom, M.; Hammer, B.; Lægsgaard, E.; Besenbacher, F.; Linderoth, T. R. Angew. Chem. Int. Ed. 2007, 46, ) Influence of molecular geometry on the adsorption orientation for oligophenylene-ethynylenes on Au(111) Weigelt, S.; Busse, C.; Nielsen, M.; Gothelf, K. V.; Lægsgaard, E.; Besenbacher, F.; Linderoth, T. R. J. Phys. Chem. B 2007, 111, ) Synthesis of an elongated linear oligo(phenylene ethynylene)-based building block for application in DNA-programmed assembly Blakskjær, P.; Gothelf, K. V. Org. Biomol. Chem. 2006, 4, ) DNA-programmed control of photosensitized singlet oxygen production Cló, E.; Snyder, J. W.; Voigt, N. V.; Ogilby, P. R.; Gothelf, K. V. J. Am. Chem. Soc. 2006, 128, ) Femtomolar electrochemical detection of DNA targets using metal sulfide nanoparticles Hansen, J. A.; Mukhopadhyay, R.; Hansen, J. Ø.; Gothelf, K. V. J. Am. Chem. Soc. 2006, 128, ) Quantum-dot/aptamer-based ultrasensitive multi-analyte electrochemical biosensor Hansen, J. A.; Wang, J.; Kawde, A.-N.; Xiang, Y.; Gothelf, K. V.; Collins, G. J. Am. Chem. Soc. 2006, 128, ) A cleavable amino-thiol linker for reversible linking of amines to DNA Højfeldt, J. W.; Blakskjær, P.; Gothelf, K. V. J. Org. Chem. 2006, 71, ) Efficient N-arylation and N-alkenylation of the five DNA/RNA nucleobases Jacobsen, M. F., Knudsen, M. M.; Gothelf, K. V. J. Org. Chem. 2006, 71,

5 44) Chiral switching by spontaneous conformational change in adsorbed organic molecules Weigelt, S.; Busse, C.; Petersen, L.; Rauls, E.; Hammer, B.; Gothelf, K. V.; Besenbacher, F.; Linderoth, T. R. Nature Mater. 2006, 5, ) Effect of water on the palladium-catalyzed amidation of aryl bromides Dallas, A. S.; Gothelf, K. V. J. Org. Chem. 2005, 70, ) A modular approach to DNA-programmed self-assembly of macromolecular nanostructures Gothelf, K. V.; Brown, R. S. Chem. Eur. J. 2005, 11, ) DNA-programmed assembly of nanostructures Gothelf, K. V.; LaBean, T. H. Org. Biomol. Chem. 2005, 3, ) Preparation temperature dependence of size and polydispersity of alkylthiol monolayer protected gold clusters Jørgensen, J. M.; Erlacher, K.; Pedersen, J. S.; Gothelf, K. V Langmuir 2005, 21, ) Electrochemical properties of mixed self-assembled monolayers on gold electrodes containing mercaptooctylhydroquinone and alkylthiols Larsen, A. G.; Gothelf, K. V. Langmuir 2005, 21, ) Two-photon photosensitized production of singlet oxygen: Sensitizers with phenylene-ethynylene-based chromophores McIlroy, S. P.; Cló, E.; Nikolajsen, L.; Frederiksen, P. K.; Nielsen, C. B.; Mikkelsen, K. V.; Gothelf, K. V.; Ogilby, P. R. J. Org. Chem. 2005, 70, ) DNA-directed coupling of organic modules by multiple parallel reductive aminations and subsequent cleavage of selected DNA sequences Nielsen, M.; Dauksaite, V.; Kjems, J.; Gothelf, K. V. Bioconjugate Chem. 2005, 16, ) Formation and structure of conjugated salen-cross-linked polymers and their application in asymmetric heterogeneous catalysis Nielsen, M. M.; Thomsen, A. H.; Jensen, T. R.; Jakobsen, H. J.; Skibsted, J.; Gothelf, K. V. Eur. J. Org. Chem. 2005, 2005, ) Self-assembly of aluminium-salen coupled nanostructures from encoded modules with cleavable disulfide DNA-linkers Brown, R. S.; Nielsen, M.; Gothelf, K. V. Chem. Commun. 2004, ) Modular DNA-programmed assembly of linear and branched conjugated nanostructures Gothelf, K. V.; Thomsen, A.; Nielsen, M.; Cló, E.; Brown, R. S. J. Am. Chem. Soc. 2004, 126, ) An electrochemical quartz crystal microbalance study of the etching of gold surfaces in the presence of tetramethylthiourea Larsen, A. G.; Johannsen, K.; Gothelf, K. V. J. Coll. Int. Sci. 2004, 279, ) Synthesis of linear and tripoidal oligo(phenylene ethynylene)-based building blocks for application in modular DNA-programmed assembly Nielsen, M.; Thomsen, A. H.; Cló, E.; Kirpekar, F.; Gothelf, K. V. J. Org. Chem. 2004, 69, ) Catalytic asymmetric Henry reactions of silyl nitronates with aldehydes Risgaard, T.; Gothelf, K. V.; Jørgensen, K. A. Org. Biomol. Chem. 2003, 1, ) Nucleophilic addition of nitrones to ketones: Development of a new catalytic asymmetric nitrone-aldol reaction Bøgevig, A.; Gothelf, K. V.; Jørgensen, K. A. Chem. Eur. J. 2002, 8, ) Catalytic asymmetric 1,3-dipolar cycloaddition reactions of azomethine ylides a simple approach to optically active highly functionalized proline derivatives Gothelf, A. S.; Gothelf, K. V.; Hazell, R. G.; Jørgensen, K. A. Angew. Chem. Int. Ed. 2002, 41,

