GC AND GC/MS. Your Essential Resource for Columns & Supplies

Transcription

1 GC AND GC/MS Your Essential Resource for Columns & Supplies

2 GC AND GC/MS Achieve excellent, reproducible performance for difficult samples For over 0 years, Agilent has broken new ground with innovations in Gas Chromatography. We continue our leadership tradition by offering the industry's broadest selection of GC and GC/MS columns and supplies. All are manufactured to Agilent s exact specifications to minimize downtime and ensure consistent, high-quality results that you can rely on. Agilent Ultra Inert solutions provide the flow path inertness vital to analytical success. Ultra Inert split and splitless liners are manufactured and tested to our highest level of scrutiny to ensure quality and consistency. Agilent J&W Ultra Inert GC columns are tested with the industry s most demanding test probe to reduce detection limits and produce more accurate data for difficult analytes. Agilent GC and GC/MS instruments bring together all elements for trace-level analysis, dramatically improving MS resolution, spectral integrity, and detection limits.

3 GC and GC/MS supplies More samples, lower detection levels, with fewer analysts. These demands challenge laboratories to maximize the productivity and performance of their instrumentation. To help you stay ahead, Agilent is continuously improving our extensive portfolio of innovative, award winning GC columns and supplies, designed to help you resolve many of the day to day setbacks encountered in your lab. You can avoid downtime and your time can be better spent on meeting your analytical and business challenges. For labs pushing the detection limits of trace level analysis on very active compounds, Agilent Inert Flow Path solutions ensure a reliably inert flow path for higher sensitivity, accuracy, and reproducibility. Install industry leading Agilent J&W GC columns with new proprietary design GC column nuts and ferrules to simplify your day yet maximize your GC and GC/MS systems output. Inert Flow Path components Ultra Inert GC columns, Ultra Inert liners, Ultra Inert gold seals, UltiMetal Plus Capillary Flow Technology devices with Flexible Metal ferrules have Agilent proprietary deactivation chemistries to ensure sample integrity. "Better Connectivity" with products such as Self Tightening column nuts, UltiMetal Plus Flexible Metal ferrules, and Ultra Inert liners in Touchless packaging improves productivity with ease of use and convenience. Full portfolio of premium GC products to support your lab needs including Agilent CrossLab brand and Agilent Bulk supplies packaging. Agilent J&W GC columns deliver the best inertness for acids, bases, and mixed functional compounds, the lowest bleed levels, and the tightest column-to-column reproducibility. Mass Spec Grade GC columns (VF-ms, DB-ms and HP-ms) give you robust performance, low column bleed, and a wide range of selectivity. LTM column modules combine a fused silica capillary GC column with heating and temperature-sensing components for efficient column heating and cooling. What s more, integrated guard columns protect your analytical columns from non-volatile compounds in the sample matrix.

4 Table of Contents Agilent Solutions, Services and Support... Featured Products... Agilent Parts and Supplies... GC and GC/MS Maintenance Schedule... Bulk GC Supplies... Inlet Septa... Inlet Liners... Agilent Ultra Inert Liners... Capillary Column Ferrules and Nuts... GC Column Connection Supplies...0 Capillary Flow Technology Supplies... Press-fit Capillary Column Connectors... Graphpak Capillary Connectors... Large Valve Oven... Valves and Loops... Sample Introduction Systems...0 Agilent Vials and Closures for GC, GC/MS and GC/HS... Headspace Vials and Closures... High Performance Septa... CombiPAL Headspace Vials and Closures... Crimping and Decapping Tools...0 Teledyne Tekmar Purge and Trap Supplies... Markes Thermal Desorption... Inlet Systems... Split/Splitless Inlets... Multimode Inlet... Cool On-Column Inlets... Programmable Temperature Vaporizer (PTV) Inlets... Purged Packed Inlets... Detector Systems... Flame Ionization Detector (FID)... Electron Capture Detector (ECD)...00 Thermal Conductivity Detector (TCD)...0 Flame Photometric Detector (FPD)...0 Nitrogen Phosphorus Detector (NPD)... Nitrogen and Sulfur Chemiluminescence Detectors... GC Standards... 0A GC System... GC/MS Parts and Supplies... MSD Contamination... Ion Source... MSD Filaments... Vent Valve Supplies... Gas Clean Filters... Quadrupole Mass Filter... MSD Electron Multipliers and Replacement Horn... Vacuum Systems and Pumps... Diffusion Pump... Quiet Cover... Foreline Pump Triple Quadrupole GC/MS Q-TOF for GC/MS... 0-MS Ion Trap Parts and Supplies... 0-MS Parts and Supplies...0 GC/MS Standards... Agilent Syringes...

5 Agilent CrossLab GC Parts and Supplies... Product Introductions... Supplies for Bruker, Varian GC Systems...0 Supplies for PerkinElmer GC Systems... Supplies for Shimadzu GC Systems... Supplies for Thermo Scientific GC Systems... Supplies for CTC GC Autosamplers... Agilent J&W GC Columns...0 Column Selection... Column Selection Principles... GC Column Application and Method Guides... Agilent J&W Ultra Inert GC Columns... Agilent J&W High Efficiency GC Capillary Columns... Low-bleed GC/MS Columns... Premium Polysiloxane Columns... Polyethylene Glycol (PEG) Columns... Specialty Columns... PLOT Columns...0 Columns with Non-Bonded Stationary Phases... Guard Columns... LTM Column Modules... Fused Silica Tubing... Stainless Steel Tubing... Packed GC Columns...0 Custom GC Column Ordering... GC Column Test Standards... Column Installation and Troubleshooting... Applications...00 Environmental...0 Hydrocarbons...0 Pesticides and Herbicides...0 Semivolatiles... Volatiles... Air Analysis... Food, Flavor and Fragrance... Energy and Fuels... Industrial Chemical...0 Forensic Toxicology and Pharma... Indices... Ordering Information...

6 Agilent Solutions PUT MORE THAN 0 YEARS OF RELENTLESS INNOVATION BEHIND YOUR EVERY RESULT By continually raising the standards for technologies that support your routine analyses, Agilent's R&D efforts have led to breakthroughs such as: New GC columns that help you achieve higher levels of inertness and column-to-column reproducibility LC column choices that deliver the sensitivity and reliability you need for demanding applications Cutting-edge sample preparation products that promote reliable extraction and concentration Fresh atomic and molecular spectroscopy ideas for identifying and confirming targets and unknowns Longtime Agilent customers have experienced our commitment firsthand. And now, we look forward to demonstrating how Agilent's approach to relentless innovation can work to your advantage, too. CHEMICAL ANALYSIS SOLUTIONS Food From high-volume pesticide screening in food products to rapid identification of pathogens, Agilent understands the analytical needs of food producers, shippers, and regulators. Utilizing our easy-to-use analyzers and updated screening libraries, customers can quickly develop robust and reliable methods. Agilent's leading gas chromatography and mass spectrometry systems are widely regarded as valuable food testing techniques for an array of different analyses. Environmental Agilent offers more than 0 years of environmental testing and regulatory expertise. We help government and private labs with the full range of assays, from routine testing of soils for heavy metals to detection of pharmaceuticals in groundwater, in concentrations down to parts per trillion. Energy & Chemicals Agilent collaborates closely with process industry customers to offer analytical systems that meet their needs for separation, detection, throughput, and support. We ll even preconfigure custom or standard analyzers so they arrive at the lab ready-to-go. From crude oil, natural gas, and refining, to specialty chemicals and alternative fuels, Agilent provides the latest technologies and solutions to increase quality, safety, and profitability for energy and chemical labs, while meeting the industry's stringent quality requirements. Agilent leads the way in ASTM collaborations that have evolved and will continue to evolve into industry standards. Forensics Whether testing for poisons in a forensics investigation, screening athletes for performance enhancing drugs, analyzing samples for recreational drugs, or checking a crime scene for explosive residue lives and professions may be dependent on the accuracy of your equipment. Agilent Technologies leads the industry with a comprehensive portfolio of workflow solutions that provide the ability to identify, confirm and quantify thousands of substances. Lab Informatics The ways labs capture, analyze and share data profoundly affect their efficiency. Agilent offers a rich, integrated suite of software products built on customer-driven architectural values with the Agilent OpenLAB Software Suite. OpenLAB delivers superior performance and connection across multiple systems, providing open systems integration and investment protection. Our commitment is to deliver more value across each step in the life cycle of scientific data from data collection and analysis to interpretation and management. Materials Science Agilent offers a newly expanded portfolio of instruments used for the research, manufacturing and testing of advanced materials, from precision optics to pulp and paper. Tools for atomic spectroscopy, molecular spectroscopy, chromatography, and X-ray crystallography all support continuous progress in materials science.

7 L I F E S C I E N C E S O L U T I O N S Biopharmaceutical Biotherapeutics have enormous potential to improve human health, with growing numbers of protein and antibody therapeutics to address unmet medical needs. At every development stage, from disease research to QA/QC and manufacturing, Agilent can help you make the right choices for moving therapeutics to market. We understand the biopharmaceutical workflow so our product families work together seamlessly, as engines of research, discovery, and development. Agilent columns deliver complete characterization of biomolecules using reversed-phase, size exclusion, ion exchange, and affinity chromatography. Our bio-inert supplies ensure that every part of your workflow delivers the performance you need to optimize your bio-separation. Pharmaceutical You need the most efficient processes to evaluate drug candidates, determine efficacy, and ensure safety and compliance during development and manufacture. Agilent has worked with pharma companies for many years to ensure reliability and reproducibility for regulatory compliance, from lab-to-lab and around the world. Our pharma solutions provide high-throughput capability at every stage of the product lifecycle, with automated sample prep, industry-leading U/HPLC systems, the largest family of Fast LC columns, open access LC/MS, spectroscopy, and automated dissolution. A complete family of LC supplies and lamps help optimize every analysis and take day-to-day lab efficiency one step further. Proteomics Research into how large sets of proteins affect the health of an organism requires special sets of analytical tools. Agilent has built a formidable arsenal of liquid chromatograph/mass spectrometers, bioinformatics systems, multiple affinity protein removal columns, and OFFGEL electrophoresis for protein identification and protein biomarker discovery. Accurate-Mass mass spectrometry and the microfluidic HPLC-Chip/MS are two Agilent innovations speeding the work of proteomics researchers around the globe. Metabolomics Collections of small molecules are increasingly being seen as rich sources of biomarkers, but studying metabolites presents many challenges. The need for speed, accuracy, and powerful interpretation capabilities in looking at chemical profile snapshots is underscored because molecules are constantly entering, leaving or changing within the metabolome. Agilent s GC, LC, and MS portfolios, along with our excellent bioinformatics offerings, user-customizable METLIN metabolite database for LC/MS, and the industry s first commercial GC/MS retention time locked metabolite library align well with the needs of metabolomics researchers. Genomics Agilent is a global leader in microarrays, scanners, and NGS reagents used in a wide variety of genomic-based disease research experiments. Our SureSelect and HaloPlex Target Enrichment Systems dominate the category, streamlining next generation sequencing studies. Agilent offers a wide range of catalog CGH and gene expresssion microarrays and a highly-developed capability to produce custom arrays using our free online design tool, SureDesign. All Agilent microarrays feature highly sensitive, selective 0-mer probes, and, with as many as eight arrays printed on a slide, the cost per sample is cost-efficient. Life Science Informatics Mirroring its extensive instrument portfolio, Agilent offers the industry s most extensive suite of bioinformatics software, helping users derive knowledge from complex genomic, proteomic, metabolomic and other biological data. SureCall and CytoGenomics software analyzes NGS and acgh data and the GeneSpring suite provides multi-omic analysis and visualization capabilities to help compare complex datasets to explore biological questions from multiple perspectives. The GeneSpring suite includes the GX module for microarray-based gene expression and genotyping data, the PA module for Pathway Analysis and multi-omic analysis and the MPP software, which analyzes mass spec data from proteomics and metabolomics experiments. Lab Automation To meet the skyrocketing demand for more throughput and automation, Agilent has substantially expanded its lab automation offerings. The Agilent line of liquid handlers and microplate processors are designed to streamline high-volume life science workflows. Agilent is also continually upgrading its advanced autosamplers for LC, GC, LC/MS and GC/MS, adding functionality and speed to reflect the performance of its advanced instruments. Vacuum Technology Agilent works with customers to solve vacuum challenges from experiments in high-energy physics to developing systems for nanotechnology. Agilent manufactures vacuum systems used in its own mass spectrometry instruments as well as those of other manufacturers. Agilent's vacuum technology has been proven by the most powerful physics experiment ever built, CERN s Big Bang machine, which was used in the discovery of the Higgs boson.

8 AGILENT SERVICE AND SUPPORT Agilent Service and Support for Instrument Systems Focus on what you do best For over 0 years, Agilent has been building and maintaining the instruments you count on to stay competitive and successful. Trust us to protect your investment with a broad portfolio of services, backed by a global network of experienced service professionals dedicated to the productivity of your lab. Agilent Advantage Service Plans Get the Agilent Service Guarantee Should your instrument require service while covered by an Agilent Advantage service agreement, we guarantee repair or we will replace your instrument for free. No other company offers this level of commitment to keep your lab up and running at peak efficiency. The best service available for your Agilent instruments Agilent offers a flexible range of service plans so that you can choose the level of coverage that is best for your lab. Agilent Advantage Gold Priority-one coverage for ultimate uptime and productivity Agilent Advantage Silver Comprehensive coverage for dependable laboratory operations Agilent Advantage Bronze Total repair coverage at a fixed annual price Agilent Repair Service Basic coverage for reliable instrument repair Agilent Advantage service plans include Agilent Remote Advisor for real-time remote monitoring and diagnostics. Through secure internet connections, you can interact with Agilent service professionals, receive detailed asset reports, and configure text or alerts to notify you before problems occur helping you to maximize instrument uptime and optimize laboratory workflows. And for Agilent-quality service on analytical instruments from other leading manufacturers, Agilent CrossLab services offer the same quality coverage you have come to expect from the expert Agilent engineers you know and trust. Agilent Compliance Services Equipment qualification that meets the most stringent requirements Enterprise Edition Compliance was developed to streamline qualification delivery compliance across your entire lab. Used worldwide in regulated labs, including standards organizations and regulatory agencies, Enterprise Edition enables you to: Laboratory decision makers and users ranked Agilent as their first choice for general laboratory compliance services. Improve qualification efficiency by harmonizing protocols across platforms to ensure greater efficiency and minimize regulatory risk Standardize your entire compliance operation with robust test designs that work with all your instruments Add, remove or reconfigure tests based upon your unique user requirements Reduce staff review time significantly with consistently formatted, computer generated, tamper-proof reports

9 AGILENT SERVICE AND SUPPORT Agilent Education and Consulting Services Our best minds, working for you Make the most of your instrument with training and consulting from the same experts who designed the instruments, software and processes you use every day. Classroom, online, and on-site training in instrument operation, troubleshooting and maintenance Customized consulting services to meet your lab s unique needs The Agilent Value Promise 0 Years of Guaranteed Value In addition to continually evolving products, we offer something else unique to the industry our 0-year value promise guarantee. The Agilent Value Promise guarantees you at least 0 years of instrument use from your date of purchase, or we will credit you with the residual value of the system toward an upgraded model. Not only does Agilent ensure a reliable purchase now, but we also ensure that your investment is just as valuable in the future. For more detailed information, please go to or contact your local Agilent Services and Support representative. Technical Support at work for you Have a hardware, software, application, instrument repair or troubleshooting question? Agilent's technical experts are available to answer your questions. With years of laboratory experience, our technical support specialists can provide in-depth knowledge and experience. For questions pertaining to supplies found in this catalog, contact your local Agilent office or Authorized Agilent Distributor or visit Need more information? Visit to: Locate your nearest Agilent office or distributor for expert technical support. Get fast sales and product assistance by phone. Simply use the scroll-down menu to select your country. Receive assistance using our convenient online forms.

10 GC And GC/Ms APPlICATIons GC and GC/Ms Applications Industry-specific applications from your partner in chromatography With over 0 years of chromatography expertise, Agilent is a great resource for all types of applications. In fact, we re developing new ones every day. Simply turn to the pages listed below for the most current applications based on your area of specialization. Environmental you ll learn how to perform critical analyses such as measuring the levels of atmospheric halocarbons and identifying organochlorine pesticides in soil while meeting your increasing demands for speed and accuracy. Turn to page 0. Food, Flavors, and Fragrances we ll discuss how to ensure quality, safety, and regulatory compliance for fragrances, perfumes, and essential oils. Applications focus on chiral compounds, menthol, and FAMEs. Turn to page. Energy and Fuels here you ll find applications such as the analysis of sulfur compounds in propylene that you can use right away to meet regulatory requirements, improve efficiency, and maintain good environmental stewardship. Turn to page. Industrial Chemical we ll help you maintain product quality and production efficiency by sharing the latest applications for alcohols, halogenated hydrocarbons, aromatic solvents, phenols, and inorganic gases. Turn to page 0. Forensic Toxicology and Pharma we ll bring you fully up-to-date on the newest screening methods for controlled substances such as amphetamines, narcotics, and alcohol. We ll also review the latest techniques for monitoring residual solvents. Turn to page. TIPs & Tools Search the ScanView database to find almost 000 GC applications and standard methods of all types, old and new. Get your free copy of ScanView at 00

11 EnVIRonMEnTAl APPlICATIons, HydRoCARBons Environmental Applications, Hydrocarbons Unleaded Gasoline db-vrx - 0 m x 0. mm,. µm Helium at 0 cm/s (0. ml/min), measured at 0 C 0 C for min, 0-00 C at C/min, 00 C for min Sampler: Purge and Trap (O.I.A. 0) Trap: BTEX (Supelco) at 0 C during purge Desorb: 0 C for min Injection: LVI (Low Volume Injector) Detector: A: FID, 0 C B: PID (O.I.A. 0), 00 C Sample: ppb gasoline in ml water A: FID B: PID. -Methylpentane. Benzene. Isooctane. Toluene. Ethylbenzene. m, p-xylene. o-xylene.,,-trimethylbenzene. Naphthalene GCEH00 0

12 EnVIRonMEnTAl APPlICATIons, HydRoCARBons determination of Chlorophenols in water and soil VF-ms CP 0 m x 0. mm, 0. µm 0 C, 0 C/min to 00 C He 0 kpa, 0. bar,. psi Injection: Splitless, initial time: min; Splitflow: 0 ml/min 0 C µl Detector: MS 0 C 000. Phenol. -Chlorophenol. -Chlorophenol. -Chlorophenol.,-Dichlorophenol.,+,-Dichlorophenol.,-Dichlorophenol.,-Dichlorophenol.,-Dichlorophenol 0.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,,-Tetrachlorophenol.,,,-Tetrachlorophenol.,,,-Tetrachlorophenol Sample: Isohexane 0000 Sample Conc: Standard, µg/ml, derivatization with acetic acid anhydride 000 Dr. Weßling, Laboratorien GmbH min PBdEs by ECd Injection: Split, 0 C Split ratio 0: db-xlb m x 0. mm, 0.0 µm Agilent Technologies custom column Hydrogen at cm/s at 00 C (.0 ml/min), constant flow mode 00 C for 0. min 00 C to 00 C at 0 C/min 00 C for min Detector: ECD, 00 C Peak, Congener (. mg/ml) Sample: µl.,',-tribde (BDE-).,,'-TriBDE (BDE-).,',',-Tetra-BDE (BDE-).,',,'-Tetra-BDE (BDE-).,',,'-TetraBDE (BDE-).,',,',-PentaBDE (BDE-00).,',,',-PentaBDE (BDE-) 0.,',,,'-PentaBDE (BDE-).,',,',,'-HexaBDE (BDE-) 0.,',,',,'-HexaBDE (BDE-).,',,,','-HexaBDE (BDE-).,',,,',',-HeptaBDE (BDE-).,,',,',,-HeptaBDE (BDE-0). DecaBDE (BDE-0) (. mg/ml) Special thanks to AccuStandard, Inc. of New Haven, CT, for PBDE standards. BDE GCES00 0

13 EnVIRonMEnTAl APPlICATIons, HydRoCARBons diesel Fuel db-ms - 0 m x 0. mm,.0 µm Helium at. cm/s, measured at 0 C 0 C for min 0-00 C at C/min 00 C for 0 min suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - Injection: Direct, 0 C Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: µl injection in hexane A: Standard, 0 ng/component B: Sample, 0. mg/ml diesel fuel standard 0 ng/component A diesel fuel 0. mg/ml B. n-c 0, Decane. n-c, Dodecane. n-c, Tetradecane. n-c, Hexadecane. n-c, Octadecane. n-c 0, Eicosane. n-c, Docusane. n-c, Tetracosane. n-c, Hexacosane 0. n-c, Octacosane GCEH00 Analysis of Polycyclic Aromatic Hydrocarbons VF-Xms CP0 0 m x 0. mm, 0.0 µm Sample: µl ca. ng per component on-column Helium, 0 kpa Injection: Split, T= C Detector: Agilent Ion Trap MS 0 +. Naphthalene. Acenaphthylene. Acenaphthene. Fluorene. Phenanthrene. Anthracene. Fluoranthene. Pyrene. Chrysene 0. Benzo[a]anthracene. Benzo[k]fluoranthene. Benzo[b]fluoranthene. Benzo[a]pyrene. Indeno[,,-cd]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene min VGC

14 EnVIRonMEnTAl APPlICATIons, HydRoCARBons dioxins and dibenzofurans CP-sil CP 0 m x 0. mm, 0.0 µm Sample:.0 µl Toluene Sample Conc: Injection: Detector: pg/µl Helium, 0 kpa (. bar, psi) 00 C to 0 C to 0 C, C/min Splitless MSD 0.,,--TCDD.,,,-TCDF.,,,,-PeCDF.,,,,,-HxCDF.,,,,,-HxCDF.,,,,-PeCDF.,,,,,-HxCDD +,,,,-PeCDD.,,,,,-HxCDD.,,,,,-HxCDD 0.,,,,,,-HxCDF.,,,,,-HpCDD.,,,,,,-HpCDD.,,,,,,,-OCDF.,,,,,,,-OCDD 0 min VGC000 semi-volatile Components on an Agilent J&w db-ui 0d db-ui 0d - 0 m x 0. mm, 0. µm Instrument Agilent 0 Series GC Helium,. ml/min constant flow, septum, purge ml/min, purge time on 0. min 0 ml/min, gas saver off 0 C (.0 min), C/min to 00 C, 0 C/min to 0 C (0. min), C to C (. min) Inlet: MMI in nonpulsed splitless mode, µl at C Inlet liner: Dual taper direct connect liner Sampler: Agilent, 0.0 µl syringe (p/n G-0) Detector: MSD: C Transfer line, 0 C source, 0 C quad, -00 amu range Abundance pa Example total ion chromatogram of a component semi-volatile standard injection with a 0 ng on-column loading for each component. 0

15 EnVIRonMEnTAl APPlICATIons, HydRoCARBons Polybrominated diphenyl Ethers (PBdEs) db-ms Ultra Inert -UI m x 0. mm, 0. µm Instrument: Sampler: Inlet: 0 to C ( C/min), hold min Detector: Agilent 0N/B MSD Agilent B,.0 µl syringe (p/n -),.0 µl splitless injection, ng each component on-column Helium cm/s, constant flow Pulsed splitless; C, 0 psi until. min, purge flow 0 ml/min at.0 min MSD source at 00 C, quadrupole at 0 C, transfer line at 00 C, scan range amu Abundance suggested supplies liner: Direct connect, dual taper, deactivated, mm id, G-000 syringe: Autosampler syringe, 0. µl, g, cone, -. BDE-. BDE-00. BDE-. BDE-. BDE-. BDE-. BDE-0. BDE-0 + EU Priority PAHs Resolution of Critical Pairs on an Agilent J&w db-eupah Column db-eupah - 0 m x 0. mm, 0. µm Instrument: Sampler: Inlet: Detector: Agilent 0N/B MSD Agilent B,.0 µl syringe, 0. µl splitless injection, injection speed µl/min Helium, ramped flow.0 ml/min (0. min), ml/min to. ml/min C splitless, purge flow 0 ml/min at 0. min C (0. min) to 00 C ( C/min),. C/min to C, C/min to C, C/min to 00 C, 0 C/min to 0 C (. min) MSD source at 00 C, quadrupole at 0 C, transfer line at 0 C, scan range 0-0 amu All + EU regulated priority PAHs are well resolved with the DB-EUPAH column. Challenging benzo[b,k,j]fluoranthene isomers are baseline resolved, allowing for accurate quantitation of each isomer. In addition, baseline resolution is achieved for critical pairs benz[a]anthracene and cyclopenta[c,d]pyrene, cyclopenta[c,d]pyrene and chrysene, and indeno[,,-cd]pyrene and dibenz[a,h]anthracene. This application demonstrates that the DB-EUPAH column can provide excellent sensitivity and selectivity for the analysis of EU regulated PAHs. Abundance suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, dual taper, deactivated, mm id, G-000 syringe: µl tapered, FN -s//hp, -. Benzo[c]fluorene. Benz[a]anthracene. Cyclopenta[c,d]pyrene. Chrysene. -Methylchrysene. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[j]fluoranthene Rs. Rs. Rs. Rs.. Benz[a]pyrene 0. Indeno[,,-cd]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene. Dibenzo[a,l]pyrene. Dibenzo[a,e]pyrene. Dibenzo[a,i]pyrene. Dibenzo[a,h]pyrene Rs Time EU_PAHs 0

16 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Environmental Applications, Pesticides and Herbicides Fast ClP Pesticides db-clp - 0 m x 0. mm, 0. µm db-clp - 0 m x 0. mm, 0.0 µm Instrument: Agilent 0 GC with dual µecd Helium, constant flow. ml/min 0 C (hold 0. min), C/min to 0 C, C/min to 00 C, 0 C/min to 0 C, hold. min Sampler: Agilent Injection: µl splitless Detector: µecd at 0 C Sample: 0 ng/ml CLP Pesticides 0. Tetrachloro-m-xylene. a-bhc. g-bhc. b-bhc. Heptachlor. d-bhc. Aldrin. Heptachlor epoxide. g-chlordane 0. a-chlordane. Endosulfan I., -DDE. Dieldrin. Endrin., -DDD. Endosulfan II., -DDT. Endrin aldehyde. Endosulfan sulfate 0. Methoxychlor. Endrin ketone. Decachlorobiphenyl 0 0, 0 0

17 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs EPA Method 0., dibromoethane (EdB),,-dibromo--chloropropane (dbcp), and,,-trichloropropane (TCP) db-clp - 0 m x 0. mm, 0. µm db-clp - 0 m x 0. mm, 0.0 µm Helium, constant flow,. ml/min 0 C, hold. min, 0 C/min to C, 0 C/min to C, hold. min Injection: µl, splitless, 00 C Detector: µecd, 00 C Sample: 00 ng/ml EPA 0. analytes, 00 ng/ml chlorinated solvents + trihalomethanes. Chloroform.,,-Trichloroethane. Carbon tetrachloride. Trichloroethane. Bromodichloromethane. Tetrachloroethane.,,-Trichloroethane. Dibromochloromethane.,-Dibromoethane (EDB) 0. Bromoform.,,-Trichloropropane (TCP).,-Dibromo--chloropropane (DBCP) 0 00 ng/ml chlorinated solvents + THMs 00 ng/ml EPA 0. analytes min 0 00 ng/ml chlorinated solvents + THMs 00 ng/ml EPA 0. analytes min Agilent J&W DB-CLP/DB-CLP columns analyze,-dibromoethane (EDB),,-dibromo--chloropropane (DBCP), and,,-trichloropropane (TCP) according to EPA Method 0. with cooler analysis temperatures allowing a faster GC cycle time. 0

18 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides, EPA Method 0B db-clp - 0 m x 0. mm, 0. µm db-clp - 0 m x 0. mm, 0. µm Instrument: Agilent 0 GC with dual µecd Helium at. cm/s (constant flow) 0 C (hold 0. min) to 0 C at 0 C/min, C/min to C, C/min to 00 C, hold min Sampler: Agilent Injection: µl, splitless Detector: µecd at C Sample: 0 ng/ml 0B analytes.,-dibromo--chloropropane. Hexachlorocyclopentadiene. -Bromo--nitrobenzene. Etridiazole. Chloroneb. Trifluralin. TCMX. Propachlor. Di-allate isomers (0 ng/ml) 0. Hexachlorobenzene. a-bhc. Pentachloronitrobenzene. g-bhc. b-bhc. Heptachlor. Dichlone. Alachlor. d-bhc. Chlorothalonil 0. Aldrin. DCPA. Isodrin. Kelthane. Heptachlor epoxide. g-chlordane. trans-nonachlor. a-chlordane. Endosulfan I., -DDE 0. Dieldrin. Chlorobenzilate (0 ng/ml). Perthane (0 ng/ml). Chloropropylate (0 ng/ml). Endrin. Nitrofen., -DDD. Endosulfan II., -DDT. Endrin aldehyde 0. Endosulfan sulfate. Captafol. Methoxychlor. Endrin ketone. Mirex. cis-permethrin. trans-permethrin. Decachlorobiphenyl , 0 0, ,, 0 0 0

19 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs db-ui organic Acid Performance db- Ultra Inert -UI 0 m x 0. mm,.0 µm Non-Agilent, 0 m x 0. mm,. µm Hydrogen, ml/min constant flow 0 C ( min), then 0 C/min to 0 C Inlet: 0 C, µl, split :00 Inlet liner: mm, glass wool Detector: FID at 0 C 00. Formic acid (<DL). Acetic acid. Propionic acid. Acrylic acid. Isobutyric acid. n-butyric acid. Methacrylic acid. Isopentanoic acid. n-pentanoic acid 0. n-heptanoic acid. Levulinic acid. -Propyl pentanoic acid. -Ethyl hexanoic acid. Citronellic acid Organic acid mix C -C 0 ( to ng) on a DB-UI column (A) and a traditional non-agilent column (R) after conditioning at 0 C for h A R EPA Method Chlorinated solvents, Trihalomethanes (THMs), and disinfection Byproducts (dbps) db-clp - 0 m x 0. mm, 0. µm db-clp - 0 m x 0. mm, 0.0 µm Helium, constant flow, cm/s C, hold. min, 0 C/min to C, 0 C/min to 00 C, hold. min Injection: µl splitless, 00 C Detector: µecd, 00 C db-clp db-clp , min min. Chloroform.,,-Trichloroethane. Carbon tetrachloride. Trichloroacetonitrile. Trichloroethane. Chloral hydrate. Bromodichloromethane.,-Dichloro--propanone. Dichloroacetonitrile 0. Chloropicrin. Tetrachloroethane.,,-Trichloroethane. Dibromochloromethane.,-Dibromoethane.,,-Trichloro--propanone. Bromochloroacetonitrile. Bromoform.,,-Trichloropropane. Dibromoacetonitrile 0.,-Dibromo--chloropropane 0

20 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Analysis of semivolatiles Column A: Column B: db m x 0. mm, 0.0 µm db m x 0. mm, 0. µm A He constant flow mode,. ml/min 0 C ( min), C/min to 0 C.0 min hold Injection: Splitless 0. µl injected at 00 C, QuickSwap pressure.0 psi during acquisition, 0.0 psi during backflush with inlet set to.0 psi during backflush US EPA Method 0, ng/ml System Performance Check Compounds Chromatogram using a DB-., 0 m x 0. mm, 0. µm.00 GCHE00 Detector: Agilent C Performance Turbo MSD equipped with mm large-aperture drawout lens, p/n G-00 B Translating 0. mm id column method to 0. mm id format results in % reduction in analysis time. Resolution of peaks of interest is also maintained for the faster 0. mm id separation US EPA Method 0, ng/ml System Performance Check Compounds Chromatogram using a DB-., 0 m x 0. mm, 0. µm GCHE00 TIPs & Tools Learn more about the Agilent 0B GC System at 0

21 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Pesticides, EPA 0. db-ms - 0 m x 0. mm, 0. µm db-xlb - 0 m x 0. mm, 0.0 µm Helium at cm/s (EPC in constant flow mode) C for 0. min -00 C at 0 C/min 00 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: µecd, 0 C Nitrogen makeup gas (column + makeup flow = 0 ml/min constant flow) Sample: 0 pg per component suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - DB-ms DB-XLB, GCEP00,0,, Hexachlorocyclopentadiene. Etridiazole. Chloroneb. Trifluralin. Propachlor. Hexachlorobezene. a-bhc. Atrazine. Pentachloronitrobenzene 0. Simazine. g-bhc. b-bhc. Heptachlor. Alachlor. d-bhc. Chlorothalonil. Aldrin. Metribuzin. Metolachlor 0. DCPA.,'-Dibromobiphenyl. Heptachlor epoxide. Cyanazine. g-chlordane. a-chlordane. Endosulfan I.,'-DDE. Dieldrin. Chlorobenzilate 0. Endrin.,'-DDD. Endosulfan II.,'-DDT. Endrin aldehyde. Endosulfan sulfate. Methoxychlor. cis-permethrin. trans-permethrin 0 0 GCEP00

22 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Phenoxy Acid Herbicides Methyl derivatives, EPA A db-ms - 0 m x 0. mm, 0. µm Helium at cm/s (EPC in constant flow mode) 0 C for 0. min 0-00 C at C/min 00-0 C at C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: µecd, 0 C Nitrogen makeup gas (column + makeup flow = 0 ml/min constant flow) Sample: 0 pg per component DB-ms suggested supplies septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - syringe: 0 µl tapered, FN -s//hp, - 0 GCEP Dalapon.,-Dichlorobenzoic acid. -Nitrophenol. Methyl-,-dichlorophenylacetate (SS). Dicamba. MCPP. MCPA.,'-Dibromooctafluorobiphenyl (IS). Dichloroprop 0.,-D. Pentachlorophenol.,,-T,P.,,-T. Chloramben. Dinoseb.,-DB. Bentazone. DCPA. Picloram 0. Acifluorofen

23 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs direct Comparison for Rapid ClP (Contract laboratory Program) Pesticide Analysis Injection: Detector: db-ms - 0 m x 0. mm, 0. µm db-xlb - 0 m x 0. mm, 0. µm Hydrogen ( cm/s at 0 C, ramped at ml/min to 0 cm/s at. min) 0 C (0. min); 0 C/min to 0 C; 0 C/min to C (0. min);. C/min to 00 C (. min) Split/splitless, 0 C, pulsed splitless ( psi for 0. min, purge flow of 0 ml/min on at min, gas saver flow 0 ml/min on min) µecd 0 C; nitrogen makeup; constant column + makeup flow 0 ml/min db-ms primary column db-xlb confirmatory column Hz Hz Hz Vendor R primary column, 0 m x 0. mm, 0. µm Vendor R confirmatory column, 0 m x 0. mm, 0. µm Co-elution 0 Peak tailing 0 Peak tailing GCHE00. Tetrachloro-m-xylene. a-bhc. g-bhc. b-bhc. d-bhc. Heptachlor. Aldrin. Heptachlor epoxide. g-chlordane 0. a-chlordane. Endosulfan I.,' DDE. Dieldrin. Endrin.,' DDD. Endosulfan II.,' DDT. Endrin aldehyde. Endosulfan sulfate 0. Methoxychlor. Endrin ketone. Decachlorobiphenyl Hz Peak tailing Peak tailing Baseline rise GCHE00 The DB-ms primary column and DB-XLB confirmatory column sufficiently resolved all the peaks of interest in less than six minutes with sharp, symmetrical peaks and minimal baseline drift. In contrast, vendor R's primary analysis column resolved only 0 of peaks with visible peak tailing. Vendor R's confirmatory column resolved all peaks of interest but with peak tailing and an unacceptable level of temperature dependent baseline drift.

24 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Aroclors 0- (without ) db-xlb - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 00 C for min 00- C at. C/min Injection: Hot on-column, 0 C Detector: MSD, 0 C transfer line, SIM Sample: µl in isooctane,. ppm suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - GCES00 ClP Pesticides db-ms - 0 m x 0. mm, 0. µm db-xlb - 0 m x 0. mm, 0.0 µm Helium at cm/s (EPC in constant flow mode) 0 C for 0. min 0-0 C at C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: µecd, 0 C Nitrogen makeup gas (column + makeup flow = 0 ml/min constant flow) Sample: 0 pg per component DB-ms 0 0 DB-XLB 0 Complete resolution and confirmation of ClP Pesticides in under minutes! 0 GCEP00. Tetrachloro m-xylene (SS). a-bhc. g-bhc. b-bhc. Heptachlor. d-bhc. Aldrin. Heptachlor epoxide. g-chlordane 0. a-chlordane. Endosulfan I.,'-DDE. Dieldrin. Endrin.,'-DDD. Endosulfan II.,'-DDT. Endrin aldehyde. Endosulfan sulfate 0. Methoxychlor. Endrin ketone. Decachlorobiphenyl (SS) SS - Surrogate Standard 0 0 suggested supplies GCEP00 septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - syringe: 0 µl tapered, FN -s//hp, -

25 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs High speed VoC, EPA Method 0 db-vrx - 0 m x 0. mm,.00 µm Helium at cm/s (. ml/min) C for.0 min -0 C at C/min 0- C at 0 C/min C for 0. min Sampler: Purge and trap (Tekmar 00) Purge: min Trap: VoCarb 000 Preheat: C Desorb: 0 C for min Bake: 0 C for 0 min Line & valve:00 C. Dichlorodifluoromethane. Chloromethane. Hydroxypropionitrile. Vinyl chloride. Bromomethane. Chloroethane. Ethanol. Acetonitrile. Acrolein 0. Trichlorofluoromethane. Isopropyl alcohol. Acetone. Ethyl ether.,-dichloroethene. tert-butyl alcohol. Acrylonitrile. Methylene chloride. Allyl chloride. Allyl alcohol 0. -Propanol. Propargyl alcohol. trans-,-dichloroethene. MTBE.,-Dichloroethane. Propionitrile. -Butanone. Diisopropyl ether. cis-,-dichloroethene. Methacrylonitrile 0. Bromochloromethane. Chloroform.,-Dichloropropane. Ethyl acetate. Ethyl-tert-butyl ether. Methyl acrylate. Dibromofluoromethane (IS). Isobutanol. Dichloroethane-d (IS). Pentafluorobenzene 0.,-Dichloroethane.,,-Trichloroethane. -Chlorobutane. Crotonaldehyde. -Chloroethanol.,-Dichloropropene. -Butanol. Carbon tetrachloride. Chloroacetonitrile. Benzene 0. tert-amylmethyl ether. Fluorobenzene (IS). -Pentanone. Dibromomethane.,-Dichloropropane. Trichloroethene. Bromodichloromethane. -Nitropropane.,-Dioxane. Epichlorohydrin 0. Methyl methacrylate. cis-,-dichloropropene. Propiolactone. Bromoacetone. Pyridine. trans-,-dichloropropene.,,-trichloroethane. Toluene-d (IS). Toluene.,-Dichloropropane 0. Paraldehyde. Ethyl methacrylate. Dibromochloromethane. -Chloropropionitrile.,-Dibromoethane. Tetrachloroethene.,,,-Tetrachloroethane. -Chlorohexane. Chlorobenzene. Ethylbenzene 0. Bromoform. m-xylene. p-xylene. trans-dichlorobutene.,-dichloro--propanol. Styrene.,,,-Tetrachloroethane. o-xylene.,,-trichloropropane. cis-dichlorobutene 0. -Bromofluorobenzene (IS). Isopropylbenzene. Bromobenzene Injection: Split, 0 C Split ratio 0: Detector: Sample:. Propylbenzene. -Chlorotoluene. -Chlorotoluene.,,-Trimethylbenzene. Pentachloroethane. tert-butylbenzene.,,-trimethylbenzene 00. sec-butylbenzene 0.,-Dichlorobenzene 0. Benzyl chloride 0.,-Dichlorobenzene-d (IS) 0.,-Dichlorobenzene 0. Isopropyltoluene 0.,-Dichlorobenzene 0. Butylbenzene 0.,-Dibromo--chloropropane 0. Hexachloroethane 0. Nitrobenzene.,,-Trichlorobenzene. Naphthalene. Hexachlorobutadiene.,,-Trichlorobenzene Agilent MSD Scan range: -0 amu Scan rate:. scans/s Quad temp: 0 C Source temp: 00 C Transfer line temp: 00 C ml Halogentated and aromatic analytes at 0 ppb Internal standards at 0 ppb Polar analytes (i.e., ethers, alcohols and ketones at ppb), 0,, suggested supplies Ideal for Msd -0, 0, , 0 0, ,, septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal, 0-0, 0,, -,,,, 0, 0, , GCEV00

26 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs PBdEs Injection: Detector: Sample: 0. µl db-xlb - 0 m x 0. mm, 0.0 µm Helium at cm/s at 00 C (. ml/min), constant flow mode 00 C for min; 00 C to 0 C at 0 C/min, 0 C for min Cool on-column, oven-track mode Agilent MSD, C transfer line, EI SIM (ions monitored:.,.0,.,., 00., 0.,.,.,.,.,.) Abundance Abundance Ion.0 (.0 to.0): PBDE-0.D Tetra-BdE 00 ppb each 0:00 :00 :00 :00 Ion.0 (.0 to.0): PBDE-0.D Penta-BdE 0 ppb each 0:00 :00 :00 :00 Abundance Ion.0 (.0 to.0): PBDE-0.D 0:00 :00 :00 :00 Hexa-BdE 00 ppb each Abundance Ion.0 (.0 to.0): PBDE-0.D :00 :00 :00 :00 Hepta-BdE 0 ppb each GCES0 For a complete Application Note, visit select "Literature" from the Library and type -00EN into the "Keyword" field.

27 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs EPA Volatiles by GC/Ms (split Injector) db-vrx - 0 m x 0. mm,.0 µm Helium at 0 cm/s, measured at C C for 0 min -0 C at C/min 0 C for min 0- C at C/min C for min Sampler: Purge and trap (O.I.A. 0) Purge: Helium for min at 0 ml/min Trap: Tenax/Silica Gel/Carbosieve Preheat: C Desorb: 0 C for 0. min Injection: Split, 0 C Split flow 0 ml/min Detector: MSD, C transfer line Full scan -0 amu (m/z subtracted) suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal kit, -,, ,,,0 0 0, 0, GCEV00. Dichlorodifluoromethane. Chloromethane. Vinyl chloride. Bromomethane. Chloroethane. Trichlorofluoromethane. Diethyl ether.,-dichloroethene. Acetone 0. Iodomethane. Carbon disulfide. Allyl chloride. Methylene chloride. Acrylonitrile. Methyl-tert-butyl ether. trans-,-dichloroethene. Hexane.,-Dichloroethane. -Butanone 0. cis-,-dichloroethene.,-dichloropropane. Propionitrile. Methyl acrylate. Methacrylonitrile. Bromochloromethane. Tetrahydrofuran. Chloroform. Pentafluorobenzene (IS).,,-Trichloroethane 0. -Chlorobutane.,-Dichloropropene. Carbon tetrachloride. Benzene.,-Dichloroethane.,-Dimethylhexane. Fluorobenzene (IS).,-Difluorobenzene (IS). Trichloroethene.,-Dichloropropane 0. Methyl methacrylate. Dibromomethane. Bromodichloromethane. -Nitropropane. Chloroacetonitrile. cis-,-dichloropropene. -Methyl--pentanone.,-Dichloro--propanone. Toluene. trans-,-dichloropropene 0. Ethyl methacrylate.,,-trichloroethane. Tetrachloroethene.,-Dichloropropane. -Hexanone. Dibromochloromethane.,-Dibromoethane. -Chloro--fluorobenzene (IS). Chlorobenzene.,,,-Tetrachloroethane 0. Ethylbenzene. m-xylene. p-xylene. o-xylene. Styrene. Bromoform. Isopropylbenzene. -Bromofluorobenzene (SS).,,,-Tetrachloroethane. Bromobenzene 0.,,-Trichloropropane. trans-,-dichloro--butene. n-propylbenzene. -Chlorotoluene.,,-Trimethylbenzene. -Chlorotoluene. tert-butylbenzene. Pentachloroethane.,,-Trimethylbenzene. sec-butylbenzene 0.,-Dichlorobenzene. p-isopropyltoluene.,-dichlorobenzene. n-butylbenzene.,-dichlorobenzene. Hexachloroethane.,-Dibromo--chloropropane. Nitrobenzene.,,-Trichlorobenzene. Hexachlorobutadiene 0. Naphthalene.,,-Trichlorobenzene

28 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs EPA Method. db-ms - 0 m x 0. mm, 0. µm Helium at cm/s, measured at C, constant flow mode C for min -0 C at 0 C/min 0 C for min 0-0 C at C/min 0-0 C at C/min 0- C at C/min C for min Compound RT m/z. Isophorone..,-Dimethyl--nitrobenzene (SS).. Dichlorvos. 0. Hexachlorocyclopentadiene.. EPTC.. Mevinphos 0.0. Butylate 0. /. Vernolate 0.. Dimethyl phthalate Terrazole (etridiazole) 0. /.,-Dinitrotoluene 0.. Tillam (pebulate) 0.. Acenaphthylene 0.. Acenaphthene-d0 (IS). Chloroneb.. -Chlorobiphenyl.. Tebuthiuron..,-Dinitrotoluene.. Molinate. 0. Diethyl phthalate.. Fluorene.. Propachlor. 0. Ethoprop.. Cycloate. /. Chlorpropham.0. Trifluralin. 0. a-bhc..,-dichlorobiphenyl. /. Hexachlorobenzene. 0. Gesatamine (atraton). /. Prometon. /. Atrazine. 00/. Simazine. 0/. b-bhc.. Pentachlorophenol.. Propazine. /. g-bhc.. Terbufos.. Pronamide. 0. Diazinon. /. Phenanthrene-d0 (IS).. Chlorothalonil.. Phenanthrene.. Terbacil.0. Methyl paraoxon.0 0. Disulfoton.0. Anthracene.0. d-bhc.0 Injection: Splitless, 00 C.0 min purge activation time Focus liner Detector: MSD, C transfer line Full scan m/z suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, Sample: - Composite mixture of AccuStandard Method. standards (M-.-SV-ASL, M-.-FS-ASL, M-.-CP-ASL, M-.-NP-ASL, M-.-NP-ASL): target compounds at ng/µl, IS/SS at ng/µl Compound RT m/z Compound RT m/z.,,-trichlorobiphenyl. 0. Metribuzin.. Alachlor. 0. Simetryn.. Ametryn. /0. Heptachlor. 00. Prometryn.0 /. Prebane (terbutryn). /. Bromacil. 0. Di-n-butyl phthalate.0.,',,'-tetrachlorobiphenyl.0 0. Metolachlor.. Dursban (chlorpyrifos). /. Cyanazine. /. Dacthal (DCPA methyl ester). 0. Aldrin.. Triadimefon.. Diphenamid. /. MGK- (isomer A). /. MGK- (isomer B).. Heptachlor epoxide. 0.,',',,-Pentachlorobiphenyl.. Merphos. 0/. g-chlordane.. Tetrachlorvinphos (stirifos). 0. Butachlor.0 /0. Pyrene-d0 (SS).. Pyrene. 0. a-chlordane. /. Endosulfan I.. trans-nonachlor Fenamiphos. 0/. Napropamide.. Tricyclazole.. p,p'-dde.. DEF. /.,',,',,'-Hexachlorobiphenyl.0 0. Dieldrin.. Carboxin.. Endrin 0. /. Chlorobenzilate Endosulfan II 0.. p,p'-ddd 0. /. Endrin aldehyde.0. Norflurazon.. Benzyl butyl phthalate.. Endosulfan sulfate.. p,p'-ddt. /. Hexazinone.. Bis(-ethylhexyl) adipate.. Triphenylphosphate (SS). / 00. Endrin ketone (breakdown product). / 0.,',,',,',-Heptachlorobiphenyl. / 0. Benz[a]anthracene. 0. Chrysene-d (IS). 0 0.,',,',,',,'-Octachlorobiphenyl.0 0/ 0. Methoxychlor. 0. Chrysene. 0. Bis(-ethylhexyl) phthalate.0 0. Fenarimol.0 0. cis-permethrin. 0. trans-permethrin.0. Benzo[b]fluoranthene.0. Benzo[k]fluoranthene.. Fluridone.. Benzo[a]pyrene.. Perylene-d (SS).. Indeno[,,-c,d]pyrene.. Dibenz[a,h]anthracene.. Benzo[g,h,i]perylene GCES0

29 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Pesticides and Fire Retardants (Us EPA ) db-ms Ultra Inert -UI 0 m x 0. mm, 0. µm Helium, cm/s, constant flow 0 C ( min) to 0 C ( C/min), 0 C/min to 0 C ( min) Injection: Splitless, 0 C, purge flow 0 ml/min at min, gas saver 0 ml/min on at min Detector: Transfer line 0 C, source 00 C, quad 0 C Sample: Pesticide/PBDE standards, ng with ng IS/SS on-column 0 -, 0, USEPA.,-Dimethyl--nitrobenzene. Acenaphthalene-D0. Dimethoate. Atrazine. Propazine. Anthracene-D0. Vinclozoline. Prometryn. Bromacil 0. Malathion. Thiazopyr. Dursban. Benthiocarb. Parathion. Terbufos sulfone. Bioallethrin. Oxychlordane. Fenamiphos. Nitrophen 0. Norflurazon. Kepone. Hexazinone. Triphenyl phosphate. Bifenthrin. Chrysene-D. BDE-. Mirex. BDE-00. BDE- 0. Perylene-D. Fenvalerate. Esfenvalerate. Hexabromobiphenyl. BDE-

30 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs EPA Method 0. Chlorinated Pesticides and Herbicides db-clp - 0 m x 0. mm, 0. µm db-clp - 0 m x 0. mm, 0.0 µm Helium, constant flow, cm/s 0 ºC, hold 0. min, ºC/min to ºC,.ºC/min to ºC, ºC/min to 00 ºC, hold min Injection: µl, splitless, 0 ºC Detector: µced, 0 ºC Sample: 00 ng/ml EPA 0. analytes, 00 ng/ml pesticide surrogate mix db-clp 0 0. Hexchlorocyclopentadiene. Etridiazole. Chloroneb. Trifluralin. Tetrachloro-m-xylene (surrogate standard). Propachlor. Hexachlorobenzene. a-bhc. Atrazine 0. Simazine. g-bhc. ß-BHC. Heptachlor. Alachlor. d-bhc. Chlorothalonil. Aldrin. Metribuzin. Metolachlor 0 0. DCPA. Heptachlor epoxide. Cyanazine. Butachlor. g-chlordane. a-chlordane. Endosulfan I.,'-DDE. Dieldrin. Chlorobenzilate 0. Endrin.,'-DDD. Endosulfan II.,'-DDT. Endrin aldehyde. Endosulfan sulfate. Methoxychlor. cis-permethrin. trans-permethrin. Decachlorobiphenyl (surrogate standard) db-clp , min min The DB-CLP column separates all chlorinated pesticide and herbicide analytes acording to EPA Method 0. 0

31 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Chlorinated Pesticides, EPA Method 0 Injection: HP-ms 0s- 0 m x 0. mm, 0. µm Helium, psi, cm/s (0 C) constant flow 0 C for min 0-0 C at 0 C/min 0-0 C at C/min 0 C for min 0-0 C at C/min 0 C for min Splitless min purge delay Detector: ECD, 0 C Nitrogen makeup gas at 0 ml/min Anode purge ml/min. Etridiazole. Chloroneb. Propachlor. Trifluralin. a-bhc. Hexachlorobezene. b-bhc. d-bhc. g-bhc 0. Chlorothalonil 0. Heptachlor. Aldrin. DCPA. Heptachlor epoxide. g-chlordane. Endosulfan I. a-chlordane. Dieldrin.,'-DDE 0. Endrin. Endosulfan II. Chlorobenzilate.,'-DDD. Endrin aldehyde. Endosulfan sulfate.,'-ddt. Methoxychlor. cis-permethrin. trans-permethrin Sample: µl suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, GCEP00 organochlorine Pesticides db m x 0. mm, 0.0 µm Helium at 0 cm/s (.0 ml/min) 0- C at C/min C for 0 min Injection: Splitless, 0 C Detector: ECD, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl of 00 pg/µl standard in isooctane.,,,-tetrachloro-m-xylene (IS). a-bhc. b-bhc. g-bhc. d-bhc. Heptachlor. Aldrin. Heptachlor epoxide. g-chlordane 0. Endosulfan I. a-chlordane. Dieldrin. p,p -DDE. Endrin. Endosulfan II. p,p -DDD. Endrin aldehyde. Endosulfan sulfate. p,p -DDT 0. Endrin ketone. Methoxychlor. Decachlorobiphenyl (IS), suggested supplies liner: Splitless, single taper, deactivated, mm id, - septum: mm Advanced Green septa, - syringe: 0 µl tapered, FN -s//hp, GCEP00

32 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides III db m x 0. mm, 0.0 µm Helium at 0 cm/s (.0 ml/min) 0- C at C/min C for 0 min Injection: Splitless, 0 C Detector: ECD, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl of 00 pg/µl standard in isooctane.,,,-tetrachloro-m-xylene (IS). a-bhc. b-bhc. g-bhc. d-bhc. Heptachlor. Aldrin. Heptachlor epoxide. g-chlordane 0. Endosulfan I. a-chlordane. Dieldrin. p,p -DDE. Endrin. Endosulfan II. p,p -DDD. Endrin aldehyde. Endosulfan sulfate. p,p -DDT 0. Endrin ketone. Methoxychlor. Decachlorobiphenyl (IS) suggested supplies septum: mm Advanced Green septa, liner: Splitless, single taper, deactivated, mm id, - syringe: 0 µl tapered, FN -s//hp, GCEP0

33 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides IV db- - 0 m x 0. mm, 0.0 µm Helium at 0 cm/s (.0 ml/min) 0- C at C/min C for 0 min Injection: Splitless, 0 C Detector: ECD, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl of 00 pg/µl standard in isooctane.,,,-tetrachloro-m-xylene (IS). a-bhc. b-bhc. g-bhc. d-bhc. Heptachlor. Aldrin. Heptachlor epoxide. g-chlordane 0. Endosulfan I. a-chlordane. Dieldrin. p,p -DDE. Endrin. Endosulfan II. p,p -DDD. Endrin aldehyde. Endosulfan sulfate. p,p -DDT 0. Endrin ketone. Methoxychlor. Decachlorobiphenyl (IS) suggested supplies septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - 0, 0 syringe: 0 µl tapered, FN -s//hp, GCEP0

34 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides, db-/db-0p db m x 0. mm, 0. µm db-0p - 0 m x 0. mm, 0. µm Guard Column m x 0. mm, 0. µm Helium at. cm/s, measured at 0 C 0 C for 0. min 0-0 C at 0 C/min 0-0 C at C/min 0 C for min Injection: Splitless, 00 C Detector: ECD, C Nitrogen makeup gas at 0 ml/min Sample:.0 µl, 0-00 pg/µl Enlarged view of critical pair on DB- DB- DB-0P Enlarged view of critical pair on DB-0P 0 0 0, 0 0 0, 0, Etridiazole. Chloroneb. Propachlor. Tetrachloro-m-xylene (IS). Trifluralin. a-bhc. Hexachlorobenzene. b-bhc. g-bhc 0. Pentachloronitrobenzene. p,p'-dichlorobiphenyl. d-bhc. Heptachlor. Alachlor. Aldrin. Chlorpyrifos. DCPA. Isodrin. Heptachlor epoxide 0. Captan. g-chlordane. o,p -DDE. Endosulfan I. a-chlordane. Dieldrin. p,p -DDE. o,p -DDD. Endrin. Endosulfan II 0. Chlorobenzilate. p,p -DDD. o,p -DDT. Endrin aldehyde. Endrin ketone. Carbophenothion. p,p -DDT. Endosulfan sulfate. Hexabromobenzene (HBB). Methoxychlor 0. Mirex. cis-permethrin. trans-permethrin. Decachlorobiphenyl (IS)

35 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides VF-ms CP 0 m x 0. mm, 0. µm Sample:.0 µl Sample Conc: 00 µg/ml Helium, 0 kpa Injection: Splitter, :00 Detector: MS, Ion Trap, TIC 00 Percent 0. a-bhc. b-bhc. d-bhc. g-bhc (lindane). Heptachlor. Aldrin. Heptachlor epoxide. Endosulfan I., -DDE 0. Dieldrin. Endrin., -DDD. Endosulfan II. Endrin aldehyde., -DDT. Endosulfan sulfate 0 min VGC000 nitrogen/phosphorus Containing Pesticides, EPA Method 0 HP-ms 0s- 0 m x 0. mm, 0. µm Helium, 0 cm/s (. psi) pressure program 0- C at 0 C/min C for min -0 C at C/min 0-0 C at 0 C/min 0 C for min Injection: Splitless, 0 C min purge delay Detector: NPD, 0 C Helium makeup gas at 0 ml/min 0 0, suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - 0 GCEP0. Dichlorvos. EPTC. Butylate. Mevinphos. Vernolate. Pebulate. Tebuthiuron. Molinate. Ethoprop 0. Cycloate. Chlorpropham. Atraton. Simazine. Prometon. Atrazine. Propazine. Terbufos. Pronamide. Diazinon 0. Disulfoton. Terbacil. Metribuzin. Simetryn. Alachlor. Ametryn. Prometryn. Terbutryn. Bromacil. Metolachlor 0. Triadimefon. MGK-. Diphenamid. Stirifos. Butachlor. Fenamiphos. Napropamide. Tricyclazole. Merphos. Carboxin 0. Norflurazon. Hexazinone. Fenarimol. Fluridone

36 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Herbicides I db-xlb - 0 m x 0. mm, 0. µm suggested supplies septum: mm Advanced Green septa, - Helium at cm/s, measured at 0 C liner: Splitless, single taper, deactivated, mm id, - 0 C for min 0-0 C at 0 C/min 0-0 C at C/min 0-0 C at 0 C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: Sample: MSD, 00 C transfer line Full scan 0-00 µl x 0-0 ng/µl solution in acetone,, 0 0 -,, syringe: 0 µl tapered, FN -s//hp, -. Monuron. Diuron. EPTC. Dichlobenil. Vernolate. Pebulate. Molinate. Sulfallate. Atraton 0. Prometon. Atrazine. Propazine. Simazine. Terbuthylazine. Pronamide. Secbumeton. Terbacil. Alachlor. Propanil 0. Ametryn. Prometryn. Simetryn. Metribuzin. Terbutryn. Metolachlor. Bromacil. Dacthal. Diphenamid. Butachlor 0. Napropamide. Carboxin. Tricyclazole. Norflurazon. Hexazinone. Difolatan. Fluridone * Impurity GCEP0 Herbicides II db m x 0. mm, 0. µm Helium at cm/s 0- C at C/min Injection: Split :0, µl Detector: ECD, 00 C Nitrogen makeup gas at 0 ml/min 0. Phorate. Ethoprop. Terbufos. Atrazine. Fonofos. Propachlor. Chlorpyrifos. Alachlor. Metolachlor 0. Cyanazine min GCHERB0

37 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs C and C Halocarbons (Freons) Gs-GasPro - 0 m x 0. mm Helium at cm/s, constant velocity 0 C for min, 0-0 C at 0 C/min 0 C for min 0-00 C at 0 C/min Injection: Splitless, 0 C 0.0 min purge activation time Detector: Sample: MSD, 0 C, Full scan -0 amu.0 µl of 00 ppm mixture of AccuStandard M-REF & M-REF-X in methanol 0 0 suggested supplies septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - seal: Gold plated seal, 0-0 syringe: 0 µl tapered, FN -s//hp, - 0 GCEA00 Freon #. Chlorotrifluoromethane*. Trifluoromethane. Bromotrifluoromethane B. Chloropentafluoroethane. Pentafluoroethane.,,-Trifluoroethane a. Dichlorodifluoromethane. Chlorodifluoromethane.,,,-Tetrafluoroethane a 0. Chloromethane 0.,,,-Tetrafluoroethane. Bromochlorodifluoromethane B.,-Difluoroethane a.,-dichloro-,,,-tetrafluoroethane. -Chloro-,,,-tetrafluoroethane. -Chloro-,-difluoroethane b. Dichlorofluoromethane. Trichlorofluoromethane. Chloroethane 0 0. Dichloromethane 0.,-Dichloro--fluoroethane b.,-dichloro-,,-trifluoroethane.,,-trichloro-,,-trifluoroethane.,-dibromo-,,,-tetrafluoroethane B *Peak not shown nitrogen Containing Herbicides (EPA Method 0) db- - 0 m x 0. mm, 0.0 µm Helium at cm/s ( ml/min), measured at 0 C 0 C for min 0-0 C at C/min 0 C for min Injection: Megabore direct, 0 C, µl of ng/µl standard Detector: NPD, 0 C 0 0 GCNITR0, 0. Eptam. Sutan. Vernam. Tillam. Ordram. Treflan. Balan. Ro-Neet. Propachlor 0. Tolban. Propazine. Atrazine. Simazine. Terbacil. Sencor. Dual. Paarlan. Prowl. Bromacil 0. Oxadiazon. GOAL. Hexazinone

38 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs Free Phenols HP-0+ 0l- 0 m x 0. mm, 0. µm Hydrogen, constant flow cm/s Injection: Split, 00: Detector: FID, 00 C 00 C min 0 C min C/min 0. Phenol. -Chlorophenol.,-Dimethylphenol. -Nitrophenol.,-Dichlorophenol. -Chloro--methylphenol.,,-Trichlorophenol.,-Dinitrophenol. -Nitrophenol 0. -Methyl-,-dinitrophenol. Pentachlorophenol 0 FREEPHEN EPA Halogenated Pesticides on "0" Type Phases VF-0 Pesticides CP00 0 m x 0. mm, 0. µm 0 C, C/min to C Injection: Split: T= C ECD: T= C, pg Highest response for p,p'-ddt Best peak shape for endrin aldehyde FactorFour VF-0ms Loss of p,p'-ddt Tailing on endrin aldehyde Vendor X '0' Tailing on endrin aldehyde Vendor y '0' Degradation of p,p'-ddt VGC000

39 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides to EPA via GC/Ms VF-ms CP 0 m x 0. mm, 0. µm Helium, approx..0 ml/min, 0 kpa C + 0 C/min to C Injection: Split/splitless, in split mode, :00 Detector: Ion Trap MS min VGC000. a-bhc. b-bhc. d-bhc. g-bhc (lindane). Heptachlor. Aldrin. Heptachlor epoxide. Endosulfan I., -DDE 0. Dieldrin. Endrin., -DDD. Endosulfan II. Endrin aldehyde., -DDT. Endosulfan sulfate organochlorine Pesticides I EPA Method 0A db-ms - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-00 C at C/min C at C/min 00 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: Sample: MSD, 00 C transfer line Full scan at m/z 0-00 µl of µg/ml composite 0A standards, AccuStandard Inc., ,.,-Dibromo--chloropropane. -Chloro--nitrobenzotrifluoride (SS). Hexachloropentadiene. -Bromo--nitrobenzene (IS). Terrazole. Chloroneb. Trifluralin. -Bromobiphenyl (SS). Tetrachloro m-xylene (SS) 0. a, a-dibromo-m-xylene. Propachlor. Di-allate A. Di-allate B. Hexachlorobenzene. a-bhc. Pentachloronitrobenzene (IS). g-bhc. b-bhc. Heptachlor 0. Alachlor. d-bhc. Chlorothalonil. Aldrin. Dacthal. Isodrin. Kelthane. Heptachlor epoxide. g-chlordane. trans-nonachlor 0. a-chlordane. Endosulfan I. Captan. p,p'-dde. Dieldrin. Chlorobenzilate. Perthane. Chloropropylate. Endrin. p,p'-ddd 0. Endosulfan II. p,p'-ddt. Endrin aldehyde. Endosulfan sulfate. Dibutyl chlorendate (SS). Captafol. Methoxychlor. Endrin ketone. Mirex. cis-permethrin 0. trans-permethrin * Breakdown Products SS - Surrogate Standard IS - Internal Standard Standards used were a composite of individual solutions supplied courtesy of AccuStandard Inc., Science Park, New Haven, CT 0, GCEP00 suggested supplies septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - syringe: 0 µl tapered, FN -s//hp, -

40 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organochlorine Pesticides II EPA Method 0A db-ms - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-00 C at C/min C at C/min 00 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: Sample: MSD, 00 C transfer line Full scan at m/z 0-00 µl of µg/ml composite 0A standards, AccuStandard Inc. Standards used were a composite of individual solutions supplied courtesy of AccuStandard Inc., Science Park, New Haven, CT 0, ,-Dibromo--chloropropane. -Chloro--nitrobenzotrifluoride (SS). Hexachloropentadiene. -Bromo--nitrobenzene (IS). Terrazole. Chloroneb. Trifluralin. -Bromobiphenyl (SS). Tetrachloro m-xylene (SS) 0. a, a-dibromo-m-xylene. Propachlor. Di-allate A. Di-allate B. Hexachlorobenzene. a-bhc. Pentachloronitrobenzene (IS). g-bhc. b-bhc. Heptachlor 0. Alachlor. d-bhc. Chlorothalonil. Aldrin. Dacthal. Isodrin,. Kelthane. Heptachlor epoxide. g-chlordane. trans-nonachlor 0. a-chlordane. Endosulfan I. Captan. p,p'-dde. Dieldrin. Chlorobenzilate. Perthane. Chloropropylate. Endrin. p,p'-ddd 0. Endosulfan II. p,p'-ddt. Endrin aldehyde. Endosulfan sulfate. Dibutyl chlorendate (SS). Captafol. Methoxychlor. Endrin ketone. Mirex. cis-permethrin 0. trans-permethrin * Breakdown Products SS - Surrogate Standard IS - Internal Standard, 0, GCEP00 0

41 EnVIRonMEnTAl APPlICATIons, PEsTICIdEs And HERBICIdEs organophosphorus Pesticides in Apple Matrix db-ms Ultra Inert -UI 0 m x 0. mm, 0. µm Instrument: Agilent 0 GC/Agilent C Series GC/MSD Sampler: Agilent B automatic liquid sampler,.0 µl syringe (p/n -) CFT Device: Purged -way splitter (p/n G0B) Split Ratio MSD:FPD = : MSD Restrictor:. m x 0. mm id deactivated fused silica tubing FPD Restrictor:. m x 0. mm id deactivated fused silica tubing PCM :. psi constant pressure Inlet: µl splitless; 0 C, purge flow 0 ml/min at 0. min, gas saver on at min 0 ml/min Helium, constant pressure. psi at C C (. min), C/min to C, C/min to C,. C/min to C, 0 C/min to 0 C (. min) Postrun Backflush: Detector: min at 0 C, PCM pressure 0 psi during backflush, psi inlet pressure during backflush 0 C transfer line, 0 C source, 0 C quad Oxydemeton-methyl. Methamidophos. Mevinphos. Acephate. Naled. Diazinon. Dimethoate. Chlorpyrifos. Malathion 0. Methidathion. TPP (surrogate std). Phosmet Msd (sim): 00 ng/ml Time Time FPd (P): 00 ng/ml GC/MS-SIM and FPD chromatograms of a matrix matched organophosphorus pesticides standard analyzed on an Agilent J&W DB-ms UI column. The effluent spilt ratio is MSD:FPD = :.

42 EnVIRonMEnTAl APPlICATIons, semivolatiles Environmental Applications, Semivolatiles Agilent's Ultra Inert Test Probe Mixture db-ms Ultra Inert -UI 0 m x 0. mm, 0. µm Sampler: Injection: Detector: Hydrogen, constant pressure, cm/s C isothermal Agilent B, 0. µl syringe (p/n -), 0.0 µl split injection Split/splitless, 0 C,. ml/min; split column flow 00 ml/min; gas saver flow ml/min at.0 min FID at C; 0 ml/min air, 0 ml/min hydrogen, ml/min nitrogen makeup A properly deactivated DB-ms Ultra Inert column delivers symmetrical peak shapes, along with increased peak heights, which allow for accurate integration and detection of trace analytes. pa Propionic acid. -Octene. n-octane. -Picoline. n-nonane. Trimethyl phosphate.,-pentanediol. n-propylbenzene. -Heptanol 0. -Octanone. n-decane 0 DBmsPeaks Trace level Polycyclic Aromatic Hydrocarbon (PAH) Analyses db-ms Ultra Inert -UI 0 m x 0. mm, 0. µm Injection: Helium constant flow 0 cm/s 0 C ( min) to 00 C ( C/min) 0 C to 0 C ( min) C/min to 0 C ( min) Split/splitless, 0 C,. ml/min total flow, purge flow 0 ml/min on at 0. min, gas saver flow 0 ml/min on at.0 min Detector: MSD source at 00 C Quadrupole at 0 C Transfer line at 0 C Scan range 0-0 amu Abundance Naphthalene. Acenaphthylene. Acenaphthene. Fluorene. Phenanthrene. Anthracene. Fluoranthene. Pyrene 0. Benz[a]anthracene 0. Chrysene. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[a]pyrene. Indeno[,,-cd]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene GCSV_PAH

43 EnVIRonMEnTAl APPlICATIons, semivolatiles Tetrachlorodibenzo-p-furans Column A: Column B: db- - 0 m x 0. mm, 0. µm db-ms - 0 m x 0. mm, 0. µm A :,,, -TCDF :0,,, -TCDF :,,, -TCDF B :,,, -TCDF Helium at ml/min 0-0 C at C/min 0 C until compounds elute Injection: Splitless, 0 C :0 :00 : :00 : 0: GCES00 Note the separation between,,,-tcdf and,,,-tcdf on DB- is also easily achievable (and actually a little better) on Agilent J&W DB-ms. Congeners in din Method PCBs db-xlb - 0 m x 0. mm, 0.0 µm Helium at. cm/s, measured at 0 C 00 C for min 00-0 C at. C/min Injection: Hot on-column, 0 C Split flow 00 ml/min Detector: MSD, 00 C transfer line SIM of.,.,.,.,.,.,.,. Sample: µl dilute Aroclor mixture BZ BZ BZ () BZ 0 suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - BZ 0 (0) BZ,, BZ BZ 0 BZ 0 BZ BZ BZ BZ GCES00

44 EnVIRonMEnTAl APPlICATIons, semivolatiles Extended Temperature Program Resolving Congeners and db-xlb - 0 m x 0. mm, 0.0 µm Helium at. cm/s, measured at 0 C BZ BZ 00 C for min 00- C at. C/min BZ Injection: Hot on-column, 0 C Split flow 00 ml/min Detector: MSD, 00 C transfer line SIM of.,.,.,.,.,.,.,. Sample: µl dilute Aroclor mixture BZ BZ BZ BZ BZ, BZ.0..0 GCES00 PCBs by EPA Method 0 db-ms - 0 m x 0. mm, 0. µm suggested supplies septum: liner: syringe: db-xlb - 0 m x 0. mm, 0.0 µm Helium at cm/s (EPC in constant flow mode) 0 C for 0. min 0-0 C at C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: µecd, 0 C Nitrogen makeup gas (column + makeup flow = 0 ml/min constant flow) Sample: 0 pg per component mm Advanced Green septa, - Splitless, single taper, deactivated, mm id, - 0 µl tapered, FN -s//hp, - DB-ms DB-XLB GCES00. IUPAC. Tetrachloro-m-xylene (IS/SS). IUPAC. IUPAC. IUPAC. IUPAC. IUPAC. IUPAC. IUPAC 0 0. IUPAC. IUPAC 0. IUPAC. IUPAC. IUPAC. IUPAC. IUPAC. IUPAC. IUPAC 0. IUPAC 0 0. IUPAC 0. Decachlorobiphenyl (IS/SS) IS/SS - Internal Standard/ Surrogate Standard

45 EnVIRonMEnTAl APPlICATIons, semivolatiles Automated Cleanup of PCB extracts from waste oil Using A sample Prep workbench db-ms - 0 m x 0. mm, 0. µm Instrument: Injection: Agilent 000 Triple Quadrupole GC/MS system Helium, ml/min constant flow During backflush: ml/min 0 C ( min), 0 C/min to 0 C,. min hold µl, pulsed splitless QuickSwap: kpa constant pressure Backflush: Start at. min Detector: Sample: MRM mode CE V, dwell time 00 ms per transition Trichloro-biphenyls:.0 >.0;.0 >.0 Tetrachloro-biphenyls:. >.0;. >.0 Pentachloro-biphenyls:. >.0;. >.0 Hexachloro-biphenyls:. >.;. >. Heptachloro-biphenyls:. >.;. >. Octachloronapthalene (IS): 0.0 > 0.0 (CE OV) Reference sample BCR-, five aliquots x0 +EI TIC MRM (** -> **) A SAM0.D 0 x0 +EI TIC MRM (** -> **) A SAM0.D 0 x0 +EI TIC MRM (** -> **) A SAM0.D 0 x0 +EI TIC MRM (** -> **) A SAM0.D 0 x0 +EI TIC MRM (** -> **) A SAM0.D Counts vs. Acquisition

46 EnVIRonMEnTAl APPlICATIons, semivolatiles Pyrethrins db m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-00 C at 0 C/min 00 C for min 00-0 C at 0 C/min 0 C for min 0- C at 0 C/min C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Helium makeup gas at 0 ml/min Sample: µl Chromatogram courtesy of Khan Nguyen and Richard Moorman of Sandoz Agro Inc Heptadecane. Octadecane. Endo-MGK. Exo-MGK. Methoprene. Cinerin I. Jasmolin I. Pyrethrin I. BPE (PB) 0. Cinerin II. Jasmolin II. Pyrethrin II MGK = N-Octyl bicycloheptene dicarboximide BPE = Butylcarbityl -propylpiperonyl ether 0 GCES00

47 EnVIRonMEnTAl APPlICATIons, semivolatiles organotin Compounds I Injection: HP- 0Z-0 m x 0. mm, 0. µm Helium, 00 kpa 0 C for min 0-0 C at C/min Splitless Sn (0 nm). Dimethylpentyltin. Tetrabutyltin. Methyltripentyltin. Tributylpentyltin. Dibutylpentyltin. Butlypentyltin. Tetrapentyltin Detector: AED, 0 C Sample: µl 0 GCES0 suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - organotin Compounds II HP- 0J-00 m x 0.0 mm, 0. µm Helium, 0. ml/min constant flow 0-0 C at C/min Injection: Splitless, 00 C Detector: AED, 00 C Hg selective at mm Sample: µl suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - Solvent Vent standard solution Bu SnPh Bu SnPh BuSnPh Harbor sediment BuSnPh pg Bu Sn Bu SnPh Me SnPh pg Bu SnPh pg Ph Sn Solvent Vent pg pg Oct SnPh Oct SnPh GCES0

48 EnVIRonMEnTAl APPlICATIons, semivolatiles semivolatile Compounds, Us EPA Method 0 HP-ms 0s- 0 m x 0. mm, 0.0 µm Ramped flow. ml/min for 0.0 min Ramp at ml/min to.0 ml/min.0 ml/min for 0. min Ramp at 0 ml/min to. ml/min 0 C for.0 min 0-00 C at C/min 00-0 C at 0 C/min 0-0 C at 0 C/min Injection: Splitless, 0 C 0 ml/min purge flow at 0. min Detector: Sample: MSD, 0 C transfer line Scan range -00 amu,. scans/s µl of 0 ng standard suggested supplies septum: liner: syringe: mm Advanced Green septa, - Splitless, single taper, deactivated, mm id, - 0 µl tapered, FN -s//hp, -. n-nitrosodimethylamine. Pyridine. -Fluorophenol. Phenol-d. Phenol. Aniline. Bis(-chloroethyl) ether. -Chlorophenol.,-Dichlorobenzene 0.,-Dichlorobenzene-d.,-Dichlorobenzene. Benzyl alcohol.,-dichlorobenzene. -Methylphenol. Bis(-chloroisopropyl) ether. -Methylphenol. n-nitroso-di-n-propylamine. Hexachloroethane. Nitrobenzene-d 0. Nitrobenzene. Isophorone. -Nitrophenol.,-Dimethylphenol. Benzoic acid. Bis(-chloroethoxy) methane.,-dichlorophenol.,,-trichlorobenzene. Naphthalene-d. Naphthalene 0. -Chloroaniline. Hexachlorobutadiene. -Chloro--methylphenol. -Methylnaphthalene. Hexachlorocyclopentadiene.,,-Trichlorophenol,.,,-Trichlorophenol. -Fluorobiphenyl. -Chloronaphthalene. -Nitroaniline 0. Dimethyl phthalate.,-dinitrotoluene. Acenaphthylene. -Nitroaniline. Acenaphthene-d0. Acenaphthene.,-Dinitrophenol. -Nitrophenol. Dibenzofuran.,-Dinitrotoluene 0. Diethyl phthalate. -Chlorophenyl-phenyl ether, 0 0, Fluorene. -Nitroaniline.,-Dinitro--methylphenol. n-nitrosodiphenylamine. Azobenzene.,,-Tribromophenol. -Bromophenyl-phenylether. Hexachlorobenzene 0. Pentachlorophenol. Phenanthrene-d0. Phenanthrene. Anthracene. Carbazole. Di-n-butyl phthalate. Fluoranthene. Pyrene 0,. Terphenyl-d. Benzidine 0. Butylbenzylphthalate.,'-Dichlorobenzidine. Benzo[a]anthracene. Chrysene-d. Chrysene. Bis(-ethylhexyl) phthalate. Di-n-octylphthalate. Benzo[b]fluoranthene. Benzo[k]fluoranthene. Benzo[a]pyrene 0. Perylene-d. Indeno[,,-cd]pyrene. Dibenz[a,h]anthracene. Benzo[g,h,i]perylene GCES0 A variety of HP-ms and DB-ms columns can be used for 0 and similar semivolatiles applications. The column shown above was chosen to maximize inertness and robustness to residues with a thicker 0. µm film, but the price paid is a slightly longer run time. An HP-ms, 0 m x 0. mm id, 0. µm, p/n 0S- would give shorter run times, with slightly less inertness and robustness. A DB-ms, 0 m x 0. mm id, 0. µm, p/n -, would give slightly less inertness, but offer better resolution of PAHs such as benzo[b]fluoranthene and benzo[k]fluoranthene. A DB-ms, 0 m x 0. mm x 0. µm, p/n -, can offer significantly reduced run times with a modest loss of inertness.

49 EnVIRonMEnTAl APPlICATIons, semivolatiles Us EPA Method 0 (Phthalate Esters) db-ms - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C constant flow program 0 C for 0. min 0-0 C at 0 C/min 0-0 C at C/min Injection: Splitless, 00 C 0 s purge activation time Detector: Sample: MSD, C transfer line Full scan m/z 0-00 µl of 0 ng/µl Method 0 mixture (AccuStandard) in hexane * 0 suggested supplies septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - syringe: 0 µl tapered, FN -s//hp, - 0. Dimethyl phthalate. Diethyl phthalate. Benzyl benzoate (IS). Diisobutyl phthalate. Di-n-butyl phthalate. Bis(-methoxyethyl) phthalate. Bis(-methyl--pentyl) phthalate *. Bis(-ethoxyethyl) phthalate. Diamyl phthalate 0. Dihexyl phthalate. Butyl benzyl phthalate. Hexyl -ethylhexyl phthalate. Bis(-n-butoxyethyl) phthalate. Dicyclohexyl phthalate. Bis(-ethylhexyl) phthalate. Diphenyl phthalate (SS). Diphenyl isophthalate (SS). Di-n-octyl phthalate. Dibenzyl phthalate (SS) 0. Dinonyl phthalate * Two isomers IS - Internal Standard SS - Surrogate Standard 0 GCES0

50 EnVIRonMEnTAl APPlICATIons, semivolatiles PAHs db-ms - 0 m x 0. mm, 0. µm Helium at:. cm/s, measured at 0 C C for 0. min -0 C at C/min 0 C for min Injection: Split, 00 C Split ratio :0 Detector: Sample: MSD, 0 C transfer line Scan 0-0 amu µl, PAH standard Ions. Naphthalene. -Methylnaphthalene,. -Methylnaphthalene,. Azulene. Acenaphthene. Biphenyl.,-Dimethylnaphthalene,. Acenaphthalene. Dibenzofuran, 0. Dibenzo-p-dioxin. Fluorene,. -Nitronaphthalene,.,0-Dihydroanthracene, 0. -Nitronaphthalene,. -Nitrobiphenyl,. Dibenzothiophene. Phenanthrene. Anthracene. -Nitrobiphenyl, 0. -Nitrobiphenyl,.,-Benzoquinoline. Carbazole. -Methylanthracene,.,,,-Tetrahydrofluoranthene, 0. -Phenylnaphthalene 0. -Methylanthracene, suggested supplies septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - Ions.,-Dimethylphenanthrene 0,.,-Dinitronaphthalene,.,-Dinitronaphthalene, 0. Fluoranthene 0.,'-Dinitrobiphenyl,. Pyrene 0. -Methylfluoranthene,.,-Benzofluorene,. Dodecahydrotriphenylene 0,. -Amino--nitronaphthalene,. -Phenylanthracene,.,-Benzanthracene. Chrysene 0 0. Benz[a]anthracene-,-dione, 0.,-Dinitrofluorene,. Benzo[b]fluoroanthene. Benzo[k]fluoranthene.,-Dimethylbenz[a]anthracene,. Benzo[e]pyrene. Benzo[a]pyrene. Perylene. -Methylcholanthrene.,0-Diphenylanthracene 0 0.,,,-Dibenzanthracene.,,,-Dibenzanthracene. Benzo[g,h,i]perylene The db-ms is also an excellent column for PAH analysis. 0, 0 0, 0 0, GCES0 0

51 EnVIRonMEnTAl APPlICATIons, semivolatiles Phenols db-ms - 0 m x 0. mm, 0. µm db-xlb - 0 m x 0. mm, 0. µm He at. ml/min constant flow 0 C for min 0-00 C at 0 C/ min 00 C for 0.0 min 00-0 C at C/min 0-0 C at 0 C/min Injection: Pulsed splitless, 00 C Pulse pressure & time: psi for min Purge flow & time: 0 ml/min for 0. min Gas saver flow & time: 0 ml/min for min Detector: MSD, 0 C transfer line Quadrupole at 0 C Source at 0 C DB-ms, suggested supplies,,,, 0 0, DB-XLB,, 0 0, septum: mm Advanced Green septa, - liner: Direct connect, single taper, deactivated, mm id, G-00 syringe: 0 µl tapered, FN -s//hp, - 0, 0 GCES0. Phenol. -Chlorophenol. -Methylphenol. -Methylphenol. -Methylphenol. -Chloro--methylphenol.,-Dimethylphenol. -Nitrophenol.,-Dimethylphenol 0.,-Dimethylphenol.,-Dichlorophenol.,-Dimethylphenol.,-Dichlorophenol.,-Dichlorophenol. -Chlorophenol. -Chlorophenol.,-Dimethylphenol.,-Dichlorophenol. -Chloro--methylphenol 0. -Chloro--methylphenol.,,-Trichlorophenol.,-Dibromophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,-Dichlorophenol.,,-Trichlorophenol.,,-Dichlorophenol. -Nitrophenol 0.,-Dinitrophenol.,-Dinitrophenol. -Nitrophenol.,,,-Tetrachlorophenol.,,,-Tetrachlorophenol.,,,-Tetrachlorophenol.,,-Trichlorophenol. -Methyl-,-dinitrophenol. Pentachlorophenol. Dinoseb 0. -Cyclohexyl-,-dinitrophenol

52 EnVIRonMEnTAl APPlICATIons, semivolatiles 0 ng/µl semivolatile Checkout standard on a 0 m x 0. mm, 0. µm Agilent J&w db-ui 0d Capillary GC Column using an Ultra Inert liner with wool db-ui 0d - 0 m x 0. mm, 0. µm Inlet: S/SL µl pulsed splitless, 00 ºC psi pulse to. min, purge flow 0 ml/min at. min, gas saver off Inlet liner: Agilent Ultra Inert single taper with wool (p/n 0-) 0 ºC (. min), ºC/min to 0 ºC (. min) Helium, constant flow. ml/min set at 0 ºC MSD: ºC transfer line, 00 ºC source, 0 ºC quad, 0-0 amu range GC/MSD: Agilent 0 Series GC/C Series GC/MSD Aux EPC: psi with ml/min bleed during run Sampler: Agilent B,.0 µl syringe (p/n G-00) Backflush: Post run. min at psi Aux EPC, psi inlet pressure. N-Nitrosodimethylamine. Aniline.,-Dichlorobenzene-d. Isophorone.,-Dimethyl--nitrobenzene. Naphthalene. Hexachlorocyclopentadiene. Mevinphos. Acenaphthene-d0 0.,-Dinitrophenol. -Nitrophenol.,-Dinitrotoluene. Fluorene.,,-Dinitro--methyl phenol. Trifluralin. Simazine. Atrazine. Pentachlorophenol. Terbufos 0. Chlorothalonil. Phenanthrene-d0. Aldrin. Heptachlor epoxide. Endrin.,'-DDT.,'-Dichlorobenzidine. Chrysene d-. Benzo[b]fluoranthene. Perylene-d Excellent peak shape and response for,-dinitrophenol Peak no. Compound. Acenaphthene-d0 0.,-Dinitrophenol. -Nitrophenol.,-Dinitrotoluene Time ,-Dinitrophenol expanded view High Resolution Phenol Analysis by GC/Ms VF-ms CP 0 m x 0. mm, 0. µm Sample Conc: Approx. -0 ng per component on-column Helium, 0 kpa Injection: Split, :00, T= C Detector: Agilent Ion Trap MS Phenol. -Chlorophenol. o-cresol. m-cresol. p-cresol. -Nitrophenol.,-Dimethylphenol.,-Dichlorophenol.,-Dichlorophenol 0. -Chloro--methylphenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol. -Nitrophenol.,-Dinitrophenol.,,, Tetrachlorophenol. -Methyl-,-dinitrophenol 0. Pentachlorophenol. -sec-butyl-,-dinitrophenol (dionseb) 0 0 min VGC00

53 EnVIRonMEnTAl APPlICATIons, semivolatiles Phenols According to EPA Method 00 Sample Conc: Injection: Detector: CP-sil CB CP 0 m x 0. mm, 0. µm ppm 0 C to 00 C, C/min H, 0 kpa (. bar, psi) Split, 00 ml/min FID + 0. Phenol. -Chlorophenol. o-cresol. m-cresol. p-cresol. -Nitrophenol.,-Dimethylphenol.,-Dichlorophenol.,-Dichlorophenol 0. -Chloro--methylphenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol.,,-Trichlorophenol. -Nitrophenol.,-Dinitrophenol.,,,-Tetrachlorophenol. -Methyl-,-dinitrophenol 0. Pentachlorophenol. -sec-butyl-,-dinitrophenol (dionseb) 0 0 min VGC00 EPA Method. db-ms - 0 m x 0. mm, 0. µm db-xlb - 0 m x 0. mm, 0.0 µm DB-ms Helium at cm/s (EPC in constant flow mode) suggested supplies septum: liner: 0 C for 0. min 0-00 C at C/min 00 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: µecd, 0 C Nitrogen makeup gas (column + makeup flow = 0 ml/min constant flow) Sample: 0 pg per component mm Advanced Green septa, - Direct connect, dual taper, deactivated, mm id, G-000 DB-XLB,, 0. Chloroacetic acid. Bromoacetic acid. Dichloroacetic acid. Dalapon. Trichloroacetic acid.,,-trichloropropane (IS). Bromochloroacetic acid. Bromodichloroacetic acid. Dibromoacetic acid 0.,-Dibromopropionic acid (SS). Chlorodibromoacetic acid. Tribromoacetic acid IS - Internal Standard SS - Surrogate Standard syringe: 0 µl tapered, FN -s//hp, - GCES00