6 28) Attachment of alkyltrichlorosilanes to the terminal 3,5-dihydroxyphenyl moiety of a self-assembled thiol monolayer on gold Gothelf, K. V.; Larsen, A. G. J. Coll. Int. Sci. 2002, 255, ) lectron transfer reactions of self- assembled monolayers of thio(phenylacetylene)n-substituted chiral metal-salen complexes Nielsen, M.; Larsen, N. B.; Gothelf, K. V. Langmuir 2002, 18, ) Density functional theory study of enantiospecific adsorption at chiral surfaces Sljivancanin, Z.; Gothelf, K. V.; Hammer, B. J. Am. Chem. Soc. 2002, 124, ) The first catalytic asymmetric Aza-Henry reaction of nitronates with imines: A novel approach to optically active β-nitro-α-amino acid- and α,β-diamino acid derivatives Knudsen, K. R.; Risgaard, T.; Nishiwaki, N.; Gothelf, K. V.; Jørgensen, K. A. J. Am. Chem. Soc. 2001, 123, ) Synthesis and catalytic properties of p-acylthio(phenylacetylene)n substituted chiral manganese salen complexes Nielsen, M.; Gothelf, K. V. J. Chem. Soc., Perkin Trans , ) Catalytic enantioselective addition of nitro compounds to imines a simple approach for the synthesis of optically active β-nitro-α-amino esters Nishiwaki, N.; Rahbek Knudsen, K.; Gothelf, K. V.; Jørgensen, K. A. Angew. Chem. Int. Ed. 2001, 40, ) Self-assembled monolayers of long-chain xanthic acids on gold studied by voltammetry Gothelf, K. V. J. Electroanal. Chem. 2000, 494, ) Cheminform abstract: Asymmetric catalysis of 1,3-dipolar cycloaddition reactions: The concepts of activation and induction of asymmetry Gothelf, K. V.; Jensen, K. B.; Jørgensen, K. A. ChemInform 2000, 31, no. 20) Catalytic enantioselective 1,3-dipolar cycloaddition reactions of nitrones Gothelf, K. V., Jørgensen, K. A. Chem. Commun. 2000, Feature Article. 19) Asymmetric catalysis of 1,3- dipolar cycloaddition reactions The concepts of activation and induction of asymmetry. Gothelf, K. V.; Jensen, K. B.; Jørgensen, K. A. Science Prog. 1999, 82, ) Catalytic enantioselective inverse-electron demand 1,3-dipolar cycloaddition reactions of nitrones with alkenes Simonsen, K. B.; Bayón, P.; Hazell, R. G.; Gothelf, K. V.; Jørgensen, K. A. J. Am. Chem. Soc. 1999, 121, ) Molecular sieve dependent absolute stereoselectivity in asymmetric catalytic 1,3- dipolar cycloaddition reactions Gothelf, K. V.; Hazell, R. G.; Jørgensen, K. A. J. Org. Chem. 1998, 63, ) Asymmetric 1,3-Dipolar cycloaddition reactions Gothelf, K. V.; Jørgensen, K. A. Chem. Rev. 1998, 98, ) A simple synthetic approach to 3,3 -diaryl BINOLs Simonsen, K. B.; Gothelf, K. V.; Jørgensen, K. A. J. Org. Chem. 1998, 63, ) On the structure of C,N-diphenylnitrone in 1,3-dipolar cycloaddition reactions Gothelf, K. V.; Hazell, R. G.; Jørgensen, K. A. Acta Chem. Scand. 1997, 51, ) On the trans-cis controversy in Ti-TADDOLate-catalysed cycloadditions. Experimental indications for the structure of the reactive catalyst-substrate intermediate Gothelf, K. V.; Jørgensen, K. A. J. Chem. Soc., Perkin Trans , ) Improvement of TADDOLate-TiCl2-catalyzed 1,3-dipolar nitrone cycloaddition reactions by substitution of the oxazolidinone auxiliary of the alkene with succinimide Jensen, K. B.; Gothelf, K. V.; Hazell, R. G.; Jørgensen, K. A. J. Org. Chem. 1997, 62,

7 11) Control of regio-, diastereo-, and enantioselectivity in the [Ti(OTs)2(TADDOLato)]-catalyzed 1,3-dipolar cycloaddition reaction between 3- acryloyloxazolidin-2-one and nitrones Jensen, K. B.; Gothelf, K. V.; Jørgensen, K. A. Helv. Chim. Acta 1997, 80, ) Lanthanide-catalyzed endo- and enantioselective 1,3-dipolar cycloaddition reactions of nitrones with alkenes Sanchez-Blanco, A. I.; Gothelf, K. V.; Jørgensen, K. A. Tetrahedron Lett. 1997, 38, ) Control of diastereo- and enantioselectivity in metal-catalyzed 1,3-dipolar cycloaddition reactions of nitrones with alkenes. Experimental and theoretical investigations Gothelf, K. V.; Hazell, R. G.; Jørgensen, K. A. J. Org. Chem. 1996, 61, ) Metal-catalyzed asymmetric 1,3-dipolar cycload- dition reactions Gothelf, K. V.; Jørgensen, K. A. Acta Chem. Scand. 1996, 50, ) A highly diastereoselective and enantioselective Ti(OTos)2-TADDOLate-catalyzed 1,3-dipolar cycloaddition reaction of alkenes with nitrones Gothelf, K. V.; Thomsen, I.; Jørgensen, K. A. J. Am. Chem. Soc. 1996, 118, ) Crystal structure of a chiral titanium catalyst-alkene complex. The intermediate in catalytic asymmetric Diels-Alder and 1,3-dipolar cycloaddition reactions Gothelf, K. V.; Hazell, R. G.; Jørgensen, K. A. J. Am. Chem. Soc. 1995, 117, ) On the mechanism of Ti-TADDOLate-catalyzed asymmetric Diels-Alder reactions Gothelf, K. V.; Jørgensen, K. A. J. Org. Chem. 1995, 60, ) Transition-metal catalyzed asymmetric 1,3-dipolar cycloaddition reactions between alkenes and nitrones Gothelf, K. V.; Jørgensen, K. A. J. Org. Chem. 1994, 59, ) Synthesis of 2,8-diarylpyrano[3,2-g]chromene-4,6-diones Gothelf, K. V.; Torssell, K. B. G. Acta Chem. Scand. 1994, 59, ) Synthesis of flavones via application of nitrile oxide and the Stille reactions Gothelf, K. V.; Torssell, K. B. G. Acta Chem. Scand. 1994, 48, ) A convenient synthesis of flavones. Synthesis of apigenin Gothelf, K. V.; Thomsen, I.; Torssell, K. B. G. Acta Chem. Scand. 1992, 46, Book Chapters 3) Self-assembling DNA Nanostructures for Patterned Molecular Assembly in Nanobiotechnology II: More Concepts and Applications, (eds. C. Niemeyer & C. Mirkin), LaBean T. H.; Gothelf, K. V.; Reif, J. H., Wiley-VCH, Weinheim, ) Asymmetric Reactions Gothelf, K. V.; Jørgensen, K. A. in Applications of 1,3-Dipolar Cycloaddition Chemistry Towards Heterocycles and Natural Products Padwa and Pearson (Eds.), Wiley, ) Asymmetric Metal-Catalyzed 1,3-Dipolar Cycloaddition Reactions Gothelf, K. V. in Cycloaddition Reactions in Organic Chemistry, pp , Kobayashi, Jørgensen (Eds.), Wiley-VCH, Others 2) Steps towards automated synthesis Rotaru, A.; Gothelf, K.V. Nature Nanotech. 2010, 5, (News and Views). 1) DNA Origami Voigt, N. V.; Tørring, T.; Gothelf, K. V. DANSK KEMI 2010, s. 18. Patents

8 a) Bis-heterocyclic Derivatives Gothelf, K. V. WO b) Macromolecular Architectures Gothelf, K. V.;Thomsen, A. H.; Nielsen, M.; Brown, R. S. WO

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