54 EnVIRonMEnTAl APPlICATIons, VolATIlEs Environmental Applications, Volatiles Extended Analyte list for EPA Method 0 (ElCd) DB- suggested supplies liner: Direct,. mm id, seal: Gold plated seal, DB-VRX 0 db- - m x 0. mm,. µm db-vrx - m x 0. mm,. µm Helium at ml/min, measured at C C for min -0 C at C/min 0 C for min 0-00 C at C/min 00 C for min Sampler: Purge and Trap (O.I.A. 0) Trap: VoCarb 000 Preheat: C Desorb: 0 C for min Injection: J&W LVI (Low Volume Injector), 0 C Detector: A: PID (O.I.A. 0), 00 C Helium makeup gas at 0 ml/min B: ELCD (O.I.A. 0), with NiCat reaction tube in the halogen mode, 0 C reactor temperature Sample: 0 ppb per component in ml water, 0, 0, 0 0 0, septum: mm Advanced Green septa, - 0 0, ,,. Dichlorodifluoromethane. Chloromethane. Vinyl chloride. Bromomethane. Chloroethane. Trichlorofluoromethane. -Chloropropane (IS).,-Dichloroethene. Iodomethane 0. Allyl chloride. Methylene chloride. trans-,-dichloroethene.,-dichloroethane. Chloroprene. cis-,-dichloroethene.,-dichloropropane. Bromochloromethane. Chloroform.,,-Trichloroethane 0. Carbon tetrachloride.,-dichloropropene. Benzene.,-Dichloroethane. Fluorobenzene (IS). Trichloroethene.,-Dichloropropane. Dibromomethane. Trifluorotoluene (IS). Bromodichloromethane 0. -Chloroethyl vinyl ether. cis-,-dichloropropene. Toluene. trans-,-dichloropropene.,,-trichloroethane. Tetrachloroethene.,-Dichloropropane. Dibromochloromethane.,-Dibromoethane. -Chloro--fluorobenzene (IS) 0. Chlorobenzene.,,,-Tetrachloroethane. Ethylbenzene. m-xlyene. p-xylene. Styrene. o-xylene. Bromoform. Isopropylbenzene. cis-,-dichlorobutene 0.,,,-Tetrachloroethane. Bromobenzene.,,-Trichloropropane. n-propylbenzene. -Chlorotoluene.,,-Trimethylbenzene. -Chlorotoluene. tert-butylbenzene.,,-trimethylbenzene. sec-butylbenzene 0.,-Dichlorobenzene. p-isopropyltoluene.,-dichlorobenzene. Benzyl chloride. n-butylbenzene.,-dichlorobenzene. Bis(-chloroisopropyl) ether.,-dibromo--chloropropane.,,-trichlorobenzene. Hexachlorobutadiene 0. Naphthalene.,,-Trichlorobenzene GCEV00

55 EnVIRonMEnTAl APPlICATIons, VolATIlEs Fast VoC Analysis db- - 0 m x 0. mm,.00 µm Helium at cm/s, (constant flow mode) C for min -00 C at C/min 00 C for 0. min 0-00 C at C/min Sampler: Purge and trap (Tekmar LSC 000) Purge: Helium for min at 0 ml/min Preheat: 0 C Desorb: 0 C for min Line & valve:00 C Detector: Sample: MSD, 0 C transfer line Full scan -0 amu. scans per s 0 ppb per component in ml water Ideal for Msd 0 0 0, 0 suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal, Dichlorofluoromethane. Chloromethane. Vinyl chloride. Bromomethane. Chloroethane. Trichlorofluoromethane.,-Dichloroethene. Methylene chloride. trans-,-dichloroethene 0.,-Dichloroethane.,-Dichloropropane. Bromochloromethane. Chloroform.,,-Trichloroethane. Carbon tetrachloride. Benzene. Fluorobenzene. Trichloroethene.,-Dichloropropane 0. Dibromomethane. Bromodichloromethane. cis-,-dichloropropene. Toluene. trans-,-dichloropropene.,,-trichloroethane. Tetrachloroethene. Dibromochloromethane.,-Dibromomethane. Chlorobenzene 0.,,,-Tetrachloroethane. Ethylbenzene. m-xylene. p-xylene. o-xylene. Bromoform. Isopropylbenzene. Bromofluorobenzene. Bromobenzene. n-propylbenzene 0. -Chlorotoluene.,,-Trimethylbenzene. tert-butylbenzene.,,-trimethylbenzene. sec-butylbenzene.,-dichlorobenzene. -Isopropyltoluene.,-Dichlorobenzene.,-Dichlorobenzene.,-Dibromo--chloropropane 0.,,-Trichlorobenzene. Hexachlorobutadiene. Naphthalene.,,-Trichlorobenzene 0 GCEV00

56 EnVIRonMEnTAl APPlICATIons, VolATIlEs Analysis of Volatile organic Compounds in Environmental waters Using the Agilent A Headspace and 0B/A GC/Ms VF-ms CP0 0 m x 0. mm,.0 µm Instrument: Agilent A Headspace and 0B/A GC/MS Helium, ml/min, 0 C C for min, then 0 C/min to 0 C for min Injection: Detector: Sample: Sample Conc: Split, :, 0 C for min, purge 00 ml/min for min A MSD, simultaneous Scan/SIM mode Standard VOC mix 0 µg/l RT, min CAs number. Dichlorodifluoromethane. --. Chloromethane. --. Vinyl chloride Bromomethane Chloroethane Trichlorofluoromethane.0 --.,-Dichloroethene. --. Carbon disulfide Dichloromethane Methyl tert-butyl ether.0-0- Counts vs. Acquisition 0 µg/l VoC standard scan and sim Traces RT, min CAs number. trans-,-dichloroethene.0-0-.,-dichloroethane. --. Ethyl tert-butyl ether cis-,-dichloroethene. --.,-Dichloropropane Bromochloromethane. --. Chloroform. --.,,-Trichloroethane. --.,-Dichloro--propene Carbon tetrachloride. -- RT, min CAs number. Benzene.0 --.,-Dichloroethane tert-amyl methyl ether Trichloroethene ,-Dichloropropane Dibromomethane Bromodichloromethane cis-,-dichloropropene Toluene trans-,-dichloropropene ,,-Trichloroethane Tetrachloroethene.0 --.,-Dichloropropane. --. Dibromochloromethane. --.,-Dibromoethane Chlorobenzene ,,,-Tetrachloroethane Ethylbenzene m and p-xylene. 0-- & o-xylene. --. Styrene Bromoform. --. Isopropylbenzene. --.,,,-Tetrachloroethane. --. Bromobenzene. 0--.,,-Trichloropropane. --. n-propylbenzene Chlorotoluene Chlorotoluene ,,-Trimethylbenzene Chlorotoluene tert-butylbenzene. -0-.,,-Trimethylbenzene sec-butylbenzene. --.,-Dichlorobenzene Isopropyltoluene.0 --.,-Dichlorobenzene ,,-Trimethylbenzene. --. n-butylbenzene ,-Dichlorobenzene. -0-.,-Dibromo--chloropropane. --.,,-Trichlorobenzene ,,-Trichlorobenzene Hexachlorobutadiene Naphthalene ,,-Trichlorobenzene µg/l VoC standard scan and sim Traces Counts vs. Acquisition

57 EnVIRonMEnTAl APPlICATIons, VolATIlEs EPA Method db m x 0. mm,.00 µm Helium at. cm/s, measured at 0 C C for min -0 C at 0 C/min 0 C for min 0-0 C at C/min 0 C for min Injection: Splitless, 00 C s purge activation time Detector: ECD, 00 C Sample: µl of 0 pg/µl, AccuStandard. Chloroform.,,-Trichloroethane. Carbon tetrachloride. Trichloroacetonitrile. Dichloroacetonitrile. Bromodichloromethane. Trichloroethene. Chloral hydrate.,-dichloro--propanone 0. Chloropicrin. Dibromochloromethane. Bromochloroacetonitrile.,-Dibromoethane. Tetrachloroethene.,,-Trichloropropanone.,-Dibromopropane (IS). Bromoform. Dibromoacetonitrile.,-Dibromo--chloropropane suggested supplies septum: mm Advanced Green septa, - liner: Splitless, single taper, deactivated, mm id, - seal: Gold plated seal, 0-0 syringe: 0 µl tapered, FN -s//hp, GCEV00 European Red list Volatiles db m x 0. mm, 0.0 µm db- - 0 m x 0. mm,.0 µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at C/min suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal, 0-0 Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of headspace of neat mixture DB-. DB-.,-Dichloroethylene.,-Dichloroethane. Chloroform.,,-Trichloroethane.,-Dichloroethane. Carbon tetrachloride. Trichloroethylene. Tetrachloroethylene GCEV00

58 EnVIRonMEnTAl APPlICATIons, VolATIlEs EPA Volatiles by GC/Ms (split Injector) db-vrx - 0 m x 0. mm,.0 µm Helium at 0 cm/s, measured at C C for 0 min -0 C at C/min 0 C for min 0- C at C/min C for min Sampler: Purge and trap (O.I.A. 0) Purge: Helium for min at 0 ml/min Trap: Tenax/Silica Gel/Carbosieve Preheat: C Desorb: 0 C for 0. min Injection: Split, 0 C Split flow 0 ml/min Detector: db- - 0 m x 0. mm,.0 µm Helium at cm/s, measured at 0 C C for min -0 C at C/min 0 C for min 0-00 C at C/min 00 C for min Sampler: Purge and trap (O.I.A. 0) Purge: Helium for min at 0 ml/min Trap: Tenax/Silica Gel/Carbosieve Preheat: C Desorb: 0 C for 0. min Injection: Split, 0 C Split flow 0 ml/min Detector:. Dichlorodifluoromethane. Chloromethane. Vinyl chloride. Bromomethane. Chloroethane. Trichlorofluoromethane. Diethyl ether.,-dichloroethene. Acetone 0. Iodomethane. Carbon disulfide. Allyl chloride. Methylene chloride. Acrylonitrile. Methyl-tert-butyl ether. trans-,-dichloroethene. Hexane.,-Dichloroethane. -Butanone MSD, C transfer line Full scan -0 amu (m/z subtracted) MSD, C transfer line Full scan -0 amu (m/z subtracted) 0. cis-,-dichloroethene.,-dichloropropane. Propionitrile. Methyl acrylate. Methacrylonitrile. Bromochloromethane. Tetrahydrofuran. Chloroform. Pentafluorobenzene (IS).,,-Trichloroethane 0. -Chlorobutane.,-Dichloropropene. Carbon tetrachloride. Benzene.,-Dichloroethane.,-Dimethylhexane. Fluorobenzene (IS).,-Difluorobenzene (IS). Trichloroethene suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal kit, ,,,0 0 0, 0, GCEV00 suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal kit, -,,, 0,,,, ,,,,,. Chlorobenzene.,,,-Tetrachloroethane 0. Ethylbenzene. m-xylene. p-xylene. o-xylene. Styrene. Bromoform. Isopropylbenzene. -Bromofluorobenzene (SS).,,,-Tetrachloroethane. Bromobenzene 0.,,-Trichloropropane. trans-,-dichloro--butene. n-propylbenzene. -Chlorotoluene.,,-Trimethylbenzene. -Chlorotoluene. tert-butylbenzene 0,, 0, 0 0 GCEV00. Pentachloroethane.,,-Trimethylbenzene. sec-butylbenzene 0.,-Dichlorobenzene. p-isopropyltoluene.,-dichlorobenzene. n-butylbenzene.,-dichlorobenzene. Hexachloroethane.,-Dibromo--chloropropane. Nitrobenzene.,,-Trichlorobenzene. Hexachlorobutadiene 0. Naphthalene.,,-Trichlorobenzene IS - Internal Standard SS - Surrogate Standard note: Some compounds not present in both chromatograms ,-Dichloropropane 0. Methyl methacrylate. Dibromomethane. Bromodichloromethane. -Nitropropane. Chloroacetonitrile. cis-,-dichloropropene. -Methyl--pentanone.,-Dichloro--propanone. Toluene. trans-,-dichloropropene 0. Ethyl methacrylate.,,-trichloroethane. Tetrachloroethene.,-Dichloropropane. -Hexanone. Dibromochloromethane.,-Dibromoethane. -Chloro--fluorobenzene (IS)

59 EnVIRonMEnTAl APPlICATIons, AIR AnAlysIs Environmental Applications, Air Analysis EPA Air Analysis Compendium Method To- standard db m x 0. mm,.00 µm Helium at cm/s measured off of CO at C constant flow mode Injection: Detector: Sample: C for min -0 C at C/min 0-0 C at 0 C/min 0 C for min Entech 00 cryogenic sample preconcentrator MSD Full scan of m/z ml of a 0 ppbv TO- standard and 00 ml of a 0 ppbv IS/SS standard suggested supplies Peak m/z Peak m/z. 0 septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal, 0-0. CO. Freon (dichlorodifluoromethane). Chloromethane. Freon (,-dichloro-,,,-tetrafluoroethane). Vinyl chloride. Bromomethane. Chloroethane. Freon (trichlorofluoromethane).,-dichloroethene 0. Methylene chloride. Freon (,,-trichloro-,,-trifluoroethane).,-dichloroethane. cis-,-dichloroethene 0. Bromochloromethane (IS). Chloroform.,-Dichloroethane.,,-Trichloroethane. Benzene. Carbon tetrachloride 0.,-Difluorobenzene (IS).,-Dichloropropane. Trichloroethene. cis-,-dichloropropene. trans-,-dichloropropene.,,-trichloroethane. Toluene-d (SS). Toluene.,-Dibromoethane. Tetrachloroethene 0. Chlorobenzene-d (SS). Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. Styrene.,,,-Tetrachloroethane. o-xylene. -Bromofluorobenzene (SS).,,-Trimethylbenzene 0.,,-Trimethylbenzene.,-Dichlorobenzene.,-Dichlorobenzene.,-Dichlorobenzene.,,-Trichlorobenzene.,-Dibromobenzene (IS). Hexachloro-,-butadiene 0 GCEA00 Agilent wishes to thank Entech Instruments for providing this chromatogram.

60 EnVIRonMEnTAl APPlICATIons, AIR AnAlysIs Formaldehyde, 0 ppb Sampler: db-ms - 0 m x 0. mm,.00 µm Helium,. ml/min C for min - C at 0 C/min Entech 00 cryogenic sample preconcentrator Detector: GC/MS 0/N Scan -0 amu 0- min -0 amu -0 min Electron impact 0 ev Sample: 00 cc 0 ppb Formaldehyde/0 ppb others suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal, 0-0. Formaldehyde. Acetaldehyde. Acetone-d. Acetone. Propanol. -Butanone Agilent wishes to thank Entech Instruments for providing this chromatogram GCEA00 sulfur in Air Sampler: db-ms - 0 m x 0. mm,.00 µm Helium,. ml/min C for min -0 C at C/min 0-0 C at C/min 0 C for min Entech 00 cryogenic sample preconcentrator Detector: GC/MS 0/N Scan -0 amu 0- min -0 amu -0 min Electron impact 0 ev. Hydrogen sulfide. Carbonyl sulfide. Methyl mercaptan. Dimethyl sulfide. Carbon disulfide. Bromochloromethane.,-Difluorobenzene. Chlorobenzene-d. -Bromofluorobenzene Sample: 00 cc 0 ppb sulfurs Agilent wishes to thank Entech Instruments for providing this chromatogram. 0 0 GCEA00 0

61 EnVIRonMEnTAl APPlICATIons, AIR AnAlysIs n o I HP-PloT Q 0P-Qo 0 m x 0. mm, 0.00 µm Helium, psi (approximately ml/min) C isothermal Injection: 0 µl, injected Split ratio : Detector: TCD, 00 C Sample: Approximately 00 ppmv methane 00 ppmv CO 0 ppmv N O (nitrogen balance gas) N CO N O CH GCEA00 n o II HP-PloT Molesieve 0P-Ms 0 m x 0. mm,.00 µm O N Helium, psi (approximately 0 ml/min) 0 C ( min), C/min to 00 C and hold N O Injection: 0 µl injected Split ratio : CH CO Detector: TCD, 0 C Column compensation on Sample: Approximately 00 ppmv methane 00 ppmv CO 0 ppmv N O (nitrogen balance gas) 0 GCEA00 n o III Gs-CarbonPloT - 0 m x 0. mm,.00 µm Helium, psi (approximately ml/min) C isothermal Injection: 0 µl injected Split ratio : Detector: TCD, 00 C Sample: Approximately 00 ppmv methane 00 ppmv CO 0 ppmv N O (nitrogen balance gas) N H O CH CO N O.... GCEA00

62 EnVIRonMEnTAl APPlICATIons, AIR AnAlysIs Permanent Gases on a Thick Film Molsieve Column Sample: 0 µl Sample Conc: % range H 0 C CP-Molsieve Å CP m x 0. mm, 0.00 µm. Helium. Neon. Argon. Oxygen. Nitrogen Injection: Detector: Split, 00 ml/min TCD 0 min VGC000 Fast Analysis of Permanent Gases and Co using Tandem PloT Columns select for Permanent Gases/Co CP Sample: 0 µl Sample Conc: % level H, 0 kpa C Injection: Split, 0 ml/min. He (from ms-å). O (from ms-å). N (from ms-å). Methane (from ms-å). CO (from ms-å). He (from PBQ). N + O + CO (from PBQ). Methane (from PBQ). CO (from PBQ) Detector: µ-tcd. min 0 min VGC000 Elutes from Molsieve Å Elutes from PoraBOND Q

63 EnVIRonMEnTAl APPlICATIons, AIR AnAlysIs EPA Air Analysis Method To- ( ppbv standard) db-ms - 0 m x 0. mm,.00 µm Sampler: Helium,. ml/min C for min -0 C at C/min 0-0 C at C/min 0 C for min Entech 00 cryogenic sample preconcentrator suggested supplies septum: mm Advanced Green septa, - liner: Direct,. mm id, seal: Gold plated seal, 0-0 Detector: GC/MS 0/N Scan -0 amu 0- min -0 amu -0 min Electron impact 0 ev Sample: 00 ml sample load All compounds at 0 ppbv except formaldehyde (0 ppbv), acetaldehyde (0 ppbv), propanol (0 ppbv), acetone (0 ppbv), -butanone (0 ppbv) Quantitation Ion. Formaldehyde 0. Propene. Dichlorodifluoromethane. Chloromethane 0. Dichlorotetrafluoroethane. Acetaldehyde. Vinyl chloride.,-butadiene. Bromomethane 0. Chloroethane. Bromoethene 0. Trichlorofluoromethane 0. Acetone. Propanal. Isopropyl alcohol.,-dichloroethene.,,-trichloro-,--trifluoroethane 0. Methylene chloride. -Chloro--propene (allyl chloride) 0. Carbon disulfide. trans-,-dichloroethene. tert-butyl methyl ether (MTBE).,-Dichloroethane. Vinyl acetate. -Butanone (MEK) Quantitation Ion. n-hexane. cis-,-dichloroethene. Ethyl acetate. Bromochloromethane (IS) 0. Chloroform. Tetrahydrofuran.,,-Trichloroethane.,-Dichloroethane. Benzene. Carbon tetrachloride. Cyclohexane.,-Difluorobenzene (IS).,,-Trimethylpentane (isooctane). n-heptane 0. Trichloroethene 0.,-Dichloropropane.,-Dioxane. Bromodichloromethane. -Methyl--pentanone (MIBK). cis-,-dichloropropene. trans-,-dichloropropene. Toluene.,,-Trichloroethane. -Hexanone 0. Dibromochloromethane Quantitation Ion. Tetrachloroethene.,-Dibromoethane 0. Chlorobenzene-d (IS). Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. Styrene 0. o-xylene 0. Bromoform.,,,-Tetrachloroethane. -Bromofluorobenzene. -Ethyltoluene 0.,,-Trimethylbenzene 0.,,-Trimethylbenzene 0.,-Dichlorobenzene. Benzyl chloride.,-dichlorobenzene.,-dichlorobenzene 0.,,-Trichlorobenzene 0. Hexachlorobutadiene,,, 0, 0, 0, 0, GCEA00 Agilent wishes to thank Entech Instruments for providing this chromatogram.

64 FooD, FLavor, and FragranCe applications Food, Flavor, and Fragrance Applications DB-UI µl/l Fermented Beverage Standard Mix DB- Ultra Inert -UI 0 m x 0. mm,.0 µm Helium,. ml/min, constant flow set at C C for min 0 C/min to 00 C for. min C/min to 0 C for.0 min C/min to 0 C for. min Inlet: Split/splitless, 0 C, µl, split 0: MSD Restrictor: Scan mode 0-00 amu, source temp 0 C, quad temp 0 C, transfer line temp 0 C Instrument: Agilent 0/C equipped with MMI and FID Sampler: Agilent A headspace with position tray, ml sample loop. Acetyl aldehyde. Methanol. Ethanol. Acetone. Isopropanol. Isobutyl aldehyde. -Propanol. Butyl aldehyde., Butanedione (VDK) 0. Ethyl acetate. -Butanol. Isobutyl alcohol. -Butanol., Pentanedione (VDK). Ethyl propanoate. Propyl acetate. -Pentanol. Isoamyl alcohol. Active amyl alcohol 0. Isobutyl acetate. -Pentanol. Ethyl butanoate. Hexanal. Isoamyl acetate. Active amyl acetate. -Hexanol. Heptanal. Octanal.,,-Trioxane impurity 0.,,-Trioxane impurity. Ethyl caprylate. -Phenyl ethyl acetate. Benzaldehyde, methoxy. Ethyl caprate

65 FooD, FLavor, and FragranCe applications Spearmint oil Column a: Column B: DB m x 0. mm, 0. µm DB m x 0. mm, 0. µm A: Helium cm/s measured at 0 C B: Hydrogen cm/s measured at 0 C A: 0 C hold min, C/min to 0 C B: 0 C hold 0. min, C/min to 0 C hold.0 min Injection: 0 C, Split 0:, µl injection Using hydrogen as a carrier gas in conjunction with the high efficiency column resulted in an overall speed gain of % compared to the original method. In addition, the resolution was well maintained throughout the method translation process. original method with a DB-, 0 m x 0. mm, 0. µm column and helium carrier A Faster method with a high efficiency DB-, 0 m x 0. mm, 0. µm column and hydrogen carrier B SPEARMINT. a-pinene. Sabinene. b-pinene. -Octanol. Myrcene. a-terpinene. r-cymene.,-cineol. Limonene 0. cis-ocimene. trans-ocimene. g-terpinene. trans-sabinene hydrate. Terpinolene. Linalool. -Octyl acetate. Isomenthone. Terpinen--ol. Dihydro carvone 0. trans-carveol. l-carvone. trans-dihydro carveol acetate. cis-carvyl acetate. cis-jasmone. b-bourbonene. a-bourbonene. b-caryophyllene. a-copaene. trans-b-farnesene 0. Germacrene-d. Viridiflorol

66 FooD, FLavor, and FragranCe applications Lavender oil Characterization Instrument: DB-ms Ultra Inert -0UI 0 m x 0. mm, 0. µm Agilent 0A/B MSD and a 0N FID equipped Sampler: Agilent B,.0 µl syringe (p/n -),.0 µl injection Inlet: Detector: Helium 0 cm/s, constant flow MSD system, cm/s FID system 00: split C. min hold, C/min to C, then C/min to C, then 00 C/min to 0 C,. min hold MSD source at 00 C, quadrupole at 0 C, transfer line at 0 C, scan range -0 amu 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Single taper, MS certified liner with restriction to hold glass wool, - Syringe: µl tapered, FN -s//hp, LAVOIL. a-pinene. Camphene. -Octen--ol. -Octanone. b-myrcene. -Carene. o-cymene. Eucalyptol. D-Limonene 0. b-trans-ocimene. b-cis-ocimene. b-linalool. Octen--ol acetate. Camphor. Borneol. Lavandulol. Terpinen--ol. a-terpineol. Hexyl butyrate 0. Cumic aldehyde. cis-geraniol. Linalool acetate. Borneol acetate. Lavandulyl acetate. Nerol acetate. Geranyl Acetate. Caryophyllene. a-santolene. a-bergamotene 0. b-farnesene. Germacrene D. g-cadinene. Caryophyllene oxide. tau-cardinol. a -Bisabolol GC/MS total ion chromatogram of lavender oil sample on an Agilent J&W DB-ms Ultra Inert 0 m x 0. mm, 0. µm capillary GC column (p/n -0UI). The well-resolved, sharp peaks observed on the column ensure reliable analysis and fingerprinting of lavender oils.

67 FooD, FLavor, and FragranCe applications essential oils DB-waX -0 0 m x 0. mm, 0. µm Hydrogen at. cm/s Measured at C C hold 0. min. C/min to 0 C Injection: Split :0, 0 C µl of : oil in acetone Detector: MSD full scan at m/z C transfer line wild chamomile peppermint 0. a-pinene. b-pinene. b-myrcene. D-Limonene. Eucalyptol.,-Hexadienal. Menthone. g-terpinene. Menthofuran 0. Iso-menthone. D-Carane. Bornyl acetate. b-caryophyllene. Isomenthol. Citronellyl formate. Menthol. t-b-farnesene. g-cadinene. d-cadinene 0. Citronellol. Nerol. b-maaliene

68 FooD, FLavor, and FragranCe applications Fragrance reference Standard DB m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at C/min Injection: Split, 0 C Split ratio :0 Detector: MSD, 00 C transfer line Sample: µl of a :0 dilution of neat sample in acetone Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Many thanks to Carl Frey, Manager of Analytical Services, Dragoco, and Kevin Myung, Director of Flavor and Perfumery Research, Bush Boake Allen, Inc. for contributing to this work.. Acetone.,-Butanedione (diacetyl). Ethyl acetate.,-pentanedione (acetyl propionyl). Ethyl propionate. Methyl butyrate. -Methylbutyl alcohol. -Methylbutyl alcohol. Isobutyl acetate 0. Ethyl butyrate. Furfural. Ethyl isovalerate. Hexanol. Allyl butyrate. Ethyl pentanoate. Hexylene glycol. a-thujone. Benzaldehyde. a-pinene 0. Camphene.,,-Trimethylhexanol. Sabinene. b-pinene. Ethyl hexanoate. Myrcene 0 0 0,, 0. Hexyl acetate cis-linalool oxide Methyl benzoate trans-linalool oxide. Methyl-cresol. Benzyl alcohol 0. para-cymene.,-cineol. Limonene.,-Dimethylhept--enal. g-terpinene. Octanol. Ethyl heptanoate. Linalool. Benzene ethanol. Rose oxide, cis-rose. Rose oxide, trans-rose. Camphor. Citronellal. Benzyl acetate. Menthone. Isoborneol. Isomenthone. Borneol. Terpinen--ol. a-terpineol , 0. Ethyl octanoate. Octyl acetate. Fenchyl acetate. Citronellol. Neral. Carvone Phenylethyl acetate 0. Geraniol. Linalyl acetate. Geranial. Hydroxycitronellal. Citronellyl formate. Bornyl acetate. Vertenex (isomer ). Ethyl nonanoate. Geranyl formate 0. Vertenex (isomer ). g-nonalactone. Citronellyl acetate. Neryl acetate. Geranyl acetate. Diphenyl oxide. Ethyl decanoate. a-copaene 0. Florazone (isomer ). Florazone (isomer ). b-caryophyllene. Citronellyl propionate.,-guaiadiene. Dodecanol. Ethyl undecanoate 0 0. Eugenyl acetate. Frambinone (raspberry ketone). Isoamyl salicylate. d-cadinene. cis-nerolidol. Rosatol (rosetone) Geranyl butyrate. trans-nerolidol. n-amyl salicylate. Phenyl ethyl tiglate 00. Ethyl dodecanoate 0. Benzophenone 0. Dibenzyl ether 0. g-dodecalactone 0. Citronellyl tiglate 0. Evernyl 0. Geranyl tiglate 0. Geranyl--methyl valerate 0. Celestolide 0. Heptadec--ene 0. Benzyl benzoate. Ethyl tetradecanoate. Benzyl salicylate. Tonalid. Nonadec--ene. Isopropylmyristate. Ethyl pentadecanoate Nonadecane. Ethyl hexadecanoate. Musk T (ethylene brassylate). Eicosane 0. Cinnamyl phenyl acetate. Heneicosane. Phenyl ethyl cinnamate. Ethyl octadecanoate. Hercolyn D (tetrahydro & dihydro methyl abietate). Cinnamyl cinnamate. Cetearyl octanoate. Cetearyl decanoate GCFF00

69 FooD, FLavor, and FragranCe applications Fragrance reference Standard DB-waX -0 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C C for min -0 C at C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: Sample: MSD, 0 C transfer line µl of a :0 dilution of neat sample in acetone Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Many thanks to Carl Frey, Manager of Analytical Services, Dragoco, and Kevin Myung, Director of Flavor and Perfumery Research, Bush Boake Allen, Inc. for contributing to this work.. Acetone. Ethyl acetate. Ethyl propionate.,-butanedione (diacetyl). Methyl butyrate. Isobutyl acetate. a-pinene. Ethyl butyrate.,-pentanedione (acetyl propionyl) 0. Camphene. Ethyl isovalerate. b-pinene. Ethyl pentanoate. Myrcene. Allyl butyrate. Limonene.,-Cineol.,,-Trimethylhexanol. -Methylbutyl alcohol 0. -Methylbutyl alcohol. Ethyl hexanoate. g-terpinene. p-cymene. Hexyl acetate. Terpinolene. Ethyl heptanoate.,-dimethylhept--enal (melonal). Rose oxide, cis-rose. Hexanol 0. Rose oxide, trans-rose. Methyl-para-cresol. Ethyl octanoate. cis-linalool oxide. Menthone. Furfural. trans-linalool oxide. Octyl acetate. Isomenthone. a-copaene 0. Camphor. Benzaldehyde. Ethyl nonanoate. Linalool. Linalyl acetate. Vertenex (isomer ). Octanol. b-caryophyllene. Vertenex (isomer ). Terpinen--ol 0. Methyl benzoate. Hexylene glycol. Ethyl decanoate. Citronellyl acetate. Isoborneol. Neral. a-terpineol. Geranyl formate. Borneol. b-bisabolene 0. Benzyl acetate. Neryl acetate. Geranial. Ethyl undecanoate. d-cadinene. Geranyl acetate. Citronellol. Ethyl dodecanoate. Geraniol. Benzyl alcohol 0. Geranyl butyrate. Nonadecane. Benzene ethanol. Nonadec--ene. Florazone (isomer ). Florazone (isomer ). Hydroxycitronellal. Dodecanol. Diphenyl oxide. Citronellyl tiglate 0. Eugenyl methyl ether. g-nonalactone. Ethyl tetradecanoate. n-amyl salicylate. Geranyl tiglate. Ethyl pentadecanoate. Isopropylmyristate 0. Phenyl ethyl tiglate. Rosatol (rosetone). Eugenyl acetate. Ethyl hexadecanoate. g-dodecalactone. Dibenzyl ether. Tonalid. Ethyl octadecanoate. Benzophenone. Benzyl benzoate 00. Cetearyl octanoate 0. Musk T (ethylene brassylate) 0. Cetearyl decanoate 0. Frambinone (raspberry ketone) 0. Cinnamyl phenyl acetate 0. Phenyl ethyl cinnamate 0. Cinnamyl cinnamate, 0, 0, 00, 0, GCFF00

70 FooD, FLavor, and FragranCe applications perfume hp-innowax 0n- 0 m x 0. mm, 0. µm Helium, 0 cm/s 0. ml/min constant flow 0 C for min 0-0 C at C/min 0 C for min Injection: Split, 0 C Split ratio 0: Detector: MSD, 0 C 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Limonene. Linalool. Linalyl acetate. Benzyl acetate. Citronellol. Benzene ethanol. a-methyl ionone. Carvacrol and geraniol. Isoamyl salicylate 0. n-amyl salicylate. Commamyl acetate. Acetyl cedrene. Diethyl phthalate. Tonalid. Coumarin. Musk xylene. Benzyl benzoate. Benzyl salicylate. Musk ketone GCFF00 Chiral Compounds in essential oils and Fragrances hp-chiral 0b 0g-B 0 m x 0. mm, 0. µm Hydrogen, cm/s, constant pressure C for min -0 C at C/min Injection: Split, 0 C Split ratio 0: Detector: FID, 00 C Sample: µl 0. ng/µl each analyte in Hexane GCFF00.,-Dimethylbenzene. Myrcene. (-)-Camphene. (+)-Camphene. (+)-b-pinene. S-(-)-b-Pinene. Cineole. (R)-(+)-Citronellal. S,R,S-(+)-Menthol 0. R,S,R-(-)-Menthol. a-terpineol. (+/-)-Isoborneol. (+)-Borneol. trans-cinnamaldehyde Menthol Cyclodex-B - 0 m x 0. mm, 0. µm Hydrogen, cm/s 0 C isothermal Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of µg/µl each chloroform. (+)-Neomenthol. (-)- Neomenthol. (+)-Menthol. (-)-Menthol min GCFF00 0

71 ,, FooD, FLavor, and FragranCe applications FaMes Suggested Supplies DB- - 0 m x 0. mm, 0. µm Hydrogen at cm/s, constant pressure mode 0 C for.0 min 0-0 C at. C/min 0- C at. C/min C for min -0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio 0: Detector: FID, 0 C Chromatogram provided courtesy of Steve Watkins and Jeremy Ching, FAME Analytics, Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - 0. C :0. C :0. C :0. C :0. C 0:0. C :0. C :0. BHT. C :0 0. C :0. C :n. C :0. C :0. C :n(trans). C :n(cis). C :0. C :. C :0. C :n(trans) 0. C :n(cis) Baseline resolution of C and C cis-, trans- isomers 0. C :n. C :n. C :n. C :n. C :(d,). C :(d0,). C 0:0. C 0:n. C 0:n 0. C 0:n 0. C 0:n. C 0:n. C 0:n. C :0. C :n. C :n. C :n. C :n. C :0 0. C :n. C :n GCFF0 analysis of Fragrance and allergens vf-waxms Cp0 0 m x 0. mm, 0. µm 00 C to 0 C with 0 C/min Helium,.0 ml/min Injection: Split :0, T=0 C Detector: GC/MS Ion Trap Trap: 00 C Manifold: 0 C Sample: 0. µl, Fragrances mixture (00 ppm). Linalool. Methyl heptine carbonate. Phenyl acetaldehyde. Methyl chavicol. Methyl octine carbonate. Citronellol. Geraniol. Methyl gamma ionone. Benzyl alcohol 0. Cinnamaldehyde 0,. Hydroxy citronellal. Methyl eugenol. Lilial. Eugenol. Amyl cinnamyl aldehyde. Anisic alcohol. Cinnamyl alcohol. Farnesol isomer I + II. Farnesol isomer III 0. iso-eugenol. Hexyl cinnamic aldehyde. Lyral (,-isomer). Coumarin. Amyl cinnamic alcohol. Benzyl benzoate. Benzyl salicylate. Benzyl cinnamate, min

72 FooD, FLavor, and FragranCe applications organophosphorus pesticide residues in olive oil extract DB-ms Ultra Inert -UI 0 m x 0. mm, 0. µm Instrument: Agilent 0/C Sampler: Agilent B,.0 µl syringe (p/n -) CFT Device: Purged -way splitter (p/n G0B) Split ratio MSD:FPD = : MSD Restrictor:. m x 0. mm id deactivated fused silica tubing FPD Restrictor: 0. m x 0. mm id deactivated fused silica tubing Aux EPC:. psi constant pressure Inlet: µl splitless; 0 C, purge flow 0 ml/min at 0. min, gas saver on at min 0 ml/min Helium, constant pressure. psi at C C (0. min), C/min to 0 C, 0 C/min to 0 C (0. min), 0 C to 0 C (. min) Postrun Backflush: Detector:. min at 0 C, Aux EPC pressure psi during backflush, psi inlet pressure during backflush MSD: 00 C transfer line, 00 C source, 0 C quad FPD: 0 C, hydrogen ml/min, air 00 ml/min, carrier + makeup (N ) 0 ml/min Response Methamidophos. Acephate. Omethoate. Diazinon. Dimethoate. Pirimiphos-methyl. Parathion-methyl. Malathion. Chlorpyrifos - 0. Fenitrothion. Parathion. Fenthion. Methidathion. Carbophenothion. Triphenyl-phosphate (surrogate std). Azinphos-methyl. Azinphos-ethyl Time GC/FPD chromatogram of a 00 ng/ml matrix-matched organophosphorus pesticide standard with analyte protectant analyzed on an Agilent J&W DB-ms UI GC column. tips & tools View the latest GC column focused applications, products and educational resources at

73 FooD, FLavor, and FragranCe applications Fragrance allergens hp-ms 0S- 0 m x 0. mm, 0. µm Suggested Supplies Septum: mm Advanced Green septa, - Helium,. ml/min, constant pressure of 0 kpa Injection: Split, 0 C Split ratio :0 Sample: 0 C in min, C/min to 0 C, 0-00 C at C/min 00 C hold, min N MSD in scan (0-0 amu) Solvent delay,.0 min µl, 0 ppm standard,, 0 mp., 0 a, b b a Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Limonene. Benzyl alcohol. Phenyl acetaldehyde. Linalool. Methyl heptine carbonate. Citronellol. Neral. Geraniol. Citral (geranial) 0. Cinnamaldehyde. Anisyl alcohol. Hydroxy citronellal. Methyl octine carbonate. Cinnamic alcohol. Eugenol. Coumarin. Cinnamyl acetate. Isoeugenol. Alpha isomethyl ionone 0. Lilial (BMHCA) a. Lyral b. Lyral. Amyl cinnamyl alcohol a. Farnesol b. Farnesol. Hexyl cinnamaldehyde. Benzyl benzoate. Benzyl salicylate. Benzyl cinnamate 0 0 GCFF00 Flavor Mixture Ultra 0B- m x 0. mm, 0. µm Injection: Split, 0 C Split ratio 0: Helium, 0 kpa,. ml/min constant flow 0 C for min 0-0 C at C/min 0 C for min Detector: IRD, 0 C Wide Band MCT, 0 to 000 cm - Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - 0. Fenchone. Thujone. Benzaldehyde. trans-carveol. Farnesol. cis-carveol. trans-geraniol. Citral. Eugenol 0. Vanillin. trans-isoeugenol. trans-citronellyl tiglate. cis-citronellyl tiglate 0 0 GCFF00

74 FooD, FLavor, and FragranCe applications Lemon oil DB m x 0.0 mm, 0.0 µm Hydrogen at 0 cm/s, measured at 0 C 0 C for min 0- C at 0 C/min C for min Injection: Split, C Split ratio : 0 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Detector: Nitrogen makeup gas at 0 ml/min. a-thujone. b-thujone Syringe: µl tapered, FN -s//hp, -. Camphene. Sabinene. b-pinene. Myrcene. Octanal. a-phellandrene. a-terpinene 0. r-cymene. d-limonene. g-terpinene. Octanol. Terpinolene. Linalool. Nonanal. Citronellal. Terpinen--ol. a-terpineol 0. Decanal. Neral. Geranial. Neryl acetate. Geranyl acetate. b-caryophyllene. trans-a-bergamotene. a-humulene. b-bisabolene min GCFF0 Cold-pressed orange oil DB m x 0.0 mm, 0.0 µm Hydrogen at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0-0 C at 0 C/min 0 C for min Injection: Split, C Split ratio : Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Chromatogram courtesy of Tastemaker Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - 0. a-pinene. Sabinene. Myrcene. Octanal. Limonene. Linalool. Nonanal. Citronellal. a-terpineol 0. Decanal. Neral. Geranial. Dodecenal. Valencene. Cadinene. b-sinensal. a-sinensal. Nootkatone. Polymethoxyflavones Polymethoxyflavones 0 GCFF0

75 FooD, FLavor, and FragranCe applications peppermint oil DB-waX -0 0 m x 0. mm, 0. µm Helium at cm/s (0. ml/min) C for min -00 C at C/min 00 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: µl neat. a-pinene. b-pinene. Sabinene. Myrcene. a-terpinene. (+/-)-Limonene.,-Cineol. cis-ocimene. Terpinene 0. r-cymene. g-terpinolene. -Octanol. -Octen--ol. trans-sabinene hydrate. (+/-)-Methone. Methofuran, 0. d-isomethone. b-bourbonene. Linalool 0. Menthyl acetate. Neomenthol. Terpinen--ol. b-caryophyllene. (+/-)-Menthol. Pulegone. a-terpineol. Germacrene-D. Piperitone. Viridiflorol Thanks to William Faas of A.M. Todd Company for providing the sample and assisting with peak identification. Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - 0 Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - min GCFF0 Spearmint oil (western) DB-waX -0 0 m x 0. mm, 0. µm Helium at cm/s (0. ml/min) C for min -00 C at C/min 00 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: µl neat. a-pinene. b-pinene. Sabinene. Myrcene. a-terpinene. (+/-)-Limonene.,-Cineol. cis-ocimene. g-terpinene 0. r-cymene. Terpinolene. -Octylacetate. -Octanol. trans-sabinene hydrate. (+/-)-Methone. b-bourbonene, 0. Linalool. Terpinen--ol. b-caryophyllene 0. Dihydro carvone. trans-dihydro carvyl. trans-b-farnesene. a-terpineol. Germacrene-D. (+/-)-Carvone. cis-carvyl acetate. trans-carveol. cis-carveol. cis-jasmone 0. Viridiflorol Thanks to William Faas of A.M. Todd Company for providing the sample and assisting with peak identification. Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - min GCFF0

76 FooD, FLavor, and FragranCe applications Ylang Ylang oil DB-XLB - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at. C/min Injection: Split, 0 C Split ratio : Detector: MSD, 0 C transfer line full scan at m/z -0 Sample: µl of 0% oil in methylene chloride. r-methylansiole. Linalool. Methylbenzoate. Benzylacetate. Geraniol. Geranyl acetate. b-caryophyllene. Cinnamyl acetate. Germacrene-D 0. Benzyl benzoate. Farnesol acetate. Benzyl salicylate 0 Enlarged view of peaks and Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. 0 GCFF0. Ylang Ylang oil DB-waX -0 0 m x 0. mm, 0. µm A: Helium. cm/s measured at C B: Hydrogen. cm/s measured at C A: C hold. min. C/min to 0 C hold. min B: C hold 0. min. C/min to 0 C hold.0 min A B 0. a-pinene. Methyl-r-cresol. a-copaene. a-gurjunene. Linalool. b-caryophyllene. Methyl benzoate. a-caryophyllene. Germacrene-d 0. Benzyl acetate. Farnescene. d-cadinene. Geranial acetate. trans-cinnamyl acetate. b-bisbolene. Farnesyl acetate. Benzyl benzoate. Benzyl salicylate GCDBWAX0

77 FooD, FLavor, and FragranCe applications rosemary oil CycloSil-B - 0 m x 0. mm, 0. µm Hydrogen at 0 cm/s, measured at 0 C C for min 0-0 C at C/min Injection: Split, 0 C Split ratio 0: Detector: FID, 0 C. (+/-)-a-pinene. (+/-)-Camphene. (+/-)-b-pinene. (+/-)-Limonene. (+/-)-Linalool. (+/-)-Camphor. (+/-)-Terpinene--ol. (+/-)-Isoborneol. (+/-)-Borneol 0. (+/-)-a-terpineol Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, GCFF0 0 0 Citrus Flavored Carbonated Beverage (Soda) Sampler: CycloSil-B - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0-0 C at ºC/min Headspace No stir, NaCl g/0 ml sample Adsorption: C for min Desorption: 0 C for min Injection: Split, : Polyacrylate fiber, µm. S-(-)-Limonene. p-cymene. (+)-Limonene. Octanol. g-terpinene. Nonanol. -Ethyl--Hexanol. Linalool. Decanol 0. Terpinen--ol. Phenethylalcohol. a-terpineol. BHT Detector: MSD, 0 C transfer line Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, GCFF0

78 FooD, FLavor, and FragranCe applications alcohol Beverage Standard Detector: hp-ffap 0F-0 0 m x 0.0 mm, 0. µm Hydrogen 0 C for min 0-00 C at C/min 00 C for min FID 0. Acetaldehyde. Acetone. Ethyl formate. Ethyl acetate. Methanol. Ethanol. Diacetyl. sec-butanol. n-propanol 0. Isobutanol. n-butanol. Isoamyl alcohol. n-amyl alcohol. Acetic acid. Propionic acid 0 min GCFF0 Bourbon hp-innowax 0n- 0 m x 0. mm, 0. µm Helium, cm/s,. psi ( C). ml/min constant flow C for min -0 C at C/min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio : Detector: FID, 0 C Sample: µl GCFF0. Acetaldehyde. Ethyl acetate. Methanol. Ethanol. Acetic acid. n-propanol. Isobutanol. -Methyl--butanol or -methyl--butanol alditol acetates DB- - 0 m x 0. mm, 0. µm Hydrogen at. cm/s 0 C isothermal Injection: Split, C Split ratio :0 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min. Rhamnitol. Fucitol. Ribitol. Arabinitol. Mannitol. Galactitol. Glucitol. Inositol Sample: µl. min GCFF00

79 FooD, FLavor, and FragranCe applications Strawberry Syrup hp-innowax 0n- 0 m x 0. mm, 0.0 µm Helium, 0 cm/s,. psi (0 C). ml/min constant flow 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio 0: Detector: FID, C 0. Ethyl acetate. Ethyl butyrate. Isoamyl acetate. Amyl acetate. Isoamyl butyrate. Amyl butyrate. Ethyl benzoate. Citronellol. Geraniol 0. Ethyl--phenyl oxiran carboxylate. Strawberry aldehyde. Benzyl benzoate GCFF0 Separation of tms-derivatized Sugars using vf-ms vf-ms Cp 0 m x 0. mm, 0. µm Sample: µl, splitless µl Sample Conc: 0 ppb He,.0 ml/min 0 C to 0 C, C/min to 00 C, 0 C/min Injection: Split; : Detector: MS / 0 0. Threitol. Erythritol. Rhamnose. Rhamnose. Xylose. Arabitol. Ribitol. -0-Methylglucose. Xylose 0. Rhamnitol. -0-Methylglucose. Glucuronic acid-,-lactone. Ribose. Manitol. Sorbitol (not identified). Galactitol. Glucuronic acid. Lactulose. Lactose 0. Sucrose. Threhalose 0 min VGC00

80 FooD, FLavor, and FragranCe applications organic acids DB-FFap - 0 m x 0. mm, 0. µm Helium at 0 cm/s, measured at 00 C 00 C for min 00-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0. Acetone. Formic acid. Acetic acid. Propionic acid. Isobutyric acid. Butyric acid. Isovaleric acid. Valeric acid (pentanoic acid). Isocaproic acid 0. Caproic acid (hexanoic acid). Heptanoic acid. Octanoic acid. Decanoic acid. Dodecanoic acid. Tetradecanoic acid. Hexadecanoic acid. Octadecanoic acid. Arachidic acid (eicosanoic acid) Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min, 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - min GCFF0 acids vf-waxms Cp0 0 m x 0. mm, 0. µm Sample: Acid sample, 0.% (Cyclohexane),.0 µl Hydrogen, kpa 0 C to 00 C, C/min vf-waxms. Acetic acid. Propionic acid. Iso-butyric acid. Butyric acid. Iso-valeric acid Injection: 0 C, split 00 ml/min vendor X vendor Y vendor Z. min. VGC00 0

81 FooD, FLavor, and FragranCe applications Bacterial Fatty acid Methyl esters DB m x 0. mm, 0. µm Hydrogen at cm/s 0 C for min 0-0 C at C/min Injection: Split ratio :00 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Detector: FID Nitrogen makeup gas at 0 ml/min 0 min 0 GCFF0. C :0 Methyl undecanoate. -OH C 0:0 Methyl -hydroxydecanoate. C :0 Methyl laurate. C :0 Methyl tridecanoate. -OH C :0 Methyl -hydroxydodecanoate. -OH C :0 Methyl -hydroxydodecanoate. C :0 Methyl myristate. -Me C :0 Methyl -methyltetradecanoate. C :0 Methyl pentadecanoate 0. -OH C :0 Methyl -hydroxytetradecanoate. -OH C :0 Methyl -hydroxytetradecanoate. C : Methyl palmitoleate. C :0 Methyl palmitate. -Me C :0 Methyl -methylhexadecanoate.,0-dime C :0 Methyl cis-,0-methyl hexadecanoate. C :0 Methyl heptadecanoate. -OH C :0 Methyl -hydroxyhexadecanoate. C : Methyl oleate. C : Methyl elaidate 0. C :0 Methyl stearate.,0-dime C :0 Methyl cis-,0-methylene octadecanoate. C :0 Methyl nonadecanoate. C 0:0 Methyl arachidate Separation of cis-trans FaMe Isomers Select FaMe Cp 00 m x 0. mm Sample: 0. µl Sample Conc: ng approx. per component on the column Helium, 0 kpa C Injection: Split, :0 Detector: FID 0. C:0. C: trans. C: trans. C: trans. C: 0 trans. C: trans. C: trans. C: trans +?. C: cis 0. C: 0 cis. C: cis. C: cis. C: cis. C: cis. C: cis 0 min VGC00

82 FooD, FLavor, and FragranCe applications Component FaMe Mix hp- - 0 m x 0. mm, 0.0 µm He at. ml/min constant flow C C to C at C/min C for min C to 0 C at C/min 0 C for min Injection: Split, 0 C Split ratio 0: µl of 0 ppm each in CHCl Detector: FID, 0 C 0 0. nc:0. nc:0. nc:0. nc:0. nc0:0. nc:0. nc:0. C: (c). nc:0 0. nc:0. C: (t). C: (c). nc:0. C: (0t). C: (0c) C: (c). nc:0. C: (t). C: (c) 0. nc:0. C: (0t). C: (0c). nc:0. C: (t). C: (t). C: (t). nc: (c). C: (c). C: (c) 0. nc: (t,t) 0. C: (0t). nc:0. C: (t). C: (c,c). C: (c). C: (0c). C: g(c,c,c). nc0:0. C: (c,c,c) 0. C0: (c). C: (0c,c). C0: (t). C: CONJ. C0: (c). C0: (c). C: (0t,c). nc:0. C0: (c,c). C: (c) 0. C0: (c,c,c). nc:0. C: (t). C0: (c,c,c,c). C0: (c,c,c). C: (c,c). C: (c). nc:0. C0: (EPA). C: (c,c) 0. C: (c). nc:0. C: (c,c,c). C: (c,0c,c,c). C: (c). C: (DPA). C: (DHA). C:- Hydroxy (t). C:0 Hydroxy. C:- Hydroxy (c) FAMEs FaMe Standard DB-waX -0 0 m x 0.0 mm, 0.0 µm Suggested Supplies Hydrogen at cm/s, measured at 0 C 0 C for 0. min 0- C at C/min -0 C at C/min 0-0 C at C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Butyric acid methyl ester (C :0 ). Caproic acid methyl ester (C :0 ). Caprylic acid methyl ester (C :0 ). Capric acid methyl ester (C 0:0 ). Undecanoic acid methyl ester (C :0 ). Lauric acid methyl ester (C :0 ). Tridecanoic acid methyl ester (C :0 ). Myristic acid methyl ester (C :0 ). Myristoleic acid methyl ester (C : ) 0. Pentadecanoic acid methyl ester (C :0 ). cis-0-pentadecenoic acid methyl ester (C : ). Palmitic acid methyl ester (C :0 ). Palmitoleic acid methyl ester (C : ). Heptadecanoic acid methyl ester (C :0 ). cis-0-heptadecenoic acid methyl ester (C : ). Stearic acid methyl ester (C :0 ). Oleic acid methyl ester (C :nc ). Elaidic acid methyl ester (C :nt ). Linoleic acid methyl ester (C :nc ) 0. Linolelaidic acid methyl ester (C :nt ). g-linolenic acid methyl ester (C :n ). Linolenic acid methyl ester (C :n ). Arachidic acid methyl ester (C 0:0 ). cis--eicosenoic acid methyl ester (C 0: ). cis-,-eicosadienoic acid methyl ester (C 0: ). cis-,,-eicosatrienoic acid methyl ester (C 0:n ). Heneicosanoic acid methyl ester (C :0 ). cis-,,-eicosatrienoic acid methyl ester (C 0:n ). Arachidonic acid methyl ester (C 0:n ) 0. cis-,,,,-eicosapentaenoic acid methyl ester (C 0:n ). Behenic acid methyl ester (C :0 ). Erucic acid methyl ester (C :n ). cis-,-docosadienoic acid methyl ester (C : ). Tricosanoic acid methyl ester (C :0 ). Lignoceric acid methyl ester (C :0 ). cis-,,0,,,-docosahexaenoic acid methyl ester (C :n ). Nervonic acid methyl ester (C : ) 0, 0 0 excellent resolution in Min!, 0 GCFF00

83 FooD, FLavor, and FragranCe applications FaMe Standard DB- - 0 m x 0.0 mm, 0.0 µm Hydrogen at. cm/s, measured at C C for 0. min - C at C/min -0 C at C/min 0-0 C at C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Butyric acid methyl ester (C:0). Caproic acid methyl ester (C:0). Caprylic acid methyl ester (C:0). Capric acid methyl ester (C0:0). Undecanoic acid methyl ester (C:0). Lauric acid methyl ester (C:0). Tridecanoic acid methyl ester (C:0). Myristic acid methyl ester (C:0). Myristoleic acid methyl ester (C:) 0. Pentadecanoic acid methyl ester (C:0). cis-0-pentadecenoic acid methyl ester (C:). Palmitic acid methyl ester (C:0). Palmitoleic acid methyl ester (C:). Heptadecanoic acid methyl ester (C:0). cis-0-heptadecenoic acid methyl ester (C:). Stearic acid methyl ester (C:0). Oleic acid methyl ester (C:nc). Elaidic acid methyl ester (C:nt). Linoleic acid methyl ester (C:nc) 0. Linolelaidic acid methyl ester (C:nt). g-linolenic acid methyl ester (C:n). Linolenic acid methyl ester (C:n). Arachidic acid methyl ester (C0:0). cis--eicosenoic acid methyl ester (C0:). cis-,-eicosadienoic acid methyl ester (C0:). cis-,,-eicosatrienoic acid methyl ester (C0:n). Heneicosanoic acid methyl ester (C:0). cis-,,-eicosatrienoic acid methyl ester (C0:n). Arachidonic acid methyl ester (C0:n) 0. cis-,,,,-eicosapentaenoic acid methyl ester (C0:n). Behenic acid methyl ester (C:0). Erucic acid methyl ester (C:n). cis-,-docosadienoic acid methyl ester (C:). Tricosanoic acid methyl ester (C:0). Lignoceric acid methyl ester (C:0). cis-,,0,,,-docosahexaenoic acid methyl ester (C:n). Nervonic acid methyl ester (C:) GCFF0

84 GCFF0 FooD, FLavor, and FragranCe applications Canola oil Margarine partially hydrogenated FaMes aocs Method c- DB- - 0 m x 0. mm, 0. µm Injection: Split, 0 C Split :00 Detector: FID, 0 C Sample: µl Helium at cm/s (0. ml/min), measured at 0 C 0-00 C at. C/min 00 C for 0 min Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. C:0 Methyl palmitate. C: Methyl palmitoleate. C:0 Methyl stearate. C: trans-methyl elaidate and multiple isomers. C: cis-methyl oleate and multiple isomers. C: trans-multiple isomers. C: cis-multiple isomers. C: Methyl linolenate. C0:0 Methyl arachidate 0. C0: Methyl -eicosanoate Butter triglycerides I DB-ht - 0 m x 0. mm, 0.0 µm Hydrogen at cm/s, measured at 0 C -0 C at 0 C/min 0-00 C at C/min 00 C for 0 min Injection: Cool on-column Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Baseline corrected Sample: µl of µg/µl in toluene (approximately % w/w solution) T T 0 min T T=total number of carbons Butter triglycerides II DB-ht - 0 m x 0. mm, 0. µm Injection: Hydrogen at 0 cm/s 0- C at C/min C for min Cool on-column Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Baseline corrected Sample: µl of µg/µl in toluene (approximately % w/w solution) Cholesterol 0 0 PPP P=palmitic acid, hexadecanoic acid, C:0 S=stearic acid, octadecanoic acid, C:0 O=oleic acid, cis--octadecanoic acid, C: PPS PPO PSS PSO POO SSO SOOOOO SSS GCFF0

85 FooD, FLavor, and FragranCe applications Fast Screening of FaMe Isomers in Butter vf-ms Cp 0 m x 0. mm, 0. µm Sample: 0. µl ca. ng per component on column Hydrogen, 0 kpa C Injection: Split, :00 T= C Detector: FID 0 Short run time. C:0. C0:0. C:0. C:0. C:. C:. C: -cis. C: -cis. C: trans 0. C: -cis. C: -cis. C: -trans, -trans. C: -cis, -trans. C: -trans,-cis. C: -cis, -cis 0 min VGC00 pesticides in Sunflower oil vf-ms Cp0 0 m x 0. mm, 0. µm Sample: Sample Conc: µl, splitless 0 ppb He,. ml/min, constant flow Injection: Detector: 0 C (.0 min), C to 0 C/min (0.0 min) to 0 C/min to 0 C (0 min) 0 with carbofrit liner A: Ion Trap in MS/MS, full scan B: MS/MS. b-hch. g-hch. d-hch. + Vinclozolin. Pyrimiphos methyl. + Malathion. Chloropyrifos. Ethyl parathion. Pyrimiphos ethyl 0. Bromofos. o,p -DDE. a-endosulfan. p,p -DDE. o,p -DDD. Dieldrin. p,p -DDD. b Endosulfan. p,p -DDT. Endosulfan sulfate. b-hch. g-hch. d-hch. + Vinclozolin. Methyl parathion. Pyrimiphos methyl. + +Fenitrothion. Chloropyrifos. Pyrimiphos ethyl 0. Promofos. o,p -DDE. a-endosulfan. p,p -DDE. o,p -DDD. Dieldrin. p,p -DDD. b Endosulfan. p,p -DDT. Endosulfan sulfate a B 0 0 min min VGC000

86 energy and FUeLS applications Energy and Fuels Applications Fast analysis of aromatic Solvent hp-innowax 0n- 0 m x 0. mm, 0.0 µm Helium at 0 psi constant pressure mode C (0 min); C/min to 00 C (0 min) 0 C/min to C (0 min) Injection: Split/splitless at 0 C 00: split ratio Detector: FID at 0 C Sample:.0 µl hp-innowax 0n- 0 m x 0. mm, 0. µm Helium at psi constant pressure mode 0 C ( min); C/min to C ( min) Injection: Split/splitless at 0 C 00: to 00: split ratio Detector: FID at 0 C Sample: 0. to.0 µl Unified aromatic solvent method pa optimized unified aromatic solvent method pa GCHE00. Heptane. Cyclohexane. Octane. Nonane. Benzene. Decane. Toluene.,-Dioxane. Undecane 0. Ethylbenzene. p-xylene. m-xylene. Cumene. Dodecane. o-xylene. Propylbenzene. p-ethyltoluene. m-ethyltoluene. t-butylbenzene 0. s-butylbenzene. Styrene. Tridecane.,-Diethylbenzene.,-Diethylbenzene. n-butylbenzene. a-methylstyrene. Phenylacetylene This application showcases the practicality using high efficiency GC columns in daily aromatic solvent analysis. The result: a four-fold reduction in run time (compared to a 0. mm id column) with no compromise in resolution.

87 energy and FUeLS applications refinery gas I hp-plot Q 0p-Qo 0 m x 0. mm, 0.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium p=.0 psi at 0 C Liner: Direct,. mm id, C for min 0-00 C at 0 C/min 00 C for min Injection: Split, 0 C Split flow 00 ml/min 0. cc valve Detector: TCD, 0 C Sample: Refinery gas and others Seal: Gold plated seal, Air/CO. C. CO. Ethylene. C. H S. COS. H O. Propylene 0. C. MeOH. i-c. t-c. n-c. cis-c. i-c. n-c 0 0 GCPE0 Unleaded gasoline DB-petro -0a 00 m x 0. mm, 0.0 µm Helium at. cm/s 0 C for min 0-0 C at C/min 0-0 C at C/min 0-0 C at C/min 0 C for 0 min Injection: Split, 00 C Split ratio :00 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: µl of neat sample. Methane. n-butane. Isopentane. n-pentane. n-hexane. Methylcyclopentane. Benzene. Cyclohexane. Isooctane 0. n-heptane. Toluene * *Valley point with = % **Valley point with = %.,,-Trimethylpentane. -Methylheptane. -Methylheptane. n-octane. Ethylbenzene. m-xylene **. p-xylene. o-xylene 0. n-nonane. Isopropylbenzene. Propylbenzene.,,-Trimethylbenzene. Isobutylbenzene. sec-butylbenzene. n-decane.,,-trimethylbenzene. Butylbenzene. n-undecane 0.,,,-Tetramethylbenzene. Naphthalene. Dodecane. Tridecane, 0,,, min GCPE0

88 energy and FUeLS applications n-paraffin Standard DB-ht Sim Dis -00 m x 0. mm, 0. µm Helium at ml/min, measured at C -0-0 C at 0 C/min Injection: OPTIC PTV -0 C at C/s Detector: FID, 0 C Nitrogen makeup gas at ml/min Sample: 0. µl of about % n-paraffins in CS 0 Peak numbers denote carbon number GCPE0 Sulfur Standards in toluene DB-Sulfur SCD g m x 0. mm,.0 µm Inlet: ºC, Split ratio 0: (Inert Flow Path split/splitless inlet) Injection: µl Burner temperature: 00 ºC Vacuum of burner: torr Vacuum of reaction cell: torr Hydrogen: 0 ml/min Air: 0 ml/min Helium, constant flow mode,. ml/min ºC for min, ºC to 0 ºC at 0 ºC/min, 0 ºC for 0 min 0 Suggested Supplies Septum: Non-stick bleed and temperature optimized (BTO) septa, mm, 0/pk, - Liner: Low pressure drop, Ultra Inert Liner with glass wool, 0- Seal: Ultra Inert gold plated seal and washer, 0- Syringe: µl tapered, FN -s//hp, - 0 CaS no. Formula Concentration (mg/kg). Hydrogen sulfide -0- H S 000. Carbonyl sulfide -- COS 000. Methanethiol -- CH SH 000. Ethanethiol -0- C H SH 000. Dimethyl sulfide -- (CH ) S 000. Carbon disulfide --0 CS Propanethiol -- C H S Methyl--propanethiol -- C H 0 S Propanethiol 0-0- C H S Ethyl methyl sulfide -- C H SCH 000. Thiophene 0-0- C H S Methyl--propanethiol --0 C H 0 S 000. Diethyl sulfide -- (C H ) S Butanethiol 0-- C H 0 S 000. Dimethyl disulfide --0 (CH S) Methylthiophene -- C H S Methylthiophene -- C H S 000. Diethyl disulfide 0-- (C H S) Methylbenzo[b]thiophene -- C H S Methylbenzothiophene -- C H S 000. **Diphenyl sulfide -- C H 0 S 000 ** Internal standard min

89 energy and FUeLS applications Sulfur Compounds in propylene ( ppm) Injection: Detector: Sample: gs-gaspro - 0 m x 0. mm 0 C for. min 0-0 C at 0 C/min OI Analytical Volatiles Inlet Split ratio : 00 µl gas sampling valve OI Analytical Model 0 PFPD ppm sulfur compounds in propylene Chromatogram courtesy of OI Analytical 0. COS. H S. Propylene. CS. Methyl mercaptan. Ethyl mercaptan. Thiophene. Dimethyl sulfide. -Propanethiol 0. -Propanethiol. -Methyl--propanethiol. -Methyl--propanethiol. -Methyl--propnaethiol. -Butanethiol 0 GCPE00 Sulfur Impurities in propylene Select Low Sulfur Cp 0 m x 0. mm C for min, 0 C/min to 0 C for min Injection: Helium, constant flow,.0 ml/min Gas sampling valve 0 C, split :0. H S. COS. CH SH Detector: SCD, 00 C Sample: Polypropylene matrix containing ~00 ppb H S and CH SH, ~00 ppb COS Injection Volume: ml Time [min]

90 energy and FUeLS applications C to C hydrocarbon Mix Sampler: poraplot Q pt Cp0pt 0 m x 0. mm, 0.00 µm Helium, ml/min in constant flow mode 0 C ( min) then to 0 C at 0 C/min, hold. min Headspace unit Oven 0 C, valve 0 C, transfer line 0 C pa... Methane. Ethane/ethylene. Acetylene. Propane. Propylene. Propyne. n-butane Detector: FID or TCD at 0 C Injection Volume: 0. ml loop fitted to inlet valve of headspace unit Inlet: Split mode at :, typically at 0 C or higher depending on column oven initial conditions. 0 min PoraPLOT Q PT, 0 m x 0. mm, with attached manufacturer-prepared integrated dual-ended particle trap, showing the absence of particles or spikes on FID. poraplot U pt Cppt m x 0. mm, 0.00 µm Helium, ml/min in constant flow mode C isothermal Sampler: Headspace unit Oven 0 C, valve 0 C, transfer line 0 C Detector: FID or TCD at 0 C Injection Volume: 0. ml loop fitted to inlet valve of headspace unit Inlet: Split mode at :, typically at 0 C or higher depending on column oven initial conditions pa 0, 0. Methane. Ethane. Ethylene. Acetylene. Propane. Propylene. Propyne. n-butane PoraPLOT U PT, m x 0. mm, 0 µm film, with attached manufacturer-prepared integrated dual-ended particle trap, showing the lack of particles or spikes on FID. min hp-plot al o KCl pt 0p-Kpt 0 m x 0. mm,.00 µm Helium, ml/min in constant flow mode 00 C (0 min) then to 0 C at 0 C/min, hold min Sampler: Headspace unit Oven 0 C, valve 0 C, transfer line 0 C Detector: FID or TCD at 0 C pa 0. Methane. Ethane. Ethylene. Propane. Propylene. n-butane. Acetylene. Propyne Injection Volume: 0. ml loop fitted to inlet valve of headspace unit Inlet: Split mode at :, typically at 0 C or higher depending on column oven initial conditions 0 0 min HP-PLOT Al O KCl PT, 0 m x 0. mm, µm film, with integrated dual-ended particle trap, showing lack of particles or spikes on FID. 0

91 energy and FUeLS applications trace Sulfur Compounds in Methane (0 ppbv) Select Low Sulfur Cp 0 m x 0. mm 0 C ( min), to 0 C at C/min, to 0 C ( min) at 0 C/min Sample: ml, split ratio: : Norm Compound. Hydrogen sulfide.. Carbonyl sulfide.0. Methylmercaptan.. Ethylmercaptan.. Dimethyl sulfide.. -Propanethiol.. Methyl ethyl sulfide. Thiophene. tert-butyl mercaptan. 0. -Butanthiol.. -Methyl- propanethiol.. Diethyl sulfide.. -Butanethiol. Signal/noise 0 00 CH min trace oxygenates in Light hydrocarbon Matrices DB- -0J m x 0. mm,.00 µm Injection: Detector: gs-oxyplot - 0 m x 0. mm Helium (tm = 0. min at 0 C) 0 C for min 0 C to 0 C Split pa FID Isooctane Benzene. Dimethyl ether. Diethyl ether. Acetaldehyde. Ethyl t-butyl ether. Methyl t-butyl ether. Diisopropyl ether. Propionaldehyde. Tert-amyl methyl ether. Propyl ether 0. Isobutylaldehyde. Butylaldehyde. Methanol. Acetone. Isovaleraldehyde. Valeraldehyde. Methyl ethyl ketone. Ethanol. n-propanol. Isopropanol 0. Allyl alcohol. Isobutanol. t-butyl alcohol. s-butyl alcohol. n-butyl alcohol. -Methyl- pentanol n-octane 0 0,, OXYGEN

92 energy and FUeLS applications Selected oxygenates gs-oxyplot - 0 m x 0. mm Helium at cm/s 0 C isothermal Injection: Split, :0, 0 C Detector: FID, 0 C pa 0 OXYGEN. n-dodecane. Methyl t-butyl ether. n-tridecane. Iso-Butyraldehyde. n-tetradecane. Methanol. Acetone. n-pentadecane noble gases hp-plot Molesieve 0p-MS0 0 m x 0. mm, 0.00 µm Helium, ml/min C for min -0 C at C/min 0 C for min Injection: Split ratio 0: Detector: TCD Sample: 0 µl Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Neon. Argon. Oxygen. Nitrogen. Krypton. Xenon GCPE00 permanent gases hp-plot Molesieve 0p-MS 0 m x 0. mm,.00 µm Helium, ml/min 0 C isothermal Injection: Split ratio : Detector: TCD Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0 Sample: 0 µl. Neon. Argon. Oxygen. Nitrogen. Methane. Carbon monoxide GCPE00

93 energy and FUeLS applications Baseline resolution of air/co, Co, and Methane in a natural gas Sample hp-plot Q 0p-Qo 0 m x 0. mm, 0.00 µm Helium (. ml/min at 0 C) 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split ratio : Detector: TCD, 0 C Sample: 0. cc natural gas sample, methane, 0%+ Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, GCPE00. Air/CO. CO. Ethane. H S. Water. C. i-c /n-c. neo-c. i-c /n-c 0. C. C natural gas hp-plot al o S 0p-S m x 0. mm,.00 µm Helium, 0 cm/s (00 C), ml/min 00 C for. min 00-0 C at 0 C/min Injection: Split, 0 C Split ratio 0: Detector: FID, 0 C Sample: µl natural gas, p/n 00- Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methane. Ethane. Propane. iso-butane. n-butane. iso-pentane. n-pentane. n-hexane 0 GCPE00

94 energy and FUeLS applications ethylene hp-plot al o S 0p-S 0 m x 0. mm,.00 µm Helium, 0 cm/s ( C), ml/min constant flow C for min -00 C at C/min Injection: Split, 0 C Split ratio : Detector: FID, 0 C Sample: µl ethylene.% 0 0. Methane. Ethane. Ethylene. Propane. Cyclopropane. Propylene. Isobutane. n-butane. Propadiene 0. Acetylene. trans--butene. Butene-. Isobutylene. cis--butene. Isopentane. n-pentane.,-butadiene. Propyne. trans--pentene 0. -Methyl--butene. Pentene-. cis--pentene. n-hexane GCPE00 Impurities in ethylene gs-alumina KCl - 0 m x 0. mm Helium at ml/min, measured at C C for min -0 C at 0 C/min 0 C for min Injection: Split, 00 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. ml of trace hydrocarbons in ethylene 0. Methane. Ethane. Ethylene. Propane. Cyclopropane. Propylene. Isobutane. Acetylene. n-butane 0. Propadiene. trans--butene. -Butene. Isobutylene. cis--butene. Isopentane. n-pentane. Propyne.,-Butadiene. -Pentene 0 0 GCPE00

95 energy and FUeLS applications Impurities in propylene gs-alumina KCl - 0 m x 0. mm Suggested Supplies Septum: mm Advanced Green septa, - Helium at 0 ml/min, measured at C C for min -0 C at 0 C/min 0 C for min Injection: Split, 00 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. ml of trace hydrocarbons in propylene Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methane. Ethane. Ethylene. Propane. Cyclopropane. Propylene. Isobutane. Acetylene. n-butane 0. Propadiene. trans--butene. -Butene. Isobutylene. cis--butene. Isopentane. n-pentane. Propyne.,-Butadiene. -Pentene GCPE00 propylene gs-alumina - 0 m x 0. mm Suggested Supplies Septum: mm Advanced Green septa, - Helium at 0 ml/min, measured at C C for min -0 C at 0 C/min 0 C for min Injection: Split, 00 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. ml of trace hydrocarbons in propylene Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methane. Ethane. Ethylene. Propane. Cyclopropane. Propylene. Isobutane. Acetylene. n-butane 0. Propadiene. trans--butene. -Butene. Isobutylene. cis--butene. Isopentane. n-pentane. Propyne.,-Butadiene. -Pentene 0. n-hexane GCPE00

96 energy and FUeLS applications,-butadiene, 0 DB- - m x 0.0 mm,. µm Helium at.0 ml/min -0 C for min -0 C to 0 C at C/min 0 C to 00 C at C/min 00 C for 0 min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Sample: 0. µl Agilent Technologies wishes to thank DCG Industries (Pearland, TX) for providing this chromatogram., 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0 refined Butadiene Standard Component gravimetric concentration (ppm). Acetylene 0.. Propane.. Propylene. Propadiene (allene).. Propyne (methylacetylene). Cyclopropane 0. Isobutane 0. Butene-. Isobutylene 0. n-butane.,-butadiene balance. trans--butene. cis--butene. -Butyne (ethylacetylene) 0..,-Butadiene.. -Methyl--butene.. Isopentane 0.. Pentene-.. n-pentane Butyne (dimethylacetylene) 0. trans--pentene.. Isoprene 0. cis--pentene.. trans-,-pentadiene.. cis-,-pentadiene.. Benzene 0.. Toluene 0.. Dimer (-vinylcyclohexene-) GCPE00

97 energy and FUeLS applications,-butadiene purity gs-alumina - 0 m x 0. mm Helium,.0 ml/min (constant flow mode) C for min C/min to C C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Sample: 0. µl 0, 0 n-c 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0 refined Butadiene Standard Component gravimetric concentration (ppm). Acetylene 0.. Propane.. Propylene. Propadiene (allene).. Propyne (methylacetylene). Cyclopropane 0. Isobutane 0. Butene-. Isobutylene 0. n-butane.,-butadiene Balance. trans--butene. cis--butene. -Butyne (ethylacetylene) 0..,-Butadiene.. -Methyl--butene.. Isopentane 0.. Pentene-.. n-pentane Butyne (dimethylacetylene) 0. trans--pentene.. Isoprene 0. cis--pentene.. trans-,-pentadiene.. cis-,-pentadiene.. Benzene 0.. Toluene 0.. Dimer (-vinylcyclohexene-) GCPE0

98 energy and FUeLS applications extended hydrocarbon analysis I 0 gs-alumina - 0 m x 0. mm Helium at cm/s (. ml/min), measured at 00 C 00 C for min 00-0 C at C/min 0 C for 0. min 0-00 C at 0 C/min Injection: Split, 0 C Split ratio : Detector: FID, C Nitrogen makeup gas at ml/min Sample: 00 µl injection of 00 ppmv SUMMA canister mixture,,,, 0 0,, 0 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methane. Ethane. Ethylene. Propane. Propylene. Isobutane. Acetylene. n-butane. trans--butene 0. -Butene. cis--butene. Cyclopentane. Isopentane. n-pentane. Propyne.,-Butadiene. Cyclopentene. -Methyl--butene. trans--pentene 0. -Methyl--butene. -Pentene. cis--pentene. Methylcyclopentane.,-Dimethylbutane. Cyclohexane.,-Dimethylbutane. -Methylpentane. -Methylpentane. Isoprene 0. n-hexane. -Methyl--pentene. trans--hexene. -Methyl--pentene. cis--hexene.,-dimethylpentane. Methylcyclohexane.,-Dimethylpentane. -Methylhexane. -Methylhexane 0. n-heptane. Benzene. Isooctane (,,-trimethylpentane).,,-trimethylpentane. -Methylheptane. -Methylheptane. n-octane. Toluene. n-nonane. Ethylbenzene 0. m-xylene. p-xylene. o-xylene GCPE0

99 energy and FUeLS applications extended hydrocarbon analysis II gs-gaspro - 0 m x 0. mm Helium at 0 cm/s (. ml/min), measured at 0 C 0 C for 0. min 0- C at C/min C for min -0 C at C/min Injection: Split, 0 C Split ratio : Detector: FID, C Nitrogen makeup gas at ml/min Sample: 00 µl injection of 00 ppmv SUMMA canister mixture 0,,, 0,, 0 0, 0 0, Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methane. Ethane. Ethylene. Propane. Propylene. Isobutane. Acetylene. n-butane. trans--butene 0. -Butene. cis--butene. Cyclopentane. Isopentane. n-pentane. Propyne.,-Butadiene. Cyclopentene. -Methyl--butene. trans--pentene 0. -Methyl--butene. -Pentene. cis--pentene. Methylcyclopentane.,-Dimethylbutane. Cyclohexane.,-Dimethylbutane. -Methylpentane. -Methylpentane. Isoprene 0. n-hexane. -Methyl--pentene. trans--hexene. -Methyl--pentene. cis--hexene.,-dimethylpentane. Methylcyclohexane.,-Dimethylpentane. -Methylhexane. -Methylhexane 0. n-heptane. Benzene. Isooctane (,,-trimethylpentane).,,-trimethylpentane. -Methylheptane. -Methylheptane. n-octane. Toluene. n-nonane. Ethylbenzene 0. m-xylene. p-xylene. o-xylene. Styrene. Isopropylbenzene (cumene). n-propylbenzene.,,-trimethylbenzene.,,-trimethylbenzene GCPE0

100 energy and FUeLS applications refinery gas hp-plot al o S 0p-S 0 m x 0. mm,.00 µm Helium ml/min 00 C isothermal Injection: Split, 0 C Split ratio 00: Detector: FID, 0 C Sample: µl 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methane. Ethane. Ethylene. Propane. Propylene. iso-butane. n-butane. trans--butene. -Butene 0. cis- Butene. iso-pentane. n-pentane 0 0 GCPE0 Sulfur gas analysis in Light hydrocarbon Streams I gs-gaspro - 0 m x 0. mm Helium, 0 psig,.0 ml/min at 0 C 0 C for min, 0 C/min to 0 C and hold Injection: Split, 00 C Split ratio :0 PFPD A B C D E Sulfur compounds (PFPD) A. Carbonyl sulfide B. Hydrogen sulfide C. Sulfur dioxide D. Carbon disulfide E. Methyl mercaptan F. Ethyl mercaptan Detector: Two separate analyses under identical conditions on FID and PFPD F 0 FID Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, Methane. Ethane. Ethylene. Acetylene. Propane. Propylene. iso-butane. n-butane. -Butene/methyl acetylene 0. trans--butene.,-butadiene. cis--butene. iso-pentane. n-pentane GCPE0 0

101 energy and FUeLS applications Sulfur gas analysis in Light hydrocarbon Streams II gs-q - 0 m x 0. mm, 0.0 µm PFPD B EF Helium, 0 psig,. ml/min at 00 C 00 C for min, 0 C/min to 0 C and hold Injection: Split, 00 C Split ratio :0 A C D Sulfur compounds (PFPD) A. Hydrogen sulfide B. Carbonyl sulfide C. Methyl mercaptan D. Ethyl mercaptan E. Carbon disulfide Detector: Two separate analyses under identical conditions on FID and PFPD Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0 FID. Methane. Ethylene/acetylene. Ethane. Propylene. Propane. Methyl acetylene. iso-butane. -Butene.,-Butadiene 0. n-butane/cis--butene. trans--butene. iso-pentane. n-pentane 0 GCPE0 Sulfur Compounds in propylene ( ppm) Injection: Detector: Sample: gs-gaspro - 0 m x 0. mm 0 C for. min 0-0 C at 0 C/min OI Analytical Volatiles Inlet Split ratio : 00 µl gas sampling valve OI Analytical Model 0 PFPD ppm sulfur compounds in propylene 0. COS. H S. Propylene. CS. Methyl mercaptan. Ethyl mercaptan. Thiophene. Dimethyl sulfide. -Propanethiol 0. -Propanethiol. -Methyl--propanethiol. -Methyl--propanethiol. -Methyl--propnaethiol. -Butanethiol Chromatogram courtesy of OI Analytical 0 GCPE00

102 energy and FUeLS applications Mercaptans Injection: Detector: Sample: gs-gaspro - 0 m x 0. mm Helium at cm/s C for min -0 C at 0 C/min Split Split flow 0 ml/min FID 0. ml Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Ethyl mercaptan. -Propyl mercaptan. -Propyl mercaptan. -Methyl--propyl mercaptan. -Methyl-propyl mercaptan. -Methyl--propyl mercaptan. -Butyl mercaptan. -Pentyl mercaptan. -Hexyl mercaptan 0 GCPE0 Sulfur Compounds in natural gas Synthetic Mixture hp- 0Z-0 0 m x 0.0 mm, 0.0 µm Helium C for 0 min -00 C at C/min Injection: Split 00: Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0 Detector: FPD Sample: 0. ml 0. Hydrogen sulfide. Methyl mercaptan. Ethyl mercaptan. Dimethyl sulfide. Isopropyl mercaptan. tert-butyl mercaptan. n-propyl mercaptan. Thiophene and sec-butyl mercaptan. Isobutyl mercaptan 0. n-butyl mercaptan. tert-amyl mercaptan. Isoamyl mercaptan. n-amyl mercaptan. n-hexyl mercaptan. tert-dibutyl disulfide. n-octyl mercaptan 0 min GCPE0

103 energy and FUeLS applications Sulfur Compounds in naphtha hp-pona 0S-00 0 m x 0.0 mm, 0.0 µm Helium, cm/s C for min -0 C at C/min 0-0 C at C/min Injection: Split ratio 00:. Thiophene. Methyl thiophenes. Ethyl and dimethyl thiophenes. Benzothiophene Detector: FPD Sample: µl min GCPE0 aromatics analysis astm D analytes hp-innowax 0n- 0 m x 0. mm, 0.0 µm Helium at 0 psi, constant pressure mode C for 0 min C/min to 00 C 0 C/min to C Injection: Split, 0 C Split ratio 00: to 00: Detector: FID, 0 C Data acquisition rate at 0 Hz. Heptane. Cyclohexane. Octane. Nonane. Benzene. Decane. Toluene.,-Dioxane. Undecane 0. Ethylbenzene. p-xylene 0 0. m-xylene. Cumene. Dodecane. o-xylene. Propylbenzene. p-ethyltoluene. m-ethyltoluene. tert-butylbenzene 0. sec-butylbenzene. Styrene. Tridecane. Diethylbenzene isomer. Diethylbenzene isomer. n-butylbenzene. a-methylstyrene. Phenylacetylene GCPE0 aromatics analysis ethylbenzene Impurities hp-innowax 0n- 0 m x 0. mm, 0.0 µm Helium at 0 psi, constant pressure mode C for 0 min C/min to 00 C 0 C/min to C Injection: Split, 0 C Split ratio 00: to 00: Detector: FID, 0 C Data acquisition rate at 0 Hz 0. Benzene. Toluene. Undecane. Ethylbenzene. p-xylene. m-xylene. Isopropylbenzene. o-xylene. n-propylbenzene 0. p-ethyltoluene. m-ethyltoluene. s-butylbenzene. Diethylbenzene. Diethylbenzene GCPE0

104 energy and FUeLS applications Impurities in p-xylene astm D hp-innowax 0n- 0 m x 0. mm, 0.0 µm Helium, cm/s,. psi (0 C),. ml/min constant flow 0 C for min 0- C at C/min C for. min -0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio 00: Detector: FID, 0 C. Non-aromatic hydrocarbon. Toluene. Ethylbenzene. p-xylene. m-xylene. o-xylene Sample: 0. µl Neat, % GCPE0 ethylene oxide Synthetic Standard hp-plot Q 0p-Qo 0 m x 0. mm, 0.00 µm Helium, psi 0 C for min 0-0 C at C/min Injection: Split ratio 0: Detector: FID Sample: µl liquid injection sample 000 ppm v/v Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Ethylene oxide. -Chloropropene GCPE0

105 energy and FUeLS applications analysis of oxygenates in Mixed C Streams porabond Q pt Cppt m x 0. mm,.00 µm Instrument: Agilent 0A Series Helium, constant flow mode, cm/s, C -0 C at C min, 0-0 C at C/min, 0 C for 0 min Injection: 00 C, split ratio 0:, 00 µl gas sampling valve Detector: FID at 0 C. CH. C H. C H. MeOH. Mixed C. DME. EtOH. Mixed C. MTBE 0. ETBE Sample: 0-00 mg/l oxygenates in mixed C 0 0 min oxygenates in gasoline astm D (gc-ofid) hp- 0Z- 0 m x 0. mm,.00 µm Helium, 0 cm/s constant flow 0 C for min 0-0 C at C/min 0 C for min 0- C at C/min C for min Injection: Split ratio 0: Detector: Wasson ECE OFID Sample: 0. µl 0. Water. Methanol. Ethanol. -Propanol. t-butanol. -Propanol. MTBE. sec-butanol. DIPE 0. Isobutanol. ETBE. TAA.,-Dimethoxyethane. -Butanol. TAME 0 0 GCPE00

106 energy and FUeLS applications Denatured Fuel ethanol astm D0 hp- 0Z-0 00 m x 0. mm, 0.0 µm Helium cm/s C for min -0 C at C/min 0 C for 0 min Injection: Split ratio 00:. Methanol. n-butane. Ethanol. Isopentane. n-pentane. Other hydrocarbons Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl 0 0 GCPE0 pona Mix as Specified by afnor Method # DB-petro -0 0 m x 0.0 mm, 0.0 µm Helium at. cm/s, measured at C 0 C for min 0-0 C at. C/min 0-0 C at. C/min Injection: Split, 0 C Split ratio :00 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl petroleum reformate, 0,, 0, Ethane. Propane. n-butane. Ethanol. Isopentane. -Pentene. -Methyl--butene. n-pentane. -Methyl--butene 0.,-Dimethylbutane. -Cyclopentene. Cyclopentane.,-Dimethylbutane. -Methylpentane. -Methylpentane. -Methyl--pentene. n-hexane.,-dimethylpentane. Methylcyclopentane 0.,-Dimethylpentane. Benzene. -Methyl--cyclopentene. Isooctane. n-heptane. Toluene.,,-Trimethylpentane. -Methylheptane. -Methylheptane. n-octane 0. Ethylbenzene. m-xylene. p-xylene. o-xylene. n-nonane. n-propylbenzene.,,-trimethylbenzene.,,-trimethylbenzene. n-decane.,,-trimethylbenzene 0. Indan.,-Diethylbenzene. -Methyl--propylbenzene.,-Diethyl--ethylbenzene.,-Diethyl--ethylbenzene. n-undecane.,,,-tetramethylbenzene.,,,-tetramethylbenzene. Naphthalene. n-dodecane 0. -Methylnaphthalene. Tetradecane GCPE0

107 energy and FUeLS applications aromatics in Finished gasoline astm Method D DB m x 0. mm,.00 µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at C/min 0 C for min Injection: Split, 0 C Split ratio :00 Detector: Sample: MSD 0. µl unleaded gasoline Calibration standard: ASTM/EPA gasoline refinery aromatics (AccuStandard M-GRA-CAL/IS-SET). Methyl-tert-butyl-ether (MTBE). n-hexane. Benzene-d (IS). Benzene. Isooctane. n-heptane. Toluene. n-octane. Ethylbenzene-d0 (IS) 0. Ethylbenzene. m-xylene 0. p-xylene. o-xylene. n-propylbenzene. -Methyl--ethylbenzene. -Methyl--ethylbenzene.,,-Trimethylbenzene. -Methyl--ethylbenzene.,,-Trimethylbenzene 0. n-decane.,,-trimethylbenzene. Indan 0.,-Diethylbenzene. n-butylbenzene (valley).,-diethylbenzene.,,,-tetramethylbenzene.,,,-tetramethylbenzene. Naphthalene-d (IS). Naphthalene 0. n-dodecane. Pentamethylbenzene. -Methylnaphthalene. -Methylnaphthalene GCPE0 Simulated Distillation Injection: Detector: DB- - 0 m x 0. mm,.00 µm Helium at ml/min -0 C at C/min Direct FID Nitrogen makeup gas at 0 ml/min 0 Suggested Supplies Septum: Non-stick bleed and temperature optimized (BTO) septa, mm, 0/pk, - Liner: Direct connect, dual taper, deactivated, mm id, G-000 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. n-pentane. n-hexane. n-heptane. n-octane. n-nonane. n-decane. n-undecane. n-dodecane. n-tetradecane 0. n-pentadecane. n-hexadecane. n-heptadecane. n-octadecane. n-eicosane. n-tetracosane. n-octacosane. n-dotriacontane. n-hexatriacontane. n-tetracontane min GCPE0

108 energy and FUeLS applications reference gas oil DB- - 0 m x 0. mm,.00 µm Injection: Detector: Helium at ml/min -0 C at C/min Direct FID Nitrogen makeup gas at 0 ml/min Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, dual taper, deactivated, mm id, G-000 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - min GCPE0 regular Unleaded gasoline (California phase ) "normal" gc run I DB-petro -0a 00 m x 0. mm, 0.0 µm Hydrogen at cm/s C for. min - C at. C/min C for min -0 C at. C/min 0 C for min 0-0 C at. C/min 0 C for. min Injection: Split ratio :00 Detector: FID, 00 C Sample: 0. µl regular Unleaded gasoline (California phase ) "normal" gc run II DB m x 0.0 mm, 0.0 µm Hydrogen at. cm/s C for. min - C at. C/min C for. min -0 C at. C/min 0 C for. min 0-0 C at. C/min 0 C for. min Injection: Split ratio :00 Detector: FID, 00 C Sample: 0. µl Enlarged view at - min Compare resolution Enlarged view at - min GCPE0

109 energy and FUeLS applications gasoline Unleaded astm D Cp-Sil pona CB Cp0 00 m x 0. mm, 0.0 µm Sample: 0. µl Helium, 0 kpa (. bar, psi) C ( min) to 0 C, C/min Injection: Split, 0 ml/min Detector: FID 0 0 / 0. Propane. Isobutane. Butane. -Methylbutane. Pentane.,-Dimethylbutane.,-Dimethylbutane. -Methylpentane. -Methylpentane 0. Hexane.,-Dimethylpentane. Methylcyclopentane.,-Dimethylpentane. Benzene. -Methylhexane.,-Dimethylpentane. -Methylhexane. Tert. amyl methyl ether (TAME). Unknown 0.,-Dimethylhexane. Methylcyclohexane. Toluene. Octane. Ethylbenzene. p-xylene. m-xylene. o-xylene. Nonane. Decane 0.,,-Trimethylbenzene. Undecane 0 min VGC00 polyethylene DB- -0 m x 0. mm, 0. µm Helium at ml/min 0-0 C at 0 C/min Injection: Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl % solution in CS. n-c0. n-c0. n-c0. n-c0. n-c0. n-c0 0 min. pa Uncompensated baseline GCPE0

110 energy and FUeLS applications Diesel analysis Detector: vf-ht Fused Silica Cp0 m x 0. mm, 0.0 µm H, 0 kpa, 0. bar,. psi 0 C ( min), C to 0 C, C to 0 C, 0 C to 0 C FID -0. Volts 0. C0. C. C. C. C. C. C. C. C 0. C. C0. C. C. C. C. C. C. C VGC00 analysis of oxygenates in a C to C hydrocarbon Mix Lowox Cp 0 m x 0. mm, 0.00 µm Sample: µl Sample Conc: 0.0% per compound Solvent: Cyclohexane He,. kpa (0. bar,. psi) 0 C ( min) to 0 C, 0 C/min Injection: Split, T=0 C Detector: FID, T=0 C. Acetaldehyde. Diethyl ether. Ethyl tert-butyl ether. Methyl tert-butyl ether. Diisopropyl ether. Propionaldehyde (propanol). Tert-amyl methyl ether. Dipropyl ether. Isobutyraldehyde 0. Butyraldehyde. Methanol. Acetone. Isovaleraldehyde. Valeraldehyde. -Butanone. Ethanol. -Propanol. -Methyl--propanol (isobutanol). -Methyl--propanol (tert-butanol) 0. -Butanol 0 C C0 C C 0 0 min VGC00 00

111 energy and FUeLS applications analysis of process gas hp-plot Q pt 0p-Qopt 0 m x 0. mm, 0.00 µm Instrument: Agilent 0A Hydrogen, constant flow mode, 0 cm/s, C C for min, C to 0 C at 0 C/min, 0 C for min, 0 to 0 C at 0 C/min Injection: 0 C, split ratio :, 0 µl gas sampling loop Detector: TCD at 0 C 0. CO/air. Methane. Carbon dioxide. Ethylene. Ethane. Hydrogen sulfide. Propylene. Propane. Dimethyl ether 0. Methanol. Butylene. Butane min Detailed hydrocarbon analysis of petroleum naphthas through n-nonane Using astm D Cp-Sil pona for astm D Cp 0 m x 0. mm, 0.0 µm Sample: 0. µl Helium ºC (0 min) at ºC/min to 00 ºC (0 min) Injection: Split/splitless, full EFC control, 0 C, split 00 ml/min Detector: FID, 0 C 0. iso-pentane. Pentane. Cyclopentane. Hexane. Benzene. Heptane. Toluene. Octane. Ethylbenzene 0. p-xylene. m-xylene. o-xylene. Nonane. t-butylbenzene.,, Trimethylbenzene 0 min 0 VGC00 0

112 InDuStrIAL ChemICAL AppLICAtIonS Industrial Chemical Applications Alcohols I DB- - 0 m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of % each solvent in CS Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal kit, - Syringe: µl tapered, FN -s//hp, -. Methanol. Ethanol. Isopropanol. tert-butanol. -Propen--ol (allyl alcohol). -Propanol. -Propyn--ol (propargyl alcohol). sec-butanol. -Methyl--buten--ol 0. Isobutanol. -Methoxyethanol (methyl cellosolve). -Buten--ol. -Methyl--butanol (tert-amyl alcohol). -Butanol. -Buten--ol (crotyl alcohol). Ethylene glycol. -Penten--ol. -Pentanol. Glycidol 0. -Pentanol. -Ethoxyethanol (cellosolve). Propylene glycol. -Methyl--butanol (isoamyl alcohol). -Methyl--butanol (active amyl alcohol). -Methyl--pentanol. -Pentanol. -Penten--ol. -Methyl--buten--ol. Cyclopentanol 0. -Hexanol. -Hexanol. -Hydroxy--methyl--pentanone. Furfuryl alcohol. cis--hexen--ol. -Hexanol. cis--hexen--ol. Cyclohexanol. -Heptanol. -Heptanol 0. -Butoxyethanol (butyl cellosolve). cis--hepten--ol. trans--hepten--ol. -Heptanol. Benzyl alcohol. -Ethyl--hexanol. a-methylphenyl alcohol. -Octanol. -Nonanol. -Phenoxyethanol 0. a-ethylphenethyl alcohol. b-ethylphenethyl alcohol. -Decanol, CS,, 0,, 0,,,, 0, 0, GCIC00 0

113 InDuStrIAL ChemICAL AppLICAtIonS halogenated hydrocarbons I DB- - 0 m x 0. mm,.0 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at cm/s C for min - C at 0 C/min Injection: Split, 0 C Split ratio :0 Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal kit, - Syringe: 0 µl tapered, FN -s//hp, - Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min, 0 0,. Pentane. Iodomethane.,-Dichloroethene.,,-Trichlorotrifluoroethane (freon ). -Chloropropene (allyl chloride). Methylene chloride.,-dichloroethane. Chloroform.,,-Trichloroethane 0. -Chlorobutane. Carbon tetrachloride.,-dichloroethane.,-dichloropropane. cis-,-dichloropropene. trans-,-dichloropropene.,,-trichloroethane.,,,-tetrachloroethane.,-dibromoethane (EDB). -Chlorohexane 0. trans-,-dichloro--butene. Iodoform. Hexachlorobutadiene.,,-Trichloropropane.,,,-Tetrachloroethane. Pentachloroethane.,-Dibromo--chloropropane (DBCP). Hexachloroethane. Hexachlorocyclopentadiene GCIC0 0

114 InDuStrIAL ChemICAL AppLICAtIonS Aromatic Solvents DB m x 0. mm, 0. µm Helium at cm/s 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl of 0. µg/µl standard in hexane 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal kit, - Syringe: 0 µl tapered, FN -s//hp, GCIC0. Benzene. Toluene. Ethylbenzene. Chlorobenzene. p-xylene. m-xylene. o-xylene. Styrene. Isopropylbenzene 0. n-propylbenzene. -Chlorotoluene. -Chlorotoluene. -Chlorotoluene. tert-butylbenzene. sec-butylbenzene. Isobutylbenzene.,-Dichlorobenzene.,-Dichlorobenzene. n-butylbenzene 0.,-Dichlorobenzene.,-Diisopropylbenzene.,-Diisopropylbenzene. -Nitrotoluene. -Nitrotoluene. -Nitrotoluene phenols I hp-ms 0S- 0 m x 0. mm, 0. µm Helium, cm/s, constant flow C for min -0 C at C/min Injection: Splitless, 0 C Detector: FID, 00 C Sample: µl 0 µg/ml phenols in methylene chloride Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal kit, - Syringe: 0 µl tapered, FN -s//hp, - 0. Phenol. -Chlorophenol. -Nitrophenol.,-Dimethylphenol.,-Dichlorophenol. -Chloro--methylphenol.,,-Trinitrophenol.,-Dinitrophenol. -Nitrophenol 0. -Methyl-,-dinitrophenol. Pentachlorophenol GCIC0 0

115 InDuStrIAL ChemICAL AppLICAtIonS Inorganic gases gs-gaspro - 0 m x 0. mm Helium at cm/s C for min -00 C at 0 C/min 00 C hold Injection: Split, 00 C Split ratio :0 Detector: TCD, 0 C Sample: 0 µl. Nitrogen. CO. SF. COS. H S. Ethylene oxide. SO Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal kit, - 0 GCIC0 Alcohols II DB-wAXetr - 0 m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio : Detector: FID, 0 C Nitrogen makeup gas at ml/min Sample: µl of 0.% each solvent in CS CS,,,, 0 0 0,,. Methanol. Ethanol. Isopropanol. tert-butanol. -Propen--ol (allyl alcohol). -Propanol. -Propyn--ol (propargyl alcohol). sec-butanol. -Methyl--buten--ol 0. Isobutanol. -Methoxyethanol (methyl cellosolve). -Buten--ol 0 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal kit, - Syringe: µl tapered, FN -s//hp, -. -Methyl--butanol (tert-amyl alcohol). -Butanol. -Buten--ol (crotyl alcohol). Ethylene glycol. -Penten--ol. -Pentanol. Glycidol 0. -Pentanol. -Ethoxyethanol (cellosolve). Propylene glycol. -Methyl--butanol (isoamyl alcohol). -Methyl--butanol (active amyl alcohol). -Methyl--pentanol. -Pentanol. -Penten--ol. -Methyl--buten--ol. Cyclopentanol 0. -Hexanol. -Hexanol. -Hydroxy--methyl--pentanone. Furfuryl alcohol. cis--hexen--ol. cis--hexen--ol. Cyclohexanol. -Heptanol. -Heptanol. -Butoxyethanol (butyl cellosolve) 0. cis--hepten--ol. trans--hepten--ol. -Heptanol. Benzyl alcohol. -Ethyl--hexanol. -Octanol. -Nonanol. -Phenoxyethanol. a-ethylphenethyl alcohol. b-ethylphenethyl alcohol 0. -Decanol GCIC00 0

116 InDuStrIAL ChemICAL AppLICAtIonS Alcohols III Injection: Split, 0 C Split ratio : Detector: FID, 0 C Sample: µl hp-innowax 0n- 0 m x 0. mm,.00 µm Helium, cm/s,.0 psi ( C) C for min -0 C at 0 C/min ml/min constant flow GCIC00. -Propanol. iso-butanol. -Methyl--pentanol. -Butanol. -Methyl--pentanol. -Pentanol. -Ethyl--butanol. -Hexanol. Cyclohexanol 0. -Heptanol Analysis of Amino Alcohols in water Cp-Sil CB Cp0 0 m x 0. mm,.00 µm Sample: 0. µl Sample Conc: ppm Solvent: Water He, 0. ml/min, 0 kpa (0. bar, psi) C to 00 C, 0 C/min Injection: Splitless Detector: MS 0 min 0. -Amino-ethanol. -Amino--propaol. -(Ethylamino)-ethanol. -Amino--butanol. -Amino--pentanol VGC00 Courtesy of Victor Berezkin and Aleksey B. Lapin, Institute of Petrochemical Synthesis, Russian Academy of Science, Moscow, Russia Amines and Alcohols Cp-Volamine Cp m x 0. mm Sample: 0. µl Sample Conc: 000 ppm, approx. ng per component on the column Solvent: Methanol Helium, 0 kpa, cm/s C (0. min) to 0 C, 0 C/min Injection: Split Detector: MS Courtesy of J. Luong, Dow Chemical Canada 0 min VGC00. Methanol. IPA. Mono ethylene glycol. MMEA methyl monoethanolamine. Diethanolamine. MDEA methyl diethanolamine 0

117 InDuStrIAL ChemICAL AppLICAtIonS Analysis of ethanolamines Cp-Sil CB for Amines Cp 0 m x 0. mm,.00 µm Sample Conc: -0 ng per component on the column Solvent: Methanol Injection: Helium, 0 kpa (0. bar, psi) 0 C ( min) to 0 C, C/min Split. MEA (mono-ethanolamine). DEA (di-ethanolamine). TEA (tri-ethanolamine) Detector: FID 0 min VGC000 ethoxyethanol hp-ffap 0F- 0 m x 0. mm,.00 µm Helium, 0 ml/min 0 C for min 0-00 C at C/min 00-0 C at 0 C/min Injection: Split ratio 0: Detector: TCD Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - GCIC00. Ethylene oxide. Ethyl formate. Ethyl alcohol. Water. -Ethoxyethanol. -Ethoxyethyl acetate. Hydroxy acetate. Acetic acid. Formic acid 0. Ethylene glycol/monoformate. Ethylene glycol/monoacetate organic Acids DB-wAXetr - 0 m x 0. mm,.00 µm Helium at cm/s, measured at 0 C C for min -0 C at C/min 0 C for min Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Injection: Split, 0 C Detector: FID, 0 C. Acetic acid. Propionic acid. Isobutyric acid. Butyric acid. Isovaleric acid. Valeric acid (pentanoic acid). Isocaproic acid. Caproic acid (hexanoic acid). Heptanoic acid GCIC00 0

118 InDuStrIAL ChemICAL AppLICAtIonS Free organic Acids/C -C Isomers hp-innowax 0n- 0 m x 0. mm, 0. µm Helium cm/s, psi (0 C). ml/min constant flow 0 C for min 0- at C/min -0 C at C/min Injection: Split, 0 C Split ratio 0: Detector: FID, 00 C Sample: µl Isobutyric acid. Butyric acid. Valerolactone. -Methyl butyric acid. Valeric acid. -Pentenoic acid. trans--methyl--butenoic acid. trans--pentenoic acid. trans--pentenoic acid GCIC00 Volatile Amines Sampler: DB m x 0. mm,.00 µm 0 C isothermal Headspace. Methylamine. Dimethylamine. Trimethylamine Injection: Split ratio :0 Detector: FID Nitrogen makeup gas at 0 ml/min min GCIC00 trace Active Amines, 0 ng on-column hp-ms 0S- 0 m x 0. mm,.00 µm Injection: Helium, constant pressure. psi C for 0. min -0 C at 0 C/min 0-0 C at C/min 0 C for min On-column Oven tracking mode Detector: FID, 00 C Sample: 0. µl of each standard in methanol hp-ms pa pa Ethanolamine 0 0 FID A, (AMNCOL00000.D) non-agilent % phenyl amines column Ethanolamine Butylbenzene Butylbenzene Nonylamine Nonylamine Triethanolamine Triethanolamine 0 0 GCIC00 0

119 InDuStrIAL ChemICAL AppLICAtIonS primary Amines Injection: Detector: CAm - 0 m x 0. mm, 0. µm Hydrogen at 0 cm/s 0 C isothermal Split FID Nitrogen makeup gas at 0 ml/min. n-octylamine. n-nonylamine. n-decylamine. Benzylamine. Dicyclohexylamine min GCIC00 polyethyleneamines DB-ms - 0 m x 0. mm, 0.0 µm Helium at 0 cm/s, measured at 00 C 00 C for min 00-0 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 00 ng/µl standard in methanol. Ethylenediamine. Diethylenetriamine. Triethylenetetramine.* Branched and piperazine analogs of peak. Tetraethylenepentamine.* Branched and piperazine analogs of peak * * * * * * 0 0. GCIC00 0

120 InDuStrIAL ChemICAL AppLICAtIonS Amines and nitriles DB-ms - 0 m x 0. mm, 0.0 µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 00 ng/µl standard in methanol Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -, 0, 0, 0. Diethylamine. Propionitrile. Diisopropylamine. Triethylamine. Pyridine. Pyrimidine. Pyrazole. Acrylamide. Pyridazine 0. Aniline. -Bromopyridine. Benzonitrile. -Cyanopyridine. Benzylamine. n-octylamine. -Methyl--pyrrolidine. N,N-Dimethylbenzylamine. Phenylethylamine. N-Benzylmethylamine 0. -Cyanopyridine. -Chloroaniline. n-nonylamine.,-dimethylaniline. -Chlorobenzonitrile.,-Dimethylaniline. -Chloroaniline. -Chloroaniline. N,N-Diethylaniline. n-decylamine 0. -Bromoaniline.,-Diaminotoluene.,-Diethylaniline. -Nitroaniline. Dicyclohexylamine.,-Dichloroaniline. -Nitroaniline. -Nitroaniline. Diphenylaniline GCIC0 0

121 InDuStrIAL ChemICAL AppLICAtIonS Amines in water CAm - 0 m x 0. mm, 0. µm Injection: Detector: Hydrogen at cm/s 0-0 C at 0 C/min Split FID Nitrogen makeup gas at 0 ml/min. Ethylenediamine. Piperazine. Diethylenetriamine. N-(-Aminoethyl) piperazine. Aminoethylethanolamine. Triethylenetetramine ( isomers). Tetraethylenepentamine ( isomers) 0 min GCIC0 Aldehydes and Acids hp-innowax 0n- 0 m x 0. mm, 0.0 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium, 0 cm/s,. psi (0 C) 0 C for min 0-0 C at 0 C/min. ml/min constant flow Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Injection: Split, 0 C Split ratio 0: Detector: FID, C Sample: 0. µl 0. Butanal. -Methyl butanal. Pentanal. Hexanal. Heptanal. Octanal. Acetic acid. Decanal. Propanoic acid 0. iso-butyric acid. Butyric acid. iso-valeric acid. Valeric acid. Hexanoic acid. Heptanoic acid. Octanoic acid. Decanoic acid GCIC0

122 InDuStrIAL ChemICAL AppLICAtIonS Aldehydes and Ketones DB m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - DB-wAX -0 0 m x 0. mm, 0.0 µm Helium at cm/s, measured at 0 C Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min DB- 0,, 0 0,. Acetaldehyde. Acrolein. Acetone. Propionaldehyde. Isobutyraldehyde. Methacrolein. Butyraldehyde. -Butanone (MEK). Crotonaldehyde 0. -Methyl--butanone. -Pentanone. -Pentanone. Valeraldehyde (pentanal). -Methyl--pentanone (MIBK). -Methyl--pentanone. -Hexanone. Cyclopentanone. -Hexanone. Hexanal 0. Furfural. -Heptanone. -Heptanone. -Heptanone. Cyclohexanone. Heptanal. Benzaldehyde. Octyl aldehyde. o-tolualdehyde. m-tolualdehyde 0. p-tolualdehyde. Nonyl aldehyde DB-WAX,, DB- provides the best overall resolution; however, DB-wAX provides better resolution of o- and m-tolualdehyde., GCIC0

123 InDuStrIAL ChemICAL AppLICAtIonS Formaldehyde underivatized DB-wAX -0 0 m x 0. mm, 0.0 µm Helium at cm/s, measured at C C isothermal Injection: Split, 00 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min *. Formaldehyde. Methanol * Formaldehyde by-products * 0 0 GCIC0 Formaldehyde-Dnph Derivative DB- -0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0-0 C at 0 C/min Injection: Split, 00 C Split ratio :00 Detector: ECD, C Nitrogen makeup gas at ml/min Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Formaldehyde-DNPH 0 GCIC0

124 InDuStrIAL ChemICAL AppLICAtIonS pfbha Derivative DB- -0 m x 0. mm, 0. µm Helium at 0 cm/s, measured at 0 C 0-00 C at 0 C/min Injection: Split, 0 C Split ratio :00 Detector: FID, C Nitrogen makeup gas at ml/min 0 GCIC0. Formaldehyde-PFBHA Aromatics I DB m x 0. mm,.00 µm CS Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min,,,,, 0, 0,,, 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Benzene. Fluorobenzene. Toluene. Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. Styrene. o-xylene 0. Isopropylbenzene (cumene). Bromobenzene. Propylbenzene. -Chlorotoluene. -Chlorotoluene. -Chlorotoluene.,,-Trimethylbenzene (mesitylene). a-methylstyrene. tert-butylbenzene.,,-trimethylbenzene (pseudocumene) 0. -Methylstyrene.,-Dichlorobenzene.,-Dichlorobenzene. Isobutylbenzene. sec-butylbenzene.,,-trimethylbenzene (hemimellitene).,-dichlorobenzene. Iodobenzene. Styrene oxide. Butylbenzene 0. -Chlorostyrene. Nitrobenzene. -tert-butyltoluene.,,-trichlorobenzene. -Nitrotoluene.,-Diisopropylbenzene.,-Diisopropylbenzene.,,-Trichlorobenzene. -Nitrotoluene. -Nitrotoluene 0.,,-Trichlorobenzene. -Chloro--nitrobenzene.,,,-Tetrachlorobenzene. Pentachlorobenzene GCIC0

125 InDuStrIAL ChemICAL AppLICAtIonS Aromatics II DB-wAX -0 0 m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min 0 0 CS 0 See below for enlarged view 0 0, Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - 0,,, 0. Benzene. Fluorobenzene. Toluene. Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. Styrene. o-xylene 0. Isopropylbenzene (cumene). Bromobenzene. Propylbenzene. -Chlorotoluene. -Chlorotoluene. -Chlorotoluene.,,-Trimethylbenzene (mesitylene). a-methylstyrene. tert-butylbenzene.,,-trimethylbenzene (pseudocumene) 0. -Methylstyrene.,-Dichlorobenzene.,-Dichlorobenzene. Isobutylbenzene. sec-butylbenzene.,,-trimethylbenzene (hemimellitene).,-dichlorobenzene. Iodobenzene. Styrene oxide (peak not shown). Butylbenzene 0. -Chlorostyrene. Nitrobenzene. -tert-butyltoluene.,,-trichlorobenzene. -Nitrotoluene.,-Diisopropylbenzene.,-Diisopropylbenzene.,,-Trichlorobenzene. -Nitrotoluene. -Nitrotoluene 0.,,-Trichlorobenzene. -Chloro--nitrobenzene.,,,-Tetrachlorobenzene. Pentachlorobenzene 0 GCIC0

126 InDuStrIAL ChemICAL AppLICAtIonS Impurities in Styrene DB-wAXetr - 0 m x 0. mm, 0.0 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at. cm/s, measured at 0 C Liner: Split, single taper, low pressure drop, glass wool, - 0 C isothermal Injection: Split, 0 C Split ratio :0 Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Detector: FID, 0 C 0. Benzene. Toluene. Ethylbenzene. p-xylene. m-xylene. Isopropylbenzene. o-xylene. n-propylbenzene. Styrene 0. a-methylstyrene. Heptane (IS) GCIC00 Impurities in ethylbenzene hp-innowax 0n- 0 m x 0. mm, 0.0 µm Helium, cm/s,. psi (0 C). ml/min constant flow 0 C for min 0- C at C/min C for. min -0 C at 0 C/min Injection: Split, 0 C Split ratio 00: ASTM Method D00 Detector: FID, 0 C Sample: 0. µl Neat, %+ 0. Hydrocarbon. Benzene. Toluene. Ethylbenzene. p-xylene. m-xylene. Cumene. o-xylene. Propylbenzene 0. Styrene GCIC0

127 InDuStrIAL ChemICAL AppLICAtIonS pyrolysates of polystyrene ultra 0A-0 0 m x 0.0 mm, 0. µm Helium, 0 psi, ml/min 0-0 at C/min Injection: Split, 0 C Split ratio 0: Pyrolyzer 00 C Detector: FID, 00 C Sample: 00 mg pyrolyzed 0. Propylene. Propane. -Butene. Butene. Pentane. Toluene. Styrene. C H -C(Ph) = CH. C H -CH CH -Ph 0. C H -C(Ph) = CH. C H -CH=C(Ph)CH. Styrene dimer. Styrene trimer GCIC0 esters I DB m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min, CS 0 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Methyl formate. Ethyl formate. Methyl acetate. Vinyl acetate. Ethyl acetate. Propyl formate. Methyl propionate. Isopropyl acetate. Ethyl acrylate 0. tert-butyl acetate. Ethyl propionate. Propyl acetate. sec-butyl acetate. Isobutyl acetate. Propyl propionate. Butyl acetate. Isoamyl acetate. Amyl acetate. -Ethoxyethyl acetate 0. -Methylbutyl acetate. Methyl benzoate. Benzyl acetate. Ethyl benzoate. Propyl benzoate GCIC0

128 InDuStrIAL ChemICAL AppLICAtIonS esters II DB- - 0 m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min, CS, 0, 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Methyl formate. Ethyl formate. Methyl acetate. Vinyl acetate. Ethyl acetate. Propyl formate. Methyl propionate. Isopropyl acetate. Ethyl acrylate 0. tert-butyl acetate. Ethyl propionate. Propyl acetate. sec-butyl acetate. Isobutyl acetate. Propyl propionate. Butyl acetate. Isoamyl acetate. Amyl acetate. -Ethoxyethyl acetate 0. -Methylbutyl acetate. Methyl benzoate. Benzyl acetate. Ethyl benzoate. Propyl benzoate GCIC0 esters III hp-innowax 0n- 0 m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium cm/s,.0 psi ( C) ml/min constant flow C for min -00 C at C/min Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - Injection: Split, 0 C Split ratio : Detector: FID, 0 C Sample: µl 0. Ethyl propionate. Propyl acetate. Ethyl butyrate. Propyl propionate. Propyl butyrate. Ethyl valerate. Butyl propionate. Propyl valerate. Ethyl caproate 0. Butyl valerate. Propyl caproate. Methyl decanoate. Butyl caproate. Methyl dodecanoate. Butyl heptanoate. Methyl tetradecanoate. Methyl hexadecanoate. Methyl octadecanoate. Methyl eicosenoate GCIC0

129 InDuStrIAL ChemICAL AppLICAtIonS ethers,, CS DB- - 0 m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min 0 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Furan. Ethyl vinyl ether. Ethyl ether.,-dioxalane. Methyl-tert-butyl ether (MTBE). Allyl ethyl ether. Isopropyl ether. Tetrahydrofuran (THF). tert-amyl methyl ether 0. Butyl methyl ether. Glyme (propylene glycol dimethyl ether). tert-amyl methyl ether. Diglyme (diethylene glycol dimethyl ether). Propyl ether. Allyl ether.,-dioxane. Butyl ethyl ether. Epichlorohydrin. Tetrahydropyran 0. Acetal (acetaldehyde diethyl acetal). Butyl ether. Pentyl ether. Triglyme (triethylene glycol dimethyl ether). Benzyl ether GCIC0 glycols I DB-wAX -0 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Injection: Megabore direct, 0 C Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - Sample: µl. Ethylene glycol monomethyl ether. Ethylene glycol monoethyl ether.,-propandiol.,-propandiol (propylene glycol).,-butandiol,.,-butandiol 0,. Ethylene glycol monobutyl ether. Diethylene glycol monomethyl ether.,-butandiol 0. Diethylene glycol monoethyl ether. Dipropylene glycol.,-pentandiol.,-hexandiol.,-heptandiol. Diethylene glycol monobutyl ether.,-octandiol.,-nonandiol. Ethylene glycol.,0-decandiol GCIC0

130 InDuStrIAL ChemICAL AppLICAtIonS glycols II DB- - 0 m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min EtOH,, 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, dual taper, deactivated, mm id, G-000 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Ethylene glycol monomethyl ether. Glyme. Ethylene glycol. Diglyme. Ethylene glycol monoethyl ether.,-propanediol.,-propanediol (propylene glycol).,-butanediol.,-butanediol 0. Ethylene glycol monobutyl ether.,-butanediol. Diethylene glycol monomethyl ether. Diethylene glycol. Diethylene glycol monoethyl ether.,-pentanediol.,-hexanediol. Diethylene glycol monobutyl ether. Triglyme.,-Heptanediol 0.,-Octanediol.,-Nonanediol.,0-Decanediol GCIC0 glycols III DB m x 0. mm,. µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Liner: Direct connect, dual taper, deactivated, mm id, G-000 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - Injection: Split, 0 C Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: µl,, 0,. Ethylene glycol monomethyl ether. Ethylene glycol monoethyl ether.,-propanediol.,-propanediol.,-butanediol.,-butanediol. Ethylene glycol monobutyl ether. Diethylene glycol monomethyl ether.,-butanediol 0. Diethylene glycol monoethyl ether. Dipropylene glycol.,-pentanediol.,-hexanediol.,-heptanediol. Diethylene glycol monobutyl ether.,-octanediol.,-nonanediol. Ethylene glycol.,0-decanediol GCIC00 0

131 InDuStrIAL ChemICAL AppLICAtIonS triethylene glycol and Impurities DB m x 0. mm,. µm Helium at cm/s, measured at 0 C 0 C isothermal Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Ethylene glycol. Diethylene glycol. Triethylene glycol 0 0 GCIC0 ethylene glycol mixture ultra 0A-0 m x 0.0 mm, 0. µm Helium, cm/s 00 C for 0. min C at 0 C/min Injection: Split, 0 C Split ratio 00: Detector: FID Sample: µl Suggested Supplies Septum: mm Advanced Green septa, - Liner: Liner, splitless, single-taper, glass wool, deactivated, 0- Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. Diethylene glycol. Triethylene glycol. Polyethylene glycol 00. Polyethylene glycol 00. Polyethylene glycol 00 min GCIC0

132 InDuStrIAL ChemICAL AppLICAtIonS glycols/diols hp- 0Z-0 0 m x 0. mm, 0. µm Helium 0 C for min 0-0 C at C/min Injection: On-column Detector: FID, 0 C Sample: µl. Ethylene glycol.,-butandiol. Ethylene glycol phenyl ether.,-hepatanediol.,-nonanediol.,0-decanediol 0 min GCIC0 halogenated hydrocarbons II DB m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at cm/s, measured at C Liner: General purpose split/splitless liner, taper, glass wool, - C for min - C at 0 C/min C for min Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample:, In pentane,, 0 0,,,,,, 0.,,-Trichlorotrifluoroethane (freon ).,-Dichloroethene. Bromoethane (ethyl bromide). Iodomethane. -Chloropropene (allyl chloride). -Chlorobutane.,-Dichloropropane. trans-,-dichloroethene.,,-trichloroethane 0. Carbon tetrachloride. Methylene chloride. Trichloroethene. Chloroform. Tetrachloroethene.,-Dichloropropane. -Chlorohexane. Bromochloromethane.,-Dichloroethane.,-Dichloroethane 0. Iodoform. cis-,-dichloropropene. Dibromomethane. Bromodichloromethane.,-Dichloropropane.,-Dichloropropane. trans-,-dichloropropene.,,-trichloroethane.,-dibromoethane (EDB).,,,-Tetrachloroethane 0. Pentachloroethane. Hexachloroethane. Bromoform. trans-,-dichloro--butene.,,-trichloropropane. Hexachlorobutadiene.,,,-Tetrachloroethane.,-Dibromo--chloropropane (DBCP). Hexachlorocyclopentadiene min GCIC0

133 InDuStrIAL ChemICAL AppLICAtIonS Chlorinated Isooctane hp-innowax 0n- 0 m x 0. mm, 0. µm Helium, cm/s,. psi (0 C) ml/min 0 C isothermal Injection: Split, 0 C Split ratio 0: Detector: FID, 00 C Sample: Monochloro isomers, 0. µl Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. -Chloro isooctane. -Chloromethyl,'-dimethyl pentane. -Chloro isooctane. -Chloro isooctane GCIC0 Solvents I DB-wAXetr - 0 m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at C/min Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - Injection: Split, 0 C Detector: FID, 0 C,, 0, Methylpentane. Hexane. Isooctane. Methyl-tert-butyl ether (MTBE). Heptane. Cyclohexane. Octane. Nonane. Methanol 0. Ethanol. Benzene. Decane. Toluene. Undecane. Ethylbenzene. p-xylene. m-xylene. Cumene. Dodecane 0. o-xylene. Propylbenzene. Chlorobenzene. Mesitylene. Styrene.,,-Trimethylbenzene. Naphthalene. -Chlorotoluene.,-Dichlorobenzene.,-Dichlorobenzene 0.,-Dichlorobenzene GCIC0

134 InDuStrIAL ChemICAL AppLICAtIonS Solvents II DB-wAXetr - 0 m x 0. mm,.00 µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :00 Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -, 0 0 GCIC0. Hexane. Isooctane. Acetone. Ethyl formate. Tetrahydrofuran. Trichloroethane. Ethyl acetate. Isopropyl acetate. Methyl ethyl ketone 0. Isopropyl alcohol. Methylene chloride. Benzene. -Pentanone. Methyl isobutyl ketone. Isobutyl acetate. Chloroform. sec-butyl alcohol. Toluene. n-propanol Solvents III DB m x 0. mm, 0.0 µm Helium at cm/s C for min - C at 0 C/min Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl of µg/µl standard in water,,, 0 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Methanol. Ethanol. Ethyl ether. Isopropanol. n-hexane. Methylene chloride. tert-butanol. n-propanol. Chloroform 0. Cyclohexane. sec-butanol. n-heptane. Acetone. Acetonitrile. Benzene. Tetrahydrofuran (THF). Trichloroethylene. n-butanol. Ethyl acetate 0. Methyl ethyl ketone (MEK). Toluene.,-Dioxane. Pyridine. Dimethylformamide (DMF) 0 0 GCIC0

135 InDuStrIAL ChemICAL AppLICAtIonS Solvents IV Injection: hp- 0Z-0 0 m x 0.0 mm, 0.0 µm Helium, 0 psi 0-00 C at C/min 00 C for min Split Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Detector: TCD Sample: µl 0. Isopropanol. Methyl ethyl ketone. Ethyl acetate. n-butyl alcohol. Ethyl cellosolve. Methyl isobutyl ketone. Toluene. n-butyl acetate. Diacetone alcohol 0. p-xylene. Cellosolve acetate. o-xylene. Butyl cellosolve. Butyl cellosolve acetate min GCIC00 Solvents porabond Q pt Cppt m x 0. mm,.00 µm Helium,. ml/min 0 C to 0 C at 0 C/min 0 C for min 0 C to 0 C at C/min 0 C for min Injection: Split, 0 C, split ratio :0 Detector: MSD, 0 C transfer line Full scan at m/z 0-0 Sample: µl Methyl alcohol. Acetaldehyde. Ethanol. Acetonitrile. Acetone. Methylene chloride. Isopropyl alcohol. -Propanamine. Ethyl formate 0. -Propanol. Ethyl ether. -Pentene. Pentane. tert-butyl alcohol. Isobutyraldehyde. Trichloromethane. Ethyl acetate. sec-butyl alcohol. -Butanol 0. Benzene. Hexane.,-Dioxane. Ethyl tert-butyl ether. Pyridine. N,N-dimethylformamide. N-Propyl acetate. -Methyl--butanol. n-propyl ether. -Pentanol 0. Toluene. Heptane. N,N-dimethylacetamide. Chlorobenzene. Ethylbenzene. m-xylene. p-xylene. o-xylene

136 InDuStrIAL ChemICAL AppLICAtIonS Analysis of Solvents porabond Q Cp m x 0. mm, 0.00 µm Sample: µl Sample Conc: 0.% per compound Solvent: DMSO He, kpa (0. bar,. psi) 00 C ( min) to 00 C, C/min Injection: Split, T=0 C Detector: FID, T=0 C 0, 0. Methane. Methanol. Ethanol. Acetonitrile. Acetone. Dichloromethane. -Propanol. Dimethyl sulfide. Diethyl ether 0. -Propanol. Pentane. -Butanone. Trichloromethane. Tetrahydrofuran. Ethyl acetate. -Methoxyethanol. Isobutanol. Butanol. Hexane 0. Benzene. Trichloroethylene. Cyclohexane.,-Dioxane. Pyridine. N,N-dimethylformamide. Dimethyl sulfoxide 0 min VGC00 nitrogen-based Solvents I DB m x 0. mm,.00 µm Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - CS 0. Acetonitrile. Acrolein. Acrylonitrile. Propionitrile. Methacrolein. Methacrylonitrile. Triethylamine. Ethyl acrylate. Pyridine 0. DMF (dimethylformamide). DMSO (dimethyl sulfoxide). Benzonitrile. -Methyl--pyrrolidinone 0 0 GCIC0

137 InDuStrIAL ChemICAL AppLICAtIonS nitrogen-based Solvents II DB- - 0 m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at 0 cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min CS Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - 0. Acetonitrile. Acrolein. Acrylonitrile. Propionitrile. Methacrolein. Methacrylonitrile. Triethylamine. Ethyl acrylate. Pyridine 0. DMF (dimethylformamide). DMSO (dimethyl sulfoxide). Benzonitrile. -Methyl--pyrrolidinone GCIC0 Acrylate Impurities I DB m x 0. mm,.00 µm Helium at. cm/s, measured at C C for min, -00 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Methyl acrylate impurities Ethyl acrylate impurities Butyl acrylate impurities GCIC0. Methanol. Ethanol. Methyl acetate. Ethyl acetate. Methyl acrylate. Methyl propionate. Isobutanol. Butanol. Ethyl acrylate 0. Ethyl propionate. Methyl methacrylate. Isopropyl acrylate. Isobutyl acetate. Butyl acetate. Isobutyl acrylate. Dibutyl ether. Isobutyl propionate. Butyl acrylate. Butyl propionate

138 InDuStrIAL ChemICAL AppLICAtIonS Acrylate Impurities II DB m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at. cm/s, measured at C C for min, -00 C at 0 C/min Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, - Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C 0 Methyl acrylate impurities Ethyl acrylate impurities Butyl acrylate impurities. Methanol. Ethanol. Methyl acetate. Ethyl acetate. Methyl acrylate. Methyl propionate. Isobutanol. Butanol. Ethyl acrylate 0. Ethyl propionate. Methyl methacrylate. Isopropyl acrylate. Isobutyl acetate. Butyl acetate. Isobutyl acrylate. Dibutyl ether. Isobutyl propionate. Butyl acrylate. Butyl propionate 0 0 GCIC0 Acrylates hp-ffap 0F- 0 m x 0. mm,.00 µm Hydrogen Injection: On-column Detector: FID Sample: µl C for min -0 C at 0 C/min 0-0 C at C/min. Methyl methacrylate. Ethyl methacrylate. sec-butyl methacrylate. Allyl acrylate. n-butyl acrylate. Hexyl methacrylate. Cyclohexyl methacrylate. Hydroxypropyl acrylate. Unknown min GCIC0

139 InDuStrIAL ChemICAL AppLICAtIonS Anilines DB-ms - m x 0.0 mm, 0. µm Helium at cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for 0 min Injection: Splitless, 0 C 0.0 min purge activation time Detector: FID, 0 C Nitrogen makeup gas at 0 ml/min Sample: µl of ng on-column per component 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Splitless, single taper, deactivated, mm id, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, GCIC00. o-toluidine. -Chloroaniline. -Methoxy--methylaniline.,,-Trimethylaniline. -Chloro--methylaniline.,-Diaminotoluene.,-Diaminoanisole. -Aminonaphthalene. -Methyl--nitroaniline 0., -Oxydianiline., -Methylenedianiline. Benzidine. -Aminoazotoluene. o-tolidine., -Thiodianiline., -Dimethoxybenzidine., -Dichlorobenzidine Substituted Anilines DB-ms - 0 m x 0. mm, 0.0 µm Helium at. cm/s, measured at 0 C 0 C for min 0-0 C at C/min 0 C for 0 min Injection: Splitless, 0 C 0 s purge activation time Detector: Sample: MSD, C transfer line µl of ng/µl standard 0 Suggested Supplies 0 0 Septum: mm Advanced Green septa, - Liner: Splitless, single taper, deactivated, mm id, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - GCIC0 m/z. Aniline. -Chloroaniline.,-Dimethylaniline. -Chloroaniline. -Chloroaniline. -Bromoaniline. -Nitroaniline.,-Dichloroaniline. -Nitroaniline 0.,,-Trichloroaniline. -Chloro--nitroaniline. -Nitroaniline. -Chloro--nitroaniline.,-Dichloro--nitroaniline. -Chloro-,-dinitroaniline.,-Dibromo--nitroaniline.,-Dinitroaniline. -Bromo-,-dinitroaniline

140 InDuStrIAL ChemICAL AppLICAtIonS phenols II DB-ms - 0 m x 0. mm, 0.0 µm Helium at cm/s, measured at 00 C 00 C for min 00-0 C at 0 C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 0 ng/µl standard in toluene/p-xylene Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -,, 0. Phenol. -Chlorophenol. o-cresol. m-cresol. p-cresol.,-xylenol.,-xylenol.,-xylenol. -Nitrophenol 0.,-Xylenol.,-Xylenol.,-Dichlorophenol.,-Xylenol.,,-Trichlorophenol.,-Dinitrophenol. -Naphthol 0 0 GCIC0 phenols III DB-wAX -0 0 m x 0. mm, 0. µm Hydrogen at cm/s C isothermal Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -, 0,.,-Xylenol. -Cresol. Phenol. -Ethylphenol.,-Xylenol. -Cresol.,-Xylenol. -Cresol. -Isopropylphenol 0.,-Xylenol.,-Xylenol. -Ethylphenol.,-Xylenol.,,-Trimethylphenol. min GCIC0 0

141 InDuStrIAL ChemICAL AppLICAtIonS halocarbons gs-gaspro - 0 m x 0. mm Suggested Supplies Septum: mm Advanced Green septa, - Helium at 0 cm/s Liner: Direct,. mm id, C for min 0- C at 0 C/min C hold Seal: Gold plated seal, 0-0 Injection: Split, 0 C Split ratio : Detector: FID, 0 C Sample: µl 0 0. CH. CHCIF (Freon ). CCI F (Freon ). CICF CF Cl (Freon ). CHCI F (Freon ). CCI F (Freon ). CF Br (Freon B). CH I. CH CI 0. trans-cich=chci. CF CCl (Freon ). cis-cich=chci. CHCI. CCI. CCI. CCI. CH CH I. CH Br. CHCI Br 0. C F I. CHCIBr. CH CH CH I 0 GCIC0 ethylene oxide DB-wAX -0 0 m x 0. mm, 0. µm Helium at ml/min 0 C for min 0-0 C at C/min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min. Ethylene oxide. -Chloroethanol. Ethylene glycol (solvent: dimethylformamide) Courtesy of J. Chromatogr. Sci., : [0] 0 GCIC0

142 InDuStrIAL ChemICAL AppLICAtIonS Impurities in mixed Xylenes DB-wAXetr - 0 m x 0. mm, 0. µm Helium at 0 cm/s, measured at C 0 C for 0 min 0-0 C at C/min 0 C for 0 min ASTM D0 Non-aromatics. Benzene. Toluene. Ethylbenzene. p-xylene. m-xylene. o-xylene. n-butylbenzene (IS) Injection: Split, 0 C Split ratio :0 Detector: FID, 0 C C aromatics GCIC0 high resolution Separation of Xylene Isomers Cp-Chirasil-Dex CB Cp0 m x 0. mm, 0. µm Sample: 0. µl Sample Conc: 0-0% Helium, 0 kpa, psi 0 C, ( min) to 0 C, C/min Injection: Split, T=0 C, :0. Benzene. Toluene. Para xylene. Meta xylene. Ethyl benzene. Ortho xylene. Styrene. Cumene Detector: FID, T=0 C 0 min VGC00 halothane gs-gaspro - m x 0. mm Helium at cm/s 0 C isothermal Injection: Split, 00 C Split ratio :00 Detector: FID, 00 C Sample: 0. µl. Nitrogen. Halothane. Diethyl ether. Acetone Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, GCIC0

143 InDuStrIAL ChemICAL AppLICAtIonS Inorganic hydride gases hp- 0Z-0 0 m x 0.0 mm, 0.0 µm Helium, cm/s A: -0 C isothermal B: 0 C isothermal Injection: Split ratio : Detector: FPD, µm filter A B -0 C 0 C. Arsine 0.%. Phosphine 0.%. Selenide 0.%. Diborane 0.0 ppm. Tetraborane 0.0 ppm. Pentaborane 0.0 ppm. Dihydropentaborane 0.0 ppm Sample: µl GCIC0 polymer Additives hp- (use only 0 m) 0g-0 0 m x 0. mm, 0. µm Injection: Detector: Helium, psi ( ml/min at 0 C) hold for min, ramp to 0 psi ( ml/min at 0 C) at psi/min EPC on-column, oven track 0. µl injection FID 0 C min 0 C 0 C/min. BHT. BHEB. Tinuvin P. Isonox. Irgafos. Irganox 0. MD 0. Irganox 00 Fast Separation of Silanes VF-00ms Cp0 0 m x 0. mm,.00 µm Hydrogen, ca.0 ml/min, 0 kpa 0 C Injection: Split/splitless, in split mode, :00 Detector: FID 0.00 Volts. Vinyl-trimethyl silane. Dichloromethyl silane. Dichloromethane. Trimethylchloro silane. Pentamethyl disiloxane. Trichloromethyl silane. Dichlorodimethyl silane min VGC00

144 InDuStrIAL ChemICAL AppLICAtIonS Sulfur gases poraplot u Cp m x 0. mm, 0.00 µm Sample: ±00 ppm H 0 C Injection: 00 ml/min. Hydrogen sulfide. Carbonyl sulfide. Sulfur dioxide. Methyl sulfide Detector: FPD 0 min VGC00 Analysis of Acetylenes' mixture Select Al o Cp 0 m x 0. mm Sample Conc: Approx 00 ppm in nitrogen, synthetic standard Injection: Detector: Helium, psig, min to psig, 0. psig/min, min 0 C, min to 0 C, 0 C/min to 00 C, 0 C/min, hold min Split, 0 ml/min FID Courtesy of J. Luong, Dow Chemical Canada 0. Methane. Ethane. Ethylene. n-butane. Propadiene. -Butene. Iso-butene.,-Butadiene.,-Butadiene 0. Ethyl acetylene 0 min VGC00

145 ForenSIC toxicology AnD pharma AppLICAtIonS Forensic Toxicology and Pharma Applications DB-Select ui for <> megabore early eluting peaks DB-Select ultra Inert -0uI 0 m x 0. mm,.00 µm Helium cm/s (approx. ml/min) set at 0 C, EPC Constant Flow 0 C 0 min hold, then 0 /min to 0 C Injection: 0 Hz Detector: FID at 0 C, H at 0 ml/min Air at 00 ml/min N makeup at ml/min (constant column + makeup) Sample: FID signal. Methane. Methanol. Ethanol. Diethyl ether.,-dichloroethylene. -Propanol. Acetonitrile. Methyl acetate. Dichloromethane 0. trans-,-dichloroethylene. n-hexane. -Propanol. Nitromethane. cis-,-dichloroethylene. Ethyl acetate. -Butanol. Chloroform.,,-Trichloroethane. Cyclohexane 0. Carbon tetrachloride. Benzene.,-Dichloroethane. Isooctane (,,-trimethylpentane). -Methyl--butanone. n-heptane. Trichloroethylene. Methylcyclohexane.,-Dioxane. Propyl acetate 0. -Ethoxyethanol. Pyridine excellent peak shape. Toluene. -Methyl--butanol

146 ForenSIC toxicology AnD pharma AppLICAtIonS Benzodiazepines I DB-ms ultra Inert -ui 0 m x 0. mm, 0. µm Hydrogen, cm/s, constant flow. for min.-. at 0 ml/min, hold min.-.0 at 0 ml/min, hold min 0 C for. min 0-0 C at. C/min, hold. min 0-0 C at. C/min, hold.0 min 0- C at 0.0 C/min, hold.0 min Injection: Pulsed splitless, 0 C 0 psi pulse pressure for 0. min 0 ml/min purge at 0.0 min Direct connect liner (p/n G-00) Detector: FID, 0 C Sample: µl of -0 ppm pa Medazepam. Halazepam. Oxazepam. Lorazepam. Diazepam. Desalkyl aurazepam. Nordazepam. Clonazam. Oxazopam Temazepam. Flunitrazepam. Bromazepam. Prazepam. Lormetazepam. Nitrazepam. Chlordiazepoxide. Clonazepam. Demoxepam. Estazolam 0. Alprazolam. Triazolam Analysis of benzodiazepines and other drugs is particularly challenging because of their high level of activity. For this reason, all aspects of the sample path particularly the GC Column must be as inert as possible Ramped Flow 0 BENZODIAZ Amphetamines and precursors tms Derivatives DB m x 0. mm, 0.0 µm Helium at cm/s, measured at 00 C Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, C at 0 C/min Seal: Gold plated seal, 0-0 Injection: Split, 0 C Split ratio :00 Syringe: 0 µl tapered, FN -s//hp, - Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of µg/µl each in pyridine 0. Phenylacetone. Dimethylamphetamine. Amphetamine. Phentermine. Methamphetamine. Methyl ephedrine. Nicotinamine. Ephedrine. Phenacetin 0.,-Methylenedioxyamphetamine (MDA).,-Methylenedioxymethylamphetamine. -Methyl-,-dimethoxyamphetamine (STP). Phenyl ephedrine.,-methylenedioxyethylamphetamine (MDE; "Eve"). Caffeine. Benzphetamine min GCLS00

147 ForenSIC toxicology AnD pharma AppLICAtIonS Barbiturates DB-ms - 0 m x 0. mm, 0. µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at cm/s, measured at 0 C Liner: Splitless, single taper, deactivated, mm id, - 0 C for 0. min 0-0 C at C/min 0-00 C at 0 C/min Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - Injection: Splitless, 0 C 0 s purge activation time Detector: MSD, 0 C transfer line full scan at m/z Barbital. Allobarbital. Aprobarbital. Butabarbital. Butethal. Butalbital. Amobarbital. Talbutal. Pentobarbital 0. Methohexital. Secobarbital. Hexobarbital. Thiopental. Cyclopentylbarbital. Mephobarbital. Thiamylal. Phenobarbital. Alphenal GCLS00 narcotics DB-ms - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for 0. min 0-0 C at C/min 0- C at 0 C/min Injection: Splitless, 0 C 0 s purge activation time Detector: MSD, 00 C transfer line full scan at m/z 0-0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -, 0. Dextromethorphan. Codeine. Dihydrocodeine. Norcodeine. Ethylmorphine. Morphine. Normorphine. -Acetylcodeine. -Monoacetylmorphine 0. Heroin 0 GCLS0

148 ForenSIC toxicology AnD pharma AppLICAtIonS Blood Alcohols I (Static headspace/split) DB-ALC - 0 m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium at 0 cm/s, measured at 0 C 0 C isothermal Liner: Direct,. mm id, Seal: Gold plated seal, 0-0 Sampler: Headspace Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at ml/min. Methanol. Acetaldehyde. Ethanol. Isopropanol. Acetone. -Propanol GCLS0 Blood Alcohols II (Static headspace/split) DB-ALC - 0 m x 0. mm,.00 µm Sampler: Helium at 0 cm/s, measured at 0 C Injection: Split, 0 C Split ratio :0 0 C isothermal Headspace 0 C Loop: 0 C Transfer line: 0 C Vial equil. time: 0 min Pressurization time: 0.0 min Loop fill time: 0.0 min Loop equil. time: 0.0 min Inject time: min Sample loop size:.0 ml Detector: FID, 00 C Nitrogen makeup gas at ml/min Sample: 0.% Ethanol, 0.00% Others Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methanol. Acetaldehyde. Ethanol. Isopropanol. Acetone. -Propanol GCLS0

149 ForenSIC toxicology AnD pharma AppLICAtIonS residual Solvents, DmI Diluent DB- - 0 m x 0. mm,.0 µm Sampler: Suggested Supplies 0-0 C, C/min 0- C,. C/min -0 C, C/min 0 C hold min Headspace Plate 0 C Transfer line, valve 0 C Sample loop ml Injection: Split, 0 C Split ratio : Detector: FID, 0 C Nitrogen makeup Sample:,000 ppm standard Septum: mm Advanced Green septa, - Liner: Direct,. mm id, Seal: Gold plated seal, 0-0. Methanol. Ethanol. Acetone. -Propanol. Acetonitrile. Methylene chloride. -Methyl--propanol (tert-butanol). MTBE. Hexane 0. -Propanol. DMI impurity 0. -Butanone (MEK). Ethyl acetate. -Butanol. Tetrahydrofuran. Cyclohexane. Isopropyl acetate.,-dimethoxyethane. Heptane 0. -Methoxy--propanol. Methylcyclohexane. -Ethoxyethanol Special thanks to Julie Kancler, Brian Wallace, Teledyne.. MIBK (-Pentanone). Toluene. -Pentanol. n,n-dimethylformamide (DMF). Ethyl benzene. m,p-xylene. o-xylene 0. Dimethyl sulfoxide (DMSO). n,n-dimethylacetamide. n-methylpyrrolidone.,-dimethyl--imidazolidinone (DMI) GCLS0 underivatized Drugs of Abuse Agilent Fast toxicology Analyzer DB-ms ultra Inert -ui m x 0. mm, 0. µm Injection: Liner: Sample: Helium, fixed pressure.0 psi Splitless µl 0 C, total flow. ml/min, ml/min switched septum purge, gas saver off, 0 ml/min after 0. min Splitless, dual taper, deactivated, mm id, (p/n -) Agilent GC/MS toxicology checkout mixture (p/n 0-0) Backflush: Post run: min psi inlet, psi aux EPC 00 C (0. min) to C (0 C/min,. min hold) Detector: MSD: Transfer line 00 C, source 00 C Quadrupole: 0 C scan mode NPD: Blos bead 00 C H ml/min, 0 ml/min air, ml/min makeup and column flow CFT Device: -Way splitter with solvent venting between MSD and NPD. Amphetamine. Phentermine. Methamphetamine. Nicotine. Methylenedioxyamphetamine (MDA). Methylenedioxymethamphetamine (MDMA). Methylenedioxyethylamphetamine. Meperidine. Phencyclidine 0. Methadone. Cocaine. SKF-a (RTL compound). Oxazepam. Tetrahydrocannabinol. Codeine. Lorazepam. Diazepam. Hydrocodone 0. Oxycodone 0. Temazepam. Diacetylmorphine. Flunitrazepam. Nitrazepam. Clonazepam. Alprazolam. Verapamil. Strychnine. Trazodone 0 Example NPD chromatogram of underivatized drugs of abuse ng/component on an Agilent J&W DB-ms UI column. Component number is used for retention time locking in the deconvolution reporting software database.

150 ForenSIC toxicology AnD pharma AppLICAtIonS Benzodiazepines II DB-ms - 0 m x 0. mm, 0. µm Helium at cm/s, measured at 0 C 0 C for 0. min 0-0 C at C/min 0-0 C at 0 C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time. Medazepam. Halazepam. Oxazepam. Lorazepam. Diazepam. Demoxepam. Desmethyldiazepam. Clobazam. Temazepam, 0. Flunitrazepam. Delorazepam. Bromazepam. Prazepam. Flurazepam. Clonazepam. Alprazolam. Triazolam Detector: MSD, 0 C transfer line full scan at m/z 0-00 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Splitless, single taper, deactivated, mm id, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, GCLS0 Drug Screen Injection: DB-ms -0 0 m x 0. mm, 0. µm Helium at 0 cm/s, measured at 0 C Detector: FID, 00 C 0 C for.0 min 0- C at C/min - C at 0 C/min C for min Cold splitless Optic II injector, 0-0 C at 0 C/s s purge activation time. Nicotine. Caffeine. Glutethimide. Lidocaine. PCP. Phenobarbital. Methadone primary metabolite. Methaqualone. Methadone 0. Cocaine. Desipramine. Carbamazepine. Trimipramine. Heroin. Fentanyl. Ibogaine. Triazolam. LSD Sample: µl injection of 0-0 ppm standard GCLS00 0

151 ForenSIC toxicology AnD pharma AppLICAtIonS Common Drug Screen DB m x 0. mm, 0. µm Suggested Supplies DB- - 0 m x 0. mm, 0. µm Hydrogen at cm/s, measured at 0 C 0 C for min 0-0 C at 0 C/min 0 C for min Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - DB- time DB- time. Nicotine... Phenmetrazine... Ibuprofen Procaine... Allobarbital..0. Aprobarbital... Butabarbital... Secobarbital... Pentobarbital.. 0. Phenacetin... Amobarbital... Benzphetamine... Acetaminophen... Hydroxyphenamate... Dimenhydrinate... Meprobamate... Benactyzine.. DB- DB- time DB- time. Hexobarbital... Doxylamine.. 0. Caffeine.0.. Chlorpheniramine... Methapyrilene... Thenyldiamine... Phenobarbital... Bromopheniramine... Chlorcyclizine 0... Cocaine... Pyrrobutamine. 0.. Codeine Diazepam... Morphine... Hydrocodone... Oxymorphone... Heroin.. 0, 0 0, min DB min GCLS00

152 ForenSIC toxicology AnD pharma AppLICAtIonS urine Drug Screen ultra 0B- 0 m x 0. mm, 0. µm Injection: Detector: Hydrogen, 0 cm/s C for. min -00 C at C/min Splitless FID 0. Amphetamine. Methamphetamine. Meperidine. Phencyclidine (PCP). Methadone. Proposyphene. Amitriptyline. Cocaine. Imipramine 0. Cyheptamide (ISTD). Codeine. Diazepam. Flurazepam min GCLS00 Analysis of Drugs of Abuse in urine via gc/ms VF-DA Cp m x 0.0 mm, optimized µm Sample: µl Solvent: Methanol Pressure: He, ca.0 ml/min 0 C,. min to 00 C, 0 C/min to 0 C, C/min to 0 C, 0 C/min. kpa,. min to kpa, kpa/min to kpa, kpa/min to 0 kpa, kpa/min. Amphetamine. MDA,-methylenedioxyamphetamine. MDA,-methylenedioxymethamphetamine. MDA,-methylenedioxy-ethylamphetamine. Cotinine Injection: Splitless Detector: MS Derivatization: Acetic acid anhydride to form acetates 0 min VGC00

153 ForenSIC toxicology AnD pharma AppLICAtIonS Anesthetics DB-ms evdx - m x 0.0 mm, 0. µm Helium at cm/s, measured at C C for min -0 C at C/min 0- C at C/min Injection: Splitless, 0 C s purge activation time Detector: Sample: Suggested Supplies MSD, 0 C transfer line full scan at m/z -00 µl of 0-00 ng/µl standard in methanol Septum: mm Advanced Green septa, - Liner: Splitless, single taper, deactivated, mm id, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - 0 GCLS00. Salicylamide. Benzocaine. Lidocaine. Procaine. Nefopam. Mepivacaine. Tetracaine. Butacaine. Dibucaine Anticonvulsants DB m x 0. mm,.0 µm Helium at ml/min 0 C for min 0- C at C/min Injection: Megabore direct, 0 C Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 00 ng/µl in methanol Suggested Supplies Septum: mm Advanced Green septa, - 0. Ethosuximide. Methsuximide. Phensuximide. N-Desmethyl methsuximide. Phenylethylmalonamide. Phenobarbital. Primidone. Carbamazepine. Phenytoin 0. -Methyl--phenylhydantoin Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - 0 min GCLS00

154 ForenSIC toxicology AnD pharma AppLICAtIonS Antihistamines DB m x 0. mm, 0. µm Helium at 0 cm/s, measured at C C for min - C at 0 C/min -0 C at 0 C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 0 ng/µl each in methanol. Pheniramine. Dimenhydrinate. Diphenhydramine. Doxylamine. Phenyltoloxamine. Tripelennamine. Methapyrilene. Chlorpheniramine. Cyclizine 0. Carbinoxamine. Diphenylpyraline. Bromopheniramine. Thonzylamine. Chlorcyclizine. Pyrilamine. Triprolidine. Promethazine. Antazoline. Clemizole 0. Hydroxyzine. Meclizine. Cinnanzine. Buclizine,, 0 Suggested Supplies Septum: mm Advanced Green septa, - Liner: Splitless, single taper, deactivated, mm id, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, min GCLS00 Antiepileptic Drugs ultra 0B-0 m x 0. mm, 0. µm Helium, psi 00-0 C at C/min Injection: Split ratio : Detector: NPD. Ethotoin. PEMA. n-des. Phenobarbital. Carbepoxide 0/. Primidone. Phenyltoin. ISTD Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - min GCLS00 tricyclic Antipsychotics ultra 0B-0 m x 0.0 mm, 0. µm Hydrogen, 0 cm/s 0 C for min 0-0 C at 0 C/min 0 C for 0 min Injection: Split ratio : Detector: FPD 0 min. Triflupromazine. Promethazine. Promazine. Chlorprothixene. Thioridazine Suggested Supplies Septum: mm Advanced Green septa, - Liner: General purpose split/splitless liner, taper, glass wool, - Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - GCLS00

155 ForenSIC toxicology AnD pharma AppLICAtIonS Fentanyls DB m x 0. mm,.00 µm Hydrogen at ml/min 0 C isothermal Injection: Split, 0 C Split ratio : Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: 0. µl Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. Fentanyl. Sufentanyl. Carfentanyl. Lofentanyl. Alfentanyl 0 min GCLS0 tocopherols DB-ms - 0 m x 0. mm, 0. µm Helium at 0 cm/s, measured at 0 C 00 C for min 00-0 C at C/min 0 C for min Injection: Split, 0 C Split ratio : Detector: Sample: MSD, 0 C transfer line full scan at m/z -0 µl of -0 ng/µl in isooctane Suggested Supplies Septum: mm Advanced Green septa, - Liner: Split, single taper, low pressure drop, glass wool, - Seal: Gold plated seal, 0-0 Syringe: µl tapered, FN -s//hp, -. d-tocopherol. b-tocopherol. g-tocopherol. a-tocopherol GCLS0

156 ForenSIC toxicology AnD pharma AppLICAtIonS hallucinogens DB-ms - 0 m x 0. mm, 0. µm Helium at 0 cm/s, measured at 0 C 0 C for 0. min 0- C at C/min - C at 0 C/min -0 C at C/min 0 C for min Injection: Splitless, 0 C 0 s purge activation time Detector: Sample: MSD, 00 C transfer line full scan at m/z 0-0 µl of 0-0 ng/µl standard in methanol Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. -Methylaminorex. Mescaline. Dimethyltryptamine. Ketamine. TCP (Tenocyclidine). Phencyclidine (PCP). Diethyltryptamine. Bufotenine. Fentanyl 0. Ibogaine. LSD. Psilocin (peak not shown) GCLS0 Sedative hypnotics DB-ms evdx - m x 0.0 mm, 0. µm Helium at cm/s, measured at C C for min -0 C at C/min 0- C at C/min C for min Injection: Splitless, 0 C s purge activation time Detector: Sample: MSD, 0 C transfer line full scan at m/z -00 µl of 0-00 ng/µl standard in methanol Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, - 0. Ethchlorvynol. Ethinamate. Pyrithyldione. Talbutal. Meprobamate. Glutethimide. Methaqualone. Propiomazine. Haloperidol 0. Sulpiride. Droperidol 0 0 GCLS0

157 ForenSIC toxicology AnD pharma AppLICAtIonS narcotics and Adulterants DB m x 0. mm, 0. µm Helium at 0 cm/s, measured at 0 C 0-0 C at C/min 0 C for min Injection: Split, 0 C Split ratio : Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 0. µg/µl each in methanol min 0. Caffeine. Ketamine. Lidocaine. Procaine. Cocaine. Codeine. Morphine. -Acetylcodeine. Diacetylmorphone (heroin) 0. Quinine. Strychnine GCLS0 over-the-counter pain Killers tms Derivatives DB m x 0. mm, 0.0 µm Helium at cm/s, measured at 00 C 00-0 C at 0 C/min Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min. Nicotine. Unknown. Acetylsalicylic acid (aspirin). Ibuprofen. Acetaminophen. Unknown. Caffeine Sample: µl of µg/µl each in pyridine min GCLS0 Aspirin and Ibuprofen in methanol DB-FFAp - 0 m x 0. mm, 0. µm Hydrogen at cm/s, measured at 0 C 0 C isothermal. Aspirin. Ibuprofen Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min. min GCLS0

158 ForenSIC toxicology AnD pharma AppLICAtIonS Free Steroids DB- - 0 m x 0. mm, 0. µm Hydrogen at cm/s 0 C isothermal Injection: Split, 0 C Split ratio :00 Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl 0. Coprostane (-ß-cholestane). -b-androsterone. -a-cholestane. Androsterone. Epiandrosterone (trans-androsterone). -a-estradiol. b-estradiol. Estrone. Progesterone 0. Cholesterol. Estriol. Stigmasterol min GCLS00 Anabolic Steroids DB m x 0. mm, 0.0 µm Helium at 0 cm/s, measured at 0 C 0-0 C at 0 C/min 0 C for min Injection: Split ratio :0 Detector: FID, Nitrogen makeup gas at 0 ml/min Sample: µl of 0. µg/µl each in methanol. Dehydroisoandrosterone (prasterone). a-androstan-a-ol--one (stanolone). -Nortestosterone (nandrolone). Mesterolone. Testosterone. -Dehydrotestosterone (boldenone). a-methyltestosterone. -Dehydro--a-methyltestosterone (methandrostenolone). Norethandrolone 0. -Dehydrotestosterone acetate. Oxymetholone. -Nortestosterone--propionate. -Chlortestosterone--acetate (clostebol). Stanozolol. -Dehydrotestosterone benzoate. -Nortestosterone--decanoate. -Dehydrotestosterone undecylenate, 0, min GCLS0

159 ForenSIC toxicology AnD pharma AppLICAtIonS marijuana (D-thC) and major metabolites tms Derivatives DB m x 0. mm, 0. µm Helium at 0 cm/s, measured at 00 C 00 C for min 00- C at 0 C/min - C at C/min Injection: Splitless, 0 C 0 s purge activation time Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min Sample: µl of 0. µg/µl each in pyridine Suggested Supplies Septum: mm Advanced Green septa, - Liner: Direct connect, single taper, deactivated, mm id, G-00 Seal: Gold plated seal, 0-0 Syringe: 0 µl tapered, FN -s//hp, -. D-THC. L--Hydroxy-D-THC. L--Carboxy--nor-D-THC. min GCLS0 Blood pollutants I DB-ALC - 0 m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium, cm/s, measured at 0 C Liner: Direct,. mm id, C for min 0-0 C at 0 C/min Seal: Gold plated seal, 0-0 Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C * * *, * *,,, 0* *, 0,,, 0. Methanol*. Acetaldehyde*. Ethanol*. Diethyl ether. Isopropyl alcohol*. Methylene chloride. Acetone*. Acetonitrile. Ethyl formate 0. t-butyl alcohol*. -Propanol. MTBE. Hexane. Chloroform. sec-butyl alcohol. -Chlorobutane. MEK (-butanone). Ethyl acetate.,-trichloroethane 0. Carbon tetrachloride. -Chlorobutane. Benzene. -Butanol. Heptane. Ethylene glycol. Isoamyl alcohol. Toluene. Isopropyl amine (not shown). Ethylbenzene 0. m,p-xylene. o-xylene. DMSO 0 GCLS0

160 ForenSIC toxicology AnD pharma AppLICAtIonS Blood pollutants II DB-ALC - 0 m x 0. mm,.00 µm Suggested Supplies Septum: mm Advanced Green septa, - Helium, cm/s, measured at 0 C Liner: Direct,. mm id, C for min 0-0 C at 0 C/min Seal: Gold plated seal, 0-0 Injection: Split, 0 C Split ratio :0 Detector: FID, 00 C * * *,, *, 0* *,,, 0 *,,, 0. Methanol*. Acetaldehyde*. Ethanol*. Diethyl ether. Isopropyl alcohol*. Methylene chloride. Acetone*. Acetonitrile. Ethyl formate 0. t-butyl alcohol*. -Propanol. MTBE. Hexane. Chloroform. sec-butyl alcohol. -Chlorobutane. MEK (-butanone). Ethyl acetate.,-trichloroethane 0. Carbon tetrachloride. -Chlorobutane. Benzene. -Butanol. Heptane. Ethylene glycol. Isoamyl alcohol. Toluene. Isopropyl amine (not shown). Ethylbenzene 0. m,p-xylene. o-xylene. DMSO 0 GCLS0 residual Solvents, usp DB- - 0 m x 0. mm,.00 µm Helium at cm/s, measured at 0 C 0 C for 0 min 0-0 C at C/min Injection: Megabore direct, 0 C m phenylmethylsilane deactivated retention gap Detector: FID, 00 C Nitrogen makeup gas at 0 ml/min. Methanol. Ethanol. Ethyl ether. Acetone. Isopropanol. Acetonitrile. Methylene chloride. tert-butanol. n-hexane 0. n-propanol. Methyl ethyl ketone (MEK). Ethyl acetate. Tetrahydrofuran (THF). Chloroform. sec-butanol. Cyclohexane. Benzene. n-heptane. Trichloroethylene 0. n-butanol.,-dioxane. Pyridine. Toluene. Dimethylformamide (DMF),, min GCLS0 0

161 ForenSIC toxicology AnD pharma AppLICAtIonS Column performance for usp <> Standards DB-Select ultra Inert -0uI 0 m x 0. mm,.0 µm Helium,. ml/min constant flow at 0 C 0 C for 0 min, then 0 C/min to 0 C min Inlet: MMI, 0 C, µl split : Inlet liner: Sample Conc: Detector: mm straight single taper Ultra Inert liner.0 ml loop FID: 0 C, H 0 ml/min, air 00 ml/min, N constant col + makeup = 0 ml/min Suggested Supplies Septum: Liner: Non-stick bleed and temperature optimized (BTO) septa, mm, 0/pk, - Liner, GC, Ultra Inert, straight, mm id, 0-0 Seal: Certified gold plated seal kit, includes washer, 0/pk, S/n =. r s = Carbon tetrachloride 0000.,-Dichloroethene.,,-Trichloroethane. Carbon tetrachloride. Benzene.,-Dichloroethane FID trace of Class solvent standard at USP <> specified limits on an Agilent J&W DB-Select UI for USP <>, 0 m x 0. mm,.0 µm column r s = r s = Methanol. Acetonitrile. Dichloromethane. trans-,-dichloroethane. cis-,-dichloroethane. Tetrahydrofuran. Cyclohexane. Methylcyclohexane.,-Dioxane 0. Toluene. Chlorobenzene. Ethylbenzene. m/p-xylene. 0-Xylene FID trace of Class A solvent standard at USP <> specified limits on an Agilent J&W DB-Select UI for USP <>, 0 m x 0. mm,.0 µm column

162 PART NUMBER INDEX Part Number Index , ,,, 0,,,, ,, ,, , , , , , , , , 0,, , LTM..., LTM..., E... -LTM..., LTM...0, -..., 0 -E...0 -LTM...0, E...0 -A...0 -AE LTM..., E LTM..., E... -LTM..., , -..., LTM...0, -..., -LTM..., LTM..., E... -PT E... -PT..., -H PT...-,, PT...,,, E LTM..., -0UI , -0LTM..., E... -0LTM..., LTM..., -0A... -0ALTM..., E... -0LTM..., LTM..., ,,,, -E... -LTM..., -UI...,, -...,,,, 00 -LTM...00, E LTM..., UI LTM...0, E... -0LTM..., LTM..., E... -0LTM..., LTM..., , 00 -E LTM...00, -UI..., 0 -UILTM...0, LTM...00, -UI...0 -UILTM...0, LTM..., -0LTM LTM..., LTM..., E ,,, E... -0LTM..., -0UI ,, -0E... -0LTM... -0UI... -0UIE UI E , -0UI..., -0UI..., LTM..., ,,, -0E... -0LTM..., -0..., -0E... -0LTM..., E LTM..., LTM...,

163 PART NUMBER INDEX -0LTM..., E... -0G... -0LTM..., -0..., -0E... -0LTM..., -0E... -0ELTM..., E..., -0A... -0AE..., -0AE... -0G E LTM LTM...0, ,,, -, 0 -G... -LTM...0, , E , -...,,, -E... -LTM..., -UI...,,, E ,,,,, -E... -UI...,,,, -...,,, 00 -LTM...00, -...,,, -,,, 00 -E E E E... -LTM..., LTM..., LTM..., LTM..., LTM..., LTM..., LTM..., E... -LTM..., E , -E LTM..., -..., -E... -LTM..., E... -LTM..., E UI , 0,, -, 0 -E...0 -LTM...0, -UI..., LTM...0, LTM...0, ,, 0 -E...0 -LTM...0, LTM , 0-0LTM...0, E , 0-0E...0-0LTM...0, -0..., 0-0E...0-0LTM...0, -0E...0-0ELTM...0, E LTM...00, LTM...00, -UI..., 0 -UILTM...0, UI LTM...00, -UI...0 -UILTM...0, , -, -, 00 -E G... -LTM...00, -UI..., -, 0 -UIE...0 -UILTM...0, -..., -,, 00 -E G... -LTM...00, -UI...,, 0 -UILTM...0, -...0, 00 -E G... -UI...0 -UILTM...0, UI E G... -UI...0-,, UI G E... -LTM..., LTM..., , E... -0LTM..., -0..., -0LTM..., , -0E... -0LTM..., -0...,, -0E... -0LTM..., E E E... -LTM..., , -LTM..., -L ,, -..., UI UI UI..., -0UI..., LTM..., E E E ALTM LTM...0, LTM...0, LTM...0, -0..., F

164 PART NUMBER INDEX LTM...0, -0..., 0-0E...0-0LTM...0, LTM...0, -0B...0-0BLTM...0, -0E...0,, 0-0ELTM...0, C...0-0F E E E E...0-0B...0-0BE...0-0E..., 0-0G...0-0LTM LTM..., E ,, 0,, E... -LTM..., -UI..., E... -UI...,, , , ,, -0LTM..., E... -LTM..., E E... -LTM..., E E , -E... -LTM..., LTM..., LTM..., , 0 -E...0 -UI...,, 0,, , 0 -LTM...0, -00LTM E ELTM...0, LTM...0, E...0-0LTM...0, E...0-0LTM...0, LTM...0, D...0-0F E...0-0LTM...0, -0..., 0-0E...0-0B...0-0BLTM...0, -0E...0-0ELTM...0, LTM...00, LTM...00, ,, 00 -E UI..., 0 -UIE , 00 -LTM...00, -UI ,, 00 -LTM...00, -UI UI LTM..., E E LTM..., LTM..., E... -0LTM..., E... -0LTM..., -0..., E LTM..., E , ,,,, -...-,,,, LTM..., E... -BD0... -BD... -BD ,, -LTM..., -..., -..., , , ,, -0..., LTM..., -0UI..., E... -0LTM..., E... -0G E LTM..., -00B E... -0LTM..., E... -0LTM..., LTM..., J... -0K LTM..., -0J LTM..., -0..., -0E... -0LTM..., -0..., -, -0E... -0LTM..., B... -0J... -0JLTM..., -0K... -0KE... -0KLTM..., -0...

165 PART NUMBER INDEX E E... -0J... -0JE... -0B... -0H... -0HB... -0HBE... -0HBLTM..., LTM..., ,, -E... -G... -LTM..., -UI..., E , -E... -UI..., -A LTM..., LTM..., , E... -LTM..., LTM..., , ,, 0 -E...0 -LTM...0, LTM..., E H , -0E... -0LTM..., J... -0K , -0E... -0LTM..., E... -0LTM..., B... -0D... -0J... -0K E... -0HB LTM...00, G... -J JLTM...00, -...-,, E LTM..., , -0E... -0LTM..., E E LTM..., E E LTM..., LTM..., A ALTM..., E E... -0LTM..., E LTM..., E LTM..., LTM..., -H... -HLTM..., E... -0LTM..., LTM..., -0E... -0ELTM..., -0N E... -0LTM..., LTM..., LTM..., E... -0FF... -0LTM..., E... -0LTM..., LTM..., LTM..., , LTM E... -LTM..., LTM...0, H LTM...00, LTM..., A-0... A-0LTM..., A-0... A-0LTM..., , , 0, , , ,, , , ,, ,, ,

166 PART NUMBER INDEX ,, , , , , -00-HSP ,, 0, , , , , , , ,, ,,,, 0-, , , E A A A A A A A A-0E... 0A A A-... 0A-... 0B B B B-0E... 0B B B-0LTM..., 0B B-0E... 0B-0LTM..., 0B B-0E... 0B-... 0B-LTM..., 0B-... 0B-E... 0F F-0E... 0F-0LTM..., 0 0F F-0E... 0F-... 0F-E... 0F-LTM..., 0 0F-... 0F-E... 0F-... 0F-... 0F-E... 0F-LTM..., 0 0G-... 0G-... 0G-E... 0G-LTM..., 0G-... 0G-... 0G-B... 0G-B... 0G-B... 0G-BE... 0J J J J J J J-0E... 0J J-0E... 0J J-... 0J-E... 0J-... 0J-E... 0J-LTM..., 0J-... 0J-E... 0J J J-... 0J-... 0J-E... 0J-... 0J-E... 0J-... 0J-E... 0J-... 0J-..., 0J-LTM..., 0J-... 0J-... 0J J-0LTM..., 0J-... 0J-... 0J-LTM..., 0J-... 0J-E... 0J-LTM..., 0J-... 0J-... 0J-E... 0J-... 0J-E... 0J-LTM..., 0J-... 0J-E... 0J-... 0J-E... 0J-LTM..., 0L L L-E...0 0L L L-0LTM...0, 0L L L-E...0 0L L L-LTM...0, 0L L-LTM...0, 0N N-0LTM..., 0 0N N-00LTM..., 0 0N N N N-0LTM..., 0 0N N-0E... 0N-... 0N-..., 0N-E... 0N-...,, 0N-... 0N-E... 0N-... 0N-E... 0N-LTM..., 0 0N-..., 0N-E... 0N N N-0E... 0N-... 0N-E... 0N-...-, 0N-E... 0N-..., 0N-..., 0N-E... 0N-... 0N-... 0N-... 0N-E... 0N-LTM..., 0 0P-K... 0P-KE... 0P-KPT..., 0P-K... 0P-KLTM..., 0P-M... 0P-ME... 0P-MS... 0P-MSE... 0P-MS... 0P-MSLTM..., 0P-MS... 0P-MSLTM..., 0P-QO... 0P-QOLTM..., 0P-QOPT..., 0P-QO... 0P-QOE... 0P-QOLTM..., 0P-QOPT..., 0P-S... 0P-SLTM..., 0P-SPT..., 0P-S... 0P-SE... 0P-SPT..., 0P-S... 0P-UO... 0P-UOE... 0P-UOLTM..., 0R R-0...,,, 0 0R R S , 0S-00E... 0S S S-0LTM...0, 0 0S S-0E...0 0S-0LTM...0, 0 0S S-LTM...0 0S S-E...0 0S-...0,, 0 0S-..., 0, -,, 0 0S-UI...,, 0 0S-UILTM...0, 0 0S-... 0S-...,, 0 0S-UI...0 0S-UILTM...0, 0 0S S-...0

167 PART NUMBER INDEX 0S-E...0 0S-UI..., 0 0S-UILTM...0, 0 0S S S-LTM...0, 0 0S S S-..., 0 0S-E...0 0S-LTM...0, 0 0S-UI..., 0 0S-UILTM...0, 0 0S S S-LTM...0, 0 0S-UI..., 0 0S-UILTM...0, 0 0S-..., -, 0 0S-E...0 0S-LTM...0, 0 0S-UI...,,, 0 0S-UIE...0 0S-UILTM...0, 0 0S S-E...0 0S-UI...0 0S S-LTM...0, 0 0S-UI..., 0 0S-UILTM...0, 0 0S S-0E... 0S-... 0S-UI... 0S-... 0S-LTM..., 0S-UI... 0S-... 0S-LTM..., 0S-UI... 0S-...0,, 0S-LTM..., 0S-UI... 0S-... 0S-E... 0S-LTM..., 0S-UI... 0S-... 0S-LTM..., 0S-... 0S-UI... 0S-... 0S-E... 0S-UI... 0S-... 0S-... 0S-UI... 0S-... 0S-E... 0S-LTM..., 0S-UI... 0S-... 0S-E... 0W W-0E... 0W-0LTM..., 0W W-0E... 0W W Y Y-0E... 0Y Y Z Z-00LTM..., 0Z Z Z Z-0LTM..., 0Z Z Z-0E... 0Z Z-... 0Z-E... 0Z-...,, 0Z-E... 0Z Z-0LTM..., 0Z-0..., 0Z-0E... 0Z-... 0Z-... 0Z-... 0Z-E... 0Z-... 0Z-... 0Z-E... 0Z-... 0Z-... 0Z-E... 0Z-...-, 0Z-E... 0Z-... 0Z-LTM..., 0Z-... 0Z-... 0Z-... 0Z-... 0Z-E... 0Z-... 0Z-... 0Z-... 0Z-E... 0Z-... 0Z-... 0Z-E... 0Z-0...,, 0Z-0E..., 0Z-... 0Z-E... 0Z-..., 0Z-LTM..., 0Z-... 0Z-E... 0Z-LTM..., 0Z-... 0F F-0E... 0F-... 0F-LTM..., 0 0F-... 0F-E... 0F-LTM..., 0 0J J-0E... 0J-... 0J-E... 0J-LTM..., 0J-... 0J-E... 0J-..., 0J-... 0J-E... 0J-... 0J-..., 0J-E... 0L L-0LTM...0, 0L L-0E...0 0L-... 0L N-... 0N-... 0N-E... 0N-LTM..., 0 0N-... 0P-K... 0P-KLTM..., 0P-KPT...,, 0P-K... 0P-KE... 0P-KPT...,, 0P-M... 0P-M... 0P-MPT..., 0P-MS0..., 0P-MS0E... 0P-MS0LTM..., 0P-MS... 0P-MS... 0P-MSE... 0P-MS..., 0P-QO... 0P-QOE... 0P-QOLTM..., 0P-QOPT...,,,, 0P-QO... 0P-QOE... 0P-QOLTM..., 0P-QOPT...-,, 0P-S... 0P-S... 0P-SPT...,, 0P-S... 0P-SE... 0P-SPT...,, 0P-UO... 0P-UO... 0P-UOE... 0P-UOLTM..., 0P-UOPT...,, 0R R S S-00E... 0S S V V-0E... 0V-0LTM..., 0 0W-... 0W-... 0Z-00..., 0Z-0..., 0Z-0E... 0Z-0LTM..., 0Z Z-0E... 0Z-0LTM..., 0Z-... 0Z-E... 0Z-LTM..., 0Z-... 0Z-E... 0Z-LTM..., 0Z Z-... 0Z-E... 0Z-... 0Z-... 0Z-E... 0Z-... 0Z-... 0Z-E... 0Z-..., 0Z-... 0Z-E... 0Z-LTM..., 0Z-..., 0Z-..., 0BD ,,, ,,, , ,, 0,,, ,, 0,,, ,, , , , , , ,, 0, ,,, ,, 0,

168 PART NUMBER INDEX ,, , , -0..., -0..., , , , ,, , , 0-0LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -UILTM... -LTM... -0LTM... -0LTM... -0LTM... -0LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -LTM... -UILTM... -LTM... -UILTM... -LTM... -LTM... -0LTM... -0LTM EHS EHS N-LTM... 0N-LTM... 0R-0LTM... 0S-UILTM... 0S-LTM... 0S-UILTM... 0S-UILTM... 0S-LTM... 0S-LTM... 0S-LTM HSP HSP HSP HSP HSP HSP HSP HSP HSP HSP , , , HSP HSP HSP HSP HSP... --HSP... --HSP , , 0, , 0, , , ,, , , , ,, 0-...,

169 PART NUMBER INDEX , 0,,, , ,,,, ,,, , , ,, 0, 0,,,,, , , , , 0-0,, ,, 0, 0,,,,, , 0-...,,, 0-...,,, , , 0, i ,, , ,,, ,, ,,, 0,,,,, , , -0..., , , ,, -...,,,,, ,,,,, , ,, -...0, -...0, -...0, -...0, -...0, -..., , , -..., -..., -..., -..., , -..., -..., -..., -..., -..., -0..., -..., , , 0, -0...,, -0..., -0..., , , ,,, 0-, ,,, -..., ,, 0, , -0..., ,,,, 0, ,,,, -..., , , -...,, ,, , -..., -...,, -..., -...,,,,, -...,, -...,, ,, , , -..., ,

170 PART NUMBER INDEX ,, ,,, ,,, 0-..., , , , , , , 0-..., , 0-..., 0-..., 0-..., , , , , , 0,, 0-..., 0-..., 0-..., 0-..., , , -..., , , , , , 0

171 PART NUMBER INDEX , , , , ,,,,, , , , , , ,,, ,, ,, -, ,, ,, ,, ,,, ,,, ,, -, ,, , , , , , , , -, ,,,, ,, -, ,, ,, ,, ,,, ,,, ,, -, ,, , , , , , , , -, ,, ,,, ,,, ,, -, ,, , , , , ,, ,, ,, ,, ,, ,, ,,, ,,, ,, ,, , , , , , , , , , , , -, , , , , ,, ,, , , , , , , , ,, , , , ,, ,, , , , ,, ,, , EHS... C-0SSC... C-AT00C... C-B00M... C-BIO0... C-BTXUG... C-CF00... C-CPLOK... C-DF00... C-GCM0... C-GAT00C... C-GT00... C-HY00C... C-PL00... C-TBE0... C-TBPCC... C-TBPCXC... C-TBPTC... C-TNXTA... C-UN00C... CP00... CP0... CP0... CP0... CP0... CP0... CP0... CP... CP..., CP... CP..., CP0... CP0... CP00... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0...0 CP0...0 CP0...0 CP...0 CP...0 CP...0 CP...0 CP... CP...0 CP...0 CP...0 CP...0 CP...0 CP... CP... CP...0 CP...0 CP...0 CP...0 CP0... CP0..., - CP0..., - CP... CP... CP... CP... CP... CP... CP... CP... CP... CP0... CP... CP..., CP0..., CP..., CP0..., CP... CP... CP... CP... CP..., CP..., CP..., CPI..., CP..., CP..., CP..., CP... CP0...

172 PART NUMBER INDEX CP..., CP0..., CP... CP..., CP0..., CP0..., CP..., CP0..., CP..., CP..., CP..., CP0... CP... CP... CP... CP0...0 CP... CP... CPPT...- CP0...0, CP0I... CP... CPI... CPPT...-, - CP... CPI... CPPT...- CP... CPI... CPPT...0, - CP..., CPI... CPPT...-, - CP... CP... CP... CP..., CP... CP... CP0... CP0... CP0... CP... CP... CP... CP..., CP... CP... CPI... CP..., CP... CP...0 CPI...0 CP0...0 CP...0 CP... CP... CP... CP... CP0... CP... CP... CP... CP...0 CP...0 CP...0 CP0..., CP... CP... CP... CPI... CP... CP... CP... CPI... CP... CPI... CP... CP... CP... CPI... CP... CP...0 CP...0 CP...0, CP... CP... CP... CP... CP..., CP...0 CP...0 CPI...0 CP..., 0 CP...0 CP...-, 0 CP...0 CP...0 CP0...0 CP0...0 CPI...0 CP... CP... CPI... CP... CP00... CP00I... CP0... CP0... CP0I... CP0... CP0... CP...0 CP..., - CPI... CP... CP... CP...0 CPI...0 CPPT...,, 0 CP...0 CPPT..., 0 CP...0 CPPT...-,, 0 CP...0 CP... CP... CPI... CP...0-,, CPI... CP...0 CP...0 CP..., CP0... CP..., CPI... CP...,, - CPI..., CP..., CP... CPI... CPPT..., CP... CPI... CP... CPPT..., CP..., CP... CPI... CPPT..., CP... CPPT..., CP0... CP0I... CP... CP..., - CP... CP... CP... CP... CP0... CP0I... CP0PT..., CP... CPI... CPPT..., CP... CP... CP..., CPI... CPPT..., CP... CP... CP... CPPT..., CP..., CP... CP..., - CP... CPI... CPPT..., CP..., CP... CPPT..., CP..., - CPI..., CP0...,, - CP..., - CP..., - CP... CP...0 CP...0 CP... CP0... CP... CP...,, - CP... CP... CPPT..., CP... CP... CP...0-,, CP... CP...0,, - CP..., - CP... CP... CPI... CP..., CPI... CP..., CP..., CPI... CP... CP0... CP..., 0 CP..., 0 CP...0 CP... CP0... CP... CP... CP...0 CP... CP... CP... CP0... CP... CP... CP... CP...0 CP... CP0... CP... CP... CP... CP...0 CP... CP... CP..., 0 CP... CP...0 CP... CPI... CP... CP...0 CP...0 CP... CP...0 CP... CP0... CP0I... CP... CP...0 CP... CPI... CP... CP... CP... CP0... CP0I... CP... CP... CP...

173 PART NUMBER INDEX CP..., CPI... CP...0 CP... CP0... CP0I... CP... CPI... CP... CP... CP... CP... CP... CP...0 CP... CPI... CP00... CP0...0 CP0... CP0... CP0... CP... CP...0 CP... CPI... CP... CP... CP...0 CPI...0 CP... CP0... CP... CP...0 CP... CPI... CP... CP...0 CP0... CP... CP...0 CP... CP0... CP... CPI... CP...0 CP... CP... CP...0 CP... CPI... CP0... CP0I... CP... CPI... CP...0 CP... CP... CP...0 CP... CP0... CP... CP...0 CP... CP... CP...0 CP... CP0... CP0I... CP... CP...0 CP... CPI... CP... CP...0 CP...0 CP... CP... CP...0 CP... CP... CP... CP...0 CP0...0 CP... CP0... CP... CP... CPI... CP... CP...0 CP0... CP... CP... CP... CP...0 CP... CPI... CP... CP... CP... CP0... CP0... CP... CP... CPI... CP... CP... CP... CP... CP... CP... CP00... CP00... CP00... CP00... CP0... CP0...0, CP0... CP0... CP0... CP0... CP00... CP0... CP0I... CP00... CP0... CP0... CP0... CP00... CP0... CP0... CP0... CP0... CP0...0 CP..., CP... CP... CP... CP... CP... CP..., CP... CP... CP... CP0...0, CP... CP0... CP... CP... CP... CP... CP0... CP... CP... CP0... CP... CP...0 CP... CP0... CP... CP0... CP...0 CP... CP... CP... CP... CP0... CP0I... CP... CP... CP... CPI... CP0... CP0... CP0... CP... CP...0 CP... CP... CP... CP... CP... CP... CP...0-, CP... CP... CP...0-, CPI... CP... CPI... CP... CP0... CP0I... CP0... CP...0 CP... CPI... CP... CP... CP...0 CP... CP0... CP...-, CPI... CP..., CPI... CP...0 CP...-0,, CPI... CP... CPI... CP... CP... CP... CP... CP... CP... CP0... CP..., CP... CP... CP... CP... CP0...,, CP... CP...0 CP...-0,, CP0... CP... CP...0 CP..., CP... CP..., CP0... CP... CP... CP... CP...0, CP... CP0...0 CP0...0 CP0...0 CP0...0 CP0...0 CP...0 CP...0 CP...0 CP...0 CPI...0 CP...0 CPI...0 CP...0 CP...0 CP...0 CP...0 CP...0 CP... CP... CP... CP... CP..., CP... CPI... CP0...0,

174 PART NUMBER INDEX CP... CP... CP... CP... CP..., CP0... CP... CP...0 CP...0 CP...0 CP...0 CP...0,, 0 CP...0 CP..., 0 CP0...0 CP...0 CP...0 CP...0 CP..., 0 CP00... CP0... CP0... CP0... CP0... CP0... CP0...0-,, CP0... CP0... CP0I... CP0... CP0... CP... CP... CPI... CP..., CP... CP... CP... CP... CP... CP... CP... CP... CP...,, CP... CP..., CP... CP... CP0... CP...0 CP...0 CP...0 CP...0 CP...0 CP..., 0 CP0...0 CP...0 CP...0, 0 CP...-, -,, 0 CPI...0 CP...0,, 0 CP...,, -, 0 CP...0 CP...0, 0 CP...0 CP0...0 CP...0 CP...0 CP...,, 0 CP...0 CP...,, 0 CP...0 CP...0 CP0..., 0 CP...0 CP...0 CP...0 CP... CP... CP..., CP... CP..., CP0... CP...0 CP...0 CP..., 0 CP...0, -, 0 CP...0 CP...0 CP0...0 CP...0 CP...0, 0 CPI...0 CP..., 0 CP...0 CP...0 CP0...0 CP..., 0 CP...0 CP...0 CP00..., 0 CP00..., 0 CP00... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP00... CP0... CP0... CP0...0 CP0...0 CP0...0 CP0...0 CP0...0 CP0...0 CP0...0 CP0... CP0... CP0... CP0... CP0... CP0... CP0..., CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP0... CP00...-, 0-,, CP0... CP0... CP0... CP0...-, 0-,, CP0... CP0..., CP0..., CP0...,, CP0..., CP00... CP0... CP00..., CP0..., CP0..., CP0..., CP0..., CP0I..., CP0..., CP0..., CP0..., CP00... CP0... CP0...,,, CP0I... CP0...,,,, CP0I... CP0... CP0I... CP0...,,, CP0... CP0I... CP0..., CP0...,, CP0... CP0... CP... CP0... CP...,, CPI... CP... CPI... CP... CP... CP... CP..., CP... CP... CP0... CP...-, CP... CP... CP0... CP0... CP0... CP0... CP0... CP0I... CP0..., CP0... CP0... CP... CP... CP... CP... CP...,,, CP... CP... CP... CP... CP0... CP... CP... CP... CP... CP..., CP... CP... CP...0 CP...0 CP...0 CP...0 CP...0 CPI...0 CP...0 CP...0 CPI...0 CP...0 CP...0 CR0...0 DY DY DY DY DY DY DY00... DY DY DY00... DY DY DY DY DY DY00... DY00... DY00... DY DY DY DY DY DY DY G G ,, -, G G G , G G0-0...

175 PART NUMBER INDEX G G G G G G G G G , G G G G G G-00..., G-00..., G ,,,,, G G G G G , G , G , G-00..., 0, G , G , G G-00..., G G G ,, G G G G G G G G-00..., G-0... G G G-0... G G G G G G G G , G , G G-0... G-0... G-0... G-0... G-0... G-0... G-0..., G-00..., G , G G G-00..., G-00..., G , GB... GC... GD... G G G-00...,, G G G G-00..., G , G G G G G-00..., G-00..., G-00..., G-0... G-0..., 0,,,, G-00..., G G ,,,, G G G G G ,, G G G G G G G , - G , G G G , - G-0... G-... G G G-0...-,,,,, G-0...-,,,,, G-0...,,,, G-0..., G-0... G-0... GA... GB... G G G G G , G-00..., 0 G G-0... G-0... G G G G G G G G G G G G G G G G G G G G G G G G ,, G ,, G0-... G0-... G G G G G G G G G G G G G , G-0... G G-0... G G-0... G G G G0-... G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G

176 PART NUMBER INDEX G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G G-0... G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G G-0... G-0... G G G G G G G G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G-0... G G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G G-0... G-0... G G G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G G-0... G-... G-0... G-... G-... G-... G-... G-... G-... G-... G-... G-0... G-... G-... G-... G-... G-... G-... G-... G-... G-0... G-... G-... G-... G-0... G-0... G-... G-... G-... G-... G-...0 G G G G G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G-... G-... G-... G-... G-... G-... G-... G-... G-0... G-... G-... G G G0-0..., G G0-0..., G G G G G G G G G , - G G G G G G G G G G G G G G G G G G G G G

177 PART NUMBER INDEX G G G G G G G G G G G G G G G G G G G G G G G G G G G G G , G G , G G G G G G G G-0... G G G G G G G G G-00..., G G-0... G-0... G-0..., G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G G-0... G-0... G-0... G-0... G-0... G-0... G-0... G G-0... G G-0... G-0... G-0... G-0... G G G G G G G G G-0... G G G0A... G0A..., G G G G G , - G G G G G G G G G G G , 0 G ,, G ,, MKI-C-QSC0... MKI-MTD-... MKI-MTD-0... MKI-SERUTD-0... MKI-U-COV0... MKI-U-COV0... MKI-U-COV0... MKI-U-DISK... MKI-U-DISK... MKI-U-T0CW-S... MKI-U-TGPC... MKI-U-TGPC-S... MKI-U-TME... MKI-U-TME-S... MKI-U-TDHS... MKI-U-TDHS-S... MKI-U-TATA-S... MKI-U-TGHG-S... MKI-U-TOP-S... MKI-U-THBL-S... MKI-U-TATX... MKI-U-TATX-S... MKI-U-TSUL-S... MKI-U-TTNX... MKI-U-TTNX-S... MKI-UTD-0... MKI-Z-0... MKI-Z-0... RDT-00..., 0 RDT RMSN-...

178 PRODUCT INDEX Product Index Agilent J&W GC Columns Application and Method Guides ASTM Methods...- Application Cross Reference Guide...- EPA Methods Drinking Water...- Solid Waste...- Waste Water...- United States Pharmacopoeia (USP) GC Phases... Capillary Columns By Group Foods, Flavors and Fragrances...0 High Temperature... Life Sciences... Low-bleed GC/MS... Non-Bonded... PAH...0 PLOT...0 Pesticides... Petroleum... Polyethylene Glycol (PEG)...- Premium Polysiloxane... Semivolatiles... Ultra Inert... Volatiles... By Stationary Phase Biodiesel...- CAM... CarboBOND... CarboPLOT P... Carbowax 0M and HP-0M... CP-0... CP-AlO/KCl...0- CP-AlO/NaSO...0- CP-Carbowax 00 for Volatiles in Alcohol...0 CP-Chirasil Val... CP-Chirasil-Dex CB... CP-Cyclodextrin-b-,,-M-... CP-FFAP CB for Free Fatty Acids in Dairy Products...0 CP-Molsieve Å... CP-Select CB... CP-Select CB for MTBE...0 CP-Sil CB... CP-Sil CB...0 CP-Sil CB for Pesticides... CP-Sil CB... CP-Sil CB... CP-Sil CB... CP-Sil CB...- CP-Sil CB for Formaldehyde... CP-Sil CB for Sulfur... CP-Sil /C CB for PCB... CP-Sil CB...- CP-Sil CB for Amines... CP-Sil CB for PCB... CP-Sil CB for Pesticides... CP-Sil...0 CP-Sil for Dioxins... CP-Sil for FAME...0 CP-Sil PAH CB UltiMetal... CP-Sil PONA CB... CP-Sil PONA for ASTM D... CP-SilicaPLOT... CP-SimDist...- CP-TAP CB for Triglycerides...0 CP-TCEP for Alcohols in Gasoline... CP-Volamine... CP-Wax CB...- CP-Wax CB...0 CP-Wax CB for Glycols and Alcohols...0 CP-Wax FFAP CB...0 CP-Wax for Volatile Amines and Diamines... CycloSil-B...0 Cyclodex-B... DB-...- DB-0... DB-... DB-0... DB-0P... DB-ht... DB-ms...0 DB-ht... DB-ms... DB-ms Ultra Inert... DB DB-0... DB-... DB-ms... DB-... DB-...0 DB-... DB-ms...0 DB-ms Ultra Inert... DB-...- DB-... DB DB-ht... DB-ms DB-ms EVDX... DB-ms Ultra Inert...0 DB-0... DB-... DB- Ultra Inert..., DB-ALC... DB-ALC... DB-CLP... DB-CLP... DB-Dioxin... DB-EUPAH...0 DB-FFAP... DB-HT SimDis...0 DB-MTBE...0 DB-Petro... DB-Select UI for <>..., DB-Sulfur SCD... DB-TPH...0 DB-UI 0D Ultra Inert... DB-UI 0D for Semivolatiles... DB-VRX...00 DB-WAX...- DB-WAX FF...- DB-WAXetr... DB-XLB...0 DX-... DX-... GS-Alumina... GS-Alumina KCl... GS-CarbonPLOT... GS-GasPro... GS-OxyPLOT... GS-Q... HP-...- HP- Aluminum Clad... HP-0... HP-... HP-ms... HP-ms Ultra Inert... HP-0M... HP-... HP-...- HP HP-ms...0 HP-ms Semivolatile... HP-ms Ultra Inert...0 HP-...0 HP-Chiral b... HP-FFAP... HP-Fast Residual Solvent... HP-INNOWax... HP-PAS... HP-PLOT AlO KCl... HP-PLOT AlO M... HP-PLOT AlO S... HP-PLOT Molesieve... HP-PLOT Q... HP-PLOT U... HP-PONA... HP-VOC...0 Lowox... PoraBOND Q... PoraBOND U... PoraPLOT Amines... PoraPLOT Q... PoraPLOT Q-HT... PoraPLOT S... PoraPLOT U... Rapid-MS... SE-0... SE-... Select AlO MAPD... Select Biodiesel... Select FAME...0 Select Low Sulfur... Select Mineral Oil...0 Select PAH...0 Select Silanes...0 Select for Permanent Gases... Ultra... Ultra... VF-0ms...- VF-0 Pesticides... VF-0ms... VF-ms...0 VF-ms...- VF-00ms... VF-ms...0

179 PRODUCT INDEX VF-ms...0 VF- Pesticides... VF-ht... VF-ms VF-ms... VF-DA... VF-WAXms...- VF-Xms...0 Metal Columns... Column Selection Column Diameter...- Column Film Thickness...0- Column Length...- Gas-Solid or PLOT Columns... Polarity...- Selecting Stationary Phases...- Stationary Phase Selection Summary... Custom Ordering... Fused Silica Tubing Deactivated...- Undeactivated... Guard Columns DuraGuard... EZ-Guard... Installation and Troubleshooting Causes of Column Performance Degradation...- Evaluating the Problem...- Quick Reference Guide...- Troubleshooting Guides Baseline Instability or Disturbances... Change in Peak Size... Excessive Baseline Noise... Loss of Resolution... Retention Time Shift... Split Peaks... Tailing Peaks... LTM Column Modules...- Packed Columns 0.% SP % OV % Carbowax 0M (G, G$)... 0% Carbowax 0M (G, G$) + % KOH... 0% OV % PEG-0M... 0% SE % UC W...0 % UC W...0 % Carbowax % Hallcomid M-... % SP % Carbowax 0M (G, G$)... 0% OV % PEG-0M... 0% Sebaconitrile... 0% Sebaconitrile/% HPO... 0% TCEP...0 % DC-00 (00 cst)... % SP % DC 00/ % DC-00 (00 cst)... % DC-00 (00 cst)... % Carbowax 0M (G, G$)...0 % Carbowax M + % Polyphenolether ring + % KOH... Carbosieve S-II...0 Carboxen Chromosorb 0... Chromosorb 0... HayeSep A... HayeSep D... HayeSep DB... HayeSep N... HayeSep N + HayeSep R :... HayeSep P... HayeSep Q... HayeSep R... HayeSep T... MolSieve X... MolSieve Å... Porapak N... Porapak N + Porapak R :... Porapak Q... Porapak QS... Porapak R... Porapak T... Silica Gel... Test Standards...- Agilent Supplies 0A GC System... Bulk GC Supplies... Capillary Column Ferrules and Nuts Column Nuts...-0 Ferrule Selection Recommendations...- For LTM Rapid Heating/Cooling System... For NCD and SCD... Reducing... Short and Long Ferrules... Specialty...-0 Straight... Capillary Flow Technology Column/Retention Gap Installation... Ferrules... Fittings... Ultimate Union... Column Connectors and Splitters Graphpak... Press-fit... Column Nuts...-0 Detector Systems Electron Capture Detector (ECD) Flame Ionization Detector (FID)...- Flame Photometric Detector (FPD)...0- Nitrogen Chemiluminescence Detector (NCD)...- Nitrogen Phosphorus Detector (NPD)...- Sulfur Chemiluminescence Detector (SCD)...- Thermal Conductivity Detector (TCD) GC Standards... GC/MS 0-MS MS Ion Trap Triple Quadropole GC/MS Q-TOF for GC/MS...- Cleaning and Maintenance...- Gas Clean Filters... GC/MSD Interface...0- Ion Source...- Chemical Ionization (CI) Ion Source...- Electron Impact (EI) Ion Source...- MSD Contamination...- MSD Electron Multipliers and Replacement Horn... MSD Filaments... Maintenance Schedule... Quadropole Mass Filter... Recommended MS Interface Connections... Standards Analyzer Kit Standards... Test and Performance Samples... Vacuum Systems and Pumps... Diffusion Pump... Foreline Pump...0 Pressure Symptoms...- Quiet Cover... Vent Valve Supplies... Inlet Liners...- Specialty Injection Direct Connect... MultiMode Inlet Heavy Matrix... PTV... Split, Original Deactivation... Splitless, Original Deactivation...0 Ultra Inert... Inlet Septa... Advanced Green... Bleed and Temperature Optimized (BTO)... General Purpose... Long-Life... Inlet Systems Cool On-Column...-0 Flip Top Inlet Sealing System... Multimode...- Programmable Temperature Vaporizer (PTV)...- Purged Packed...- Split/Splitless Inlet Seals..., - Large Valve Oven... Liner O-rings... Maintenance Schedule...- Markes Thermal Desorption...- Merlin Microseal...- Oven Exhaust Deflector... Purge and Trap Systems Archon... Teledyne Tekmar...- Sample Introduction Systems A Automatic Liquid Sampler...0 A Headspace Sampler...- Automatic Liquid Sampler... GA Network Headspace Sampler... GA Network Headspace Sampler... G0A XLSI Accessory... Syringes... / On-Column Autosampler Syringes... Blue Line Autosampler Syringes for A ALS Advanced Sample Enhancement... Fitted Plungers... PTFE-Tipped Plungers... Gold Standard Autosampler Syringes Straight Needle, and s Gauge...0 Tapered Needle, -s Gauge... HP 0// Autosampler Syringes... Needle Gauge... Needle Termination... Needle Tip Design... Valves and Loops...-

180 PRODUCT INDEX Vials and Closures Headspace 0 mm Caps and Septa... CombiPAL mm Screw Top Caps with Septa... CombiPAL Screw Top Vials... Convenience Packs... Crimp Top Vials... High Performance Septa...- Electronic Crimpers and Decappers...0 Manual Crimpers and Decappers... Applications Energy and Fuels... Environmental Air Analysis... Hydrocarbons...0 Pesticides and Herbicides...0 Semivolatiles... Volatiles... Food, Flavor and Fragrance... Industrial Chemical...0 Forensic Toxicology and Pharma... CrossLab Supplies Bruker, Varian GC Systems Autosampler Syringes...0 Capillary Column Ferrules...0 Column Nuts...0 Detector Replacement Flame Ionization Detector (FID)... Pulsed Flame Photometric Detector (PFPD)...-0 Thermal Conductivity Detector (TCD)... Thermionic Specific Detector (TSD)...0 Injector Replacement 0 Packed/Wide Bore On-Column (PWOC) injector... 0 Packed/0 µm Capillary Column Injector... 0 Large Volume Injector (LVI)... 0 Cool On-Column (COC) Injector... Split/Splitless Injector... Inlet Liners 00/0 Injector...0 0/0 Injector...0 0/0 Injector /0 Injector Injector Inlet Septa...- Liner O-rings...0 Packed Column Ferrules...0 CTC GC Autosamplers Autosampler Syringes... Column Ferrules...- Inlet Liners...- Inlet Septa...-0 Advanced Green...0 Bleed and Temperature Optimized (BTO)...0 General Purpose...0 Long-Life...0 Liner O-rings... Perkin Elmer GC Systems Autosampler Syringes... Capillary Column Ferrules... Column Nuts... Inlet Liners AutoSystem...- AutoSystem XL...- Clarus...- Inlet Septa... Liner O-rings... Packed Column Ferrules... Shimadzu GC Systems Autosampler Syringes... Capillary Column Ferrules... Column Nuts... Inlet Liners Systems...0 A Systems and 00 Plus Systems... 0 Systems... Inlet Septa... Liner O-rings...0 Packed Column Ferrules... Syringes...- Thermo Scientific GC Systems Autosampler Syringes... Capillary Column Ferrules... Column Nuts... Inlet Liners Focus Systems... Trace Systems... Inlet Septa...- Liner O-rings... 0

181 APPLICATION TITLE INDEX Application Title Index,-Butadiene...,-Butadiene Purity... 0 ng/µl Semivolatile Checkout Standard on a 0 m x 0. mm, 0. µm Agilent J&W DB-UI 0D Capillary GC Column using an Ultra Inert Liner with Wool... + EU Priority PAHs...0 Component FAME Mix... Semi-volatile Components on an Agilent J&W DB-UI 0D...0 A Acids...0 Acrylate Impurities I... Acrylate Impurities II... Acrylates... Agilent's Ultra Inert Test Probe Mixture... Alcohol Beverage Standard... Alcohols I...0 Alcohols II...0 Alcohols III...0 Aldehydes and Acids... Aldehydes and Ketones... Alditol Acetates... Amines and Alcohols...0 Amines and Nitriles...0 Amines in Water... Amphetamines and Precursors TMS Derivatives... Anabolic Steroids... Analysis of Acetylenes' Mixture... Analysis of Amino Alcohols in Water...0 Analysis of Drugs of Abuse in Urine via GC/MS... Analysis of Ethanolamines...0 Analysis of Fragrance and Allergens... Analysis of Oxygenates in Mixed C Streams... Analysis of Oxygenates in a C to C Hydrocarbon Mix...00 Analysis of Polycyclic Aromatic Hydrocarbons...0 Analysis of Process Gas...0 Analysis of Semivolatiles...0 Analysis of Solvents... Analysis of Volatile Organic Compounds in Environmental Waters Using the Agilent A Headspace and 0B/A GC/MS... Anesthetics... Anilines... Anticonvulsants... Antiepileptic Drugs... Antihistamines... Aroclors 0- (without )... Aromatic Solvents...0 Aromatics Analysis ASTM D Analytes... Aromatics Analysis Ethylbenzene Impurities... Aromatics I... Aromatics II... Aromatics in Finished Gasoline ASTM Method D... Aspirin and Ibuprofen in Methanol... Automated Cleanup of PCB extracts from Waste Oil Using A Sample Prep Workbench... B Bacterial Fatty Acid Methyl Esters... Barbiturates... Baseline Resolution of Air/CO, CO, and Methane in a Natural Gas Sample... Benzodiazepines I... Benzodiazepines II...0 Blood Alcohols I (Static Headspace/Split)... Blood Alcohols II (Static Headspace/Split)... Blood Pollutants I... Blood Pollutants II...0 Bourbon... Butter Triglycerides I... Butter Triglycerides II... C C to C Hydrocarbon Mix...0 C and C Halocarbons (Freons)... CLP Pesticides... Canola Oil Margarine Partially Hydrogenated FAMEs AOCS Method c-... Chiral Compounds in Essential Oils and Fragrances...0 Chlorinated Isooctane... Chlorinated Pesticides, EPA Method 0... Citrus Flavored Carbonated Beverage (Soda)... CLP Pesticides... Cold-pressed Orange Oil... Column Performance for USP <> Standards... Common Drug Screen... Congeners in DIN Method PCBs... D DB-UI µl/l Fermented Beverage Standard Mix... DB-UI Organic Acid Performance...0 DB-Select UI for <> Megabore Early Eluting Peaks... Denatured Fuel Ethanol ASTM D0... Detailed Hydrocarbon Analysis of Petroleum Naphthas Through N-nonane Using ASTM D...0 Determination of Chlorophenols in Water and Soil...0 Diesel Analysis...00 Diesel Fuel...0 Dioxins and Dibenzofurans...0 Direct Comparison for Rapid CLP (Contract Laboratory Program) Pesticide Analysis... Drug Screen...0 E EPA Halogenated Pesticides on "0" Type Phases... EPA Air Analysis Compendium Method TO- Standard... EPA Air Analysis Method TO- ( ppbv standard)... EPA Method 0., dibromoethane (EDB),,-dibromo--chloropropane (DBCP), and,,-trichloropropane (TCP)...0 EPA Method 0. Chlorinated Pesticides and Herbicides...0 EPA Method... EPA Method... EPA Method Chlorinated Solvents, Trihalomethanes (THMs), and Disinfection Byproducts (DBPs)...0 EPA Method... EPA Volatiles by GC/MS (Split Injector)..., Essential Oils... Esters I... Esters II... Esters III... Ethers... Ethoxyethanol...0 Ethylene... Ethylene Glycol Mixture... Ethylene Oxide... Ethylene Oxide Synthetic Standard... European Red List Volatiles... Extended Analyte List for EPA Method 0 (ELCD)... Extended Hydrocarbon Analysis I... Extended Hydrocarbon Analysis II... Extended Temperature Program Resolving Congeners and... F FAME Standard..., FAMEs... Fast Analysis of Aromatic Solvent... Fast Analysis of Permanent Gases and CO using Tandem PLOT columns... Fast CLP Pesticides...0 Fast Screening of FAME Isomers in Butter... Fast Separation of Silanes... Fast VOC Analysis... Fentanyls... Flavor Mixture... Formaldehyde Underivatized... Formaldehyde, 0 ppb...0 Formaldehyde-DNPH Derivative... Fragrance Allergens... Fragrance Reference Standard..., Free Organic Acids/C -C Isomers...0 Free Phenols... Free Steroids... G Gasoline Unleaded ASTM D... Glycols I... Glycols II...0 Glycols III...0 Glycols/Diols...

182 APPLICATION TITLE INDEX H Hallucinogens... Halocarbons... Halogenated Hydrocarbons I...0 Halogenated Hydrocarbons II... Halothane... Herbicides I... Herbicides II... High Resolution Phenol Analysis by GC/MS... High Resolution Separation of Xylene Isomers... High Speed VOC, EPA Method 0... I Impurities in Ethylbenzene... Impurities in Ethylene... Impurities in Mixed Xylenes... Impurities in Propylene... Impurities in Styrene... Impurities in p-xylene ASTM D... Inorganic Gases...0 Inorganic Hydride Gases... L Lavender Oil Characterization... Lemon Oil... M Marijuana (Δ-THC) and Major Metabolites TMS Derivatives... Menthol...0 Mercaptans... N N O I... N O II... N O III... Narcotics... Narcotics and Adulterants... Natural Gas... Nitrogen Containing Herbicides (EPA Method 0)... Nitrogen-based Solvents I... Nitrogen-based Solvents II... Nitrogen/Phosphorus Containing Pesticides, EPA Method 0... Noble Gases... n-paraffin Standard... O Organic Acids...0, 0 Organochlorine Pesticides..., Organochlorine Pesticides I EPA Method 0A... Organochlorine Pesticides II EPA Method 0A...0 Organochlorine Pesticides III... Organochlorine Pesticides IV... Organochlorine Pesticides to EPA via GC/MS... Organochlorine Pesticides, DB-/DB-0P... Organochlorine Pesticides, EPA Method 0B...0 Organophosphorous Pesticides in Apple Matrix... Organophosphorus Pesticide Residues in Olive Oil Extract... Organotin Compounds I... Organotin Compounds II... Over-the-Counter Pain Killers TMS Derivatives... Oxygenates in Gasoline ASTM D (GC-OFID)... P PAHs...0 PBDEs... PBDEs by ECD...0 PCBs by EPA Method 0... PFBHA Derivative... PONA Mix as Specified by AFNOR Method #... Peppermint Oil... Perfume...0 Permanent Gases... Permanent Gases on a Thick Film Molsieve Column... Pesticides and Fire Retardants (US EPA )... Pesticides in Sunflower Oil... Pesticides, EPA Phenols... Phenols According to EPA Method Phenols I...0 Phenols II...0 Phenols III...0 Phenoxy Acid Herbicides Methyl Derivatives, EPA A... Polybrominated Diphenyl Ethers (PBDEs)...0 Polyethylene... Polyethyleneamines...0 Polymer Additives... Primary Amines...0 Propylene... Pyrethrins... Pyrolysates of Polystyrene... R Reference Gas Oil... Refinery Gas...0 Refinery Gas I... Regular Unleaded Gasoline (California Phase ) "Normal" GC Run I... Regular Unleaded Gasoline (California Phase ) "Normal" GC Run II... Residual Solvents, DMI Diluent... Residual Solvents, USP...0 Rosemary Oil... S Sedative Hypnotics... Selected Oxygenates... Semivolatile Compounds, US EPA Method 0... Separation of TMS-derivatized Sugars using VF-ms... Separation of cis-trans FAME Isomers... Simulated Distillation... Solvents... Solvents I... Solvents II... Solvents III... Solvents IV... Spearmint Oil... Spearmint Oil (Western)... Strawberry Syrup... Substituted Anilines... Sulfur Compounds in Naphtha... Sulfur Compounds in Natural Gas Synthetic Mixture... Sulfur Compounds in Propylene ( ppm)..., Sulfur Gas Analysis in Light Hydrocarbon Streams I...0 Sulfur Gas Analysis in Light Hydrocarbon Streams II... Sulfur Gases... Sulfur Impurities in Propylene... Sulfur Standards in Toluene... Sulfur in Air...0 T Tetrachlorodibenzo-p-furans... Tocopherols... Trace Active Amines, 0 ng on-column...0 Trace Level Polycyclic Aromatic Hydrocarbon (PAH) Analyses... Trace Oxygenates in Light Hydrocarbon Matrices... Trace Sulfur Compounds in Methane (0 ppbv)... Tricyclic Antipsychotics... Triethylene Glycol and Impurities... U US EPA Method 0 (Phthalate Esters)... Underivatized Drugs of Abuse Agilent Fast Toxicology Analyzer... Unleaded Gasoline...0, Urine Drug Screen... V Volatile Amines...0 Y Ylang Ylang Oil...

183 COMPOUND INDEX Compound Index A Acenaphthalene...0 Acenaphthalene-d0... Acenaphthene...0,,, 0 Acenaphthene-d0...,, Acenaphthylene...0,,, Acephate..., Acetal (acetaldehyde diethyl acetal)... Acetaldehyde...0,,,, 00,,,, -0 Acetaminophen..., Acetic acid...0,, 0, 0, Acetone...,,, 0, -, -,, 0, -, 00,, -,, -, -0 Acetone-d...0 Acetonitrile..., -,,, - Acetyl aldehyde... Acetylcedrene...0 -Acetylcodeine..., Acetylene...0, -0 Acetylsalicylic acid (aspirin)... Acifluorofen... Acrolein...,, - Acrylamide...0 Acrylic acid...0 Acrylonitrile...,,, - Air/CO...,, 0 Alachlor...0,,, 0, -, -0 Aldrin...0, 0,, -,, 0-, -0, Alfentanyl... Allobarbital..., Allyl acrylate... Allyl alcohol..., Allyl butyrate...- Allyl chloride...,,, Allyl ether... Allyl ethyl ether... Alpha isomethyl ionone... Alphenal... Alprazolam...,, -0 Ametryn..., - -Aminoazotoluene... -Amino--butanol...0 -Amino-ethanol...0 Aminoethylethanolamine... n-(-aminoethyl) piperazine... -Aminonaphthalene... -Amino--nitronaphthalene...0 -Amino--pentanol...0 -Amino--propaol...0 Amitriptyline... Amobarbital..., Amphetamine...,, Amyl acetate...,, - Amyl alcohol... n-amyl alcohol... Amyl butyrate... Amyl cinnamic alcohol... Amyl cinnamyl alcohol... Amyl cinnamyl aldehyde... n-amyl mercaptan... tert-amyl mercaptan... tert-amyl methyl ether (TAME)...,,,,, 00, n-amyl salicylate...-0 α-androstan-α-ol--one (stanolone)... Androsterone... -b-androsterone... Aniline...,, 0, Anisic alcohol... Anisyl alcohol... Antazoline... Anthracene...0,,,, 0 Anthracene-d0... Aprobarbital..., Arabinitol... Arabitol... Arachidic acid (eicosanoic acid)...0 Arachidic acid methyl ester..., Arachidonic acid methyl ester..., Argon..., Arsine... Atraton...- Atrazine..., -0, -, Azinphos-ethyl... Azinphos methyl..., Azobenzene... Azulene...0 B Balan... Barbital... BDE...0, Behenic acid methyl ester..., Benactyzine... Bentazone... Benthiocarb... Benz[a]anthracene...0,, Benz[a]anthracene-,-dione...0 Benzaldehyde...-,, Benzaldehyde, methoxy...,-benzanthracene...0 Benzene...0,,, -, -,, -, -,, -,, 0, 0, -, -,,, - Benzene-d... Benzene ethanol...-0 Benzidine..., Benzo[a]anthracene...0, Benzocaine... Benzo[b]fluoranthene...0, 0,,,, Benzo[j]fluoranthene...0 Benzo[k]fluoranthene...0, 0,,,, 0 Benzo[b]fluoroanthene...0 Benzo[c]fluorene...0,-Benzofluorene...0 Benzo[g,h,i]perylene...0, 0,,,, 0 Benzo[a]pyrene...0,,,, 0 Benzo[e]pyrene...0 Benzoic acid... Benzonitrile...0, - Benzophenone...-,-Benzoquinoline...0 Benzothiophene... Benzphetamine..., Benz[a]pyrene...0 Benzyl acetate...-0,, - Benzyl alcohol..., -,,, 0, 0 Benzylamine Benzyl benzoate..., -,,, Benzyl butyl phthalate... Benzyl chloride...,, Benzyl cinnamate..., Benzyl ether... n-benzylmethylamine...0 Benzyl salicylate..., 0-,, α-bergamotene... trans-α-bergamotene... α-bhc..0, 0,, -,, 0-, -0 b-bhc..0, 0,, -,, 0-, -0 δ-bhc..0, 0,, -,, 0-, -0 γ-bhc...0, 0,, -,, 0-, -0 BHEB... BHT...,, Bifenthrin... Bioallethrin... Biphenyl...0 b-bisabolene...,, α-bisabolol... Borneol..., -0, Borneol acetate... Bornyl acetate...- α-bourbonene... b-bourbonene..., BPE (PB)... Bromacil...-, - Bromazepam..., 0 Bromoacetic acid... Bromoacetone... -Bromoaniline...0, Bromobenzene...,, -,, - -Bromobiphenyl...-0 Bromochloroacetic acid... Bromochloroacetonitrile...0, Bromochlorodifluoromethane... Bromochloromethane...,, -, - 0,, Bromodichloroacetic acid... Bromodichloromethane...0, 0,,, -,, -Bromo-,-dinitroaniline... Bromoethane (ethyl bromide)..., Bromofluorobenzene... -Bromofluorobenzene...,, 0, -, Bromoform...0, 0,,, -,, Bromofos... Bromomethane...,, -, -, -Bromo--nitrobenzene...0, -0 Bromopheniramine..., -Bromophenyl-phenylether... -Bromopyridine...0 Bromotrifluoromethane... Buclizine... Bufotenine... Butabarbital..., Butacaine... Butachlor..., 0, -

184 COMPOUND INDEX,-Butadiene...-,,-Butadiene..., -, Butalbital... Butanal...,-Butandiol...,,-Butandiol...,-Butandiol... Butane..., 0 iso-butane..., 0- n-butane..., 0, -0,, n-butane/cis--butene...,-butanediol...0,-butanediol...0,-butanediol...0, Butanedione (VDK)...,-Butanedione (diacetyl)...- -Butanethiol...-,, Butanol...- -Butanol...,,, 00, 0, 0-0,, -0 -Butanol...,, iso-butanol...0 n-butanol...,, 0 sec-butanol...,, 0, 0,, 0 tert-butanol..., 0, 0,, 0 -Butanone (MEK)...,,, 0,, 00,,, -Butanthiol... Butene... Butene-..., - -Butene...-, -,, cis--butene...-0 trans--butene...- -Butene/methyl acetylene...0 -Buten--ol...0, 0 -Buten--ol (crotyl alcohol)...0, 0 Butethal... Butlypentyltin... -Butoxyethanol...0, 0 bis(-n-butoxyethyl) phthalate... Butyl acetate...-, - n-butyl acetate... sec-butyl acetate...- n-butylbenzene...,,,,,,, 0, tert-butyl acetate...- Butyl acrylate...- n-butyl acrylate... n-butyl alcohol..., s-butyl alcohol... sec-butyl alcohol...-, -0 tert-butyl alcohol...,,, -0 Butyl aldehyde..., Butylate..., Butylbenzene...,, 0, - s-butylbenzene..., sec-butylbenzene...,, -,,,, 0, - tert-butylbenzene...,, -,,,, 0, 0, - Butyl benzyl phthalate..., Butyl caproate... Butyl cellosolve... Butyl cellosolve acetate... Butylene...0 Butyl ether... Butyl ethyl ether... Butyl heptanoate... -Butyl mercaptan... n-butyl mercaptan... tert-butyl mercaptan..., sec-butyl methacrylate... Butyl methyl ether... tert-butyl methyl ether (MTBE)... Butyl propionate..., - -tert-butyltoluene...- Butyl valerate... -Butyne (dimethylacetylene)...- -Butyne (ethylacetylene)...- -sec-butyl-,-dinitrophenol (dionseb)..., Butyraldehyde...00, Butyric acid...0, 0-0, iso-butyric acid... n-butyric acid...0 Butyric acid methyl ester..., C Cadinene... δ-cadinene...-, γ-cadinene...- Caffeine..., 0-, Camphene..., -, 0,, Camphor..., -, Capric acid methyl ester...,, Caproic acid methyl ester...,, 0,, 0 Caprylic acid methyl ester...,, Captafol...0, -0 Captan..., -0 d-carane... Carbamazepine...0, Carbazole..., 0 Carbepoxide 0/... Carbinoxamine... Carbon dioxide...,,,, 0, 0 CO/air..., 0 Carbon disulfide...,,, 0,,,, Carbon monoxide... Carbon tetrachloride...0, 0,,, -,, 0,,, - Carbonyl sulfide (COS)...0, -,,, 0, Carbophenothion..., Carboxin..., - tau-cardinol... -Carene... Carfentanyl... Carvacrol...0 cis-carveol..., trans-carveol...,, Carvone... l-carvone... Carvone phenylethyl acetate... cis-carvyl acetate..., Caryophyllene... α-caryophyllene... β-caryophyllene..., -, - Caryophyllene oxide... Celestolide... Cellosolve acetate... Cetearyl decanoate...- Cetearyl octanoate...- Chloral hydrate...0, Chloramben... Chlorcyclizine..., α-chlordane...0, 0,, -,, 0-, -0 γ-chlordane...0, 0,, -,, 0-, -0 Chlordiazepoxide... Chloroacetic acid... Chloroacetonitrile...,, -Chloroaniline...0, -Chloroaniline...0, -Chloroaniline..., 0, Chlorobenzene...,, -, -,, 0, -,,, Chlorobenzene-d...0,, Chlorobenzilate...0,,, 0-,, -0 -Chlorobenzonitrile...0 -Chlorobiphenyl... -Chlorobutane...,,, 0,, -0 -Chlorobutane...-0 Chlorodibromoacetic acid... -Chloro-,-difluoroethane... Chlorodifluoromethane... -Chloro-,-dinitroaniline... Chloroethane...,,, -, -, -Chloroethanol..., bis(-chloroethoxy) methane... bis(-chloroethyl) ether... -Chloroethyl vinyl ether... -Chloro--fluorobenzene...,, Chloroform...0, 0,,, -,, 0,,,, -0 -Chlorohexane..., 0, -Chloro isooctane... -Chloro isooctane... -Chloro isooctane... bis(-chloroisopropyl) ether..., Chloromethane...,,, -, -, -Chloro--methylaniline... -Chloromethyl,'-dimethyl pentane... -Chloro--methylphenol... -Chloro--methylphenol... -Chloro--methylphenol...,, -, 0 -Chloronaphthalene... Chloroneb...0,,, 0-,, -0 -Chloro--nitroaniline... -Chloro--nitroaniline... -Chloro--nitrobenzene...- -Chloro--nitrobenzotrifluoride...-0 Chloropentafluoroethane... -Chlorophenol...0,,, -, 0, 0 -Chlorophenol...0 -Chlorophenol...0, -Chlorophenyl-phenyl ether... Chloropicrin...0, Chloroprene... -Chloropropane... -Chloropropene... -Chloropropene (allyl chloride)..., 0, -Chloropropionitrile... Chloropropylate...0, -0

185 COMPOUND INDEX Chloropyrifos... -Chlorostyrene...- -Chloro-,,,-tetrafluoroethane... Chlorothalonil...0,,, 0-, -0, -Chlorotoluene...,, -,, 0, - -Chlorotoluene..., 0, - -Chlorotoluene...,,,,, 0, -, Chlorotrifluoromethane... Chlorpheniramine..., Chlorpropham..., Chlorprothixene... Chlorpyrifos...,,, -Chlortestosterone--acetate (clostebol)... -α-cholestane... Cholesterol... Chrysene...0, 0,,,, 0 Chrysene-d...-,,,-Cineol..., -, Cineole...0 Cinerin I... Cinerin II... Cinnamaldehyde..., trans-cinnamaldehyde...0 Cinnamic alcohol... Cinnamyl acetate..., trans-cinnamyl acetate... Cinnamyl alcohol... Cinnamyl cinnamate...- Cinnamyl phenyl acetate...- Cinnanzine... Citral... Citronellal..., Citronellic acid...0 Citronellol...-,, Citronellyl acetate...- Citronellyl formate...- Citronellyl propionate... Citronellyl tiglate...- cis-citronellyl tiglate... trans-citronellyl tiglate... Clemizole... Clobazam...0 Clonazam... Clonazepam...,, -0 Cocaine...-, Codeine...,, -, Commamyl acetate...0 α-copaene..., -, Coprostane (-ß-cholestane)... Cotinine... Coumarin...0-, -Cresol...0 -Cresol...0 -Cresol...0 m-cresol...-, 0 o-cresol...-, 0 p-cresol...-, 0 Crotonaldehyde..., Cumene...,,,, Cumic aldehyde... Cyanazine...,, 0, -Cyanopyridine...0 -Cyanopyridine...0 Cyclizine... Cycloate..., Cyclohexane..., -, -,, -,,,, 0- Cyclohexanol...0, 0-0 Cyclohexanone... -Cyclohexyl-,-dinitrophenol... Cyclohexyl methacrylate... Cyclopenta[c,d]pyrene...0 Cyclopentane...-,, 0 Cyclopentanol...0, 0 Cyclopentanone... Cyclopentene...- -Cyclopentene... Cyclopentylbarbital... Cyclopropane...- Cyheptamide... ο-cymene... p-cymene...,, r-cymene..., - D,-D... Dalapon...,,-DB...,'-DDD...0, 0,,,, 0-,, o,p -DDD..., p,p'-ddd..., -, -0,,'-DDE...0, 0,,,, 0-,, p,p'-dde..., -, -0, o,p -DDE...,,'-DDT...0, 0,,,, 0-,,,, o,p -DDT... p,p'-ddt..., -, -0, Decabromobiphenyl ether (decabde)...0 Decachlorobiphenyl...0, 0, -, 0-,. Decanal...,,0-Decandiol... Decane..., -, 0,,,, n-decane..., 0,,, -,0-Decanediol..., 0, Decanoic acid...0, Decanol... -Decanol...0, 0 n-decylamine DEF... -Dehydro--a-methyltestosterone (methandrostenolone)... Dehydroisoandrosterone (prasterone)... -Dehydrotestosterone acetate... -Dehydrotestosterone benzoate... -Dehydrotestosterone (boldenone)... -Dehydrotestosterone undecylenate... Delorazepam...0 Demoxepam..., 0 n-des... Desalkyl aurazepam... Desipramine...0 Desmethyldiazepam...0 n-desmethyl methsuximide... Dextromethorphan... Diacetone alcohol... Diacetyl... Diacetylmorphone (heroin)...,, -, Di-allate A...-0 Di-allate B...-0,-Diaminoanisole...,-Diaminotoluene...,-Diaminotoluene...0 Diamyl phthalate... Diazepam..., - Diazinon...,,, Dibenz[a,h]anthracene...0, 0,,,,,,-Dibenzanthracene...0,,,-Dibenzanthracene...0 Dibenzo[a,e]pyrene...0 Dibenzo[a,h]pyrene...0 Dibenzo[a,i]pyrene...0 Dibenzo[a,l]pyrene...0 Dibenzofuran..., 0 Dibenzo-p-dioxin...0 Dibenzothiophene...0 Dibenzyl ether...- Dibenzyl phthalate... Diborane... Dibromoacetic acid... Dibromoacetonitrile...0,,-Dibromobenzene...,'-Dibromobiphenyl... Dibromochloromethane...0, 0,,, -,,-Dibromo--chloropropane (DBCP)...0-0,,, -0, -, 0,,-Dibromoethane (EDB)...0, 0,,,, -,, 0, Dibromofluoromethane... Dibromomethane...,, -,,,-Dibromomethane... α, α-dibromo-m-xylene...-0,-dibromo--nitroaniline...,'-dibromooctafluorobiphenyl...,-dibromophenol...,-dibromopropane...,-dibromopropionic acid...,-dibromo-,,,-tetrafluoroethane... Dibucaine... Dibutyl chlorendate...-0 tert-dibutyl disulfide... Dibutyl ether...- Dibutylpentyltin... Dicamba... Dichlobenil... Dichlone...0 Dichloroacetic acid... Dichloroacetonitrile...0,,-Dichloroaniline...0,,-Dichlorobenzene.,,, -, -,, 0, -,,-Dichlorobenzene...,,,,, -, -,, 0, -,,-Dichlorobenzene...,,,,, -, -,, 0, -,,-Dichlorobenzene-d...,,,'-Dichlorobenzidine...,,,-Dichlorobenzoic acid...,-dichlorobiphenyl...

186 COMPOUND INDEX p,p'-dichlorobiphenyl... cis-dichlorobutene... cis-,-dichlorobutene... trans-dichlorobutene... trans-,-dichloro--butene...,, 0, Dichlorodifluoromethane...,,,,,,, Dichlorodimethyl silane... Dichloroethane-d...,-Dichloroethane...,, -,, 0,,-Dichloroethane...,,, -,, 0,,, cis-,-dichloroethane... trans-,-dichloroethane...,-dichloroethene...,, -, -,, 0,, cis-,-dichloroethene...,,,, -, trans-,-dichloroethene...,, -,,,,-Dichloroethylene..., cis-,-dichloroethylene... trans-,-dichloroethylene...,-dichloro--fluoroethane... Dichlorofluoromethane..., Dichloromethane...,,,,, Dichloromethyl silane...,-dichloro--nitroaniline...,-dichlorophenol...0,,-dichlorophenol...0,,, -, 0, 0,-Dichlorophenol...0,,-Dichlorophenol...0, -,-Dichlorophenol...0,,-Dichlorophenol...0, Dichloroprop...,-Dichloropropane...,-Dichloropropane...,, -, -,, 0,,-Dichloropropane...,,,,,,-Dichloropropane...,, -,,,-Dichloro--propanol...,-Dichloro--propanone...0,, -,-Dichloropropene...,,,,-Dichloro--propene... cis-,-dichloropropene...0 cis-,-dichloropropene...,, -, -,, trans-,-dichloropropene...0 trans-,-dichloropropene...,, -, -,, Dichlorotetrafluoroethane...,-Dichloro-,,,-tetrafluoroethane...,,-Dichloro-,,-trifluoroethane... Dichlorvos..., Dicyclohexylamine Dicyclohexyl phthalate... Dieldrin...0, 0,, -,, 0-, -0, Diethanolamine (DEA)...0, 0 Diethylamine...0 n,n-diethylaniline...0,-diethylaniline...0 Diethylbenzene...,-Diethylbenzene...,,-Diethylbenzene...,,-Diethylbenzene... Diethylbenzene isomer... Diethyl disulfide... Diethylene glycol...0- Diethylene glycol monobutyl ether..., 0 Diethylene glycol monoethyl ether..., 0 Diethylene glycol monomethyl ether..., 0 Diethylenetriamine... Diethyl ether...,,, 00,,,, -0,-Diethyl--ethylbenzene...,-Diethyl--ethylbenzene... Diethyl formamide (DEF)... Diethyl phthalate..., -, 0 Diethyl sulfide..., Diethyltryptamine...,-Difluorobenzene...0,, -,,-Difluoroethane... Difolatan... Diglyme..., 0 Dihexyl phthalate...,0-dihydroanthracene...0 trans-dihydro carveol acetate... Dihydro carvone..., trans-dihydro carvyl... Dihydrocodeine... Dihydropentaborane... Diisobutyl phthalate... Diisopropylamine...0,-Diisopropylbenzene...0, -,-Diisopropylbenzene...0, - Diisopropyl ether (DIPE)...,,, 00 Dimenhydrinate..., Dimethoate...,,, -Dimethoxybenzidine...,-Dimethoxyethane..., Dimethoxyethane (DME)... n,n-dimethylacetamide..., Dimethylamine...0 Dimethylamphetamine...,-Dimethylaniline...0,-Dimethylaniline...0,,-Dimethylbenz[a]anthracene...0,-Dimethylbenzene...0 n,n-dimethylbenzylamine...0,-dimethylbutane...-,,,-dimethylbutane...-,, Dimethyl disulfide... Dimethyl ether (DME)..., 0 Dimethylformamide (DMF)..., -, 0 n,n-dimethylformamide...-,,-dimethylhept--enal (melonal)...,,-dimethylhexane...,,,-dimethyl--imidazolidinone (DMI)...,-Dimethylnaphthalene...0,-Dimethyl--nitrobenzene...,-Dimethyl--nitrobenzene...,,-Dimethylpentane...,,-Dimethylpentane...-,,-Dimethylpentane...-,, Dimethylpentyltin...,-Dimethylphenanthrene...0,-Dimethylphenol...,-Dimethylphenol...,, -, 0,-Dimethylphenol...,-Dimethylphenol...,-Dimethylphenol... Dimethyl phthalate...,, Dimethyl sulfide...0, -,, -, Dimethyl sulfoxide (DMSO)...-,, -0 Dimethyl tetrachloroterephthalate (DCPA)...0, -,, 0-,,, -0 Dimethyltryptamine... Di-n-butyl phthalate...,,,-dinitroaniline...,'-dinitrobiphenyl...0,-dinitrofluorene...0,,-dinitro--methyl phenol...,,-dinitronaphthalene...0,-dinitronaphthalene...0,-dinitrophenol...,, -, 0, 0,-Dinitrophenol...,-Dinitrotoluene...,,,-Dinitrotoluene..., Di-n-octyl phthalate..., Dinonyl phthalate... Dinoseb...,,-Dioxalane...,-Dioxane...,,,,, -,, 0- Diphenamid..., - Diphenhydramine... Diphenylaniline...0,0-Diphenylanthracene...0 Diphenyl isophthalate... Diphenyl oxide...- Diphenyl phthalate... Diphenyl pyraline... Diphenyl sulfide... Dipropylene glycol...-0 Dipropyl ether...00 Disulfoton..., Diuron... cis-,-docosadienoic acid methyl ester..., cis-,,0,,,-docosahexaenoic acid methyl ester..., Docusane...0 Dodecahydrotriphenylene...0 γ-dodecalactone...- Dodecane..., -, 0, -,, n-dodecane..., 0,, - Dodecanoic acid...0 Dodecanol...- Dodecenal... n-dotriacontane... Doxylamine..., Droperidol... Dursban (chlorpyrifos)..., E cis-,-eicosadienoic acid methyl ester..., Eicosane...0, n-eicosane... cis-,,,,-eicosapentaenoic acid methyl ester..., cis-,,-eicosatrienoic acid methyl ester..., cis-,,-eicosatrienoic acid methyl ester..., cis--eicosenoic acid methyl ester..., Elaidic acid methyl ester...,

187 COMPOUND INDEX Endosulfan I...0, 0,, -,, 0-, -0 Endosulfan II...0, 0,, -,, 0-, -0 α-endosulfan... b Endosulfan... Endosulfan sulfate...0, 0,, -,, 0-, -0, Endrin...0, 0,, -,, 0-, -0, Endrin aldehyde...0, 0,, -,, 0-, -0 Endrin ketone...0, 0, -,, -, -0 Ephedrine... Epiandrosterone (trans-androsterone)... Epichlorohydrin..., EPTC..., - Eptam... Erucic acid methyl ester..., Erythritol... Esfenvalerate... Estazolam... -α-estradiol... b-estradiol... Estriol... Estrone... Ethane...0, -, -,, 0, Ethane/ethylene...0 Ethanethiol... Ethanol...,,,, -, 00, 0, 0, -,, -, -0 Ethanolamine...0 Ethchlorvynol... Ethinamate... Ethoprop..., - Ethosuximide... Ethotoin... -Ethoxyethanol...0, 0, 0,, bis(-ethoxyethyl) phthalate... -Ethoxyethyl acetate...0, - -Ethyl--hexanol... bis(-ethylhexyl) adipate... bis(-ethylhexyl) phthalate..., - Ethyl acetate..., -, -, -, -, -,,, -0 Ethyl acetylene... Ethyl acrylate...-, - Ethyl alcohol...0 -(Ethylamino)-ethanol...0 Ethyl and dimethyl thiophenes... Ethylbenzene...0,,, -, -,, -, -, -, -,, 0, 0, -,,,,, - Ethylbenzene-d0... Ethyl benzoate..., - Ethyl butanoate... -Ethyl--butanol...0 Ethyl t-butyl ether (ETBE),,,, 00,, Ethyl butyrate...-,, Ethyl caprate... Ethyl caproate... Ethyl caprylate... Ethyl cellosolve... Ethyl decanoate...- Ethyl dodecanoate...- Ethylene..., 0, -, -0, 0, Ethylene/acetylene... Ethylenediamine... Ethylene... Ethylene glycol...0, 0, -, -0 Ethylene glycol monoacetate...0 Ethylene glycol monobutyl ether...-0 Ethylene glycol monoethyl ether...-0 Ethylene glycol monoformate...0 Ethylene glycol monomethyl ether...-0 Ethylene glycol phenyl ether... Ethylene oxide..., 0, 0, Ethyl ether...,, -, 0 Ethyl formate..., 0, -, -, -0 Ethyl heptanoate...- Ethyl hexadecanoate...- Ethyl hexanoate...- -Ethyl hexanoic acid...0 -Ethyl--hexanol...0, 0 Ethyl isovalerate...- Ethyl mercaptan...,, - Ethyl methacrylate...,,, Ethyl methyl sulfide... Ethyl morphine... Ethyl nonanoate...- Ethyl octadecanoate...- Ethyl octanoate...- Ethyl parathion... Ethyl pentadecanoate... Ethyl pentadecanoate nonadecane... Ethyl pentanoate...- α-ethylphenethyl alcohol...0, 0 b-ethylphenethyl alcohol...0, 0 -Ethylphenol...0 -Ethylphenol...0 Ethyl--phenyl oxiran carboxylate... Ethyl propanoate... Ethyl propionate...-, -, - Ethyl tetradecanoate...- -Ethyltoluene... m-ethyltoluene..., p-ethyltoluene..., Ethyl undecanoate...- Ethyl valerate... Ethyl vinyl ether... Etridiazole...0,, 0-, Eucalyptol...- Eugenol..., iso-eugenol... Evernyl... Eugenyl acetate...- Eugenyl methyl ether... F Farnescene... b-farnesene... t-b-farnesene... trans-b-farnesene..., Farnesol... Farnesol... Farnesol acetate... Farnesol isomer... Farnesyl acetate... Fenamiphos...-, Fenarimol..., Fenchone... Fenchyl acetate... Fenitrothion..., Fentanyl...0, - Fenthion... Fenvalerate... Florazone...- Flunitrazepam...,, -0 Fluoranthene...0,,, 0 Fluorene...0,,,, 0, Fluorobenzene...,,,,, - -Fluorobiphenyl... -Fluorophenol... Flurazepam...0, Fluridone..., - Fonofos... Formaldehyde...0,, Formaldehyde-DNPH... Formaldehyde-PFBHA... Formic acid...0, 0, 0 Frambinone (raspberry ketone)...- Fucitol... Furan... Furfural...-, Furfuryl alcohol...0, 0 G Galactitol...- Geranial...-, Geranial acetate... Geraniol...-, 0,,,, cis-geraniol... trans-geraniol... Geranyl acetate..., -,, Geranyl butyrate... Geranyl formate...- Geranyl--methyl valerate... Geranyl tiglate...- Germacrene-d...,,, Gesatamine (atraton)... Glucitol... Glucuronic acid... Glucuronic acid-,-lactone... Glutethimide...0, Glycidol...0, 0 Glyme...0 Glyme (propylene glycol dimethyl ether)..., 0 GOAL...,-Guaiadiene... α-gurjunene... H Halazepam..., 0 Haloperidol... Halothane... Helium... Heneicosane... Heneicosanoic acid methyl ester...,,-hepatanediol...0 Heptachlor...0, 0,, -,, 0-, -0

188 COMPOUND INDEX Heptachlor epoxide...0, 0,, -,, 0-, -0,,',,',,',-Heptachlorobiphenyl... Heptadec--ene... Heptadecane... n-heptadecane... Heptadecanoic acid methyl ester..., cis-0-heptadecenoic acid methyl ester..., Heptanal..., -,-Heptandiol..., 0 Heptane...,, 0,,,,, -0 n-heptane...,, -, -,,, 0 Heptanoic acid...0, 0, n-heptanoic acid...0 -Heptanol..., 0, 0-0 -Heptanol...0, 0 -Heptanol...0, 0 -Heptanone... -Heptanone... -Heptanone... cis--hepten--ol...0, 0 trans--hepten--ol...0, 0 Hercolyn D (tetrahydro & dihydro methyl abietate)... Heroin...,, -, Hexabromobenzene (HBB)... Hexabromobiphenyl... Hexacosane...0 Hexachlorobenzene...0,, 0,, -0, Hexachlorobezene...,,',,',,'-Hexachlorobiphenyl... Hexachlorobutadiene...,,, -,,, 0, Hexachloro-,-butadiene... b-hexacholorcyclohexane... δ-hexacholorcyclohexane... γ-hexacholorcyclohexane... Hexachlorocyclopentadiene...0,,,,, 0, Hexachloroethane...,,,, 0, Hexachloropentadiene...-0 Hexadecane...0 n-hexadecane..., Hexadecanoic acid...0,-hexadienal... Hexanal..., -,-Hexandiol... Hexane...,,, 0, -,, -0 n-hexane...,, -, -, -,,, 0,-Hexanediol...0 Hexanoic acid... Hexanol..., -, - -Hexanol..., 0, 0 -Hexanol...0, 0 -Hexanol...0, 0 -Hexanone...,,, -Hexanone... n-hexatriacontane... Hexazinone...-, - Hexchlorocyclopentadiene...0 cis--hexen--ol...0, 0 cis--hexen--ol...0, 0 cis--hexene...- trans--hexene...- Hexobarbital..., Hexyl acetate...- Hexyl butyrate... Hexyl cinnamaldehyde... Hexyl cinnamic aldehyde... Hexylene glycol...- Hexyl -ethylhexyl phthalate... -Hexyl mercaptan... n-hexyl mercaptan... Hexyl methacrylate... α-humulene... Hydrocarbon... Hydrocodone..., Hydrogen oxide... Hydrogen sulfide...0, -,,,,, 0, 0, Hydroxy acetate...0 Hydroxy citronellal...-,, -Hydroxy--methyl--pentanone...0, 0 Hydroxyphenamate... Hydroxypropionitrile... Hydroxypropyl acrylate... Hydroxyzine... I Ibogaine...0, Ibuprofen..., Imipramine... Indan...- Indeno[,,-c,d]pyrene...0, 0,,, Inositol... Iodobenzene...- Iodoform...0, Iodomethane...,,, 0, Irgafos... Irganox... Isoamyl acetate...,, - Isoamyl alcohol...,, -0 Isoamyl butyrate... Isoamyl mercaptan... Isoamyl salicylate..., 0 Isoborneol...-0, Isobutane...-, Isobutanol...,,,, 0, 0, - Iso-butene... Isobutyl acetate..., -, -,, - Isobutyl acrylate...- Isobutyl alcohol... Isobutyl aldehyde..., Isobutylbenzene..., 0, - Isobutylene...- Isobutyl mercaptan... Isobutyl propionate...- Isobutyraldehyde..., 00,, Isobutyric acid...0, 0, 0-0 Isocaproic acid...0, 0 Isodrin...0,, -0 Isoeugenol... trans-isoeugenol... Isomenthol... Isomenthone..., - d-isomethone... Isonox... Isooctane..., -, -, -, Isopentane..., -, Isopentanoic acid...0 Isophorone...,, Isoprene...- Isopropanol...,, 0, 0, -,, 0 Isopropyl acetate...-,, Isopropyl acrylate...- Isopropyl alcohol...,, -, -0 Isopropyl amine...-0 Isopropyl benzene...,, -,,,,,, 0, - Isopropyl ether... Isopropyl mercaptan... Isopropyl myristate...- -Isopropylphenol...0 Isopropyltoluene... -Isopropyltoluene...- p-isopropyltoluene...,, Isovaleraldehyde..., 00 Isovaleric acid...0, 0 J Jasmolin I... Jasmolin II... cis-jasmone..., K Kelthane...0, -0 Kepone... Ketamine..., Krypton... L L--Carboxy--nor-δ-THC... L--Hydroxy-δ-THC... Lactose... Lactulose... Lauric acid methyl ester..., Lavandulol... Lavandulyl acetate... Levulinic acid...0 Lidocaine...0,, Lignoceric acid methyl ester..., Lilial..., Limonene..., -0, -,, δ-limonene...-, S-(-)-Limonene... Linalool..., -, - b-linalool... Linalool acetate... cis-linalool oxide...- trans-linalool oxide...- Linalyl acetate...-0 Linoleic acid methyl ester..., Linolelaidic acid methyl ester..., Linolenic acid methyl ester..., γ-linolenic acid methyl ester..., Lofentanyl... Lorazepam..., -0 Lormetazepam... Lyral... Lyral... Lyral... Lysergic acid diethylamide (LSD)...0,

189 COMPOUND INDEX M b-maaliene... Malathion...,,, Manitol... Mannitol... Meclizine... Medazepam..., 0 Menthofuran... Menthol (MeOH)..., 0,,, Menthone...- Menthyl acetate... Meperidine..., Mephobarbital... Mepivacaine... Meprobamate..., Merphos..., Mescaline... Mesitylene... Mesterolone... Methacrolein..., - Methacrylic acid...0 Methacrylonitrile...,,, - Methadone...-0, Methamidophos..., Methamphetamine...,, Methane...,, 0, -, -, 0,, - Methanethiol... Methanol...,, -, -, 00-0, 0-0,, -, -,, -, - Methapyrilene..., Methaqualone...0, Methidathion..., Methofuran... Methohexital... Methone... Methoprene... Methoxychlor...0, 0,, -,, 0-, -0 -Methoxyethanol...0, 0, bis(-methoxyethyl) phthalate... -Methoxy--methylaniline... -Methoxy--propanol... Methsuximide... Methyl acetate...-, -, Methyl acetylene... Methyl acrylate...,,, - Methyl alcohol... Methylamine...0 -Methylaminorex... r-methylansiole... -Methylanthracene...0 -Methylanthracene...0 Methyl arachidate... Methyl benzoate...-,, - -Methylbenzo[b]thiophene... -Methylbenzothiophene... -Methyl butanal... -Methylbutane... -Methyl--butanol..., 0, 0, -Methyl--butanol...0, 0 -Methyl--butanol..., 0, 0,, -Methyl--butanone..., -Methyl--buten--ol...0, 0 -Methyl--buten--ol...0, 0 -Methyl--butene... -Methyl--butene..., -, -Methyl--butene...- trans--methyl--butenoic acid...0 -Methylbutyl acetate...- -Methylbutyl alcohol...- -Methylbutyl alcohol...- Methyl t-butyl ether (MTBE)...,,, -0 Methyl butyrate...- -Methyl butyric acid...0 Methyl chavicol... -Methylcholanthrene...0 -Methyl--chlorophenoxyacetic acid (MCPA)... Methyl chlorophenoxypropionic acid (MCPP)... -Methylchrysene...0 Methyl-cresol... Methyl-p-cresol... Methyl-r-cresol... Methylcyclohexane...-,,,, Methylcyclopentane..., -,, -Methyl--cyclopentene... Methyl decanoate... Methyl-,-dichlorophenylacetate... Methyl diethanolamine (MDEA)...0 -Methyl-,-dimethoxyamphetamine (STP)... -Methyl-,-dinitrophenol..., -, 0 Methyl dodecanoate... Methyl eicosenoate... Methyl elaidate..., -Methylenedianiline...,-Methyl enedioxyamphetamine...,-methyl enedioxyethylamphetamine...,-methyl enedioxymethamphetamine... Methyl ethyl ketone (-butanone)..., 0 Methyl isobutyl ketone (MIBK)... α-methyl ionone...0 Methyl cis-,0-methylene octadecanoate... Methyl cis-,0-methyl hexadecanoate... Methylene chloride...,, -, -,, 0,, -,, -0 Methylenedioxyamphetamine (MDA)..., Methylenedioxyethylamphetamine (MDE)..., Methylenedioxymethamphetamine (MDMA)..., Methyl ephedrine... -Methyl--ethylbenzene... -Methyl--ethylbenzene... -Methyl--ethylbenzene... Methyl ethyl ketone (MEK)..., -, 0 Methyl ethyl sulfide... Methyl eugenol... -Methylfluoranthene...0 Methyl formate...- Methyl γ ionone Methylglucose Methylglucose... Methyl heptadecanoate... -Methylheptane..., -, -Methylheptane...-, -Methylheptane... Methyl heptine carbonate..., Methyl hexadecanoate... -Methylhexane...-, -Methylhexane...-, Methyl -hydroxydecanoate... Methyl -hydroxydodecanoate... Methyl -hydroxydodecanoate... Methyl -hydroxyhexadecanoate... Methyl -hydroxytetradecanoate... Methyl -hydroxytetradecanoate... Methyl isobutyl ketone...- Methyl laurate... Methyl mercaptan...0,,, - Methyl methacrylate...,,, - Methyl -methylhexadecanoate... Methyl -methyltetradecanoate... Methyl monoethanolamine (MMEA)...0 Methyl myristate... -Methylnaphthalene...0, -Methylnaphthalene..., 0, - -Methyl--nitroaniline... Methyl nonadecanoate... Methyl octadecanoate... Methyl octine carbonate..., Methyl oleate... Methyl palmitate... Methyl palmitoleate... Methyl paraoxon... Methyl parathion... Methyl pentadecanoate... -Methylpentane...-,, -Methylpentane...0, -,,, -Methyl- pentanol... -Methyl--pentanol...0 -Methyl--pentanol...0, 0-0 -Methyl--pentanone... -Methyl--pentanone (MIBK)...,,, -Methyl--pentene...-, -Methyl--pentene...- bis(-methyl--pentyl) phthalate... α-methylphenyl alcohol...0 -Methylphenol..., -Methylphenol... -Methylphenol..., -Methyl--phenylhydantoin... -Methyl--propanethiol...-,, -Methyl--propanethiol...-, -Methyl--propanol (isobutanol) Methyl--propanol (tert-butanol)...00, Methyl propionate...-, - -Methyl--propnaethiol..., -Methyl--propylbenzene... -Methyl--propyl mercaptan... -Methyl-propyl mercaptan... -Methyl--propyl mercaptan... -Methyl--pyrrolidine...0 -Methyl--pyrrolidinone...- n-methylpyrrolidone... Methyl stearate... α-methylstyrene...,, - -Methylstyrene...- Methyl sulfide... Methyl tert-butyl ether (MTBE)...,,, -,, 00,, α-methyltestosterone... Methyl tetradecanoate... -Methylthiophene... -Methylthiophene... Methyl thiophenes... Methyl tridecanoate... Methyltripentyltin...

190 COMPOUND INDEX Methyl undecanoate... Metolachlor...,, 0, - Metribuzin...,, 0, - Mevinphos...,,, MGK-..., Endo-MGK..., Exo-MGK..., Mirex...0,,, -0 Molinate..., - -Monoacetylmorphine... Mono ethylene glycol...0 Mono-ethanolamine (MEA)...0 Monuron... Morphine...,, Musk T (ethylene brassylate)...- Musk ketone...0 Musk xylene...0 Myrcene..., -0, - b-myrcene...- Myristic acid methyl ester..., Myristoleic acid methyl ester..., N Naled... Naphthalene..., -, 0, 0,,,,, 0,, -,,, -, Naphthalene-d..., -Naphthol...0 Napropamide..., - Nefopam... Neomenthol...0, Neon..., Neral...-, - Nerol... Nerol acetate... cis-nerolidol... trans-nerolidol... Nervonic acid methyl ester..., Neryl acetate...-, Nicotinamine... Nicotine...-, Nitrazepam...,, -Nitroaniline..., 0, -Nitroaniline..., 0, -Nitroaniline..., 0, Nitrobenzene...,,,, - Nitrobenzene-d... -Nitrobiphenyl...0 -Nitrobiphenyl...0 -Nitrobiphenyl...0 Nitrofen...0 Nitrogen...,, 0, Nitromethane... -Nitronaphthalene...0 -Nitronaphthalene...0 Nitrophen... -Nitrophenol...,, -, 0, 0 -Nitrophenol... -Nitrophenol...,,, -, 0 -Nitropropane...,, n-nitrosodimethylamine..., n-nitrosodiphenylamine... n-nitroso-di-n-propylamine... -Nitrotoluene...0, - -Nitrotoluene...0, - -Nitrotoluene...0, - trans-nonachlor...0,, -0 Nonadecane... Nonadec--ene...- Nonanal... γ-nonalactone...-,-nonandiol... Nonane...,,, 0, n-nonane...,, -, -,-Nonanediol...0, Nonanol... -Nonanol...0, 0 Nonyl aldehyde... Nonylamine...0 n-nonylamine Nootkatone... Norcodeine... Nordazepam... Norethandrolone... Norflurazon...-, - Normorphine... -Nortestosterone (nandrolone)... -Nortestosterone--decanoate... -Nortestosterone--propionate... O cis-ocimene..., trans-ocimene... b-cis-ocimene... b-trans-ocimene... Octacosane...0 n-octacosane...,',,',,',,'-octachlorobiphenyl...,,,,,,,-octachlorodibenzodioxin...0,,,,,,,-octachlorodibenzofurans...0 Octadecane...0, n-octadecane... Octadecanoic acid...0 Octanal...,,,-Octandiol... Octane...,,, 0, isooctane...0 n-octane...,, -, -,-Octanediol...0 Octanoic acid...0, Octanol...-,, -Octanol...0, 0 -Octanol..., -Octanone..., -Octene... -Octen--ol..., Octen--ol acetate... Octyl acetate...- -Octyl acetate..., Octyl aldehyde... n-octylamine n-octyl mercaptan... Oleic acid methyl ester..., Omethoate... Ordram... Oxadiazon... Oxazepam..., -0 Oxazopam... Oxychlordane... Oxycodone..., Oxydemeton-methyl..., -Oxydianiline... Oxygen..., Oxymetholone... Oxymorphone... P Paarlan... Palmitic acid methyl ester..., Palmitoleic acid methyl ester..., Paraldehyde... Parathion..., Parathion-methyl... Pebulate...- Pentaborane...,',,,'-Pentabromodiphenyl ether...0,',,',-pentabromodiphenyl ether...0,',,',-pentabromodiphenyl ether...0 Pentachlorobenzene...-,',',,-Pentachlorobiphenyl...,,,,-Pentachlorodibenzofuran...0,,,,-Pentachlorodibenzofuran...0 Pentachloroethane...,,, 0, Pentachloronitrobenzene...0,,, -0 Pentachlorophenol...,,,, -, 0 n-pentadecane...,, Pentadecanoic acid methyl ester..., cis-0-pentadecenoic acid methyl ester..., cis-,-pentadiene...- trans-,-pentadiene...- Pentafluorobenzene...,, Pentafluoroethane... Pentamethylbenzene... Pentamethyl disiloxane... Pentanal...,-Pentandiol... Pentane..., 0, 0,, - iso-pentane..., 0-, 0 n-pentane..., -, -,-Pentanediol...,-Pentanediol...0, Pentanedione (VDK)...,-Pentanedione (acetyl propionyl)...- n-pentanoic acid...0 -Pentanol..., 0, 0-0,, -Pentanol...0, 0 -Pentanol..., 0, 0 -Pentanone...,, -Pentanone... Pentene-..., - -Pentene...-, -,, cis--pentene..., - trans--pentene..., - -Pentenoic acid...0 trans--pentenoic acid...0 trans--pentenoic acid...0 -Penten--ol...0, 0 -Penten--ol...0, 0 Pentobarbital..., Pentyl ether... -Pentyl mercaptan... cis-permethrin...0,,, 0-,, -0 0

191 COMPOUND INDEX trans-permethrin...0,,, 0-,, -0 Perthane...0, -0 Perylene...0 Perylene-d...-,, α-phellandrene... Phenacetin..., Phenanthrene...0,,,, 0 Phenanthrene-d0...,, Phencyclidine (PCP)..., 0,, Phenethylalcohol... Pheniramine... Phenmetrazine... Phenobarbital..., 0-, - Phenol..., -, 0,,, -, 0, 0 Phenol-d... -Phenoxyethanol...0, 0 Phensuximide... Phentermine..., Phenyl acetaldehyde..., Phenylacetone... Phenylacetylene..., -Phenylanthracene...0 Phenyl ephedrine... -Phenyl ethyl acetate... Phenylethylamine...0 Phenyl ethyl cinnamate...- Phenylethylmalonamide... Phenyl ethyl tiglate...- -Phenylnaphthalene...0 Phenyltoin... Phenyltoloxamine... Phenytoin... Phorate... Phosmet... Phosphine... Phylethylmalonamide (PEMA)... Picloram... -Picoline... α-pinene...-, - b-pinene..., -0, -, Piperazine... Piperitone... Pirimiphos-methyl... Polyethylene glycol... Polymethoxyflavones... Prazepam..., 0 Prebane (terbutryn)... Primidone...- Procaine...,, Progesterone... Promazine... Promethazine... Prometon..., - Prometryn...-, - Promofos... Pronamide..., - Propachlor...0,,, 0-,, -, -0 Propadiene...-, Propanal... -Propanamine...,-Propandiol...,-Propandiol (propylene glycol)... Propane...0, -,,, 0,,-Propanediol (propylene glycol)...0,-propanediol...0 -Propanethiol...-, -Propanethiol...-,, Propanil... Propanoic acid... Propanol...0 -Propanol...,,, 00, 0, 0-0, -,, -, -0 -Propanol...,,, n-propanol...,,, 0 Propargyl alcohol... Propazine...-, - Propene... -Propen--ol (allyl alcohol)...0, 0 Propiolactone... Propiomazine... Propionaldehyde..., 00, Propionic acid...0,, 0, 0 -Propionic acid... Propionitrile...,,, 0, - Proposyphene... Propyl acetate..., -, n-propyl acetate... Propylbenzene..., -,, -, n-propylbenzene...,, -,, -,, -, 0, Propyl benzoate...- Propyl butyrate... Propyl caproate... Propylene..., -0, -, 0, Propylene glycol...0, 0 Propyl ether..., n-propyl ether... Propyl formate...- -Propyl mercaptan... -Propyl mercaptan... n-propyl mercaptan... -Propyl pentanoic acid...0 Propyl propionate...- Propyl valerate... Propyne...0, -, - -Propyn--ol (propargyl alcohol)...0, 0 Prowl... Psilocin... Pulegone... Pyrazole...0 Pyrene...0,,,, 0 Pyrene-d0... Pyrethrin I... Pyrethrin II... Pyridazine...0 Pyridine...,, 0, -,, 0 Pyrilamine... Pyrimidine...0 Pyrimiphos ethyl... Pyrimiphos methyl... Pyrithyldione... Pyrrobutamine... Q Quinine... R Rhamnitol...- Rhamnose... Rhamnose... Ribitol...- Ribose... Ro-Neet... Rosatol (rosetone)... Rosatol (rosetone) geranyl butyrate... Rose oxide, cis-rose...- Rose oxide, trans-rose...- S Sabinene...,, - trans-sabinene hydrate..., Salicylamide... α-santolene... Secbumeton... Secobarbital..., Selenide... Sencor... Simazine...,, 0, -, Simetryn..., - α-sinensal... b-sinensal... Sorbitol... Stanozolol... Stearic acid methyl ester..., Stigmasterol... Stirifos... Strawberry aldehyde... Strychnine..., Styrene...,,,, -,,, -,, 0, -,, Styrene dimer... Styrene oxide..., Styrene trimer... Sucrose... Sufentanyl... Sulfallate... Sulfur dioxide...0, Sulpiride... Sutan... T Talbutal..., Tebuthiuron..., Temazepam...,, -0 Tenocyclidine (TCP)... Terbacil..., - Terbufos..., -, Terbufos sulfone... Terbuthylazine... Terbutryn...- Terphenyl-d... Terpinene... α-terpinene..., - γ-terpinene..., -, -, Terpinen--ol...-, -, -, α-terpineol..., -0, -, Terpinolene...,, - γ-terpinolene... Terrazole..., -0

192 COMPOUND INDEX Testosterone...,',,'-Tetrabromodiphenyl ether...0,',,'- Tetrabromodiphenyl ether...0,',',- Tetrabromodiphenyl ether...0 Tetraborane... Tetrabutyltin... Tetracaine...,,,-Tetrachlorobenzene...-,',,'-Tetrachlorobiphenyl...,,--Tetrachlorodibenzodioxin (TCDD)...0,,,- Tetrachlorodibenzofuran (TCDF)...0 Tetrachloroethane...0, 0,,,-Tetrachloroethane...,, -,, 0,,,,-Tetrachloroethane...,,,, -,, 0, Tetrachloroethene...,, -,, Tetrachloroethylene... Tetrachloro-m-xylene (TCMS)...0, 0, -, 0,, -0,,,,-Tetrachloro-m-xylene...-,,,-Tetrachlorophenol...0,,,,-Tetrachlorophenol...0,,,,-Tetrachlorophenol...0, - Tetrachlorvinphos (stirifos)... n-tetracontane... Tetracosane...0 n-tetracosane... Tetradecane...0, n-tetradecane...,, Tetradecanoic acid...0 Tetraethylenepentamine...,,,-Tetrafluoroethane...,,,-Tetrafluoroethane... Tetrahydrocannabinol... δ-tetrahydrocannabinol (THC)...,,,-Tetrahydrofluoranthene...0 Tetrahydrofuran (THF)...,,,,,,, 0, Tetrahydropyran...,,,-Tetramethylbenzene...-,,,-Tetramethylbenzene..., - Tetrapentyltin... Thenyldiamine... Thiamine pyrophosphate (TPP)... Thiamylal... Thiazopyr..., -Thiodianiline... Thiopental... Thiophene...-,,,, Thioridazine... Thonzylamine... Threhalose... Threitol... Thujone... α-thujone..., b-thujone... Tillam..., Tinuvin P... α-tocopherol... b-tocopherol... δ-tocopherol... γ-tocopherol... Tolban... o-tolidine... m-tolualdehyde... o-tolualdehyde... p-tolualdehyde... Toluene..., -, 0,,, -, -,,,, -, -, -,, 0, 0, -, -,,,, - Toluene-d..., o-toluidine... Tonalid...-0 Trazodone... Treflan...,',-TriBDE (BDE-)...0,,'-TriBDE (BDE-)...0 Triacetonamine (TAA)... Triadimefon..., Triazolam..., 0 Tribromoacetic acid...,,-tribromophenol... Tributylpentyltin... Trichloroacetic acid... Trichloroacetonitrile...0,,,-Trichloroaniline...,,-Trichlorobenzene...,, -,, -,,-Trichlorobenzene...,,, -, -,, -,,-Trichlorobenzene..., -,,-Trichlorobiphenyl... Trichloroethane...0, 0,,-Trichloroethane...-0,,-Trichloroethane...0, 0,,, -,, 0,,,,,-Trichloroethane...0, 0,,, -, -,, 0, Trichloroethene...,, -,, Trichloroethylene...,,,, 0 Trichlorofluoromethane...,,, -,,,,,-trichloro-,,-trifluoroethane)... Trichloromethane...- Trichloromethyl silane...,,-trichlorophenol...0, -,,-Trichlorophenol...0, -,,-Trichlorophenol...0, -,,-Trichlorophenol...0,, -,,-Trichlorophenol...0,,, -, 0,,-Trichlorophenol... 0,,,-Trichlorophenoxyacetic acid...,,-trichloropropane...0, 0,,, -,,, 0,,,-Trichloropropanone...,,-Trichloro--propanone...0,,-Trichloro-,,-trifluoroethane...,,,-Trichlorotrifluoroethane...0, Tricosanoic acid methyl ester..., Tricyclazole..., - Tridecane...-, n-tridecane..., Tridecanoic acid methyl ester..., Triethanolamine (TEA)...0, 0 Triethylamine...0, - Triethylene glycol... Triethylenetetramine...,,-Trifluoroethane... Trifluoromethane... Trifluorotoluene... Triflupromazine... Trifluralin...0,,, 0-,, -0, Triglyme (triethylene glycol dimethyl ether)..., 0 Trimethylamine...0,,-Trimethylaniline...,,-Trimethylbenzene (hemimellitene)...,, -,, 0, -,,-Trimethylbenzene (pseudocumene)...0,,, -, -,,, -, -, -,,,-Trimethylbenzene (mesitylene)...,, -, -,, -, -, - Trimethylchloro silane...,,-trimethylhexanol...-,,-trimethylpentane (isooctane)...,,-trimethylpentane...,,,-trimethylpentane...-,,-trimethylphenol...0 Trimethyl phosphate... Trimipramine...0,,-Trinitrophenol...0,,-Trioxane impurity... Tripelennamine... Triphenyl phosphate...,, Triprolidine... U Undecane...,,, n-undecane..., 0,, - Undecanoic acid methyl ester..., V Valencene... Valeraldehyde (pentanal)..., 00, Valeric acid (pentanoic acid)...0, 0, 0, iso-valeric acid... Valerolactone...0 Vanillin... Verapamil... Vernam... Vernolate..., - Vertenex...- Vinclozolin..., Vinyl acetate..., - Vinyl chloride...,, -, -, Vinyl-trimethyl silane... Viridiflorol..., W Water...,, 0 X Xenon... m-xylene...,, -, -,, -, -, -, -,, 0, 0, -,,, m,p-xylene...0,, -

193 COMPOUND INDEX o-xylene...0,,, -, -,, -, -, -, -,, 0, 0, -,,,,, - p-xylene...,, -, -,, -, -, -, -,, 0, 0, -,,,,-Xylenol...0,-Xylenol...0,-Xylenol...0,-Xylenol...0,-Xylenol...0,-Xylenol...0 Xylose... Xylose...

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215 ENSURING AN INERT GC FLOW PATH HAS NEVER BEEN MORE CRITICAL For labs that need to perform trace level analysis on very active compounds, Agilent Inert Flow Path solutions ensure a reliably inert flow path for higher sensitivity, accuracy, and reproducibility. These analyses can now be done with the utmost confidence because each lot of Agilent Inert Flow Path components are qualified using chromatographic QC tests to provide reliable, consistent inertness that spans the entire flow path.. MSD Ion Source. UltiMetal Plus Split/Splitless Inlet. Ultra Inert Inlet Liners. Ultra Inert Gold Plated Inlet Seals. Gas Clean Filter System. Ultra Inert Capillary Column. UltiMetal Plus Capillary Flow Technology Dean Switch. UltiMetal Plus Flexible Metal Ferrules 0B GC configured with A Series GC/MSD and A Automatic Liquid Sampler Learn more about creating an inert flow path, and order the poster at agilent.com/chem/inert